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Title:
POLYMER ELECTROLYTE MEMBRANE, MEMBRANE ELECTRODE ASSEMBLY USING SAME, AND SOLID POLYMER FUEL CELL
Document Type and Number:
WIPO Patent Application WO/2013/031675
Kind Code:
A1
Abstract:
Provided is a polymer electrolyte membrane that has excellent proton conductivity even under low humidification conditions, has excellent mechanical strength and chemical stability, and can achieve high output and excellent physical durability when made into a solid polymer fuel cell. This polymer electrolyte membrane comprises a block copolymer including at least one each of a segment (A1) that contains an ionic group and a segment (A2) that does not contain an ionic group, the polymer electrolyte membrane being characterized by: forming a co-continuous (M1) or lamellar (M2) phase-separated structure; and having a crystallization heat quantity of 0.1 J/g or greater as measured by differential scanning calorimetry, or a degree of crystallinity of 0.5% or greater as measured by wide-angle X-ray diffraction.

Inventors:
UMEDA HIROAKI (JP)
IZUHARA DAISUKE (JP)
AMANO EMI (JP)
Application Number:
PCT/JP2012/071408
Publication Date:
March 07, 2013
Filing Date:
August 24, 2012
Export Citation:
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Assignee:
TORAY INDUSTRIES (JP)
UMEDA HIROAKI (JP)
IZUHARA DAISUKE (JP)
AMANO EMI (JP)
International Classes:
C08G65/40; H01M8/02; C08G81/00; C08J5/00; H01B1/06; H01M8/10
Domestic Patent References:
WO2008018487A12008-02-14
WO2008018487A12008-02-14
Foreign References:
JP2008007759A2008-01-17
JP2006278321A2006-10-12
JP2005126684A2005-05-19
JP2004031307A2004-01-29
JP2011181423A2011-09-15
JP2005190830A2005-07-14
JP2005216525A2005-08-11
JP2011023308A2011-02-03
JP2005126684A2005-05-19
JPH0216126A1990-01-19
JPH02208322A1990-08-17
JP2009009910A2009-01-15
Other References:
ANNUAL REVIEW OF PHYSICAL CHEMISTRY, vol. 41, 1990, pages 525
JOURNAL OF MEMBRANE SCIENCE, vol. 197, 2002, pages 231 - 242
POLYMER PREPRINTS, JAPAN, vol. 51, 2002, pages 750
THEODORA W. GREENE: "Protective Groups in Organic Synthesis", 1981, JOHN WILEY & SONS, INC.
J. ELECTROCHEM. SOC., vol. 53, 1985, pages 269
ELECTROCHEMICAL SCIENCE AND TECHNOLOGY, vol. 135, no. 9, 1988, pages 2209
Attorney, Agent or Firm:
Seiryu Patent Professional Corporation et al. (JP)
Clear stream international patent business corporation (JP)
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Claims: