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Title:
MULTILAYER DISPLAY AND MANUFACTURING METHOD USING SEALANT COMPOSITION
Document Type and Number:
WIPO Patent Application WO/2004/051354
Kind Code:
A1
Abstract:
The application relates to a liquid crystal or electro(magneto)phoretic display comprising a stack of several, preferably two, layers of cells (51, 52) with liquid crystal or electro(magneto)phoretic fluids, which are preferably arranged in a staggered fashion, and a manufacturing method therefor by lamination of several layers of sealed display cells. The electrophoretic display according to the application provides improved contrast ratio, switching performance, reflectivity at the minimum optical density, and structural integrity. The display cells are sealed by means of a sealant composition comprising a solvent which is immiscible with the display fluid, and a thermoplastic elastomer.

Inventors:
Liang, Rong-chang (20142 Pacifica Drive, Cupertino, CA, 95014, US)
Zang, Hongmei (209 E. Red Oak Drive, Apt. #D Sunnyvale, CA, 94086, US)
Wang, Xiaojia (2589 Olive Avenue, Fremont, CA, 94539, US)
Application Number:
PCT/US2003/036879
Publication Date:
June 17, 2004
Filing Date:
November 18, 2003
Export Citation:
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Assignee:
SIPIX IMAGING, INC. (1075 Montague Expressway, Milpitas, CA, 95035, US)
International Classes:
C08K5/01; C08L53/00; C09J153/00; G02F1/1341; G02F1/167; G09F9/00; G02F1/1333; G02F1/1334; G02F1/1347; (IPC1-7): G02F1/1341; G02F1/167; G02F1/1347; C09J153/00
Domestic Patent References:
WO2002056097A22002-07-18
Foreign References:
US20020018043A12002-02-14
US3612758A1971-10-12
US20030176557A12003-09-18
Other References:
"Datasheet Isopar E", EXXONMOBIL CHEMICAL, XP002273408
Attorney, Agent or Firm:
Halluin, Albert P. (Howrey Simon Arnold & White LLP, 301 Ravenswood Avenue Menlo Park, CA, 94025, US)
Download PDF:
Claims:
WHAT IS CLAIMED IS :
1. A display comprising more than one layer of display cells wherein said display cells are filled with a display fluid and sealed with a composition comprising: a) a solvent or, solvent mixture which is immiscible with the display fluid contained within the cells, and b) a thermoplastic elastomer.
2. The display of Claim 1 wherein said solvent has a specific gravity no greater than that of the display fluid.
3. The display of Claim 1 wherein said thermoplastic elastomer has a specific gravity no greater than that of the display fluid.
4. The display of Claim 1 wherein said solvent or solvent mixture has a surface tension of lower than 40 dyne/cm.
5. The display of Claim 1 wherein said solvent or solvent mixture has a surface tension of lower than 35 dyne/cm.
6. The display of Claim 1 wherein said solvent or solvent mixture is selected from the group consisting of alkanes, cyclic alkanes, alkylbenzenes, alkyl esters, ketones and alkyl alcohols.
7. The display of Claim 6 wherein said solvent is heptane, octane, nonane, cyclohexane, decalin, toluene, xylene and their isomers or mixtures thereof.
8. The display of Claim 1 wherein said thermoplastic elastomer is selected from a group consisting of ABA and (AB) n types of diblock, triblock and multiblock copolymers, in which: A is styrene, (xmethylstyrene, ethylene, propylene or norbonene, B is butadiene,isoprene, ethylene, propylene, butylene, dimethylsiloxane or propylene sulfide, and A and B are not the same, and n is> 1.
9. The display of Claim 8 wherein n is 110.
10. The display of Claim 8 wherein said thermoplastic elastomer is poly (styrenebbutadiene), (poly (styrenebbutadienebstyrene), poly (styreneb isoprenebstyrene), poly (styrenebethylene/butylenesbstyrene), poly (styreneb <BR> <BR> <BR> dimethylsiloxanebstyrene), poly (amethylstyrenebisoprene), poly (amethylstyreneb isoprenebamethylstyrene), poly (amethylstyrenebpropylene sulfideba methylstyrene), poly (amethylstyrenebdimethylsiloxanebamethylstyrene) or their grafted copolymers and derivatives thereof.
11. The display of Claim 1 wherein the thermoplastic elastomer is polyester polyurethane, polyether polyurethane, polybutadiene polyurethane, polysiloxane polyurethane, poly (ethylenecopropyleneco5methylene2norbornene), (ethylene propylenediene terpolymer) or their grafted copolymers and derivatives thereof.
12. The display of Claim 1 wherein said sealing composition further comprises a thermoplastic material that is compatible with one of the blocks of the thermoplastic elastomer.
13. The display of Claim 12 wherein the thermoplastic material is selected from the group consisting of polystyrene and poly (amethylstyrene).
14. The display of Claim 1 wherein said composition further comprises a wetting agent.
15. The display of Claim 14 wherein said wetting agent is selected from a group consisting of surfactants, ZONYL fluorosurfactants, fluoroacrylates, fluoromethacrylates, fluorosubstituted long chain alcohols, perfluorosubstituted long chain carboxylic acids, SILWET silicone surfactants and derivatives thereof.
16. The display of Claim 1 wherein said composition further comprising one or more of the following agents: a crosslinking agent, a vulcanizer, a multifunctional monomer or oligomer, a thermal initiator or a photoinitiator.
17. The display of Claim 16 wherein said crosslinking agent is a bisazide and said vulcanizer is a disulfide.
18. The display of Claim 17 wherein said bisazide is 4,4' diazidodiphenyl methane or 2, 6di (4'azidobenzal)4methylcyclohexanone).
19. The display of Claim 17 wherein said disulfide is 2benzothiazolyl disulfide or tetramethylthiuram disulfide.
20. The display of Claim 1 wherein said display fluid is an electrophoretic display fluid.
21. The display of Claim 1 wherein said display fluid comprises a liquid crystal.
22. A process for the manufacture of an electrophoretic display of more than one layer of display panel, which process comprises: a) preparing separately two layers of display cells, each on a conductor plate or film by: (i) preparing display cells on two separate conductor plates or films ; (ii) filling the display cells with a display fluid; and (iii) sealing said filled display cells with a sealing composition comprising a solvent or solvent mixture which is immiscible with the display fluid contained within the cells, and a thermoplastic elastomer ; b) laminating one of the layers over the other optionally with an adhesive layer.
23. The process of Claim 22 wherein step (b) is carried out by laminating one layer of the display cells over the other display panel with the sealing sides of the two layers facing each other.
24. A process for the preparation of an electrophoretic display of more than one layer of display panel, which process comprises: a) forming a first layer of display cells on a conductor plate or film by: by: (i) preparing display cells on a conductor plate or film ; (ii) filling the display cells with a display fluid ; and (iii) sealing said filled display cells with a sealing composition comprising a solvent or solvent mixture whichis immiscible with the display fluid contained within the cells, and a thermoplastic elastomer ; b) forming a second layer of display cells on a transfer release layer following the steps of a (i) a (iii) except that the cells are formed on a transfer release layer rather than a conductor plate or film ; c) laminating said second layer over said first layer and removing said transfer release layer ; d) optionally forming separately additional layers of display cells on transfer release layers following step (b) ; e) laminating said additional layers over a stack of layers already formed and removing the transfer release layers ; and f) laminating a second conductor plate or film over the topmost layer of said stack.
25. The process of Claim 24 wherein step (c) is carried out by laminating said second layer over said first layer with the sealing sides of the two layers facing each other ; followed by removing said transfer release layer.
26. The process of Claim 24 wherein step (e) is carried out by laminating said additional layers over the top layer in said stack of layers already formed, with the sealing sides of the additional layers facing the layers underneath, followed by removing said transfer release layers.
27. The process of Claim 24 wherein step (f) is carried out by lamination with or without an adhesive layer.
28. The process of Claim 22 or 24 wherein said solvent or solvent mixture has a specific gravity no greater than that of the display fluid.
29. The process of Claim 22 or 24 wherein said thermoplastic elastomer has a specific gravity no greater than that of the display fluid.
30. The process of Claim 22 or 24 wherein said cells are prepared by microembossing.
31. The process of Claim 22 or 24 wherein said cells are prepared by photolithography or prepunched holes.
32. The process of Claim 22 or 24 wherein display cells of different layers are prepared by different methods.
33. The process of Claim 32 wherein said methods are independently microembossing, photolithography or prepunched holes.
34. The process of Claim 22 or 24 wherein said sealing step further comprises exposing the sealing layer to UV radiation or thermal baking.
35. The process of Claim 22 or 24 wherein said solvent or solvent mixture in the sealing composition has a surface tension of lower than 40 dyne/cm.
36. The process of Claim 22 or 24 wherein said solvent or solvent mixture has a surface tension of lower than 35 dyne/cm.
37. The process of Claim 22 or 24 wherein said solvent or solvent mixture is selected from the group consisting of alkanes, cyclic alkanes, alkylbenzenes, alkyl esters, ketones and alkyl alcohols.
38. The process of Claim 37 wherein said solvent is heptane, octane, nonane, cyclohexane, decalin, toluene, xylene and their isomers or mixtures thereof.
39. The process of Claim 22 or 24 wherein said thermoplastic elastomer is selected from a group consisting of ABA and (AB) n types of diblock, triblock and multiblock copolymers, in which: A is styrene, amethylstyrene, ethylene, propylene or norbonene, B is butadiene, isoprene, ethylene, propylene, butylen, dimethylsiloxane or propylene sulfide, and A and B are not the same, and n is 2 1.
40. The process of Claim 39 wherein n is 110.
41. The process of Claim 22 or 24 wherein said thermoplastic elastomer is poly (styrenebbutadiene), (poly (styrenebbutadienebstyrene), poly (styreneb isoprenebstyrene), poly (styrenebethylene/butylenesbstyrene), poly (styreneb dimethylsiloxanebstyrene), poly (amethylstyrenebisoprene), poly (amethylstyreneb isoprenebamethylstyrene), poly (amethylstyrenebpropylene sulfideba methylstyrene), poly (amethylstyrenebd imethylsiloxanebamethylstyrene), and their grafted copolymers and derivatives thereof.
42. The process of Claim 22 or 24 wherein the thermoplastic elastomer is polyester polyurethane, polyether polyurethane, polybutadiene polyurethane, polysiloxane polyurethane, poly (ethylenecopropyleneco5methylene2norbornene), (ethylenepropylenediene terpolymer) or their grafted copolymers and derivatives thereof.
43. The process of Claim 22 or 24 wherein said sealing composition further comprises a thermoplastic material that is compatible with one of the blocks of the thermoplastic elastomer.
44. The process of Claim 43 wherein the thermoplastic material is selected from the group consisting of polystyrene and poly (amethylstyrene).
45. The process of Claim 20 or 24 wherein said sealing composition further comprises a wetting agent.
46. The process of Claim 45 wherein said wetting agent is selected from a group consisting of surfactants, ZONYL fluorosurfactants, fluoroacrylates, fluoromethacrylates, fluorosubstituted long chain alcohols, perfluorosubstituted long chain carboxylic acids, SILWET silicone surfactants and their derivatives.
47. The process of Claim 22 or 24 wherein said sealing composition further comprising one or more of the following agents: a crosslinking agent, a vulcanizer, a multifunctional monomer or oligomer, a thermal initiator or a photoinitiator.
48. The process of Claim 47 wherein said crosslinking agent is a bisazide and said vulcanizer is a disulfide.
49. The display of Claim 1 wherein said display cell is of the groove or channel type.
50. The display of Claim 49 wherein the groove or channel type cell has a length in the range of about 10 ! lm to about 90 inches, a width of the groove or channel opening in the range of about 10 to about 500 ßm and a width of the groove or channel partition wall in the range of about 2 to about 500 Am.
51. The display of Claim 49 wherein the groove or channel type cell has a length in the range of about 60 um to about 40 inches, a width of the groove opening in the range of about 40 to about 200 pm and a width of the groove partition wall in the range of from about 5 to about 50 pLm.
52. The display of Claim 1 wherein said display cell is of the grid type.
53. The display of Claim 52 wherein said grid type cell has a length and a width of the grid opening in the range of about 10 to about 300 tm and a width of the partition wall in the range of about 2 to about 500 µm.
54. The display of Claim 52 wherein said grid type cell has a length and a width of the grid opening in the range of about 40 to about 100 gm and a width of the partition wall in the range of about 5 to about 50 pm.
Description:
MULTILAYER DISPLAY AND MANUFACTURING METHOD USING SEALANT COMPOSITION BACKGROUND The electrophoretic display is a non-emissive device based on the electrophoresis phenomenon of charged pigment particles suspended in a solvent. It was first proposed in 1969. The display usually comprises two plates with electrodes placed opposing each other, separated by using spacers. One of the electrodes is usually transparent. A suspension composed of a colored solvent and charged pigment particles is enclosed between the two plates. When a voltage difference is imposed between the two electrodes, the pigment particles migrate to one side and then either the color of the pigment or the color of the solvent can be seen according to the polarity of the voltage difference.

