The present invention relates to an improved process for preparing purified N-acyl aminoalkane sulfonates. The present invention also relates to an improved process for preparing blends of N-acyl aminoalkane sulfonates and amphoteric and/or anionic surfactants.

BACKGROUND OF THE PRESENT INVENTION

Acyl taurinates and acyl isethionates, broadly classed as acyl aminoalkane sulfonates and acyloxyalkane sulfonates respectively, are known ingredients useful in synthetic detergent bars (syndet bars), shampoos, bubble baths, body washes, creams and lotions.

The reaction of acid chlorides of carboxylic acids with 2-amino- or 2- hydroxyalkanesulfonic acids and their alkali metal salts to yield anionic surfactants (for example, sodium N-acyltaurates and sodium acylisethionates, respectively) is well known as the Schotten-Baumann synthesis.

The Schotten-Baumann chemistry is very laborious and costly, requiring the handling of hazardous raw materials such as phosphorus trichloride and intermediates like acid chlorides as well as wastes like phosphorus acid. Large quantities of waste products are generated as a result of this chemistry. Also, the finished products contain significant amounts of sodium chloride as an undesirable by-product. The removal of the sodium chloride is possible, but expensive.

Sodium acyl aminoalkane sulfonate synthesis has been greatly improved by the direct amidation of sodium taurinate with fatty acids or by reacting a fatty amide with a sodium isethionate. This direct esterification route is cost-effective and these products are suitable for use in commercial toilet soap preparations.

/

The preparation of such sulfonates by direct amidation of an aminoalkane sulfonate with a fatty acid has presented difficulties because of the high temperature required to obtain suitable conversion. At temperatures required for direct acylation, usually in the range of 180° to 250°C, the molten reaction product rapidly degrades in color and loses activity. It has been found necessary to rapidly cool the reaction mass in order to obtain a final product.

PCT publication WO 95/18095 teaches preparing a taurinate by direct acylation, chilling the reaction mixture on a plate, redissolving the solid reaction mixture in lower alkanols or ketones under reflux followed by cooling to separate the insoluble product from the byproducts and solvent.

U.S. patent 2,697,872 teaches acylating a sodium N-methyl taurine with molten fatty acid anhydride in the absence of catalyst. The reaction generally is conducted at 100° to 200° F. (though higher temperatures are mentioned genetically). At some temperature acetone is added and the mixture cooled to 60° F to isolate a purified product. It is noted that the acetone is added to the reaction mixture so that one would presume that the reaction mixture is not being quenched from an elevated temperature.

U.S. patent 3,429,136 teaches that in preparing acyl isethionates by direct esterification, the molten reaction mass can be cooled by injecting cold water directly into the molten crude reaction mixture to cool the mass by evaporative cooling below a temperature at which rapid discoloration would occur and this can be done without causing appreciable hydrolysis of the ester.

Since this crude reaction product ordinarily contains unreacted fatty acid, sulfonate or both, various methods have been proposed for purification. Generally these methods comprise forming liquid systems in which the impurities are soluble and the product is insoluble. Following cooling, the soluble impurities separated with the liquid by filtration means.

U.S. Patent 4,515,721 teaches that excess fatty acid can be removed from an isethionate reaction mixture by quenching the hot crude fatty acid ester by immersion in a liquid in which the desired ester product is insoluble and the unreacted fatty acid soluble. The phases are separated to affect purification. In this patent the isethionate can be

quenched in vaπous products includmg lower cham length alcohols, fatty alcohols, fatty alcohol ethoxylates, polyethylene glycols, polyoxyalkylene deπvatives of polyethylene glycol, fatty triglyceπdes, fatty esters and fatty amides. The preferable quenching liquid is isopropanol. U.S. Patent 4,612,132 descπbes a process for prepaπng an aqueous surfactant solution and gel of an acyloxyalkane sulfonate salt by combining the sulfonate salt with a water soluble polyol and water This mixture is heated above the boiling point of water under super atmosphenc pressure to form a reversible solid colloidal solution from which the product can then be recovered. See also, U. S. Patent 4,696,767. U.S. Patent 5,415,810 discloses that blends of SCI and betaine (zwitteπoncs) can be made in an aqueous system where the zwitteπonic surfactant assists m the dissolution ofthe isethionate.

