Title:
OCTAHYDROBINAPHTHOL DERIVATIVE FOR L/D OPTICAL CONVERSION AND OPTICAL RESOLUTION
Document Type and Number:
WIPO Patent Application WO/2011/122917
Kind Code:
A3
Abstract:
The present invention relates to an octahydrobinaphthol derivative which recognizes an amino acid and amino alcohol in a chiral-selective manner, converts L-amino acid into D-amino acid, and performs optical resolution on an amino acid and amino alcohol with high efficiency.
Inventors:
KIM KWAN-MOOK (KR)
Application Number:
PCT/KR2011/002301
Publication Date:
March 08, 2012
Filing Date:
April 01, 2011
Export Citation:
Assignee:
UNIV EWHA IND COLLABORATION (KR)
AMINOLUX INC (KR)
KIM KWAN-MOOK (KR)
AMINOLUX INC (KR)
KIM KWAN-MOOK (KR)
International Classes:
C07C275/32; C07C273/00; C07C275/38; C07C279/18
Other References:
PARK, HYEON JEONG ET AL.: "Bioinspired chemical inversion of L-amino acids to D-amino acids", JOURNAL OF AMERICAN CHEMISTRY SOCIETY, vol. 129, 1 November 2007 (2007-11-01), pages 1518 - 1519, XP002736711, DOI: doi:10.1021/JA067724G
KWAN MOOK KIM ET AL.: "Enantioselective recognition of 1,2-amino alcohols by reversible formation ofimines with resonance-assisted hydrogen bonds", ORGANIC LETTERS, vol. 7, 7 July 2005 (2005-07-07), pages 3525 - 3527, XP009070748, DOI: doi:10.1021/ol051267b
MICHAEL, B. ET AL.: "A convenient protocol for the synthesis of axially chiral bronsted acids", TETRAHEDRON, vol. 64, 23 November 2007 (2007-11-23), pages 1316 - 1322, XP022413105, DOI: doi:10.1016/j.tet.2007.11.067
REETZ, M. T. ET AL.: "A new chiral ligand for metal-catalyzed enatioselective reactions", TETRAHEDRON LETTERS, vol. 38, 27 March 1998 (1998-03-27), pages 5273 - 5276
KWAN MOOK KIM ET AL.: "Enantioselective recognition of 1,2-amino alcohols by reversible formation ofimines with resonance-assisted hydrogen bonds", ORGANIC LETTERS, vol. 7, 7 July 2005 (2005-07-07), pages 3525 - 3527, XP009070748, DOI: doi:10.1021/ol051267b
MICHAEL, B. ET AL.: "A convenient protocol for the synthesis of axially chiral bronsted acids", TETRAHEDRON, vol. 64, 23 November 2007 (2007-11-23), pages 1316 - 1322, XP022413105, DOI: doi:10.1016/j.tet.2007.11.067
REETZ, M. T. ET AL.: "A new chiral ligand for metal-catalyzed enatioselective reactions", TETRAHEDRON LETTERS, vol. 38, 27 March 1998 (1998-03-27), pages 5273 - 5276
Attorney, Agent or Firm:
HANYANG PATENT FIRM (412-1 Dogok-dong Gangnam-gu, Seoul 135-854, KR)
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Claims: