KIM, Jong Hyo (#207-103 Daejeon Deurium Apartment, 317-1 Daejeong-dong, Yuseong-gu, Daejeon 305-251, KR)
JANG, Dong Gyu (#16-308, Sujeong ApartmentDunsan2-dong, Seo-gu, Daejeon 302-775, KR)
KIM, Jong Hyo (#207-103 Daejeon Deurium Apartment, 317-1 Daejeong-dong, Yuseong-gu, Daejeon 305-251, KR)
[CLAIMS] [Claim 1]
An optical resin composition comprising:
(a) 30 to 60% by weight of a mixture of isophorone diisocyanate and hexamethy1ene di isocyanate;
(b) 40 to 70% by weight of pentaerythritol tetrakis(3- mercaptopropionate), or a mixture of pentaerythritol tetrakis(3- mercaptopropionate) and pentaerythritol tetrakis(mercaptoacetate);
(c) 0.005 to 6% by weight of a UV absorber, 0.001 to 5% by weight of a release agent and 0.01 to 5% by weight of a polymerization initiator, based on the total weight of the components (a) and (b), wherein the composition has a solid refractive index (nD) of 1.53 to 1.57, an Abbe number of 35 to 48, a liquid specific gravity of 0.97 to 1.25 and a solid specific gravity of 1.10 to 1.35.
[Claim 2]
The optical resin composition according to claim 1, wherein the isophorone diisocyanate is used in an amount of not more than 0.6 mol, with respect to 1 mol of the hexamethylene diisocyanate.
[Claim 3]
The optical resin composition according to claim 1, wherein the optical resin composition has a liquid viscosity of 20 to 160 cps (at 20°C).
[Claim 4]
The optical resin composition according to claim 1, wherein the UV absorber is selected from the group consisting of 2-(2'-hydroxy-5- methylphenyl)-2H-benzotriazole, 2-(2'-hydroxy-3' ,5'—dl—t-butylphenyl)-5- chloro-2H-benzotriazole, 2-(2'-hydroxy-3'-t-butyl-5 1 -methylphenyl)-5-chloro- 2H-benzotriazole, 2-(2'-hydroxy-3 1 ,5'-di-t-amylphenyl)-2H-benzotriazole, 2- (2 1 -hydroxy-3',5'-di-t-butylphenyl)-2H-benzotriazole, 2-(2'-hydroxy-5'-t- butylphenyl)-2H-benzotriazole, 2-(2'-hydroxy-5'-t-octylphenyl)-2H- benzotriazole, 2,4-dihydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2- hydroxy-4-octy1oxybenzophenone, 4-dodecy1oxy-2-hydroxybenzophenone, 4- benzoxy-2-hydroxybenzophenone, 2,2' ,4,4'-tetrahydroxybenzophenone, 2,2'— dihydroxy-4,4'-dimethoxybenzophenone and a mixture thereof.
[Claim 5]
The optical resin composition according to claim 1, wherein the release agent is an phosphate ester, an phosphonic acid ester or a mixture thereof .
[Claim 6]
The optical resin composition according to claim 5, wherein the phosphate ester is selected from the group consisting of isopropyl phosphate, diisopropyl phosphate, butyl phosphate, octyl phosphate, dioctyl phosphate, isodecyl phosphate, diisodecyl phosphate, tridecanol phosphate, bis(tridecanol) phosphate and a mixture thereof.
[Claim 7]
The optical resin composition according to claim 1, wherein the polymerization initiator is an amine compound or a tin compound.
[Claim 8]
The optical resin composition according to claim 7, wherein the tin compound is selected from the group consisting of butyltin dilaurate, dibutyltin dichloride, dibutyltin diacetate, tin (I) octylate, dibutyltin dilaurate, tetrafluorotin, tetrachlorotin, tetrabromotin, tetraiodotin, methyltin trichloride, butyltin trichloride, dimethyltin dichloride, trimethyltin chloride, tributyltin chloride, triphenyltin chloride, dibutyltin sulfide, di(2-ethylhexyl)tin oxide and a mixture thereof.
[Claim 9]
The optical resin composition according to claim 1, wherein the content of the pentaerythritol tetrakis(mercaptoacetate) is not more than 50%, with respect to the pentaerythritol tetrakis(3-mercaptopropionate).
[Claim 10]
A plastic optical lens produced by thermally curing the optical resin composition according to any one of claims 1 to 9.
[Claim 11] The optical resin composition according to claim 10, wherein the plastic optical lens is a spectacle lens. [Claim 12]
A method for producing a spectacle lens comprising- injecting a resin composition into a reactor, the resin composition comprising: (a) 30 to 60% by weight of a mixture of isophorone diisocyanate and hexamethylene diisocyanate; (b) 40 to 70% by weight of pentaerythritol tetrakis(3-mercaptopropionate) or a mixture of pentaerythritol tetrakis(3- mercaptopropionate) and pentaerythritol tetrakis(mercaptoacetate); (c) 0.005 to 6% by weight of a UV absorber, 0.001 to 5% by weight of a release agent, and 0.01 to 5% by weight of a polymerization initiator, based on the total weight of the components (a) and (b), replacing the air in the reactor by nitrogen, stirring the composition under reduced pressure for 2 hours, after completion of the stirring, defoaming the composition under reduced pressure and injecting the composition into a mold; allowing the mold to stand in an oven under the conditions of maintaining at 33-37°C over 2 hours, elevating to 38-42 0 C over 3 hours, elevating to 115-125°C over 12 hours, maintaining at 115-125°C over 2 hours and decreasing to 60-80°C over 2 hours, and releasing the composition from the mold, to obtain an optical lens; and subjecting the optical lens to annealing at 100 to 120 0 C for 1 to 4 hours. [Claim 133
The method according to claim 12, further comprising: hard-coating and multi-coating the optical lens after annealing. |
[DESCRIPTION] [Invention Title]
OPTICAL RESIN COMPOSITION HAVING EXCELLENT IMPACT RESISTANCE AND METHOD FOR FABRICATING OPTICAL LENS USING THE SAME
[Technical Field]
The present invention relates to an optical resin composition with superior impact resistance and a method for producing an optical lens using the composition. More specifically, the present invention relates to a plastic optical resin composition that has superior impact resistance as well as light-weight, superior moldability, excellent dyeing ability, a high Abbe number and good transparency, and a method for producing an optical lens from the composition.
[Background Art]
Plastic optical lenses are generally used due to superior impact resistance, light-weight and superior moldability, as compared to glass lenses. Recently, in an attempt to prevent scattered reflection of plastic optical lenses and improve light transmissivity thereof, the both sides of the lenses have been multi-coated with a material such as Siθ2 or ZKV
However, such a multi-coating undesirably causes a deterioration in impact resistance of the lens, which is common to all lenses, e.g. low-, medium-, high- and super high-refractive index lenses.
When a steel ball with a weight of 16.8 g (FDA standard weight) is let fall from a height of 127 cm onto the center of plastic optical lenses (central thickness: 1.2 mm), which are produced from diethylene glycol bis(allylcarbonate) as a low-refractive monomer and then multicoated, the plastic optical lenses are undesirably broken.
Several methods for preparing medium-refractive lenses were suggested. For example, Korean Patent Publication No. 1992-0004464 discloses preparation of a medium-refractive lens from dialIyI isophthalate, polyhydric alcohol-
containing dial IyI isophthalate and diethylene glycol bis(allylcarbonate) copolymers, and Korean Patent Publication No. 1993-0010567 discloses preparation of a medium-refractive plastic lens (with a central thickness of 1.2 mm) using modified-dialIyI isophthalate, where polyhydric alcohols are grafted into dial IyI isophthalate, so as to improve impact strength, as compared to cases where dialIyI isophthalate, modified-dialIyI isophthalate or modified-diethylene glycol bis(allylcarbonate) copolymers are used singly. However, these medium-refractive plastic lenses also fail to pass a FDA impact test following multi-coating.
In addition, Korean Patent Publication No. 2003-0078494 discloses a method for producing an optical lens with superior impact strength, the method comprising adding secondary alcohol to isophorone diisocyanate and hexamethylene diisocyanate and curing the resulting product with pentaerythritol tetrakis(3-mercaptopropionate) or the like. However, in this case, it takes a long time to inject a resin composition into the optical lens due to high viscosity of the composition and traces of the composition which flows into the lens remain therein. As a result, the method has a problem of a high defect ratio of optical lens products.
Several methods for preparing high-refractive and super-high refractive lenses were suggested. For example, Korean Patent Publication No. 1994- 0004010 discloses the use of xylene diisocyanate and l,2-bismercaptoethyl-3- mercaptopropane copolymers to increase refractive index of lenses, and Korean Patent Registration No. 1993-0006918 discloses the use of aliphatic diisocyanate, l,2-bismercaptoethyl-3-mercaptoρropane and pentaerythritol tetrakis(3-mercaptoρroρionate) to improve the refractive index of lenses. These methods enable an increase in the refractive index of lenses, but disadvantageousIy fail to pass a FDA impact test following multicoating.
A polycarbonate injection lens exhibits excellent impact resistance even after multi-coating, but has a problem of considerable modification in the center thereof due to poor heat resistance.
{Disclosure]
[Technical Problem]
The present invention has been made to solve the foregoing problems of the prior art and it is an aspect of the present invention to provide a plastic optical resin composition with superior impact resistance as well as light-weight, superior moldability, excellent dyeing ability, a high Abbe number and good transparency, and an optical lens produced from the composition maintains superior impact resistance even after hard-coating and multi-coating (anti-reflective coating).
The present invention demonstrates that the optical lens with superior impact resistance as well as good optical properties is obtained by thermally curing the plastic optical resin composition to obtain an optical lens, and hard-coating and multi-coating the optical lens, wherein the plastic optical resin composition comprises: 30 to 60% by weight of a mixture of isophorone diisocyanate and hexamethylene diisocyanate; 40 to 70% by weight of pentaerythritol tetrakis(3~mercaptopropionate); 0.005 to 6% by weight of a UV absorber; 0.001 to 5% by weight of a release agent; and 0.01 to 5% by weight of a polymerization initiator.
The other aspects, features and other advantages of the present invention are encompassed in the following detailed description and will be more clearly understood from the preferred examples.
[Technical Solution]
In accordance with one aspect of the present invention for achieving the above aspect, there is provided an optical resin composition with superior impact resistance that has a solid refractive index (nD) of 1.53 to 1.57, an Abbe number of 35 to 48, a liquid specific gravity of 0.97 to 1.25 and a solid specific gravity of 1.10 to 1.35, which comprises: (a) 30 to 60% by weight of a mixture of isophorone diisocyanate and hexamethylene diisocyanate; (b) 40 to 70% by weight of pentaerythritol tetrakis(3- mercaptopropionate) or a mixture of pentaerythritol tetrakis(3-
mercaptopropionate) and pentaerythritol tetrakisCmercaptoacetate); (c) 0.005 to 6% by weight of a UV absorber, 0.001 to 5% by weight of a release agent and 0.01 to 5% by weight of a polymerization initiator, based on the total weight of the components (a) and (b).
In accordance with another aspect of the present invention for achieving the above aspect, there is provided an optical lens produced by thermally curing the optical resin composition.
Preferably, the optical resin composition has a liquid viscosity of 20 to 160 cps (at 20"C).
[Best Mode]
The present invention will now be described with reference to the accompanying drawings in greater detail.
In the present invention, diisocyanate compounds are preferably used in a mixture of isophorone diisocyanate and hexamethylene diisocyanate. The isophorone diisocyanate is preferably used in an amount not more than 0.6 mol, more preferably 0.01 to 0.5 mol, with respect to 1 mol of the hexamethylene diisocyanate. In a case where isophorone diisocyanate is used exclusively or in an amount not less than 71 wt%, an optical lens suffers from problems, e.g. , occurrence of a mass of bubbles and deterioration in impact resistance during curing. In an attempt to solve these problems, when the composition is subjected to vacuum-deforming stirring at a temperature of 30°C or higher, the foaming is decreased to some extent, but several problems occur e.g. , long composition injection time due to an increased viscosity of the composition, difficulty in removing bubbles derived from the injection and deteriorated impact resistance. In a case where isophorone diisocyanate is used in an amount not more than 20 wt%, an optical lens has superior impact resistance, but has poor heat resistance, thus causing a multi-coated film to be cracked and modification in the center of an optical lens. Besides, the use of a diisocyanate compound such as nrxylene-diisocyanate, p-χylene- diisocyanate or tetrachloro-nrxylene-diisocyanate leads to a significant
deterioration in impact resistance of lenses. Thus, when a steel ball with a weight of 16.8 g is let fall from a height of 127 cm onto the center of the lens after multi-coating, the lens is undesirably broken.
