Title:
NANOSCALE GOLD CATALYSTS, ACTIVATING AGENTS, SUPPORT MEDIA, AND RELATED METHODOLOGIES USEFUL FOR MAKING SUCH CATALYST SYSTEMS ESPECIALLY WHEN THE GOLD IS DEPOSITED ONTO THE SUPPORT MEDIA USING PHYSICAL VAPOR DEPOSITION
Document Type and Number:
WIPO Patent Application WO2005030382
Kind Code:
A3
Abstract:
Use of physical vapor deposition methodologies to deposit nanoscale gold on activating support media makes the use of catalytically active gold dramatically easier and opens the door to significant improvements associated with developing, making, and using gold-based, catalytic systems. The present invention, therefore, relates to novel features, ingredients, and formulations of gold-based, heterogeneous catalyst systems generally comprising nanoscale gold deposited onto a nanoporous support.
Inventors:
BREY LARRY A
WOOD THOMAS E
BUCCELLATO GINA M
JONES MARVIN E
CHAMBERLAIN CRAIG S
SIEDLE ALLEN R
WOOD THOMAS E
BUCCELLATO GINA M
JONES MARVIN E
CHAMBERLAIN CRAIG S
SIEDLE ALLEN R
Application Number:
PCT/US2004/031265
Publication Date:
November 17, 2005
Filing Date:
September 23, 2004
Export Citation:
Assignee:
3M INNOVATIVE PROPERTIES CO (US)
International Classes:
B01D53/86; B01D53/94; B01J21/04; B01J21/06; B01J21/18; B01J23/02; B01J23/04; B01J23/06; B01J23/52; B01J23/66; C01B32/50; B01J35/00; B01J35/02; B01J35/10; B01J37/02; B01J37/34; C01B32/40; C01B32/60; C01B32/942; (IPC1-7): B01J23/52; B01J23/66; B01J35/10; B01J35/02; B01J37/34; B01J37/02; B01J21/18; B01J21/04; B01J21/06; B01D53/86
Domestic Patent References:
| WO1997043042A1 | 1997-11-20 | |||
| WO1998000413A1 | 1998-01-08 | |||
| WO2000059632A1 | 2000-10-12 | |||
| WO2004112958A1 | 2004-12-29 |
Foreign References:
| US20030004054A1 | 2003-01-02 | |||
| DE10030637A1 | 2002-01-10 | |||
| US20030073573A1 | 2003-04-17 | |||
| EP1040869A2 | 2000-10-04 | |||
| US20030134741A1 | 2003-07-17 | |||
| EP0827779A1 | 1998-03-11 | |||
| US4469640A | 1984-09-04 | |||
| GB1486108A | 1977-09-21 | |||
| US5559065A | 1996-09-24 | |||
| US20030013904A1 | 2003-01-16 | |||
| US4046712A | 1977-09-06 |
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BOND G C ET AL: "CATALYSIS BY GOLD", CATALYSIS REVIEWS SCIENCE AND ENGINEERING, vol. 41, no. 3/4, 1999, pages 319 - 388, XP008017051
HARUTA M ET AL: "Thin Films of Supported Gold Catalysts for CO Detection", SENSORS AND ACTUATORS B, vol. 1, 1990, pages 222 - 225, XP002322907
VALDEN M ET AL: "Onset of Catalytic Activity of Gold Clusters on Titania with the Appearance of Nonmetallic Properties", SCIENCE, vol. 281, no. 5383, 11 September 1998 (1998-09-11), pages 1647 - 1650, XP002322908
GUCZI L ET AL: ""Modeling Gold Nanoparticles: Morphology, Electron Structure and Catalytic Activity in CO Oxidation", JOURNAL OF PHYSICAL CHEMISTRY B, vol. 104, no. 14, 16 February 2000 (2000-02-16), pages 3183 - 3193, XP002322909
