The present application claims priority from US provisional patent application no. 62/018,874 filed on June 30, 2014, the contents of which are incorporated herein by reference. BACKGROUND OF THE INVENTION

In the agriculture industry, agronomists often have to establish and follow an agro-environmental fertilization plan when cultivating a field. Such a plan determines the spreading limits for fertilizers for a given growing season. In order to best determine the fertilization needs of a particular area of land, it is often necessary to analyze soil samples in order to measure pH, and the concentration of several minerals, such as potassium, phosphorus, magnesium, aluminum and calcium, among others. Current methods for analyzing samples involve four main steps: (1) collecting a soil sample; (2) transporting the sample to a laboratory and preparing it for analysis; (3) dissolving the sample chemically; and (4) analyzing the sample using methods such as Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-OES) or Flame Atomic Absorption Spectrometry (FAAS). These methods involve many different physical and chemical operations, both when preparing and analyzing samples. For example, many samples must be collected from several locations and prepared for transport to a lab. Next, the samples are subject to a laborious analyzing process involving drying, grinding, sieving, extracting and filtering.

Existing methods are both time consuming and expensive. For example, these methods require large individual samples (approximately 500g) from various parts of a field which must each be transported to a lab. Once at the lab, analyzing the soil may require several different tests in order to analyze different characteristics of the soil. These tests can take a significant amount of time, making the turnaround time relatively slow.

In existing methods, there is also a significant risk that samples can become contaminated and/or confused. For example, identification information is often hand-written on sample containers, making identification difficult when the identification information contains mistakably similar characters, or when it is written with poor handwriting. What's more, in order to carry out a test, a portion of a soil sample must be transferred into a separate test container, creating an opportunity to introduce contaminants or lose track of a sample.

US Patent 8,286,857 describes a soil sample tracking system and method in which soil sample containers are provided with unique identifiers. The containers are used to temporarily store the soil samples until they are analyzed. The soil samples must thus be removed from their containers for analysis, and thus there is still a risk of mixing or contaminating the different soil samples. These shortcomings have a significant impact on the use of such methods in practice. For example, due to the costs involved, many agronomists generally limit sampling to a single sample per field. This is not ideal, as it does not provide sufficiently fine-grained information about the soil characteristics of a field, and thus limits the effectiveness of an agro-environmental fertilization plan when it is based on that information.

Some improvements have already been made to the step of analyzing a sample in the laboratory. For example, soil can be analyzed using a method known as Laser Induced Breakdown Spectroscopy (LIBS), such as the method disclosed in US patent 7,692,789. While this technology is an improvement in the lab, there is yet to be a practical method for using LIBS technology in the context of gathering several samples of soil from a field and managing data from the analysis of those samples.

There is therefore a need for an improved method and system which reduces costs and simplifies the overall process of sampling and analyzing soil by leveraging LIBS technology.

SUMMARY OF THE INVENTION

It is therefore an object of the present invention to provide a method and system for improving the sampling and analysis of soil, particularly in the context of the agriculture industry. According to an aspect, a method for sampling and analyzing soil is provided. The method includes the steps of: providing a soil sample container having porous sidewalls and a unique identifier; associating, on a database, a geographic position with the unique identifier, the geographic position corresponding to a location where a soil sample was taken; receiving the soil sample container with the soil sample contained therein; compacting the soil sample while inside the soil sample container; analyzing the soil sample while inside the soil sample container using a Laser Induced Breakdown Spectroscopy (LIBS) system and generating analysis results; and associating the analysis results of the soil sample with the unique identifier of the soil sample container.

In an embodiment, the soil sample is dried while inside the soil sample container below a humidity level of approximately 10%.

In an embodiment, drying the soil sample includes heating the soil sample inside an oven at a temperature between approximately 30°C and 45°C for a period of between approximately 2 hours and 48 hours. In an embodiment, compacting the soil sample comprises hydraulically pressing the soil sample with a weight of between approximately 15 tonnes and 30 tonnes. In an embodiment, the soil sample contained in the soil sample container is between approximately 5 grams and 150 grams.

In an embodiment, a plurality of soil samples is analyzed sequentially in the LIBS system as part of a batch.

In an embodiment, analyzing the soil sample is performed in less than 60 seconds.

In an embodiment, the batch includes at least one control sample for calibrating the LIBS system; between approximately 10% and 20% of the soil samples in the batch can be control samples. In an alternate embodiment, the LIBS system can be pre-calibrated prior to analyzing the batch.

In an embodiment, the plurality of soil samples is compacted sequentially as part of a batch.

In an embodiment, the method further includes a step of loading the plurality of soil samples in a support tray, with at least one of the steps of drying, compacting, analyzing and archiving being performed while the soil samples are in the support tray.

In an embodiment, the unique identifier within the LIBS system is scanned prior to performing the analysis of the soil sample. In an embodiment, analyzing the soil sample using the LIBS system includes shining a laser on a plurality of different areas on an exposed surface of the soil sample. In an embodiment, the method further includes the steps of receiving report preferences from a user and generating a report summarizing the analysis according to the report preferences.

