Macauba oil for the production of Oleochemicals

The present invention relates to a process of manufacturing fatty acid amides or alkoxylated fatty acid esters comprising the step of converting oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr into the fatty acid amides or alkoxylated fatty acid esters. Further, the present invention relates to fatty acid amides or alkoxylated fatty acid esters obtained from the fruits of a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr and the use thereof in suitable applications.

Numerous oil-based products are derived from renewable materials such as oil palm (principal source of palm oil). While such an approach is advantage since it safes the petroleum deposit it also provides several downsides. One issue is the deforestation in order to plant e.g. oil palm plantations, which aggravates the current climate change. Deforestation further leads to undesired loss of biodiversity and the loss of habitats for local tribes. In addition, particularly oil palms need tropical conditions and preferred temperatures between about 24 to 28 ° C, monthly rainfalls of at least 100 mm/m ² , and a humidity between about 50 to 70%. These factors limit the possibility of a profitable cultivation.

At the same time the demand for renewable oil increases every year since the worldwide consume is increasing. Products derived from renewable oil can be found in every important industrial section, e.g. food products, pharmaceuticals, consumer goods, or energy (biodiesel).

Against this background, there is an ongoing need for a more environmental friendly alternative to known products derived from renewable oil such as palm oil. In particular, it was an object of the present invention to provide a fatty acid amide composition or an alkoxylated fatty acid ester composition having an improved sustainability profile and improved properties, as well as an improved process of manufacturing thereof. Further, it was an object of the present invention to provide fatty acid amides or alkoxylated fatty acid esters, wherein the starting material is derived from plants that are less vulnerable against temperature fluctuation, as well as a process of manufacturing thereof. Finally, it was an objection to provide a personal care composition, a cleaning composition, a nutrition formulation, a pharmaceutical formulation, or a crop formulation having an improved sustainability profile and improved properties, as well as an improved process of manufacturing thereof. In this connection, a more environmental friendly alternative preferably provides at least one, more preferably at least two, still more preferably at least three, and in particular at least four, of the following impacts: reduced water demand, reduction of the loss of biodiversity, reduction of loss of habitats for local tribes, reduction of deforestation, improved recovery of degraded areas and springs and watersheds, improved retention of moisture in the soil, improved resistance to temperature fluctuations and climate change. BASF SE

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It has surprisingly been found that at least one of these objects can be achieved by applying an oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr.

Thus, according to one aspect, the present invention relates to a process of manufacturing a fatty acid amide composition or an alkoxylated fatty acid ester composition, the process comprising the step a) converting oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr into fatty acid amides or alkoxylated fatty acid esters.

I n the following, preferred embodiments of the above process are described in further detail. It is to be understood that each preferred embodiment is relevant on its own as well as in combination with other preferred embodiments.

I n a preferred embodiment Al of the first aspect, the Macauba palm is Acrocomia acu/eata and/or wherein the the oil is extracted from the palm pulp and/or the palm kernel, preferably wherein the oil is extracted from the Macauba kernel, and in particular wherein the Macauba pal mis Acrocomia acuieata and the oil is extracted from Acrocomia acuieata kernel.

I n a preferred embodiment A2 of the first aspect, in step a) the conversion is conducted under chemical or enzymatic conditions, preferably under chemical conditions and/or wherein step a) involves a condensation or a transesterification.

I n a preferred embodiment A3 of the first aspect, the Macauba palmhas an oil yield in tons per hectare per year in the range of 6 to 30 t/ha/yr, preferably 7 to 20 t/ha/yr, more preferably of 8 to 15 t/ha/yr.

I n a preferred embodiment A4 of the first aspect, a fatty acid amide composition is manufactured, preferably wherein the fatty acid amide composition is selected from the group consisting of a fatty acid amido alkanolamide (fatty acid alkanolamide) composition and a fatty acid amidoalkylbetaine composition and in step a) the oil is converted into the fatty acid amido alkanolamides (fatty acid alkanolamides) or the fatty acid amidoalkylbetaines.

I n a preferred embodiment A5 of the first aspect, the fatty acid amide composition provided in step a) comprises at least 40 wt.-%, based on the total weight of the fatty acid amide composition, of C ₄ -C ₂₂ fatty acid amides, preferably C ₆ -C ₂₀ fatty acid amides, more preferably C ₈ -C ₁₈ fatty acid amides, even more preferably C ₈ -C ₁₆ fatty acid amides or C ₁₆ -C ₁₈ fatty acid amides, and in particular C ₁₀ -C ₁₆ fatty acid amides and/or

1 to 20 of wt.-% of a C ₈ fatty acid amide,

1 to 8 of wt.-% of a C ₁₀ fatty acid amide,

30 to 48 wt.-% of a C ₁₂ fatty acid amide,

5 to 15 wt.-% of a C ₁₄ fatty acid amide,

4 to 13 wt.-% of a C ₁₆ fatty acid amide,

15 to 42 wt.-% of a C ₁₈ fatty acid amide, and

0 to 5 wt.-% of a C ₂₀ fatty acid amide, BASF SE

3 each based on the total weight of the fatty acid amide composition.

In a preferred embodiment A6 of the first aspect, the fatty acid amide composition provided in step a) is a fatty acid amido alkanolamide (fatty acid alkanolamide) composition, preferably selected from the group consisting of fatty acid amido monoalkylamide (fatty acid monoalkylamide) composition and fatty acid amido dialkylamide (atty acid dialkylamide) composition, more preferably selected from the group consisting of fatty acid amido monoethanolamide (fatty acid monoethanolamide) composition and fatty acid amido diethanolamide (fatty acid diethanolamide) composition or wherein the fatty acid amide composition provided in step a) is a fatty acid amidoalkylbetaine, preferably a fatty acid amidopropylbetaine composition.

In a preferred embodiment A7 of the first aspect, step a) further comprises the step a.i) blending the oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr with an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr, preferably wherein the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from coconut oil (CNO), palm oil (PO), and/or palm kernel oil (PKO) and/or the fatty acid amide composition obtained in step a) is blended with a fatty acid amide composition obtained from an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr and a subsequent conversion into the respective fatty acid amide com-position, preferably wherein the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from coconut oil (CNO), palm oil (PO), and/or palm kernel oil (PKO).

In a second aspect, the present invention relates to a fatty acid amide composition obtained by a process according to the first aspect.

In a third aspect, the present invention relates to fatty acid amide composition or an alkoxylated fatty acid ester composition obtained from the fruits of a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr, wherein the oil obtained from the Macauba palmis converted into the fatty acid amide or the alkoxylated fatty acid ester.

In a fourth aspect, the present invention relates to alkoxylated fatty acid ester composition obtained by a process according to the first aspect.

In a fifth aspect, the present invention relates to the use of oil extracted from fruits of a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr for manufacturing fatty acid amides or alkoxylated fatty acid esters.

In a sixth aspect, the present invention relates to the use of the fatty acid amide composition according to the second or the third aspect, or the alkoxylated fatty acid ester composition according to the third or the fourth aspect, in a personal care composition, a cleaning composition, a nutrition formulation, a pharmaceutical formulation, or a crops formulation. BASF SE

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In a seventh aspect, the present invention relates to a personal care composition, a cleaning composition, a nutrition formulation, a pharmaceutical formulation, or a crop formulation comprising the fatty acid amide composition according to second or the third aspect, or the alkoxylated fatty acid ester composition according to the third or the fourth aspect.

In an eighth aspect, the present invention relates to process of manufacturing glycerol, the process comprising the step a) converting oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr into glycerol.

Before describing in detail exemplary embodiments of the present invention, definitions which are important for understanding the present invention are given.

As used in this specification and in the appended claims, the singular forms of "a" and "an" also include the respective plurals unless the context clearly dictates otherwise. In the context of the present invention, the terms "about" and "approximately" denote an interval of accuracy that a person skilled in the art will understand to still ensure the technical effect of the feature in question. The term typically indicates a deviation from the indicated numerical value of ± 10 %, preferably ± 8 %, more preferably ± 5 %, even more preferably ± 2 %. It is to be understood that the term "comprising" and “encompassing” is not limiting. For the purposes of the present invention the term "consisting of" is considered to be a preferred embodiment of the term "comprising of". If hereinafter a group is defined to comprise at least a certain number of embodiments, this is meant to also encompass a group which preferably consists of these embodiments only. Furthermore, the terms "first", "second", "third" or "(a)", "(b)", "(c)", "(d)" etc. and the like in the description and in the claims, are used for distinguishing between similar elements and not necessarily for describing a sequential or chronological order. It is to be understood that the terms so used are interchangeable under appropriate circumstances and that the embodiments of the invention described herein are capable of operation in other sequences than described or illustrated herein. In case the terms "first", "second", "third" or "(a)", "(b)", "(c)", "(d)", "i", "ii" etc. relate to steps of a method or use or assay there is no time or time interval coherence between the steps, i.e. the steps may be carried out simultaneously or there may be time intervals of seconds, minutes, hours, days, weeks, months or even years between such steps, unless otherwise indicated in the application as set forth herein above or below. It is to be understood that this invention is not limited to the particular methodology, protocols, reagents etc. described herein as these may vary. It is also to be understood that the terminology used herein is for the purpose of describing particular embodiments only, and is not intended to limit the scope of the present invention that will be limited only by the appended claims. Unless defined otherwise, all technical and scientific terms used herein have the same meanings as commonly understood by one of ordinary skill in the art.

As used herein the term “does not comprise”, “does not contain”, or “free of” means in the context that the composition of the present invention is free of a specific compound or group of compounds, which may be combined under a collective term, that the composition does not comprise said compound or group of compounds in an amount of more than 0.8 % by weight, based on the total weight of the composition. Furthermore, it is preferred that the BASF SE

5 composition according to the present invention does not comprise said compounds or group of compounds in an amount of more than 0.5 % by weight, preferably the composition does not comprise said compounds or group of compounds at all.

When referring to compositions and the weight percent of the therein comprised ingredients it is to be understood that according to the present invention the overall amount of ingredients does not exceed 100% (± 1% due to rounding).

The term “personal care composition” refers to any topical and oral product that can be used at least once daily by the consumer as an everyday care product for caring, cleaning, protecting, maintaining, perfuming or changing the appearance or feel of the human body, e.g. for face, hair, body, or oral care. The personal care composition may comprise one or more active agents, e.g., organic and/or inorganic UV filters, as well as other ingredients or additives, e.g., emulsifiers, emollients, viscosity regulators, stabilizers, preservatives, or fragrances. Suitable daily care composition are according to the present invention, e.g. leave-on face and body care products and rinse-off face and body care products.

Suitable leave-on face and body care products are, e.g. sunscreen compositions, decorative preparations, and skin care preparations.

The term “sunscreen composition” or “sunscreen” refers to any topical product, which absorbs and which may further reflect and scatter certain parts of UV radiation. Thus, the term “sunscreen composition” is to be understood as not only including sunscreen compositions, but also any cosmetic compositions that provide UV protection. The term “topical product” refers to a product that is applied to the skin and can refer, e.g., to sprays, lotions, creams, oils, foams, powders, or gels. According to the present invention the sunscreen composition may comprise one or more active agents, e.g., organic and inorganic UV filters, as well as other ingredients or additives, e.g., emulsifiers, emollients, viscosity regulators, stabilizers, preservatives, or fragrances.

Suitable decorative preparations are, e.g., lipsticks, nail varnishes, eye shadows, mascaras, dry and moist make-up, rouge, powders, depilatory agents and suntan lotions.

Suitable skin care preparations are e.g., moisturizing, refining, and lifting preparations. The cited daily care compositions can be in the form of creams, ointments, pastes, foams, gels, lotions, powders, make-ups, sprays, sticks or aerosols.

The term “UV filter” or “ultraviolet filter” as used herein refers to organic or inorganic compounds, which can absorb and may further reflect and scatter UV radiation caused by sunlight. UV-filter can be classified based on their UV protection curve as UV-A, UV-B, or broadband filters.

In general, UV light can be divided into UV-A radiation (320 - 400 nm) and UV-B radiation (290 - 320 nm). The definition of “broadband” protection (also referred to as broadspectrum or broad protection) is based on the “critical wavelength”. For broadband coverage, UV-B and UV-A protection must be provided. According to the US requirements, a critical wavelength of at least 370 nm is required for achieving broad spectrum protection. The term “critical wavelength” is defined as the wavelength at which the area under the UV protection curve (% protection versus wavelength) represents 90 % of the total area under the curve in the UV region (290-400 nm). For example, a critical wavelength of 370 nm indicates that the protection of the sunscreen composition is not limited to the wavelengths of UV-B, i.e. wavelengths from 290-320 nm, but extends to 370 nm in such a way that 90 % of the total area under the protective curve in the UV region are reached at 370 nm. BASF SE

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Suitable rinse-off face and body care products are, e.g. shampoo, conditioner, shower gel, body scrub, face scrub, and hand soap. In particular rinse-off products are hair shampoos, shower gels, soaps, syndet bars, washing pastes, washing lotions, scrub preparations, facial cleansers, intimate hygiene washes, foam baths, oil baths, shower baths, shaving foams, shaving lotions, shaving creams, foaming powders/tabs and dental care products (for example toothpastes, mouthwashes and the like). Also baby care products like baby shampoo and baths are suitable rinse-off products.

The term “emollient” relates to cosmetic specific oils used for protecting, moisturizing and lubricating the skin. The word emollient is derived from the Latin word mo/Hre, to soften. In general, emollients prevent evaporation of water from the skin by forming an occlusive coating. They can be divided into different groups depending on their polarity index.

The term “polarity index” refers to non-polar or polar oils. Non-polar oils are mainly based on hydrocarbons and lack an electronegative element, such as oxygen. In contrast, polar oils contain heteroatoms that differ in electronegativity, which results in a dipole moment. However, such oils are still insoluble in water, i.e. hydrophobic. The polarity index can be determined by measuring the interfacial tension between the respective oil and water.

The term “administration” refers to the application of a sunscreen or daily care composition to the skin of a person.

The term “fatty alcohol” as used herein is directed to linear or branched, preferably linear, primary alcohols. Fatty alcohols may comprise from 4 to 26 carbon atoms. According to the present invention, the term fatty alcohol encompasses saturated and unsaturated alcohol. The double bond of an unsaturated fatty alcohol can give either cis or trans isomers. According to the present invention, the term fatty alcohol encompasses saturated and unsaturated alcohols. 1-Butanol, 1-hexanol, 1-octanol, 1-decanol, lauryl alcohol, myristyl alcohol, cetyl alcohol, palmitoyl alcohol, stearyl alcohol, oleyl alcohol, arachidyl alcohol, behenyl alcohol, erucyl alcohol, lignoceryl alcohol, and ceryl alcohol should be named in this connection.

The term “fatty alcohol-based surfactant” as used herein denotes a surfactant that originates from a reaction of the primary alcohol group of a fatty alcohol.

The term “fatty acid” as used herein is directed to linear or branched, preferably linear, primary carboxylic acids. Fatty acids may comprise from 4 to 26 carbon atoms. According to the present invention, the term fatty acid encompasses saturated and unsaturated acids. The double bond of an unsaturated fatty acid can give either cis or trans isomers. Caprylic acid, capric acid, lauric acid, myristic acid, myristoleic acid, palmitic acid, palmitoleic acid, sapienic acid, stearic acid, oleic acid, elaidic acid, vaccenic acid, linoleic acid, linoelaidic acid, a -Linolenic acid, arachidic acid, arachidonic acid, eicosapentaenoic acid, erucic acid, behenic acid, docosahexaenoic acid, lignoceric acid, and cerotic acid should be named in this connection.

The term “fatty acid-based surfactant” as used herein denotes a surfactant that originates from a reaction of the primary carboxylic group of a fatty acid.

The prefix C _n -C _m indicates in each case the possible number of carbon atoms in the group.

