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Title:
MOLDED ARTICLE
Document Type and Number:
WIPO Patent Application WO/2019/189316
Kind Code:
A1
Abstract:
Provided is a molded article having exceptional mechanical strength and heat resistance. A molded article containing crystals of a fluoropolymer, wherein the molded article is characterized in that: the fluoropolymer is at least one selected from the group consisting of vinylidene fluoride/tetrafluoroethylene copolymers, polychlorotrifluoroethylene, ethylene/tetrafluoroethylene copolymers, tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymers, and tetrafluoroethylene/hexafluoropropylene copolymers; and the crystals are nano-oriented crystals that are 300 nm or less in size.

Inventors:
FUKUSHIMA TOSHIYUKI (JP)
SAWAKI KYOUHEI (JP)
OKANISHI KEN (JP)
Application Number:
PCT/JP2019/013103
Publication Date:
October 03, 2019
Filing Date:
March 27, 2019
Export Citation:
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Assignee:
DAIKIN IND LTD (JP)
International Classes:
C08J5/00; C08J5/18
Domestic Patent References:
WO2010084750A12010-07-29
WO2012108463A12012-08-16
WO2007026832A12007-03-08
WO2008108251A12008-09-12
WO2016035598A12016-03-10
Foreign References:
JP2014156581A2014-08-28
JP2017043829A2017-03-02
JP2017155087A2017-09-07
JP2012149152A2012-08-09
JP2008248039A2008-10-16
JP2010168485A2010-08-05
JP2002219750A2002-08-06
Other References:
HIKOSAKA, MASAMICHI ET AL.: "High heat resistance and high strength of nano-oriented crystals (NOC) discovered by strain-induced crystallization of Polymer", POLYMER PREPRINTS, vol. 64, no. 2, 25 August 2015 (2015-08-25), Japan, pages 1G11, XP009523740
OKADA, KIYOKA ET AL.: "The universality of nano-oriented crystal formation in strain-induced crystallization and verification of nucleation rate-limiting", POLYMER PREPRINTS, vol. 63, no. 1, Japan
FUKUSHIMA, TOSHIYUKI ET AL.: "Undercooling dependence of nucleation rate of vinylidene fluoride/tetrafluoroethylene copolymer (P(VDF/TFE", POLYMER PREPRINTS, vol. 66, no. 1, 15 May 2017 (2017-05-15), Japan, pages 2C03, XP009523739
K. OKADAJ. WASHIYAMAK. WATANABES. SASAKIH. MASUNAGAM. HIKOSAKA, POLYMER J., vol. 42, 2010, pages 464 - 473
M. HIKOSAKAK. OKADA, POLYM. PREPR., JPN., vol. 60, no. 2, 2011, pages 3014 - 3015
HIKOSAKA, M. ET AL., POLYMER PREPRINTS, JAPAN, vol. 64, no. 2, 2015, pages 1G11
M. HIKOSAKA ET AL., POLYMER PREPRINTS, JAPAN, vol. 38, no. 10, 1989, pages 3308 - 3310
YU AWAYA: "Introduction to polarization microscope for polymer material", 2001, AGNE GIJUTSU CENTER INC., pages: 75 - 103
MASAO KAKUDONOBUTAMI KASAI: "Kobunshi Ekkusu-sen Kaisetsu (Polymer X-ray diffraction", 1995, MARUZEN PUBLISHING CO., LTD.
See also references of EP 3763772A4
Attorney, Agent or Firm:
YASUTOMI & ASSOCIATES (JP)
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