In order to prevent undesired movement of the particles, such as sedimentation, partitions between the two electrodes were proposed for dividing the space into smaller cells (see M. A. Hopper and V. Novotny, IEEE Trans. Electr. Dev. , 26 (8): 1148-1152 (1979) ). However, in the case of partition-type electrophoretic displays, difficulties were encountered in the formation of the partitions and the process of enclosing the suspension. Furthermore, it was also difficult to keep suspensions of different colors separate from each other in the partition-type electrophoretic display.

Another type of EPD (see US Patent No. 3,612, 758) has electrophoretic cells that are formed from parallel line reservoirs (the channel or groove type). The filling and sealing of the electrophoretic fluid in the channels are accomplished by a batch- wise process. In addition, the problem of undesirable particle movement or sedimentation, particularly in the longitude direction, remains an issue.

Subsequently, attempts were made to enclose the suspension in microcapsules.

US Patent Nos. 5,961, 804,5, 930,026 and 6,017, 584 describe microencapsulated electrophoretic displays. The microcapsule type display has a substantially two dimensional arrangement of microcapsules each having therein an electrophoretic composition of a dielectric fluid and a suspension of charged pigment particles that visually contrast with the dielectric solvent. The microcapsules can be formed by interfacial polymerization, in-situ polymerization or other known methods such as physical processes, in-liquid curing or simple/complex coacervation. The microcapsules, after their formation, may be injected into a cell housing two spaced-

apart electrodes, or"printed"onto or coated on a transparent conductor film. The microcapsules may also be immobilized within a transparent matrix or binder that is itself sandwiched between the two electrodes.

The electrophoretic displays prepared by these processes previously known, in particular, the microencapsulation process as disclosed in US Patent Nos.

5,930, 026 and 6, 017,584, have many shortcomings. For example, the electrophoretic display manufactured by the microencapsulation process suffers from sensitivity to environmental changes (in particular, sensitivity to moisture and temperature) due to the wall chemistry of the microcapsules. Secondly, the electrophoretic display based on the microcapsules has poor scratch resistance due to the thin wall and large particle size of the microcapsules. To improve the handleability of the display, microcapsules are embedded in a large quantity of a polymer matrix which results in a slow response time due to the large distance between the two electrodes and a low contrast ratio because of the low payload of pigment particles. It is also difficult to increase the surface charge density on the pigment particles because charge-controlling agents tend to diffuse to the water/oil interface during the microencapsulation process. The low charge density or zeta potential of the pigment particles in the microcapsules also results in a slow response rate. Furthermore, because of the large particle size and broad size distribution of the microcapsules, the electrophoretic display of this type previously known has poor resolution and addressability for color applications.

