Title:
PHOSPHORUS ELECTROLYTIC SOLUTION CONTAINING MAGNESIUM IONS
Document Type and Number:
WIPO Patent Application WO/2017/204322
Kind Code:
A1
Abstract:
The present invention pertains to a magnesium battery electrolytic solution and the like obtained by mixing a compound represented by general formula (I) below, a Lewis acid or a compound represented by general formula (A) below, and a solvent. {In the formulae, m represents 0 or 2, n represents 2 when m=0, and represents 0 or 1 when m=2, X1 represents a chlorine atom or a bromine atom, and the two R1s each independently represent a magnesium chloride oxy group; a magnesium bromide oxy group; an alky group, which may have a halogen group or the like as a substituent; an alkoxy group; an aryl group, which may have an alkoxy group or the like as a substituent; an aryloxy group, which may have an alkoxy group or the like as a substituent; or a group represented by general formula (1) below. The two R1s may also form general formula (2) below.} (In the formula, the four R10s each independently represent an alkyl group, a perfluoroalkyl group, a phenyl group, or a perfluorophenyl group.)
Inventors:
SATO KAZUHIKO (JP)
MORI GORO (JP)
WATAHIKI HIROMI (JP)
OKAMOTO KUNIAKI (JP)
SHIMAMURA NOBUTAKA (JP)
MORI GORO (JP)
WATAHIKI HIROMI (JP)
OKAMOTO KUNIAKI (JP)
SHIMAMURA NOBUTAKA (JP)
Application Number:
PCT/JP2017/019648
Publication Date:
November 30, 2017
Filing Date:
May 26, 2017
Export Citation:
Assignee:
WAKO PURE CHEM IND LTD (JP)
International Classes:
H01M10/0568; C07F19/00; H01M10/054; H01M10/0567; H01M10/0569; C07F3/02; C07F9/30; C07F9/38; C07F9/46
Foreign References:
| JPS5617131B2 | 1981-04-21 | |||
| JP5786540B2 | 2015-09-30 |
Other References:
GRIM ET AL.: "SYNTHESIS AND MAGNETIC RESONANCE STUDIES OF SOME PHOSPHINOUS ACIDS, PHOSPHORYLACETIC ACIDS, AND SOME OF THEIR COORDINATION COMPOUNDS", J.INORG.NUCL.CHEM., vol. 39, no. 3, 1977, pages 499 - 511, XP055553964
MARYNICK ET AL.: "Theoretical studies of metal- phosphate interactions: Interaction of Li+, Na+, K+, Be++, Mg++, and Ca++ with H2PO4- and ( CH 3O)2PO2-: Implications for nucleic acid solvation", PROC. NAT.ACAD.SCI.USA, vol. 72, no. 10, 1975, pages 3794 - 3798, XP055553986
NATURE, vol. 407, 2000, pages 724 - 727
CHEM. COMMUN., vol. 48, 2012, pages 10763 - 10765
J. MATER. CHEM. A, vol. 2, 2014, pages 581 - 584
J. ELECTROCHEM. SOC., vol. 161, 2014, pages A593
See also references of EP 3467931A4
MARYNICK ET AL.: "Theoretical studies of metal- phosphate interactions: Interaction of Li+, Na+, K+, Be++, Mg++, and Ca++ with H2PO4- and ( CH 3O)2PO2-: Implications for nucleic acid solvation", PROC. NAT.ACAD.SCI.USA, vol. 72, no. 10, 1975, pages 3794 - 3798, XP055553986
NATURE, vol. 407, 2000, pages 724 - 727
CHEM. COMMUN., vol. 48, 2012, pages 10763 - 10765
J. MATER. CHEM. A, vol. 2, 2014, pages 581 - 584
J. ELECTROCHEM. SOC., vol. 161, 2014, pages A593
See also references of EP 3467931A4
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