The term “hydroxyalkyl” as used herein denotes in each case a linear or branched alkyl group having usually from 1 to 8 carbon atoms, preferably from 1 to 6 carbon atoms and being further substituted with 1 to 5, preferably with 1 to 2 hydroxy groups, in particular BASF SE

7 with 1 hydroxy group. Preferably, the one hydroxy group is terminating the linear or branched alkyl group so that the hydroxy group is bonded to an alkyl bridge, which is bonded to the remainder of the molecule. Examples of an hydroxyalkyl group are hydroxymethyl, hydroxyethyl, n-hydroxypropyl, 2-hydroxypropyl, n-hydroxybutyl, 2- hydroxybutyl, 2-hydroxy-2-methylpropyl, n-hydroxypentyl, and n-hydroxyhexyl.

The term "alkyl" as used herein denotes in each case a linear or branched alkyl group having usually from 1 to 30 carbon atoms, preferably 4 to 26 or of 1 to 6 or of 1 to 3 carbon atoms. Examples of an alkyl group are methyl, ethyl, n-propyl, iso-propyl, n-butyl, 2-butyl, iso-butyl, tert-butyl, n-pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 2,2-di- methylpropyl, 1 -ethyl propyl, n-hexyl, 1,1-dimethylpropyl, 1 ,2-d imethyl propyl , 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,1-dimethylbutyl, 1 ,2-d imethyl butyl , 1,3- dimethyl butyl , 2,2-dimethylbutyl, 2, 3-d imethyl butyl , 3, 3-d imethyl butyl , 1-ethyl butyl , 2- ethylbutyl, 1 ,1 ,2-tri methyl propyl , 1,2,2-tri methyl propyl , 1-ethyl - 1- methyl propyl , and 1-ethyl- 2-methylpropyl.

The term “oil palm” as used herein denotes a species of palm, which is also known as “ Eiaeis guineensis" . It is the principal source of “palm oil”.

The term “coconut tree” as used herein denotes a member of the palm tree family (Arecaceae) and is also referred to as Cocos nucifera. It is the principal source for “coconut oil”.

The term “Macauba palm” as used herein denotes a species of palm. Exemplary species are known as “ Acrocomia acuieata" (also known as “macaiba”, “boicaiuva”, “macauva”, “coco-de-catarro”, “coco-baboso”, and “coco-de-espinho”), “ Acrocomia hassieri' , and "Acrocomia totei. Macauba palms can grow high, e.g. up to about 15 m. The Macauba fruit comprises pulp and kernel.

The term “pulp” as used herein refers to inner flesh of a fruit.

The term “kernel” as used herein is interchangeable with “seed” or “almond”.

The term “cleaning composition” as used herein encompasses home care formulation, industrial care formulation, and institutional care formulation. Home care formulations are typically used by private consumer, whereas industrial care formulations are typically used by the industry, and institutional care formulations are typically used in e.g. clinics and nursing homes. It is however also possible that the respective formulations can be used in different areas than intended. Hence, the institutional care formulation may also be used by private consumer or the industry and vice versa. Typically cleaning compositions are e.g. for the laundry, dishwashing, hard surface cleaning, food service and kitchen hygiene, food and beverage processing, commercial laundry, sanitation, institutional cleaning, industrial cleaning, and vehicle and transportation care.

The term “nutrition formulation” as used herein encompasses food and feed formulations. The nutrition formulation can have any suitable form, e.g. liquid or solid and can be administered or uptaken in any suitable manner, e.g. orally, parenterally, or rectally.

The term “pharmaceutical formulation” as used herein refers to any suitable pharmaceutical formulation, which may e.g. be administered in any suitable manner such as by oral, transdermal, parenteral, nasal, vaginal, or rectal application. Suitable solid pharmaceutical formulation can be in form of tablets, suppositories, or capsules or in form of a spray. Suitable transdermal pharmaceutical formulations encompass patches or BASF SE

8 formulations such as sprays, lotions, creams, oils, foams, ointments, powders, or gels. Liquid pharmaceutical formulations are preferably administered orally, parenterally, or nasal.

The term “liquid” as used herein also encompasses semi-solid conditions, wherein the fluid has an increased viscosity (e.g. creamy, gels, ointments).

The term “crop formulation” as used herein encompasses pesticide formulations, fungicide formulations, and herbicide formulations.

The term “oil yield in tons per hectare per year” as used herein is directed to the oil derived from the fruit of the plant via e.g. extraction, wherein the fruit comprises the pulp and the kernel. It refers to the oil produced per hectare. It is to be understood that the value refers to the oil yield obtained from a monoculture, wherein the plants are cultivated under standard conditions, which depend on the respective plant and are known to the skilled person. Hence, in the event that the plant is not cultivated in a monoculture (e.g. on a cattle field), the respective value for this particular cultivation may be reduced. Typically, oil palm has an oil yield in tons per hectare per year of about 3.8 t/ha/yr, rapeseed has an oil yield in tons per hectare per year of about 0.8 t/ha/yr, sunflower has an oil yield in tons per hectare per year of about 0.7 t/ha/yr, and soya has an oil yield in tons per hectare per year of about 0.6 t/ha/yr.

The term “monoculture” as used herein denotes the practice of growing one plant, e.g. Macauba palm, in a field at a time. On the example of Macauba palm, about 500 to about 600 palms can be planted per hectare. In this connection, it is preferred that the minimum distance between the tress is about 3.5 to 4.5 meters. This number varies depending on e.g. the soil. The growing of the Macauba plants is described in the following. In the first year, growth is slower, as the major development occurs below the soil. Hence, the plant itself grows about 80 to 100 cm. From the second year onwards, when the plant size is approximately 100 to 150 cm), growth is faster and there is an increased development of the aerial part of the plant. A fully mature plant providing the claimed oil yield per hectare per year is about 5 to 6 years old.

The water consumption of the Macauba plant is 50% lower than of palm. Macauba plantations can be located in regions with a minimum rainfall of 1.200 mm per year.

The term “agroforestry” as used herein denotes a land use management system in which trees or shrubs are grown around or among other plant such as other trees or other shrubs or crops or pastureland. It is to be understood that not only one further plant can be present in agroforestry. On the example of Macauba palm, e.g. about 250 to about 360 or about 325 to about 350, trees can be planted per hectare. In this connection, suitable crops that may be planted together with Macauba palm are exemplarily beans, mandioca, corn, cereals, sunflower, peanut, rapeseed, soya, and mixtures thereof.

The term “silvopastoral” as used herein denotes a land use management system in which trees and optionally forage are planted within the grazing of domesticated animals. On the example of Macauba palm, e.g. about 275 to about 450 or about 375 to about 400, trees can be planted per hectare.

Preferred embodiments regarding the process of manufacturing a fatty acid amide composition, an alkoxylated fatty acid ester composition, a specific a fatty acid amide and BASF SE

9 blends thereof, or a specific alkoxylated fatty acid ester and blends thereof, as well as the use thereof, and the products comprising the same are described hereinafter. It is to be understood that the preferred embodiments of the invention are preferred alone or in combination with each other.

One advantage of the present invention is that the fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters of the present invention exhibit improved storage stability and improved handling and processability.

The fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters of the present invention have in particular an improved storage stability. Improved storage stability is achieved if the composition does not exhibit any visible (e.g., cloudiness, discoloration, phase separation, agglomeration) or measurable (e.g. pH, viscosity, active substance content, color value) or perceivable (odor) changes over time. Preferably, improved storage stability is achieved if less color formation during storage at elevated temperatures is observed. In case of aqueous compositions elevated temperatures are temperatures such as 40° C or more, for non-aqueous compositions elevated temperatures are temperatures above the melting point. Also preferably, improved storage stability is achieved if no cloudiness or phase separation during storage at low temperatures such as 15° C or lower can be observed in case of aqueous compositions. Even more preferably, improved storage stability is achieved if the composition solidifies and melts over a well-defined, narrow temperature range. The solidification-/melting-temperature range of a composition can be determined by a DSC measurement (differential scanning calorimetry). Most preferably, improved storage stability is achieved if the time wherein the composition is unchanged and stable is as long as possible.

Preferably, the fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters of the present invention have an improved handling and processability. Improved handling and processability is in particular achieved if the aqueous composition has a viscosity that allows for free-flowing at room temperature (-23° C) and/or to be easily stirred and pumped (e.g. showing a shear thinning behavior). Furthermore improved handling and processability is in particular achieved if the non-aqueous composition has a lower melting point and a lower viscosity that allows for free-flowing at temperatures above the melting point.

One advantage of the present invention is that the personal care composition, cleaning composition, nutrition formulation, pharmaceutical formulation, or crop formulation of the fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters of the present invention show improved viscosity and flow behavior and/or improved appearance/transparency and/or improved mildness and/or improved surface activity and cleaning capability and/or improved foaming capability and/or improved care performance. BASF SE

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What is understood as advantageous viscosity and flow behavior depends on the intended use and application of the personal care compositions. For aqueous personal care composition, cleaning composition, nutrition formulation, pharmaceutical formulation, or crop formulation of the fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters of the present invention such as shower gels and shampoos it is desirable to have a high viscosity in the range of 5000 - 20000 mPas (measured using a Brookfield RV laboratory rheometer at 23° C, 10 rpm, spindle choice depending on viscosity range). As is known, “mPas” means millipascal seconds. Hence, improved viscosity and flow behavior for aqueous personal care composition, cleaning composition, nutrition formulation, pharmaceutical formulation, or crop formulation of the fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters of the present invention such as shower gels and shampoos is preferably achieved by either having higher viscosity with the same concentration of the fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters (and same concentration of other components) or by having the same viscosity with a lower concentration of fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters (and/or lower concentration of other components). Preferably, improved viscosity and flow behavior for aqueous personal care composition, cleaning composition, nutrition formulation, pharmaceutical formulation, or crop formulation of the fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters of the present invention such as shower gels and shampoos is achieved, if the viscosity is not or less sensitive to the temperature (e.g., no or less viscosity decrease at elevated temperatures such as 40° C or more). Finally, also preferably, improved viscosity and flow behavior for aqueous personal care composition, cleaning composition, nutrition formulation, pharmaceutical formulation, or crop formulation of the fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters of the present invention such as shower gels and shampoos is achieved if the viscosity is not or less sensitive to the addition of a parfum (e.g. no or less viscosity decrease), and/or if the compositions have a shear-thinning flow behavior, means that the viscosity decreases when shear-stress is applied to the composition (e.g. when it’s moved, stirred, pumped, shaken), and/or if the viscosity when the composition is at rest (in the bottle/ packaging, when collected on the palm of hand) is high and the viscosity under shear-stress (e.g. when dosed, squeezed out of the bottle or distributed/applied and rubbed between hands and/or hair) is low.

For aqueous personal care composition, cleaning composition, nutrition formulation, pharmaceutical formulation, or crop formulation of the fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters of the present invention such as pump foams, sprays, micellar waters, or make-up removers a very low viscosity of less than 200 mPas is desired. BASF SE

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In this case it is advantageous to either achieve a lower viscosity with the same concentration of fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters (and same concentration of other components) or the same viscosity with a higher concentration of fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters (and/or higher concentration of other components).

For aqueous personal care composition, cleaning composition, nutrition formulation, pharmaceutical formulation, or crop formulation of the fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters of the present invention very often clear compositions are required, especially if transparent packaging is used. Hence, preferably, the care compositions of the present invention have an improved transparency. Transparency can be quantitatively determined by means of a transmission measurement with a TurbiScan MA 2000 (measuring instrument from Formulaction) at 23° C. Preferably, the care composition of the present invention has an average transmission of at least 80%, preferably more of at least 85%, and most preferably of at least 88%.

For personal care composition, cleaning composition, nutrition formulation, pharmaceutical formulation, or crop formulation of the fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters of the present invention it is desirable to have a good skin and mucous membrane (ocular and oral) compatibility and thus a low irritation potential, also denoted as mildness. The personal care composition, cleaning composition, nutrition formulation, pharmaceutical formulation, or crop formulation of the fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters of the present invention have an improved mildness. The irritation potential can be determined by methods known to those skilled in the art, e.g., in vitro methods like RBC, HET-CAM or test on model tissues (Epi- Ocular/Epi-Oral) and also by test subjects (e.g., epicutaneous patch test, “tear-free” tests with panelist).

For personal care composition, cleaning composition, nutrition formulation, pharmaceutical formulation, or crop formulation of the fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters of the present invention it is also advantageous to have improved surface activity. Improved surface activity is characterized by either a lower CMC (critical micellar concentration), a lower surface tension or the ability to reduce the surface tension faster than a composition comprising fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters derived from other oil sources. The surface can for example be the interface between the aqueous composition and either air, gas or oil. Hence, the personal care composition, cleaning composition, nutrition formulation, pharmaceutical formulation, or crop formulation of the fatty acid amide compositions, alkoxylated fatty acid BASF SE

12 ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters of the present invention preferably have an improved surface activity. The surface activity can be measured CMC measurement with a tensiometer (DCAT, DataPhysics Instruments GmbH or comparable), dynamic surface tension measurement with the bubble pressure method (SITA-Online T60, Sita Messtechnik GmbH or comparable). These characteristics are also relevant to determine the cleansing, dispersing, emulsifying and solubilisation capability of a composition, specifically for the removal of dirt and oily substances from hair, skin, hard surfaces, and textiles.

In parallel to the compositions comprising fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters of the present invention, also personal care composition, cleaning composition, nutrition formulation, pharmaceutical formulation, or crop formulation of the fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters of the present invention show improved storage stability as defined above.

It is desirable that personal care composition, cleaning composition, nutrition formulation, pharmaceutical formulation, or crop formulation of the fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters of the present invention have a good foaming ability. It is in particular desirable that the compositions are capable to create a foam with a high initial foam volume when the composition is used, e.g. by rubbing between hands, skin and/or hair; and/or that is stable after foam formation was finished, so showing no or less volume decrease compared to the initial foam volume and/or with no or less drainage (no or only little liquid accumulates below the foam); and/or that has small foam bubbles and a narrow foam bubble size distribution; and/or that has high water content (liquid volume in foam/ total volume of foam); and/or that has high elasticity; and/or that has a pleasant foam sensory such as soft and dense feeling of the foam, creaminess, elasticity, moldability and overall acceptance by the consumer. Preferably, the foam derived from the personal care composition, cleaning composition, nutrition formulation, pharmaceutical formulation, or crop formulation of the fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters of the present invention shows the above-mentioned characteristics even under challenging conditions such as in hard water (e.g. 15° dH), at low temperatures, under acidic or alkaline conditions, in presence of a high oil load, in presence of a high salt load, with no anionic sulfate-surfactants present.

The foaming behavior of an aqueous composition (or a dried composition that has been dissolved in water) can be investigated e.g. by agitating the solution within a short time period (-10-200 seconds) by means of stirring, shaking, pumping, bubbling through a gas stream or in other way and then monitoring the foam volume over time (up to 30 minutes) and taking pictures of the foam structure for image analysis. Test equipment such as the Foam Expert (SITA Messtechnik GmbH) or Dynamic Foam Analyzer DFA 100 (Kriiss) can be BASF SE

13 used for that purpose. In addition, the foam can be evaluated by the means of rheological measurements in a viscosimeter.

Preferably, the personal care composition, cleaning composition, nutrition formulation, pharmaceutical formulation, or crop formulation of the fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters derived from Macauba oil leave a more caring feeling after use on hair and/or skin than compositions comprising fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters derived from other oil sources. This can be investigated, for example, by a test panel by reference to subjective skin feel (smoothness, dryness etc.) or haptics and feel of the treated hair. Mechanical measurement methods, such as combability of the hair or hair breakage, can also be used.

Preferred embodiments regarding the composition comprising fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters derived from Macauba palm oil or the composition comprising fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters obtainable by a process comprising the steps of amidation and reaction with chloroacetic acid, as well as the use thereof for the production of fatty acid amide compositions, alkoxylated fatty acid ester compositions, specific fatty acid amides, and blends thereof, or specific alkoxylated fatty acid esters, the use thereof as surfactants in personal care compositions and/or cleaning compositions and these personal care composition and cleaning composition themselves are described hereinafter. It is to be understood that the preferred embodiments of the invention are preferred alone or in combination with each other.

It is a special advantage of the process of the present invention that it is more efficient and less energy intensive and thus has higher sustainability and better carbon footprint. Reason is that the Macauba oil has a lower melting point than for example usually used palm kernel oil. Hence, it has lower viscosities at comparable temperatures and thus can be process with lower energy demand at lower temperatures. Another reason is that the sustainability of the Macauba oil is higher than the substainability of oil from other oil sources such as coconut oil, palm oil, or palm kernel oil due to the less water intensive growing conditions, less need for space, higher productivity and higher robustness to allow for growing in less specialized conditions.

Another reason is that the lower melting point leads to lower free fatty acid contents. Free fatty acids need to be removed before transesterification as preferably used in the process of the present invention. Such a removal can be done either by chemical refinement, in which the free fatty acids are transformed into soaps and subsequently wash out with e.g. water, or by physical refinement, in which the free fatty acids are contacted with steam and are subsequently collected. Furthermore, the removed free fatty acids are at least in production again re-esterified and re-added to the feed stock. Hence, lower free fatty acid BASF SE

14 content needs to lower demand of energy and material, rendering the overall process more efficient and sustainable.

As indicated above, the present invention relates in one embodiment to a process of manufacturing a fatty acid amide composition or an alkoxylated fatty acid ester composition, the process comprising the step a) converting oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr into fatty acid amides or alkoxylated fatty acid esters.

In a preferred embodiment, the Macauba palm is Acrocomia hass/eri, Acrocomia totei, and/or Acrocomia acuieata, and in particular Acrocomia acuieata.

In a preferred embodiment, the oil is extracted from the palm pulp and/or the palm kernel.

In a preferred embodiment, the oil is extracted from the Macauba kernel, preferably wherein the Macauba palmis Acrocomia hass/eri, Acrocomia totei, and/or Acrocomia acuieata and the oil is extracted from more preferably Acrocomia hass/eri kernel, Acrocomia tote/kernel, and/or Acrocomia acuieata kernel, and in particular wherein the Macauba palmis Acrocomia acuieata and the oil is extracted from Acrocomia acuieata kernel.

In another preferred embodiment, the oil is extracted from the Macauba pulp, and in particular wherein the Macauba palmis Acrocomia acuieata and the oil is extracted from Acrocomia acuieata pulp.

In another preferred embodiment, the oil is extracted from the Macauba pulp and kernel, and in particular wherein the Macauba palmis Acrocomia acuieata and the oil is extracted from Acrocomia acuieata pulp and kernel.

In a preferred embodiment, the Macauba palmcan sufficiently grow under tropical and subtropical conditions.

In a preferred embodiment, the Macauba palmcan sufficiently grow in regions from the 30 ^th parallel north to the 28 ^th parallel south, preferably from the 25 ^th parallel north to the 25 ^th parallel south.

In a preferred embodiment, the Macauba palmsufficiently grows at a temperature range of 18 to 30 ° C, more preferably of 20 to 28 ° C. In this connection it is to be understood that the temperature range is the average temperature over one year. Hence, the Macauba palmis preferably less vulnerable to temperature fluctuation.

The term “sufficiently grow” as used herein denotes that the claimed oil yield is achievable under standard cultivation.

In addition, particularly oil palm need tropical conditions and preferred temperatures between about 24 to 28 ° C, monthly rainfalls of at least 100 mm/m ² , and a humidity between about 50 to 70%. These factors limit the possibility of a profitable cultivation.

In a preferred embodiment, the process provides a reduced water demand.

In a preferred embodiment, the process provides a reduction of the loss of biodiversity.

In a preferred embodiment, the process provides a reduction of loss of habitats for local tribes.

In a preferred embodiment, the process provides a reduction of deforestation.

In a preferred embodiment, the process provides an improved recovery of degraded areas and/or springs and watersheds. BASF SE

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In a preferred embodiment, the process provides an improved retention of moisture in the soil.

In this connection it is to be understood that the above-outlined reductions or improvements are compared to plants having an oil yield in tons per hectare per year of less than 6 t/ha/yr, preferably compared to oil palm.

In a preferred embodiment, the oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr is the crude oil, i.e. not further treated after the extraction from the Macauba palm.

In another preferred embodiment, the oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr is the filtered oil, i.e. wherein the crude oil is first filtered by any known in the art filtering systems and then used in the process. A suitable filtration process is e.g. press filtration.

In a preferred embodiment, the oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr is the crude oil, i.e. not further treated after the extraction from the Macauba palm, having a free fatty acids content of not more than 4 wt%.

In a preferred embodiment, in step a) the conversion is conducted under chemical or enzymatic conditions, preferably under chemical conditions.

In a preferred embodiment, step a) involves an amidation. Any suitable amidation method can be conducted. In a preferred embodiment, the condensation is conducted in the presence of an amine (e.g. mono-, di- or tri-amine), preferably wherein the amine is provided in excess. The reaction can further comprise the addition of a catalysts.

In a preferred embodiment, step a) involves a transesterification. Any suitable transesterification method can be conducted. Preferably, the transesterification is conducted in the presence of alkoxylated alcohol providing glycerol and the respective esters. The reaction can further comprise the addition of a catalysts. Preferably, the alkoxylated alcohol is provided in excess.

In a preferred embodiment, the process further comprises a hydrogenation, wherein the double bonds of the fatty acid moieties are completely or partially removed. If the process comprises a complete hydrogenation, the fatty acid composition does not comprise unsaturated moieties.

In a preferred embodiment, the Macauba palmhas an oil yield in tons per hectare per year in the range of at least 7 t/ha/yr, preferably at least 8 t/ha/yr.

In a preferred embodiment, the Macauba palmhas an oil yield in tons per hectare per year in the range of 6 to 30 t/ha/yr, preferably 7 to 20 t/ha/yr, more preferably of 8 to 15 t/ha/yr or of 8 to 12 t/ha/y r or of 8 to 11 t/ha/yr.

In a preferred embodiment, the process of the present invention produces a simple fatty acid ester. Another preferred embodiment of the present invention relates to the use of such simple fatty acid ester as an emollient in cosmetic compositions. BASF SE

16

I n a preferred embodiment, a fatty acid amide composition is manufactured, preferably wherein the fatty acid amide composition is selected from the group consisting of a fatty acid amido alkanolamide (fatty acid alkanolamide) composition, a fatty acid amidoalkylbetaine composition, and in step a) the oil is converted into the fatty acid amido alkanolamides (fatty acid alkanolamides), the fatty acid amidoalkylbetaines.

I n an especially preferred embodiment, a fatty acid amide composition is manufactured, preferably wherein the fatty acid amide composition is selected from the group consisting of a fatty acid amido alkanolamide (fatty acid alkanolamide) composition and a fatty acid amidoalkylbetaine composition and in step a) the oil is converted into the fatty acid amido alkanolamides (fatty acid alkanolamides) or the fatty acid amidoalkylbetaines.

Suitable fatty acid amido al kanolamides (fatty acid alkanolamides) can be expressed by the general formula (I)

R-CO-NR^ ² (I), wherein R is saturated or unsaturated C ₄ -C ₂₄ -a I kyl , preferably C ₆ -C ₂₀ -al kyl , R ¹ is H or C _r C ₈ - hydroxyalkyl, preferably H or C ₁ -C ₄ -hydroxyalkyl, and R ² is H or Cj-Cg-hydroxyalkyl preferably H or Cj-C^-hydroxyalkyL

I n a preferred embodiment, the fatty acid amido alkanolamides (fatty acid alkanolamides) can be expressed by the general formula (I)

R-CO-NR^ ² (I), wherein R is saturated or unsaturated C ₄ -C ₂₄ -a I kyl , preferably C ₆ -C ₂₀ -al kyl , R ¹ is H and R ² is H or Cj-Cg-hydroxyalkyl preferably H or Cj-C^-hydroxyalkyL I NCI Cocamide M EA and INCI Lauramide MEA may be named in this connection.

I n another preferred embodiment, the fatty acid amido alkanolamides (fatty acid alkanolamides) can be expressed by the general formula (I)

R-CO-NR^ ² (I), wherein R is saturated or unsaturated C ₄ -C ₂₄ -a I kyl , preferably C ₆ -C ₂₀ -al kyl , R ¹ is Cj-Cg- hydroxyalkyl, preferably H or C ₁ -C ₄ -hydroxyalkyl, and R ² is Cj-Cg-hydroxyalkyl preferably H or C ₁ -C ₄ -hydroxyalkyl. Cocamide COD (INCI Cocamide DEA) and INCI Lauramide DEA may be named in this connection.

I n a preferred embodiment, the fatty acid amido alkanolamide (fatty acid alkanolamide) is selected from the group consisting of fatty acid amido monoethanolamide and fatty acid amido diethanolamide.

Fatty acid amido alkanolamides (fatty acid alkanolamides) are accessible via any suitable known in the art method.

Suitable fatty acid amidoalkylbetaines can be expressed by the general formula (I I) wherein R ⁹ is saturated or unsaturated C ₄ -C ₂₄ -a I kyl , preferably C ₆ -C ₂₀ -al kyl and n is an integer of 1 to 10, preferably of 2 to 4. BASF SE

17

In a preferred embodiment, the fatty acid amidoalkylbetaines is a fatty acid amidopropylbetaine. INCI Cocamidopropyl Betaine, INCI Lauramidopropyl Betaine, and Dehyton PK45 may be named in this connection. Fatty acid amidoalkylbetaines are accessible via any suitable known in the art method.

In a preferred embodiment, the fatty acid amide composition provided in step a) comprises at least 40 wt.-%, based on the total weight of the fatty acid amide composition, of C ₄ -C ₂₂ fatty acid amides, preferably C ₆ -C ₂₀ fatty acid amides, more preferably C ₈ -C ₁₈ fatty acid amides, even more preferably C ₈ -C ₁₆ fatty acid amides or C ₁₆ -C ₁₈ fatty acid amides, and in particular C ₁₀ -C ₁₆ fatty acid amides or C ₁₂ -C ₁₄ fatty amides.

In a preferred embodiment, the fatty acid amide composition provided in step a) comprises

1 to 20 of wt.-% of a C ₈ fatty acid amide,

1 to 8 of wt.-% of a C ₁₀ fatty acid amide,

30 to 48 wt.-% of a C ₁₂ fatty acid amide,

5 to 15 wt.-% of a C ₁₄ fatty acid amide,

4 to 13 wt.-% of a C ₁₆ fatty acid amide,

15 to 42 wt.-% of a C ₁₈ fatty acid amide, and

0 to 5 wt.-% of a C ₂₀ fatty acid amide, each based on the total weight of the fatty acid amide composition. Said fatty acid amide composition is preferably obtained from oil extracted from Macauba kernel. In a preferred embodiment, the fatty acid amide composition provided in step a) comprises

3 to 7 wt.-%, preferably 4 to 6 wt.-%, of a C ₈ fatty acid amide,

2 to 6 wt.-%, preferably 3 to 5 wt.-%, of a C ₁₀ fatty acid amide,

36 to 46 wt.-%, preferably 38 to 42 wt.-%, of a C ₁₂ fatty acid amide,

6 to 13 wt.-%, preferably 8 to 11 wt.-%, of a C ₁₄ fatty acid amide,

5 to 11 wt.-%, preferably 6 to 9 wt.-%, of a C ₁₆ fatty acid amide,

25 to 40 wt.-%, preferably 30 to 38 wt.-% of a C ₁₈ fatty acid amide, and

0 to 4 wt.-%, preferably 0 to 3 wt.-%, of a C ₂₀ fatty acid amide, each based on the total weight of the fatty acid amide composition. Said fatty acid amide composition is preferably obtained from oil extracted from Macauba kernel.

In a preferred embodiment, the fatty acid amide composition provided in step a) comprises 0 to 5 wt.-%, preferably 0 to 3 wt.-%, and in particular 0 to 2 wt.-%, of a C ₁₀ fatty acid amide,

0 to 6 wt.-%, preferably 0 to 5 wt.-%, and in particular 1 to 4 wt.-%, of a C ₁₂ fatty acid amide,

0 to 6 wt.-%, preferably 0 to 5 wt.-%, and in particular 1 to 4 wt.-%, of a C ₁₄ fatty acid amide,

10 to 35 wt.-%, preferably 13 to 32 wt.-%, and in particular 15 to 30 wt.-%, of a C ₁₆ fatty acid amide,

55 to 85 wt.-%, preferably 60 to 80 wt.-%, and in particular 65 to 75 wt.-%, of a C ₁₈ fatty acid amide,

0 to 4 wt.-%, preferably 0 to 3 wt.-%, and in particular 0 to 2 wt.-%, of a C ₂₀ fatty acid amide, each based on the total weight of the fatty acid amide composition. Said fatty acid amide composition is preferably obtained from oil extracted from Macauba pulp.

In a more preferred embodiment, the fatty acid amide composition comprises 0.1 to 10 wt.-% of a C ₆ fatty acid amide,

1 to 20 wt.-% of a C ₈ fatty acid amide,

1 to 8 wt.-% of a C ₁₀ fatty acid amide, BASF SE

18

30 to 48 wt.-% of a C ₁₂ fatty acid amide,

5 to 15 wt.-% of a C ₁₄ fatty acid amide,

4 to 13 wt.-% of a C ₁₆ fatty acid amide,

15 to 42 wt.-% of a C ₁₈ fatty acid amide, and

0 to 5 wt.-% of a C ₂₀ fatty acid amide, each based on the total weight of the fatty acid amide composition.

In an even more preferred embodiment, the fatty acid amide composition comprises 0.2 to 4 wt.-%, preferably 0.4 to 1.5 wt.-% of a C ₆ fatty acid amide, 3 to 7 wt.-%, preferably 4 to 6 wt.-%, of a C ₈ fatty acid amide,

2 to 6 wt.-%, preferably 3 to 5 wt.-%, of a C ₁₀ fatty acid amide,

36 to 46 wt.-%, preferably 38 to 42 wt.-%, of a C ₁₂ fatty acid amide,

6 to 13 wt.-%, preferably 8 to 11 wt.-%, of a C ₁₄ fatty acid amide,

5 to 11 wt.-%, preferably 6 to 9 wt.-%, of a C ₁₆ fatty acid amide,

25 to 40 wt.-%, preferably 30 to 38 wt.-% of a C ₁₈ fatty acid amide, and

0 to 4 wt.-%, preferably 0 to 3 wt.-%, of a C ₂₀ fatty acid amide, each based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition provided in step a) comprises at least 85 wt.-% based on the total weight of the fatty acid amide composition, of C ₄ -C ₂₂ fatty acid amides, preferably C ₁₀ -C ₂₂ fatty acid amides, more preferably C ₁₂ -C ₂₀ fatty acid amides, even more preferably C ₁₂ -C ₂₀ fatty acid amides, and in particular C ₁₂ -C ₁₈ fatty acid amides.

In a preferred embodiment, the fatty acid amide composition provided in step a) comprises at least 10 wt.-% of C ₁₆ fatty acid amides and at least 65 wt.-% of C ₁₈ fatty acid amides, each based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition provided in step a) comprises 10 to 40 wt.-% of C ₁₆ fatty acid amides and 60 to 90 wt.-% of C ₁₈ fatty acid amides, each based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition provided in step a) comprises at least 30 wt.-%, preferably at least 35 wt.-%, and in particular at least 40 wt.-%, based on the total weight of the fatty acid amide composition, of C _12-14 fatty acid amides.

In a preferred embodiment, the fatty acid amide composition provided in step a) comprises at least 2 wt.-% of C ₁₀ fatty acid amides, at least 25 wt.-% of C ₁₂ fatty acid amides, at least 5 wt.-% of C ₁₄ fatty acid amides, and at least 4 wt.-% of C ₁₆ fatty acid amides, each based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition provided in step a) comprises 0 to 5 wt.-% of C ₈ fatty acid amides, 2 to 6 wt.-% of C ₁₀ fatty acid amides, 25 to 45 wt.-% of C ₁₂ fatty acid amides, 5 to 20 wt.-% of C ₁₄ fatty acid amides, and 4 to 15 wt.-% of C ₁₆ fatty acid amides, each based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition comprises 0.2 to 4 wt.-% of C ₆ fatty acid amides, 3 to 7 wt.-% of C ₈ fatty acid amides, 2 to 6 wt.-% of C ₁₀ fatty acid amides, 35 to 45 wt.-% of C ₁₂ fatty acid amides, 5 to 13 wt.-% of C ₁₄ fatty acid amides, and 4 to 10 wt.-% of C ₁₆ fatty acid amides, each based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition comprises at least 90 wt.-% of C ₆ fatty acid amides, based on the total weight of the fatty acid amide composition. BASF SE

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In a preferred embodiment, the fatty acid amide composition comprises at least 95 wt.-%, based on the total weight of the fatty acid amide composition, of C ₁₂ _i ₄ fatty acid amides, and further comprises 36 to 46 wt.-%, preferably 38 to 42 wt.-%, of a C ₁₂ fatty acid amide, and 6 to 13 wt.-%, preferably 8 to 11 wt.-%, of a C ₁₄ fatty acid amide, each based on the total weight of the fatty acid amide composition.

In an especially preferred embodiment of the invention, the fatty acid amide composition provided in step a) additionally comprises glycerol.

In a preferred embodiment, the fatty acid amide composition provided in step a) is a fatty acid amido alkanolamide (fatty acid alkanolamide) composition, preferably selected from the group consisting of fatty acid amido monoalkylamide (fatty acid monoalkylamide) composition and fatty acid amido dialkylamide (fatty acid dialkylamide) composition, more preferably selected from the group consisting of fatty acid amido monoethanolamide (fatty acid monoethanolamide) composition and fatty acid amido diethanolamide (fatty acid diethanolamide) composition.

In another preferred embodiment, the fatty acid amide composition provided in step a) is a fatty acid amidoalkylbetaine, preferably a fatty acid amidopropylbetaine composition.

In a preferred embodiment, step a) further comprises the step a.i) blending the oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr, preferably of at least 7 t/ha/yr, more preferably of at least 8 t/ha/yr, with an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr, preferably of less than 5 t/ha/yr, more preferably of less than 4.5 t/ha/yr. In a preferred embodiment, the oil extracted from a Macauba palm having an oil yield in tons per hectare per year of 6 to 30 t/ha/yr, more preferably 7 to 20 t/ha/yr, even more preferably of 8 to 15 t/ha/yr or of 8 to 12 t/ha/y r or of 8 to 11 t/ha/yr, is blended with oil extracted from a plant having an oil yield in tons per hectare per year of 0.1 to less than 6 t/ha/yr, preferably of 0.3 to 5 t/ha/yr, more preferably of 0.5 to 4.5 t/ha/yr. In a preferred embodiment, the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from coconut oil (CNO), palm oil (PO), and/or palm kernel oil (PKO). In another preferred embodiment, the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from soy oil, sunflower oil, olive oil, and/or rapeseed oil.

In yet another preferred embodiment the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from coconut oil (CNO), palm oil (PO), palm kernel oil (PKO), soy oil, sunflower oil, olive oil, and/or rapeseed oil.

In a preferred embodiment, the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from coconut oil (CNO), and/or palm kernel oil (PKO).

In a preferred embodiment, the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from palm oil (PO) and/or palm kernel oil (PKO).

In a preferred embodiment, step a) further comprises the step BASF SE

20 a.i) blending the oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr, which is derived from Macauba kernel, with an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr, which is derived from palm kernel oil (PKO).

In a preferred embodiment, step a) further comprises the step a.i) blending the oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr, which is derived from Macauba kernel, with an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr, which is derived from coconut oil (CNO).

In a preferred embodiment, step a) further comprises the step a.i) blending the oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr, which is derived from Macauba kernel, with an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr, which is derived from palm kernel oil (PKO) and coconut oil (CNO).

In a preferred embodiment, step a) further comprises the step a.i) blending the oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr, which is derived from Macauba pulp, with an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr, which is derived from palm oil (PO).

In a preferred embodiment, the fatty acid amide composition obtained in step a) is blended with a fatty acid amide composition obtained from an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr (preferably of 0.1 to less than 6 t/ha/yr, preferably of 0.3 to 5 t/ha/yr, more preferably of 0.5 to 4.5 t/ha/yr) and a subsequent conversion into the respective fatty acid amide composition. In a preferred embodiment, the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from coconut oil (CNO), palm oil (PO), and/or palm kernel oil (PKO). In another preferred embodiment, the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from soy oil, sunflower oil, olive oil, and/or rapeseed oil.

In yet another preferred embodiment the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from coconut oil (CNO), palm oil (PO), palm kernel oil (PKO), soy oil, sunflower oil, olive oil, and/or rapeseed oil.

In a preferred embodiment, the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from coconut oil (CNO), and/or palm kernel oil (PKO).

In a preferred embodiment, the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from palm oil (PO) and/or palm kernel oil (PKO).

In a preferred embodiment, the fatty acid amide composition obtained in step a), which is obtained from an oil extracted from a Macauba palmhaving an oil yield in tons per hectare per year of at least 6 t/ha/y, which is derived from Macauba kernel, is blended with a fatty acid amide composition obtained from an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr, which is derived from palm kernel oil (PKO). BASF SE

In a preferred embodiment, the fatty acid amide composition obtained in step a), which is obtained from an oil extracted from a Macauba palmhaving an oil yield in tons per hectare per year of at least 6 t/ha/y, which is derived from Macauba kernel, is blended with a fatty acid amide composition obtained from an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/y r, which is derived from coconut oil (CNO).

In a preferred embodiment, the fatty acid amide composition obtained in step a), which is obtained from an oil extracted from a Macauba palmhaving an oil yield in tons per hectare per year of at least 6 t/ha/y, which is derived from Macauba kernel, is blended with a fatty acid amide composition obtained from an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/y r, which is derived from palm kernel oil (PKO) and coconut oil (CNO).

In a preferred embodiment, the fatty acid amide composition obtained in step a), which is obtained from an oil extracted from a Macauba palmhaving an oil yield in tons per hectare per year of at least 6 t/ha/y, which is derived from Macauba pulp, is blended with a fatty acid amide composition obtained from an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/y r, which is derived from palm oil (PO).

In a preferred embodiment, an alkoxylated fatty acid ester composition is manufactured.

Suitable alkoxylated fatty acid esters can be expressed by the general formula (III) wherein R is saturated or unsaturated C ₄ -C ₂₄ -a I kyl , preferably C ₆ -C ₂₀ -al kyl , and n is an average number of 1 to 12, preferably of 3 to 10. In this connection it is to be understood that the star in formula (III) denotes a stereocenter. PEG-7 Glyceryl Cocoate may be named in this connection.

Suitable alkoxylated fatty acid esters can be also be expressed by the general formula (IV) R-CO-(OCH ₂ ) _m -R ³ (IV), wherein R is saturated or unsaturated C ₄ -C ₂₄ -a I kyl , preferably C ₆ -C ₂₀ -al kyl , or saturated or unsaturated C ₄ -C ₂₄ -alkoxyl, preferably C ₆ -C ₂₀ -alkoxyl, m is an average number of 1 to 12, preferably of 3 to 10, and R ³ is Cj-Cg-alkyl or Cj-Cg-hydroxyalkyl.

Alkoxylated fatty acid esters are accessible via any suitable known in the art method.

In a preferred embodiment, the alkoxylated fatty acid ester composition provided in step a) comprises at least 40 wt.-%, based on the total weight of the alkoxylated fatty acid ester composition, of C ₄ -C ₂₂ alkoxylated fatty acid esters, preferably C ₆ -C ₂₀ alkoxylated fatty acid esters, more preferably C ₈ -C ₁₈ alkoxylated fatty acid esters, even more preferably C ₈ -C ₁₆ alkoxylated fatty acid esters or C ₁₆ -C ₁₈ alkoxylated fatty acid esters, and in particular C ₁₀ -C ₁₆ alkoxylated fatty acid esters or C ₁₂ -C ₁₄ - alkoxylated fatty acid esters. BASF SE

22

In a preferred embodiment, the alkoxylated fatty acid ester composition provided in step a) comprises

1 to 20 of wt.-% of a C ₈ alkoxylated fatty acid ester,

1 to 8 of wt.-% of a C ₁₀ alkoxylated fatty acid ester,

30 to 48 wt.-% of a C ₁₂ alkoxylated fatty acid ester,

5 to 15 wt.-% of a C ₁₄ alkoxylated fatty acid ester,

4 to 13 wt.-% of a C ₁₆ alkoxylated fatty acid ester,

15 to 42 wt.-% of a C ₁₈ alkoxylated fatty acid ester, and

0 to 5 wt.-% of a C ₂₀ alkoxylated fatty acid ester, each based on the total weight of the alkoxylated fatty acid ester composition. Said alkoxylated fatty acid ester composition is preferably obtained from oil extracted from Macauba kernel.

In a preferred embodiment, the alkoxylated fatty acid ester composition provided in step a) comprises

3 to 7 wt.-%, preferably 4 to 6 wt.-%, of a C ₈ alkoxylated fatty acid ester,

2 to 6 wt.-%, preferably 3 to 5 wt.-%, of a C ₁₀ alkoxylated fatty acid ester,

36 to 46 wt.-%, preferably 38 to 42 wt.-%, of a C ₁₂ alkoxylated fatty acid ester,

6 to 13 wt.-%, preferably 8 to 11 wt.-%, of a C ₁₄ alkoxylated fatty acid ester,

5 to 11 wt.-%, preferably 6 to 9 wt.-%, of a C ₁₆ alkoxylated fatty acid ester,

25 to 40 wt.-%, preferably 30 to 38 wt.-% of a C ₁₈ alkoxylated fatty acid ester, and

0 to 4 wt.-%, preferably 0 to 3 wt.-%, of a C ₂₀ alkoxylated fatty acid ester, each based on the total weight of the alkoxylated fatty acid ester composition. Said alkoxylated fatty acid ester composition is preferably obtained from oil extracted from Macauba kernel.

In a preferred embodiment, the alkoxylated fatty acid ester composition provided in step a) comprises

0 to 5 wt.-%, preferably 0 to 3 wt.-%, and in particular 0 to 2 wt.-%, of a C ₁₀ alkoxylated fatty acid ester,

0 to 6 wt.-%, preferably 0 to 5 wt.-%, and in particular 1 to 4 wt.-%, of a C ₁₂ alkoxylated fatty acid ester,

0 to 6 wt.-%, preferably 0 to 5 wt.-%, and in particular 1 to 4 wt.-%, of a C ₁₄ alkoxylated fatty acid ester,

10 to 35 wt.-%, preferably 13 to 32 wt.-%, and in particular 15 to 30 wt.-%, of a C ₁₆ alkoxylated fatty acid ester,

55 to 85 wt.-%, preferably 60 to 80 wt.-%, and in particular 65 to 75 wt.-%, of a C ₁₈ alkoxylated fatty acid ester,

0 to 4 wt.-%, preferably 0 to 3 wt.-%, and in particular 0 to 2 wt.-%, of a C ₂₀ alkoxylated fatty acid ester, each based on the total weight of the alkoxylated fatty acid ester composition. Said alkoxylated fatty acid ester composition is preferably obtained from oil extracted from Macauba pulp.

In a more preferred embodiment, the alkoxylated fatty acid ester composition comprises 0.1 to 10 wt.-% of a C ₆ alkoxylated fatty acid ester,

1 to 20 wt.-% of a C ₈ alkoxylated fatty acid ester,

1 to 8 wt.-% of a C ₁₀ alkoxylated fatty acid ester, BASF SE

23

30 to 48 wt.-% of a C ₁₂ alkoxylated fatty acid ester,

5 to 15 wt.-% of a C ₁₄ alkoxylated fatty acid ester,

4 to 13 wt.-% of a C ₁₆ alkoxylated fatty acid ester,

15 to 42 wt.-% of a C ₁₈ alkoxylated fatty acid ester, and

0 to 5 wt.-% of a C ₂₀ alkoxylated fatty acid ester, each based on the total weight of the alkoxylated fatty acid ester composition.

In an even more preferred embodiment, the alkoxylated fatty acid ester composition comprises

0.2 to 4 wt.-%, preferably 0.4 to 1.5 wt.-% of a C ₆ alkoxylated fatty acid ester,

3 to 7 wt.-%, preferably 4 to 6 wt.-%, of a C ₈ alkoxylated fatty acid ester,

2 to 6 wt.-%, preferably 3 to 5 wt.-%, of a C ₁₀ alkoxylated fatty acid ester,

36 to 46 wt.-%, preferably 38 to 42 wt.-%, of a C ₁₂ alkoxylated fatty acid ester,

6 to 13 wt.-%, preferably 8 to 11 wt.-%, of a C ₁₄ alkoxylated fatty acid ester,

5 to 11 wt.-%, preferably 6 to 9 wt.-%, of a C ₁₆ alkoxylated fatty acid ester,

25 to 40 wt.-%, preferably 30 to 38 wt.-% of a C ₁₈ alkoxylated fatty acid ester, and 0 to 4 wt.-%, preferably 0 to 3 wt.-%, of a C ₂₀ alkoxylated fatty acid ester, each based on the total weight of the alkoxylated fatty acid ester composition.

In a preferred embodiment, the alkoxylated fatty acid ester composition provided in step a) comprises at least 85 wt.-% based on the total weight of the alkoxylated fatty acid ester composition, of C ₄ -C ₂₂ alkoxylated fatty acid esters, preferably C ₁₀ -C ₂₂ alkoxylated fatty acid esters, more preferably C ₁₂ -C ₂₀ alkoxylated fatty acid esters, even more preferably C ₁₂ -C ₂₀ alkoxylated fatty acid esters, and in particular C ₁₂ -C ₁₈ alkoxylated fatty acid esters.

In a preferred embodiment, the alkoxylated fatty acid ester composition provided in step a) comprises at least 10 wt.-% of C ₁₆ alkoxylated fatty acid esters and at least 65 wt.-% of C ₁₈ alkoxylated fatty acid esters, each based on the total weight of the alkoxylated fatty acid ester composition.

In a preferred embodiment, the alkoxylated fatty acid ester composition provided in step a) comprises 10 to 40 wt.-% of C ₁₆ alkoxylated fatty acid esters and 60 to 90 wt.-% of C ₁₈ alkoxylated fatty acid esters, each based on the total weight of the alkoxylated fatty acid ester composition.

In a preferred embodiment, the alkoxylated fatty acid ester composition provided in step a) comprises at least 30 wt.-%, preferably at least 35 wt.-%, and in particular at least 40 wt.-%, based on the total weight of the alkoxylated fatty acid ester composition, of C _12-14 alkoxylated fatty acid esters.

In a preferred embodiment, the alkoxylated fatty acid ester composition provided in step a) comprises at least 2 wt.-% of C ₁₀ alkoxylated fatty acid esters, at least 25 wt.-% of C ₁₂ alkoxylated fatty acid esters, at least 5 wt.-% of C ₁₄ alkoxylated fatty acid esters, and at least 4 wt.-% of C ₁₆ alkoxylated fatty acid esters, each based on the total weight of the alkoxylated fatty acid ester composition.

In a preferred embodiment, the alkoxylated fatty acid ester composition provided in step a) comprises 0 to 5 wt.-% of C ₈ alkoxylated fatty acid esters, 2 to 6 wt.-% of C ₁₀ alkoxylated fatty acid esters, 25 to 45 wt.-% of C ₁₂ alkoxylated fatty acid esters, 5 to 20 wt.-% of C ₁₄ alkoxylated fatty acid esters, and 4 to 15 wt.-% of C ₁₆ alkoxylated fatty acid esters, each based on the total weight of the alkoxylated fatty acid ester composition. BASF SE

24

In a preferred embodiment, step a) further comprises the step a.i) blending the oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr, preferably of at least 7 t/ha/yr, more preferably of at least 8 t/ha/yr, with an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr, preferably of less than 5 t/ha/yr, more preferably of less than 4.5 t/ha/yr. In a preferred embodiment, the oil extracted from a Macauba palm having an oil yield in tons per hectare per year of 6 to 30 t/ha/yr, more preferably 7 to 20 t/ha/yr, even more preferably of 8 to 15 t/ha/yr or of 8 to 12 t/ha/y r or of 8 to 11 t/ha/yr, is blended with oil extracted from a plant having an oil yield in tons per hectare per year of 0.1 to less than 6 t/ha/yr, preferably of 0.3 to 5 t/ha/yr, more preferably of 0.5 to 4.5 t/ha/yr. In a preferred embodiment, the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from coconut oil (CNO), palm oil (PO), and/or palm kernel oil (PKO). In another preferred embodiment, the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from soy oil, sunflower oil, olive oil, and/or rapeseed oil.

In yet another preferred embodiment the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from coconut oil (CNO), palm oil (PO), palm kernel oil (PKO), soy oil, sunflower oil, olive oil, and/or rapeseed oil.

In a preferred embodiment, the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from coconut oil (CNO), and/or palm kernel oil (PKO).

In a preferred embodiment, the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from palm oil (PO) and/or palm kernel oil (PKO).

In a preferred embodiment, step a) further comprises the step a.i) blending the oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr, which is derived from Macauba kernel, with an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr, which is derived from palm kernel oil (PKO).

In a preferred embodiment, step a) further comprises the step a.i) blending the oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr, which is derived from Macauba kernel, with an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr, which is derived from coconut oil (CNO).

In a preferred embodiment, step a) further comprises the step a.i) blending the oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr, which is derived from Macauba kernel, with an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr, which is derived from palm kernel oil (PKO) and coconut oil (CNO).

In a preferred embodiment, step a) further comprises the step a.i) blending the oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr, which is derived from Macauba pulp, with an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr, which is derived from palm oil (PO). BASF SE

25

In a preferred embodiment, alkoxylated fatty acid ester composition obtained in step a) is blended with a alkoxylated fatty acid ester composition obtained from an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr (preferably of 0.1 to less than 6 t/ha/yr, preferably of 0.3 to 5 t/ha/yr, more preferably of 0.5 to 4.5 t/ha/yr) and a subsequent conversion into the respective alkoxylated fatty acid ester composition. In a preferred embodiment, the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from coconut oil (CNO), palm oil (PO), and/or palm kernel oil (PKO). In another preferred embodiment, the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from soy oil, sunflower oil, olive oil, and/or rapeseed oil.

In yet another preferred embodiment the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from coconut oil (CNO), palm oil (PO), palm kernel oil (PKO), soy oil, sunflower oil, olive oil, and/or rapeseed oil.

In a preferred embodiment, the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from coconut oil (CNO), and/or palm kernel oil (PKO).

In a preferred embodiment, the oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr is derived from palm oil (PO) and/or palm kernel oil (PKO).

In a preferred embodiment, the alkoxylated fatty acid ester composition obtained in step a), which is obtained from an oil extracted from a Macauba palmhaving an oil yield in tons per hectare per year of at least 6 t/ha/y, which is derived from Macauba kernel, is blended with a alkoxylated fatty acid ester composition obtained from an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr, which is derived from palm kernel oil (PKO).

In a preferred embodiment, the alkoxylated fatty acid ester composition obtained in step a), which is obtained from an oil extracted from a Macauba palmhaving an oil yield in tons per hectare per year of at least 6 t/ha/y, which is derived from Macauba kernel, is blended with a alkoxylated fatty acid ester composition obtained from an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr, which is derived from coconut oil (CNO).

In a preferred embodiment, the alkoxylated fatty acid ester composition obtained in step a), which is obtained from an oil extracted from a Macauba palmhaving an oil yield in tons per hectare per year of at least 6 t/ha/y, which is derived from Macauba kernel, is blended with a alkoxylated fatty acid ester composition obtained from an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr, which is derived from palm kernel oil (PKO) and coconut oil (CNO).

In a preferred embodiment, the alkoxylated fatty acid ester composition obtained in step a), which is obtained from an oil extracted from a Macauba palmhaving an oil yield in tons per hectare per year of at least 6 t/ha/y, which is derived from Macauba pulp, is blended with a alkoxylated fatty acid ester composition obtained from an oil extracted from a plant having an oil yield in tons per hectare per year of less than 6 t/ha/yr, which is derived from palm oil (PO). BASF SE

26

As indicated above, the present invention further relates to a fatty acid amide composition obtained by the above-outlined process.

Suitable fatty acid amido alkanolamides (fatty acid alkanolamides) can be expressed by the general formula (I)

R-CO-NR^ ² (I), wherein R is saturated or unsaturated C ₄ -C ₂₄ -a I kyl , preferably C ₆ -C ₂₀ -al kyl , R ¹ is H or C C ₈ - hydroxyalkyl, preferably H or C ₁ -C ₄ -hydroxyalkyl, and R ² is H or Cj-Cg-hydroxyalkyl preferably H or Cj-CLphydroxyalkyl.

In a preferred embodiment, the fatty acid amido alkanolamides (fatty acid alkanolamides) have the general formula (I)

R-CO-NR^ ² (I), wherein R is linear, saturated or unsaturated C ₄ -C ₂₄ -al kyl , preferably C ₆ -C ₂₀ -a I ky I , R ¹ is H and R ² is H or Cj-Cg-hydroxyalkyl preferably H or Cj-CLphydroxyalkyl. INCI Cocamide MEA and INCI Lauramide MEA may be named in this connection.

In another preferred embodiment, the fatty acid amido alkanolamides (fatty acid alkanolamides) have the general formula (I)

R-CO-NR^ ² (I), wherein R is saturated or unsaturated C ₄ -C ₂₄ -a I kyl , preferably C ₆ -C ₂₀ -al kyl , R ¹ is Cj-Cg- hydroxyalkyl, preferably H or C ₁ -C ₄ -hydroxyalkyl, and R ² is Cj-Cg-hydroxyalkyl preferably H or C ₁ -C ₄ -hydroxyalkyl. Cocamide COD (INCI Cocamide DEA) and INCI Lauramide DEA may be named in this connection.

In a preferred embodiment, the fatty acid amido alkanolamide (fatty acid alkanolamide) is selected from the group consisting of fatty acid amido monoethanolamide (fatty acid monoethanolamide) and fatty acid amido diethanolamide (fatty acid diethanolamide).

Suitable fatty acid amidoalkylbetaines can be expressed by the general formula (II) wherein R ⁹ is saturated or unsaturated C ₄ -C ₂₄ -a I kyl , preferably C ₆ -C ₂₀ -al kyl and n is an integer of 1 to 10, preferably of 2 to 4.

In a preferred embodiment, the fatty acid amidoalkylbetaines is a fatty acid amidopropylbetaine. INCI Cocamidopropyl Betaine, INCI Lauramidopropyl Betaine, and Dehyton PK45 may be named in this connection.

In a preferred embodiment, the fatty acid amide composition is selected from the group consisting of fatty acid amido alkanolamide (fatty acid alkanolamide) composition and a fatty acid amidoalkylbetaine composition.

In a preferred embodiment, the fatty acid amide composition is a fatty acid amido alkanolamide (fatty acid alkanolamide) composition, preferably selected from the group consisting of fatty acid amido monoalkylamide (fatty acid monoalkylamide) composition and fatty acid amido dialkylamide (fatty acid dialkylamide) composition, more preferably selected from the group consisting of fatty acid amido monoethanolamide (fatty acid BASF SE

27 monoethanolamide) composition and fatty acid amido diethanolamide (fatty acid amido diethanolamide) composition.

In another preferred embodiment, the fatty acid amide composition is a fatty acid amidoalkylbetaine, preferably a fatty acid amidopropylbetaine composition.

In a preferred embodiment, the fatty acid amide composition comprises at least 40 wt.-%, based on the total weight of the fatty acid amide composition, of C ₄ -C ₂₂ fatty acid amides, preferably C ₆ -C ₂₀ fatty acid amides, more preferably C ₈ -C ₁₈ fatty acid amides, even more preferably C ₈ -C ₁₆ fatty acid amides or C ₁₆ -C ₁₈ fatty acid amides, and in particular C ₁₀ -C ₁₆ fatty acid amides.

In a preferred embodiment, the fatty acid amide composition comprises

1 to 20 of wt.-% of a C ₈ fatty acid amide,

1 to 8 of wt.-% of a C ₁₀ fatty acid amide,

30 to 48 wt.-% of a C ₁₂ fatty acid amide,

5 to 15 wt.-% of a C ₁₄ fatty acid amide,

4 to 13 wt.-% of a C ₁₆ fatty acid amide,

15 to 42 wt.-% of a C ₁₈ fatty acid amide, and

0 to 5 wt.-% of a C ₂₀ fatty acid amide, each based on the total weight of the fatty acid amide composition. Said fatty acid amide composition is preferably obtained from oil extracted from Macauba kernel.

In a preferred embodiment, the fatty acid amide composition comprises

3 to 7 wt.-%, preferably 4 to 6 wt.-%, of a C ₈ fatty acid amide,

2 to 6 wt.-%, preferably 3 to 5 wt.-%, of a C ₁₀ fatty acid amide,

36 to 46 wt.-%, preferably 38 to 42 wt.-%, of a C ₁₂ fatty acid amide,

6 to 13 wt.-%, preferably 8 to 11 wt.-%, of a C ₁₄ fatty acid amide,

5 to 11 wt.-%, preferably 6 to 9 wt.-%, of a C ₁₆ fatty acid amide,

25 to 40 wt.-%, preferably 30 to 38 wt.-% of a C ₁₈ fatty acid amide, and

0 to 4 wt.-%, preferably 0 to 3 wt.-%, of a C ₂₀ fatty acid amide, each based on the total weight of the fatty acid amide composition. Said fatty acid amide composition is preferably obtained from oil extracted from Macauba kernel.

In a preferred embodiment, the fatty acid amide composition comprises

0 to 5 wt.-%, preferably 0 to 3 wt.-%, and in particular 0 to 2 wt.-%, of a C ₁₀ fatty acid amide,

0 to 6 wt.-%, preferably 0 to 5 wt.-%, and in particular 1 to 4 wt.-%, of a C ₁₂ fatty acid amide,

0 to 6 wt.-%, preferably 0 to 5 wt.-%, and in particular 1 to 4 wt.-%, of a C ₁₄ fatty acid amide,

10 to 35 wt.-%, preferably 13 to 32 wt.-%, and in particular 15 to 30 wt.-%, of a C ₁₆ fatty acid amide,

55 to 85 wt.-%, preferably 60 to 80 wt.-%, and in particular 65 to 75 wt.-%, of a C ₁₈ fatty acid amide,

0 to 4 wt.-%, preferably 0 to 3 wt.-%, and in particular 0 to 2 wt.-%, of a C ₂₀ fatty acid amide, each based on the total weight of the fatty acid amide composition. Said fatty acid amide composition is preferably obtained from oil extracted from Macauba pulp.

In a more preferred embodiment, the fatty acid amide composition comprises 0.1 to 10 wt.-% of a C ₆ fatty acid amide, 1 to 20 wt.-% of a C ₈ fatty acid amide, 1 to 8 wt.-% of a C ₁₀ fatty acid amide, BASF SE

28

30 to 48 wt.-% of a C ₁₂ fatty acid amide,

5 to 15 wt.-% of a C ₁₄ fatty acid amide,

4 to 13 wt.-% of a C ₁₆ fatty acid amide,

15 to 42 wt.-% of a C ₁₈ fatty acid amide, and

0 to 5 wt.-% of a C ₂₀ fatty acid amide, each based on the total weight of the fatty acid amide composition.

In an even more preferred embodiment, the fatty acid amide composition comprises 0.2 to 4 wt.-%, preferably 0.4 to 1.5 wt.-% of a C ₆ fatty acid amide, 3 to 7 wt.-%, preferably 4 to 6 wt.-%, of a C ₈ fatty acid amide,

2 to 6 wt.-%, preferably 3 to 5 wt.-%, of a C ₁₀ fatty acid amide,

36 to 46 wt.-%, preferably 38 to 42 wt.-%, of a C ₁₂ fatty acid amide,

6 to 13 wt.-%, preferably 8 to 11 wt.-%, of a C ₁₄ fatty acid amide,

5 to 11 wt.-%, preferably 6 to 9 wt.-%, of a C ₁₆ fatty acid amide,

25 to 40 wt.-%, preferably 30 to 38 wt.-% of a C ₁₈ fatty acid amide, and

0 to 4 wt.-%, preferably 0 to 3 wt.-%, of a C ₂₀ fatty acid amide, each based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition comprises at least 85 wt.-% based on the total weight of the fatty acid amide composition, of C ₄ -C ₂₂ fatty acid amides, preferably C ₁₀ -C ₂₂ fatty acid amides, more preferably C ₁₂ -C ₂₀ fatty acid amides, even more preferably C ₁₂ -C ₂₀ fatty acid amides, and in particular C ₁₂ -C ₁₈ fatty acid amides.

In a preferred embodiment, the fatty acid amide composition comprises at least 10 wt.-% of C ₁₆ fatty acid amides and at least 75 wt.-% of C ₁₈ fatty acid amides, each based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition comprises 10 to 40 wt.-% of C ₁₆ fatty acid amides and 60 to 90 wt.-% of C ₁₈ fatty acid amides, each based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition comprises at least 30 wt.-%, preferably at least 35 wt.-%, and in particular at least 40 wt.-%, based on the total weight of the fatty acid amide composition, of C _12-14 fatty acid amides.

In a preferred embodiment, the fatty acid amide composition comprises at least 2 wt.-% of C ₁₀ fatty acid amides, at least 25 wt.-% of C ₁₂ fatty acid amides, at least 5 wt.-% of C ₁₄ fatty acid amides, and at least 4 wt.-% of C ₁₆ fatty acid amides, each based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition comprises 0 to 5 wt.-% of C ₈ fatty acid amides, 2 to 6 wt.-% of C ₁₀ fatty acid amides, 25 to 45 wt.-% of C ₁₂ fatty acid amides, 5 to 20 wt.-% of C ₁₄ fatty acid amides, and 4 to 15 wt.-% of C ₁₆ fatty acid amides, each based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition comprises 0.2 to 4 wt.-% of C ₆ fatty acid amides, 3 to 7 wt.-% of C ₈ fatty acid amides, 2 to 6 wt.-% of C ₁₀ fatty acid amides, 35 to 45 wt.-% of C ₁₂ fatty acid amides, 5 to 13 wt.-% of C ₁₄ fatty acid amides, and 4 to 10 wt.-% of C ₁₆ fatty acid amides, each based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition comprises at least 90 wt.-% of C ₆ fatty acid amides, based on the total weight of the fatty acid amide composition. BASF SE

29

In a preferred embodiment, the fatty acid amide composition comprises at least 95 wt.-%, based on the total weight of the fatty acid amide composition, of C ₁₂ _i ₄ fatty acid amides, and further comprises 36 to 46 wt.-%, preferably 38 to 42 wt.-%, of a C ₁₂ fatty acid amide, and 6 to 13 wt.-%, preferably 8 to 11 wt.-%, of a C ₁₄ fatty acid amide, each based on the total weight of the fatty acid amide composition.

