Title:
METHOD FOR SEPARATING 2-ALKYL ANTHRACENE AND USE OF 2-ALKYL ANTHRACENE IN PREPARATION OF HYDROGEN PEROXIDE
Document Type and Number:
WIPO Patent Application WO/2020/211572
Kind Code:
A1
Abstract:
The present invention relates to a method for preparing 2-alkyl anthracene, comprising the following step: separating 2-alkyl anthracene from a reaction product of an anthracene alkylation reaction, the anthracene alkylation reaction being a reaction of anthracene and an alkylation agent under an alkylation condition in presence of an alkylation reaction solvent and a catalyst, wherein the reaction product of the anthracene alkylation reaction comprises anthracene and a series of alkyl anthracene products comprising 2-alkyl anthracene, and preferably, the alkyl is C4-C7 alkyl.
Inventors:
ZONG BAONING (CN)
ZHENG BO (CN)
ZHU ZHENXING (CN)
PAN ZHIYONG (CN)
QIE SIYUAN (CN)
GAO GUOHUA (CN)
FEI JIANQI (CN)
MAO JUNYI (CN)
TANG XIAOJIN (CN)
HU LIFENG (CN)
LIU ZHENG (CN)
ZHENG BO (CN)
ZHU ZHENXING (CN)
PAN ZHIYONG (CN)
QIE SIYUAN (CN)
GAO GUOHUA (CN)
FEI JIANQI (CN)
MAO JUNYI (CN)
TANG XIAOJIN (CN)
HU LIFENG (CN)
LIU ZHENG (CN)
Application Number:
PCT/CN2020/078563
Publication Date:
October 22, 2020
Filing Date:
March 10, 2020
Export Citation:
Assignee:
CHINA PETROLEUM & CHEM CORP (CN)
SINOPEC RES INST PETROLEUM (CN)
SINOPEC RES INST PETROLEUM (CN)
International Classes:
C07C7/00; C07C2/66; C07C2/70; C07C15/28; C07C46/04
Domestic Patent References:
| WO2003016436A1 | 2003-02-27 |
Foreign References:
| CN109704910A | 2019-05-03 | |||
| CN109704910A | 2019-05-03 | |||
| CN109574779A | 2019-04-05 | |||
| CN109574779A | 2019-04-05 | |||
| CN107602368A | 2018-01-19 | |||
| CN107602368A | 2018-01-19 | |||
| CN107746372A | 2018-03-02 | |||
| US4255343A | 1981-03-10 | |||
| US4255343A | 1981-03-10 | |||
| CN107744828A | 2018-03-02 | |||
| CN1690035A | 2005-11-02 | |||
| CN106542502A | 2017-03-29 | |||
| CN106995402A | 2017-08-01 | |||
| US4255343A | 1981-03-10 | |||
| TW200623958A | 2006-07-01 | |||
| US3953482A | 1976-04-27 |
Other References:
PAUL MÜELLER ET AL.: "Rh-catalyzed oxidation of anthracenes to anthraquinones using t-butylhydroperoxide", TETRAHEDRON LETTERS, vol. 24, no. 49, 2 April 2001 (2001-04-02), XP055743763, ISSN: 0040-4039
MIN CHEN ET AL.: "Alkylation of anthracene to 2-isopropylanthracene catalyzed by Lewis acid ionic liquids", KOREAN JOURNAL OF CHEMICAL ENGINEERING, vol. 26, no. 6, 16 February 2010 (2010-02-16), XP055743767, ISSN: 0256-1115
GERRIT WIENHÖFER ET AL.: "A Novel Process for Selective Ruthenium-Catalyzed Oxidation of Naphthalenes and Phenols", ADVANCED SYNTHESIS & CATALYSIS, vol. 352, no. 10, 30 June 2010 (2010-06-30), pages 1615 - 1620, XP055743770, ISSN: 1615-4150
A. E. GEKHMAN ET AL.: "Role of the V(V)/1O2 Complex in Oxidative Reactions in the H2O2/V(V)/AcOH System: Oxidation of Alkenes and Anthracenes", KINETICS AND CATALYSIS, vol. 42, no. 4, 31 July 2001 (2001-07-31), XP055743771, ISSN: 0023-1584
See also references of EP 3957621A4
MIN CHEN ET AL.: "Alkylation of anthracene to 2-isopropylanthracene catalyzed by Lewis acid ionic liquids", KOREAN JOURNAL OF CHEMICAL ENGINEERING, vol. 26, no. 6, 16 February 2010 (2010-02-16), XP055743767, ISSN: 0256-1115
GERRIT WIENHÖFER ET AL.: "A Novel Process for Selective Ruthenium-Catalyzed Oxidation of Naphthalenes and Phenols", ADVANCED SYNTHESIS & CATALYSIS, vol. 352, no. 10, 30 June 2010 (2010-06-30), pages 1615 - 1620, XP055743770, ISSN: 1615-4150
A. E. GEKHMAN ET AL.: "Role of the V(V)/1O2 Complex in Oxidative Reactions in the H2O2/V(V)/AcOH System: Oxidation of Alkenes and Anthracenes", KINETICS AND CATALYSIS, vol. 42, no. 4, 31 July 2001 (2001-07-31), XP055743771, ISSN: 0023-1584
See also references of EP 3957621A4
Attorney, Agent or Firm:
CHINA PATENT AGENT (H.K.) LTD. (CN)
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