In an embodiment, the method further includes the step of grouping a plurality of soil sample containers in a sample group box and mailing the sample group box via a postal service.

In an embodiment, the method further includes the step of providing the sample group box with a pre-paid postage label for returning the sample group box to a lab after the soil sample containers have been filled.

In an embodiment, the plurality of soil samples is archived while inside the sample group box. In an embodiment, archiving the plurality of soil sample includes storing the plurality of soil samples within their respective soil sample containers in a climate controlled environment for a period of at least 6 months.

In an embodiment, the plurality of soil samples is archived while inside the soil sample containers.

According to an aspect, a system for sampling and analyzing soil is provided. The system includes: a plurality soil sample containers, each soil sample container including porous sidewalls and having a unique identifier associated therewith; a database associating, for each of the soil sample containers, a geographic position with the unique identifier, the geographic position corresponding to a location where a soil sample was taken; a press for compacting soil samples inside the soil sample containers, the press including at least one automated piston sized and shaped for fitting within an open-end of the soil sample containers; a LIBS system and a server. The LIBS system includes: a scanning device to scan the unique identifier associated with each of the plurality of soil sample containers; a laser head assembly and a spectrograph to analyze the soil samples while inside the soil sample containers; and to generate analysis results; a processor and a memory, the memory having stored therein instructions executable by the processor to control the scanning device, the laser head assembly and spectrograph. The server includes a processor and a memory. The server is in communication with the LIBS system and the database, with the memory having stored thereon instructions executable by the processor to receive the analysis results from the LIBS system and associate the analysis results with the unique identifiers in the database.

In an embodiment, each of the plurality of soil sample containers includes: a body including a base and the porous sidewalls, the porous sidewalls extending peripherally from the base and defining, together with the base, a cavity with an open end for containing a soil sample; and a removable lid covering the open end, the unique identifier being provided in at least one of the body and the lid.

In an embodiment, a thickness of the base is selected such that the base can support a weight of between approximately 15 tonnes and 30 tonnes. In an embodiment, the system includes an oven for drying the soil samples while inside the soil sample containers.

In an embodiment, the press is shaped and configured to receive several of said soil sample containers at a time. In an embodiment, the system includes a support tray for supporting the plurality of soil sample containers, the tray including cavities sized and shaped for receiving the soil sample containers therein. In an embodiment, the support tray includes: a base having a top side and a bottom side, the top side being provided with the cavities arranged peripherally around a central axis; and lid supports extending from the top side of the base adjacent each cavity for supporting the removable lids of the soil sample containers peripherally around the central axis, the lid supports including support arms for retaining the lids of the soil sample containers in an upright position.

In an embodiment, the tray further includes a locking mechanism for retaining the soil sample containers in the base of the tray. In an embodiment, the system includes a client device in communication with the server, the client device including a processor, memory, a scanning mechanism and a geographic position sensor, the memory having stored therein instructions executable by the processor to cause the client device to scan the unique identifiers of the soil sample containers using the scanning mechanism, capture geographic position coordinates corresponding to a location from which a sample in a corresponding soil sample container was taken using the geographic position sensor, and transmit the geographic position coordinates associated with corresponding unique identifiers for storage in the database. In an embodiment, the system includes a reusable sample group box for transporting groups of soil sample containers to and from a lab, and for archiving groups of soil sample containers, the box including a plurality of slots for receiving the group of soil sample containers and a lid for enclosing the group of soil sample containers within the box. According to an aspect, a method is provided for sampling and analyzing soil. The method includes the steps of: (1) collecting samples of soil; (2) tagging the samples; (3) grouping a collection of samples; (4) sending the samples to a laboratory; (5) receiving a collection of samples at a laboratory and identifying the collection; (6) drying the samples; (7) compacting the samples; (8) analyzing the samples using LIBS, or other such technology; (9) generating a report from the analyzed data; and (10) archiving the samples.

In an embodiment, the tagging of samples is done using a unique identifier, such as QR codes. Each tagged sample is further associated with indicia of source, such as the GPS coordinates of where the sample originates, or a timestamp indicating when the sample was taken.

According to an aspect, a system for containing and transporting samples is provided. The system includes porous cups for containing individual samples. The cups can have a label affixed to the exterior displaying a unique identifier, such as a QR code or other tagging method for identifying the cup. The system also includes a shippable cardboard box adapted to receive a plurality of cups, such as twelve or twenty-four of the porous cups. The cardboard box can be further identified by a unique tag for classification and archiving.

According to an aspect, a computerized system for managing samples and manipulating analyzed data is provided. The system includes at least a server and a client device. The client device is adapted to read a tagged sample, via the unique identifier for example, and transmit to the server information to be associated with the sample. Such information may include, for example, GPS coordinates, a timestamp, or both, or the results of LI BS analysis. The server is adapted to gather data collected from the client, store it in a database, and present it in the form of a report, which can be accessible via a web browser, for example. In an embodiment, one client device may be a mobile phone, the mobile phone being equipped with a camera, GPS receiver and mobile data connection. A user scans the QR code of a sample at the very location it was taken, while the mobile phone registers the current GPS location and sends this data to the server. A second client device may be the machine carrying out the sample analysis. The machine automatically scans a QR code and stores the analysis information in the server database along with the GPS data. Information collected by both clients can be combined to generate a report.