As indicated above, the present invention further relates to an alkoxylated fatty acid ester composition obtained by the above-outlined process.

Suitable alkoxylated fatty acid esters can be expressed by the general formula (III) wherein R is saturated or unsaturated C ₄ -C ₂₄ -a I kyl , preferably C ₆ -C ₂₀ -al kyl , and n is an average number of 1 to 12, preferably of 3 to 10. In this connection it is to be understood that the star in formula (III) denotes a stereocenter. PEG-7 Glyceryl Cocoate may be named in this connection.

Suitable alkoxylated fatty acid esters can be also be expressed by the general formula (IV) R-CO-(OCH ₂ ) _m -R ³ (IV), wherein R is saturated or unsaturated C ₄ -C ₂₄ -a I kyl , preferably C ₆ -C ₂₀ -al kyl , or saturated or unsaturated C ₄ -C ₂₄ -alkoxyl, preferably C ₆ -C ₂₀ -alkoxyl, m is an average number of 1 to 12, preferably of 3 to 10, and R ³ is Cj-Cg-alkyl or Cj-Cg-hydroxyalkyl.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises at least 40 wt.-%, based on the total weight of the alkoxylated fatty acid ester composition, of C ₄ -C ₂₂ alkoxylated fatty acid esters, preferably C ₆ -C ₂₀ alkoxylated fatty acid esters, more preferably C ₈ -C ₁₈ alkoxylated fatty acid esters, even more preferably C ₈ -C ₁₆ alkoxylated fatty acid esters or C ₁₆ -C ₁₈ alkoxylated fatty acid esters, and in particular C ₁₀ -C ₁₆ alkoxylated fatty acid esters or C ₁₂ -C ₁₄ - alkoxylated fatty acid esters.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises

1 to 20 of wt.-% of a C ₈ alkoxylated fatty acid ester,

1 to 8 of wt.-% of a C ₁₀ alkoxylated fatty acid ester,

30 to 48 wt.-% of a C ₁₂ alkoxylated fatty acid ester,

5 to 15 wt.-% of a C ₁₄ alkoxylated fatty acid ester,

4 to 13 wt.-% of a C ₁₆ alkoxylated fatty acid ester,

15 to 42 wt.-% of a C ₁₈ alkoxylated fatty acid ester, and

0 to 5 wt.-% of a C ₂₀ alkoxylated fatty acid ester, each based on the total weight of the alkoxylated fatty acid ester composition. Said alkoxylated fatty acid ester composition is preferably obtained from oil extracted from Macauba kernel. BASF SE

30

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises

3 to 7 wt.-%, preferably 4 to 6 wt.-%, of a C ₈ alkoxylated fatty acid ester,

2 to 6 wt.-%, preferably 3 to 5 wt.-%, of a C ₁₀ alkoxylated fatty acid ester,

36 to 46 wt.-%, preferably 38 to 42 wt.-%, of a C ₁₂ alkoxylated fatty acid ester,

6 to 13 wt.-%, preferably 8 to 11 wt.-%, of a C ₁₄ alkoxylated fatty acid ester,

5 to 11 wt.-%, preferably 6 to 9 wt.-%, of a C ₁₆ alkoxylated fatty acid ester,

25 to 40 wt.-%, preferably 30 to 38 wt.-% of a C ₁₈ alkoxylated fatty acid ester, and

0 to 4 wt.-%, preferably 0 to 3 wt.-%, of a C ₂₀ alkoxylated fatty acid ester, each based on the total weight of the alkoxylated fatty acid ester composition. Said alkoxylated fatty acid ester composition is preferably obtained from oil extracted from Macauba kernel.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises

0 to 5 wt.-%, preferably 0 to 3 wt.-%, and in particular 0 to 2 wt.-%, of a C ₁₀ alkoxylated fatty acid ester,

0 to 6 wt.-%, preferably 0 to 5 wt.-%, and in particular 1 to 4 wt.-%, of a C ₁₂ alkoxylated fatty acid ester,

0 to 6 wt.-%, preferably 0 to 5 wt.-%, and in particular 1 to 4 wt.-%, of a C ₁₄ alkoxylated fatty acid ester,

10 to 35 wt.-%, preferably 13 to 32 wt.-%, and in particular 15 to 30 wt.-%, of a C ₁₆ alkoxylated fatty acid ester,

55 to 85 wt.-%, preferably 60 to 80 wt.-%, and in particular 65 to 75 wt.-%, of a C ₁₈ alkoxylated fatty acid ester,

0 to 4 wt.-%, preferably 0 to 3 wt.-%, and in particular 0 to 2 wt.-%, of a C ₂₀ alkoxylated fatty acid ester, each based on the total weight of the alkoxylated fatty acid ester composition. Said alkoxylated fatty acid ester composition is preferably obtained from oil extracted from Macauba pulp.

In a more preferred embodiment, the alkoxylated fatty acid ester composition comprises 0.1 to 10 wt.-% of a C ₆ alkoxylated fatty acid ester,

1 to 20 wt.-% of a C ₈ alkoxylated fatty acid ester,

1 to 8 wt.-% of a C ₁₀ alkoxylated fatty acid ester,

30 to 48 wt.-% of a C ₁₂ alkoxylated fatty acid ester,

5 to 15 wt.-% of a C ₁₄ alkoxylated fatty acid ester,

4 to 13 wt.-% of a C ₁₆ alkoxylated fatty acid ester,

15 to 42 wt.-% of a C ₁₈ alkoxylated fatty acid ester, and

0 to 5 wt.-% of a C ₂₀ alkoxylated fatty acid ester, each based on the total weight of the alkoxylated fatty acid ester composition.

In an even more preferred embodiment, the alkoxylated fatty acid ester composition comprises

0.2 to 4 wt.-%, preferably 0.4 to 1.5 wt.-% of a C ₆ alkoxylated fatty acid ester,

3 to 7 wt.-%, preferably 4 to 6 wt.-%, of a C ₈ alkoxylated fatty acid ester,

2 to 6 wt.-%, preferably 3 to 5 wt.-%, of a C ₁₀ alkoxylated fatty acid ester,

36 to 46 wt.-%, preferably 38 to 42 wt.-%, of a C ₁₂ alkoxylated fatty acid ester,

6 to 13 wt.-%, preferably 8 to 11 wt.-%, of a C ₁₄ alkoxylated fatty acid ester,

5 to 11 wt.-%, preferably 6 to 9 wt.-%, of a C ₁₆ alkoxylated fatty acid ester, BASF SE

31

25 to 40 wt.-%, preferably 30 to 38 wt.-% of a C ₁₈ alkoxylated fatty acid ester, and 0 to 4 wt.-%, preferably 0 to 3 wt.-%, of a C ₂₀ alkoxylated fatty acid ester, each based on the total weight of the alkoxylated fatty acid ester composition.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises at least 85 wt.-% based on the total weight of the alkoxylated fatty acid ester composition, of C ₄ -C ₂₂ alkoxylated fatty acid esters, preferably C ₁₀ -C ₂₂ alkoxylated fatty acid esters, more preferably C ₁₂ -C ₂₀ alkoxylated fatty acid esters, even more preferably C ₁₂ -C ₂₀ alkoxylated fatty acid esters, and in particular C ₁₂ -C ₁₈ alkoxylated fatty acid esters.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises at least 10 wt.-% of C ₁₆ alkoxylated fatty acid esters and at least 65 wt.-% of C ₁₈ alkoxylated fatty acid esters, each based on the total weight of the alkoxylated fatty acid ester composition.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises 10 to 40 wt.-% of C ₁₆ alkoxylated fatty acid esters and 60 to 90 wt.-% of C ₁₈ alkoxylated fatty acid esters, each based on the total weight of the alkoxylated fatty acid ester composition.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises at least 30 wt.-%, preferably at least 35 wt.-%, and in particular at least 40 wt.-%, based on the total weight of the alkoxylated fatty acid ester composition, of C _12-14 alkoxylated fatty acid esters.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises at least 2 wt.-% of C ₁₀ alkoxylated fatty acid esters, at least 25 wt.-% of C ₁₂ alkoxylated fatty acid esters, at least 5 wt.-% of C ₁₄ alkoxylated fatty acid esters, and at least 4 wt.-% of C ₁₆ alkoxylated fatty acid esters, each based on the total weight of the alkoxylated fatty acid ester composition.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises 0 to 5 wt.-% of C ₈ alkoxylated fatty acid esters, 2 to 6 wt.-% of C ₁₀ alkoxylated fatty acid esters, 25 to 45 wt.-% of C ₁₂ alkoxylated fatty acid esters, 5 to 20 wt.-% of C ₁₄ alkoxylated fatty acid esters, and 4 to 15 wt.-% of C ₁₆ alkoxylated fatty acid esters, each based on the total weight of the alkoxylated fatty acid ester composition.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises 0.2 to 4 wt.-% of C ₆ alkoxylated fatty acid esters, 3 to 7 wt.-% of C ₈ alkoxylated fatty acid esters, 2 to 6 wt.-% of C ₁₀ alkoxylated fatty acid esters, 35 to 45 wt.-% of C ₁₂ alkoxylated fatty acid esters, 5 to 13 wt.-% of C ₁₄ alkoxylated fatty acid esters, and 4 to 10 wt.-% of C ₁₆ alkoxylated fatty acid esters, each based on the total weight of the alkoxylated fatty acid ester composition.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises at least 90 wt.-% of C ₆ alkoxylated fatty acid esters, based on the total weight of the alkoxylated fatty acid ester composition.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises at least 95 wt.-%, based on the total weight of the alkoxylated fatty acid ester composition, of C _12-14 alkoxylated fatty acid esters, and further comprises 36 to 46 wt.-%, preferably 38 to 42 wt.- %, of a C ₁₂ alkoxylated fatty acid ester, and 6 to 13 wt.-%, preferably 8 to 11 wt.-%, of a C ₁₄ alkoxylated fatty acid ester, each based on the total weight of the alkoxylated fatty acid ester composition. BASF SE

32

As indicated above, the present invention further relates to a fatty acid amide composition or an alkoxylated fatty acid ester composition obtained from the fruits of a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr, wherein the oil obtained from the Macauba palmis converted into the fatty acid amide or the alkoxylated fatty acid ester.

Preferred embodiments (e.g. regarding the fatty acid amide composition or the alkoxylated fatty acid ester composition and the Macauba palm) are already above-outlined in the process of manufacturing a fatty acid amide composition or a alkoxylated fatty acid ester composition and in the further details regarding the fatty acid amide composition or the alkoxylated fatty acid ester composition and shal l apply for the fatty acid amide composition or the alkoxylated fatty acid ester composition, as well. Particular preferred embodiment are mentioned in the following.

In a preferred embodiment, the Macauba palm is Acrocomia hass/eri, Acrocomia totei, and/or Acrocomia acuieata , and in particular Acrocomia acuieata and/or wherein the oil is obtained by extraction of the fruits, preferably wherein the oil is extracted from the palm pulp and/or the palm kernel, more preferably wherein the oil is extracted from the Macauba kernel, still more preferably wherein the Macauba palmis Acrocomia hass/eri, Acrocomia totei, and/or Acrocomia acuieata and the oil is extracted from more preferably Acrocomia hass/eri kernel, Acrocomia tote/ kernel, and/or Acrocomia acuieata kernel, and in particular wherein the Macauba palmis Acrocomia acuieata and the oil is extracted from Acrocomia acuieata kernel.

I n a preferred embodiment, the fatty acid amide composition is obtained, preferably wherein the fatty acid amide composition is selected from the group consisting of a fatty acid amido alkanolamide (fatty acid alkanolamide) composition and a fatty acid amidoalkylbetaine composition and in step a) the oil is converted into the fatty acid amido alkanolamides (fatty acid alkanolamides) or the fatty acid amidoalkylbetaines.

Suitable fatty acid amido al kanolamides (fatty acid alkanolamides) can be expressed by the general formula (I)

R-CO-NR^ ² (I), wherein R is saturated or unsaturated C ₄ -C ₂₄ -a I kyl , preferably C ₆ -C ₂₀ -al kyl , R ¹ is H or C C ₈ - hydroxyalkyl, preferably H or C ₁ -C ₄ -hydroxyalkyl, and R ² is H or Cj-Cg-hydroxyalkyl preferably H or Cj-C/j-hydroxyalkyL

I n a preferred embodiment, the fatty acid amido alkanolamides (fatty acid alkanolamides) can be expressed by the general formula (I)

R-CO-NR^ ² (I), wherein R is saturated or unsaturated C ₄ -C ₂₄ -a I kyl , preferably C ₆ -C ₂₀ -al kyl , R ¹ is H and R ² is H or Cj-Cg-hydroxyalkyl preferably H or Cj-C/j-hydroxyalkyL I NCI Cocamide M EA and INCI Lauramide MEA may be named in this connection.

I n another preferred embodiment, the fatty acid amido alkanolamides (fatty acid alkanolamides) can be expressed by the general formula (I)

R-CO-NR^ ² (I), BASF SE

33 wherein R is saturated or unsaturated C ₄ -C ₂₄ -a I kyl , preferably C ₆ -C ₂₀ -al kyl , R ¹ is Cj-C ₈ - hydroxyalkyl, preferably H or Cj-C ₄ - hyd roxya I ky I , and R ² is Cj-Cg-hydroxyalkyl preferably H or Cj-C^-hydroxyalkyL Cocamide COD (INCI Cocamide DEA) and INCI Lauramide DEA may be named in this connection.

In a preferred embodiment, the fatty acid amido alkanolamide (fatty acid alkanolamide) is selected from the group consisting of fatty acid amido monoethanolamide (fatty acid monoethanolamide) and fatty acid amido diethanolamide (fatty acid diethanolamide).

Suitable fatty acid amidoalkylbetaines can be expressed by the general formula (II) wherein R ⁹ is saturated or unsaturated C ₄ -C ₂₄ -a I kyl , preferably C ₆ -C ₂₀ -al kyl and n is an integer of 1 to 10, preferably of 2 to 4.

In a preferred embodiment, the fatty acid amidoalkylbetaines is a fatty acid amidopropylbetaine. INCI Cocamidopropyl Betaine, INCI Lauramidopropyl Betaine, and Dehyton PK45 may be named in this connection.

In a preferred embodiment, the fatty acid amide composition comprises at least 40 wt.-%, based on the total weight of the fatty acid amide composition, of C ₄ -C ₂₂ fatty acid amides, preferably C ₆ -C ₂₀ fatty acid amides, more preferably C ₈ -C ₁₈ fatty acid amides, even more preferably C ₈ -C ₁₆ fatty acid amides or C ₁₆ -C ₁₈ fatty acid amides, and in particular C ₁₀ -C ₁₆ fatty acid amides.

In a preferred embodiment, the fatty acid amide composition comprises

1 to 20 of wt.-% of a C ₈ fatty acid amide,

1 to 8 of wt.-% of a C ₁₀ fatty acid amide,

30 to 48 wt.-% of a C ₁₂ fatty acid amide,

5 to 15 wt.-% of a C ₁₄ fatty acid amide,

4 to 13 wt.-% of a C ₁₆ fatty acid amide,

15 to 42 wt.-% of a C ₁₈ fatty acid amide, and

0 to 5 wt.-% of a C ₂₀ fatty acid amide, each based on the total weight of the fatty acid amide composition. Said fatty acid amide composition is preferably obtained from oil extracted from Macauba kernel.

