MOULDING OF CONSTRUCTION PRODUCTS TECHNICAL FIELD OF THE INVENTION

This invention relates to the manufacture of construction products and in particular of hollow cored 5. construction products such as partition panels, roof decking, and pipes. DISCLOSURE OF THE INVENTION

The invention provides a method of manufacturing construction products comprising the steps of feeding

10. dry or substantially dry constituents including a liquid setting powder and a reinforcement therefor into a moulding zone, compacting the constituents in such zone, exposing at least one upstanding surface of the compacted constituents and applying to that surface a predetermined

15. quantity of setting liquid, being a quantity sufficient to wet all of the compacted constituents in the moulding zone but insufficient completely to saturate the same.

The invention also provides a construction product manufactured by the method aforesaid. .

20. In a preferred form the method consists of comp- pacting dry liquid setting powders, such as Portland cement, gypsum hemi-hydrate and fillers and reinforcement, such as polypropylene or steel mesh, glass or wood fibres, into a moulding zone containing at least one vertically

25. disposed bore former which may be tapered or bell-mouthed, withdrawing the former(s) and applying limited quantities of setting liquid to the powder surface of the bore(s)

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during or after withdrawal of the bore former(s). The method is a development of the method described in British Patent Specification No. 1,346,767, but, instead of saturating the powder-fibre mix by gradually filling 5. the bores with liσuid after withdrawing the bore former(s) in the new method only just sufficient liσuid is applied t wet the powder/fibre mix by, for example, lightly spraying the powder surfaces of the bore(s).

Despite the increase in weight from wetting the

10. powder, if the procedures described hereafter are followed, the material does not collapse notwithstanding the absence of the bore formers; nor are the powdery surfaces of the bores eroded or pitted during the wetting action. Provided sufficiently well compacted dry

15. constituents containing sufficient fine particles are dampened with little or no more liquid than that needed to ^' just wet all of the material, the moulding can be sufficiently cohesive to be removed from the mould without waiting for the chemical reaction of hardening to commence.

20. This is not possible with the method in British Patent No. 1,346,767, in which the saturated mixture has the consistency of a thixotropiσ mud which tends to stick to the moul surfaces and is not self-supporting until chemical hardening is sufficiently far advanced. With

25. the new method the material has the consistency of a damp stiff sandy clay and can come away.from the mould quite readily. Demoulding strength is substantially furth increased if a significant proportion of fibres is included in the mix and large fibrous mouldings can be

30. handled by conventional means immediately after wetting. The advantage of early demoulding is that the number of moulds needed for mass production can be dramatically reduced, particularly with slow setting materials such as Portland cement. Even with quick setting materials

(such as gypsum) there are advantages, as the setting liquid can be applied rapidly over the entire bore surface by, for example, vertically oscillating spray . tubes, whereas in British Patent No. 1,346,767 the liquid 5. can only rise sequentially and very gradually in the bores. Another advantage with the new method, particularly in respect of gypsum products, is that only just enough . liquid need be applied to complete the chemical reaction of hardening so as to dispense with or significantly

10. reduce the drying processes needed to drive off excess liquid in the earlier saturation method.

Immediate demoulding of dampened, compressed granular/ powder material is well-known in concrete block-making, but here the constituents are dampened before entering

15. the moulds and do not contain reinforcement. These

"earth damp" mixtures used in block-making by virtue of their dampness, are much less free-flowing than the substantially dry materials used in the new process and are much less easy to compact into confined spaces. The

20. resulting mouldings consequentially can have nowhere near the intricacy of shape or handling strength achievable by the new method. Furthermore, particle flow becomes particularly difficult or even impossible if structurally significant proportions of tensile reinforcement are added

25. to the damp materials used in block-making, and hence the exceptionally high early demoulding strengths resulting from such reinforcement are not available to conventional methods. In particular, when mixtures containing fibrous reinforcement are processed conventionally substantial

30. extra quantities of liquid are added to make the mix fluid enough for moulding and the excess liquid is then extracted by pressing or suction. This generally limits such pro- • cesses to simple flat sections. More complex sections of fibrous mixtures can be extruded but generally mixes

containing only very short fibres can be processed in this way. No conventional process can achieve the unusual combination of features characteristic of the new method where, for example, complex sections such as those 5. shown in Figs. 1, 2 and 4 can be manufactured with structurally significant proportions of long fibres (e.g. 100 mm) feeding into gaps between bore formers and mould sides of as little as 2mm, while also achieving high enough strengths immediately after wetting to enable 10. 3000mm long sections to be demoulded without relying on chemical setting.

