BACKGROUND

Embodiments of the present disclosure relate to electron-accepting compounds and more specifically, but not by way of limitation, to compounds containing electron-accepting and electron donating units, the compounds being suitable for use as an electron-accepting material in a photoresponsive device.

Electron-accepting non-fullerene compounds are known.

KR20190117086 discloses an organic solar cell containing a compound of formula:

In which Pulll is an electron-withdrawing group, k is 1-10 and LI has formula:

Kim et al, “Synthesis of ITIC Derivatives with Extended ^-Conjugation as Non-Fullerene Acceptors for Organic Solar Cells” ACS Appl. Mater. Interfaces 2019, 11, 50, 47121 discloses A-D-A'-D-A-type molecular acceptors solar cells based on indacenodithienothiophene (IDTT) and thiophene-flanked 2, 1,3-benzothiadiazole.

Kim et al “Alkylated Indacenodithiophene-Based Non-fullerene Acceptors with Extended TI- Conjugation for High-Performance Large-Area Organic Solar Cells” ACS Appl. Mater. Interfaces 2020, 12, 45, 50638-50647 discloses A-D-A'-D-A-type electron acceptors for organic solar cells based on alkylated indacenodithiophene (C8IDT), dicyanated thiopheneflanked 2, 1 ,3-benzothiadiazole 2-(3-oxo-2,3-dihydro- l /7-inden-l - ylidenejmalononitrile (INCN) or 2-(5,6-difluoro-3-oxo-2,3-dihydro- 17/-inden- 1 -ylidene) malononitrile (FINCN).

Zhang et al, “Designing efficient A-D-Ai-D-A-type non-fullerene acceptors with enhanced fill factor via noncovalently conformational locking” Synthetic Metals Volume 278, August 2021,116838 discloses A-D-Ai-D-A-type non-fullerene acceptors (NFAs) PZ-dIDTC6 and PD-dIDTC6, consisting of indacenodi thiophene (IDT) dimers bridged with weak electron withdrawing pyrazine (PZ) or pyridine (PD) unit for improving the fill factor of non-fullerene organic solar cells.

Cai et al, “Effects of -Bridge on Fused-Ring Electron Acceptor Dimers” ACS Appl. Polym. Mater. 2021, 3, 1, 23-29 discloses photovoltaic cells containing nonfullerene acceptors (TTIDIC and BTIDIC), consisting of indacenodithiophene (IDT) dimers bridged with electron-rich thi enothiophene (TT) or electron-accepting benzothiadiazole (BT).

Zhang et al, “A2-D-Ai-D-A2-type small molecule acceptors incorporated with electrondeficient core for non-fullerene organic solar cells” Solar Energy Volume 197, February 2020, Pages 511-518 discloses small molecule acceptors DFB-dIDT and BT-dIDT with 2,5- difluorobenzene (DFB) or benzothiadiazole (BT) as electron-withdrawing core (Ai) and a derivative of indanone as A2 units for applications in organic solar cells.

Zhang et al, “Electron-Deficient and Quinoid Central Unit Engineering for Unfused Ring- Based Ai-D-A2-D-Ai-Type Acceptor Enables High Performance Nonfullerene Polymer Solar Cells with High E _oc and PCE Simultaneously”, Small, DOI: 10.1002/smll.201907681 discloses nonfullerene small molecule acceptors BO2FIDT-4C1 and BT2FIDT-4C1 which possess the same terminals (Ai), indacenodithiophene unit (D), and a fluorinated electrondeficient central unit (A2) of difluorobenzoxadiazole or difluorobenzothiadiazole for use in solar cells.

SUMMARY

In some embodiments, the present disclosure provides a compound of formula (I): wherein: A ¹ is a divalent heteroaromatic electron-accepting group comprising at least 3 fused aromatic rings and / or A ¹ is a divalent heteroaromatic electron-accepting group having a modelled LUMO of more than 2.70 eV from vacuum level

A ² and A ³ are each independently a monovalent electron-accepting group;

D ¹ and D ² independently in each occurrence is an electron-donating group, wherein at least one occurrence of at least one of D ¹ and D ² is a fused heteroaromatic group comprising at least 4 fused rings;

B ¹ and B ² independently in each occurrence is a bridging group; x ¹ and x ² are each independently 0, 1, 2 or 3; y ¹ and y ² are each independently at least 1; and z ¹ and z ² are each independently 0, 1, 2 or 3.

DESCRIPTION OF DRAWINGS

The disclosed technology and accompanying figures describe some implementations of the disclosed technology.

Figure 1 illustrates an organic photoresponsive device according to some embodiments;

Figure 2 shows absorption spectra for Compound Example 1 according to an embodiment of the present disclosure and a comparative compound;

Figure 3 shows solution and film absorption spectra for Compound Example 2 according to an embodiment of the present disclosure;

Figure 4 shows external quantum efficiency vs. wavelength for organic photodetectors containing Compound Example 2; and

Figure 5 shows dark current (current density vs. voltage) for organic photodetectors containing Compound Example 2.

The drawings are not drawn to scale and have various viewpoints and perspectives. The drawings are some implementations and examples. Additionally, some components and/or operations may be separated into different blocks or combined into a single block for the purposes of discussion of some of the embodiments of the disclosed technology. Moreover, while the technology is amenable to various modifications and alternative forms, specific embodiments have been shown by way of example in the drawings and are described in detail below. The intention, however, is not to limit the technology to the particular implementations described. On the contrary, the technology is intended to cover all modifications, equivalents, and alternatives falling within the scope of the technology as defined by the appended claims.

DETAILED DESCRIPTION

Unless the context clearly requires otherwise, throughout the description and the claims, the words "comprise," "comprising," and the like are to be construed in an inclusive sense, as opposed to an exclusive or exhaustive sense; that is to say, in the sense of "including, but not limited to." Additionally, the words "herein," "above," "below," and words of similar import, when used in this application, refer to this application as a whole and not to any particular portions of this application. Where the context permits, words in the Detailed Description using the singular or plural number may also include the plural or singular number respectively. The word "or," in reference to a list of two or more items, covers all of the following interpretations of the word: any of the items in the list, all of the items in the list, and any combination of the items in the list. References to a layer “over” another layer when used in this application means that the layers may be in direct contact or one or more intervening layers are may be present. References to a layer “on” another layer when used in this application means that the layers are in direct contact. References to a specific atom include any isotope of that atom unless specifically stated otherwise.

