Title:
PHOTOELECTRIC CONVERSION ELEMENT, DYE-SENSITIZED SOLAR CELL, METAL COMPLEX DYE, DYE SOLUTION, DYE-ADSORBED ELECTRODE, AND METHOD FOR MANUFACTURING DYE-SENSITIZED SOLAR CELL
Document Type and Number:
WIPO Patent Application WO/2014/077356
Kind Code:
A1
Abstract:
A photoelectric conversion element which comprises a conductive supporting body, a photosensitive layer containing an electrolyte, a charge transfer layer containing an electrolyte, and a counter electrode, and wherein the photosensitive layer contains fine semiconductor particles that are loaded with a metal complex dye represented by formula (I); a metal complex dye; a dye solution; a dye-adsorbed electrode; a dye-sensitized solar cell; and a method for manufacturing the dye-sensitized solar cell.
M(LA)(LD)(LX)mX·(CI)mY formula (I)
In formula (I), M represents a metal ion; LA represents a tridentate ligand represented by formula (AL); LD represents a bidentate or tridentate ligand wherein at least one coordinating atom is an anion; LX represents a monodentate ligand; CI represents a counter ion; mX represents 0 or 1; and mY represents an integer of 0-3.
formula (AL)
In formula (AL), each of rings A-C represents a nitrogen-containing aromatic hetero ring; each of Z1 and Z2 represents a carbon atom or a nitrogen atom; each of Anc1-Anc3 represents an acidic group; each of X1 and X3 represents a single bond or a linking group; X2 represents a linking group that is linked in a conjugated form or a single bond, and in cases where X2 is a linking group, the linking group contains an ethenylene group, an ethynylene group, an arylene group or a heteroarylene group in a linking chain; each of R1-R3 represents a substituent; each of l1 and l3 represents an integer of 1-4; l2 represents an integer of 1-5; each of m1 and m3 represents an integer of 0-4; m2 represents an integer of 1-3; each of n1 and n2 represents an integer of 0-3; and n3 represents an integer of 0-4. In cases where X2 is a single bond, m1 or m3 represents an integer of 1-4 and X1 or X3 represents a linking group.
Inventors:
WATANABE KOUSUKE (JP)
TANI YUKIO (JP)
SASAKI KOUITSU (JP)
SATOU HIROTAKA (JP)
TSUNA KAZUHIRO (JP)
KOBAYASHI KATSUMI (JP)
TANI YUKIO (JP)
SASAKI KOUITSU (JP)
SATOU HIROTAKA (JP)
TSUNA KAZUHIRO (JP)
KOBAYASHI KATSUMI (JP)
Application Number:
PCT/JP2013/080883
Publication Date:
May 22, 2014
Filing Date:
November 15, 2013
Export Citation:
Assignee:
FUJIFILM CORP (JP)
International Classes:
C07D213/55; H01M14/00; C07D213/57; C07D401/14; C07D409/14; C07D495/04; C07F15/00; H01L31/04; C09B57/10; C09B67/44
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See also references of EP 2922137A4
KREBS ET AL: "DYE SENSITIZED PHOTOVOLTAIC CELLS: ATTACHING CONJUGATED POLYMERS TO ZWITTERIONICRUTHENIUM DYES", SOLAR ENERGY MATERIALS AND SOLAR CELLS, vol. 90, no. 2, 23 January 2006 (2006-01-23), pages 142 - 165, XP028002061
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J. ORG. CHEM., vol. 73, 2008, pages 4309 - 4312
See also references of EP 2922137A4
Attorney, Agent or Firm:
IIDA, Toshizo et al. (JP)
Toshizo Iida (JP)
Toshizo Iida (JP)
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