AMENDED CLAIMS

received by the International Bureau on 02 February 2015 (02.02.2015)

1. Liquid Fuel production Method from waste treatment, without the use of catalytic compounds, which through devices and high frequency technology applications, converts waste to liquid fuel, with friendly way to environment, by executing the following steps:

1) waste entrance to the system (2) for treatment, in any form free or packaged, preferably in pellets form produced by the method described in national patent GR1007756

2) mechanical degradation and homogenization treatment, using high frequency pulsators system

3) material UV degradation treatment to UV radiation exposure, in the range of 170nm to 450nm

4) thermal degradation, using a continuous flow special reactor (4) for the conversion of the feeding material to gaseous, exposure to temperatures between 250-600°C

5) produced reactive gases condensation to a liquid material, using a three stage system of condensers (5), exposure to temperatures up to 10°C.

6) automatic adjustment of final product ph between 4-4.5 and viscosity stabilization

7) filtering of liquid material to remove viscous fraction, tar and coal.

2. Liquid Fuel production apparatus hybrid system from waste treatment, without the use of catalytic compounds, characterized by the fact that it comprises at least:

i) a vertical cylindrical section treatment pre-chamber (3), consisting of mechanical degradation-final homogenization devices by the using of high frequency pulsators system and UV degradation exposure to UV radiation

ii) the main vertical double bottom chamber of thermal degradation- treatment (4)

iii) the three stages vertical cylindrical system of condensers (5) of gas to liquid material and simultaneously stabilization of the final viscosity and ph.

3. Liquid Fuel production apparatus hybrid system according to claim 2, which is characterized by the fact that, provided the pellet form for the 20 waste entrance is chosen, it comprises at least one conveyor system of any kind, preferably chain conveyor for the feeding of waste to the main system, while if free or packaged in any other form for the waste entrance is chosen, it is characterized by the fact that it comprises at least one conveyor system of any kind, preferably chain conveyor for the waste transportation to a treatment pre-chamber with integrated shredding system, under which there is a liquid tank with at least one special viscous pump. 4. Liquid Fuel production apparatus hybrid system according to claims 2 and 3, characterized by the fact that for the waste mechanical degradation, it is used at least one high frequency system pulsator for material homogenization which is placed in a robust metallic cylindrical construction in the vertical treatment pre-chamber (3), comprising of a rotating axis that comes vertically from at least two metallic supporting discs, which between them bear pulse elements which are mounted with a perforated axis on axes parallel to axis, while on the lower part of the metallic construction there is a metallic array of horizontal elements controlling the volume, which are situated in determined distances between them creating openings, with exit to the main vertical double- bottom thermal degradation chamber (4).

5. Liquid Fuel production apparatus hybrid system according to claims 2 to 4, characterized by the fact that for the waste UV degradation it is used at least one Stabilization Chamber of cylindrical shape and stable diameter, placed within robust metallic cylindrical structure in the vertical treatment pre-chamber (3) which possesses circumferentially on its the walls but also on the axis, special devices emitting UV radiation, those of them that are placed on the axis are covered with a special transparent material for their protection, which emit radiation in the range of 170nm to 450nm.

6. Liquid Fuel production apparatus hybrid system according to claims 2 to 5, characterized by the fact that for the waste thermal degradation a reaction chamber (4) is used which is comprised of a double wall in order to create an outer heating mantle. The special reactor is a continuous stirred flow, where the waste is subjected to temperatures between 250 - 600°C for the conversion of feeding stream to gaseous mass. The raw 21 material enters the reactor where it is stirred continuously for the large exploitation of the specific surface of the particles and the effective yield of fission reactions of carbon chain. 7. Liquid Fuel production apparatus hybrid system according to claims 2 and 6, characterized by the fact that for the thermal degradation, the use of catalytic compounds is not required, since by combining the action of mechanical and UV degradation, the material to be treated becomes unstable and thus will be degraded faster and to lower temperature.

8. Liquid Fuel production apparatus hybrid system according to claims 2, 6 and 7, characterized by the fact that the thermal degradation gets on in three stages:

First stage - Drying: This phase takes place in the temperature range up to 300°C resulting in the evaporation of moisture content of waste and of volatile components.

Second stage - Dry filtering: This phase continues at temperatures of 300 up to 500 °C by temperature increasing, most volatile components are evaporated.

Third stage - Detachment: The detachment phase continues at temperature range 500 up to 600 °C where from carbon and liquid organic materials, stable gases begin to be created.

9. Liquid Fuel production apparatus hybrid system according to claims 2 and 6, characterized by the fact that the thermal degradation takes place in an appropriate closed loop system, where no gaseous emissions exit.

10. Liquid Fuel production apparatus hybrid system according to claim 2, characterized by the fact that the produced gas mixture is led to three stage condensers dehumidification system (5), where is conversed to a liquid fraction. The three stage system (5) comprises of at least three vertical cylindrical chambers, which are attached circumferentially to the main chamber. The spacing (area distance) of the condensers is equal in order to avoid the gas static follicles formation that may cover the heat transfer surface. The condensation process gets on three stages:

In the first stage, the superheated gas is cooled to condensation temperature, below 10 °C which corresponds to the gas pressure. 22

In the second stage takes place the condensation of gas to high pressure liquid, with simultaneous emission of large amounts of heat to the environment.

In the third step, the liquefied medium is cooled a little longer, up to 5°C at a temperature lower than the condensation temperature so as the liquid medium thawing to take place.

1 1. Liquid Fuel production apparatus hybrid system according to claim 2, characterized by the fact that the produced liquid pass through an automatic system of simultaneous stabilization of final product ph between 4-4.5 and of final viscosity. It concerns at least three devices, placed along the vertical cylindrical chambers, which contain the condensing systems, which are attached perimetrically the main reaction chamber.

12. Liquid Fuel production apparatus hybrid system according to claims 2 and 1 1 , characterized by the fact that in order to increase and stabilize the final product ph between 4-4,5, a special ph adjustment system is used, that includes the product neutralization with regulated strong bases addition, and that in order to reduce the viscosity, a suitable solvent is added during the liquefaction process.

13. Liquid Fuel production apparatus hybrid system according to claim 2, characterized by the fact that the liquid end product before storage is led at least to a suitable - filtering-refining device and solid impurities discharge (viscous fuel) from the liquid product. It concerns a vertical multilayer filtering device consisting of porous media - cleaning filters.