The teachings of the technology provided herein can be applied to other systems, not necessarily the system described below. The elements and acts of the various examples described below can be combined to provide further implementations of the technology. Some alternative implementations of the technology may include not only additional elements to those implementations noted below, but also may include fewer elements.

These and other changes can be made to the technology in light of the following detailed description. While the description describes certain examples of the technology, and describes the best mode contemplated, no matter how detailed the description appears, the technology can be practiced in many ways. As noted above, particular terminology used when describing certain features or aspects of the technology should not be taken to imply that the terminology is being redefined herein to be restricted to any specific characteristics, features, or aspects of the technology with which that terminology is associated. In general, the terms used in the following claims should not be construed to limit the technology to the specific examples disclosed in the specification, unless the Detailed Description section explicitly defines such terms. Accordingly, the actual scope of the technology encompasses not only the disclosed examples, but also all equivalent ways of practicing or implementing the technology under the claims.

To reduce the number of claims, certain aspects of the technology are presented below in certain claim forms, but the applicant contemplates the various aspects of the technology in any number of claim forms.

In the following description, for the purposes of explanation, numerous specific details are set forth in order to provide a thorough understanding of implementations of the disclosed technology. It will be apparent, however, to one skilled in the art that embodiments of the disclosed technology may be practiced without some of these specific details.

A compound of formula (I) as described herein may be provided in a bulk heterojunction layer of a photoresponsive device, preferably a photodetector, in which the bulk heterojunction layer is disposed between an anode and a cathode.

The bulk heterojunction layer comprises or consists of an electron-donating material and an electron-accepting compound of formula (I) as described herein.

In some embodiments, the bulk heterojunction layer contains two or more accepting materials and / or two or more electron-accepting materials.

In some embodiments, the weight of the electron-donating material(s) to the electronaccepting material(s) is from about 1 :0.5 to about 1:2, preferably about 1 : 1.1 to about 1 :2.

Preferably, the electron-donating material has a type II interface with the electron-accepting material, i.e. the electron-donating material has a shallower HOMO and LUMO that the corresponding HOMO and LUMO levels of the electron-accepting material. Preferably, the compound of formula (I) has a HOMO level that is at least 0.05 eV deeper, optionally at least 0.10 eV deeper, than the HOMO of the electron-donating material.

Optionally, the gap between the HOMO level of the electron-donating material and the LUMO level of the electron-accepting compound of formula (I) is less than 1.4 eV.

Unless stated otherwise, HOMO and LUMO levels of materials as described herein are as measured by square wave voltammetry (SWV).

In SWV, the current at a working electrode is measured while the potential between the working electrode and a reference electrode is swept linearly in time. The difference current between a forward and reverse pulse is plotted as a function of potential to yield a voltammogram. Measurement may be with a CHI 660D Potentiostat.

The apparatus to measure HOMO or LUMO energy levels by SWV may comprise a cell containing 0.1 M tertiary butyl ammonium hexafluorophosphate in acetonitrile; a 3 mm diameter glassy carbon working electrode; a platinum counter electrode and a leak free Ag/AgCl reference electrode.

Ferrocene is added directly to the existing cell at the end of the experiment for calculation purposes where the potentials are determined for the oxidation and reduction of ferrocene versus Ag/AgCl using cyclic voltammetry (CV).

The sample is dissolved in toluene (3 mg / ml) and spun at 3000 rpm directly on to the glassy carbon working electrode.

LUMO = 4.8 - E ferrocene (peak to peak average) - E reduction of sample (peak maximum).

HOMO = 4.8 - E ferrocene (peak to peak average) + E oxidation of sample (peak maximum).

A typical SWV experiment runs at 15 Hz frequency; 25 mV amplitude and 0.004 V increment steps. Results are calculated from 3 freshly spun film samples for both the HOMO and LUMO data.

Preferably, the compound of formula (I) has an absorption peak greater than 1000 nm, more preferably greater than 1100 nm or 1200 nm, optionally in the range of 1000-1400 nm. Unless stated otherwise, absorption spectra of materials as described herein are measured using a Cary 5000 UV-VIS-NIR Spectrometer. Measurements were taken from 300 nm to 2500 nm using a PbSmart NIR detector for extended photometric range with variable slit widths (down to 0.01 nm) for optimum control over data resolution.

Absorption data are obtained by measuring the intensity of transmitted radiation through a solution sample. Absorption intensity is plotted vs. incident wavelength to generate an absorption spectrum. Solution absorption may be measured from a 0.015 mg / ml solution in a quartz cuvette and comparing to a cuvette containing the solvent only.

In some embodiments, the electron-accepting compound has formula (I):

D ¹ and D ² independently in each occurrence is an electron-donating group. The compound of formula (I) contains at least one group selected from D ¹ and D ² which is a heteroaromatic group comprising at least 4 fused rings.

In some embodiments, A ¹ is a divalent heteroaromatic electron-accepting group comprising at least 3 fused aromatic rings.

In some embodiments, A ¹ is a divalent heteroaromatic electron-accepting group having a modelled LUMO level of more than 2.70 eV from vacuum level, optionally at least 2.75 eV from vacuum level..

A ² and A ³ are each independently a monovalent electron-accepting group.

B ¹ and B ² in each occurrence are independently a bridging group. x ¹ and x ² are each independently 0, 1, 2 or 3, preferably 0 or 1. y ¹ and y ² are each independently at least 1, preferably 1, 2 or 3, more preferably 1. z ¹ and z ² are each independently 0, 1, 2 or 3, preferably 0 or 1. Each of the electron-accepting groups A ¹ , A ² and A ³ has a lowest unoccupied molecular orbital (LUMO) level that is deeper (i.e., further from vacuum) than the LUMO of either of the electron-donating groups D ¹ or D ² , preferably at least 1 eV deeper. The LUMO levels of electron-accepting groups and electron-donating groups may be as determined by modelling the LUMO level of these groups, in which each bond to adjacent group is replaced with a bond to a hydrogen atom. Modelling may be performed using Gaussian09 software available from Gaussian using Gaussian09 with B3LYP (functional) and LACVP* (Basis set).

Acceptor Unit A ¹

A ¹ may be a polycyclic heteroaromatic group which is unsubstituted or substituted with one or more substituents.