SIGMA-ALDRICH CO.: "Nanomaterials", INTERNET ARTICLE, XP002322910, Retrieved from the Internet [retrieved on 20050322]
DEMYDOV D ET AL: "Characterization of mixed metal oxides (SrTiO3 and BaTiO3) synthesized by a modified aerogel procedure", JOURNAL OF NON-CRYSTALLINE SOLIDS, NORTH-HOLLAND PHYSICS PUBLISHING. AMSTERDAM, NL, vol. 350, 15 December 2004 (2004-12-15), pages 165 - 172, XP004665346, ISSN: 0022-3093
KALCK PHILIPPE ET AL: "Chemical Vapor Deposition Methods for the Controlled Preparation of Supported Catalytic Materials", CHEMICAL REVIEWS, vol. 102, no. 9, 3 August 2002 (2002-08-03), pages 3085 - 3128, XP002322911
HARUTA M ET AL: "Chemical vapor deposition of gold on Al2O3, SiO2, and TiO2 for the oxidation of CO and of H2", CATALYSIS LETTERS, vol. 51, no. 1-2, January 1998 (1998-01-01), pages 53 - 58, XP002322912
OKUMURA M ET AL: "The reactivities of dimethylgold(III)beta-diketone on the surface of TiO2", SOLID STATE IONICS, NORTH HOLLAND PUB. COMPANY. AMSTERDAM, NL, vol. 95, no. 1, 2 February 1997 (1997-02-02), pages 143 - 149, XP004058876, ISSN: 0167-2738
OKUMURA M ET AL: "Chemical Vapor Deposition of Gold Nanoparticles on MCM-41 and Their Catalytic Activities for the Low-temperature Oxidation of CO and H2", CHEMISTRY LETTERS, vol. 27, no. 4, 1998, pages 315 - 316, XP002322913
KOZLOVA A P ET AL: "Iron-Oxide Supported Gold Catalysts Derived from Gold-Phosphine Complex Au(PPh3)(NO3): State and Structure of the Support", JOURNAL OF CATALYSIS, ACADEMIC PRESS, DULUTH, MN, US, vol. 176, no. 2, 10 June 1998 (1998-06-10), pages 426 - 438, XP004447354, ISSN: 0021-9517
CARNES C L ET AL: "SYNTHESIS, CHARACTERIZATION, AND ADSORPTION STUDIES OF NANOCRYSTALLINE ALUMINUM OXIDE AND A BIMETALLIC NANOCRYSTALLINE ALUMINUM OXIDE/MAGNESIUM OXIDE", CHEMISTRY OF MATERIALS, AMERICAN CHEMICAL SOCIETY, WASHINGTON, US, vol. 14, no. 7, July 2002 (2002-07-01), pages 2922 - 2929, XP001190712, ISSN: 0897-4756
POTTERS INDUSTRIES INC.: "SPHERIGLASS(R) Solid Glass Spheres", INTERNET ARTICLE, XP002322914, Retrieved from the Internet [retrieved on 20050329]
PRATI L ET AL: "Gold on Carbon as a New Catalyst for Selective Liquid Phase Oxidation of Diols", JOURNAL OF CATALYSIS, ACADEMIC PRESS, DULUTH, MN, US, vol. 176, no. 2, 10 June 1998 (1998-06-10), pages 552 - 560, XP004447366, ISSN: 0021-9517
BALERNA A ET AL: "A Structural Investigation on Small Gold Clusters by EXAFS", SURFACE SCIENCE, vol. 156, 1985, pages 206 - 213, XP002322929
SOLLIARD C ET AL: "Surface Stress and Size Effects on the Lattice Parameter in Small Particles of Gold and Platinum", SURFACE SCIENCE, vol. 156, 1985, pages 487 - 494, XP002322930
