Title:
NOVEL ORGANOMETALLIC COMPOUND HAVING HIGH METATHESIS ACTIVITY AND METHOD FOR PREPARATION THEREOF, METATHESIS REACTION CATALYST COMPRISING THE COMPOUND, METHOD OF POLYMERIZATION USING THE CATALYST, AND POLYMER PRODUCED BY THE METHOD OF POLYMERIZATION
Document Type and Number:
WIPO Patent Application WO/2002/018399
Kind Code:
A1
Abstract:
An organometallic compound represented by the general formula (1) or (2); a method for preparing the organometallic compound; a metathesis reaction catalyst comprising the organometallic compound; a method of polymerization using the metathesis reaction catalyst; and a polymer produced by the method of polymerization.
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Inventors:
MORITA TAKEHARU (JP)
HIRAIKE HIROSHI (JP)
GOTO NOBUHIRO (JP)
NAKATANI MASAFUMI (JP)
OZAWA FUMIYUKI (JP)
KATAYAMA HIROYUKI (JP)
HIRAIKE HIROSHI (JP)
GOTO NOBUHIRO (JP)
NAKATANI MASAFUMI (JP)
OZAWA FUMIYUKI (JP)
KATAYAMA HIROYUKI (JP)
Application Number:
PCT/JP2001/007401
Publication Date:
March 07, 2002
Filing Date:
August 29, 2001
Export Citation:
Assignee:
SEKISUI CHEMICAL CO LTD (JP)
MORITA TAKEHARU (JP)
HIRAIKE HIROSHI (JP)
GOTO NOBUHIRO (JP)
NAKATANI MASAFUMI (JP)
OZAWA FUMIYUKI (JP)
KATAYAMA HIROYUKI (JP)
MORITA TAKEHARU (JP)
HIRAIKE HIROSHI (JP)
GOTO NOBUHIRO (JP)
NAKATANI MASAFUMI (JP)
OZAWA FUMIYUKI (JP)
KATAYAMA HIROYUKI (JP)
International Classes:
C07F19/00; C07F15/00; C08G61/08; (IPC1-7): C07F19/00; C08G61/08
Domestic Patent References:
| WO1998039346A1 | 1998-09-11 | |||
| WO1997006185A1 | 1997-02-20 |
Foreign References:
| JP2001302888A | 2001-10-31 |
Other References:
KATAYAMA H. ET AL.: "The new possibility of vinylidene-ruthenium(II) complexes derived from terminal alkynes: ring-opening metathesis polymerization of norbornana derivatives", CHEMISTRY LETTERS, vol. 1998, no. 1, 1998, pages 67 - 68, XP002906754
KARLOU-EYRISCH K. ET AL.: "Ethenolysis of silicon containing cycloolefins", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 606, no. 1, 2000, pages 3 - 7, XP002906755
HUANG D. ET AL.: "16-Electron ruthenium(0) complexes containing the Ru(NO)L2+ substructure: planar ruch3(NO)L2 vs sawhorse (Ru(NO)(C=C(SiMe3)2)L2)+", ORGANOMETALLICS, vol. 19, no. 10, 2000, pages 1967 - 1972, XP002906756
BARBARO P. ET AL.: "Regio- and stereoselective dimerization of 1-alkynes catalyzed by an Os(ii) complex", INORGANICA CHIMICA ACTA, vol. 220, no. 1-2, 1994, pages 5 - 19, XP002906757
HEROGUEZ V. ET AL.: "Synthesis of alpha- and omega-norbornenyl-polybutadiene macromonomers and their ring-opening metathesis polymerization", MACROMOL. CHEM. PHYS., vol. 199, no. 7, 1998, pages 1405 - 1412, XP002906758
KATAYAMA H. ET AL.: "Convenient routes to vinylidene-ruthenium dichlorides with basic and bulky tertiary phosphine ligands (PPri3 and PCy3)", ORGANOMETALLICS, vol. 17, no. 23, 1998, pages 5190 - 5196, XP002906759
HUANG D. ET AL.: "CO-Induced C(sp2)/C(sp) couping on Ru and Os: a comparative study", ORGANOMETALLICS, vol. 17, no. 21, 1998, pages 4700 - 4706, XP002906760
OLIVAN M. ET AL.: "New access to vinylidenes from ruthenium polyhidrides", ORGANOMETALLICS, vol. 16, no. 11, 1997, pages 2227 - 2229, XP002906761
OLIVAN M. ET AL.: "Hydride is not a spectator ligand in the formation of hydrido vinylidene from terminal alkyne and ruthenium and osmium hydrides: mechanistic differences", ORGANOMETALLICS, vol. 17, no. 14, 1998, pages 3091 - 3100, XP002906762
See also references of EP 1334977A4
KARLOU-EYRISCH K. ET AL.: "Ethenolysis of silicon containing cycloolefins", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 606, no. 1, 2000, pages 3 - 7, XP002906755
HUANG D. ET AL.: "16-Electron ruthenium(0) complexes containing the Ru(NO)L2+ substructure: planar ruch3(NO)L2 vs sawhorse (Ru(NO)(C=C(SiMe3)2)L2)+", ORGANOMETALLICS, vol. 19, no. 10, 2000, pages 1967 - 1972, XP002906756
BARBARO P. ET AL.: "Regio- and stereoselective dimerization of 1-alkynes catalyzed by an Os(ii) complex", INORGANICA CHIMICA ACTA, vol. 220, no. 1-2, 1994, pages 5 - 19, XP002906757
HEROGUEZ V. ET AL.: "Synthesis of alpha- and omega-norbornenyl-polybutadiene macromonomers and their ring-opening metathesis polymerization", MACROMOL. CHEM. PHYS., vol. 199, no. 7, 1998, pages 1405 - 1412, XP002906758
KATAYAMA H. ET AL.: "Convenient routes to vinylidene-ruthenium dichlorides with basic and bulky tertiary phosphine ligands (PPri3 and PCy3)", ORGANOMETALLICS, vol. 17, no. 23, 1998, pages 5190 - 5196, XP002906759
HUANG D. ET AL.: "CO-Induced C(sp2)/C(sp) couping on Ru and Os: a comparative study", ORGANOMETALLICS, vol. 17, no. 21, 1998, pages 4700 - 4706, XP002906760
OLIVAN M. ET AL.: "New access to vinylidenes from ruthenium polyhidrides", ORGANOMETALLICS, vol. 16, no. 11, 1997, pages 2227 - 2229, XP002906761
OLIVAN M. ET AL.: "Hydride is not a spectator ligand in the formation of hydrido vinylidene from terminal alkyne and ruthenium and osmium hydrides: mechanistic differences", ORGANOMETALLICS, vol. 17, no. 14, 1998, pages 3091 - 3100, XP002906762
See also references of EP 1334977A4
Attorney, Agent or Firm:
Kawabi, Kenji (6th floor 9-7, Higashi-ikebukuro 3-chome Toshima-ku Tokyo, JP)
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