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Title:
ORGANIC ELECTROCHROMIC MATERIALS HAVING HIGH TRANSPARENCY AND HIGH CONTRAST IN THE VISIBLE RANGE
Document Type and Number:
WIPO Patent Application WO/2013/038243
Kind Code:
A3
Abstract:
The present invention relates to electrochromic polymers, obtained by polymerization of monomers. The present invention further relates to monomers of general formula (I) or (II), wherein A and B are specific functional groups selected among the following: -C=0, -C=S, - 0(C=0), -0(C=S), -0(C=0)0, -(C=0)0, -(C=S)0, -(C=S)S, -(C=0)N, -(C=S)N, -SO, - S02, or, as an alternative, any linear or branched alkylic chain or a glycolic chain; wherein R and R' are linear or branched alkylic chains or glycolic chains, and wherein W is a monodisperse electrochromic derivative of general formula (III), wherein Het-1 and Het-2 are specific heterocyclic groups, and wherein π represents one of the following: a double bond, a triple bond or a plurality of double or triple bonds conjugated in a number n, n being equal to 2 or 3 or, for example, a benzenic ring or a thiophenic ring; X represents one of the following elements: O, S, Se; wherein R2, R3 and R4 are substituents; and wherein m is equal to 0, 4, 5 or 6. The present invention also relates to electrochromic panels and electrochromic ophthalmic lenses, comprising polymers in accordance with the present invention.

Inventors:
PAGANI GIORGIO A (IT)
BEVERINA LUCA (IT)
SASSI MAURO (IT)
SALAMONE MATTEO MARCO (IT)
MARI CLAUDIO MARIA (IT)
RUFFO RICCARDO (IT)
Application Number:
PCT/IB2012/001687
Publication Date:
March 13, 2014
Filing Date:
August 30, 2012
Export Citation:
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Assignee:
CONSORZIO INTERUNIVERSITARIO NAZ PER LA SCIENZA E TECNOLOGIA DEI MATERIALI (IT)
UNIV MILANO BICOCCA (IT)
PAGANI GIORGIO A (IT)
BEVERINA LUCA (IT)
SASSI MAURO (IT)
SALAMONE MATTEO MARCO (IT)
MARI CLAUDIO MARIA (IT)
RUFFO RICCARDO (IT)
International Classes:
C09B69/10; C09B23/10
Domestic Patent References:
WO2004092820A12004-10-28
WO2009120658A12009-10-01
WO2005034070A22005-04-14
Foreign References:
EP1928000A12008-06-04
US20040189187A12004-09-30
US20080020208A12008-01-24
Other References:
CZARDYBON A ET AL: "Synthesis, Electrochemical and Spectroelectrochemical Properties of Viologen Derivative of PEDOT", POLISH JOURNAL OF CHEMISTRY, POLSKIE TOWARZYSTWO CHEMICZNE, PL, vol. 78, 31 July 2004 (2004-07-31), pages 1533 - 1541, XP008154613, ISSN: 0137-5083
Attorney, Agent or Firm:
DINI, Roberto et al. (Via Sestriere 100, None, IT)
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