ENSINGER W ET AL: "Surface treatment of aluminum oxide and tungsten carbide powders by ion beam sputter deposition", SURFACE AND COATINGS TECHNOLOGY, vol. 163-164, 3 October 2002 (2002-10-03), pages 281 - 285, XP002338435
ENSINGER W ET AL: "Noble metal deposition on aluminum oxide powder surfaces by ion beam sputtering", NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH, SECTION - B: BEAM INTERACTIONS WITH MATERIALS AND ATOMS, NORTH-HOLLAND PUBLISHING COMPANY. AMSTERDAM, NL, vol. 141, no. 1-4, May 1998 (1998-05-01), pages 693 - 698, XP004440775, ISSN: 0168-583X
ENSINGER W ET AL: "THE ROTATING WING DRUM: AN APPARATUS FOR ION BEAM TREATMENT OF POWDERS", REVIEW OF SCIENTIFIC INSTRUMENTS, AMERICAN INSTITUTE OF PHYSICS. NEW YORK, US, vol. 65, no. 9, 1 September 1994 (1994-09-01), pages 2963 - 2967, XP000469237, ISSN: 0034-6748
CHEN Y-J ET AL: "Deposition of Highly Dispersed Gold on Alumina Support", JOURNAL OF CATALYSIS, ACADEMIC PRESS, DULUTH, MN, US, vol. 200, no. 1, 15 May 2001 (2001-05-15), pages 59 - 68, XP004432551, ISSN: 0021-9517
ARRII S ET AL: "Oxidation of CO on Gold Supported Catalysts Prepared by Laser Vaporization: Direct Evidence of Support Contribution", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 126, no. 4, 10 January 2004 (2004-01-10), pages 1199 - 1205, XP002338436, ISSN: 1566-7367
VEITH G M ET AL: "Nanoparticles of gold on gamma-Al2O3 produced by dc magnetron sputtering", JOURNAL OF CATALYSIS, ACADEMIC PRESS, DULUTH, MN, US, vol. 231, no. 1, 1 April 2005 (2005-04-01), pages 151 - 158, XP004803507, ISSN: 0021-9517
GRISEL R J H ET AL: "Selective Oxidation of CO, over Supported Au Catalysts", JOURNAL OF CATALYSIS, ACADEMIC PRESS, DULUTH, MN, US, vol. 199, no. 1, 1 April 2001 (2001-04-01), pages 48 - 59, XP004432592, ISSN: 0021-9517
ENDRES H-E ET AL: "A thin-film SnO2 sensor system for simultaneous detection of CO and NO2 with neural signal evaluation", SENSORS AND ACTUATORS B, ELSEVIER SEQUOIA S.A., LAUSANNE, CH, vol. 36, no. 1, October 1996 (1996-10-01), pages 353 - 357, XP004061094, ISSN: 0925-4005
LEGORE L J ET AL: "Aggregation and sticking probability of gold on tungsten trioxide films", SENSORS AND ACTUATORS B, ELSEVIER SEQUOIA S.A., LAUSANNE, CH, vol. 76, no. 1-3, 1 June 2001 (2001-06-01), pages 373 - 379, XP004241146, ISSN: 0925-4005
ANDO M ET AL: "Large optical CO sensitivity of NO2-pretreated Au-NiO composite films", SENSORS AND ACTUATORS B, ELSEVIER SEQUOIA S.A., LAUSANNE, CH, vol. 36, no. 1, October 1996 (1996-10-01), pages 513 - 516, XP004061120, ISSN: 0925-4005
BOND G C ET AL: "CATALYSIS BY GOLD", CATALYSIS REVIEWS SCIENCE AND ENGINEERING, vol. 41, no. 3/4, 1999, pages 319 - 388, XP008017051
HARUTA M ET AL: "Thin Films of Supported Gold Catalysts for CO Detection", SENSORS AND ACTUATORS B, vol. 1, 1990, pages 222 - 225, XP002322907