It is known to prepare blends of surfactants to accomplish vaπous desired end results Blends of isethionates and betaines, optionally with soap, are known for producing syndet bars (U.S Patent 5 ,372,751).

Presently, blends of taunnates and betaines are made by dissolving or slurrying the tauπnate in a heated (40° C.) aqueous betaine solution This procedure requires the preparation of solid tauπnate and the reheating ofthe betaine solution.

It is an object of the invention to prepare a high active content, substantially salt free acyl tauπnate by a process which eliminates the steps of solidification and reslurrying The present process is thereby more economical because the quenching operation is faster than the flaking operation insuring lower decomposition of product dunng manufacture.

It is also an object ofthe invention to prepare blends of taunnates with amphoteπc and/or amomc surfactants, optionally with other mgredients and surfactants in a process which eliminates the need for solidifying and reslurrying the taurinate, reduces product decomposition, thereby making the product in a more economical manner

SUMMARY OF THE INVENTION

In accordance with the invention, acyl taunnates can be effectively purified by directly reacting taurinate salts with a fatty acid or fatty acid ester or a hydroxyalkane sulfonate with a fatty acid amide at elevated temperature sufficient to effectively amidate without excessive product decomposition (from about 180° to about 250 °C) followed by quenching the molten reaction mixture in a lower molecule weight alcohol or ketone. The product separates as a solid and is removed by centrifugation or filtration or other appropriate solid separation techniques. The product can be used as is or further washed.

Another embodiment of the invention includes quenching the molten acyl taurinate prepared as above in an aqueous solution of amphoteric and/or anionic surfactant optionally including other ingredients and/or surfactants. This allows for the convenient preparation of taurinate/amphoteric and/or anionic surfactant blends while avoiding the solidification, classification, and reslurrying techniques required presently. The product can be a viscous liquid or paste depending on solids concentration.

DETAILED DESCRIPTION OF THE INVENTION

The embodiments of the invention proceed from a molten reaction mixture of an N-acyl aminoalkane sulfonate preferably prepared by reacting an aminoalkane sulfonate with a fatty acid or fatty acid ester. Alternatively, the N-acyl aminoalkane sulfonate can be prepared by reacting a hydoxyalkane sulfonate with a fatty acid amide. The N-acyl aminoalkane sulfonates can be represented by the formula

R,-C(0)-N-(CH ₂ ) _n -SO ₃ Y Formula I

I

R ₂ wherein R _] is a hydrocarbyl radical, desirably from about 6 to about 26 carbon atoms, R ₂ represents hydrogen, methyl or cyclohexyl, n is integer of from 2 to 4, preferably 2 and Y is an alkali metal or alkaline earth metal, more particularly, sodium, potassium, lithium or magnesium and preferably sodium. The alkane portion of the sulfonate detergents of Formula 1 for use herein includes ethylene and branched or unbranched propylene or butylene. The fatty acyl moiety is a hydrocarbyl radical containing from about 6 to about 26 and preferably from about 6 to about 20 carbon atoms such as hexanoic, octanoic,

decanoic, dodecanoic, lauric. behenic, palmitic, stearic. myristic, arachidic, oleic, linolenic, linoleic. and the like including mixtures of the foregoing as in the particularly preferred cocoyl derivatives from coconut oil fatty acids. Fatty acids from natural sources are comprised of numerous fatty acids whose chain lengths generally all fall within the stated carbon range. A small proportion of mono - or di - unsaturated fatty acid derivatives may be desirable to provide adequate foaming and solubility in blends containing the neat soap. Normally, the degree of unsaturation will not be less than about 2 or more than 12 , when measured by iodine number. It will be observed in this context that the term "hydrocarbyl" is intended to embrace linear and branched aliphatic radicals that include alkyl, alkenyl alkynyl, and alkadienyl moieties. Too large a proportion of unsaturation, tends to render the sulfonate susceptible to oxidative degradation. The preferred compounds are N-methyl taurinates wherein R ₂ represents methyl and n is an integer of 2. Preferably. R, represents cocoyl or oleyl, and M is an alkali or alkaline earth metal, preferably sodium. Compounds of Formula I can be prepared by the direct amidation of an aminoalkane sulfonic acid of Formula II.

R ₂ N-(CH ₂ ) _n -SO ₃ H Formula II.

I

H with a fatty acid of Formula III

R,-C(0)-OH Formula III wherein R ₂ , n and R| are as previously defined.