Pentaerythritol tetrakisCS-mercaptopropionate) may be used singly or in combination with pentaerythritol tetrakis(mercaptoacetate). Preferred is the single use of pentaerythritol tetrakisCS-mercaptopropionate). The combination use of pentaerythritol tetrakis(3-mercaptopropionate) with pentaerythritol tetrakis(mercaptoacetate) results in a slight increase in heat resistance of lenses, but undesirably involves a high polymerization defect ratio due to an increased reaction rate during curing. In particular, such a phenomenon significantly occurs in a case where pentaerythritol tetrakis mercaptoacetate is used in an amount not less than 50 wt%.
The content of the UV absorber used for the composition of the present invention is 0.005 to 6% by weight (ca. 50 to 60,000 ppm), preferably 0.1 to 3% by weight (ca. 1,000 to 30,000 ppm), based on the total weight of the compound. When the content of the UV absorber is less than 0.005% by weight, efficient UV absorbability cannot be obtained, and the lens thus undergoes serious yellowing upon exposure to UV radiation. On the other hand, when the UV absorber is used in an amount not less than 6% by weight, it cannot be completely soluble in the composition and polymerization may be seriously defective during curing. Examples of the UV absorber includes 2-(2'-hydroxy- 5-methylphenyl)-2H~benzotriazole, 2-(2'-hydroxy-3' ,5'-di-t-butylphenyl)-5- chloro-2H-benzotriazole, 2-(2'-hydroxy-3'-t-buty1-5'-methylphenyl)-5-chloro- 2H-benzotriazole, 2-(2'-hydroxy-3' ,5'-di-t-amylphenyl)-2H-benzotriazole, 2- (2'-hydroxy-3',5'-di-t-butylρhenyl)-2H-benzotriazole, 2-(2'-hydroxy-5'-t- butylpheny1)-2H-benzotriazo1e, 2-(2'-hydroxy-5'-t-octylpheny1)-2H- benzotriazole, 2,4-dihydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2- hydroxy-4-octyloxybenzophenone, 4-dodecyloxy-2-hydroxybenzoρhenone, 4- benzoxy-2-hydroxybenzophenone, 2,2' ,4,4'-tetrahydroxybenzophenone, and 2,2'- dihydroxy-4,4'-dimethoxybenzophenone. The UV absorber may be used singly or in combination thereof. Preferred is the use of 2-(2'-hydroxy-5'-t-
octylphenyl)-2H-benzotriazole or 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, each of which exhibits good UV absorbability at a wavelength not more than 400 nm and is well soluble in the composition of the present invention.
The composition of the present invention may further comprise an organic dye well-known in the art. The organic dye may be added in a small amount within a well-known usage. In one embodiment of the present invention, l-hydroxy-4-(p-toluidine)anthraquinone (available from Kyoungin
Synthetic Corp.) and a PERINONE dye are used as organic dyes. The release agent that can be used in the present invention is selected from fluorinated nonionic surfactants, si Iicone-based nonionic surfactants, alkyl quaternary ammonium salts, phosphate esters and phosphonic acid esters. The release agent may be used singly or in combination thereof. Preferred is the use of phosphate ester or phosphonic acid ester. The use of a metal- or glass mold as a mold, into which the composition is applied, enables improvement of demoldability. Examples of phosphate esters include isopropyl phosphate, diisopropyl phosphate, butyl phosphate, octyl phosphate, dioctyl phosphate, isodecyl phosphate, diisodecyl phosphate, tridecanol phosphate, bis(tridecanol) phosphate and a combination thereof. The tests in accordance
TM with Examples of the present invention demonstrate that ZELEC UN (available from Dupont Corp.), phosphate ester, exhibits the most superior demoldability. The content of the release agent is 0.001 to 5% by weight, preferably 0.05 to 2% by weight, with respect to the weight of the monomers, in view of good demoldability and high polymerization yield. The polymerization initiator that can be used in the present invention is an amine- or tin-compound. Examples of the tin compound include butyltin dilaurate, dibutyltin dichloride, dibutyltin diacetate, tin (I) octylate, dibutyltin dilaurate, tetrafluorotin, tetrachlorotin, tetrabromotin, tetraiodotin, methyltin trichloride, butyltin trichloride, dimethyltin dichloride, trimethyltin chloride, tributyltin chloride, triphenyltin chloride, dibutyltin sulfide and di(2~ethylhexyl)tin oxide. The tin compound
may be used singly or in combination thereof. The use of the tin compound causes a high polymerization yield and no foaming. The content of the tin compound is preferably 0.01 to 5% by weight, based on the total weight of the composition.
