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Title:
MICROCRYSTALLINE STARCH
Document Type and Number:
WIPO Patent Application WO/1992/021703
Kind Code:
A1
Abstract:
A microcrystalline starch composition is prepared by disintegration of microporous starch granules produced by partial hydrolysis of granular starch. The composition finds use particularly as a fat substitute in reduced calorie foods. The starch composition is optionally treated with starch reactive cross-linking agents and/or other surface modifying agents to optimize its rheological properties and the organoleptic qualities of processed foods containing the microcrystalline starch composition.

Inventors:
WHISTLER ROY L (US)
Application Number:
PCT/US1992/004740
Publication Date:
December 10, 1992
Filing Date:
May 28, 1992
Export Citation:
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Assignee:
WHISTLER ROY L (US)
International Classes:
A23L1/09; C08B30/12; C12P19/14; (IPC1-7): C08B30/00
Foreign References:
US4985082A1991-01-15
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Claims:
CLAIMS:
1. A method for preparing a microcrystalline starch composition useful as a fat substitute in reduced calorie foods, said method comprising the steps of partially hydrolyzing granular starch to form a microporous granular starch and disintegrating the microporous granular starch into crystalline starch particles.
2. The method of claim 1 wherein the microporous granular starch is formed by action of an a ylase enzyme on granular starch.
3. The method of claim 1 herein the microporous granular starch is formed by action of a mineral acid on granular starch.
4. The method of claim 1 wherein the microporous granular starch is mechanically disintegrated to form the microcrystalline starch composition.
5. The method of claim 1 wherein the microporous granular starch is chemically disintegrated to form the microcrystalline starch composition.
6. The method of claim 2 wherein the microporous granular starch is mechanically disintegrated to form the microcrystalline starch composition.
7. The method of claim 1 further comprising the step of reacting the starch with a chemical crosslinking agent.
8. The method of claim 2 further comprising the step of reacting the starch with a chemical crosslinking agent.
9. The method of claim 4 further comprising the steps of reacting the starch with a chemical crosslinking agent.
10. The method of claim 1 further comprising the step of treating the starch with a surface modifying agent effective to increase lipophilicity of the product microcrystalline starch.
11. The method of claim 2 further comprising the step of treating the starch with a surface modifying agent effective to increase lipophilicity of the product microcrystalline starch.
12. The method of claim 3 further comprising the step of treating the starch with a surface modifying agent effective to increase lipophilicity of the product microcrystalline starch.
13. The method of claim 4 further comprising the step of treating the starch with a surface modifying agent effective to increase lipophilicity of the product microcrystalline starch.
14. The method of claim 6 further comprising the step of treating the starch with a surface modifying agent effective to increase lipophilicity of the product microcrystalline starch.
15. A microcrystalline starch composition useful as a fat substitute in reduced calorie foods, said composition comprising birefringent starch particles, said particles produced by chemical or mechanical disintegration of microporous, partially hydrolyzed granular starch.
16. The composition of claim 15 wherein the partially hydrolyzed granular starch is formed by action of an amylase enzyme on granular starch.
17. The composition of claim 15 wherein the microporous partially hydrolyzed granular starch is formed by action of a mineral acid on granular starch.
18. The composition of claim 17 produced by mechanical disintegration of microporous partially hydrolyzed granular starch.
19. The composition of claim 15 prepared by mechanical disintegration of microporous partially hydrolyzed granular starch.
20. The composition of claim 15 wherein said crystalline starch particles are crosslinked with a chemical crosslinking agent.
21. The composition of claim 15 wherein the crystalline starch particles are treated with a surface modifying agent effective to increase lipophilicity of the microcrystalline starch particles.
22. The composition of claim 16 prepared by mechanical disintegration of microporous partially hydrolyzed granular starch.
23. The composition of claim 16 wherein said crystalline starch particles are crosslinked with a chemical crosslinking agent.
24. The composition of claim 16 wherein the crystalline starch particles are treated with a surface modifying agent effective to increase lipophilicity of the microcrystalline starch particles.
Description:
MICROCRYSTALLINE STARCH

Field of the Invention

This invention relates to a modified starch composition. More particularly, the present invention is directed to a microcrystalline particulate starch composition useful as a fat substitute in processed reduced calorie foods.

Background and Summary of the Invention

The food industry has invested in a significant research and development effort to identify food ingredient products that can exhibit a sensory perception of fattiness in foods without the high calorie content of common oil and fat ingredients. For example, certain protein and carbohydrate compositions are proposed as fat replacements in U.S. Patent 4,911,946 and references identified therein. Carbohydrates and proteins have less than one-half of the calories of available metabolic energy than carbohydrates on a per gram basis. Two significant proteins, namely whey protein and egg white protein, in the form of microspheres of about 1-10 microns have been made by at least two companies for use as fat mimics. The above referenced U.S. Patent 4,911,946 suggests that small substantially spherical carbohydrate-based particles, including small whole starch granules in the 0.1-3 micron diameter size range, are acceptable fat mimics.