The componds of Formula I can also be prepared by amidating a hydroxyalkane

sulfonate ofthe formula:

HO(CH ₂ ) _n -SO ₃ H Formula IV

with a fatty acid amide of Formula V R,-C(O)-NH ₂ Formula V

The amidation is generally conducted at an elevated temperature sufficient to effect reaction but insufficient to cause product degradation, generally above 180°C. to about 250° C. (temperatures of about 195°C. - about 200° C. being prefened if the reaction mixture can be kept molten) in the presence of catalytic amounts of boric acid and/or zinc or magnesium oxide. Temperatures above the decomposition point can be handled by incoφorating scrubber to puπfy the area. The addition of viscosity modifiers such as paraffin wax can lower the viscosity so that more complete condensation can be achieved The reaction is conducted for a penod of time sufficient to achieve conversion but insufficient to allow substantial product degradation, for example from about 1 to about 10 hours.

Conversion to acyltauπnate is monitored by decreasing acid number and increasing anionic activity based on two-phase methylene blue titration The analytical techniques used for monitoring the progress of the reaction include titπmetπc and gas chromatographic analyses well known by those skilled in the art to trace the decrease in fatty acid content of the mixture and the increase in the taurate content as the reaction progresses toward completion (For examples of such analytical techniques see Detergent Analysis - A Handbook for Cost-Effective Quality Control, by E. M. Milwidsky and D. M. Gabπel (George Goodwin, London, 1982) incoφorated by reference herein m its entirety, especially at pages 1 19-120. 133-134, and 255

Products from said reactions can be used to manufacture a number of personal cleansing formulations (e.g., bar soap, shampoos, body washes, etc.)

In accordance with the invention, the molten reaction product is quenched m an aqueous solution of amphoteπc and/or amomc surfactant at a rate sufficient to cool the reaction mass below degradation temperature

Amphoteπc/ Zwffleπonic Surfactants. Amphotenc surfactants useful in the invention can broadly be described as a surface active agent contaimng at least one amomc and one catiomc group and can act as either acids or bases depending on pH Some of these compounds are aliphatic

derivatives of heterocyclic secondary and tertiary amines in which the aliphatic radical may be straight or branched and wherein one of the aliphatic substituents contains from about 6 to about 20, preferably 8 to 18, carbon atoms and at least one contains an anionic water-solubilizing group, e.g., carboxy, phosphonate, phosphate, sulfonate, sulfate. Zwitterionic surfactants can be broadly described as surface active agents having a positive and negative charge in the same molecule which molecule is zwitterionic at all pHs. Zwitterionic surfactants can be best illustrated by betaines and sultaines. The zwitterionic compounds generally contain a quaternary ammonium, quaternary phosphonium or a tertiary sulfonium moiety. The cationic atom in the quaternary compound can be part of a heterocyclic ring. In all of these compounds there is at least one aliphatic group, straight chain or branched, containing from about 6 to 20, preferably 8 to 18, carbon atoms and at least one aliphatic substituent containing an anionic water- solubilizing group, e.g., carboxy, sulfonate. sulfate, phosphate or phosphonate.

Examples of suitable amphoteric and zwitterionic surfactants include the alkali metal, alkaline earth metal, ammonium or substituted ammomum salts of alkyl amphocarboxyglycinates and alkyl amphocarboxypropionates, alkyl amphodipropionates, alkyl monoacetate, alkyl diacetates. alkyl amphoglycinates, and alkyl amphopropionates wherein alkyl represents an alkyl group having from 6 to about 20 carbon atoms. Other suitable surfactants include aJkyliminomonoacetates, alkyliminidiacetates, alkyliminopropionates, alkyliminidipropionates, and alkylamphopropylsulfonates having between 12 and 18 carbon atoms, alkyl betaines and alkylamidoalkylene betaines and alkyl sultaines and alkylamidoalkylenehydroxy sulfonates.

