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Document Type and Number:
WIPO Patent Application WO/2014/133017
Kind Code:
Provided is a mononuclear iron complex that comprises an iron-silicon bond that is represented by formula (1) and that exhibits excellent catalyst activity in each of a hydrosilylation reaction, a hydrogenation reaction, and reduction of a carbonyl compound. In formula (1), R1-R6 either independently represent an alkyl group, an aryl group, an aralkyl group or the like that may be substituted with a hydrogen atom or X, or represent a crosslinking substituent in which at least one pair comprising one of R1-R3 and one of R4-R6 is combined. X represents a halogen atom, an organoxy group, or the like. L represents a two-electron ligand other than CO. When a plurality of L are present, the plurality of L may be the same as or different from each other. When two L are present, the two L may be bonded to each other. n and m independently represent an integer of 1 to 3 with the stipulation that n + m equals 3 or 4.

NAGASHIMA Hideo (National University Corporation 6-1, Kasuga-Koen, Kasuga-sh, Fukuoka 80, 〒8168580, JP)
SUNADA Yusuke (National University Corporation 6-1, Kasuga-Koen, Kasuga-sh, Fukuoka 80, 〒8168580, JP)
TSUTSUMI Hironori (National University Corporation 6-1, Kasuga-Koen, Kasuga-sh, Fukuoka 80, 〒8168580, JP)
HASHIMOTO Toru (National University Corporation 6-1, Kasuga-Koen, Kasuga-sh, Fukuoka 80, 〒8168580, JP)
SAKUTA Koji (Shin-Etsu Chemical Co. Ltd., 1-10, Hitomi, Matsuida-machi, Annaka-sh, Gunma 24, 〒3790224, JP)
Application Number:
Publication Date:
September 04, 2014
Filing Date:
February 26, 2014
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KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION (10-1, Hakozaki 6-chome Higashi-ku, Fukuoka-sh, Fukuoka 81, 〒8128581, JP)
SHIN-ETSU CHEMICAL CO., LTD. (6-1 Ohtemachi 2-chome, Chiyoda-ku Tokyo, 04, 〒1000004, JP)
International Classes:
C07F19/00; B01J31/22; C07C5/03; C07C9/16; C07C13/10; C07C13/18; C07C15/073; C07C15/18; C07C29/14; C07C29/143; C07C29/147; C07C31/135; C07C33/20; C07C41/26; C07C43/23; C07C209/50; C07C211/27; C07C211/29; C07C213/00; C07C217/58; C07C227/00; C07C229/38; C07D223/04; C07F7/08; C07B61/00; C07F15/02
Domestic Patent References:
Foreign References:
Other References:
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Attorney, Agent or Firm:
KOJIMA Takashi et al. (GINZA OHTSUKA Bldg. 2F, 16-12 Ginza 2-chome, Chuo-k, Tokyo 61, 〒1040061, JP)
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