An improved EPD technology was recently disclosed in co-pending applications, US Serial Number 09/518,488 filed on March 3,2000 (corresponding to WO 01/67170), US Serial Number 09/759,212 filed on January 11,2001 (corresponding to WO 02/56097), US Serial Number 09/606,654 filed on June 28,2000 (corresponding to WO 02/01280) and US Serial Number 09/784,972 filed on February 15, 2001 (corresponding to WO 02/65215), all of which are incorporated herein by reference.

The improved EPD comprises isolated cells formed from microcups of well-defined shape, size and aspect ratio and filled with charged pigment or pigment-containing microparticles dispersed in a dielectric solvent, preferably a fluorinated solvent, or solvent mixture. The filled cells are individually sealed with a polymeric sealing layer, preferably formed from a composition comprising a material selected from the group consisting of thermoplastics, thermosets and precursors thereof.

The microcup structure enables a format flexible and efficient roll-to-roll continuous manufacturing process for the preparation of EPDs. The displays can be prepared on a continuous web of a conductor film such as ITO/PET by, for example, (1) coating a radiation curable composition onto the ITO/PET film, (2) forming the microcup structure by a microembossing or photolithographic method, (3) filling the electrophoretic fluid into the microcups and sealing the filled microcups, (4) laminating the sealed microcups with the other conductor film and (5) slicing and cutting the display to a desirable size or format for assembling.

The sealing of the microcups after they are filled with a dispersion of charged pigment particles in a dielectric fluid can be accomplished by overcoating the electrophoretic fluid with a solution containing the sealing composition. To reduce or eliminate the degree of intermixing during and after the overcoating process, it is highly advantageous to use a sealing composition that is immiscible with the electrophoretic fluid and preferably has a specific gravity no greater than the dielectric fluid. The sealing is then accomplished by hardening the sealing composition by solvent evaporation, interfacial reaction, moisture, heat, radiation or a combination thereof to form a seamless polymeric sealing layer on the electrophoretic fluid. The process as described is the two-pass sealing method.

Alternatively, the sealing can be accomplished by a one-pass method involving first dispersing a sealing composition in the electrophoretic fluid before the filling step.

The sealing composition is immiscible with the dielectric solvent and has a specific gravity no greater than that of the solvent and the pigment particles. After filling, the sealing composition phase separates from the electrophoretic fluid and forms a supernatant layer on top of the fluid. The sealing of the microcups is then conveniently accomplished by hardening the precursor layer by solvent evaporation, interfacial reaction, moisture, heat or radiation. UV radiation is the preferred method to seal the microcups, although a combination of two or more curing mechanisms as described above may be used to increase the throughput of sealing.

One advantage of this type of EPD is that the microcup wall is in fact a built-in spacer to keep the top and bottom substrates apart at a fixed distance. The mechanical properties and structural integrity of microcup displays are significantly better than any displays previously known including those manufactured by using spacer particles. In addition, displays involving microcups have desirable mechanical

properties including reliable display performance when the display is bent, rolled or under compression pressure from, for example, a touch screen application. The use of the microcup technology also eliminates the need of an edge seal adhesive which would limit and predefine the size of the display panel and confine the display fluid inside a predefined area. The display fluid within a conventional display prepared by the edge sealing adhesive method will leak out completely if the display is cut in any way, or if a hole is drilled through the display. The damaged display will be no longer functional. In contrast, the display fluid within the display prepared by the microcup technology is enclosed and isolated in each cell. The microcup display may be cut to almost any dimensions without the risk of damaging the display performance due to the loss of display fluid in the active areas. In other words, the microcup structure enables a format flexible display manufacturing process, wherein the process produces a continuous output of displays in a large sheet format which can be cut into any desired format and size. The isolated microcup or cell structure is particularly important when cells are filled with fluids of different specific properties such as colors and switching rates. Without the microcup structure, it will be very difficult to prevent the fluids in adjacent areas from intermixing or being subject to cross-talk during operation.

In order to achieve a higher contrast ratio, one of two approaches may be taken: (1) using a darkened background to reduce the light leaking through the inactive partition wall or (2) using a microcup of wider opening and narrower partition to increase the payload. However, the darkened background typically results in a lower reflectivity at the Dmin state. On the other hand, display cells formed from wider microcups and narrower partition walls tend to have a poor resistance against compression and/or shear forces imposed by, for example, a sharp stylus for a touch screen panel.

Moreover, the use of high payload cells increases not only the degree of difficulty in manufacturing but also the cost of manufacturing.

Substructures within microcup have been disclosed in a copending patent application, US Serial Number 60/315,647 filed on August 28,2001, to improve the mechanical properties and image uniformity of displays made from microcups having wide openings and narrow partition walls. However, the manufacturing of such microcups with substructures is costly and the trade-off between contrast ratio and reflectivity at the Dmin state remains unresolved.

SUMMARY OF THE INVENTION The present invention is directed to a multilayer display having improved contrast ratio, switching performance, reflectivity at the Dmin state and structural integrity, and its manufacture.

The first aspect of the invention is directed to a multiplayer display wherein the display cells are sealed by a sealing composition comprising the following ingredients: (1) a solvent or solvent mixture which is immiscible with the display fluid in the microcups and exhibits a specific gravity no greater than that of the display fluid ; and (2) a thermoplastic elastomer.

The second aspect of the invention is directed to methods for the preparation of the multilayer displays.

The display cells of the multiplayer display of the present invention may be sealed seamless and free of defects by a continuous web process using the sealing composition.

The sealing composition also has many other advantages. For example, it also exhibits good wetting properties over the filled microcups throughout the coating process and develops good film integrity over the display fluid even before the solvent evaporates completely. As a result, the integrity of the coating is maintained and no dewetting or beading on the electrophoretic fluid is observed. In addition, the composition enables the continuous sealing of wider microcups, particularly those having a width greater than 100 microns. Furthermore, the sealing composition enables the formation of a sealing layer less than 3 micron thick which is typically difficult to achieve by using traditional sealing compositions. The thinner sealing layer shortens the distance between the top and bottom electrodes resulting in a faster switching rate.

As taught in the copending patent applications US Serial Number 09/518,488 filed on March 3,2000 (corresponding to WO 01/67170), US Serial Number 09/759,212 filed on January 11,2001 (corresponding to WO 02/56097); US Serial Number 09/606, 654 filed on June 28,2000 (corresponding to WO 02/01280); US Serial Number 09/784,972 filed on February 15,2001 (corresponding to WO 02/65215); and US Serial Number 09/879, 408 filed on June 11,2001, the sealing composition may be predispersed in the electrophoretic fluid, filled in the microcups to form a seamless

sealing layer in a one-pass seeing process. In this case, the sealing composition may<BR> <BR> <BR> <BR> be in-line blended with the eiectrophoretic fluid immediately before the one pass filling and sealing process. The sealing composition may also be applied by the two-pass sealing method.

BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 shows a typical display cell prepared by the microcup technology with a darkened background to improve the contrast ratio.

Figures 2a and 2b show the"on" (Dmin) and"off" (Dmax) states, respectively, of a two-layer electrophoretic display.

Figures 3a and 3b show a two-layer color electrophoretic display wherein the top layer comprises microcups filled with red, green and blue electrophoretic fluids and the bottom layer comprises microcups filled with a black electrophoretic fluid.

