Title:
ORGANOZINC COMPOUND PRODUCING METHOD, CHAIN TRANSFER AGENT, BLOCK COPOLYMER, AND RESIN COMPOSITION
Document Type and Number:
WIPO Patent Application WO/2022/025701
Kind Code:
A1
Abstract:
The present invention relates to a chain transfer agent containing an organozinc compound, a method for preparing same, and a method for preparing a block copolymer using same. A chain transfer agent is obtained by a preparation method comprising the steps of: preparing a Grignard reagent containing a styrene residue; and reacting the prepared Grignard reagent with an alkyl zinc alkoxide as a zinc compound, and has no catalyst poison and byproducts and contains 96 wt% or more of a target compound. A block copolymer obtained by polymerization using the chain transfer agent and a resin composition comprising the block copolymer have excellent mechanical properties.
Inventors:
SA SEOK PIL (KR)
SHIN EUN JI (KR)
LEE KI SOO (KR)
LEE BUN YEOUL (KR)
LEE JONG CHUL (KR)
SHIN EUN JI (KR)
LEE KI SOO (KR)
LEE BUN YEOUL (KR)
LEE JONG CHUL (KR)
Application Number:
PCT/KR2021/009967
Publication Date:
February 03, 2022
Filing Date:
July 30, 2021
Export Citation:
Assignee:
LG CHEMICAL LTD (KR)
International Classes:
C07F3/00; C07F7/08; C08F210/16; C08F212/08; C08F297/02; C08L23/12; C08L23/16; C08L91/00
Foreign References:
| KR20170107329A | 2017-09-25 | |||
| KR20190114713A | 2019-10-10 | |||
| KR20200096160A | 2020-08-11 | |||
| KR20210100045A | 2021-08-13 | |||
| KR101829382B1 | 2018-02-20 | |||
| KR101732418B1 | 2017-05-24 | |||
| KR101829382B1 | 2018-02-20 | |||
| KR101732418B1 | 2017-05-24 |
Other References:
SEUNG SOO PARK, CHUNG SOL KIM, SUNG DONG KIM, SU JIN KWON, HYUN MO LEE, TAE HEE KIM, JONG YEOB JEON, BUN YEOUL LEE: "Biaxial Chain Growth of Polyolefin and Polystyrene from 1,6-Hexanediylzinc Species for Triblock Copolymers", MACROMOLECULES, vol. 50, no. 17, 12 September 2017 (2017-09-12), US , pages 6606 - 6616, XP055605641, ISSN: 0024-9297, DOI: 10.1021/acs.macromol.7b01365
CHUNG SOL KIM,SEUNG SOO PARK,SUNG DONG KIM,SU JIN KWON,JUN WON BAEK ,BUN YEOUL LEE: "Polystyrene Chain Growth from Di-End-Functional Polyolefins for Polystyrene-Polyolefin-Polystyrene Block Copolymers", POLYMERS, vol. 9, no. 10, 481, 2 October 2017 (2017-10-02), pages 1 - 14, XP055637559, DOI: 10.3390/polym9100481
COTÉ A, CHARETTE A B: "General Method of the Expedient Synthesis of Salt-Free Diorganozine Reagents Using Zinc Methoxide", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 130, no. 9, 5 March 2008 (2008-03-05), pages 2771 - 2773, XP008124269, ISSN: 0002-7863, DOI: 10.1021/JA710864P
LEE JONG CHUL, PARK KYUNG LEE, BAE SUNG MOON, LEE HYUN JU, BAEK JUN WON, LEE JUNSEONG, SA SEOKPIL, SHIN EUN JI, LEE KI SOO, LEE BU: "Styrene Moiety-Carrying Diorganozinc Compound Preparation for Polystyrene-Poly(ethylene- co -1-hexene)-Polystyrene Triblock Copolymer Production", MACROMOLECULES, vol. 53, no. 17, 8 September 2020 (2020-09-08), US , pages 7274 - 7284, XP055892238, ISSN: 0024-9297, DOI: 10.1021/acs.macromol.0c01253
See also references of EP 4169927A4
CHUNG SOL KIM,SEUNG SOO PARK,SUNG DONG KIM,SU JIN KWON,JUN WON BAEK ,BUN YEOUL LEE: "Polystyrene Chain Growth from Di-End-Functional Polyolefins for Polystyrene-Polyolefin-Polystyrene Block Copolymers", POLYMERS, vol. 9, no. 10, 481, 2 October 2017 (2017-10-02), pages 1 - 14, XP055637559, DOI: 10.3390/polym9100481
COTÉ A, CHARETTE A B: "General Method of the Expedient Synthesis of Salt-Free Diorganozine Reagents Using Zinc Methoxide", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 130, no. 9, 5 March 2008 (2008-03-05), pages 2771 - 2773, XP008124269, ISSN: 0002-7863, DOI: 10.1021/JA710864P
LEE JONG CHUL, PARK KYUNG LEE, BAE SUNG MOON, LEE HYUN JU, BAEK JUN WON, LEE JUNSEONG, SA SEOKPIL, SHIN EUN JI, LEE KI SOO, LEE BU: "Styrene Moiety-Carrying Diorganozinc Compound Preparation for Polystyrene-Poly(ethylene- co -1-hexene)-Polystyrene Triblock Copolymer Production", MACROMOLECULES, vol. 53, no. 17, 8 September 2020 (2020-09-08), US , pages 7274 - 7284, XP055892238, ISSN: 0024-9297, DOI: 10.1021/acs.macromol.0c01253
See also references of EP 4169927A4
Attorney, Agent or Firm:
BAE, KIM & LEE IP (KR)
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