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Title:
OPTOELECTRONIC SEMICONDUCTOR DEVICE AND MANUFACTURING METHOD OF AN OPTOELECTRONIC SEMICONDUCTOR DEVICE
Document Type and Number:
WIPO Patent Application WO/2023/222385
Kind Code:
A1
Abstract:
An optoelectronic semiconductor device (1) is described comprising - at least one semiconductor layer stack (2) including an active region (5) and having one or more side surfaces (2C), wherein the active region (5) extends to the one or more side surfaces (2C), - a regrowth semiconductor layer (7) covering the active region (5) at the one or more side surfaces (2C), wherein the at least one semiconductor layer stack (2) is free of etching traces at the one or more side surfaces (2C). For example, the optoelectronic semiconductor device (1) is a MicroLed also known for example as micro-LED, μLED, μ-LED, uLED, u-LED or micro light emitting diode. Moreover, a manufacturing method for producing such an optoelectronic semiconductor device (1) is described.

Inventors:
KASPRZAK-ZABLOCKA ANNA (DE)
HETZL MARTIN (DE)
VARGHESE TANSEN (DE)
Application Number:
PCT/EP2023/061687
Publication Date:
November 23, 2023
Filing Date:
May 03, 2023
Export Citation:
Click for automatic bibliography generation   Help
Assignee:
AMS OSRAM INT GMBH (DE)
International Classes:
H01L21/02; H01L33/00; H01L33/44; H01L33/20
Foreign References:
US20200313036A12020-10-01
JP2011114155A2011-06-09
US20160315218A12016-10-27
CN113410355A2021-09-17
DE102022112344A2022-05-17
Attorney, Agent or Firm:
EPPING HERMANN FISCHER PATENTANWALTSGESELLSCHAFT MBH (DE)
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Claims:
Claims

1. An optoelectronic semiconductor device (1) comprising

- at least one semiconductor layer stack (2) including an active region (5) and having one or more side surfaces (2C) , wherein the active region (5) extends to the one or more side surfaces (2C) ,

- a regrowth semiconductor layer (7) covering the active region (5) at the one or more side surfaces (2C) , wherein the at least one semiconductor layer stack (2) is free of etching traces at the one or more side surfaces (2C) .

2. The optoelectronic semiconductor device (1) according to the preceding claim, wherein the regrowth semiconductor layer (7) covers every side surface (2C) at least for the most part .

3. The optoelectronic semiconductor device (1) according to any of the preceding claims, wherein the regrowth semiconductor layer (7) extends from the one or more side surfaces (2C) to a main surface (2A) of the at least one semiconductor layer stack (2) , wherein the main surface (2A) is arranged obliquely to every side surface (2C) .

4. The optoelectronic semiconductor device (1) according to the preceding claim, wherein the regrowth semiconductor layer (7) comprises an opening (8) at the main surface (2A) , and an electric contact layer (9) is arranged in the opening (8) and electrically contacts the at least one semiconductor layer stack ( 2 ) .

5. The optoelectronic semiconductor device (1) according to any of the preceding claims, wherein a semiconductor material system of the at least one semiconductor layer stack (2) and/or the regrowth semiconductor layer (7) is InGaAlP or AlInGaAsP.

6. The optoelectronic semiconductor device (1) according to any of the preceding claims, wherein the at least one semiconductor layer stack (2) has a cross section similar to an acute trapezoid, wherein values of each acute angle (a) range between 15° and 60°.

7. The optoelectronic semiconductor device (1) according to any of the preceding claims, which is a MicroLed.

8. A manufacturing method for producing an optoelectronic semiconductor device (1) according to any of the preceding claims, comprising the following steps:

- providing a patterned growth substrate (14) comprising at least one opening (12) ,

- growing a semiconductor layer sequence (15) on the patterned growth substrate (14) such that the semiconductor layer sequence (15) is arranged in the at least one opening (12) , wherein the semiconductor layer sequence (15) in the at least one opening (12) forms a semiconductor layer stack (2) including an active region (5) and having one or more side surfaces (2C) ,

- removing parts of the patterned growth substrate (14) which cover the one or more side surfaces (2C) of the at least one semiconductor layer stack (2) ,

- depositing a regrowth semiconductor layer (7) on the one or more side surfaces (2C) of the at least one semiconductor layer stack (2) , wherein the regrowth semiconductor layer (7) covers the active region (5) at the one or more side surfaces 9. The manufacturing method according to the preceding claim, wherein the at least one semiconductor layer stack (2) is formed with a height (h) lower than a depth (d) of the at least one opening (12) .

10. The manufacturing method according to either of the two preceding claims, wherein the step of removing parts of the patterned growth substrate (14) includes an etching process.

11. The manufacturing method according to claims 8 to 10, wherein the step of providing a patterned growth substrate

(14) includes providing a growth substrate layer (10) and removing material from the growth substrate layer (10) to form the at least one opening (12) of the patterned growth substrate (14) , wherein the growth substrate layer (10) comprises a semiconductor material.

12. The manufacturing method according to claims 8 to 10, wherein the step of providing a patterned growth substrate

(14) includes providing a growth substrate layer (10) , which comprises a semiconductor material, and forming a patterned layer (16) on the growth substrate layer (10) , wherein the patterned layer (16) comprises the at least one opening (12) of the patterned growth substrate (14) .

13. The manufacturing method according to the preceding claim, wherein the patterned layer (16) comprises a dielectric material.

14. The manufacturing method according to the preceding claim, wherein the step of forming the patterned layer (16) includes : - providing a resist mask (11) on the growth substrate layer (10) in areas where the at least one opening (12) is to be formed,

- depositing material (16' ) of the patterned layer (16) on the growth substrate layer (10) around the resist mask (11) , and

- removing the resist mask (11) , wherein the at least one opening (12) is formed.

15. The manufacturing method according to claim 12, wherein the patterned layer (16) comprises a semiconductor material.

16. The manufacturing method according to the preceding claim, wherein the step of forming the patterned layer (16) includes :

- providing a resist mask (11) on the growth substrate layer (10) in areas where the patterned layer (16) is to be formed,

- depositing a dielectric material (17) on the growth substrate layer (10) around the resist mask (11) ,

- removing the resist mask (11) ,

- depositing material (16' ) of the patterned layer (16) on the growth substrate layer (10) in areas where the resist mask (11) has been removed, and

- removing the dielectric material (17) , wherein the at least one opening (12) is formed.

Description:
Description

OPTOELECTRONIC SEMICONDUCTOR DEVICE AND MANUFACTURING METHOD OF AN OPTOELECTRONIC SEMICONDUCTOR DEVICE

An optoelectronic semiconductor device and a manufacturing method for producing such an optoelectronic semiconductor device are speci fied . For example , the optoelectronic semiconductor device is suited for emitting electromagnetic radiation, in particular in the infrared, visible or ultraviolet spectral range .

In an exemplary method for producing an optoelectronic semiconductor device , a semiconductor layer stack of the optoelectronic semiconductor device may be produced by patterning a semiconductor layer sequence by means of an etching process . In this context , the problem can arise that some layers of the semiconductor layer sequence having a heterostructure are etched with di f ferent etch rates and thus undergo underetching, which leads to steps between layers of di f ferent material compositions at side surfaces of the semiconductor layer stack . However, for a subsequent layer applied to the side surfaces of the semiconductor layer stack, it is crucial that a slope of the semiconductor layer stack is rather smooth . Especially i f the subsequent layer is grown on the side surfaces , a smooth slope is important . Otherwise , it can have a lot of defects , which decrease device ef ficiency .

One obj ect inter alia is to speci fy an optoelectronic semiconductor device providing improved ef ficiency . This obj ect is achieved inter alia by the optoelectronic semiconductor device according to the independent claim . Further embodiments and further developments of the optoelectronic semiconductor device are the subj ect-matter of the dependent claims .

Another obj ect inter alia is to speci fy a manufacturing method for producing an optoelectronic semiconductor device providing improved ef ficiency . This obj ect is achieved inter alia by the manufacturing method according to the independent claim . Further embodiments and further developments of the manufacturing method are the subj ect-matter of the dependent claims .

According to at least one embodiment of an optoelectronic semiconductor device , it comprises at least one semiconductor layer stack including an active region . The active region may be provided for generating and emitting electromagnetic radiation . For example , the optoelectronic semiconductor device is suitable for emitting electromagnetic radiation having a wavelength in the infrared, visible or ultraviolet spectral range .

Moreover, the semiconductor layer stack may comprise one or more side surfaces . Dependent on the geometry of the semiconductor layer stack, it has one side surface , for example i f cylindrical , or several side surfaces , for example i f polyhedral . The one or more side surfaces delimit the semiconductor layer stack in lateral directions .

Furthermore , the active region may extend to the one or more side surfaces . In other words , a side surface or side surfaces of the active region may form a part of the one or more side surfaces of the semiconductor layer stack . According to at least one embodiment , the optoelectronic semiconductor device comprises a regrowth semiconductor layer covering the active region at the one or more side surfaces . In other words , the regrowth semiconductor layer may be arranged on the one or more side surfaces of the semiconductor layer stack such that it covers the active region or side surfaces of the active region . By means of the regrowth semiconductor layer covering the active region, the number of traps at the one or more side surfaces can be reduced and thus radiation ef ficiency of the active region can be improved .

According to at least one embodiment , the at least one semiconductor layer stack is free of etching traces at the one or more side surfaces . Etching traces are recogni zable in the surface structure of the semiconductor layer stack, for example in the form of steps between layers of di f ferent material compositions at side surfaces of the semiconductor layer stacks . A manufacturing method presented here does not require any direct etching process for structuring the semiconductor layer stack, and thus the semiconductor layer stack may have a rather smooth slope and fewer defects occur in the regrowth semiconductor layer than in the case of an etching process .

According to at least one embodiment of an optoelectronic semiconductor device , it comprises :

- at least one semiconductor layer stack including an active region and having one or more side surfaces , wherein the active region extends to the one or more side surfaces ,

- a regrowth semiconductor layer covering the active region at the one or more side surfaces , wherein the at least one semiconductor layer stack is free of etching traces at the one or more side surfaces .

According to at least one embodiment or configuration, the regrowth semiconductor layer is applied directly on the semiconductor layer stack . Hence , the regrowth semiconductor layer and the semiconductor layer stack may touch each other .

According to at least one embodiment or configuration, the regrowth semiconductor layer covers every side surface at least for the most part . In other words , the semiconductor layer stack may be laterally surrounded at least for the most part by the regrowth semiconductor layer .

According to at least one embodiment or configuration, the regrowth semiconductor layer extends from the one or more side surfaces to a main surface of the at least one semiconductor layer stack . In other words , the regrowth semiconductor layer may also cover the main surface . The main surface may be arranged obliquely to every side surface . For example , the main surface may delimit the semiconductor layer stack in a vertical direction, wherein the vertical direction runs perpendicularly to the lateral directions . For example , the vertical direction is the direction in which semiconductor layers of the semiconductor layer sequence follow one another .

According to at least one embodiment or configuration, the regrowth semiconductor layer comprises an opening at the main surface . Hence , the regrowth semiconductor layer partly covers the main surface . An electric contact layer may be arranged in the opening and may electrically contact the at least one semiconductor layer stack . The electric contact layer may comprise a metallic layer and/or a layer of a transparent conductive oxide , like ITO . Alternatively, the regrowth semiconductor layer may be formed without any opening at the main surface . And the electric contact layer may electrically contact the regrowth semiconductor layer in this case .

According to at least one embodiment or configuration, a semiconductor material system of the semiconductor layer stack and/or the regrowth semiconductor layer is InGaAlP or Al InGaAsP . However, it is also possible that the semiconductor layer stack and/or the regrowth semiconductor layer are based on an Al InGaN material system or on an Al InGaAs material system . For example , in the case of an InGaAlP or Al InGasAsP material system, the regrowth semiconductor layer may comprise an undoped InGaAlP layer or a p-doped InAlP layer . Moreover, in the case of an Al InGaN material system, the regrowth semiconductor layer may comprise an undoped InGaAlN layer or a p-doped InGaAlN layer . Especially, the semiconductor layer stack and the regrowth semiconductor layer are based on the same semiconductor material system .

According to at least one embodiment or configuration, the semiconductor layer stack comprises a first semiconductor region of a first conductivity type , for example a p-doped semiconductor region, and a second semiconductor region of a second conductivity type , for example an n-doped semiconductor region .

The active region may be arranged between the first and second semiconductor regions . The active region may comprise a sequence of single layers which form a quantum well structure , in particular a single quantum well ( SQW) structure or multiple quantum well (MQW) structure .

Moreover, the first and second semiconductor regions may each have a sequence of single layers , some of which may be undoped or lightly doped . The single layers of the semiconductor regions may be epitaxially deposited on a patterned growth substrate .

Moreover, the regrowth semiconductor layer may be single layer and can be made of a single material homogeneously distributed all across the regrowth semiconductor layer . But it is also possible that the regrowth semiconductor layer is a multi-layer and comprises two or more sub-layers . Adj acent sub-layers or all the sub-layers may di f fer from each other in a material composition and/or in a doping concentration and/or in a doping type .

According to at least one embodiment or configuration, the at least one semiconductor layer stack has a cross section similar to an acute trapezoid, wherein values of each acute angle range between 15 ° and 60 ° . The manufacturing method presented here , which does not require any direct etching process , allows for selecting the angles rather freely .

According to at least one embodiment or configuration, the optoelectronic semiconductor device comprises a plurality of semiconductor layer stacks as described above , wherein every semiconductor layer stack includes an active region and has one or more side surfaces . The semiconductor layer stacks may be arranged on a common carrier . Especially, the optoelectronic semiconductor device comprises a regrowth semiconductor layer covering every active region at the one or more side surfaces of the semiconductor layer stacks .

According to at least one embodiment or configuration, the optoelectronic semiconductor device is a MicroLed also known for example as micro-LED, pLED, p-LED, uLED, u-LED or micro light emitting diode . In this embodiment or configuration, the optoelectronic semiconductor device has a particularly small si ze .

The method described below is suitable for the production of an optoelectronic semiconductor device described here . The features described in connection with the optoelectronic semiconductor device can therefore also apply to the method, and vice versa .

According to at least one embodiment of a manufacturing method for producing an optoelectronic semiconductor device as described above , the method comprises the following steps , preferably in the stated order :

- providing a patterned growth substrate comprising at least one opening,

- growing, especially epitaxially growing, a semiconductor layer sequence on the patterned growth substrate such that the semiconductor layer sequence is arranged in the at least one opening, wherein the semiconductor layer sequence in the at least one opening forms a semiconductor layer stack including an active region and having one or more side surfaces ,

- removing parts of the patterned growth substrate which cover the one or more side surfaces of the at least one semiconductor layer stack, - depositing, especially epitaxially growing, a regrowth semiconductor layer on the one or more side surfaces of the at least one semiconductor layer stack, wherein the regrowth semiconductor layer covers the active region at the one or more side surfaces .