Particularly useful amphoteric surfactants include both mono and dicarboxylates such as those ofthe formulae:

O CH ₂ CH ₂ OH

R— C— NHCH ₂ CH ₃ N ' (I); and

(CH ₂ ) _x COOM

O CH-,CH ₂ OH (CH ₂ ) _x COOM ιι I /

R— C— NCH ₂ CH ₂ N (II);

^ (CH ₂ ) _x COOM

( CH ₂ ) _x COOM

R — N and (III); ^(CH ₂ ) _x COOM

wherein R is an alkyl group of 6-20 carbon atoms, x is 1 or 2 and M is hydrogen or sodium. Mixtures ofthe above structures are particularly preferred. Other amphoteric surfactants can be illustrated by the following formulae:

Alkyl betaines

CH ₃ |

R— ^* N— CH, COO ^" (IV)

I

CH ₃ Amidopropyl betaines

CH

Alkyl sultaines CH ₃

R-^4 ⁺ — CH ₂ — CH— CH ₂ SO ₃ ^" (VI); and

CH ₃ OH

Alkyl amidopropylhydroxy sultaines

O CH ₃

I! I

R— -C— NH— CH ₂ CH ₂ CH _: — ⁺ N— CH ₂ — CH— CH ₂ SO ₃ ^' (VII); CH ₃ OH wherein R is an alkyl group of 6-20 carbon atoms.

Of the above amphoteric surfactants, particularly preferred are compounds wherein the alkyl group is derived from natural sources such as coconut oil or is a lauryl group. In reciting a carbon chain length range, it is intended to include groups such as coco which are naturally derived materials which have various specific chain lengths or an average chain length within the range.

Commercially useful and preferred amphoteric surfactants include (as sodium salts): cocoamphoacetate (sold under the trademarks MIRANOL ^® CM CONC. and MIRAPON ^® FA. and MIRANOL* ULTRA C-32 (prefened). cocoamphodiacetate (sold under the trademarks MIRANOL ^® C2M CONC. and

MIRAPON ^® FB), cocoamphopropionate (sold under the trademarks MIRANOL ^® CM-SF CONC. and

MIRAPON ^® FAS), cocoamphodipropionate (sold under the trademarks MIRANOL ^® C2M-SF and

MIRANOL ^® FBS). lauroamphoacetate (sold under the trademarks MIRANOL ^® HM CONC. and MIRAPON ^®

LA), lauroamphodiacetate (sold under the trademarks MIRANOL ^® H2M CONC. and MIRAPON ^® LB), lauroamphodipropionate (sold under the trademarks MIRANOL ^® H2M-SF CONC. AND

MIRAPON ^® LBS), lauroamphodiacetate obtained from a mixture of lauric and myristic acids (sold under the trademark MIRANOL* BM CONC), and cocoamphopropyl sulfonate (sold under the trademark MIRANOL ^® CS CONC). Somewhat less preferred are:

caproamphodiacetate (sold under the trademark MIRANOL ^® S2M CONC), caproamphoacetate (sold under the trademark MIRANOL ^® SM CONC), caproamphodipropionate (sold under the trademark MIRANOL ^® S2M-SF CONC), and stearoamphoacetate (sold under the trademark MIRANOL ^® DM).

As used herein the term " ampho ^" is intended to refer to a structure derived from imidazoiine chemistry. Various structures have been assigned to these products and the following are representative (x is as defined hereinbefore):

O

— CNHCH _: CH ₂ N (

O

The quench liquid can also contain as the sole surfactant an anionic surfactant or the anionic surfactant can be coblended with an amphoteric surfactant during the quenching or after quenching.

Anionic Surfactants Anionic surfactant detergents which may be included in the quench liquid used in the invention are those surfactant compounds which contain a long chain hydrocarbon hydrophobic group in their molecular structure and a hydrophilic group, including salts such as carboxylate, sulfonate. sulfate or phosphate groups. The salts may be sodium, potassium, calcium, magnesium, barium, iron, ammonium and amine salts of such surfactants.

Anionic surfactant detergents which may be included in the quench liquid used in the invention are those surfactant compounds which contain a long chain hydrocarbon

