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Patent Searching and Data


Title:
METHOD FOR PRODUCING α,β-UNSATURATED ALDEHYDE
Document Type and Number:
WIPO Patent Application WO/2019/116608
Kind Code:
A1
Abstract:
The purpose of the present invention is to provide a method for producing an aldehyde, wherein a desired aldehyde can be obtained with a high selectivity and the formation of byproducts can be suppressed. The present invention pertains to a method for producing an α,β-unsaturated aldehyde, the method comprising a step for reacting a compound of formula (I) with a compound of formula (II) to obtain an α,β-unsaturated aldehyde of formula (III), wherein in said step, an alkali metal hydroxide and a C1-4 alkanol are used, the amount of the alkali metal hydroxide is 8-12 mol% with respect to the compound of formula (I), and the total amount of water contained in the raw materials used in the reaction is 10-15 mol% with respect to the compound of formula (I).

Inventors:
ARAI Tsubasa
MASUMURA Kensuke
KARASU Kensuke
NAKAGAWA Yuki
Application Number:
JP2018/022404
Publication Date:
June 20, 2019
Filing Date:
June 12, 2018
Export Citation:
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Assignee:
KAO CORPORATION (14-10, Nihonbashi Kayabacho 1-chome Chuo-k, Tokyo 10, 〒1038210, JP)
International Classes:
C07C45/74; C07C47/232
Foreign References:
CN101265167A2008-09-17
JP2007153818A2007-06-21
JP2003511431A2003-03-25
JPH0314535A1991-01-23
Other References:
VASHISHTHA, MANU ET AL.: "A novel approach for selective cross aldol condensation using reusable NaOH-cationic micellar systems", APPLIED CATALYSIS, A: GENERAL, vol. 466, 2013, pages 38 - 44, XP028695514, DOI: doi:10.1016/j.apcata.2013.06.015
Attorney, Agent or Firm:
IKEUCHI & PARTNERS (26th Floor, OAP TOWER 8-30, Tenmabashi 1-chome, Kita-ku, Osaka-sh, Osaka 26, 〒5306026, JP)
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