Title:
OPEN-CHAIN TERPENE COMPOUND
Document Type and Number:
WIPO Patent Application WO/1991/008187
Kind Code:
A1
Abstract:
A novel open-chain terpene compound useful as an intermediate for sarcophytol A having a resistance to a carcinogenesis and an antitumor activity and represented by general formula (I), wherein R1 is a hydrogen atom, a 1-alkoxyalkyl group, a tetrahydrofuryl group, a tetrahydropyranyl group or an acyl group, R2 is -CHO, -CH2OR3 or (a), wherein R3 is a hydrogen atom, a 1-alkoxyalkyl group, a tetrahydrofuryl group, a tetrahydropyranyl group or an acyl group, R4 is an alkyl group having 1 to 4 carbon atoms, provided that R1 and R3 are not simultaneously the same substituents and, when R1 is a hydrogen atom, R3 is neither an acetyl group nor a tetrahydropyranyl group and, when R2 is a group represented by formula (a), R1 is not a hydrogen atom.
Inventors:
TAKAYANAGI HISAO (JP)
KITANO YASUNORI (JP)
MORINAKA YASUHIRO (JP)
KITANO YASUNORI (JP)
MORINAKA YASUHIRO (JP)
Application Number:
PCT/JP1990/001554
Publication Date:
June 13, 1991
Filing Date:
November 29, 1990
Export Citation:
Assignee:
MITSUBISHI CHEM IND (JP)
International Classes:
C07C43/315; C07C45/29; C07C47/263; C07C47/277; C07C69/025; C07C69/732; C07C69/734; C07D307/20; C07D309/12; (IPC1-7): C07C43/315; C07C47/263; C07C47/277; C07C69/025; C07C69/732; C07C69/734; C07D307/20; C07D309/12
Foreign References:
| JPH06320213B |
Other References:
Journal of Organic Chemistry, Vol. 52, No. 17, (1987), J. A, MARSHALL. et al. (Synthesis of Cembrane Natural Products via (2, 3) Wittig Ring Contraction of Propargylic Ethers) p. 3860-3866.
Journal of Organic Chemistry, Vol. 51, No. 22, (1986), J. A. MARSHALL. et al. ( (2, 3) Wittig Ring Contraction. A new Route to Cembranoid Natural Products) p. 4316-4319.
Journal of Chemical Society, Chemical Communication, Vol. 13, (1987), S. INOUE. et al. (Stereoselective Total Synthesis of (S) -(-)-Dolichol-20) p. 1036-1037.
See also references of EP 0455822A4
Journal of Organic Chemistry, Vol. 51, No. 22, (1986), J. A. MARSHALL. et al. ( (2, 3) Wittig Ring Contraction. A new Route to Cembranoid Natural Products) p. 4316-4319.
Journal of Chemical Society, Chemical Communication, Vol. 13, (1987), S. INOUE. et al. (Stereoselective Total Synthesis of (S) -(-)-Dolichol-20) p. 1036-1037.
See also references of EP 0455822A4
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