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Title:
PI-CONJUGATED MACROMOLECULE AND BLOCK COPOLYMER PROVIDED WITH SAID PI-CONJUGATED MACROMOLECULE
Document Type and Number:
WIPO Patent Application WO/2015/079824
Kind Code:
A1
Abstract:
[Problem] To provide a pi-conjugated macromolecule with which both "control of molecular weight in accordance with catalytic amount" and a "reduction in use of precious metal catalysts and transition metal catalysts" can be achieved. [Solution] In the formation of this pi-conjugated macromolecule, a monomer provided with a perfluoroarene group, a pi-electron unit, and a silyl group is used. A fluoride is used as an initiator and a catalyst. Due to this, beginning with the release of the silyl group from the first monomer, the pi-electron unit itself constitutes a nucleophilic anion. Meanwhile, the perfluoroarene group of the second monomer bonds with the nucleophilic anion in the first monomer. The fluoride anion generates/regenerates anew, and releases the silyl group in the monomer that is to be polymerized next. Therein, the amount of the fluoride anion constitutes the catalytic amount in relation to the monomer, and thus the molecular weight can be controlled in accordance with the catalytic amount.

Inventors:
SANJI Takanobu (2-12-1 Ookayam, Meguro-ku Tokyo 50, 〒1528550, JP)
MOTOSHIGE Asahi (2-12-1 Ookayam, Meguro-ku Tokyo 50, 〒1528550, JP)
KAMBE Junko (2-12-1 Ookayam, Meguro-ku Tokyo 50, 〒1528550, JP)
WATANABE Satoru (2-12-1 Ookayam, Meguro-ku Tokyo 50, 〒1528550, JP)
IYODA Tomokazu (2-12-1 Ookayam, Meguro-ku Tokyo 50, 〒1528550, JP)
Application Number:
JP2014/077648
Publication Date:
June 04, 2015
Filing Date:
October 17, 2014
Export Citation:
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Assignee:
TOKYO INSTITUTE OF TECHNOLOGY (2-12-1, Ookayama Meguro-ku Tokyo, 50, 〒1528550, JP)
International Classes:
C08G61/12
Other References:
YONGFENG WANG ET AL.: "Transition-Metal-Free Synthesis of Alternating Thiophene- Perfluoroarene Copolymers", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 128, no. 8, 2006, pages 2536 - 2537
TAKASHI MORIKITA ET AL.: "Luminescent n- conjugated poly(aryleneethynylene)s consisting of plural aromatic units: Preparation and systematic studies on their optical properties", REACTIVE AND FUNCTIONAL POLYMERS, vol. 68, 2008, pages 1483 - 1491, XP025427757, DOI: doi:10.1016/j.reactfunctpolym.2008.07.007
KATHY B ET AL.: "Alternating Arene- Perfluoroarene Poly(phenylene ethynylenes", MACROMOLECULES, vol. 40, no. 13, 2007, pages 4470 - 4473
Attorney, Agent or Firm:
FUSE Takuya (35-1-701, Yamashita Narumi-cho, Midori-k, Nagoya-shi Aichi 01, 〒4580801, JP)
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