Figures 4a and 4b show a two-layer full color electrophoretic display wherein the top layer comprises microcups filled with red, green and blue electrophoretic fluids and the bottom layer comprises microcups filled with red, green, blue and black electrophoretic fluid. The red, green, blue and inactive partition areas of the upper layer are overlapped with registration to the red, green, blue and black microcups of the lower layer, respectively.

Figures 5a and 5b show the methods for the manufacture of an electrophoretic display having two or more layers of display cells. Figure 5a shows a process of preparing a two-layer electrophoretic display by laminating two microcup layers with the sealing sides of the microcups facing each other. Figure 5b shows another process of preparing a two-layer electrophoretic display by (i) transferring a microcup layer from a release substrate onto a second microcup layer on a conductor film and (ii) laminating the resultant composite film onto a conductor film, optionally with an adhesive. The process (i) may be repeated to prepare an electrophoretic display having more than two layers of display cells.

Figure 6a, 6b, and 6c show three alternative partition type cell structures. Figure 6a is the groove type, 6b is the groove type with substructure and 6c is the grid type.

All of the display cells referred to above, in the context of the present application, are sealed by either the one-pass or two-pass process with a composition comprising: (a) a solvent or solvent mixture which is immiscible with the display fluid in the microcups and exhibits a specific gravity no greater than that of the display fluid ; and (b) a thermoplastic elastomer.

DETAILED DESCRIPTION OF THE INVENTION I. Definitions Unless defined otherwise in this specification, all technical terms are used herein according to their conventional definitions as they are commonly used and understood by those of ordinary skill in the art.

The term"microcup"refers to the cup-like indentations, which may be created by methods such as microembossing, photolithography (as disclosed in WO 01/67170) or pre-punched holes (as disclosed in US Serial Number 09/942,532 published under US Publication No. 2002-75556).

The term"cell", in the context of the present invention, is intended to mean the single unit formed from a sealed microcup. The cells are filled with charged pigment particles dispersed in a solvent or solvent mixture. The electrophoretic fluid may also be replaced by a suitable liquid crystal composition having the ordinary refractive index matched to that of the isotropic cup material. In the"on"state, the liquid crystal in the microcups is aligned to the field direction and is transparent. In the"off"state, the liquid crystal is not aligned and scatters light. To maximize the light scattering effect of a liquid crystal display, the diameter of the microcups is typically in the range of 0.5-10 microns.

The term"aspect ratio"is a commonly known term in the art and is the depth to width ratio or the depth to diameter ratio of the microcup opening.

The term"Dmax"refers to the maximum achievable optical density of the display.

The term"Dmin"refers to the minimum optical density of the display background.

The term"contrast ratio". is defined as the ratio of the % reflectance of an electrophoretic display at the Dmin state to the % reflectance of the display at the Dmax state.

li. The Multilayer Display Electrophoretic display cells prepared by the microcup technology, as shown in Figure 1, comprise two electrode plates (10,11), at least one of which is transparent (10), and a layer of cells (12) enclosed between the two electrodes. The cells are filled with charged pigment or pigment-containing microparticles dispersed in a colored dielectric solvent and sealed with a sealing layer (13). Not shown in Figure 1, the sealing layer preferably extends over the partition walls (16) and forms a contiguous layer thereon. The sealed cells are laminated onto the second conductor film (10) optionally with an adhesive layer (14). When a voltage difference is imposed between the two electrodes, the charged particles migrate to one side, such that either the color of the pigment or the color of the solvent is seen through the transparent conductor plate or film (10). In addition, at least one of the two conductor films is patterned. To improve the contrast ratio of the EPD, one of two approaches is typically taken: (a) using microcups of a higher payload (a higher aspect ratio and/or a higher ratio of opening area to total area) or (b) using a blackened conductor film (11) on the non- viewing side. Since no light scattering particles are present in the inactive partition areas (16), the viewer will see the background color through the partition areas in both the"on"and"off"states. The blackened background of such a single layer EPD results in a higher Dmax and contrast ratio, but a lower reflectivity in the Dmin state.

The trade-off between contrast ratio and reflectivity in the Dmin state is eliminated in the staggered two-layer structure depicted in Figures 2a and 2b.

In the two figures, the display has an upper cell layer (21) and a lower cell layer (22).

The cells of the two layers are individually sealed with a sealing layer (23). The two layers are arranged in a staggered fashion and the sealing sides of the two layers face each other. The two-layer structure is sandwiched between a top transparent conductor film (24) and a bottom conductor film (25).

In the"on"state (Figure 2a), the white particles in both upper and lower layers are attracted to the top of the cells (toward the viewing side). The partition areas (26) of the top layer will appear"white"since light is reflected back by the particles in the lower layer. In contrast, at the"off"state (Figure 2b), the white particles in both layers are attracted to the bottom of the cells (toward the non-viewing side). The partition areas of the top layer will appear"colored"since light is absorbed by the colored dielectric

solvent in the lower layer. As a result, Dmax and contrast ratio of the display may be improved without the trade-off in the reflectivity in the Dmin state.

The two-layer or multilayer EPD also allows the use of a cell with a lower payload (a lower aspect ratio and a lower ratio of opening area to total area) to achieve a high contrast ratio with a higher reflectivity at the Dmin state. This significantly improves the release properties of the embossing process and reduces the cost and degree of difficulty in the mold making process.

Figures 3a and 3b show a two-layer color electrophoretic display wherein the top layer (31) comprises display cells filled with red, green and blue electrophoretic fluids and the bottom layer (32) comprises display cells filled with a black electrophoretic fluid.

In both figures, the inactive partition areas (36) of the upper layer (31) are staggered with the active cell areas of the lower layer (32). The two-layer structure is sandwiched between two conductor films (34) and (35). At least one of the two conductor films is transparent.

Figures 4a and 4b show a two-layer full-color electrophoretic display wherein the top layer (41) comprises display cells filled with red, green and blue electrophoretic fluids and the bottom layer (42) comprises display cells filled with red, green, blue and black electrophoretic fluids. The colored cells and the inactive partition areas (46) of the two layers are arranged in a staggered manner so that the red, green, blue and inactive partition areas of the top layer (41) are overlapped with registration to the red, green, blue and black microcups of the bottom layer (42), respectively. The two layer structure is sandwiched between two conductor films (44) and (45). At least one of the two conductor films is transparent.

In the two-layer structure, the top microcup layer may be laminated onto the bottom layer at an appropriate angle to avoid formation of the undesirable Moire pattern. Alternatively, a less symmetrical microcup array may be used for similar purpose.

The pigment or pigment-containing microparticles or the colorant particles may also be magnetic. In one embodiment, a two-layer electromagnetophoretic display may have a bottom layer comprises display cells which are filled with an electromagnetophoretic fluid comprising a mixture of black magnetic particles and white non-magnetic particles dispersed in a colorless clear solvent or solvent mixture. The top layer may comprise red, green and blue cells which are filled with electrophoretic

fluids comprising white particles dispersed in red, green and blue solvents, respectively.

Alternatively, the top layer may comprise display cells which are filled with an electrophoretic fluid comprising a mixture of white and black particles dispersed in a colorless clear solvent or solvent mixture.

Details of the electromagnetophoretic display layer are disclosed in pending applications, US Serial Number 60/367,325 filed on March 21,2002 and US Serial Number 60/375,299 filed on April 23,2002, the contents of which are incorporated herein in their entirety by reference.

In general, the cell gap or the shortest distance between the two electrodes in a multilayer display may be in the range of 15 to 200, um, preferably in the range of 20 to 50 pm. The thickness of each display cell layer may vary. In one embodiment, it may be in the range of 10 to 100 um, preferably in the range of 12 to 30 ; j. m. The concentration of particles and dyes or colorants in each display cell layer may also vary for different applications.