According to yet another aspect, a system for preparing the soil samples for the LIBS analysis is provided. The system includes a unit for drying the samples, and a unit for compacting the samples. BRIEF DESCRIPTION OF THE DRAWINGS

Figures 1A to 1 C contain a flow chart schematically illustrating the steps in a method for sampling and analyzing soil, according to an embodiment. Figure 2A is a perspective view of a soil sample container for use in the method of Figures 1A to 1C, according to an embodiment.

Figure 2B is a perspective view of a container lid for sealing and identifying the soil sample container of Figure 2A.

Figures 2C and 2D are perspective views of the soil sample container and lid of Figures 2A and 2B assembled together.

Figure 3 is a block diagram illustrating a computer system for identifying and tracking soil samples for use in the method of Figures 1A to 1C, according to an embodiment. Figure 4A is a perspective view of a sample group box for use in the method of Figures 1A to 1C, according to an embodiment, shown in an assembled and a disassembled configuration.

Figure 4B is a perspective view of the sample group box of Figure 4A in an open configuration, showing soil sample containers supported by a removable group tray. Figure 4C is a perspective view of the sample group box of Figure 4A in a closed configuration, showing a configuration of shipping and identification labels affixed thereto.

Figure 4D is a perspective view of a sample group box for use in the method of Figures 1A to 1 C, according to an alternate embodiment where the sample group box accommodates two removable group trays.

Figures 5A and 5B are schematic illustrations of a drying device useful during the drying step in the method of Figures 1A to 1 C, according to an embodiment.

Figure 6A is a partially transparent front view of a pressing device useful during the pressing step in the method of Figures 1A to 1C, according to an embodiment. Figure 6B is a partially transparent perspective view of the pressing device of Figure 6A, showing a soil sample container support tray supported therein.

Figures 6C and 6D are detail views of a pressing unit, according to an embodiment where the pressing unit is provided with an ejection piston. Figure 6E is a schematic view of a pressing device according to an embodiment where the pressing device comprises a plurality of pressing heads.

Figures 7 A and 7B are top and bottom perspective views of a capsule support tray for use in the method of Figures 1A to 1 C, according to an embodiment.

Figure 7C is an exploded view of the capsule support tray of Figures 7A and 7C.

Figure 7D is a schematic of a capsule support tray according to an alternate embodiment which supports the capsules while inside a group tray.

Figure 8A is a partially transparent front view of a LIBS system for use in the method of Figures 1A to 1C, according to an embodiment. Figure 8B is a partially transparent side view of the LIBS system of Figure 8A.

Figure 8C is a cross-sectional view of the LIBS system of Figure 8B taken along line 8C— 8C. Figure 9 is a block diagram illustrating a computerized system for identifying and analyzing soil samples for use in the method of Figures 1A to 1 C, according to an embodiment.

Figure 10 is a schematic illustrating a sample report generated during the method of Figures 1 A to 1 C.

DETAILED DESCRIPTION

In the following description, the term "client device" refers to any electronic device capable of executing computer code and communicating with a server via a communication channel. Examples of a client device may include, but are not limited to: a laptop or desktop computer, a tablet, or a smartphone device. The term "server" refers to a computing device capable responding to requests from a client device, by means of a communication channel. As will be evident in the remainder of the description, the server carries out a variety of functions. These functions need not be done on the same physical device, and thus the definition of a server may also refer to a collection or cluster of computing devices networked in some fashion.

What follows describes a preferred embodiment of the present invention, and provides examples for possible implementations. These are but one of many ways to implement the invention. As such, the examples provided should not be taken as to limit the scope of the invention in any way. In the figures, the same numerical references refer to similar elements. Furthermore, for the sake of simplicity and clarity, namely so as to not unduly burden the figures with several references numbers, not all figures contain references to all the components and features, and references to some components and features may be found in only one figure, and components and features of the present disclosure which are illustrated in other figures can be easily inferred therefrom. A. Method

Referring to Figures 1A-1C, a diagram illustrating the main steps in the method of the present invention is shown, according to an embodiment. It should be understood that different steps in the method can occur in different locations. For example, some steps can occur on-site where the soil samples are collected, and some steps can occur at a lab where the soil samples are analyzed. It should be understood that the word "lab" is use herein to lighten the text. A "lab" can include any location on site or off site which has the necessary equipment to perform the analysis of the soil samples. The first step comprises sampling. In this step, an agronomist, or other operator, collects samples of soil from strategic locations across an area of land, and places them in containers which were received from a lab or other entity. Typically, the soil samples are collected manually, for example with a shovel or a coring tool, or with the help of a machine adapted to collect samples. In the presently described embodiment, the containers are porous soil sample containers. The size of the samples can be relatively small. For example, each soil sample container can contain between 5 grams and 150 grams of soil sample. Once inside the containers, the samples are tagged according to a predetermined tagging scheme, preferably indicating where the samples originated. This step of tagging allows associating soil samples with specific geographic locations or positions on an area of land from where they were taken. This can be accomplished, for example, with the help of a client device and a QR code affixed to the soil sample container. Preferably, prior to or after filling a soil sample container, a client device is used to scan a QR code on the container and capture GPS coordinates, the GPS coordinates corresponding to where the sample was taken. The QR code and corresponding coordinate information is wirelessly transmitted and received on a server where they can be associated in a database. Once tagged, several samples are grouped together and prepared for shipping. The individual samples are packed together into a sample group box, i.e. a larger container suitable for holding a group of multiple samples, and being adapted for shipping the samples safely. The group box can also be adapted such that they identify from where the samples originate, for example by providing a label with client information. Once prepared, the group box is shipped to a lab for processing.

