Title:
PHENOLATE ESTER COMPOUNDS
Document Type and Number:
WIPO Patent Application WO/2010/130241
Kind Code:
A3
Abstract:
The invention relates to phenolate ester compounds. In order to create a new product class which is suited as a coating material, a compound is created within the scope of the invention, having a chemical structure of the following formula: [R1 - Ph - O]aX (R2)b (R3)c (OR)n-a-b-c where X = Si, Ti, Zr, Mo, Mn, Cr, W, Hf, Ge, Sn, Pb, where n=4 or X= B, V, Al, Ga, In, where n=3 or X= Zn, Ni, Cu earth alkaline, where n= 2, R1 = O-H, H, O-Y or an organic side chain, Y = an element which is different from or the same as X and has appropriate substituents, R2 = alkyl group or functional organic side chain, R3 = an organic side chain that is the same as or different from R2, Ph = aryl group, R = alkyl group, a is an integer between 1 and n; b= 0 or 1 and c= 0 or 1, and a+b+c = n. A compound is obtained, in which an aryl group is linked into an ester by way of an O-X group. Surprisingly, it was found that materials which are stable toward hydrolysis and highly stable toward chemicals are obtained by the transesterification of silanes with phenolic compounds.
Inventors:
SEPEUR STEFAN (DE)
GROSS FRANK (DE)
GROSS FRANK (DE)
Application Number:
PCT/DE2010/000500
Publication Date:
January 06, 2011
Filing Date:
May 04, 2010
Export Citation:
Assignee:
NANO X GMBH (DE)
SEPEUR STEFAN (DE)
GROSS FRANK (DE)
SEPEUR STEFAN (DE)
GROSS FRANK (DE)
International Classes:
B05D1/00; C07F7/18; C08G77/18; C25D13/04
Domestic Patent References:
| WO2002050191A2 | 2002-06-27 |
Foreign References:
| US20030020049A1 | 2003-01-30 | |||
| JP2001166425A | 2001-06-22 | |||
| JPH01105249A | 1989-04-21 | |||
| US3940430A | 1976-02-24 | |||
| US3647749A | 1972-03-07 | |||
| US3491137A | 1970-01-20 | |||
| GB1203072A | 1970-08-26 | |||
| US3352896A | 1967-11-14 | |||
| DE4030663A1 | 1992-04-02 |
Other References:
HONG X-B ET AL: "Properties of organic silane modified bisphenol F epoxy resin", GAOFENZI CAILIAO KEXUE YU GONGCHENG - POLYMER MATERIALS SCIENCE AND ENGINEERING, vol. 24, no. 2, February 2008 (2008-02-01), pages 59 - 62, XP009138520, ISSN: 1000-7555
HONG X-B ET AL: "Studies on thermal properties of bisphenol F epoxy resin modified by organic silane", REGUXING SHUZHI - THERMOSETTING RESIN, vol. 22, no. 2, March 2007 (2007-03-01), pages 7 - 10,15, XP009138513, ISSN: 1002-7432
SUN J ET AL: "H-bonding assisted template synthesis of a novel ladder-like organo-bridged polymethylsiloxane", POLYMER, vol. 44, no. 10, May 2003 (2003-05-01), pages 2867 - 2874, XP004420078, ISSN: 0032-3861, DOI: 10.1016/S0032-3861(03)00210-6
APKHAZAVA P N ET AL: "Photostability of azo dyes bearing different substituents", IZVESTIJA AKADEMII NAUK GRUZINSKOJ SSR - PROCEEDINGS OF THE ACADEMY OF SCIENCES OF THE GEORGIAN SSR, vol. 17, no. 4, 1991, pages 266 - 269, XP009138508, ISSN: 0132-6074
CHIRAKADZE G G ET AL: "Radiolysis of azo dyes. I. Water and acetone solutions of azo dyes", IZVESTIJA AKADEMII NAUK GRUZINSKOJ SSR - PROCEEDINGS OF THE ACADEMY OF SCIENCES OF THE GEORGIAN SSR, vol. 15, no. 3, 1989, pages 177 - 184, XP009138509, ISSN: 0132-6074
SHANDILYA P R ET AL: "Organosilicon(IV) and organogermanium(IV) salicylhydroxamates", INDIAN JOURNAL OF CHEMISTRY. SECTION A. INORGANIC, PHYSICAL,THEORETICAL AND ANALYTICA, vol. 25A, no. 2, February 1986 (1986-02-01), pages 155 - 157, XP009138511, ISSN: 0376-4710
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; WADA S ET AL: "Unsaturated polyester resin compositions", XP002604816, retrieved from STN Database accession no. 1972:128159
GENTZKOW V ET AL: "Blocked antioxidant for cable- and wire insulations of cross-linked polyethylene", SIEMENS FORSCHUNGS- UND ENTWICKLUNGSBERICHTE, vol. 12, no. 3, 1983, pages 143 - 148, XP009138746, ISSN: 0370-9736
HONG X-B ET AL: "Studies on thermal properties of bisphenol F epoxy resin modified by organic silane", REGUXING SHUZHI - THERMOSETTING RESIN, vol. 22, no. 2, March 2007 (2007-03-01), pages 7 - 10,15, XP009138513, ISSN: 1002-7432
SUN J ET AL: "H-bonding assisted template synthesis of a novel ladder-like organo-bridged polymethylsiloxane", POLYMER, vol. 44, no. 10, May 2003 (2003-05-01), pages 2867 - 2874, XP004420078, ISSN: 0032-3861, DOI: 10.1016/S0032-3861(03)00210-6
APKHAZAVA P N ET AL: "Photostability of azo dyes bearing different substituents", IZVESTIJA AKADEMII NAUK GRUZINSKOJ SSR - PROCEEDINGS OF THE ACADEMY OF SCIENCES OF THE GEORGIAN SSR, vol. 17, no. 4, 1991, pages 266 - 269, XP009138508, ISSN: 0132-6074
CHIRAKADZE G G ET AL: "Radiolysis of azo dyes. I. Water and acetone solutions of azo dyes", IZVESTIJA AKADEMII NAUK GRUZINSKOJ SSR - PROCEEDINGS OF THE ACADEMY OF SCIENCES OF THE GEORGIAN SSR, vol. 15, no. 3, 1989, pages 177 - 184, XP009138509, ISSN: 0132-6074
SHANDILYA P R ET AL: "Organosilicon(IV) and organogermanium(IV) salicylhydroxamates", INDIAN JOURNAL OF CHEMISTRY. SECTION A. INORGANIC, PHYSICAL,THEORETICAL AND ANALYTICA, vol. 25A, no. 2, February 1986 (1986-02-01), pages 155 - 157, XP009138511, ISSN: 0376-4710
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; WADA S ET AL: "Unsaturated polyester resin compositions", XP002604816, retrieved from STN Database accession no. 1972:128159
GENTZKOW V ET AL: "Blocked antioxidant for cable- and wire insulations of cross-linked polyethylene", SIEMENS FORSCHUNGS- UND ENTWICKLUNGSBERICHTE, vol. 12, no. 3, 1983, pages 143 - 148, XP009138746, ISSN: 0370-9736
Attorney, Agent or Firm:
VIÉL, Christof et al. (Feldmannstrasse 110, Saarbrücken, DE)
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