A plastic optical lens, in particular, a spectacle lens, is obtained by thermally curing the optical resin composition of the present invention. In accordance with a preferred embodiment of the present invention, a method for producing a spectacle lens by thermally curing the composition is given as follows. First, after a polymerization initiator is added to the composition, air contained in a mixing container (i.e. reactor) is replaced by nitrogen, and the composition is stirred under reduced pressure for 2 to 5 hours. After completion of the stirring, the composition is defoamed under reduced pressure and injected into a mold. The mold may be a plastic gasket, or a glass- or metal-mold which is fixed with a polyester or polypropylene adhesive tape. The glass mold containing the composition is injected into a forced convection oven. The oven temperature is maintained at 33-37"C over 2 hours, elevated to 38-42°C over 3 hours, elevated to 115-125°C over 12 hours, maintained at 115-125°C over 2 hours and decreased to 60-80°C over 2 hours. Then, the composition is released from the mold to obtain an optical lens. The optical lens thus obtained is subjected to annealing at 100 to 120°C for 1 to 4 hours to obtain an intended plastic optical lens.
To improve optical properties, the plastic optical lens is subjected to hard-coating and multi-coating. The hard coating layer is formed by impregnating a coating composition into the optical lens, or coating the composition onto the surface thereof to a thickness of 0.5 to 10 μm by spin coating, followed by heating or UV curing. The coating composition comprises at least one si1 lane compound and at least one colloidal metal oxide as main ingredients. The si 1lane compound contains one functional group selected from epoxy, alkoxy and vinyl groups. Examples of metal oxide include silicon oxide, titanium oxide, antimony oxide, tin oxide, tungsten oxide and aluminum oxide.
A multi-coating layer, i.e. an antireflective layer, is formed by vacuum- depositing or sputtering metal oxide such as silicon oxide, magnesium fluoride, aluminum oxide, zirconium oxide, titanium oxide, tantalum oxide and yttrium oxide. Most preferably, silicon oxide and zirconium oxide are vacuum-deposited three times on the hard-coating layers of the both sides of the optical lens and silicon oxide is then vacuum-deposited on the resulting structure. If needed, an ITO layer between the silicon oxide and the zirconium oxide may be further formed as a water layer on the outermost layer.
If necessary, the optical lens of the present invention may be dyed with a dispersive dye or electrochromic dye.
The optical resin composition is not particularly limited to plastic optical lenses. Accordingly, the composition may be utilized in various optical products.
[Mode for Invention]
The present invention will be better understood from the following examples. These examples are not to be construed as limiting the scope of the invention.
EXAMPLES Example 1
(1) Into a mixing container equipped with a stirrer were injected: a mixture of 53.2g of hexamethylene diisocyanate (HMDI) and 362g of isophorone diisocyanate (IPDI); 584.δg of pentaerythritol tetrakis(3-mercaptopropionate) (PETMP); 2Og of 2-(2'-hydroxy-5-methylρhenyl)-2H-benzotriazole as an UV absorber; O.lg of diisopropyl phosphate as a release agent; 20 ppm of 1- hydroxy-4-(p-toluidine)anthraquinone as a 1% organic dye solution (blue); 10
TM ppm of a PERINONE dye as a 1% organic dye solution (red); and 1.0 g of butyltin dilaurate as a polymerization initiator. The air in the mixing container was replaced by nitrogen. Then, the composition was stirred under
reduced pressure for 2 hours. After completion of the stirring, the composition was defoamed under reduced pressure and injected into a glass mold fixed with a polyester adhesive tape (diopter (D): -5.00).