A preferred group, A ¹ of formula (I) is a group of formula (II): wherein:

Ar ¹ is a monocyclic or polycyclic aromatic or heteroaromatic group; and

Y is O, S, NR ⁴ or R ¹ -C=C-R ¹ wherein R ¹ in each occurrence is independently H or a substituent wherein two substituents R ¹ may be linked to form a monocyclic or polycyclic ring; and R ⁴ is H or a substituent.

R ² groups wherein R ² in each occurrence is independently a substituent.

Preferred R ² groups are selected from

F;

CN; NO ₂ ;

C1-20 alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ wherein R ⁷ is a Ci-n hydrocarbyl, COO or CO and one or more H atoms of the alkyl may be replaced with F; an aromatic or heteroaromatic group, preferably phenyl, which is unsubstituted or substituted with one or more substituents; and a group selected from wherein Z ⁴⁰ , Z ⁴¹ , Z ⁴² and Z ⁴³ are each independently CR ¹³ or N wherein R ¹³ in each occurrence is H or a substituent, preferably a C 1-20 hydrocarb yl group; Y ⁴⁰ and Y ⁴¹ are each independently O, S, NX ⁷¹ wherein X ⁷¹ is CN or COOR ⁴⁰ ; or CX ⁶⁰ X ⁶¹ wherein X ⁶⁰ and X ⁶¹ is independently CN, CF3 or COOR ⁴⁰ ; W ⁴⁰ and W ⁴¹ are each independently O, S, NX ⁷¹ or CX ⁶⁰ X ⁶¹ wherein X ⁶⁰ and X ⁶¹ is independently CN, CF3 or COOR ⁴⁰ ; and R ⁴⁰ in each occurrence is H or a substituent, preferably H or a C1-20 hydrocarbyl group. Exemplary substituents of an aromatic or heteroaromatic group R ² are F, CN, NO2, and C1-12 alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , COO or CO and one or more H atoms of the alkyl may be replaced with F.

R ⁷ as described anywhere herein may be, for example, C1-12 alkyl, unsubstituted phenyl; or phenyl substituted with one or more C1-6 alkyl groups.

If a C atom of an alkyl group as described anywhere herein is replaced with another atom or group, the replaced C atom may be a terminal C atom of the alkyl group or a non-terminal C- atom.

By “non-terminal C atom” of an alkyl group as used anywhere herein means a C atom other than the C atom of the methyl group at the end of an n-alkyl chain or the C atoms of the methyl groups at the ends of a branched alkyl chain. If a terminal C atom of a group as described anywhere herein is replaced then the resulting group may be an anionic group comprising a countercation, e.g., an ammonium or metal countercation, preferably an ammonium or alkali metal cation.

A C atom of an alkyl substituent group which is replaced with another atom or group as described anywhere herein is preferably a non-terminal C atom, and the resultant substituent group is preferably non-ionic.

Exemplary monocyclic heteroaromatic groups Ar ¹ are oxadiazole, thiadiazole, triazole and 1,4-diazine which is unsubstituted or substituted with one or more substituents. Thiadiazole is particularly preferred.

Exemplary polycyclic heteroaromatic groups Ar ¹ are groups of formula (V):

X ¹ and X ² , are each independently selected from N and CR ³ wherein R ³ is H or a substituent, optionally H or a substituent R ² as described above.

X ³ , X ⁴ , X ⁵ and X ⁶ are each independently selected from N and CR ³ with the proviso that at least one of X ³ , X ⁴ , X ⁵ and X ⁶ is CR ³ .

Z is selected from O, S, SO ₂ , NR ⁴ , PR ⁴ , C(R ³ ) ₂ , Si(R ³ ) ₂ C=O, C=S and C=C(R ⁵ ) ₂ wherein R ³ is as described above; R ⁴ is H or a substituent; and R ⁵ in each occurrence is an electronwithdrawing group.

Optionally, each R ⁴ of any NR ⁴ or PR ⁴ described anywhere herein is independently selected from H; Ci -20 alkyl wherein one or more non-adjacent C atoms other than the C atom bound to N or P may be replaced with O, S, NR ⁷ , COO or CO and one or more H atoms of the alkyl may be replaced with F; and phenyl which is unsubstituted or substituted with one or more substituents, optionally one or more C1-12 alkyl groups wherein one or more non-adjacent C atoms of the alkyl may be replaced with O, S, NR ⁷ , COO or CO and one or more H atoms of the alkyl may be replaced with F.

Preferably, each R ⁵ is CN, COOR ⁴⁰ ; or CX ⁶⁰ X ⁶¹ wherein X ⁶⁰ and X ⁶¹ is independently CN, CF3 or COOR ⁴⁰ and R ⁴⁰ in each occurrence is H or a substituent, preferably H or a C1-20 hydrocarb yl group.

A ¹ groups of formula (II) are preferably selected from groups of formulae (Ila) and (lib):

For compounds of formula (lib), the two R ¹ groups may or may not be linked.

Preferably, when the two R ¹ groups are not linked each R ¹ is independently selected from H; F; CN; NO ₂ ; Ci -20 alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , CO, COO, NR ⁴ , PR ⁴ , or Si(R ³ ) ₂ wherein R ³ and R ⁴ are as described above and one or more H atoms may be replaced with F; and aryl or heteroaryl, preferably phenyl, which may be unsubstituted or substituted with one or more substituents. Substituents of the aryl or heteroaryl group may be selected from one or more of F; CN; NO ₂ ; and C1-20 alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , CO, COO and one or more H atoms may be replaced with F.

Preferably, when the two R ¹ groups are linked, the group of formula (lib) has formula (IIb-1) or (IIb-2):

Ar ² is an aromatic or heteroaromatic group, preferably benzene, which is unsubstituted or substituted with one or more substituents. Ar ² may be unsubstituted or substituted with one or more substituents R ² as described above.

X is selected from O, S, SO ₂ , NR ⁴ , PR ⁴ , C(R ³ ) ₂ , Si(R ³ ) ₂ C=O, C=S and C=C(R ⁵ ) ₂ wherein R ³ , R ⁴ and R ⁵ are as described above.