Ill. Preparation Of the Microcup Array The microcup-based display cells may be prepared by either microembossing, photolithography or pre-punched holes as taught in copending patent applications, US Serial Number 09/518,488 filed on March 3,2000 (corresponding to WO 01/67170), US Serial Number 09/942,532 filed on August 29,2002 (US Publication No. 2002-75556 published on June 20,2002), US Serial Number 09/759,212 filed on January 11,2001 (corresponding to WO 02/56097), US Serial Number 09/606,654 filed on June 28,2000 (corresponding to WO 02/01280) and US Serial Number 09/784,972 filed on February 15,2001 (corresponding to WO 02/65215), all of which are incorporated herein by reference.

In general, the microcup-based cells can be of any shape, and their sizes and shapes may vary. The cells may be of substantially uniform size and shape in one system. However, in order to maximize the optical effect, cells having a mixture of different shapes and sizes may be produced. For example, cells filled with a dispersion of the red color may have a different shape or size from the green cells or the blue cells. Furthermore, a pixel may consist of different numbers of cells of different colors.

For example, a pixel may consist of a number of small green cells, a number of large

red cells and a number of small blue cells. It is not necessary to have the same shape and number for the different colors.

The opening ? of the microcups may be circular, square, rectangular, hexagonal ..') or any other shape, he partition areas between the openings are preferably kept small in order to achieve high color saturation and contrast ratio while maintaining desirable mechanical properties. Consequently, the honeycomb-shaped opening is preferred over, for example, the circular opening.

For reflective electrophoretic displays, the dimension of each individual microcup may be in the range of about 102 to about 1 o6, um2, preferably about 103 to about 105 pm2. The depth of the microcups may be in the range of about 3 to about 200 lim, preferably about 10 to about 50, um. The ratio of opening area to total area may be in the range of about 0.1 to about 0.95, preferably about 0.4 to about 0.90. The width of the partition between microcups may be in the range of about 2 to about 200 µm, preferably about 5 to about 20 lim.

In the case of groove or channel type of display cells as shown in Figure 6a and 6b, the length of the groove may be in the range of about 10 lim to about 90 inches, preferably in the range of about 60 um to about 40 inches. The width of the groove or channel opening may be in the range of about 10 to about 500 lim, preferably in the range of about 40 to about 200 pLm. The width of the groove or channel partition wall may be in the range of about 2 to about 500 um, preferably about 5 to about 50 p, m.

For the groove type cells, an edge seal adhesive may be applied to the first block at both ends (in the longitudinal direction) of the grooves. The groove type cells are also useful for multicolor applications.

In the case of the grid type of display cells as shown in Figure 6c, the length and width of the grid opening may be in the range of about 10 to about 300 p. m, preferably in the range of about 40 to about 100 µm. The width of the grid partition wall may be in the range of about 2 to about 500 jj. m, preferably about 5 to about 50, um.

IV. The Sealing Composition and Process After the microcups are filled with a display fluid (e. g. , an electrophoretic display fluid or a liquid crystal composition), the filled microcups are sealed with a sealing composition comprising the following ingredients:

(1) a solvent or solvent mixture which is immiscible with the display fluid in the microcups and exhibits a specific gravity no greater than that of the display fluid ; and (2) a thermoplastic elastomer.

Compositions comprising a thermoplastic elastomer having good compatibility with the microcup material and good barrier properties against the display fluid are useful. Examples of thermoplastic elastomers include ABA, and (AB) n type of di-block, tri-block and multi-block copolymers wherein A is styrene, a-methylstyrene, ethylene, propylene or norbonene; B is butadiene, isoprene, ethylene, propylene, butylen, dimethylsiloxane or propylene sulfide ; and A and B cannot be the same in the formula.

The number, n, is > 1, preferably 1-10. In one embodiment, the thermoplastic elastomers may include di-block or tri-block copolymers of styrene and a-methylstyrene such as SB (poly (styrene-b-butadiene) ), SBS (poly (styrene-b-butadiene-b-styrene) ), SIS (poly (styrene-b-isoprene-b-styrene) ), SEBS (poly (styrene-b-ethylene/butylene-b- styrene) ), poly (styrene-b-dimethylsiloxane-b-styrene), poly (a-methylstyrene-b-isoprene), poly (a-methylstyrene-b-isoprene-b-a-methylstyrene), poly (a-methylstyrene-b-propylene sulfide-b-a-methylstyrene) or poly (a-methylstyrene-b-dimethylsiloxane-b-a- methylstyrene). A review of the preparation of the thermoplastic elastomers can be found in N. R. Legge, G. Holden, and H. E. Schroeder ed.,"Thermoplastic Elastomers", Hanser Publisher (1987). In one embodiment, commercially available styrene block copolymers such as Kraton D and G series (from Kraton Polymer, Houston, TX) are used.

Polyurethane thermoplastic elastomers and crystalline rubbers such as polyether polyurethanes, polyester polyurethanes, polybutadiene polyurethanes, polysiloxane polyurethanes or poly (ethylene-co-propylene-co-5-methylene-2-norbornene) or EPDM (ethylene-propylene-diene terpolymer) rubbers such as Vistalon 6505 (from Exxon Mobil, Houston, TX) or grafted copolymers thereof have also been found useful.

The sealing composition significantly enhances the modulus and film integrity of the sealing layer throughout the coating and drying processes of the sealing layer.

Thermoplastic elastomers having low critical surface tension (e. g., lower than 40 dyne/cm) and high modulus or Shore A hardness (e. g. , higher than 60) have been found useful probably because of their favorable wetting property and film integrity over the display fluid.

The thermoplastic elastomer is dissolved in a solvent or solvent mixture which is immiscible with the display fluid in the microcups and exhibits a specific gravity no greater than that of the display fluid. Low surface tension solvents are used because of their better wetting properties over the microcup walls and the electrophoretic fluid. In one embodiment, the solvents or solvent mixtures may have a surface tension lower than 40 dyne/cm. In another embodiment, the solvent or solvent mixtures may have a surface tension of lower than 35 dyne/cm.

Suitable solvents include alkanes (including C6-12 alkane such as heptane, octane or Isopar solvents from Exxon Chemical Company, nonane, decane or their isomers), cycloalkanes (including C6-12 cycloalkanes such as cyclohexane and decalin or the like), alkylbezenes (including mono-or di-C16 alkyl benzenes such as toluene, xylene or the like), alkyl esters (including C25 alkyl esters such as ethyl acetate, propyl acetate, isobutyl acetate or the like), ketones (including C3 7 ketones such as methyl ethyl ketone, methyl propyl ketone, methyl butyl ketone, cyclohexanone or the like) or C3-5 alkyl alcohols (including isopropanol, butanol or the like). Mixtures of an alkylbenzene and an alkane are useful for hydrocarbon elastomers.

Cosolvens and wetting agents (such as the FC surfactants from 3M Company, Zonyl fluorosurfactants from DuPont, fluoroacrylates, fluoromethacrylates, fluoro- substituted long chain alcohols, perfluoro-substituted long chain carboxylic acids and derivatives thereof and Silwet silicone surfactants from OSi, Greenwich, CT) may also be included in the composition to improve the adhesion of the sealant to the microcups and provide a wider coating process latitude. Other ingredients including crosslinking agents (e. g. , bisazides such as 4, 4'-diazidodiphenylmethane and 2, 6-di- (4'- azidobenzal)-4-methylcyclohexanone), vulcanizers (e. g., 2-benzothiazolyl disulfide and tetramethylthiuram disulfide), multifunctional monomers or oligomers (e. g., hexanediol, diacrylates, trimethylolpropane, triacrylate, divinylbenzene, diallylphthalene), thermal initiators (e. g., dilauroyl peroxide, benzoyl peroxide) and photoinitiators (e. g., isopropyl thioxanthone (ITX), Irgacure 651 and Irgacure 369 from Ciba-Geigy) are also highly useful to enhance the physicomechanical properties of the sealing layer by crosslinking or polymerization reactions during or after the sealing process. The sealing composition may also comprise a thermoplastic material that is compatible with one of the blocks of the thermoplastic elastomer. Examples of such thermoplastic materials include polystyrene and poly (a-methylstyrene).

In the two-pass method, the sealing composition is typically overcoated onto partially filled microcups. Alternatively, the sealing composition may be predispersed in the electrophoretic fluid and filled in the microcups to form a seamless sealing layer by the one-pass process. In the one-pass process, the sealing composition may be predispersed by in-line blending into the electrophoretic fluid immediately before being filled into the microcups.

The sealed microcups optionally may be post treated by UV radiation or thermal baking to further improve the barrier properties. The adhesion of the sealing layer to the microcups may also be improved by the post-curing reaction, likely due to the formation of an interpenetration network at the microcup-sealing layer interphase.

V. Preparation of a Single Layer Display The process can be a continuous roll-to-roll process as disclosed in WO 01/67170. It may comprise the following steps: 1. Coat a layer of an embossable composition comprising a thermoplastic, thermoset or a precursor thereof optionally with a solvent, on a conductor plate or film.

The solvent, if present, readily evaporates.

2.-Emboss the embossable layer at a temperature higher than the glass transition temperature of the thermoplastic, thermoset or precursor layer by a pre- patterned male mold.

3. Release the mold from the embossable layer preferably during or after it is hardened by proper means. by proper means.

4. Fill the microcups with an electrophoretic fluid or a liquid crystal composition and seal the filled microcups with a sealing composition as described above by either the one-pass or two-pass overcoating process.

5. Laminate the sealed array of electrophoretic cells with a second conductor plate or film, optionally with an adhesive layer which may be a pressure sensitive adhesive, a hot melt adhesive, a heat, moisture or radiation curable adhesive.

The laminate adhesive may be post cured by radiation such as UV through the top conductor film if the latter is transparent to the radiation. The finished product may be cut to various size and shape after the lamination step.

The preparation of the microcups described above can be conveniently replaced by the alternative procedure of photolithography as disclosed in WO 01/67170 or the

pre-punched holes as disclosed in US Patent Publication No. 2002-75556. A full color EPDs may be prepared by sequentially filling red, green and blue electrophoretic fluids into the microcups and subsequently sealing the filled microcups by the one-pass or two-pass sealing method.

VI. Electrophoretic Display Having Multiple Layers of Display Panel and its Manufacture Figures 5a and 5b show the methods for the manufacture of an electrophoretic display having two or more layers of display cells.

Figure 5a shows the process of preparing a two-layer electrophoretic display by laminating a top layer (51) and a bottom layer (52) of display cells prepared by, for example, the procedure described in the steps 1-4 in Section V. The filled display cells are individually sealed with a sealing layer (53). The sealing layer is formed from a composition as described in Section IV above. The conductor film (54) on the viewing side is transparent and the conductor film (55) on the non-viewing side may be blackened or colored. An adhesive layer may be used to facilitate the lamination process. The two layers (51 and 52) are arranged with the inactive partition areas (56) of one layer and the active cell areas of another layer in a staggered fashion.

Figure 5b shows another process of preparing a two layer electrophoretic display by (i) preparing a layer of display cells (52) on a conductor film (55) by, for example, the procedure described in the steps 1-4 in Section V; (ii) preparing another layer of display cells (51) on a release substrate (57) by the same procedure in (i); (iii) laminating the layer of display cells (51) on the release substrate (57) onto the layer (52), optionally with an adhesive (not shown); (iv) removing the release substrate and (v) laminating the resultant composite film onto a conductor film (54), optionally with an adhesive (not shown). The steps (ii), (iii), and (iv) may be repeated to prepare an electrophoretic display having more than two layers of display cells.

In the two-layer or multilayer electrophoretic display as prepared above, it is important that the inactive partition areas of the upper microcup layer are arranged with the active microcup areas of the lower layer in a staggered manner. At least one of the two conductor films (54 and 55) is pre-patterned. Also at least the conductor film (54) on the viewing side is transparent.

EXAMPLES

Example 1: Microcup Formulation 35 Parts by weight of Ebecryl 600 (UCB), 40 parts of SR-399 (Sartomer), 10 parts of Ebecry ! 4827 (UCB), 7 parts of Ebecryl 1360 (UCB), 8 parts of HDDA, (UCB), 0.05 parts of Irgacure 369 (Ciba Specialty Chemicals) and 0.01 parts of isopropyl thioxanthone (ITX from Aldrich) were mixed homogeneously and used for microembossing.

Example 2: Preparation of Microcup Array A primer solution comprising of 5 parts of Ebecryl 830, 2. 6 parts of SR-399 (from Sartomer), 1.8 parts of Ebecry 1701,1 part of PMMA (Mw= 350,000 from Aldrich), 0.5 parts of Irgacure 500 and 40 parts of methyl ethyl ketone (MEK) was coated onto a 2 mil 60 ohm/sq. ITO/PET film (from Sheldahl Inc., MN.) using a #3 Myrad bar, dried and UV cured by using the Zeta 7410 (5 w/cm2, from Loctite) exposure unit for 15 minutes in air. The microcup formulation prepared in Example 1 was coated onto the treated ITO/PET film with a targeted thickness of about 501lu, embossed with a Ni-Co male mold having a 60 (length) x 60 (width), um repetitive protrusion square pattern with 25- 50 jj. m protrusion height and 10 p. m wide partition lines, UV cured from the PET side for 20 seconds and removed from the mold with a 2"peeling bar at a speed of about 4-5 ft/min. Well-defined microcups with depth ranging from 25 to 50 im were prepared by using male molds having corresponding protrusion heights. Microcup arrays of various dimension such as 70 (length) x70 (width) x35 (depth) x10 (partition), 100 (L) x100 (W) x35 (D) x10 (P), and 100 (L) x100 (W) x30 (D) x10 (P), um were also prepared by the same procedure.

Example 3: Pigment Dispersion 6.42 Grams of Ti Pure R706 were dispersed with a homogenizer into a solution containing 1.94 grams of Fluorolink D from Solvay Solexis, 0.22 grams of Fluorolink 7004 also from Solvay Solexis, 0.37 grams of a fluorinated copper phthalocyanine dye from 3M and 52.54 grams of perfluor solvent HT-200 (Solvay Solexis).

Example 4: Pigment Dispersion The procedure of Example 3 was followed, except that the Ti Pure R706 and Fluorolink were replaced by a polymer coated TiO2 particles PC-9003 from Elimentis (Highstown, NJ) and Krytox (Du Pont), respectively.

Example 5 : Microcup Sealing The electrophoretic fluid prepared in Example 3 was diluted with a volatile perfluor co-solvent FC-33 from 3M and coated onto a 35 microns deep microcup array prepared in Example 2. The volatile cosolvent was allowed to evaporate to expose a partially filled microcup array. A 7.5% solution of polyisoprene (97% cis, from Aldrich) in heptane was then overcoated onto the partially filled microcups by a Universal Blade Applicator with an opening of 3 mil. The overcoated microcups were then dried at room temperature. A seamless sealing layer of about 7-8 Am thickness (dry) with acceptable adhesion and uniformity was formed on the microcup array. No observable entrapped air bubble in the sealed microcups was found under microscope. A second ITO/PET conductor precoated with an adhesive layer was laminated onto the sealed microcups.

The electrophoretic cell showed satisfactory switching performance with good flexure resistance. No observable weight loss was found after being aged in a 66°C oven for 5 days.

Example 6: Microcup Sealing The procedure of Example 5 was followed, except that the thickness of the polyisoprene layer was reduced to 4 microns by using a blade applicator of 2 mil opening. Pinholes and broken sealing layer were clearly observed under optical microscope.

Examples 7-14: Microcup Sealing The procedure of Example 5 was followed, except that the sealing layer was replaced by polyisoprene, polystyrene, polyvinylbutyral (Butvar 72, from Solutia Inc., St.

Louis, MO) and thermoplastic elastomers such as SIS (Kraton D1107, 15% styrene), SBS (Kraton D1101, 31% styrene) SEBS (Kraton G1650 and FG1901, 30% styrene) and EPDM (Vistalon 6505,57% ethylene), respectively. The results are summarized in Table 1. As it can be seen from Table 1, thermoplastic elastomers enabled thinner and higher quality sealing even on microcups of wide openings.

Table 1: Sealing of microcups Example No. Sealing Coating solution Estimated dry Cup dimension Coating quality Coating quality Polymer thickness (L x W x D x P), um (visual) (Microscopic) comparative 5 Polyisoprene 7.5% in heptane 4-5 um 60x60x35x10 Fair pinholes, broken (97% cis) layer comparative 6 Polyisoprene 7.5% in heptane 7-8 um 60x60x35x10 good good (97% cis) comparative 7 Polystyrene 30% in toluene 7-8 um 60x60x35x10 very poor, severe incomplete dewetting sealing, defects comparative 8 Butvar 72 8.5% in 4-5 um 60x60x35x10 poor fair isopropanol reproducibility 9 SIS (Kraton 4% in Heptane 4-5 um 70x70x35x10 good good D1107); 15% Styrene 10 SIS (Kraton 4% in Heptane 3-4 um 100x100x35x10 good good D1107); 15% Styrene 11 SBS (Kraton 10% in toluene/ 4-5 um 70x70x35x10 good good D1107); 31% heptane (20/80) Styrene 12 SEBS (Kraton 10% in xylene/ 4-5 um 70x70x35x10 good good FG-1901, Isopar E (5/95) 30% styrene, 1.5% maleic anhydride) 13 SEBS (Kraton 5% in toluene/ 4-5 um 70x70x35x10 good good G 1650, 30% heptane (5/95) styrene) 14 EPDM 10% in Isopar E 4-5 um 70x70x35x10 good good (Vistalon 6505, 57% ethylene) Preparation 1 Synthesis of a Multifunctional Reactive Protective Colloid Rf-amine

Formula (I) 17.8 Gm of Krytox (É) methyl ester (DuPont, 17.8 g, MW = about-1780, g= about 10, DuPont) was dissolved in a solvent mixture containing 12 gm of 1,1, 2- trichlorotrifluoroethane (Aldrich) and 1.5 gm of a, a, a-trifluorotoluene (Aldrich). The resultant solution was added drop by drop into a solution containing 7.3 gm of tris (2- aminoethyl) amine (Aldrich) in 25 gm of oc, a, a-trifluorotoluene and 30 gm of 1,1, 2- trichlorotrifluoroethane over 2 hours with stirring at room temperature. The mixture was then stirred for another 8 hours to allow the reaction to complete. The IR spectrum of the crude product clearly indicated the disappearance of C=O vibration for methyl ester at 1780 cm~1 and the appearance of C=O vibration for the amide product at 1695 cm-1.

Solvents were removed by rotary evaporation followed by vacuum stripping at 100°C for 4-6 hours. The crude product was then dissolved in 50 ml of PFS2 solvent (low m. w. perfluoropolyether from Solvay Solexis) and extracted with 20 mi of ethyl acetate three times, then dried to yield 17 gm of purified product (Rf-amine1900) which showed excellent solubility in HT200. The product (Rf-amine1780) showed good solubility in HT200.

Other reactive multifunctional Rf-amines of Formula (I) having different molecular weights such as Rf-amine4900 (g = about 30), Rf-amine2000 (g = about 11), Rf- amine800 (g = about 4) and Rf-amine650 (g= about 3) were also synthesized according to the same procedure.

Preparation 2 Preparation of TiOz-containinq MicroParticles 9. 05 Gm of DesmodurQ) N3400 aliphatic polyisocyanate (from Bayer AG) and 0.49 gm of triethanolamine (99%, Dow) were dissolved in 3.79 gm of MEK. To the resultant solution, 13 gm of Ti02 R706 (DuPont) was added and homogenized for 2 minutes with a rotor-stator homogenizer (IKA ULTRA-TURRAX T25, IKA WORKS) at ambient temperature. A solution containing 1.67 gm of 1, 5-pentanediol (BASF), 1.35 gm of polypropylene oxide (m. w. = 725, from Aldrich), 2.47 gm of MEK and 0.32 gm of a 2% dibutyltin dilaurate (Aldrich) solution in MEK was added and further homogenized for 2 minutes. In the final step, 0.9 gm of Rf-amine 4900 prepared from Preparation 1 in 40.0 gm of HT-200 (Solvay Solexis) was added and homogenized for 2 minutes, followed by addition of additional 0.9 gm of Rf-amine 4900 in 33.0 gm of HT-200 and homogenization for 2 minutes. A low viscosity microcapsule dispersion was obtained.

The microcapsule dispersion obtained was heated at 80°C overnight and stirred under low shear to post-cure the particles. The resultant microcapsule dispersion was filtered through a 400-mesh (38 micrometer) screen. The particle and the solid content of the filtered dispersion was measured to be 29 wt% by weight with an IR-200 Moisture Analyzer (Denver Instrument Company). The average particle size of the filtered dispersion was measured with a Beckman Coulter LS230 Particle Analyzer to be about 2, um.

An EPD fluid containing 1.0 wt% by weight of CuPc-C8F17 (structure given below) and various amount of the resultant Ti02-containing microcapsule dispersion in HT-200 was filled into the microcups which were then sealed and sandwiched between two ITO/PET films according to the procedure described in Preparation 3.

Preparation 3A Primer Coated Transparent Conductor Film A primer coating solution containing 33.2 gm of EB 600TM (UCB, Smyrna, GA), 16.12 gm of SR 399TM (Sartomer, Exton, PA), 16.12 gm of TMPTA (UCB, Smyrna, GA), 20.61 gm of HDODA (UCB, Smyrna, GA), 2 gm of IrgacureT" 369 (Ciba, Tarrytown, NY), 0.1 gm of Irganoxrm 1035 (Ciba), 44.35 gm of poly (ethyl methacrylate) (MW. 515,000, Aldrich, Milwaukee, WI) and 399.15 gm of MEK (methyl ethyl ketone) was mixed thoroughly and coated onto a 5 mil transparent conductor film (ITO/PET film, 5 mil OC50 from CPFilms, Martinsville, VA) using a &num 4 drawdown bar. The coated ITO film was dried in an oven at 65°C for 10 minutes and exposed to 1.8 J/cm2 of UV light under nitrogen using a UV conveyer (DDU, Los Angles, CA).

Preparation 3B Preparation of Microcups Table 2: Microcup Composition Component Weight Part Source EB 600 33.15 UCB SR 399 32.24 Sartomer HDDA 20.61 UCB EB1360 6.00 UCB Hycar X43 8.00 BF Goodrich Irwqacure 369 0.20 Ciba ITX 0. 04 Aldrich Antioxidant Ir1035 0.10 Ciba

33.15 Gm of EB 600TM (UCB, Smyrna, GA), 32.24 gm of SR 399tu (Sartomer, Exton, PA), 6 gm of EB1360TM (UCB, Smyrna, GA), 8. gm of Hycar 1300x43 (reactive liquid polymer, Noveon Inc. Cleveland, OH), 0.2 gm of lrgacuretm 369 (Ciba, Tarrytown, NY), 0.04 gm of ITX (Isopropyl-9H-thioxanthen-9-one, Aldrich, Milwaukee, WI), 0.1 gm of IRganoxTM 1035 (Ciba, Tarrytown, NY) and 20.61 gm of HDDA (1, 6-hexanediol diacrylate, UCB, Smyrna, GA) were mixed thoroughly with a Stir-Pak mixer (Cole Parmer, Vernon, IL) at room temperature for about 1 hour and debubbled by a centrifuge at 2000 rpm for about 15 minutes.