VALDEN M ET AL: "Onset of Catalytic Activity of Gold Clusters on Titania with the Appearance of Nonmetallic Properties", SCIENCE, vol. 281, no. 5383, 11 September 1998 (1998-09-11), pages 1647 - 1650, XP002322908
GUCZI L ET AL: ""Modeling Gold Nanoparticles: Morphology, Electron Structure and Catalytic Activity in CO Oxidation", JOURNAL OF PHYSICAL CHEMISTRY B, vol. 104, no. 14, 16 February 2000 (2000-02-16), pages 3183 - 3193, XP002322909
SIGMA-ALDRICH CO.: "Nanomaterials", INTERNET ARTICLE, XP002322910, Retrieved from the Internet
DEMYDOV D ET AL: "Characterization of mixed metal oxides (SrTiO3 and BaTiO3) synthesized by a modified aerogel procedure", JOURNAL OF NON-CRYSTALLINE SOLIDS, NORTH-HOLLAND PHYSICS PUBLISHING. AMSTERDAM, NL, vol. 350, 15 December 2004 (2004-12-15), pages 165 - 172, XP004665346, ISSN: 0022-3093
KALCK PHILIPPE ET AL: "Chemical Vapor Deposition Methods for the Controlled Preparation of Supported Catalytic Materials", CHEMICAL REVIEWS, vol. 102, no. 9, 3 August 2002 (2002-08-03), pages 3085 - 3128, XP002322911
HARUTA M ET AL: "Chemical vapor deposition of gold on Al2O3, SiO2, and TiO2 for the oxidation of CO and of H2", CATALYSIS LETTERS, vol. 51, no. 1-2, January 1998 (1998-01-01), pages 53 - 58, XP002322912
OKUMURA M ET AL: "The reactivities of dimethylgold(III)beta-diketone on the surface of TiO2", SOLID STATE IONICS, NORTH HOLLAND PUB. COMPANY. AMSTERDAM, NL, vol. 95, no. 1, 2 February 1997 (1997-02-02), pages 143 - 149, XP004058876, ISSN: 0167-2738
OKUMURA M ET AL: "Chemical Vapor Deposition of Gold Nanoparticles on MCM-41 and Their Catalytic Activities for the Low-temperature Oxidation of CO and H2", CHEMISTRY LETTERS, vol. 27, no. 4, 1998, pages 315 - 316, XP002322913
KOZLOVA A P ET AL: "Iron-Oxide Supported Gold Catalysts Derived from Gold-Phosphine Complex Au(PPh3)(NO3): State and Structure of the Support", JOURNAL OF CATALYSIS, ACADEMIC PRESS, DULUTH, MN, US, vol. 176, no. 2, 10 June 1998 (1998-06-10), pages 426 - 438, XP004447354, ISSN: 0021-9517
CARNES C L ET AL: "SYNTHESIS, CHARACTERIZATION, AND ADSORPTION STUDIES OF NANOCRYSTALLINE ALUMINUM OXIDE AND A BIMETALLIC NANOCRYSTALLINE ALUMINUM OXIDE/MAGNESIUM OXIDE", CHEMISTRY OF MATERIALS, AMERICAN CHEMICAL SOCIETY, WASHINGTON, US, vol. 14, no. 7, July 2002 (2002-07-01), pages 2922 - 2929, XP001190712, ISSN: 0897-4756
POTTERS INDUSTRIES INC.: "SPHERIGLASS(R) Solid Glass Spheres", INTERNET ARTICLE, XP002322914, Retrieved from the Internet
PRATI L ET AL: "Gold on Carbon as a New Catalyst for Selective Liquid Phase Oxidation of Diols", JOURNAL OF CATALYSIS, ACADEMIC PRESS, DULUTH, MN, US, vol. 176, no. 2, 10 June 1998 (1998-06-10), pages 552 - 560, XP004447366, ISSN: 0021-9517
BALERNA A ET AL: "A Structural Investigation on Small Gold Clusters by EXAFS", SURFACE SCIENCE, vol. 156, 1985, pages 206 - 213, XP002322929