Exemplary electron-accepting groups of formula (II) include, without limitation:

wherein Ak ¹ is a C1-20 alkyl group

Another preferred acceptor unit is thiophene fused to a 5-membered or 6-membered heteroaromatic ring containing at least one N atom, optionally pyridine, 1,4-diazine or thiadiazole. Aromatic carbon atoms of this acceptor unit may be unsubstituted or substituted with one or more substituents, optionally one or more substituents selected from non-H R ²⁵ groups as described below.

Divalent electron-accepting groups other than formula (II) are optionally selected from formulae (IVa)-(IVe):

R ²³ in each occurrence is a substituent, optionally C1-12 alkyl wherein one or more non- adjacent C atoms other than the C atom attached to Z ¹ may be replaced with O, S, NR ⁷ , COO or CO and one or more H atoms of the alkyl may be replaced with F. R ²⁵ is H; F; CN; NO2; C1-12 alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , COO or CO and one or more H atoms of the alkyl may be replaced with F; an aromatic group, optionally phenyl, which is unsubstituted or substituted with one or more substituents selected from F and C1-12 alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , COO or CO; or wherein Z ⁴⁰ , Z ⁴¹ , Z ⁴² and Z ⁴³ are each independently CR ¹³ or N wherein R ¹³ in each occurrence is H or a substituent, preferably a C 1-20 hydrocarb yl group;

Y ⁴⁰ and Y ⁴¹ are each independently O, S, NX ⁷¹ wherein X ⁷¹ is CN or COOR ⁴⁰ ; or CX ⁶⁰ X ⁶¹ wherein X ⁶⁰ and X ⁶¹ is independently CN, CF3 or COOR ⁴⁰ ;

W ⁴⁰ and W ⁴¹ are each independently O, S, NX ⁷¹ wherein X ⁷¹ is CN or COOR ⁴⁰ ; or CX ⁶⁰ X ⁶¹ wherein X ⁶⁰ and X ⁶¹ is independently CN, CF3 or COOR ⁴⁰ ; and

R ⁴⁰ in each occurrence is H or a substituent, preferably H or a C1-20 hydrocarbyl group.

Z ¹ is N or P.

T ¹ , T ² and T ³ each independently represent an aryl or a heteroaryl ring, optionally benzene, which may be fused to one or more further rings. Substituents of T ¹ , T ² and T ³ , where present, are optionally selected from non-H groups of R ²⁵ .

Electron-Accepting Groups A ² , A ³

The monovalent acceptor Groups A ² and A ³ may each independently be selected from any such units known to the skilled person. A ² and A ³ may be the same or different, preferably the same.

Exemplary monovalent acceptor units include, without limitation, units of formulae (Illa)- (Illq)

U is a 5- or 6-membered ring which is unsubstituted or substituted with one or more substituents and which may be fused to one or more further rings.

The N atom of formula (Ille) may be unsubstituted or substituted.

R ¹⁰ is H or a substituent, preferably a substituent selected from the group consisting of C1-12 alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , COO or CO and one or more H atoms of the alkyl may be replaced with F; and an aromatic group, optionally phenyl, which is unsubstituted or substituted with one or more substituents selected from F and C1-12 alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , COO or CO.

Preferably, R ¹⁰ is H.

J is O or S, preferably O.

R ¹³ in each occurrence is a substituent, optionally C1-12 alkyl wherein one or more non- adjacent C atoms may be replaced with O, S, NR ⁷ , COO or CO and one or more H atoms of the alkyl may be replaced with F.

R ¹⁵ in each occurrence is independently H; F; C1-12 alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , COO or CO and one or more H atoms of the alkyl may be replaced with F; aromatic group Ar ² , optionally phenyl, which is unsubstituted or substituted with one or more substituents selected from F and C1-12 alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , COO or CO; or a group selected from:

R ¹⁶ is H or a substituent, preferably a substituent selected from:

-(Ar ³ ) _w wherein Ar ³ in each occurrence is independently an unsubstituted or substituted aryl or heteroaryl group, preferably thiophene, and w is 1, 2 or 3; Ci-12 alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , COO or CO and one or more H atoms of the alkyl may be replaced with F.

Ar ⁶ is a 5-membered heteroaromatic group, preferably thiophene or furan, which is unsubstituted or substituted with one or more substituents.

Substituents of Ar ³ and Ar ⁶ , where present, are optionally selected from C1-12 alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , COO or CO and one or more H atoms of the alkyl may be replaced with F.

T ¹ , T ² and T ³ are each independently as described above.

Ar ⁸ is a fused heteroaromatic group which is unsubstituted or substituted with one or more substituents, optionally one or more non-H substituents R ¹⁰ , and which is bound to an aromatic C atom of B ² and to a boron substituent of B ² .

Preferred groups A ² and A ³ are groups having a non-aromatic carbon-carbon bond which is bound directly to D ¹ or D ² or, if present to B ² .

Preferably at least one of A ² and A ³ , preferably both of A ² and A ³ , are a group of formula (IIIa-1): wherein:

R ¹⁰ is as described above; each X ⁷ -X ¹⁰ is independently CR ¹² or N wherein R ¹² in each occurrence is H or a substituent selected from C 1-20 hydrocarb yl and an electron withdrawing group. Preferably, the electron withdrawing group is F, Cl, Br or CN, more preferably F, Cl or CN; and

X ⁶⁰ and X ⁶¹ is independently CN, CF3 or COOR ⁴⁰ wherein R ⁴⁰ in each occurrence is H or a substituent, preferably H or a C1-20 hydrocarbyl group. Preferably, X ⁶⁰ and X ⁶¹ are each CN.

The Ci -20 hydrocarbyl group R ¹² may be selected from C1-20 alkyl; unsubstituted phenyl; and phenyl substituted with one or more C1-12 alkyl groups.

Exemplary groups of formula (Hid) include:

Exemplary groups of formula (Ille) include:

An exemplary group of formula (Illq) is:

An exemplary group of formula (Illg) is:

An exemplary group of formula (Illj) is: wherein Ak is a C1-12 alkylene chain in which one or more C atoms may be replaced with O, S, NR ⁷ , CO or COO; An is an anion, optionally -SOf; and each benzene ring is independently unsubstituted or substituted with one or more substituents selected from substituents described with reference to R ¹⁰ .