In a preferred embodiment, the fatty acid amide composition comprises

3 to 7 wt.-%, preferably 4 to 6 wt.-%, of a C ₈ fatty acid amide,

2 to 6 wt.-%, preferably 3 to 5 wt.-%, of a C ₁₀ fatty acid amide,

36 to 46 wt.-%, preferably 38 to 42 wt.-%, of a C ₁₂ fatty acid amide,

6 to 13 wt.-%, preferably 8 to 11 wt.-%, of a C ₁₄ fatty acid amide,

5 to 11 wt.-%, preferably 6 to 9 wt.-%, of a C ₁₆ fatty acid amide,

25 to 40 wt.-%, preferably 30 to 38 wt.-% of a C ₁₈ fatty acid amide, and

0 to 4 wt.-%, preferably 0 to 3 wt.-%, of a C ₂₀ fatty acid amide, each based on the total weight of the fatty acid amide composition. Said fatty acid amide composition is preferably obtained from oil extracted from Macauba kernel. BASF SE

34

In a preferred embodiment, the fatty acid amide composition comprises

0 to 5 wt.-%, preferably 0 to 3 wt.-%, and in particular 0 to 2 wt.-%, of a C ₁₀ fatty acid amide,

0 to 6 wt.-%, preferably 0 to 5 wt.-%, and in particular 1 to 4 wt.-%, of a C ₁₂ fatty acid amide,

0 to 6 wt.-%, preferably 0 to 5 wt.-%, and in particular 1 to 4 wt.-%, of a C ₁₄ fatty acid amide,

10 to 35 wt.-%, preferably 13 to 2 wt.-%, and in particular 15 to 30 wt.-%, of a C ₁₆ fatty acid amide,

55 to 85 wt.-%, preferably 60 to 80 wt.-%, and in particular 65 to 75 wt.-%, of a C ₁₈ fatty acid amide,

0 to 4 wt.-%, preferably 0 to 3 wt.-%, and in particular 0 to 2 wt.-%, of a C ₂₀ fatty acid amide, each based on the total weight of the fatty acid amide composition. Said fatty acid amide composition is preferably obtained from oil extracted from Macauba pulp.

In a more preferred embodiment, the fatty acid amide composition comprises

0.1 to 10 wt.-% of a C ₆ fatty acid amide,

1 to 20 wt.-% of a C ₈ fatty acid amide,

1 to 8 wt.-% of a C ₁₀ fatty acid amide,

30 to 48 wt.-% of a C ₁₂ fatty acid amide,

5 to 15 wt.-% of a C ₁₄ fatty acid amide,

4 to 13 wt.-% of a C ₁₆ fatty acid amide,

15 to 42 wt.-% of a C ₁₈ fatty acid amide, and

0 to 5 wt.-% of a C ₂₀ fatty acid amide, each based on the total weight of the fatty acid amide composition.

In an even more preferred embodiment, the fatty acid amide composition comprises 0.2 to 4 wt.-%, preferably 0.4 to 1.5 wt.-% of a C ₆ fatty acid amide, 3 to 7 wt.-%, preferably 4 to 6 wt.-%, of a C ₈ fatty acid amide,

2 to 6 wt.-%, preferably 3 to 5 wt.-%, of a C ₁₀ fatty acid amide,

36 to 46 wt.-%, preferably 38 to 42 wt.-%, of a C ₁₂ fatty acid amide,

6 to 13 wt.-%, preferably 8 to 11 wt.-%, of a C ₁₄ fatty acid amide,

5 to 11 wt.-%, preferably 6 to 9 wt.-%, of a C ₁₆ fatty acid amide,

25 to 40 wt.-%, preferably 30 to 38 wt.-% of a C ₁₈ fatty acid amide, and

0 to 4 wt.-%, preferably 0 to 3 wt.-%, of a C ₂₀ fatty acid amide, each based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition comprises at least 85 wt.-% based on the total weight of the fatty acid amide composition, of C ₄ -C ₂₂ fatty acid amides, preferably C ₁₀ -C ₂₂ fatty acid amides, more preferably C ₁₂ -C ₂₀ fatty acid amides, even more preferably C ₁₂ -C ₂₀ fatty acid amides, and in particular C ₁₂ -C ₁₈ fatty acid amides.

In a preferred embodiment, the fatty acid amide composition comprises at least 10 wt.-% of C ₁₆ fatty acid amides and at least 65 wt.-% of C ₁₈ fatty acid amides, each based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition comprises 10 to 40 wt.-% of C ₁₆ fatty acid amides and 60 to 90 wt.-% of C ₁₈ fatty acid amides, each based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition comprises at least 30 wt.-%, preferably at least 35 wt.-%, and in particular at least 40 wt.-%, based on the total weight of the fatty acid amide composition, of C _12-14 fatty acid amides. BASF SE

In a preferred embodiment, the fatty acid amide composition comprises at least 2 wt.-% of C ₁₀ fatty acid amides, at least 25 wt.-% of C ₁₂ fatty acid amides, at least 5 wt.-% of C ₁₄ fatty acid amides, and at least 4 wt.-% of C ₁₆ fatty acid amides, each based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition comprises 0 to 5 wt.-% of C ₈ fatty acid amides, 2 to 6 wt.-% of C ₁₀ fatty acid amides, 25 to 45 wt.-% of C ₁₂ fatty acid amides, 5 to 20 wt.-% of C ₁₄ fatty acid amides, and 4 to 15 wt.-% of C ₁₆ fatty acid amides, each based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition comprises 0.2 to 4 wt.-% of C ₆ fatty acid amides, 3 to 7 wt.-% of C ₈ fatty acid amides, 2 to 6 wt.-% of C ₁₀ fatty acid amides, 35 to 45 wt.-% of C ₁₂ fatty acid amides, 5 to 13 wt.-% of C ₁₄ fatty acid amides, and 4 to 10 wt.-% of C ₁₆ fatty acid amides, each based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition comprises at least 90 wt.-% of C ₆ fatty acid amides, based on the total weight of the fatty acid amide composition.

In a preferred embodiment, the fatty acid amide composition comprises at least 95 wt.-%, based on the total weight of the fatty acid amide composition, of C _12-14 fatty acid amides, and further comprises 36 to 46 wt.-%, preferably 38 to 42 wt.-%, of a C ₁₂ fatty acid amide, and 6 to 13 wt.-%, preferably 8 to 11 wt.-%, of a C ₁₄ fatty acid amide, each based on the total weight of the fatty acid amide composition.

In another preferred embodiment, the alkoxylated fatty acid ester composition is obtained.

Suitable alkoxylated fatty acid esters can be expressed by the general formula (III) wherein R is saturated or unsaturated C ₄ -C ₂₄ -a I kyl , preferably C ₆ -C ₂₀ -al kyl , and n is an average number of 1 to 12, preferably of 3 to 10. In this connection it is to be understood that the star in formula (III) denotes a stereocenter. PEG-7 Glyceryl Cocoate may be named in this connection.

Suitable alkoxylated fatty acid esters can be also be expressed by the general formula (IV) R-CO-(OCH ₂ ) _m -R ³ (IV), wherein R is saturated or unsaturated C ₄ -C ₂₄ -a I kyl , preferably C ₆ -C ₂₀ -al kyl , or saturated or unsaturated C ₄ -C ₂₄ -alkoxyl, preferably C ₆ -C ₂₀ -alkoxyl, m is an average number of 1 to 12, preferably of 3 to 10, and R ³ is Cj-Cg-alkyl or Cj-Cg-hydroxyalkyl.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises at least 40 wt.-%, based on the total weight of the alkoxylated fatty acid ester composition, of C ₄ -C ₂₂ BASF SE

36 alkoxylated fatty acid esters, preferably C ₆ -C ₂₀ alkoxylated fatty acid esters, more preferably C ₈ -C ₁₈ alkoxylated fatty acid esters, even more preferably C ₈ -C ₁₆ alkoxylated fatty acid esters or C ₁₆ -C ₁₈ alkoxylated fatty acid esters, and in particular C ₁₀ -C ₁₆ alkoxylated fatty acid esters.

I n a preferred embodiment, the alkoxylated fatty acid ester composition comprises

1 to 20 of wt.-% of a C ₈ alkoxylated fatty acid ester,

1 to 8 of wt.-% of a C ₁₀ alkoxylated fatty acid ester,

30 to 48 wt.-% of a C ₁₂ alkoxylated fatty acid ester,

5 to 15 wt.-% of a C ₁₄ alkoxylated fatty acid ester,

4 to 13 wt.-% of a C ₁₆ alkoxylated fatty acid ester,

15 to 42 wt.-% of a C ₁₈ alkoxylated fatty acid ester, and

0 to 5 wt.-% of a C ₂₀ alkoxylated fatty acid ester, each based on the total weight of the alkoxylated fatty acid ester composition. Said alkoxylated fatty acid ester composition is preferably obtained from oil extracted from Macauba kernel.

I n a preferred embodiment, the alkoxylated fatty acid ester composition comprises

3 to 7 wt.-%, preferably 4 to 6 wt.-%, of a C ₈ alkoxylated fatty acid ester,

2 to 6 wt.-%, preferably 3 to 5 wt.-%, of a C ₁₀ alkoxylated fatty acid ester,

36 to 46 wt.-%, preferably 38 to 42 wt.-%, of a C ₁₂ alkoxylated fatty acid ester,

6 to 13 wt.-%, preferably 8 to 11 wt.-%, of a C ₁₄ alkoxylated fatty acid ester,

5 to 11 wt.-%, preferably 6 to 9 wt.-%, of a C ₁₆ alkoxylated fatty acid ester,

25 to 40 wt.-%, preferably 30 to 38 wt.-% of a C ₁₈ alkoxylated fatty acid ester, and

0 to 4 wt.-%, preferably 0 to 3 wt.-%, of a C ₂₀ alkoxylated fatty acid ester, each based on the total weight of the alkoxylated fatty acid ester composition. Said alkoxylated fatty acid ester composition is preferably obtained from oil extracted from Macauba kernel.

I n a preferred embodiment, the alkoxylated fatty acid ester composition comprises

0 to 5 wt.-%, preferably 0 to 3 wt.-%, and in particular 0 to 2 wt.-%, of a C ₁₀ alkoxylated fatty acid ester,

0 to 6 wt.-%, preferably 0 to 5 wt.-%, and in particular 1 to 4 wt.-%, of a C ₁₂ alkoxylated fatty acid ester,

0 to 6 wt.-%, preferably 0 to 5 wt.-%, and in particular 1 to 4 wt.-%, of a C ₁₄ alkoxylated fatty acid ester,

10 to 35 wt.-%, preferably 13 to 32 wt.-%, and in particular 15 to 30 wt.-%, of a C ₁₆ alkoxylated fatty acid ester,

55 to 85 wt.-%, preferably 60 to 80 wt.-%, and in particular 65 to 75 wt.-%, of a C ₁₈ alkoxylated fatty acid ester,

0 to 4 wt.-%, preferably 0 to 3 wt.-%, and in particular 0 to 2 wt.-%, of a C ₂₀ alkoxylated fatty acid ester, each based on the total weight of the alkoxylated fatty acid ester composition. Said alkoxylated fatty acid ester composition is preferably obtained from oil extracted from Macauba pul p.

I n a more preferred embodiment, the alkoxylated fatty acid ester composition comprises 0.1 to 10 wt.-% of a C ₆ alkoxylated fatty acid ester,

1 to 20 wt.-% of a C ₈ alkoxylated fatty acid ester, BASF SE

37

1 to 8 wt.-% of a C ₁₀ alkoxylated fatty acid ester,

30 to 48 wt.-% of a C ₁₂ alkoxylated fatty acid ester,

5 to 15 wt.-% of a C ₁₄ alkoxylated fatty acid ester,

4 to 13 wt.-% of a C ₁₆ alkoxylated fatty acid ester,

15 to 42 wt.-% of a C ₁₈ alkoxylated fatty acid ester, and

0 to 5 wt.-% of a C ₂₀ alkoxylated fatty acid ester, each based on the total weight of the alkoxylated fatty acid ester composition.

In an even more preferred embodiment, the alkoxylated fatty acid ester composition comprises

0.2 to 4 wt.-%, preferably 0.4 to 1.5 wt.-% of a C ₆ alkoxylated fatty acid ester,

3 to 7 wt.-%, preferably 4 to 6 wt.-%, of a C ₈ alkoxylated fatty acid ester,

2 to 6 wt.-%, preferably 3 to 5 wt.-%, of a C ₁₀ alkoxylated fatty acid ester,

36 to 46 wt.-%, preferably 38 to 42 wt.-%, of a C ₁₂ alkoxylated fatty acid ester,

6 to 13 wt.-%, preferably 8 to 11 wt.-%, of a C ₁₄ alkoxylated fatty acid ester,

5 to 11 wt.-%, preferably 6 to 9 wt.-%, of a C ₁₆ alkoxylated fatty acid ester,

25 to 40 wt.-%, preferably 30 to 38 wt.-% of a C ₁₈ alkoxylated fatty acid ester, and

0 to 4 wt.-%, preferably 0 to 3 wt.-%, of a C ₂₀ alkoxylated fatty acid ester, each based on the total weight of the alkoxylated fatty acid ester composition.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises at least 85 wt.-% based on the total weight of the alkoxylated fatty acid ester composition, of C ₄ -C ₂₂ alkoxylated fatty acid esters, preferably C ₁₀ -C ₂₂ alkoxylated fatty acid esters, more preferably C ₁₂ -C ₂₀ alkoxylated fatty acid esters, even more preferably C ₁₂ -C ₂₀ alkoxylated fatty acid esters, and in particular C ₁₂ -C ₁₈ alkoxylated fatty acid esters.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises at least 10 wt.-% of C ₁₆ alkoxylated fatty acid esters and at least 65 wt.-% of C ₁₈ alkoxylated fatty acid esters, each based on the total weight of the alkoxylated fatty acid ester composition.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises 10 to 40 wt.-% of C ₁₆ alkoxylated fatty acid esters and 60 to 90 wt.-% of C ₁₈ alkoxylated fatty acid esters, each based on the total weight of the alkoxylated fatty acid ester composition.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises at least 30 wt.-%, preferably at least 35 wt.-%, and in particular at least 40 wt.-%, based on the total weight of the alkoxylated fatty acid ester composition, of C _12-14 alkoxylated fatty acid esters.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises at least 2 wt.-% of C ₁₀ alkoxylated fatty acid esters, at least 25 wt.-% of C ₁₂ alkoxylated fatty acid esters, at least 5 wt.-% of C ₁₄ alkoxylated fatty acid esters, and at least 4 wt.-% of C ₁₆ alkoxylated fatty acid esters, each based on the total weight of the alkoxylated fatty acid ester composition.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises 0 to 5 wt.-% of C ₈ alkoxylated fatty acid esters, 2 to 6 wt.-% of C ₁₀ alkoxylated fatty acid esters, 25 to 45 wt.-% of C ₁₂ alkoxylated fatty acid esters, 5 to 20 wt.-% of C ₁₄ alkoxylated fatty acid esters, and 4 to 15 wt.-% of C ₁₆ alkoxylated fatty acid esters, each based on the total weight of the alkoxylated fatty acid ester composition.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises 0.2 to 4 wt.-% of C ₆ alkoxylated fatty acid esters, 3 to 7 wt.-% of C ₈ alkoxylated fatty acid esters, 2 to BASF SE

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6 wt.-% of C ₁₀ alkoxylated fatty acid esters, 35 to 45 wt.-% of C ₁₂ alkoxylated fatty acid esters, 5 to 13 wt.-% of C ₁₄ alkoxylated fatty acid esters, and 4 to 10 wt.-% of C ₁₆ alkoxylated fatty acid esters, each based on the total weight of the alkoxylated fatty acid ester composition.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises at least 90 wt.-% of C ₆ alkoxylated fatty acid esters, based on the total weight of the alkoxylated fatty acid ester composition.

In a preferred embodiment, the alkoxylated fatty acid ester composition comprises at least 95 wt.-%, based on the total weight of the alkoxylated fatty acid ester composition, of C _12-14 alkoxylated fatty acid esters, and further comprises 36 to 46 wt.-%, preferably 38 to 42 wt.- %, of a C ₁₂ alkoxylated fatty acid ester, and 6 to 13 wt.-%, preferably 8 to 11 wt.-%, of a C ₁₄ alkoxylated fatty acid ester, each based on the total weight of the alkoxylated fatty acid ester composition.