Due to the growth in the at least one opening, the semiconductor layer stack formed therein essentially, that is within common production tolerances , has the same three- dimensional shape as the at least one opening . And the semiconductor layer stack can be grown with a desired three- dimensional shape . Hence , there is no need for patterning the semiconductor layer sequence , for example by an etching process , in order to create a semiconductor layer stack having a desired three-dimensional shape . And thus , the at least one semiconductor layer stack can be produced without etching traces at the one or more side surfaces . For example , the three-dimensional shape of the semiconductor layer stack and the opening may be a truncated cone or a truncated pyramid .

According to at least one embodiment or configuration, the at least one semiconductor layer stack is formed with a height lower than a depth of the at least one opening . This leads to portions of the patterned growth substrate which proj ect beyond a main surface of the at least one semiconductor layer stack facing away from a bottom of the opening . The portions proj ecting beyond the main surface facilitate the removal of parts of the patterned growth substrate . For example , a height of the at least one semiconductor layer stack is at least 0 . 2 pm and at most 10 pm . The height and depth may be determined along the vertical direction . According to at least one embodiment or configuration, the step of removing parts of the patterned growth substrate includes an etching process . The step of removing parts of the patterned growth substrate may be preceded by a step of removing the semiconductor layer sequence on the parts to be removed by chemical mechanical polishing, for example .

According to at least one embodiment or configuration, the step of providing a patterned growth substrate includes providing a growth substrate layer and removing material from the growth substrate layer to form the at least one opening of the patterned growth substrate , wherein the growth substrate layer comprises a semiconductor material . For example , the growth substrate layer may comprise or consist of GaAs . For example , the growth substrate layer may be patterned by lithography using a resist mask and an etching process , for example a wet chemical etching process .

Alternatively, the step of providing a patterned growth substrate may include providing a growth substrate layer, which comprises or consists of a semiconductor material , for example GaAs , and forming a patterned layer on the growth substrate layer, wherein the patterned layer comprises the at least one opening of the patterned growth substrate .

According to at least one configuration, the step of forming the patterned layer may include :

- providing a resist mask on the growth substrate layer in areas where the at least one opening is to be formed,

- depositing material of the patterned layer on the growth substrate layer around the resist mask, and - removing the resist mask, wherein the at least one opening is formed . The patterned layer may comprise a dielectric material , for example A12O3 .

The step of depositing material of the patterned layer on the growth substrate layer may include a sputtering process or any low temperature process which does not lead to a damage of the resist mask .

Moreover, the step of removing the resist mask may be preceded by a step of removing the material of the patterned layer on an upper surface of the resist mask facing away from the growth substrate layer, for example by chemical mechanical polishing or dry etching, and then removing the resist mask, for example by a solvent .

Alternatively, the step of forming the patterned layer may include :

- providing a resist mask on the growth substrate layer in areas where the patterned layer is to be formed,

- depositing a dielectric material , for example SiO2 , on the growth substrate layer around the resist mask,

- removing the resist mask,

- depositing material of the patterned layer on the growth substrate layer in areas where the resist mask has been removed, and

- removing the dielectric material , wherein the at least one opening is formed . For example , the patterned layer may comprise a semiconductor material like GaAs . The patterned layer may be grown, especially epitaxially grown, on the growth substrate layer . The step of depositing the dielectric material on the growth substrate layer may include a sputtering process or any low temperature process which does not lead to a damage of the resist mask .

Moreover, the step of removing the resist mask may be preceded by a step of removing the dielectric material on the upper surface of the resist mask together with the resist mask by a li ft-of f technique or by chemical mechanical polishing and resist stripping .

Furthermore , the step of removing the dielectric material to create the at least one opening may include an etching process .

In the embodiments described, the step of providing a resist mask may include applying a resist layer on the growth substrate layer and patterning the resist layer by lithography .

The optoelectronic semiconductor device presented here may be a MicroLed and is suitable for AR ( augmented reality) , VR (virtual reality) and display applications . The MicroLed or a plurality of microLeds may form pixels or subpixels of a display device and emit light of a defined color . Small pixel si ze and a high density with close distances make the microLed ( s ) suitable , among others , for small monolithic displays for AR applications , especially data glasses . Moreover, the MicroLed ( s ) may be used for communication and lighting applications .

Further preferred embodiments and further developments of the optoelectronic semiconductor device and the manufacturing method for producing the optoelectronic semiconductor device will become apparent from the exemplary embodiments explained below in conj unction with Figures 1 to 9 .

Figure 1 shows a schematic cross-sectional view of an exemplary embodiment of an optoelectronic semiconductor device ,

Figure 2 shows a schematic cross-sectional view of a comparative example of an optoelectronic semiconductor device ,

Figures 3A to 3F show schematic cross-sectional views of method steps of a first exemplary embodiment of a manufacturing method for optoelectronic semiconductor devices described herein,

Figures 3A to 3C and 4A to 4C show schematic cross-sectional views of method steps of a second exemplary embodiment of a manufacturing method for optoelectronic semiconductor devices described herein,

Figures 5 to 7 show schematic cross-sectional views of patterned growth substrates according to di f ferent exemplary embodiments ,

Figures 8A to 8H show schematic cross-sectional views of method steps of a third exemplary embodiment of a manufacturing method for optoelectronic semiconductor devices described herein, Figures 9A to 91 show schematic cross-sectional views of method steps of a forth exemplary embodiment of a manufacturing method for optoelectronic semiconductor devices described herein .

Identical , equivalent or equivalently acting elements may be indicated with the same reference numerals in the figures . The figures are schematic illustrations and thus not necessarily true to scale . Comparatively small elements and particularly layer thicknesses can rather be illustrated exaggeratedly large for the purpose of better clari fication .

Figure 1 illustrates an exemplary embodiment of an optoelectronic semiconductor device 1 . The optoelectronic semiconductor device 1 comprises two or more semiconductor layer stacks 2 . However, as indicated by a separation line , it is also possible that the optoelectronic semiconductor device 1 comprises only one semiconductor layer stack 2 . The semiconductor layer stacks 2 are arranged on a common carrier 3 , which may be a part of a patterned growth substrate 14 used for depositing a semiconductor layer sequence 15 in order to produce the semiconductor layer stacks 2 as described below in more detail ( see Figures 3D to 3F, for example ) .

The semiconductor layer stacks 2 in each case include an active region 5 , in particular for generating and emitting electromagnetic radiation . For example , the optoelectronic semiconductor device 1 is suitable for emitting electromagnetic radiation having a wavelength in the infrared, visible or ultraviolet spectral range . Moreover, the semiconductor layer stacks 2 in each case comprise a first semiconductor region 4 of a first conductivity type , for example a p-doped semiconductor region, and a second semiconductor region 6 of a second conductivity type , for example an n-doped semiconductor region .

The active region 5 is arranged between the first and second semiconductor regions 4 , 6 and may comprise a sequence of single layers which form a quantum well structure , in particular a single quantum well ( SQW) structure or multiple quantum well (MQW) structure . Moreover, the first and second semiconductor regions 4 , 6 may each have a sequence of single layers , some of which may be undoped or lightly doped (not shown) .

The semiconductor layer stacks 2 in each case have a three- dimensional shape similar to a truncated pyramid and at least three , preferably at least four, side surfaces 2C, which delimit the respective semiconductor layer stack 2 in lateral directions L and run obliquely to a main extension plane of the carrier 3 . The lateral directions L may be parallel to the main extension plane of the carrier 3 . The semiconductor layer stacks 2 in each case have a cross section similar to an acute trapezoid, wherein values of each acute angle a range between 15 ° and 60 ° . The angle a is the angle between the respective side surface 2C and a second main surface 2B .

The active regions 5 in each case run essentially, that is within common production tolerances , parallel to the main extension plane of the carrier 3 and extend to the side surfaces 2C . In other words , side surfaces of the active regions 4 may in each case form a part of the side surfaces 2C of the semiconductor layer stacks 2 .

The optoelectronic semiconductor device 1 further comprises a regrowth semiconductor layer 7 covering the active regions 5 at the side surfaces 2C of every semiconductor layer stack 2 . In other words , the regrowth semiconductor layer 7 is arranged on the side surfaces 2C of every semiconductor layer stack 2 such that it covers the active regions 5 or the side surfaces of the active regions 5 . Especially, the regrowth semiconductor layer 7 covers every side surface 2C at least for the most part such that the semiconductor layer stacks 2 in each case are laterally surrounded at least for the most part by the regrowth semiconductor layer 7 . The regrowth semiconductor layer 7 may be applied directly on the semiconductor layer stacks 2 and thus touch the semiconductor layer stacks 2 . Preferably, the regrowth semiconductor layer 7 is epitaxially grown on the semiconductor layer stacks 2 .

By means of the regrowth semiconductor layer 7 covering the active regions 5 , the number of traps at the side surfaces 2C can be reduced and thus radiation ef ficiency of the active regions 5 can be improved .

The regrowth semiconductor layer 7 extends in each case from the side surfaces 2C to a first main surface 2A of the semiconductor layer stacks 2 , wherein the first main surface 2A in each case is arranged on a side opposite to the carrier 3 and obliquely to every side surface 2C . The main surface 2A in each case delimits the semiconductor layer stack 2 in a vertical direction V, wherein the vertical direction V runs perpendicularly to the lateral directions L . Moreover, the second main surface 2B in each case delimits the semiconductor layer stack 2 on a side facing the carrier 3 .

The regrowth semiconductor layer 7 comprises an opening 8 at every first main surface 2A and hence partly covers the respective first main surface 2A. An electric contact layer 9 is arranged on a side of the regrowth semiconductor layer 7 facing away from the semiconductor layer stacks 2 and extends in the openings 8 . The electric contact layer 9 in each case electrically contacts the semiconductor layer stacks 2 . The electric contact layer 9 may comprise a metallic layer and/or a layer of a transparent conductive oxide , like ITO . Alternatively, the regrowth semiconductor layer 7 may be formed without any opening at the first main surface 2A. And the electric contact layer 9 may electrically contact the regrowth semiconductor layer 7 in this case .

A suitable semiconductor material system of the semiconductor layer stacks 2 and/or the regrowth semiconductor layer 7 is InGaAlP or Al InGaAsP . However, it is also possible that the semiconductor layer stacks 2 and/or the regrowth semiconductor layer 7 are based on an Al InGaN material system or on an Al InGaAs material system . For example , in the case of an InGaAlP or Al InGasAsP material system, the regrowth semiconductor layer 7 may comprise an undoped InGaAlP layer or a p-doped InAlP layer . Moreover, in the case of an Al InGaN material system, the regrowth semiconductor layer 7 may comprise an undoped InGaAlN layer or a p-doped InGaAlN layer . Especially, the semiconductor layer stacks 2 and the regrowth semiconductor layer 7 are based on the same semiconductor material system . The regrowth semiconductor layer 7 may be a single layer and can be made of a single material homogeneously distributed all across the regrowth semiconductor layer 7 . But it is also possible that the regrowth semiconductor layer 7 is a multilayer and comprises two or more sub-layers (not shown) . Adj acent sub-layers or all the sub-layers may di f fer from each other in a material composition and/or in a doping concentration and/or in a doping type .

A height h of the semiconductor layer stacks 2 , that is a maximum extension along the vertical direction V, in each case may be at least 0 . 2 gm and at most 10 gm .

Moreover, a width w of the semiconductor layer stacks 2 , that is a maximum extension along at least one lateral direction L, in each case may be at least 200 nm and at most 100 gm .

The optoelectronic semiconductor device 1 may be embodied as a MicroLed with a particularly small si ze including a maximum extension along the vertical direction V ranging from 1 . 5 gm to 10 gm, for example , and a maximum extension along the lateral direction ( s ) L less than or equal to 100 gm or less than or equal to 70 gm or less than or equal to 50 gm .

The semiconductor layer stacks 2 in each case are free of etching traces at the side surfaces 2C . Etching traces are recogni zable in the surface structure of the semiconductor layer stacks 2 , for example in the form of steps between layers of di f ferent material compositions at side surfaces 2C' of the semiconductor layer stacks 2 ' as becomes evident from Figure 2 . The semiconductor layer stacks 2 ' of the comparative example shown in Figure 2 are produced, for example , by patterning a semiconductor layer sequence by means of an etching process , wherein some layers of the semiconductor layer sequence having a heterostructure are etched with di f ferent etch rates and thus undergo underetching, which leads to steps between layers of di f ferent material compositions at the side surfaces 2C' of the semiconductor layer stacks 2 ’ .

However, the semiconductor layer stacks 2 as shown in Figure 1 in each case have a rather smooth slope , and thus fewer defects than in the case of an etching process occur in the regrowth semiconductor layer 7 , which is applied on the side surfaces 2C of the semiconductor layer stacks 2 . This results in an improved device ef ficiency .

In connection with Figures 3A to 3F, a first exemplary embodiment of a manufacturing method for producing an optoelectronic semiconductor device as described in connection with Figure 1 , for example , is explained in more detail .

Starting with Figure 3A, the method comprises the step of providing a growth substrate layer 10 , which comprises or consists of a semiconductor material like GaAs .

Continuing with Figure 3B, the method further comprises the steps of providing a resist layer (not shown) on the growth substrate layer 10 , patterning the resist layer by lithography and producing a resist mask 11 . In a further step, the growth substrate layer 10 is patterned by the resist mask 11 using an etching process , for example a wet chemical etching process , and material is removed from the growth substrate layer 10 such that one or several openings 12 are produced in the growth substrate layer 10 . The patterned growth substrate layer 10 comprises proj ecting portions 13 , which laterally surround the openings 12 , wherein angles a between side surfaces 13C of the proj ecting portions 13 and a respective bottom face 10B at a bottom of the openings 12 in each case are essentially, that is within common production tolerances , identical to the angles a between the side surfaces 2C and the second main surface 2B of the semiconductor layer stack/ s 2 to be produced ( see Figure 1 ) .

As shown in Figure 3C, the resist mask 11 is removed after patterning the growth substrate layer 10 . The patterned growth substrate layer 10 constitutes a patterned growth substrate 14 comprising at least one opening 12 .

Continuing with Figure 3D, the method further comprises the step of growing a semiconductor layer sequence 15 on the patterned growth substrate 14 such that the semiconductor layer sequence 15 is arranged in the openings 12 , wherein the semiconductor layer sequence 15 in the openings 12 in each case forms a semiconductor layer stack 2 including an active region 5 and having one or more side surfaces 2C . The semiconductor layer sequence 15 is formed from the semiconductor material as mentioned above in connection with the semiconductor layer stacks 2 .

In particular, the semiconductor layer sequence 15 is epitaxially grown on the patterned growth substrate 14 . While parasitic growth occurs in each case on main surfaces 13A of the proj ecting portions 13 , the growth conditions can be controlled in such a way that growth on edges of the main surfaces 13A is prevented .

Continuing with Figure 3E , the method further comprises the step of removing the parasitic growth portions on the main surfaces 13A of the proj ecting portions 13 by chemicalmechanical polishing, for example . Here , the semiconductor layer stacks 2 are formed in each case with a height h similar to the height of the proj ecting portions 13 or a depth d of the openings 12 .