BRIEF DESCRIPTION OF THE DRAWINGS

Figs. 1,2,4,5 and 6 are cross-sectional elevations of typical construction products manufactured 15. in accordance with the present invention; and

Fig. 3 is a diagrammatic elevation of one form of apparatus suitable for use in practising the invention. BEST MODE OF CARRYING OUT THE INVENTION 20. One of the simplest types of equipment using the new method is shown in Fig. 3. A vibrating tray 1 dis¬ tributes the dry powder/fibre mix into a laterally oscillating chute 2 so that two equal streams of material pass either side of a bore former support 3 and are 25. guided by a hopper 4 into a mould 5, containing bore formers 6 which are fitted at their base with vibrators 7. While filling the mould, the bore formers, preferably together with the hopper and bore former support, are vibrated to settle and thoroughly compact the mixture. 30. After filling the mould, the upper parts of the mixture which are not compacted by a head of material above them, are further consolidated by pressing the bore former support 3 (preferably together with the bore formers 6) onto the powder/fibre surface until the whole mass is

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uniformly compacted. Vibration then ceases and the bore formers and bore former support are withdrawn from the mould, which then moves laterally to locate over spray tubes 8. These tubes are fitted at their ends with fine 5. spray nozzles 9, which are oscillated vertically in the bores until sufficient liquid has been delivered to the powder/fibre bore surfaces to just wet the mixture throughout.

Sprays need to be fine and of modest velocity to

10. avoid surface pitting and should generally deliver liquid at an average rate which does not exceed the rate at which the liquid can be absorbed into the powder by capillary action. This prevents the surface from becoming saturated and causing drip marks or local collapse.

15. Spraying is usually terminated before full wetting occurs, so that wetting of the still dry thicker parts of the moulding is completed by capillary action, drawing liquid from the adjacent wet parts. This allows the minimum quantity of liquid to be applied for full wetting, thus

20. avoiding the risk of over-wetting which can cause the mixture to stick to the mould sides and reduce demoulding strengths. When the damp areas have spread throughout the mass, the mould is opened and the uncured product transferred (by vacuum lifting methods, for example) _

25. to conventional curing bays for hardening.

For large bores, a number of spray nozzles may be attached to the sides of delivery tubes 8 so the entire bore surface can be sprayed with little or no vertical oscillation of the tubes. A further, refinement is to

30. attach spray nozzles to the ends of suitably hollowed bore formers 6 so that spraying commences immediately the.formers start being withdrawn. Generally it is difficult to deliver sufficient liquid for full wetting by this method unless the bore formers are withdrawn

very slowly. However, the method can provide an initial coating of liσuid and wetting can be completed by spray tubes 8 as previously described. Such progressive whole or partial wetting of the upper part of the bores while 5. the dry parts below the spray nozzles are still covered by the bore formers, allows less cohesive dry powder mixtures to be used as these now do not have to support a full head of dry material. The technique can be useful for very tall products, although the fibre

10. content needed for adequate strength of the finished product generally imparts sufficient strength to the dry compacted materials to resist collapse and generally such initial wetting is unnecessary. The self weight of the dry material in such cases can be resisted by

15. a combination of arch action against the mould faces and the tensile support given by the reinforcement. This allows practically any height of material to be self-supporting when the bore formers are moved.

It is also possible to apply the liquid by means

20. other than spraying. For example, the liquid can be made to emerge from the ends of suitably hollowed bore formers 6 while the latter are being withdrawn. The rate of bore former withdrawal, liquid flow and capillary absorption have to be carefully balanced to ensure even

25. wetting and prevent progressive over wetting. This leads to slow wetting rates in production but the method is useful when core diameters are too small to accommodate the spray nozzles. It can be preferable to allow the liquid to emerge from slots in,or castillated ends of,

30. the hollow bore formers, to reduce the incidence of blow holes on the bore surface as locked-in air tries to escape through the film of liquid on the bore surface. In this arrangement the liquid penetrates initially where it is in contact with the powder, allowing the

air to escape through the intervening dry parts between the slots of castillations. The dry parts are then wetted by capillary action.