As indicated above, the present invention further relates to the use of oil extracted from fruits of a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr for manufacturing fatty acid amides or alkoxylated fatty acid esters.

Preferred embodiments (e.g. regarding the fatty acid amide compositions or the alkoxylated fatty acid ester compositions and the Macauba palm) are already aboveoutlined in the process of manufacturing a fatty acid amide composition or a alkoxylated fatty acid ester composition and shall apply for the use, as well.

As indicated above, the present invention further relates to the use of the above-outlined fatty acid amide composition, or the above-outlined alkoxylated fatty acid ester composition, in a personal care composition, a cleaning composition, a nutrition formulation, a pharmaceutical formulation, or a crops formulation. Preferably, the above-outlined fatty acid amide composition, or the above-outlined alkoxylated fatty acid ester composition are used as surfactant.

In a preferred embodiment, the above-outlined surfactants are used in a personal care composition, preferably selected from the group consisting of face care composition, hair care composition, body care composition, oral care composition, or antiperspirants and deodorants.

Suitable cosmetic formulations containing active ingredients are, e.g., hormone preparations, vitamin preparations, vegetable extract preparations and antibacterial preparations.

According to the present invention the personal care composition may comprise one or more active agent(s), e.g., organic and inorganic UV filters and vitamins, as well as other ingredients or additives, e.g., pigments, emulsifiers, emollients, viscosity regulators, stabilizers, preservatives, or fragrances.

In a preferred embodiment, the above-outlined surfactants are used in a sunscreen.

In a preferred embodiment, the above-outlined surfactants are used in a decorative preparations, preferably selected from the group consisting of lipsticks, nail varnishes, eye BASF SE

39 shadows, mascaras, dry and moist make-up, rouge, powders, depilatory agents and suntan lotions.

The personal care composition is preferably in form of creams, ointments, pastes, foams, gels, lotions, powders, make-ups, sprays, sticks or aerosols.

Preferably, the surfactant is used to control the metal ions, improve the dispersing, improve the emulsifying, control the foaming, modify the surface, and/or protect the active agent(s).

In a preferred embodiment, the above-outlined surfactants are used in a cleaning composition, preferably selected from the group consisting of home care formulation, industrial care formulation, and institutional care formulation.

In a preferred embodiment, the cleaning composition is selected from the group consisting of laundry composition (personal and commercial), dishwashing composition, hard surface cleaning composition, food service and kitchen hygiene composition, food and beverage processing composition, sanitation composition, institutional cleaning composition, industrial cleaning composition, and vehicle and transportation care composition.

The cleaning composition may comprise at least one bleaching system known in the art in an amount of from 0 to 50 wt.-%. Suitable bleaching components include bleaching catalysts, photobleaches, bleach activators, sources of hydrogen peroxide such as sodium percarbonate and sodium perborates, preformed peracids, and mixtures thereof.

The cleaning compositions may furthermore comprise dirt-suspending agents, for example sodium carboxymethylcellulose; pH regulators, for example alkali metal or alkaline earth metal silicates; bactericides; foam regulators, for example soap; salts for adjusting the spray drying and the granulating properties, for example sodium sulfate; fragrances; antistatic agents; fabric conditioners; further bleaching agents; pigments; and/or toning agents.

Preferably, the surfactant is used to control the metal ions, improve the dispersing, improve the emulsifying, control the foaming, modify the surface, and/or protect the ingredient(s).

In a preferred embodiment, the above-outlined surfactants are used in a nutrition formulation, preferably from the group selected from food formulations and feed formulations. The nutrition formulation can have any suitable form, e.g. liquid or solid and can be administered or uptaken in any suitable manner, e.g. orally, parenterally, or rectally.

For the preparation of a nutrition formulation, or a premix or a precursor, the process may comprise mixing a stabilized solid and/or liquid formulation comprising at least one or more food substance(s) and at least one additional ingredient(s) such as stabilizing agent.

Suitable stabilizing agents may be selected from the group consisting of gummi arabicum, at least one plant protein and mixtures thereof. It is understood that the stabilizing agent can be selected from one agent, e.g. only gummi arabicum or be composed of a mixture of e.g. one plant protein and gummi arabicum or a mixture of two or three or more different plant proteins. In one embodiment, the stabilizing agent is gummi arabicum. In another embodiment, the stabilizing agent is at least one plant protein.

Preferably, the surfactant is used to control the metal ions, improve the dispersing, improve the emulsifying, control the foaming, modify the surface, and/or protect the BASF SE

40 ingredient(s).

In a preferred embodiment, the above-outlined surfactants are used in pharmaceutical formulation. The pharmaceutical formulation may be administered in any suitable manner such as by oral, transdermal, parenteral, nasal, vaginal, or rectal application. Suitable solid pharmaceutical formulation can be in form of tablets, suppositories, or capsules or in form of a spray. Suitable transdermal pharmaceutical formulations encompass patches or formulations such as sprays, lotions, creams, oils, foams, ointments, powders, or gels. Suitable liquid pharmaceutical formulations are preferably administered orally, parenterally, or nasal.

The pharmaceutical formulation is preferably in solid, semi-solid, or liquid form, preferably in form of tablets, suppositories, capsules, patches, as sprays, lotions, creams, oils, foams, ointments, powders, gels, or fluid.

The pharmaceutical formulation comprises at least one active agent, e.g. selected from the group consisting of anti-cancer agent, hormone, antiviral agent, antifungal agent, antibacterial agent, and inhibitor.

Preferably, the surfactant is used to control the metal ions, improve the dispersing, improve the emulsifying, control the foaming, modify the surface, and/or protect the active agent(s).

In a preferred embodiment, the above-outlined surfactants are used in crop formulation, preferably selected from the group consisting of pesticide formulations, fungicide formulations, and herbicide formulations.

The crop formulation is preferably in solid, semi-solid, or liquid form. Preferably, the crop formulation is suitable for a ready to use spray.

In a preferred embodiment, the pesticide formulation comprises a pesticide selected from the group consisting of chlorpyrifos, endosulfan, imazalil, DDT, toxaphene, lindane, methoxychlor, dieldrin, kelthane, chlordane, Perthane, endrin, aldrin, and heptachlor.

In a preferred embodiment, the fungicide formulation comprises a fungicide selected from the group consisting of azoxystrobin, pyraclostrobin, fluoxastrobin, trifloxystrobin, picoxystrobin, epoxiconazole, prothioconazole, myclobutanil, tebuconazole, propiconazole, cyproconazole, fenbuconazole, boscalid, penthiopyrad, bixafen, isopyrazam, sedaxane, fluopyram, and thifluzamide.

In a preferred embodiment, the herbicide formulation comprises a herbicide selected from the group consisting of glyphosate, glufosinate, imidazolinone (such as imazamethabenz, imazamox, imazapic (e.g. Kifix), imazapyr, imazaquin and imazethapyr), and cyclohexanediones (such as tepraloxydim and clethodim).

Suitable herbicide formulation show enhanced herbicide action against undesirable harmful plants, in particular against Aca/ypha species such as Aca/ypha indica, Dinebra species such as Dinebra Arabica, Cynotis spec such as Cynotis axillaris, Parthenium spec such as Parthenium hysterophorus, Physalis spec such as Physalis minima, Digera spec such as Digera arvensis, A/opecurus myosuroides, Apera spicaventi, Brachiaria spec, such as Brachiaria def/exa or Brachiaria p/antaginea, Echinoch/oa spec, such as Echinoch/oa co/onum, Leptoch/oa spec, such as Leptoch/oa fusca, Rottboellia cochinchinensis, Digitaria sanguina/is, Eleusine indica, Saccharum spontaneum, Cynodon dactylon, Euphorbia hirta, BASF SE

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Euphorbia genicuiata, Commeiina benghaiensis, Commeiina communis, certain undesired Oryza spec, such as weedy rice or red rice ( Qryza sativa), Pha laris spec, such as Pha laris canariensis, Celosia argentea, Xanthium strumarium, Papaver rhoeas, Geranium spec, Brassica spec, Avena fatua, Bromus spec., Lo/ium spec., Pha/aris spec., Setaria spec., Digitaria spec., brachiaria spec., Amaranthus spec., Chenopodium spec., Abuti/on theophrasti, Galium aparine, Veronica spec., or So/anum spec, and/or to improve their compatibility with crop plants, such as soybean, peanut, pea, bean, lentil, green gram, black gram, cluster bean, fenugreek, palm, other pulse or leguminous crops, or crops which are tolerant to the action of acetohydroxyacid synthase inhibiting herbicides, such as for example Clearfield® wheat, Clearfield® barley, Clearfield® corn, Clearfield® lentil, Clearfield® oilseed rape or canola, Clearfield® rice, Cultivance® soybean and/or Clearfield® sunflower. The formulation should also have a good pre-emergence herbicidal activity.

Preferably, the surfactant is used to control the metal ions, improve the dispersing, improve the emulsifying, control the foaming, modify the surface, and/or protect the crop.

In a preferred embodiment, the personal care composition, the cleaning composition, the nutrition formulation, the pharmaceutical formulation, or the crop formulation comprises at least two surfactants. In this connection it is to be understood that the personal care composition, the cleaning composition, the nutrition formulation, the pharmaceutical formulation, or the crop formulation may comprise at least two above-outlined surfactant, at least three of the above-outlined surfactant or at least one of the above-outlined surfactant in combination with at least one further, different surfactant. The at least one further, different surfactant may be fatty acid-based surfactants such as sulfonates, amides, isethionates, taurates, glycolipids, amino acids, esterquats, sophorolipids, rhamnolipids, amphoacetates, and fatty acid methyl esters or its sulfonate or a fatty alcohol-based surfactant.

Potential mixtures of one of the above-outlined surfactants are listed in the following. Preferably, these surfactants are also derived from Macauba oil with the exceptions of Nr. 18 and Nr. 20. BASF SE

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As indicated above, the invention further relates to a personal care composition, a cleaning composition, a nutrition formulation, a pharmaceutical formulation, or a crop formulation comprising the above-outlined fatty acid amide composition, or the above-outlined alkoxylated fatty acid ester composition. It is to be understood that the further specification of the use of the above-outlined fatty acid amide composition, or the above-outlined alkoxylated fatty acid ester composition in the respective personal care composition, a cleaning composition, a nutrition formulation, a pharmaceutical formulation, or a crop formulation also applies for the personal care composition, a cleaning composition, a nutrition formulation, a pharmaceutical formulation, or a crop formulation.

As indicated above, the present invention further relates to process of manufacturing glycerol, the process comprising the step a) converting oil extracted from a Macauba palm having an oil yield in tons per hectare per year of at least 6 t/ha/yr into glycerol.

Preferred embodiments (e.g. regarding fatty acid amide compositions or alkoxylated fatty acid ester compositions, the Macauba palm, and process parameters) are already aboveoutlined in the process of manufacturing a fatty acid amide composition or a alkoxylated fatty acid ester composition and shall apply for the method of manufacturing glycerol, as well. Particular preferred embodiment are mentioned in the following.

Glycerol may be provided as a side reaction of the above-outlined process of manufacturing a fatty acid amide composition or a alkoxylated fatty acid ester composition.

In a preferred embodiment, the process further comprises the step of b) refining, which preferably is conducted via filtration, centrifugation, chemical addition, and/or fractional vacuum distillation.

Examples

The present invention is further illustrated by the following prophetic examples.

The following examples are considered for the Macauba palm (e.g. having registration number AEB402A) having an oil yield in tons per hectare per year of about 9.0 t/ha/yr.

Measurement methods a) Free fatty acid contents

The determination of free fatty acids content in the oil has been made according to DIN EN ISO 660, the method used for measuring the acid value was ISO 4314, and the method for measurement of the saponification value was DIN EN ISO 3657 / DIN EN ISO 3681. b) Comparative cold stability test BASF SE

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Samples (32 grams each) are filled into glass vials (diameter 2.5cm, height 8.5 cm). They are first kept overnight in an oven at a temperature that ensures that the samples are completely dissolved and clear (here 45° C). The next day the vials are immersed in a tempered water bath (23° C) with the sample level being below the water level. The temperature of the water batch is reduced stepwise (-2k/h to 17° C, then -IK/h to 15° C). In the end the appearance of the cooled samples is observed. The samples are then taken out of the water bath and kept at room temperature (RT=23° C) for another 16 hours. Again, the appearance is observed. c) Thickening behavior

Samples of 200 g are filled in a beaker and Sodium Chloride is added to the sample. The sample is then mixed until the salt has dissolved. The sample is kept at room temperature (23° C) until all gas bubbles that were introduced during mixing have disappeared. The viscosity is measured using a Brookfield RV laboratory rheometer at 12 rpm, spindle set RV 02 to 07 (spindle selection according to viscosity range). The appearance of the samples is also inspected visually. The wt.-% of NaCI are calculated as weight of added NaCI per 200 g. d) Foaming behavior

Solutions of the surfactant samples are prepared (1 I in total) having a concentration of 1 g active matter/liter and a pH of 5.5 (adjusted with citric acid or sodium hydroxide solution). The sample solution is prepared with DI water (0° dH) and tempered to 15° C. The foam measurement is done with the Foam Expert device (SITA Messtechnik GmbH). 250 ml of solutions are filled in the stirring vessel and then stirred at 1300 rpm for 10 seconds, then the total volume and the liquid volume is measured (and with this the foam volume = total volume - liquid volume). The stirring and volume measurement is done 18 times. Then the sample is flushed, the stirring vessel cleaned with DI water and the same measurement (250 ml, 18x10 s) is repeated two more times. The results for foam and liquid volume over stirring time are calculated as mean values of the three repetitions. Usually, the foam volume shows an asymptotic expansion. The following characteristic data can be obtained:

Maximum foam volume [ml]

Time to max foam volume [s] = stirring time until maximum foam volume is achieved Foam Formation Half Time [s] = stirring time until % of max. foam volume is achieved e) Method for extracting the oil from the fruit

The oil is extracted by cold crushing in a dry-route process. In this process, the fruits are dried, and then pulped, and only after these steps the pulp/kernel are crushed.

Inventive Example 1 (IE1)

The Macauba palm is planted on a cattle field, e.g. about 380 trees per hectare. No deforestation is needed since the Macauba palms are cultivated on already existing fields (silvopastoral) and the farmer can in addition to cattle breeding and/or milk production BASF SE

44 distribute the Macauba fruits. 312 Macauba palms have been planted per hectare. Each palm generates from 61kg to 90kg of fruits/hectare per year (depending on the palm maturity and cultivation conditions). The harvest is done only once a year during the raining season (Oct - Jan). Roughly 3% of the fruit is Kernel Oil, 8% is Pulp Oil.

Inventive Example 2 (IE2)

The Macauba palm is planted on soya plantation (having a growth height of about 20 to 80 cm and an oil yield in tons per hectare per year about 0.6 t/ha/yr), e.g. about 340 trees per hectare. Again, no deforestation is needed since the Macauba palms are cultivated on an already existing plantation (agroforestry). As the Macauba palm grows up to about 15 meters in height, the soya can be cultivated parallel. In this connection, it is also possible to cultivate at least one more additional different plant (having a growth height of about 1 to 7 m) such as sunflower (having an oil yield in tons per hectare per year of about 0.7 t/ha/yr) or beans parallel.

As can be seen from the above examples, deforestation can be significantly reduced by cultivating Macauba palms. Further, the biodiversity can be increased. In addition, even if the Macauba palm is not cultivated as a monoculture, the total oil yield can be comparable with an oil palm (having an oil yield in tons per hectare per year of about 3.8 t/ha/yr) monoculture since the oil yield as above-defined of the Macauba palm is higher. Without being bound to any theory, using a plant having an improved oil yield, degraded areas and springs and watersheds can more easily recover. Further, the retention of moisture in the soil is improved.