Exemplary groups of formula (Illm) are:

An exemplary group of formula (Ilin) is:

Groups of formula (IIIo) are bound directly to a bridging group B ² substituted with a -B(R ¹⁴ )2 wherein R ¹⁴ in each occurrence is a substituent, optionally a C 1-20 hydrocarb yl group; — > is a bond to the boron atom -B(R ¹⁴ )2 of R ³ or R ⁶ ; and — is the bond to B ² . Optionally, R ¹⁴ is selected from C1-12 alkyl; unsubstituted phenyl; and phenyl substituted with one or more C1-12 alkyl groups.

The group of formula (IIIo), the B ² group and the B(R ¹⁴ )2 substituent of B ² may be linked together to form a 5- or 6-membered ring.

Optionally groups of formula (IIIo) are selected from:

Bridging units

Bridging units B ¹ and B ² are preferably each selected from vinylene, arylene, heteroarylene, arylene vinylene and heteroarylenevinylene wherein the arylene and heteroarylene groups are monocyclic or bicyclic groups, each of which may be unsubstituted or substituted with one or more substituents.

Bridging units B ¹ and B ² preferably are monocyclic or fused bicyclic arylene or heteroarylene groups, more preferably monocyclic or fused bicyclic heteroarylene groups.

If x ¹ and x ² are each at least 1 then each B ¹ is preferably the same.

If z ¹ and z ² are each at least 1 then each B ² is preferably the same.

Optionally, B ¹ and B ² are independently selected from units of formulae (Via) - (VIn):

(Vim) (VIn) wherein R ⁵⁵ is H or a substituent; R ⁸ in each occurrence is independently H or a substituent, preferably H or a substituent selected from F; CN; NO2; C1-20 alkyl wherein one or more nonadj acent C atoms may be replaced with O, S, NR ⁷ , COO or CO and one or more H atoms of the alkyl may be replaced with F; phenyl which is unsubstituted or substituted with one or more substituents; and -B(R ¹⁴ )2 wherein R ¹⁴ in each occurrence is a substituent, optionally a C1-20 hydrocarbyl group. R ⁸ groups of formulae (Via), (VIb) and (Vic) may be linked to form a bicyclic ring, for example thi enopyrazine.

R ⁸ is preferably H, C1-20 alkyl, -COO-C1-19 alkyl, C1-19 alkoxy or C1-19 thioalkyl.

Electron-Donating Groups D ¹ and D ²

Electron-donating groups D ¹ and D ² preferably are fused aromatic or heteroaromatic groups, more preferably fused heteroaromatic groups containing 3 or more rings. At least one D ¹ and / or at least one D ² contains at least 4 fused rings. Preferably, each D ¹ and / or each D ² contains at least 4 fused rings. Most preferably, D ¹ and D ² in each occurrence contains at least 4 fused rings.

D ¹ and D ² may be the same or different. Preferably they are the same.

Particularly preferred electron-donating groups comprise fused thiophene or furan rings, optionally fused rings containing thiophene or furan rings and one or more rings selected from benzene, cyclopentadiene, tetrahydropyran, tetrahydrothiopyran and piperidine rings, each of said rings being unsubstituted or substituted with one or more substituents.

Exemplary electron-donating groups D ¹ and D ² having at least 4 fused rings include groups of formulae (Vlla)-(VIIs):

(Vllm) (Vlln)

Where present, electron-donating groups D ¹ and D ² having only 3 fused rings may be selected from groups of formulae (Vllla)-(VIIIe): wherein Y ^A in each occurrence is independently O, S or NR ⁵⁵ , Z ^A in each occurrence is O, CO, S, NR ⁵⁵ or C(R ⁵⁴ )2; R ⁵¹ , R ⁵² R ⁵⁴ and R ⁵⁵ independently in each occurrence is H or a substituent; and R ⁵³ independently in each occurrence is a substituent.

Optionally, R ⁵¹ and R ⁵² independently in each occurrence are selected from H; F; C1-20 alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , COO or CO and one or more H atoms of the alkyl may be replaced with F; and an aromatic or heteroaromatic group Ar ³ which is unsubstituted or substituted with one or more substituents.

In some embodiments, Ar ³ may be an aromatic group, e.g., phenyl.

The one or more substituents of Ar ³ , if present, may be selected from C1-12 alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , COO or CO and one or more H atoms of the alkyl may be replaced with F.

Preferably, each R ⁵⁴ is selected from the group consisting of:

H;

F; linear, branched or cyclic C1-20 alkyl wherein one or more non-adjacent C atoms may be replaced by O, S, NR ⁷ , CO or COO wherein R ⁷ is a C 1-12 hydrocarbyl and one or more H atoms of the C1-20 alkyl may be replaced with F; and a group of formula (Ak)u-(Ar ⁷ )v wherein Ak is a C1-20 alkylene chain in which one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , CO or COO; u is 0 or 1; Ar ⁷ in each occurrence is independently an aromatic or heteroaromatic group which is unsubstituted or substituted with one or more substituents; and v is at least 1, optionally 1, 2 or 3.

Substituents of Ar ⁷ , if present, are preferably selected from F; Cl; NO2; CN; and C1-20 alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , CO or COO and one or more H atoms may be replaced with F. Preferably, Ar ⁷ is phenyl.

Preferably, R ⁵⁴ is a C1-20 hydrocarbyl group, e.g., C1-20 alkyl, unsubstituted aryl, or aryl substituted with one or more C1-12 alkyl groups. The aryl group is preferably phenyl.

Preferably, each R ⁵¹ is H.

Optionally, R ⁵³ independently in each occurrence is selected from C1-20 alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , COO or CO and one or more H atoms of the alkyl may be replaced with F; and aryl or heteroaryl, preferably phenyl, which is unsubstituted or substituted with one or more substituents, optionally one or more C1-12 alkyl groups wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , COO or CO and one or more H atoms of the alkyl may be replaced with F.

Preferably, R ⁵⁵ as described anywhere herein is H or C 1-30 hydrocarbyl group.

In some embodiments, y ¹ and y ² are each 1.

In some embodiments, at least one of y ¹ and y ² is greater than 1. In these embodiments, the chain of D ¹ and / or D ² groups, respectively, may be linked in any orientation.

Electron-donating material

A bulk heterojunction layer as described herein comprises an electron-donating material and a compound of formula (I) as described herein.

Exemplary donor materials are disclosed in, for example, WO2013051676, the contents of which are incorporated herein by reference.