The microcup composition was slowly coated onto a 4"x4"electroformed Ni male mold for an array of 100 gm (length) x 100 je. m (width) x 25, um (depth) x 15 µm (width of top surface of the partition wall between cups) microcups. A plastic blade was used to remove excess of fluid and gently squeeze it into"valleys"of the Ni mold. The coated Ni mold was heated in an oven at 65°C for 5 minutes and laminated with the primer coated ITO/PET film prepared in Preparation 3A, with the primer layer facing the Ni mold using a GBC Eagle 35 laminator (GBC, Northbrook, IL) preset at a roller temperature of 100°C, lamination speed of 1 ft/min and the roll gap at"heavy gauge". A UV curing station with a UV intensity of 2.5 mJ/cm2 was used to cure the panel for 5 seconds. The ITO/PET film was then peeled away from the Ni mold at a peeling angle of about 30 degree to give a 4"x4"microcup array on ITO/PET. An acceptable release of the microcup array from the mold was observed. The thus obtained microcup array was further post-cured with a UV conveyor curing system (DDU, Los Angles, CA) with a UV dosage of 1.7 J/cm2.

Preparation 3C Filling and Sealing with a Sealing Composition An electrophoretic fluid containing 9.7% by weight (dry weight) of the Ti02- containing microcapsules prepared according to the Preparation 2,1. 0% by weight of CuPc-C8F17 and 0. 5% by weight of Rf-amine2000 (based on the total dry weight of the TiO2-containing microcapsule) prepared according to Preparation 1 in HT-200 was filled into the 4"x4"microcup array prepared from Preparation 3B using a #0 drawdown bar.

The excess of fluid was scraped away by a rubber blade.

A sealing composition containing 14% by weight of polyurethane IROSTIC P9815-20 (from Huntsman Polyurethane) in MEK/IPAc/CHO (47. 5/47. 5/5) was overcoated onto the filled microcups using a Universal Blade Applicator and dried at room temperature to form a seamless sealing layer of about 2-311m dry thickness with good uniformity. The lamination of the electrode layer over the sealed microcups was accomplished by pressing the ITO side of an ITO/PET film (5 mil) onto the sealing layer by a laminator at 120°C and at the speed of 20cm/min.

Comparative Example 15: Single Layer Microcup EPD The resultant single layer microcup EPD prepared according to the Preparation 3C was then coated with a thin layer of black coating on the outer surface of the electrode on the sealing side of the display (the non-viewing side). The electrode film on the side opposite to the sealing layer is the viewing side from which all the electro- optic performances were measured. The test results including contrast ratio and Dmin at various normalized field strength are listed in Table 3.

Example 16: Staggered Two-laver Microcup EPD An electrophoretic fluid containing 6.0% by weight (dry weight) of the TiO2- containing microcapsules prepared according to Preparation 2,1. 0 wt% by weight of CuPc-CsFi7 and 0.5 % by weight (based on the total dry weight of the Ti02-containing microparticles) of Rf-amine2000 (from Preparation 1) in HT200 was filled and sealed into a microcup array prepared in Preparation 3C (the lower layer). The sealed microcup layer was laminated to a second sealed microcup layer (the upper layer) prepared in the Comparative Example 15 to form a staggered two-layer EPD film in which the inactive partition areas of the upper microcup layer were arranged in a staggered manner with registration to the active microcup areas of the lower layer. The

resultant two-layer EPD film was evaluated as in the Comparative Example 15. The contrast ratio and Dmin at various normalized field strength measured from the upper layer side are also summarized in Table 3.

Example 17: Staggered Two-layer Microcup EPD The same procedure of Example 16 was followed except that the upper microcup layer was filled with an electrophoretic fluid containing 9. 7% by weight (dry weight) of Ti02-containing microparticles from Preparation 2,1. 0% by weight of CuPc- C8F17 and 0.5% by weight (based upon the total dry weight of the Ti02-containing microparticles) of Rf-amine2000 in HT200; and the lower microcup layer was filled with 9. 7% by weight of the Ti02-containing microparticles, 1.5% by weight of CuPc-C8F17 and 0.5% by weight (based upon the total dry weight of the Ti02-containg microparticles) of Rf-amine 2000 in HT200. The contrast ratio and Dmin at various normalized field strength are summarized in Table 3. The contrast ratio and Dmin were shown to have been further improved by the increases in dye and particle concentrations in the lower layer.

Example 18: Staggered Two-layer Microcup EPD The same procedure of Example 16 was followed, except that the electrophoretic fluid of the upper microcup layer contained 9. 7% by weight of the TiO2- containing microparticles from Preparation 2,0. 7% by weight of CuPc-CsFi7 and 0.5% by weight (based upon the total dry weight of the TiO2-containg microparticles) of Rf-. amine2000 in HT200; and the lower microcup layer contained 9. 7% by weight of the Ti02-containing microparticles, 1.5% by weight of CuPc-C8F17 and 0.5% by weight (based upon the total dry weight of the TiO2-containg microparticles) of Rf-amine2000 in HT200. The contrast ratio and Dmin at various normalized field strength are summarized in Table 3.

Table 3: Contrast Ratios and Dmin of Examples 15-18 Upper Layer Lower Layer Normalized Field Strength wt% CuPc wt% TiO2 wt% CuPc-wt% TiO2 C8F, microparticle CBF17 microparticle 10 20 30 40 Contrast Comparative ratio 2.50 9. 00 9. 20 9. 50 Example 15 1.0 9.7 N.A. N. A. Dmin 0. 84 0. 76 0. 76 0. 75 Contrast ratio 3. 50 12.30 13.50 14. 00 Example 16 1.0 9.7 1.0 6.0 Dmin 0.76 0. 69 0.69 0. 68 Contrast ratio 2.50 14.50 17.00 19. 00 Exam le 17 1. 0 9. 7 1. 5 g, 7 Dmin 0. 78 0. 66 0. 66 0. 65 Contrast ratio 5. 00 8. 00 9. 50 9. 50 Example 18 2.0 9.7 1.5 9.7 Dmin 0. 75 0. 67 0. 65 0. 65

It is evident from Table 3 that under the same normalized field strength, all of the two-layer EPDs (Examples 16-18) showed significantly higher contrast ratio and lower Dmin (higher reflectivity in the Dmin state) than the single layer EPD (Comparative Example 15).

While the present invention has been described with reference to the specific embodiments thereof, it should be understood by those skilled in the art that various changes may be made and equivalents may be substituted without departing from the true spirit and scope of the invention. In addition, many modifications may be made to adapt a particular situation, materials, compositions, processes, process step or steps, to the objective, spirit and scope of the present invention. All such modifications are intended to be within the scope of the claims appended hereto. For example, it should be noted that the method of the invention for preparing microcups may also be used for preparing microcups for liquid crystal displays. Similarly, the microcup selective filling, sealing and ITO laminating methods of the invention may also be employed in the manufacture of liquid crystal displays. Moreover, both the one-pass and two-pass sealing and filling processes and compositions are also useful to fill and seal electrophoretic displays having the groove type, the grid type as shown in Figure 6a, 6b and 6c and other partition type of cell structures.

It is therefore wished that this invention to be defined by the scope of the appended claims as broadly as the prior art will permit, and in view of the specification if need be.