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Title:
MODIFIED POLYESTER AND PREPARATION METHOD THEREFOR
Document Type and Number:
WIPO Patent Application WO/2018/040688
Kind Code:
A1
Abstract:
The present invention relates to a modified polyester and a preparation method therefor. The modified polyester is composed of a terephthalic acid chain segment, an ethylene glycol chain segment, and a dihydric alcohol chain segment containing a branch chain. The dihydric alcohol chain segment containing a branch chain refers to a dihydric alcohol chain segment with a branch chain positioned on one non-terminal carbon of the dihydric alcohol chain segment, wherein the branch chain is a linear carbon chain containing 5 - 10 carbon atoms. The preparation method for the modified polyester involves: carrying out an esterification reaction on terephthalic acid and a dihydric alcohol containing a branch chain under the catalysis of a concentrated sulfuric acid to obtain a dihydric alcohol terephthalate; then, formulating terephthalic acid and ethylene glycol, and carrying out an esterification reaction on same to obtain ethylene glycol terephthalate; and finally, stirring and mixing the two, and under the action of a catalyst and a stabilizing agent, carrying out a polycondensation reaction in a low vacuum stage and a high vacuum stage to obtain the modified polyester. The increasing amplitude in space gaps between molecular chains inside the modified polyester is far greater than that of a branch chain-free polyester at the same temperature, this being beneficial for the degree by which tiny particles such as a dye enter the modified polyester, and improving the dyeing rate.

Inventors:
FAN HONGWEI (CN)
LIU ZHILI (CN)
LI WENGANG (CN)
TANG FANGMING (CN)
WANG LILI (CN)
YIN LIXIN (CN)
Application Number:
PCT/CN2017/089943
Publication Date:
March 08, 2018
Filing Date:
June 26, 2017
Export Citation:
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Assignee:
JIANGSU HENGLI CHEMICAL FIBRE CO LTD (CN)
International Classes:
C08G63/183; C08G63/78; D01F6/84
Domestic Patent References:
WO2012027885A12012-03-08
Foreign References:
CN106380580A2017-02-08
CN102020761A2011-04-20
CN102030893A2011-04-27
CN101817917A2010-09-01
JP2014189933A2014-10-06
Other References:
See also references of EP 3508511A4
None
Attorney, Agent or Firm:
TONGSHE INTELLECTUAL PROPERTY AGENCY (CN)
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