This invention relates to a granular starch-derived microcrystalline starch composition for use as a fat mimic. The microcrystalline starch composition is prepared by disintegration of partially hydrolyzed (microporous) starch granules by use of mild acid hydrolysis or by mechanical action, such as that of a ball mill or a roll mill. The resulting microparticulate starch product comprises irregularly shaped starch particles

which, when used as a substitute for at least a portion of the fat content of processed foods, imparts the sensory perception of fattiness with less calorie content and without compromise of other organoleptic qualities of the modified food product. The microcrystalline particulate starch composition in accordance with this invention is optionally treated with a surface modifying agent to complement the functional qualities of the starch composition.

Detailed Description of the Invention

Microporous starch granules prepared by the action of acid or amylase on granular starch are well known in the literature. See, for example, the description in "Photomicrographs" in my book. Starch Chemistry and

Technology. 2nd Edition, 1984, Academic Press, Inc., New York, New York. A process for preparing surface modified microporous granular starch is described in my U.S. Patent No. 4,985,082, issued January 15, 1991, the disclosure of which is expressly incorporated herein by reference.

Microporous starch granules can thus be prepared by partial hydrolysis by acid or, more preferably, enzyme action on granular starch for a period of time sufficient to solubilize up to about 10 to about 50% of their mass. Starch hydrolysis does not occur at equal rates at all points on the granule surface. Hydrolysis occurs preferentially, more precisely at a faster rate, at the more amorphous regions on the granule surface. Regions of higher crystallinity are denser and thus the starch molecules are less accessible to the amylolytic action of starch hydrolyzing enzymes or even acid hydrolysis. The resultant microporous granular starch compositions are thus comprised of the more crystalline regions of the granules in a network of "bridges" of adjacent unhydrolyzed portions of the starch granule.

-3-

In accordance with the present invention, a microcrystalline particulate composition is prepared by disintegration of the resultant weakened granular structure by mechanical force such as by crushing/shearing in a ball mill or roll mill. Alternatively the microporous granular starch can be disintegrated by mild acid hydrolysis. The present starch composition comprises the resultant irregularly shaped super-crystalline domains of starch granules with appendant remains of the starch "bridges" broken during disintegration of the microporous granular starch. The microcrystalline starch composition is thus characterized as comprising birefringent starch particles with protruding remains of the starch "bridges", hich give the appearance, under microscopic examination, of a diffuse outer surface.

Particle size distribution in the microcrystalline starch composition of this invention depends to some extent on the source of the starch (thus the size distribution of the native granular starch starting material) and processing conditions, e.g., degree of hydrolysis in producing the microporous starch intermediate and the means/extent of disintegration of that intermediate. Typically the average particle size ranges from about 0.1 to about 10 microns, but most are within the range of about 0.1 to about 6 microns.

Optionally, the microcrystalline starch composition can be chemically modified to optimize the functional characteristics associated with its use as a fat substitute for processed foods. Chemical treatments which work to increase the lipophilic character of the starch composition are particularly useful. Chemical modification of the starch composition can be effected either by adsorption of surface modifying agents or by reaction of the starch with starch reactive chemical reagents which form covalent bonds with the starch substrate. Such starch

modifying agents include chemical cross-linking agents which can be employed to enhance the firmness and gelation temperature of the modified microcrystalline starch particles. Any of a wide variety of food acceptable starch modifying agents can be employed, including more particularly, those described in my U.S. Patent No. 4,985,082, incorporated herein by reference. The optional chemical modification of the microcrystalline starch composition in accordance with this invention can be performed on the microporous granular starch intermediate product before the disintegration step or on the microcrystalline composition after disintegration of the microporous starch intermediate. Alternatively, the starch can be subjected to treatment with two or more chemical modifying agents at the same or at different points in the process of their manufacture.

In carrying out the present invention, the microporous starch intermediate is preferably prepared by the partial enzymatic hydrolysis of granular starch from any one of a wide variety of sources including corn, wheat, or potato, with a raw starch hydrolyzing enzyme such as alpha amylase or glucoamylase. Typically the granular starch is hydrolyzed at a temperature of about 25°-65° C. for a period of about 1/2 to about 4 hours. The microporous granular starch product is dried, optionally subjected to chemical modifications, and thereafter disintegrated mechanically or chemically to form the microcrystalline starch composition of the present invention. The product microcrystalline starch composition is recovered by product handling/processing techniques commonly utilized in the production of art-recognized chemically modified granular starches. The microcrystalline starch composition can be also subjected to size classification processing using, for example, cyclone separators to produce microcrystalline starch

-5- fractions having improved food functional characteristics deriving from their enhanced particle size homogeneity.

The product microcrystalline starch in accordance with this invention is utilized as a food ingredient and a substitute for all or a portion of the fat content in processed foods to provide a low calorie form of the food product with minimal compromise of organoleptic quality.

The microcrystalline starch composition of the present invention mimics the mouth feel and other functional characteristics of fats in processed food products and offers a significant improvement over reduced-calorie fat substitutes known in the art.

Although the invention has been described in detail with reference to its preferred embodiments, variations and modifications exist within the scope and spirit of the invention as defined in the following claims.