Continuing with Figure 3F, the method further comprises the step of removing parts of the patterned growth substrate 14 , which cover the one or more side surfaces 2C of the semiconductor layer stacks 2 . Especially, the proj ecting portions 13 are removed in this step . The removal process is an etching process , for example . After the removal process , the side surfaces 2C may undergo a cleaning process in order to reduce defects . The semiconductor layer stacks 2 produced in this way are arranged on a common carrier 3 , which is a part of the patterned growth substrate 14 , and are laterally spaced from each other by interspaces originating from the removed parts of the patterned growth substrate 14 .

The method further comprises the step of depositing, especially epitaxially growing, a regrowth semiconductor layer 7 on the side surfaces 2C of the semiconductor layer stacks , wherein the regrowth semiconductor layer 7 in each case covers the active regions 5 at the side surfaces 2C .

The method may further comprise the step of producing an electric contact layer (not shown) . Due to the growth in the openings 12 , the semiconductor layer stacks 2 formed therein in each case essentially, that is within common production tolerances , have the same three- dimensional shape as the openings 12 . And the semiconductor layer stacks 2 can be grown with a desired three-dimensional shape . Hence , there is no need for patterning the semiconductor layer sequence 15 , for example by an etching process , in order to create semiconductor layer stacks 2 having a desired three-dimensional shape . And thus , the semiconductor layer stacks 2 can be produced without etching traces at the side surfaces 2C providing for smoother slopes and thus for a better quality of the regrowth semiconductor layer 7 . For example , the three-dimensional shape of the openings 12 may in each case be a truncated pyramid .

In addition, the method may have any of the features , characteristics and advantages mentioned in connection with the further exemplary embodiments .

In connection with Figures 4A to 4C, a second exemplary embodiment of a manufacturing method for producing an optoelectronic semiconductor device as described in connection with Figure 1 , for example , is explained in more detail .

The method steps illustrated in Figures 4A to 4C may be preceded by the method steps described in connection with Figures 3A to 3C .

As illustrated in Figure 4A, when growing the semiconductor layer sequence 15 , the semiconductor layer stacks 2 in the openings 12 are formed with a height h lower than the depth d of the openings 12 . This leads to proj ecting portions 13 , which in each case proj ect beyond the first main surfaces 2A of the semiconductor layer stacks 2 .

The proj ecting portions 13 , which are higher than the semiconductor layer stacks 2 , are easier to remove . The parasitic growth portions of the semiconductor layer sequence 15 on the main surfaces 13A of the proj ecting portions 13 can be removed along with the proj ecting portions 13 or parts of the patterned growth substrate 14 by etching, for example ( see Figure 4B ) . Thus , the step of chemical-mechanical polishing can be omitted .

Subsequent steps of the manufacturing method ( see Figure 4C ) can be conducted as described in connection with Figure 3F .

In addition, the method may have any of the features , characteristics and advantages mentioned in connection with the further exemplary embodiments .

Figures 5 to 7 show di f ferent exemplary embodiments of the patterned growth substrate 14 . As becomes evident from these Figures , the angle a between a side surface 13C of a proj ecting portion 13 and a bottom face 10B at the bottom of an opening 12 can be selected rather freely, for example between 0 ° and 90 ° , preferably between 15 ° and 60 ° , independent of the material of the semiconductor layer sequence and in a manner best suited for depositing the regrowth layer .

In connection with Figures 8A to 8H, a third exemplary embodiment of a manufacturing method for producing an optoelectronic semiconductor device as described in connection with Figure 1 , for example , is explained in more detail .

Starting with Figure 8A, a growth substrate layer 10 is provided, which comprises or consists of a semiconductor material , for example GaAs .

Continuing with Figure 8B, a resist mask 11 is provided on the growth substrate layer 10 in areas where openings 12 of the patterned growth substrate 14 ( see Figure 8E ) are to be formed . A shape of the resist mask 11 can be tuned with lithography conditions .

Continuing with Figure 8C, material 16 ' of a patterned layer 16 ( see Figure 8E ) is deposited on the growth substrate layer 10 around the resist mask 11 . The material 16 ' may cover upper and side surfaces 11A, 11C of the resist mask 11 . The material 16 ' of the patterned layer 16 may be a dielectric material , for example A12O3 . The material 16 ' of the patterned layer 16 may be deposited by a sputtering process or any low temperature process which does not lead to a damage of the resist mask 11 .

Continuing with Figure 8D, the material 16 ' of the patterned layer 16 on the upper surface 11A of the resist mask 11 facing away from the growth substrate layer 10 is removed by chemical mechanical polishing or dry etching, for example .

Continuing with Figure 8E , the resist mask 11 is removed by a solvent , for example , and thus a patterned layer 16 is formed comprising openings 12 . The growth substrate layer 10 with the patterned layer 16 constitutes a patterned growth substrate 14 . Continuing with Figure 8 F, a semiconductor layer sequence 15 is grown on the patterned growth substrate 14 such that the semiconductor layer sequence 15 is arranged in the openings 12 , wherein the semiconductor layer sequence 15 in the openings 12 in each case forms a semiconductor layer stack 2 including an active region 5 and having one or more side surfaces 2C . The growth process can be an MOCVD (Metal- Organic Chemical Vapor Deposition) process . The semiconductor layer stacks 2 are at the most as high as the openings 12 are deep .