Numerous variations are possible within the same . 5. basic principles. For example, the plant may include equipment for inserting a reinforcing mat into the gaps between the mould sides and the bore formers. Bore formers may alternatively be upward withdrawing and spray tubes may enter from the top instead of at the base.

10. Filling rates for the dry materials, vibration and aspects other than spraying operations are generally as described in British Patent No. "1,346,767.

Numerous product designs are also possible. Apart from the typical basic shapes shown in Figs. 1, 2 and 6,

15. bores may be of any convenient shape and may occur in more than one row. Outer surfaces may also be shaped as shown in Fig. 4. Alternatively the product may have only one bore, giving for example, a box section or the pipe section shown in Fig. 5. Outer and inner surfaces can

20. also be varied as, for example, in the bell-mouth ends for standard type junctions. Typical panels may be 50mm thick, 1200mm wide and 2400mm long, with internal webs and flange thicknesses of around 3mm. Pipes may be 2400mm long and 600mm in diameter. Floor sections (as in

25 ^' . Fig. 6) may have 200mm overall thickness, 5000mm length and 1200mm width. Web thicknesses could be around 300 for mesh reinforced panels or 15mm for steel fibre reinforced units.

A wide range of liquid setting powders and

30. fillers can be used and mixes include Portland cement, gypsum plaster, ground granulated blast furnace slag and pulverised fuel ash _* Larger sized particles can be included, such as sand and/or lightweight aggregates such as expanded clay, perlite or vermiculite.

For such,mixes, the aggregates do not generally exceed 3mm but for larger diameter and more open rein¬ forcement (such as steel mesh) it can be advantageous to increase aggregate sizes. 5. The powder constituents in the mix can have particle sizes varying from around 200 microns to within the colloidal range of under two microns.

The powdery packing round the reinforcement generates frictional resistance to reinforcement pull-out and this

10. composite action usually provides more than adequate strength for satisfactory processing. Hence with most reinforced products in practice the powder characteristics themselves are generally not critical to process stability. In practice, the powder constituent is also generally the

15. reactive (i.e. liσuid setting) component and it has been ^' found that all the usually commercially available types of cement and gypsum plaster can be processed satisfactorily.

The degree of compaction needed can only be deter¬ mined empirically by, for example, increasing vibration

20. energy and top pressure until reliable mouldings are produced. Ideally, for optimum end product strength and stability during manufacture, the particles should be brought together as close as possible before wetting. Side pressure can also be applied but this is usually

25. not necessary. Normal concrete vibration equipment operating at 3000 cycles per minute can be adequate for many mixes. Vibration frequency can also be adjusted to optimise compaction rates, with higher frequencies usually being more effective for the smaller particle

30. sizes. The degree of vibration (and hence compaction) also significantly affects the end product strength after curing and for commercially viable products made by the new process, the proximity of particles to each other should normally be at least as close as commercially

acceptable products made by conventional wet methods. It has been found that the vibration needed to obtain such normally compacted products is generally more than adequate for processing stability, provided adequate 5. support from reinforcement is available. For very widely spaced reinforcement, the degree of compaction becomes more critical as one approaches the unreinforced condition of co-pending Application No. 8000421.

Typical reinforcing fibres include standard commer-

10. cially available glass or polypropylene fibres, steel wire, wood chips or flakes, chopped jute and sisal. Fibre lengths used are preferably in the 25mm to 100mm range. Typical reinforcing mats may be of fibrillated poly¬ propylene, woven vegetable fibre, chopped glass strand

15. mat or steel. Mats should be open textured to allow the • powders to penetrate and compact around the individual strands. For structural reasons reinforcing fibres or mats should preferably be concentrated towards the outer faces of the product and typical glass fibre

20. or polypropylene mat weights in partition panels, for

2 example, may be around 60 to 100 gms. per of reinforcement in each face. In addition to main rein¬ forcing fibres, it is often desirable to include a proportion of much shorter fibres in the matrix to

25. improve impact resistance of- the finished product and cohesiveness for early demoulding. Such matrix fibres may include wood flour, fine short chopped poypropylene onofilament or asbestos fibre. With very fine well dispersed fibres, additions of under 1% can be

30. effective.