The second step comprises receiving the samples at the lab. The sample group box is received, and is identified according to its origin, for example using an identifier such as a QR code and/or a customer information label. This step is optional since it is possible to include customer information in the QR code on each sampling container. Tracking the sample group box when it arrives in the lab allows tracking the time between receiving a sample group box and analyzing the samples of the sample group box. When the group box is identified, the samples contained therein can be associated with a particular group, for example using the identifier or customer information. For example, a single group box can correspond to samples taken at various locations in a single field. The samples can therefore be associated to a group which corresponds to the field. The association of individual samples to a particular group can, for example, be stored in a database on a server. It should be noted that, in an embodiment, this association can be made prior to receiving the samples at the lab. For example, the lab can prepare a group box with several empty soil sample containers therein, and associate the soil sample containers with a group prior to mailing the empty soil sample containers to a client to be filled.

Once identified, the next steps involve preparing the sample for analysis. Preferably, the preparation and analysis of the sample is done in the same container in which the sample was shipped, for example to reduce the materials used and to avoid having an extra step of transferring portions of the samples to different containers. The preparation and analysis can be done with the sample inside the soil sample container in which it was shipped or, in some cases, with the sample inside the group box or the group tray in which it was shipped. In some embodiments, the soil sample containers can be transferred to a support tray which supports the samples throughout the preparation and analysis steps.

The third step comprises an optional step of drying the samples in order to prepare the samples for analysis. This can be done, for example, over the course of 12 to 18 hours at a temperature of about 37°C in a drying chamber, such as an oven or incubator for example. The time and temperature can vary according to the sample and/or testing conditions. For example, the drying period can be anywhere between approximately 2 hours and 48 hours, and the drying temperature can be anywhere between 30°C and 45°C. Drying is done in order to remove humidity from the samples to avoid leaching of nutrients, or water seepage in subsequent steps in which the samples are compacted and analyzed. Such effects can be avoided if, for example, the samples are dried to a humidity level of about 10% or less. In some embodiments, the drying step can be accomplished outside of the lab. For example, the samples can be dried during transport, either on their own in an ambient environment, or in a climate controlled area of a transport vehicle. In some embodiments, the soil samples can be sufficiently dried prior to arriving at the lab, and need not be dried in the oven or incubator. The fourth step comprises pressing or compacting the samples, for example with the help of a pressing system. In this step, each sample is compressed under a weight of about 23 tonnes for several seconds. The soil is compacted to account for the fact that each sample may contain material with different characteristics. In order to get a consistent reading from each sample, they must all have a uniform surface. Compacting the soil assures that each sample is uniform. The weight applied to the samples can vary, for example according to the composition of the soil. In typical embodiments, the soil samples are pressed with a weight of between approximately 15 tonnes and 30 tonnes. Preferably, the soil samples are compacted while inside their sample containers. This provides the advantage of avoiding transferring or manipulating the soil samples. In an embodiment, each sample in a group of samples can be compacted one at a time. In an alternate embodiment, two or more samples of a group can be compacted simultaneously. Preferably, compacting a group of samples is automated. For example, the press can be configured to compact a first sample or a first set of samples, and then move the samples or the pressing head in order to continue compacting the remaining samples without manual human intervention. To aid in this task, the soil sample containers can be loaded in a support tray which allows the compacting system to more easily manipulate and reposition the soil sample containers. Once compacted, the fifth step comprises analyzing the samples using a LIBS system. The samples can be analyzed using known LIBS analysis methods, for example the one disclosed in the international PCT application no WO 2015/077867. Preferably, the analysis is done on the samples while they are still inside their corresponding soil sample containers, and can involve shining a laser on a plurality of different areas on an exposed surface of the soil sample (i.e. the uniform surface created during the pressing step). Preferably, prior to analyzing the sample using the laser, the unique identifier of the soil sample container is scanned by the LIBS system. In this fashion, data acquired by the analysis can be associated with the sample by means of the unique identifier, for example by transmitting the analysis data to a server for storage in a database. Preferably, the analysis of a group of samples is automated. For example, the LIBS system can be configured to analyze a first sample, and then reposition the samples or the laser head in order to analyze subsequent samples without manual human intervention. To aid in this task, the soil sample containers can be loaded in a support tray which allows the LIBS system to more easily manipulate and reposition the soil sample containers. Preferably, each sample in the group is analyzed in this fashion in 60 seconds or less. Preferably, the support tray can be provided with control samples for calibrating the LIBS system. For example, between approximately 10% and 20% of the samples being scanned can be controls. The control samples can be identified by the LIBS system by unique identifiers on their corresponding soil sample containers. In an embodiment where a group of sample comprises 12 containers, the support tray can be configured to hold 14 soil sample containers, 2 of which contain control samples.