The electron-donating material may be a non-polymeric or polymeric material. In a preferred embodiment the electron-donating material is an organic conjugated polymer, which can be a homopolymer or copolymer including alternating, random or block copolymers. The conjugated polymer is preferably a donor-acceptor polymer comprising alternating electron-donating repeat units and electron-accepting repeat units.

Preferred are non-crystalline or semi- crystalline conjugated organic polymers.

Further preferably the electron-donating polymer is a conjugated organic polymer with a low bandgap, typically between 2.5 eV and 1.5 eV, preferably between 2.3 eV and 1.8 eV. Optionally, the electron-donating polymer has a HOMO level no more than 5.5 eV from vacuum level. Optionally, the electron-donating polymer has a HOMO level at least 4.1 eV from vacuum level. As exemplary electron-donating polymers, polymers selected from conjugated hydrocarbon or heterocyclic polymers including polyacene, polyaniline, polyazulene, polybenzofuran, polyfluorene, polyfuran, polyindenofluorene, polyindole, polyphenylene, polypyrazoline, polypyrene, polypyridazine, polypyridine, polytriarylamine, poly(phenylene vinylene), poly(3-substituted thiophene), poly(3,4-bi substituted thiophene), polyselenophene, poly(3-substituted selenophene), poly(3,4- bisubstituted selenophene), poly(bisthiophene), poly(terthiophene), poly(bisselenophene), poly(terselenophene), polythieno[2,3-b]thiophene, polythieno[3,2-b]thiophene, polybenzothiophene, polybenzofl ,2-b:4,5-b']dithiophene, polyisothianaphthene, poly(monosubstituted pyrrole), poly(3,4- bisubstituted pyrrole), poly-l,3,4-oxadiazoles, polyisothianaphthene, derivatives and copolymers thereof may be mentioned.

Preferred examples of donor polymers are copolymers of polyfluorenes and polythiophenes, each of which may be substituted, and polymers comprising benzothiadiazole-based and thiophene-based repeating units, each of which may be substituted.

A particularly preferred donor polymer comprises donor unit (Villa) provided as a repeat unit of the polymer, most preferably with an electron-accepting repeat unit, for example divalent electron-accepting units as described herein provided as polymeric repeat units.

Another particularly preferred donor polymer comprises a donor repeat unit and an electronaccepting repeat unit wherein the donor unit is an optionally substituted benzofl, 2-b:4, 5- b'] dithiophene unit. Optionally, the polymer comprises an electron-donating benzofl, 2-b:4,5-b']dithiophene repeat unit of formula (X): wherein R ¹⁷ and R ¹⁸ are each independently selected from H; F; C1-20 alkyl wherein one or more non-adjacent, non-terminal C atoms may be replaced with O, S, COO or CO and one or more H atoms of the alkyl may be replaced with F; or an aromatic group or heteroaromatic group Ar ¹⁰ which is unsubstituted or substituted with one or more substituents selected from F and C1-12 alkyl wherein one or more non-adjacent, non-terminal C atoms may be replaced with O, S, COO or CO.

A particularly preferred electron-accepting repeat unit of a polymer comprising an optionally substituted benzofl ,2-b:4,5-b']dithiophene unit donor unit is a repeat unit of formula (XI): wherein R ²⁷ and R ²⁸ are each independently selected from H or a substituent, more preferably an electron withdrawing substituent, with the proviso that at least one of R ²⁷ and R ²⁸ is an electron-withdrawing substituent. Exemplary electron-withdrawing substituents are F; CN; NO2; and COOR ²⁹ wherein R ²⁹ is a Ci -20 hydrocarbyl group, optionally a C1-12 alkyl or phenyl which is optionally substituted with one or more C1-12 alkyl groups.

Additional Electron-Accepting Materials In some embodiments, the compound of formula (I) as described herein is the only electronaccepting material of a bulk heterojunction layer.

In some embodiments, the bulk heterojunction layer contains a compound of formula (I) and one or more further electron-accepting materials. The one or more further electron-accepting materials may be selected from non-fullerene acceptors and fullerenes.

Non-fullerene acceptors are described in, for example, Cheng et. al., “Next-generation organic photovoltaics based on non-fullerene acceptors”, Nature Photonics volume 12, pages 131-142 (2018), the contents of which are incorporated herein by reference, and which include, without limitation, PDI, ITIC, ITIC, IEICO and derivatives thereof, e.g., fluorinated derivatives thereof such as ITIC-4F and IEICO-4F.

Exemplary fullerene electron-accepting compounds are Ceo, C70, C76, C78 and Cs4 fullerenes or a derivative thereof, including, without limitation, PCBM-type fullerene derivatives including phenyl-Cei-butyric acid methyl ester (CeoPCBM), TCBM-type fullerene derivatives (e.g. tolyl-Cei-butyric acid methyl ester (CeoTCBM)), and ThCBM-type fullerene derivatives (e.g. thienyl -Cei-butyric acid methyl ester (CeoThCBM).

Fullerene derivatives may have formula (V): wherein A, together with the C-C group of the fullerene, forms a monocyclic or fused ring group which may be unsubstituted or substituted with one or more substituents.

Exemplary fullerene derivatives include formulae (Va), (Vb) and (Vc):

wherein R ²⁰ -R ³² are each independently H or a substituent.

Substituents R ²⁰ -R ³² are optionally and independently in each occurrence selected from the group consisting of aryl or heteroaryl, optionally phenyl, which may be unsubstituted or substituted with one or more substituents; and C1-20 alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , CO or COO and one or more H atoms may be replaced with F.

Substituents of aryl or heteroaryl, where present, are optionally selected from C1-12 alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, NR ⁷ , CO or COO and one or more H atoms may be replaced with F.

Formulations

The bulk heterojunction layer may be formed by any process including, without limitation, thermal evaporation and solution deposition methods.

Preferably, the bulk heterojunction layer is formed by depositing a formulation comprising the electron-donating material(s), the electron-accepting material(s) and any other components of the bulk heterojunction layer dissolved or dispersed in a solvent or a mixture of two or more solvents. The formulation may be deposited by any coating or printing method including, without limitation, spin-coating, dip-coating, roll-coating, spray coating, doctor blade coating, wire bar coating, slit coating, ink jet printing, screen printing, gravure printing and flexographic printing.