Reinforcing fibres may be orientated either parallel or perpendicular to the bores depending on the type of reinforcement used. Loose fibres tend to slew round into the horizontal position on striking the compacted powder/

fibre already _. in the mould and orientate horizontally and at right angles to the vertica.1 bores. If the fibres are long in relation to the gaps between bore formers, most of the reinforcement may be trapped in the gap 5. between the mould sides and the bore formers with very little reinforcement passing into the webs. For certain applications this concentration of reinforcement in the outer layers can be used to economic advantage. For example, if fibre length is made about 30 times gap width,

10. less than 1% of fibres may pass through the barrier formed by the row of bore formers. This can be achieved, for example, with lOOmm long fibres and 3mm gaps. The percentage of fibres passing into the webs increases as fibre length/gap width ratio decreases: at fibre

15. lengths of around 15 times gap width about 10% pass through the bore former barrier and about 20% pass for fibre lengths of about 5 times gap width. Deliberate screening out of most of the reinforcing fibres from the web zone is a departure from the earlier method in

20. British Patent No. 1,346,767 where the aim was to dis¬ tribute reinforcing fibres throughout the matrix evenly to provide a support medium during wetting. In accordance with the present invention provided sufficient fine particles are included and sufficient compaction is applied

25. as described earlier, web zones with appreciably less rein¬ forcement can be made sufficiently stable for effective product manufacture. However, completely fibre-free webs (such as can be obtained by the mat reinforcement described later) can be vulnerable during manufacture

30. and at least some form of fibrous additive, such as the short matrix fibres described earlier, should be included.

Reinforcement with preferential orientation parallel to the bores can be achieved by inserting appropriately

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orientated mesh or mat reinforcement in gaps between the mould sides and the bore formers. In this case the powder mixture can be fed down the gaps between bore formers and, on reaching the compacted material in the 5. mould, is vibrated into the open textured mats. This presses the reinforcement against the mould faces giving the most effective location for optimum bending strength. This applies mainly to glass fibre or poly¬ propylene mats, where corrosion is not a serious

10. problem and hence the cover layer to the reinforcement can be small. For uncoated steel meshes however rein¬ forcement has to be located in the mould so it is at least 12mm from the surface of the finished product. If loose fibres are also included in the powder mix,

15. these tend to orientate horizontally in the webs and at right angles to the mats, giving the most effective location of web reinforcement for optimum shear strength. Generally for all types of reinforcement, the amount of reinforcement needed to impart adequate structural

20. strength to the end product, is more than sufficient to support the dry materials effectively and help prevent collapse during bore former withdrawal. This applies particularly to fibrous reinforcement but quite open meshes can provide a substantial degree of support.

25. A further improvement is to locate continuous vert- ' ical reinforcing strands instead of mats at or near the . mould sides prior to powder filling and include reasonably long (e.g. 50 to lOOmm) chopped reinforcing fibres in the powder mix. This gives the effect of a mat (as the

30. chopped fibres slew round to orientate at right angles to the continuous strands) but without incurring the cost of weaving into a mat. Furthermore, filling rates can be faster as the fixed horizontal strands in a mat tends to inhibit the downward compaction of the

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powders, whereas the loose chopped fibres can move freely with the compacting motion. -

Setting liσuid is generally water, which is frequently heated to aid rapid penetration. It is also.advantageous 5. to preheat the powder to maximise the effect of the heated water. For some powders (particularly some types of pulverised fuel ash) suitable wetting agents should be added to ensure effective penetration. The time taken for complete powder wetting varies with

10. the type of powder, degree of compaction and wall thickness, wetting time can be as low as 30 seconds. This compares very favourably with the method in British Patent No. 1,346,767, where 1200mm high products may require 30 minutes for complete wetting.

15. The degree of dryness of the constituents for effectiv flow and compaction vary with fibre content, particle size and shape and mould intricacy. Limiting moisture contents can only be determined by trial and error but generally the drier the constituents the better. The moisture conten

20. in the powder/fibre mixture should certainly-be well below that needed for the chemical reaction of setting. Typic¬ ally, in the case of gypsum without coarse aggregate moisture contents of readily flowable constituents are under 1% of the dry materials, as against around 20%

25. when just sufficiently dampened for immediate demoulding. In such products the latter water content is little more than is needed for the setting reaction. This compares with liquid contents of around 40% for saturated materials as used in the method disclosed in British

30. Patent No. 1,346,767. For some mixtures, such as those containing high percentages of Portland cement, the _. 20% moisture content of demoulding may be inadequate for completing the full chemical reaction of hardening and additional moisture may have to be provided during

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curing. This can be provided, for example, by additional spraying after demoulding and curing in 100% humid conditions. For cementitious mixes containing a relatively high proportion of coarse aggregate fillers the proportion

5. of water needed to just wet the mix in some cases is as low as 10% of the weight of the dry mix. With these latter mixes, excessive wetting, say, to 22% may well have a deleterious effect on mould separation before chemical cure. This problem of over-wetting is of lesser

10. relevance in the case of gypsum products, in that such materials are much faster setting and it is normal to effect curing before demoulding.