Once the samples are analyzed, a sixth step comprises generating a report. The report can serve to present the analysis results. For example, the reports can be that from a single point of sampling, from all the sampling points, or a summary for a whole field. Preferably, the report is generated by a server connected to a database which contains the analysis results and other data associated with a sample. Preferably, the report can be accessed over the internet, for example through a web portal by a client or operator. Preferably, the report cannot be tampered with. In an embodiment, an agronomic report can be generated where recommendations are made. In such a report the client can specify report preferences which can include types of data to include in the report, and the report can be generated according to the report preferences. The recommendations can be compiled in a file readable by a fertilization device, the file providing the fertilization device with instructions to automatically distribute nutrients in a field according to the analysis results of the samples and their associated geographic locations.

Finally, the seventh step, which is optional, comprises archiving the samples. The samples can be archived inside the group box so that they can be recovered or re-analyzed at a later date. The group box can be provided with a label on a front surface, for example, so that it can be easily identified when stacked vertically, thus helping to save space. Preferably, the samples are stored for a period of at least 6 months following their analysis, according to ISO 17025 standards. The samples can be archived in a climate controlled environment, for example to avoid deterioration.

B. System i. Soil Sample Container

With reference to Figures 2A to 2D, a soil sample container 200 is provided for use in the above-described method. In the illustrated embodiment, the soil sample container 200 is a sampling cup, but other shapes are also possible. The soil sample container 200 is provided with a base 204 and sidewalls 202 defining a substantially round outer contour and an inner cavity 208. The inner cavity is sized and shaped for receiving between 5 grams and 150 grams of a sample of soil 210. The upper portion of the cup is provided with a lip 206, which can serve to receive a lid, or to provide an abutment to allow the soil sample container to rest inside a support with a round cavity. Preferably, at least the sidewalls 202 or the base 204 comprise a porous material 203. The porous material 203 can be a porous plastic which allows moisture to exit the container, such as polyethylene for example with pore size diameters ranging from 7 to 150 micrometers. Preferably still, the base 204 and sidewalls 202 are sized and shaped so that they can support between at least 15 tonnes and 30 tonnes. In this configuration, the soil sample container 200 can be used to contain the sample 210 during the entire process, including the steps of drying, compacting and analyzing the sample. This eliminates the need to transfer the sample to other containers during the analysis steps, and thus reduces the steps in the overall collection/analysis process. Of course, other types of materials are also possible according to varying needs. For example, the cup could also be made out of a recyclable material. Preferably, the base 204 and sidewalls 202 are made from the same material, but in possible embodiments, the base 204 can be made of a different material which can support a higher load.

The soil sample container 200 can further be provided with a removable lid 220. The lid 220 comprises a cover portion which can be provided with a tag or identifier 222, such as a QR code or a barcode, for example, on an outer surface thereof. According to different possible embodiments, the lid 220 can be configured to fit inside the inner cavity 208, or can be provided with a rim 224 so that it fits around the lip 206 of the soil sample container 200. The lid serves to contain the sample 210 inside the container 200, and can also be used to identify the sample using the unique identifier 222. In the illustrated embodiment, the lid is secured to a hoop 226 via a flexible joint 225. The hoop 226 comprises a hole 227 sized to fit the container therein. In this fashion, the lid assembly can be secured to the container, while allowing the lid 220 to close by folding the cover over the flexible joint 225 and towards the hoop 226. The lib can also consist of a laminated membrane which is removably glued to the top edges of the sidewall of the container. The lid 220 may further be provided with identification information 228 on the under-side of the cover. In other embodiments, a unique identifier can be provided elsewhere in the container or in the cover. For example, a RFID chip can be affixed to the container or the cover, or embedded therein. ii. Computer System for Identifying and Tracking Soil Samples

Referring now to Figure 3, a computer system 300 is shown for identifying soil samples during the sampling step of the above-described method, and tracking the samples throughout the remaining steps. The system 300 includes a client device 302 and a server 320 which communicate via a communication channel 312. The client device 302 is preferably a mobile device 302' equipped at least with a processor 304, memory, a scanner 306 and a geolocation sensor such as GPS 308. The server 320 is equipped with at least a processor 322 and a database 324. The server can be a single computer 320' or several interconnected computers among which the processor and database are distributed.