SOLLIARD C ET AL: "Surface Stress and Size Effects on the Lattice Parameter in Small Particles of Gold and Platinum", SURFACE SCIENCE, vol. 156, 1985, pages 487 - 494, XP002322930
ENSINGER W ET AL: "Surface treatment of aluminum oxide and tungsten carbide powders by ion beam sputter deposition", SURFACE AND COATINGS TECHNOLOGY, vol. 163-164, 3 October 2002 (2002-10-03), pages 281 - 285, XP002338435
ENSINGER W ET AL: "Noble metal deposition on aluminum oxide powder surfaces by ion beam sputtering", NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH, SECTION - B: BEAM INTERACTIONS WITH MATERIALS AND ATOMS, NORTH-HOLLAND PUBLISHING COMPANY. AMSTERDAM, NL, vol. 141, no. 1-4, May 1998 (1998-05-01), pages 693 - 698, XP004440775, ISSN: 0168-583X
ENSINGER W ET AL: "THE ROTATING WING DRUM: AN APPARATUS FOR ION BEAM TREATMENT OF POWDERS", REVIEW OF SCIENTIFIC INSTRUMENTS, AMERICAN INSTITUTE OF PHYSICS. NEW YORK, US, vol. 65, no. 9, 1 September 1994 (1994-09-01), pages 2963 - 2967, XP000469237, ISSN: 0034-6748
CHEN Y-J ET AL: "Deposition of Highly Dispersed Gold on Alumina Support", JOURNAL OF CATALYSIS, ACADEMIC PRESS, DULUTH, MN, US, vol. 200, no. 1, 15 May 2001 (2001-05-15), pages 59 - 68, XP004432551, ISSN: 0021-9517
ARRII S ET AL: "Oxidation of CO on Gold Supported Catalysts Prepared by Laser Vaporization: Direct Evidence of Support Contribution", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 126, no. 4, 10 January 2004 (2004-01-10), pages 1199 - 1205, XP002338436, ISSN: 1566-7367
VEITH G M ET AL: "Nanoparticles of gold on gamma-Al2O3 produced by dc magnetron sputtering", JOURNAL OF CATALYSIS, ACADEMIC PRESS, DULUTH, MN, US, vol. 231, no. 1, 1 April 2005 (2005-04-01), pages 151 - 158, XP004803507, ISSN: 0021-9517
GRISEL R J H ET AL: "Selective Oxidation of CO, over Supported Au Catalysts", JOURNAL OF CATALYSIS, ACADEMIC PRESS, DULUTH, MN, US, vol. 199, no. 1, 1 April 2001 (2001-04-01), pages 48 - 59, XP004432592, ISSN: 0021-9517
ENDRES H-E ET AL: "A thin-film SnO2 sensor system for simultaneous detection of CO and NO2 with neural signal evaluation", SENSORS AND ACTUATORS B, ELSEVIER SEQUOIA S.A., LAUSANNE, CH, vol. 36, no. 1, October 1996 (1996-10-01), pages 353 - 357, XP004061094, ISSN: 0925-4005
LEGORE L J ET AL: "Aggregation and sticking probability of gold on tungsten trioxide films", SENSORS AND ACTUATORS B, ELSEVIER SEQUOIA S.A., LAUSANNE, CH, vol. 76, no. 1-3, 1 June 2001 (2001-06-01), pages 373 - 379, XP004241146, ISSN: 0925-4005
ANDO M ET AL: "Large optical CO sensitivity of NO2-pretreated Au-NiO composite films", SENSORS AND ACTUATORS B, ELSEVIER SEQUOIA S.A., LAUSANNE, CH, vol. 36, no. 1, October 1996 (1996-10-01), pages 513 - 516, XP004061120, ISSN: 0925-4005
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