hydrophobic group in their molecular structure and a hydrophilic group, including salts such as carboxylate, sulfonate. sulfate or phosphate groups. The salts may be sodium, potassium, calcium, magnesium, barium, iron, ammonium and amine salts of such surfactants. Anionic surfactants include the alkali metal, ammonium and alkanol ammonium salts of organic sulfuric reaction products having in their molecular structure an alkyl, or alkaryl group containing from 8 to 22 carbon atoms and a sulfonic or sulfuric acid ester group. Examples of such anionic surfactants include water soluble salts of alkyl benzene sulfonates having between 8 and 22 carbon atoms in the alkyl group, alkyl ether sulfates having between 8 and 22 carbon atoms in the alkyl group and 2 to 9 moles ethylene oxide in the ether group. Other anionic surfactants that can be mentioned include alkyl sulfosuccinates, alkyl ether sulfosuccinates, olefin sulfonates, alkyl sarcosinates. alkyl monoglyceride sulfates and ether sulfates, alkyl ether carboxylates, paraffinic sulfonates, mono and di alkyl phosphate esters and ethoxylated deritives, acyl isethionates, fatty acid soaps, collagen hydrosvlate derivatives, sulfoacetates. acyl lactates, aryloxide disulfonates, sulfosucinamides. naphthalene-formaldehyde condensates and the like. Aryl groups generally include one and two rings, alkyl generally includes from 8 to 22 carbon atoms and the ether groups generally range from 1 to 9 moles of EO and/or PO, preferably EO. Specific anionic surfactants which may be selected include linear alkyl benzene sulfonates such as decylbenzene sulfonate, undecyl benzene sulfonate. dodecyl benzene sulfonate. tridecylbenzene sulfonate. nonylbenzene sulfate and the sodium, potassium, ammonium, triethanol ammonium and isopropyl ammonium salts thereof. Particularly prefened sulfonate salt is sodium dodecylbenzene sulfonate. Such chemicals have been sold under the trade name Biosoft BlOO by Stepan Chemicals of Northfield, Illinois. Other anionic surfactants include polyethoxylated alcohol sulfates, such as those sold under the trade name Neodol 25-3S by Shell Chemical Company. Examples of other anionic surfactants are provided in U.S. Pat. Nos. 3.976,586 and 5,415,810. To the extent necessary, these patents are expressly incoφorated herein by reference.

In addition to the amphoteric and/or anionic surfactants, the quench liquid used in the process of the invention can optionally comprise one or more of a nonionic or cationic surfactants as well as other optional ingredients.

Nonionic Surfactants

The quench liquid of the invention can optionally also include one or more nonionic surfactants. The nonionic surfactant(s) is not critical and may be any of the known nonionic surfactants which are generally selected on the basis of compatibility, effectiveness and economy. Examples of useful nonionic surfactants include condensates of ethylene oxide with a hydrophobic moiety which has an average hydrophilic lipolytic balance (HLB) between about 8 to about 16. and preferably between about 10 and about 12.5. The surfactants include the ethoxylated primary or secondary aliphatic alcohols having from about 8 to about 24 carbon atoms, in either straight or branch chain configuration, with from about 2 to about 40. and preferably between about 2 and about 9 moles of ethylene oxide per mole of alcohol.

Other suitable nonionic surfactants include the condensation products of from about 6 to about 12 carbon atoms alkyl phenols with about 3 to about 30. and preferably between about 5 to about 14 moles of ethylene oxide. Examples of such surfactants are sold under the trade names Igepal CO 530, Igepal CO 630, Igepal CO 720 and Igepal CO 730 by Rhόne-Poulenc Inc. Still other suitable nonionic surfactants are described in U.S. Pat. No. 3,976,586 which, to the extent necessary, is expressly incoφorated herein by reference.

Cationic Surfactants

Many cationic surfactants are known in the art and almost any cationic surfactant having at least one long chain alkyl group of about 10 to 24 carbon atoms is suitable for optional use in the present invention. Such compounds are described in "Cationic Surfactants", Jungermann. 1970, incoφorated herein by reference.

Specific cationic surfactants which can be used as surfactants in the invention are described in U.S. Pat. No. 4.497.718. incoφorated herein by reference.

As with the nonionic and anionic surfactants, the compositions the invention may use cationic surfactants alone but preferably in combination with other surfactants as is known in the art. The composition of the invention can contain any useful amount but preferably up to about 20% by weight of surfactant actives based on the total surfactant actives weight in the quench liquid. Of course, the composition may contain no cationic surfactants at all.

pH Adjusting Chemicals pH adjusting chemicals such as acids, bases and buffers can be added to the quench liquid. Prefened pH adjusting chemicals include lower alkanolamines such as monoethanolamine (MEA) and triethanolamine (TEA). Sodium hydroxide solutions may be utilized as an alkaline pH adjusting agent. These solutions further function to neutralize acidic materials that may be present. Mixtures of more than one pH adjusting chemical can also be utilized.

Optional Ingredients In addition to essential ingredients described hereinbefore, the quenching liquid of the present invention can also contain a series of optional ingredients which are used for known functionality at conventional levels.

The quenching liquid of the invention can contain phase regulants (well known liquid detergent technology). These can be represented by lower aliphatic alcohols having from 2 to 6 carbon atoms and from 1 to 3 hydroxyl groups, ethers of diethylene glycol and lower aliphatic monoalcohols having from 1 to 4 carbon atoms and the like.

Detergent hydrotropes could also be included. Examples of these hydrotropes include salts of alkylarylsulfonates having up to 3 carbon atoms in the alkyl group e.g., sodium, potassium, ammonium, and ethanolamine salts of xylene. toluene, ethylbenzene, cumene. and isopropyl benzene sulfonic acids.

Other supplemental additives include defoamers such as high molecular weight aliphatic acids, especially saturated fatty acids and soaps derived from them, dyes and perfumes; fluorescent agents or optical brighteners; anti-redeposition agents such as carboxymethyl cellulose and hydroxypropylmethyl cellulose; suspension stabilizing agents and soil release promoters such as copolymers of polyethylene terephthalate and polyoxyethylene terephthalate; antioxidants; softening agents and anti-static agents; photo activators and preservatives: polyacids, suds regulators, opacifiers, bacteriacide, and the like. Suds regulants can illustrated by alkylated polysiloxanes and opacifiers can be illustrated by polystyrene: bactericide can be illustrated by butylated hydroxytoluene. Although not required, an inorganic or organic builder may optionally be added in small amounts to the final composition. Examples of inorganic builders include water- soluble alkali metal carbonates, bicarbonates, silicates and crystalline and amoφhous alumino silicates. Examples of organic builders include the alkali metal, alkaline metal, ammonium and substituted ammonium polyacetates. carboxylates, polycarboxylates, polyacetyl, carboxylates and polyhydroxy sulfonates. One example of a commonly used builder is sodium citrate.

The optional ingredients. pH adjusting chemicals and optional surfactants can be added to the quenching liquid before, during or after quenching as desired or as practical. Blends can be made directly for sale or for compounding to meet the needs of the user. The molten reaction mixture is added to the quench liquid at a rate sufficient to effectively cool the reaction mixture beneath the degradation temperature without over heating the quench liquid. Rate of addition, quantity, heat transfer capabilities as well as the total solids desired in the final product will control and these can be readily determined by one of ordinary skill in the art. Quenching is conducted using good chemical manufacturing techniques. The molten reaction product is preferably transfened directly to a quench vessel containing the quench liquid but can be conducted through heated piping to maintain the reaction product in molten condition. The quench vessel is preferably equipped with an agitator and a cooling jacket. While a pressurized vessel could be use, this would require a pump to overcome the difference in pressure between the reaction vessel and the quench vessel

while maintaining molten flow. The quench vessel is preferably equipped with a condensation means for condensing the water evaporated from the quench liquid during quenching. The condensate is preferably reintroduced into the quench liquid.

The molten material being quenched generally can contain from about 80% to about 95%, generally around 90%. actives, the remainder of the solids being impurities and reactants. The amount of actives depends on the efficiency of fatty acid removal from the reaction mixture. The molten material is added to sufficient quenching liquid to reduce the temperature of the reaction mixture below the decomposition temperature of the reaction product. Larger amounts of quench liquid can be desirable to absorb more heat. The amount of reaction product quenched is not a function of the degree of solubility of the reaction product in the quenching liquid The amount of reaction product quenched could be above or beiow the solubility limit of the reaction product in the quenching liquid.

It is prefened that the total solids in the quenching liquid after quenching (not including solids added after quenching is complete) not exceed about 60%, preferably about 50% and more preferably about 45% Included in the solids are the reaction product, the amphoteric or anionic surfactant, the optional surfactants, and the remaining optional ingredients including the pH adjusting chemicals The ratio of reaction product to amphoteric and/or anionic surfactant can be expressed as ranging from about 85% - '5% reaction product to about 15% to about 85% amphoteric and/or amomc surfactant based on solids. It is preferable to use from about 40% to about 60% and from about 60% to about 40% and more preferably about 50% to about 50% reaction product to amphoteπc and/or anionic surfactant.