The client device's scanner 306 can be any type of sensor which allows the client device 302 to read a unique identifier 222 associated with a soil sample container. For example, if the identifier 222 is a QR code, the scanner 306 can be an optical sensor or camera. If the identifier 222 is an RFID chip, the scanner 306 could be a near field communication (NFC) reader. The memory contains instructions executable by the processor 304 which allow the identifier 222 on a soil sample container to be scanned by the client device 302 using the scanner 306. The unique identifier 222, along with any other information relating to the sample in the soil sample container, such as GPS coordinates, can be transmitted to the server. The information is transmitted to the server by means of a communication channel 312, for example over the internet by a wireless data connection. It should be noted that this information need not be transmitted immediately. In some cases, for example if an internet connection is not available when the sample is scanned, the information gathered by the client device 302 can be stored on a database local to the client device 302. The client device 302 can transmit the information to the server 320 and/or synchronize information with the server 320 at a later time, for example when an internet connection 312 becomes available.

The server 320, being provided at least with a processor 322 and a database 324, can process the data received from the client 302, and store it for later access. Preferably, the server 320 can be configured to associate a unique identifier 222 with a sample and the GPS coordinates. Preferably, this association is stored within the database 324. It should be understood that, although in the illustrated figures the client device 302 only collects GPS information, other information collected by any other sensors on the client device can also be transmitted to the server and associated with the unique identifier 222 of a sample. For example, when scanning the sample, the client device 302 can also measure the current ambient temperature and record the current date and time.

Such a system can provide a simplified mechanism which allows managing large volumes of samples, and retaining information about the geographic origin of each sample. It can also simplify the sampling process by automating the gathering of information about a sample, such as its GPS coordinates for example. Of course, during the scanning step, the client 302 can transmit other information for storing on the server, such as information relating to the owner of the sample, the operator performing the sampling, or the field from which the sample was taken. The client device 302 can also generate an order form to request the analysis of the sample. iii. Sample Group Box With reference now to Figures 4A to 4C, a sample group box 400 (or sample aggregation box) is shown. The sample group box 400 can serve to collect several soil sample containers 200 into a single container for easier transport and storage. The sample group box 400 can therefore be useful in the sampling and reception steps of the above-described method, when the samples are mailed to a lab. It can also be useful in the archiving step of the above-described method, so that the samples can be stored in a space-efficient manner for future access.

The illustrated sample group box 400 comprises a closeable lid 402 and slots 410 configured to receive soil sample containers 200. The group box 400 can comprise two separable components: a shell 404 and a group tray 408. The shell 404 comprises the lid 402 and a cavity 406 adapted for receiving the tray component 408 therein. As is best illustrated in Figure 4A, the box can be assembled from flat pieces of material, such as cardboard. Of course, in other embodiments, other materials are also possible.

The closeable lid 402 allows the box 400 to be sealed, and can thus allow the group box 400 to serve as a container for shipping a group of samples. The box 400 can further be provided with labels 412, 413 to simplify the transport and identification of the box 400. For example, the box 400 can be provided with a shipping label 413 on a top surface thereof for mailing the box 400 using a parcel delivery service. The box 400 can also be provided with an identification label 412 on a side surface thereof, allowing the box 400 to be easily identified when stacked vertically among other boxes. The identification label 412 could include a unique identification number, a unique code such as a QR or barcode, or any other identification means.

An operator collecting samples can, for example, pre-pay for a group box 400. Once prepaid, the operator can receive the box 400 with the necessary labels 412, 413 affixed thereto, and with empty soil sample containers 200 stored therein. The operator can thus proceed with sample collection, and ship the box 400 with the samples contained therein immediately once the sampling is complete. Once the box 400 has arrived at its destination, which is typically the laboratory, the tray component 408 can be removed. Subsequent steps can be performed with the soil sample containers in the group tray 408, or by transferring the soil sample containers to another support. During the archiving step, the tray 408 can be returned to the shell 404 with the soil sample containers 200 stored therein. The box 300 can then be sealed for storage. The box 400 thus serves as a single container which can be used throughout the collection, analysis and archiving steps, effectively reducing the need to transfer samples and simplifying the overall process, all the while keeping groups of samples together to avoiding contamination or confusion.

In the illustrated embodiment of Figured 4A to 4C, the box 400 is adapted to fit 12 sampling containers 200 of a single group. However, this can vary according to other embodiments. For example, as illustrated in Figure 4D, the box 400 can be configured to accommodate 24 or more samples by layering two or more trays 408 on top of one another. This can allow, for example, for a single box 400 to store soil sample containers 200 from more than one group, or store soil sample containers 200 for a single larger group. Additionally, according to other embodiments, the box 400 can be configured differently to satisfy varying needs. For example, the trays 408 and the shell 404 can be a single unit. iv. Drying Unit Referring now to Figured 5A and 5B, a drying unit 500 is shown for drying the samples during the drying step of the above-described method. In the present embodiment, the drying unit 500 is an incubator, but in other embodiments, other types of drying units are also possible, such as an oven for example. Preferably, the drying unit 500 comprises a temperature control, allowing the temperature to be maintained between approximately 30°C and 45°C for a period of between approximately 2 hours and 48 hours. In an embodiment, the drying unit 500 can be set at a temperature of 37°C for 12 to 18 hours.