Continuing with Figure 8G, parts of the patterned growth substrate 14 which cover the side surfaces 2C of the semiconductor layer stacks 2 , are removed . Especially, the parts which are removed are proj ecting portions 13 of the patterned growth substrate 14 formed by the patterned layer 16 . After the removal process , the side surfaces 2C may undergo a cleaning process in order to reduce defects . The semiconductor layer stacks 2 produced in this way are arranged on a common carrier 3 , which is a part of the patterned growth substrate 14 , and are laterally spaced from each other by interspaces originating from the removed parts of the patterned growth substrate 14 .

Subsequent steps of the manufacturing method ( see Figure 8H) can be conducted as described in connection with Figure 3F .

In addition, the method may have any of the features , characteristics and advantages mentioned in connection with the further exemplary embodiments . In connection with Figures 9A to 91 , a forth exemplary embodiment of a manufacturing method for producing an optoelectronic semiconductor device as described in connection with Figure 1 , for example , is explained in more detail .

Starting with Figure 9A, a growth substrate layer 10 is provided, which comprises or consists of a semiconductor material , for example GaAs .

Continuing with Figure 9B, a resist mask 11 is provided on the growth substrate layer 10 in areas where a patterned layer 16 is to be formed ( see Figure 9F) . A shape of the resist mask 11 can be tuned with lithography conditions .

Continuing with Figure 9C, a dielectric material 17 , for example SiO2 , is deposited on the growth substrate layer 10 around the resist mask 11 . The material 17 may cover upper and side surfaces 11A, 11C of the resist mask 11 . The material 17 may be deposited by a sputtering process or any low temperature process which does not lead to a damage of the resist mask 11 .

Continuing with Figure 9D, the resist mask 11 is removed, which is preceded by either removing the dielectric material 17 on the upper surface 11A of the resist mask 11 together with the resist mask 11 by a li ft-of f technique or by chemical mechanical polishing as described in connection with Figure 8D and resist stripping .

Continuing with Figure 9E , material 16 ' of a patterned layer

16 ( see Figure 9F) is deposited on the growth substrate layer

10 in areas where the resist mask 11 ( see Figure 9C ) has been removed . The deposition process may be an epitaxial growth process with controlled conditions to avoid parasitic growth on the dielectric material 17 . The material 16 ' of the patterned layer 16 may be a semiconductor material like GaAs .

Continuing with Figure 9F, the dielectric material 17 is removed, wherein openings 12 are formed . The removal process may be an etching process . The growth substrate layer 10 with the patterned layer 16 constitutes a patterned growth substrate 14 .

Continuing with Figure 9G, a semiconductor layer sequence 15 is grown on the patterned growth substrate 14 such that the semiconductor layer sequence 15 is arranged in the openings 12 , wherein the semiconductor layer sequence 15 in the openings 12 in each case forms a semiconductor layer stack 2 including an active region 5 and having one or more side surfaces 2C .

While parasitic growth occurs in each case on main surfaces 13A of the proj ecting portions 13 , the growth conditions can be controlled in such a way that growth on edges of the main surfaces 13A is prevented .

Continuing with Figure 9H, the parasitic growth portions on the main surfaces 13A of the proj ecting portions 13 are removed by chemical-mechanical polishing, for example . And parts of the patterned growth substrate 14 which cover the one or more side surfaces 2C of the semiconductor layer stacks 2 are removed . Especially, the proj ecting portions 13 are removed in this step . The removal process is an etching process , for example . After the removal process , the side surfaces 2C may undergo a cleaning process in order to reduce defects . The semiconductor layer stacks 2 produced in this way are arranged on a common carrier 3 , which is a part of the patterned growth substrate 14 , and are laterally spaced from each other by interspaces originating from the removed parts of the patterned growth substrate 14 .

Continuing with Figure 91 , a regrowth semiconductor layer 7 is deposited or grown on the side surfaces 2C of the semiconductor layer stacks 2 , wherein the regrowth semiconductor layer 7 in each case covers the active regions 5 at the side surfaces 2C .

In addition, the method may have any of the features , characteristics and advantages mentioned in connection with the further exemplary embodiments .

The invention is not limited to these embodiments by the description based on the embodiments . Rather, the invention includes any new feature and any combination of features , which includes in particular any combination of features in the patent claims , even i f this feature or this combination itsel f is not explicitly indicated in the patent claims or embodiments .

This patent application claims the priority of German patent application 102022112344 . 8 , the disclosure content of which is hereby incorporated by reference . References

I optoelectronic semiconductor device

2 , 2 ' semiconductor layer stack

2A first main surface

2B second main surface

2C, 2C' side surface

3 carrier

4 first semiconductor region

5 active region

6 second semiconductor region

7 regrowth semiconductor layer

8 opening of regrowth semiconductor layer

9 electric contact layer

10 growth substrate layer

10B bottom face

I I resist mask

11A upper surface

11C side surface

12 opening of patterned growth substrate

13 proj ecting portion

13A main surface

13C side surface

14 patterned growth substrate

15 semiconductor layer sequence

16 patterned layer

16 ' material of the patterned layer

17 dielectric material a angle d depth h height w width L lateral direction

V vertical direction