(2) The glass mold containing the composition was thermally cured in a forced convection oven under the conditions of maintaining at 35 0 C over 2 hours, elevating to 40°C over 3 hours, elevating to 12O 0 C over 12 hours, maintaining at 120 0 C over 2 hours and decreasing to 70°C over 2 hours. Then, the composition was released from the mold to obtain an optical lens with a central thickness of 1 mm.
(3) After the optical lens thus obtained in (2) was processed such that it has a diameter of 72 mm, it was ultrasonic-cleaned with an aqueous alkaline cleaning solution and annealed at 120°C for 2 hours.
(4) The optical lens thus obtained in (3) was dipped in a hard solution
IM
(ST11TN-8H available from Finecoat Co., Ltd.) and thermal-cured. Silicon oxide, zirconium oxide, silicon oxide, ITO, zirconium oxide, and a fluoride resin were sequentially vacuum-deposited on the both sides of the resulting lens to obtain a hard- and multi-coated optical lens.
Test methods
The physical properties of the optical lens were evaluated in accordance with the following manner. The results are shown in Table 1.
1. Refractive index and Abbe Number:
A DTM-I model (Atacota Co., LTD.) was used as an Abbe refractometer.
2. Light transmittance:
A spectrophotometer was used to measure a light transmittance.
3. Specific gravity:
The specific gravity was calculated from the volume and weight which were measured by water-displacement.
4. Heat resistance:
The optical lens (Deopter: -5.00) was stood in an oven at 100°C for 2 hours and allowed to cool to 70°C over one hour. After the lens was taken
out from the oven, it was observed whether or not the center of the lens was depressed. In a case where 8 or more out of 10 lenses are not center- depressed, it was represented by 11 O". Otherwise, in a case where 3 or more out of the 10 lenses are center-depressed, it was represented by "x".
5. Defoaming:
Ten optical lenses were produced by injecting the composition into a mold and thermally-curing in the same manner as in Example 1. It was observed whether or not bubbles were formed in the edges or center of the optical lenses. The foaming degree of the optical lenses was classified into the following three grades: a) none out of ten lenses was foamed: grade "O"; b) one to three out of ten was foamed: grade "δ"; and c) four or more out of ten were foamed: grade "x".
6. Impact resistance:
A steel ball with a weight of 16.8 g (FDA standard weight) was let fall from a height of 127 cm onto the center of ten optical lenses (deopter: -5.00) which were hard-coated and multi-coated. At this time, in a case where none of the ten optical lenses was broken, "O" was graded. Otherwise, in a case where at least one out of the ten was broken, "x" was graded.
7. Light resistance:
The optical lenses (diopter: -5.00) were exposed to QUV/Spray model (5w) available from Q-Pannellad products for 200 hours. When the lenses were not changed in color, "O" was graded. Otherwise, "x" was graded.
8. Demoldability:
A mixture of monomers, additives and a polymerization initiator was vacuunrdefoamed, injected into a glass mold and thermally-cured to produce a lens. In a case where the lens was released from the mold without causing damage to the mold, the lens was graded "O". Otherwise, the lens was graded " x ".
Examples 2 to 24
In the same manner as in Example 1, optical resin compositions were each prepared in accordance with the compositions as set forth in Tables 1 to 3 and a lens was produced from the composition. The results are shown in Tables 1 to 3.
Comparative Example 1
An optical resin composition was prepared in the same manner as in Example 1, except that 300% by weight of dialIyI therephthalate and 300% by weight of ethylene glycol bis(allyl)carbonate were mixed with 400% by weight of the component (A) represented by Formula (I) below:
CH2=CHCH 2 0C0-Rl-C00-(R 2 0C0-Rl-C00) B -CH2CH=CH2 (Component A) wherein Ri is benzene; R 2 is a compound containing 4 carbon atoms! and m represents 1 to 4 (83%), 5 to 10 (14%), and 11 to 20 (3%).