Preferably, the drying unit 500 is provided with supports, such as racks or shelves, for supporting soil sample containers which are to be dried. During the drying step, the soil sample containers can be placed inside the drying unit 500 while inside a support tray 700, a group tray 408, or even a group box 400. The drying unit 500 can be adapted to hold up to 120 or more trays at a time, and can be adapted to function on 208V 3-phase power. v. Pressing System

With reference now to Figures 6A and 6B, a pressing system 600 is shown for use in the pressing step of the above-described method. In the present embodiment, the pressing system 600 is provided with two pressing units 602 for simultaneously compacting samples in two different soil sample containers 200. It should be understood that in other embodiments, the pressing system 600 can be provided with one or a plurality of pressing units 602. Each pressing unit 602 comprises an automated piston which can, for example, be driven hydraulically using a motor 606. Each pressing unit is provided with a pressing head 603 sized and shaped to fit inside a sampling container and compress a sample contained therein.

Preferably, the pressing system 600 is configured to automatically compact each sample in a group of samples. In other words, the pressing system 600 can process the samples as part of a batch. In the present embodiment, the pressing system 600 is provided with a rotatable stage 608. The stage 608 can be configured to accommodate a support tray 700 which contains a plurality of soil sample containers. In operation, the two pressing units 602 are operated to simultaneously compact samples in two soil sample containers 200 opposite one another in the support tray 700. Once the first two samples have been compacted, the stage 608 is rotated, for example automatically using a motor, to position two subsequent soil sample containers 200 under the pressing units 602. This process is repeated sequentially until all the samples in the support tray 700 have been compacted. It should be understood that this process can vary according to the configuration of the pressing system 600. For example, if the system 600 comprises a single pressing unit 602, the samples can be compacted one at a time. In another embodiment, such as the one illustrated in Figure 6E, a pressing unit 602 can be provided with enough pressing heads 603 to press all of the soil sample containers 200 at once.

Preferably, the press is configured to apply 23 tonnes of weight for 15 seconds, but this can vary according to the sample composition, tolerances of the soil sample containers, or preparation requirements. Typically, between 15 tonnes and 30 tonnes are applied to compress a sample. Additionally, the surface area being pressed may vary according to other embodiments. For example, the entire surface of the sample could be pressed, or only a portion of it.

With reference to Figures 6C and 6D, in an embodiment, each pressing unit 602 is further provided with an ejection piston 604. Such a piston is situated below the sampling containers such that after the contents of the sampling containers have been compressed, the containers can be ejected from the pressing unit 602 by engaging the piston 604. Of course, in other embodiments, other types of ejection devices are also possible in lieu of ejection pistons 604. For example, this can be done with a burst of air through the extremities of the pressing units 602. According to other embodiments, the ejection piston may be located inside the pressing head 603.

[Pourrait-on considerer inclure I'equipement de compression a meme le systeme LIBS. vi. Support Tray With reference now to Figure 7A to 7C, a support tray 700 is shown for supporting a plurality of soil sample containers 200. The support tray 700 can simplify the above-described method by providing a means to more easily manipulate and manage a plurality of samples in several of the described steps. During the preparation step, each of the soil sample containers in a group can be transferred into a support tray 700. The samples can be dried, compacted and analyzed while the soil sample containers 200 are inside the support tray 700. In this fashion, when moving from machine-to-machine in the various steps in the method, all of the samples can be moved at once while inside the same support tray 700, effectively eliminating the need to transfer each of the soil sample containers 200 individually. What's more, the support tray 700 can act as an interface to aid in automating the steps of drying, compacting and analyzing. For example, the support tray 700 can be configured to be mounted to a stage within the devices used in the drying, compacting and analyzing steps, allowing those devices to more easily manipulate the soil sample containers without the need for human intervention.

The support tray 700 comprises cavities 706 sized and shaped for receiving soil sample containers therein. In the illustrated embodiment, the support tray 700 comprises a base 702 having a top side 702a and a bottom side 702b. The top side of the base 702a is provided with the cavities 706 arranged peripherally around a central axis 716. Lid supports 708 comprising lid support arms extend from the top side 702a adjacent each cavity 706. The support arms define a lid slot 710 for receiving and supporting the removable lids 220 in an upright position peripherally around the central axis 716. Preferably, the lid supports 708 are configured to support the lids 220 such that an identifier 222 on the lid 220 faces peripherally outward. Preferably, the support tray 700 comprises a locking mechanism 704 for retaining the soil sample containers 200 in the base 702. In the illustrated embodiment, the locking mechanism 704 comprises a plate removably affixed to the base 702. The plate fits over the sample containers while inside the cavities 706 in the base 702, securing the containers 200 therein. The plate includes cavities which align with the cavities 706 in the base 702, allowing access to the open end of the sample containers 200 from above. A spacer 718 can be provided between the plate and the base 702

In an embodiment, the base 702 can provide additional support to the base of the sample containers 200. For example, the base can include a plate on which the base of the sample containers 200 rest. In this fashion, when the sample containers 200 are compressed, the weight can be supported by the plate. The base 702 can also be provided with feet 712 for supporting the support tray 700 at an elevation. As can be appreciated, the described embodiment of the support tray 700 allows simplifying the manipulation and displacement of the sample containers 200 while inside the various devices used in the steps of the above-described method. For example, the support tray 700 can be removably mounted to a stage which allows the support tray 700 to be rotated or displaced within the devices, allowing the devices to position samples as required without the need for human intervention.