Typical mixes for the manufacture of (for example)

36mm thick panels with 28mm diameter core holes spaced

15. at 31.5mm centres were as follows:

Example 1

Matrix: 67% unretarded gypsum hemi-hydrate casting plaster

("C.B. Stucco" from British Gypsum Limited) ;

33% expanded clay aggregate approximately 1mm

20. to 2mm diameter (crushed "Leca" from Leca Limited)-;

0.2% polypropylene matrix support fibre, 2.5 denier X 5mm long; intimately mixed and dispersed into the gypsum powder prior to mould, filling.

Reinforcement: Two layers (one at each panel face) of 92 2 25. gm/ jute scrim (i.e. open mesh or "hessian") from Low Brothers ^Limited inserted between the mould sides and core formers before filling.

Example 2

Matrix: Unretarded gypsum as Example 1 above but 30. with no coarse aggregate or matrix fibre;

Transverse Reinforcement: 50mm chopped strand Ε-glass fibre (from Fibreglass Limited) metered into the flow of matrix material by regulating the speed of the glass cutter to give 70gm/m 2

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(i.e.- 35gm/m2 per side) of reinforcement, which orientates itself horizontally in the mould during filling; due to the screening - effects of the bore formers described earlier, 5. about 90% of these fibres are trapped in the outer layers between the mould sides and the central row of bore formers. Longitudinal Reinforcement: 136 tex E-glass fibre yarn (from Marglass Limited) placed in evenly 10. spaced vertical lines at 3.75mm centres at each mould face before matrix filling to give

2 approximately 36.3gm/m longitudinal reinforce¬ ment per side. Example 3 15. Matrix: 23% ground granulated blast furnace slag

("Cemsave" from Frodingham Cement Company Ltd) ; 4.5% ground gypsum; 1.5% ordinary Portland cement; 57% sintered pelletised pulverised fuel ash 20. lightweight aggregate (from Lytag Limited) with particle sizes from 2.35mm to dust; 14% pulverised fuel ash (standard waste product from coal fined powder stations supplied by Pozzalin Limited) ; 25. 0.2% polypropylene matrix fibre as in Example

1.

Reinforcement: 160gm/m 2 (i.e. 80gm/m2 per side) of

50mm long chopped strand alkali resistant glass fibre ("Ce fill" from Fibreglass Limited) 30. metered into the mix as for the transverse reinforcement in Example 2. (Note: in this formulation the granulated slag, gypsum, and Portland cement react together forming a substance known in the industry as a supersulphated cement, which

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is characterised by having a low alkali content and as such minimises alkali attack on the ^' glass fibres) .

The apparatus for manufacturing all these Examples was similar to that shown in Fig. 3. 5. Vibration characteristics were optimised to give maximum compaction without causing erratic fibre patterns or particle size segretation. Bore former withdrawal was aided by slightly loosening the mould sides and re- tightening prior to spraying. Spray heads were the

10. smallest capacity available commerically and gave a very fine, mist-like atomisation. The cement based formul¬ ation (Example 3) was demoulded immediately after spraying for approximately 80 seconds and allowing a further minute to allow the moisture to spread to all

15. parts of the moulding. The damp but substantially . uncured samples were then transferred to the curing racks. The gypsum based samples (Examples 1 and 2) were demoulded after two minutes spraying and a further 20 minutes in-mould curing.

20. The reinforcement content of all the samples was sufficient to give ultimate flexural strengths of the composite above the strength of the matrix on its own. Tests on samples of Examples 1 to 3 indicated that the flexural and impact performance in all cases would be

25. adequate for typical building application (such as partition panels and roof decking) .

The cement based formulation in Example 3 would also be suitable for small and medium sized pipes (e.g. 100 to 300mm diameter with 5mm to 10mm wall thickness)

30. as shown in Fig. 5 or- for larger diameter using the configuration shown in Fig. 2.