Title:
METHOD FOR SYNTHESIZING COMPOUND CONTAINING NON-TERMINAL DOUBLE BOND
Document Type and Number:
WIPO Patent Application WO/2017/173975
Kind Code:
A1
Abstract:
Disclosed in the present application is a process for the preparation of a compound III containing a non-terminal carbon-carbon double bond, characterized in that, a compound I containing a carbon-carbon double bond, in the presence of a catalyst, is subjected to a coupling reaction with a peroxide II to prepare the compound containing the non-terminal carbon-carbon double bond. By introducing the peroxide, which acts as an efficient and controllable alkylating agent, into the reaction, the compound containing the non-terminal double bond is prepared. The method has the advantages of cheap raw material and catalyst, mild reaction condition, simple operation and high reaction efficiency.
Inventors:
BAO HONGLI (CN)
GE LIANG (CN)
ZHU NENGBO (CN)
JIAN WUJUN (CN)
ZHOU HUAN (CN)
CHEN SHAOWEI (CN)
FENG WEIWEI (CN)
GE LIANG (CN)
ZHU NENGBO (CN)
JIAN WUJUN (CN)
ZHOU HUAN (CN)
CHEN SHAOWEI (CN)
FENG WEIWEI (CN)
Application Number:
PCT/CN2017/079432
Publication Date:
October 12, 2017
Filing Date:
April 05, 2017
Export Citation:
Assignee:
FUJIAN INST RES STR MATTER CAS (CN)
International Classes:
C07C1/20; C07B37/00; C07C2/86; C07C13/465; C07C15/44; C07C17/263; C07C41/30; C07C43/215; C07C67/293; C07C69/145; C07C209/68; C07C211/27
Foreign References:
| JPH0482860A | 1992-03-16 |
Other References:
YOSHIDA, M. ET AL.: "Heptafluoropropylation of electron-rich olefins with bis (heptafluorobutyryl) peroxides", CHEMISTRY LETTERS, vol. 14, no. 6, 30 June 1985 (1985-06-30), pages 755 - 758, XP003032483, ISSN: 0366-7022
LI, Y ET AL.: "Copper-Catalyzed Regioselective 1,2-Alkylesterification of Dienes to Allylic Esters", ORGANIC LETTERS, vol. 18, no. 3, 20 January 2016 (2016-01-20), pages 392 - 395, XP055427704, ISSN: 1523-7052
LI, Y ET AL.: "Copper-Catalyzed Regioselective 1,2-Alkylesterification of Dienes to Allylic Esters", ORGANIC LETTERS, vol. 18, no. 3, 20 January 2016 (2016-01-20), pages 392 - 395, XP055427704, ISSN: 1523-7052
Attorney, Agent or Firm:
PERIODIC LAW FIRM (CN)
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