In an embodiment, the sample containers 200 can be placed in the support tray without leaving the group tray in which they were shipped. Referring to Figure 7D, an alternate embodiment of a support tray 750 is shown. The support tray 750 comprises a sleeve 752 and a handle 754. The sleeve 752 is adapted to receive a single group tray 408, and is provided with holes 756 aligned above each sample container 200 in the tray 408, such that the samples are accessible from above. In the present embodiment, the sleeve 752 is comprised of metal; however, the material may vary according to other embodiments. The handle 754 encloses the tray 408 in the sleeve 752, such that the ensemble forms a drawer which can fit inside a LIBS system or a pressing system, and can be moved as needed along X and Y axes. vii. LIBS System

Referring to Figures 8A to 8C, a LIBS system is shown 800 for use during the analysis step of the above-described method. The LIBS system 800 comprises a laser head assembly and spectrograph 802 to analyze soil samples while inside their soil sample containers 200, a scanning device 808 to scan the unique identifier associated with each sample, and a computing system 801 comprising at least a processor and memory. The LIBS system 800 also comprises a stage 804 for accommodating a support tray 700. The support tray 700 can be rotated or displaced using a motor 806 or actuator, for example. In operation, the LIBS system 800 is controlled by the computing system 801 to identify an individual sample 810 by reading the unique identifier (i.e. barcode, QR code, etc.) on the soil sample container 200 using the scanning device 808. The scanning device 808 can comprise any type of sensor capable of reading the unique identifier. For example, if the unique identifier is a QR code, the scanning device can comprise an optical sensor or a camera. Once the identifier is scanned, the system 801 can direct the laser head assembly and spectrograph 802 to perform an analysis on the sample 810 in the container and generate analysis results. Preferably, analyzing the sample and generating the analysis results is performed in 60 seconds or less. Once the analysis of a sample is complete, the system 801 can operate the stage 804 to move another sample container 200 into position for analysis. This can be repeated until each of the samples has been analyzed, thus allowing all the samples to be analyzed sequentially without manual human intervention. In other words, the LIBS system 800 can process the samples as part of a batch. The system 801 can be configured to only read an identifier if a sampling cup is present in the slot to be analyzed. If a sample is missing from a particular slot, or if the sample is up-side down, the system 801 can skip the analysis for that slot. viii. Computer System for Analyzing Samples, Storing Results and Generating Reports

With reference now to Figure 9, an overview of a computer system 900 for analyzing samples, storing analysis results, and generating reports is shown. The system 900 comprises the analysis device 800 (i.e. the LIBS system) and the server 320 in communication via a communication channel 902. In operation, the processor 801 in the LIBS system 800 transmits to the server 320 the results from an analysis of a sample, along with the sample's identification information (read via the scanner 808). The data can be transmitted to the server via a communication channel 902, such as over the internet, wide area network or local area network, depending on where the server 320 is physically located relative to the LIBS system 800. The server 320 can then store the analysis information and associate it with the identified sample in the database 324, along with the information collected about the sample during the sampling step in the above-described method (such as the GPS location information).

The analysis results, tagging/identification information, and any other information stored in the server's database 324 can be used to generate a report. A sample of such a report is shown in Figure 10. The report may include details about the analysis of a single sample, or may collect data from several samples to help in developing an agro-environmental fertilization plan. This report can be accessed, for example, by communicating with the server over the internet. In such a fashion, an operator who ordered the analysis of samples will be able to consult the analysis report by visiting a web-page on the internet, immediately after the analysis has been completed. The operator could also specify report preferences, and the server can use these preferences in order to generate a report which displays certain information according to the preferences. Information in the report may include the pH level of the soil sample, and the concentration of various minerals such as potassium, phosphorus, magnesium, aluminum and calcium, among others. Such information can be presented, for example, by using tables or graphs. The report can also include indications to identify the report, in addition to indications to identify the sample, by using a QR code for example. The report can further include information for identifying the operator who ordered the report, information to identify the person who carried out the analysis, and information relating to how the analysis was performed. As is evident from the present disclosure, the method and systems described herein provide a streamlined process for gathering and analyzing soil samples. A single container is used to collect, ship, and analyze samples, eliminating the need to transfer the samples to different containers several times during the process, as is the case in the prior art. Additionally, the present invention provides a solution for using LI BS technology, or the like, in the context of analyzing soil from many samples, possibly across several fields, and provides a method to easily manage and access information relating to the analysis. It further allows analyzing soil in a fashion which does not destroy the samples, thus permitting repeated analyses if necessary. Finally, the method and system provide a simplified means for ordering soil analysis by an operator. The operator need only order a pre-paid box, tag samples, and ship the box. Once the analysis is complete, the operator can immediately consult a report over the internet. This removes a significant amount of paper from the process, and automates the organization and management of analysis data.