The one or more solvents of the formulation may optionally comprise or consist of benzene substituted with one or more substituents selected from chlorine, Ci-io alkyl and Ci-io alkoxy wherein two or more substituents may be linked to form a ring which may be unsubstituted or substituted with one or more Ci-6 alkyl groups, optionally toluene, xylenes, trimethylbenzenes, tetramethylbenzenes, anisole, indane and its alkyl-substituted derivatives, and tetralin and its alkyl-substituted derivatives.

The formulation may comprise a mixture of two or more solvents, preferably a mixture comprising at least one benzene substituted with one or more substituents as described above and one or more further solvents. The one or more further solvents may be selected from esters, optionally alkyl or aryl esters of alkyl or aryl carboxylic acids, optionally a Ci-io alkyl benzoate, benzyl benzoate or dimethoxybenzene. In preferred embodiments, a mixture of trimethylbenzene and benzyl benzoate is used as the solvent. In other preferred embodiments, a mixture of trimethylbenzene and dimethoxybenzene is used as the solvent.

The formulation may comprise further components in addition to the electron-accepting material, the electron-donating material and the one or more solvents. As examples of such components, adhesive agents, defoaming agents, deaerators, viscosity enhancers, diluents, auxiliaries, flow improvers colourants, dyes or pigments, sensitizers, stabilizers, nanoparticles, surface-active compounds, lubricating agents, wetting agents, dispersing agents and inhibitors may be mentioned.

Organic Electronic Device

A polymer or composition as described herein may be provided as an active layer of an organic electronic device. In a preferred embodiment, a bulk heterojunction layer of an organic photoresponsive device, more preferably an organic photodetector, comprises a composition as described herein.

Figure 1 illustrates an organic photoresponsive device according to some embodiments of the present disclosure. The organic photoresponsive device comprises a cathode 103, an anode 107 and a bulk heterojunction layer 105 disposed between the anode and the cathode. The organic photoresponsive device may be supported on a substrate 101, optionally a glass or plastic substrate.

Each of the anode and cathode may independently be a single conductive layer or may comprise a plurality of layers.

At least one of the anode and cathode is transparent so that light incident on the device may reach the bulk heterojunction layer. In some embodiments, both of the anode and cathode are transparent. The transmittance of a transparent electrode may be selected according to an emission wavelength of a light source for use with the organic photodetector.

Figure 1 illustrates an arrangement in which the cathode is disposed between the substrate and the anode. In other embodiments, the anode may be disposed between the cathode and the substrate.

The organic photoresponsive device may comprise layers other than the anode, cathode and bulk heterojunction layer shown in Figure 1. In some embodiments, a hole-transporting layer is disposed between the anode and the bulk heterojunction layer. In some embodiments, an electron-transporting layer is disposed between the cathode and the bulk heterojunction layer. In some embodiments, a work function modification layer is disposed between the bulk heterojunction layer and the anode, and/or between the bulk heterojunction layer and the cathode.

The area of the OPD may be less than about 3 cm ² , less than about 2 cm ² , less than about 1 cm ² , less than about 0.75 cm ² , less than about 0.5 cm ² or less than about 0.25 cm ² . Optionally, each OPD may be part of an OPD array wherein each OPD is a pixel of the array having an area as described herein, optionally an area of less than 1 mm ² , optionally in the range of 0.5 micron ² - 900 micron ² .

The substrate may be, without limitation, a glass or plastic substrate. The substrate can be an inorganic semiconductor. In some embodiments, the substrate may be silicon. For example, the substrate can be a wafer of silicon. The substrate is transparent if, in use, incident light is to be transmitted through the substrate and the electrode supported by the substrate.

The bulk heterojunction layer contains a polymer as described herein and an electronaccepting compound. The bulk heterojunction layer may consist of these materials or may comprise one or more further materials, for example one or more further electron-donating materials and / or one or more further electron-accepting compounds.

Applications

A circuit may comprise the OPD connected to a voltage source for applying a reverse bias to the device and / or a device configured to measure photocurrent. The voltage applied to the photodetector may be variable. In some embodiments, the photodetector may be continuously biased when in use.

In some embodiments, a photodetector system comprises a plurality of photodetectors as described herein, such as an image sensor of a camera.

In some embodiments, a sensor may comprise an OPD as described herein and a light source wherein the OPD is configured to receive light emitted from the light source. In some embodiments, the light source has a peak wavelength of at least 900 nm, preferably at least 1000 nm, optionally in the range of 1000-1500 nm.

The present inventors have found that a material comprising an electron-accepting unit of formula (I) may be used for the detection of light at longer wavelengths, particularly 1300- 1400 nm.

In some embodiments, the light from the light source may or may not be changed before reaching the OPD. For example, the light may be reflected, filtered, down-converted or up- converted before it reaches the OPD.

The organic photoresponsive device as described herein may be an organic photovoltaic device or an organic photodetector. An organic photodetector as described herein may be used in a wide range of applications including, without limitation, detecting the presence and / or brightness of ambient light and in a sensor comprising the organic photodetector and a light source. The photodetector may be configured such that light emitted from the light source is incident on the photodetector and changes in wavelength and/or brightness of the light may be detected, e.g., due to absorption by, reflection by and/or emission of light from an object, e.g. a target material in a sample disposed in a light path between the light source and the organic photodetector. The sample may be a non-biological sample, e.g. a water sample, or a biological sample taken from a human or animal subject. The sensor may be, without limitation, a gas sensor, a biosensor, an X-ray imaging device, an image sensor such as a camera image sensor, a motion sensor (for example for use in security applications) a proximity sensor or a fingerprint sensor. A ID or 2D photosensor array may comprise a plurality of photodetectors as described herein in an image sensor. The photodetector may be configured to detect light emitted from a target analyte which emits light upon irradiation by the light source or which is bound to a luminescent tag which emits light upon irradiation by the light source. The photodetector may be configured to detect a wavelength of light emitted by the target analyte or a luminescent tag bound thereto.

EXAMPLES

Compound Example 1

Compound Example 1 was prepared according to the following reaction scheme:

High Performance Nonfullerene Polymer Solar Cells with High F _oc and PCE Simultaneously” Small 2020, 16, 1907681.

Compound 2

A solution of Compound 1 (3.94 g, 1.97 mmol) in toluene (100 mL) was degassed for 45 minutes. Intermediate 1 (0.29 g, 0.82 mmol), Pd2(dba)s (0.06 g, 0.07 mmol), and P(o-Tol)3 (0.08 g, 0.25 mmol) were added, and the mixture was heated to 65 °C for 3.5 hours under nitrogen and stirred at room temperature overnight. After this time, additional catalyst (60 mg) and ligand (75 mg) were added, and the solution was heated to 100 °C for 1 hour. An additional 90 mg of BisBT-diBr was added (50 mg), and the solution was heated at 100 °C for a further 4.5 hours. After this time the mixture was cooled to room temperature and the solvent was removed in vacuo to give a red/brown solid. The crude residue was purified by column chromatography (heptane/dichloromethane and toluene/heptane. to give Compound 2 (100g) as a dark red/brown solid.

Compound 3

Compound 2 (0.90 g, 0.45 mmol) was added to DMF (30 mL) under nitrogen and the mixture was heated gently until it dissolved. The mixture was then cooled to ~2 °C with an ice bath. POCh (0.45 mL, 4.47 mmol) was added dropwise (maintaining temperature < 5 °C). Once the addition was complete the mixture was stirred at room temperature for 15 minutes before being heated to 80 °C for 3.5 hours. The reaction was then cooled to room temperature and quenched with saturated sodium acetate, then additional water was added. The mixture was extracted three times with toluene and the organic phases were combined and extracted with aqueous NaCl to remove any residual DMF. The crude residue was purified by column chromatography (toluene) to give Compound 3 (0.99 g) as a red/brown solid.

Compound Example 1

Compound 3 (0.63 g, 0.30 mmol), Intermediate 2 (0.39 g, 1.52 mmol) and p-toluenesulfonic acid (0.43 g, 2.28 mmol) were placed in a flask under nitrogen. Toluene (8 mL) and ethanol (16 mL) were added and the mixture purged with nitrogen for 15 minutes. It was then was heated up to 65 °C overnight. After cooling to room temperature, it was filtered, washed twice with hot EtOH (25 mL), three times with hot MeOH (25 mL), and three times with pentane (25 mL) to give 0.66 g of a black solid The crude solid was purified via column chromatography (dichloromethane/heptane), dissolved in dichloromethane (10 mL) and reprecipitated into pentane (100 mL) to give Compound Example 1 (0.23 g) as a black solid.

'H NMR (300 MHz, THF-ds): 8 9.15 (bs, 2H), 9.01 (d, 3.93 Hz, 2H), 8.42 (s, 2H),

8.12 (s, 2H), 8.05 (bs, 2H), 7.88 (s, 2H), 7.38 (d, 8.11 Hz, 8H), 7.27 (d, 7.73 Hz, 8H),

7.13 (t, 7.93 Hz, 16H), 2.58 (t, 7.01 Hz, 16H), 1.62-1.57 (m, 16H), 1.36-1.28 (m, 48H), 0.89-0.85 (m, 24H).

LCMS (APCI+ve): 2513.45 ([M]+).

Compound Example 2

Compound Example 2 was prepared according to the following reaction scheme and as described for Compound Example 1 except that Compound 4 was used in place of Compound 1.

Compound 4 may be prepared as described in WO 2020/109825, the contents of which are incorporated herein by reference.

Absorption spectra An absorption spectrum for Compound Example 1 in o-dichlorobenzene solution is shown in Figure 2. This is overlaid with the absorption spectrum of Comparative Compound 1, illustrated below, which is reproduced from Zhang et al, “Electron-Deficient and Quinoid Central Unit Engineering for Unfused Ring-Based A ₁ –D–A ₂ –D–A ₁ -Type Acceptor Enables High Performance Nonfullerene Polymer Solar Cells with High Voc and PCE Simultaneously”, Small, DOI: 10.1002/smll.201907681. As shown in Figure 2, the absorption peak of Compound Example 1 is at around 1000 nm whereas that of Comparative Compound 1 is around 700 nm. Figure 3 shows the absorption spectrum of Compound Example 2 in 1 x 10 ^-6 M toluene solution and in a film coated from toluene solution.Compound Example 2 has a HOMO of - 5.16 eV and a LUMO of -4.11 eV as measured by square wave voltammetry of a film of Compound Example 2. Device Example 1 An organic photodetector having the following structure was prepared: Cathode / Donor : Acceptor layer / Anode A glass substrate coated with a layer of indium-tin oxide (ITO) was treated with polyethyleneimine (PEIE) to modify the work function of the ITO.

A mixture of Donor Polymer 1 (donor, illustrated below) and Compound Example 2 (nonfullerene acceptor) and PCBM (fullerene acceptor) in a donor : NFA : fullerene mas ratio of 1 : 0.875 : 0.625 was deposited over the modified ITO layer by blade coating from a 10 mg / ml solution in 1,2,4 trimethylbenzene : butyl benzoate 90: 10 v/v solvent mixture. The film was dried at 80°C to form a ca. 350-400 nm thick bulk heterojunction layer. An anode stack of MoOs (lOnm) and ITO (50nm) was formed over the bulk heterojunction by thermal evaporation (MoOs) and sputtering (ITO).

Donor Polymer 1 is a donor-acceptor polymer shown below, having a donor repeat unit of formula (Vila) and an acceptor repeat unit. Donor Polymer 1 may be prepared as described in WO2013/051676, the contents of which are incorporated herein by reference.

Donor Polymer 1

Device Example 2

Device Example 2 was prepared as described for Device Example 1 except that Donor

Polymer 2 was used in place of Donor Polymer 1 :

Donor Polymer 2

External quantum efficiencies and dark currents of Device Examples 1 and 2 are shown in Figures 4 and 5, respectively.

Modelling Examples

All modelling as described in these examples was performed using Gaussian09 software available from Gaussian using Gaussian09 with B3LYP (functional).

HOMO and LUMO levels were modelled for individual donor and acceptor units. Results are set out in Tables 1-3.

Table 1

Table 2 {

Table 3 |

| I i

Compounds with donor groups having 3 fused rings and more than 3 fused rings were modelled and results are set out in Table 4 in which Slf corresponds to oscillator strength of the transition from SI (predicting absorption intensity), Eopt is the modelled optical gap.

As shown in Table 4, compounds containing donor groups with 4 or more fused rings have a longer wavelength optical gap than comparative compounds in which the donor groups have only 3 fused rings.