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Title:
Poly(9,9'-spiro-bisfluorenes), the production and use of same
Document Type and Number:
WIPO Patent Application WO1997020877
Kind Code:
A3
Abstract:
PCT No. PCT/EP96/05091 Sec. 371 Date May 29, 1998 Sec. 102(e) Date May 29, 1998 PCT Filed Nov. 19, 1996 PCT Pub. No. WO97/20877 PCT Pub. Date Jun. 12, 1997Soluble poly(bis-9,9'-fluorenes) comprise identical or different structural repeating units of the formula I, where the two R1s are, independently of one another, H, C1-C18alkyl, C6-C14aryl, C7-C15aralkyl, C1-C18alkoxy, R2-(O-CnH2n)m-O-, C1-C18alkylthio, C1-C18dialkylamino, -C(O)OH, -C(O)O-C1-C18alkyl, -C(O)-N(C1-C18alkyl)2, -SO3H, -SO3-C1-C18alkyl, -SO2-N(C1-C18alkyl)2, C1-C17-alkyl-C(O)-O- or C1-C17alkyl-C(O)-, R2 is H or C1-C12alkyl, n is from 2 to 6 and m is from 1 to 12. The polymers can be used either alone or in admixture with at least one additional fluorophore whose absorption band overlaps the emission band (fluorescent emission) of the polymer of the formula I as active radiative layer for light-emitting diodes, VDUs and display elements.

Inventors:
RIETZ RALF-ROMAN (DE)
WERNET WOLFGANG (DE)
Application Number:
PCT/EP1996/005091
Publication Date:
September 12, 1997
Filing Date:
November 19, 1996
Export Citation:
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Assignee:
RIETZ RALF-ROMAN (DE)
WERNET WOLFGANG (DE)
CIBA GEIGY JAPAN LTD (JP)
International Classes:
C07B61/00; C07C17/093; C07C17/12; C07C25/22; C07C45/46; C07C49/792; C07C49/813; C07C63/49; C08G61/00; C08G61/10; C08L65/00; C09K11/06; H01L51/50; (IPC1-7): C08G61/00; H05B33/14; C07C25/22; C07C43/20; C07C211/43; C07C63/42; C07C69/76; C07C233/85; C07C309/74; C07C311/16; C07C49/782; C07C69/035; C07C309/38
Foreign References:
EP0676461A21995-10-11
EP0707020A21996-04-17
US5026894A1991-06-25
Other References:
CHEMICAL ABSTRACTS, vol. 113, no. 22, 26 November 1990, Columbus, Ohio, US; abstract no. 192072
TAKAKAZU YAMAMOTO ET AL: "PREPARATION OF -CONJUGATED POLY(THIOPHENE-2,5-DIYL), POLY(P- PHENYLENE), AND RELATED POLYMERS USING ZEROVALENT NICKEL COMPLEXES LINEAR STRUCTURE AND PROPERTIES OF THE -CONJUGATED POLYMERS", MACROMOLECULES, vol. 25, no. 4, 17 February 1992 (1992-02-17), pages 1214 - 1223, XP000257555
CHEMICAL ABSTRACTS, vol. 118, no. 23, 7 June 1993, Columbus, Ohio, US; abstract no. 233206
CHEMICAL ABSTRACTS, vol. 116, no. 5, 3 February 1992, Columbus, Ohio, US; abstract no. 41262
DATABASE WPI Week 9238, Derwent World Patents Index; AN 313655
TOUR, J.: "Soluble oligo- and Polyphenylenes", ADV.MATER., vol. 6, no. 3, 1994, pages 190 - 198, XP002025942
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