When using a blend of amphoteric and anionic surfactants in the quench liquid, one can use from a negible amount of amphoteπc surfactant to slightly less than 100% with the complementary ranges for the anionic surfactant. It is preferable to use from about 30% to about 70% amphoteric surfactant to about 70% to about 30% anionic surfactant on a solids basis and more preferably from about 45% to about 55% amphoteric surfactant to about 55% to about 45% anionic surfactant on a solids basis.

The nonionic surfactant based on total solids in the quenching liquid should not exceed about 20%. the cationic surfactant not more than about 10% of the solids and the optional ingredients not more than 10% of the total solids

After quenching, the quenched mateπal can be cooled and used as is or further purified such as by redissolvmg in a lower aliphatic alcohol, e.g , isopropanol The product can be a pumpable liquid or a paste depending on the concentration of the ingredients Higher levels oi acyloxyalkane sulfonate lead to gels so that it may be desirable to use lower leveis to prepare pumpable products

The blends of the invention can be used directly in various personal care and household cleaning products or blended with further ingredients as desired By this invention, blends of ingredients can be made using the product of the invention as a base

The present invention be more fully illustrated in the following non-limiting examples

EXAMPLE 1

Reaction apparatus

The reaction kettle was an oil ιacketed 4 necked 2 liter resin pot having a dπp tip drain The kettle was equipped with a mechanical stiner thermometer, nitrogen sparge and Dean Starke trap leading to a reflux condenser The kettle dram was connected to a 5 liter, three necked round bottom flask equipped with stiner and reflux condenser Procedure

The kettle was charged with 631 1 g (2 5 M) oleic acid

295 2 g ( 1 5 M) of 81 9% active sodium N-methyl taurinate 15 78 g sodium hypophosphite and a mixture of 10 71 g phosphorous acid and 20 27 g of 50% sodium hvdroxide

The reaction was heated to 230 ^C C and maintained 5 hours with stimng and nitrogen sparge. A total of 41 2 grams water was removed via the Dean Starke tube. The hot reaction mixture was slowlv drained at 230°C into the 5 liter round bottom flask containing 3 liters of isopropanol The isopropanol was constantly agitated The white slurry obtained was centrifuged at 1000-2000 φm for 15 mm. and the supernatant decanted The white solid was washed with 1 liter isopropanol and recentrifuged The solid was dried at 85°C in a \acuum oven yielding 692.2 g of 80 1% active product

EXAMPLE 2 Preparation of sodium N-coco\ l N-methyl taurinate

To the reaction kettle as described in Example 1 was charged 461 2 2 (2 25 M) coconut fatty acid 15 8 g sodium orthophosphite and 15 8 g sodium hypophosphite The reaction kettle was heated to 200-210°C and 380 0 grams (66 7% active) N- methyl taurine (1 56 M) was added over a 2 hour peπod Water was removed dunng the addition The dropping funnel was maintained at 40°C to keep the N-methyl taunne flowable. After addition was complete, the reaction mixture was heated to 225°C and held for 5 hours The reaction mixture was drained into 3 liters of isopropanol The white slurry is then filtered and washed with isopropanol to vield 582 grams of 84% active product

EXAMPLE 3 Blends of N-coco\ l N-methyl taurinate with amphoteric surfactant can be prepared by adding the following to a 4 neck 2 liter reaction vessel as previously described:

380 g coconut fatty acid (C 108). 13 0 g sodium nypopnosphite and 1 1 7 g sodium orthophosphite The reaction mixture was heated to 190-200°C and an aqueous solution of 557 grams (37% active. 1 27 M) N-methyl taurine was added slowly over a 5 hour peπod

Water was removed continually. The reaction was held 3 hours at 230°C until water evolution ceased. Excess fatty acid was removed by vacuum distillation. Activity by methylene blue titration was 85%. The molten reaction mixture was discharged via the bottom outlet into the 5 liter flask containing 1265 grams water and 1810 grams sodium cocoamphoacetate (Miranol ^® Ultra C-32). A comparison of the above blend and a similar blend at a different concentration prepared in like manner is shown below

TABLE I

INGREDIENT EXAMPLE

3 4

Wgt. % Wgt. %

Sodium Cocoyl N-methyl Tauπnate 15 30

[Geropon TC 270 (82% ActiveX 100% Solids)]

Water 35 20

Sodium Cocoamphoacetate 50 50

[Ultra C-32 (30% Active)(38% Solids)]

Observation Viscous Liq. Paste