Comparative Examples 2 to 8
In the same manner as in Comparative Example 1, an optical resin composition was prepared in accordance with the composition as set forth in Table 4 and a lens was then produced from the composition. The results are shown in Table 4.
[Table 1]
[Table 2]
[Table 3]
[Table 4]
List of Abbreviations in Tables 1 to 4 * Monomers
IPDI: isophorone diisocyanate
HMDI: hexamethylene diisocyanate
PETMP: pentaerythritol tetrakis(3-mercaptopropionate)
PETMA: pentaerythritol tetrakis(mercaptoacetate)
XDI : m-χylene-diisocyanate
DBzM: dibenzyl maleate
DAIP: dialIyI isophthalate
P-DAIPE". ethylene glycol polyester oligomer isophthalate
CR-39: diethylene glycol bis(allyl)carbonate
BMEMP: l,2-bis(mercaρtoethyl)-3-mercaρtoρroρan
* UV absorbers
HMBT: 2-(2'-hydroxy-5-methylρhenyl)-2H-benzotriazole HBCBT: 2-(2'-hydroxy-3' ,5'-di-t-butylρheny1)-5-chloro-2H-benzotriazole HBMCBT: 2-(2'-hydroxy-3 1 -t-butyl-5 1 -methyphenyl)-5-chloro-2H- benzotriazo1e
HAPBT: 2-(2'-hydroxy-3 1 ,5'-di-t-araylρhenyl)-2H-benzotriazole
HDBPBT: 2-(2'-hydroxy-3' ,5'-di-t-butylρhenyl)-2H-benzotriazole
HBPBT: 2-(2'-hydroxy-5'-t-butylρhenyl)-2H-benzotriazole
HOPBT: 2-(2'-hydroxy-5'-t-octylphenyl)-2H-benzotriazole
DHBP: 2,4-dihydroxybenzophenone
HMBP: 2-hydroxy-4-methoxybenzophenone
HOOBP: 2-hydroxy-4-octy1oxybenzophenone
DOHBP: 4-dodecy1oxy-2-hydroxybenzophenone
BHBP: 4-benzoxy-2-hydroxybenzophenone
THBP: 2,2',4,4 l -tetrahydroxybenzophenone
DHMBP: 2,2'-dihydroxy-4,4'-dimethoxybenzophenone
BHMCBT: 2-(3'-t-butyl-2'-hydroxy-methylphenyl)-5-chlorobenzotriazole
* Release agents
IPPT: isopropyl phosphate
DIPP: diisopropyl phosphate BP: butyl phosphate OP: octyl phosphate DOP: dioctyl phosphate IDP: isodecyl phosphate DIDP: diisodecyl phosphate TDP: tridecanol phosphate BTDP: bis(tridecanol) phosphate
* 1% dye solution
1 g of each organic dye was dissolved in 99 g of toluene to prepare 1% organic dye solutions.
HTAQ: 1-hydroxy-4-(ρ-toluidine)anthraquinone PRD: Perinone dye
* Pigment dispersion
TM
0.9 g of dye particles (PB-80 available from Daiichi Kasei Co., Ltd.; diameter of 0.3 to 2μm) , 0.1 g of dye particles (500RS available from Toso Co., Ltd.) and 0.175 g of polyoxyethylene nonylether are dispersed in CR-39 lOOg with the use of a ball mill for 2 hours and filtered through a filter paper (2 μm) to prepare a pigment dispersion.
* Polymerization initiators BTL: butyltin dilaurate BTC: dibutyltin dichloride BTA: dibutyltin diacetate TEA: triethylamine
IPP: diisopropyl peroxydicarbonate NPP: di-n-propyl peroxydicarbonate
[Industrial Applicability]
As apparent from the foregoing, the optical resin composition has superior impact resistance as well as light-weight, superior moldability, excellent dyeing ability, a high Abbe number and good transparency. The optical lens produced from the composition maintains superior impact resistance even after hard-coating and multi-coating (anti-reflective coating). Based on these advantages, the resin composition may be widely utilized in the optical field including multicoated spectacle lenses.