Title:
POLYMERIZABLE SPHERICAL TRANSITION METAL COMPLEXES, SPHERICAL TRANSITION METAL COMPLEXES, AND PROCESSES FOR THE PRODUCTION OF BOTH
Document Type and Number:
WIPO Patent Application WO/2007/102501
Kind Code:
A1
Abstract:
[PROBLEMS] To provide a polymerizable spherical transition metal complex which has a hollow shell structure composed of transition metal atoms and bidentate organic ligands having substituents having polymerizable groups at the end, wherein the substituents are arrayed in the interior of the shell; a spherical transition metal complex as described above wherein the polymerizable groups are polymerized in the interior of the shell; and processes for the production of both. [MEANS FOR SOLVING PROBLEMS] A polymerizable spherical transition metal complex having a hollow shell structure, characterized in that the shell is composed of a transition metal atoms (wherein a is an integer of 6 to 60) and 2a bidentate organic ligands having substituents each having one or more polymerizable groups at the end and that the substituents are arrayed in the interior of the shell; a spherical transition metal complex as described above wherein the polymerizable groups are polymerized in the interior of the shell; and processes for the production of both.
Inventors:
FUJITA MAKOTO (JP)
SATO SOTA (JP)
MURASE TAKASHI (JP)
IIDA TETSUYA (JP)
HIGUCHI TAKANOBU (JP)
TANAKA SATORU (JP)
SATO SOTA (JP)
MURASE TAKASHI (JP)
IIDA TETSUYA (JP)
HIGUCHI TAKANOBU (JP)
TANAKA SATORU (JP)
Application Number:
PCT/JP2007/054313
Publication Date:
September 13, 2007
Filing Date:
March 06, 2007
Export Citation:
Assignee:
UNIV TOKYO (JP)
PIONEER CORP (JP)
FUJITA MAKOTO (JP)
SATO SOTA (JP)
MURASE TAKASHI (JP)
IIDA TETSUYA (JP)
HIGUCHI TAKANOBU (JP)
TANAKA SATORU (JP)
PIONEER CORP (JP)
FUJITA MAKOTO (JP)
SATO SOTA (JP)
MURASE TAKASHI (JP)
IIDA TETSUYA (JP)
HIGUCHI TAKANOBU (JP)
TANAKA SATORU (JP)
International Classes:
C07D213/30; C07F15/00
Domestic Patent References:
| WO2004039781A1 | 2004-05-13 |
Foreign References:
| JP2007015947A | 2007-01-25 | |||
| US20030166920A1 | 2003-09-04 | |||
| JP2006008996A | 2006-01-12 |
Other References:
TOMINAGA M. ET AL.: "24-Fold Endohedral Functionalication of a Self-Assembled M12L24 Coordination Nanoball", J. AM. CHEM. SOC., vol. 127, 2005, pages 11950 - 11951, XP002402975
OLENYUK B. ET AL.: "Molecular architecture of cyclic nanostructures: use of co-ordination chemistry in the building of supermolecules with predefined geometric shapes", J. CHEM. SOC. DALTON TRANS., no. 11, 1998, pages 1707 - 1728, XP003017664
FUJITA M. ET AL.: "Molecular paneling via coordination", CHEM. COMMUN., no. 6, 2001, pages 509 - 518, XP003017665
AOYAGI M. ET AL.: "Spectroscopic and crystallographic studies on the stability of self-assembled coordination nanotubes", CHEM. COMMUN., vol. 24, 2002, pages 2036 - 2037, XP003017666
FUJITA M. ET AL.: "Self-assembly of ten molecules into nanometre-sized organic host frameworks", NATURE, vol. 378, no. 30, 1995, pages 469 - 471, XP003017667
TAKEDA N. ET AL.: "A nanometre-sized hexahedral coordination capsule assembled from 24 components", NATURE, vol. 398, 1999, pages 794 - 796, XP003017668
OLENYUK B. ET AL.: "Molecular architecture of cyclic nanostructures: use of co-ordination chemistry in the building of supermolecules with predefined geometric shapes", J. CHEM. SOC. DALTON TRANS., no. 11, 1998, pages 1707 - 1728, XP003017664
FUJITA M. ET AL.: "Molecular paneling via coordination", CHEM. COMMUN., no. 6, 2001, pages 509 - 518, XP003017665
AOYAGI M. ET AL.: "Spectroscopic and crystallographic studies on the stability of self-assembled coordination nanotubes", CHEM. COMMUN., vol. 24, 2002, pages 2036 - 2037, XP003017666
FUJITA M. ET AL.: "Self-assembly of ten molecules into nanometre-sized organic host frameworks", NATURE, vol. 378, no. 30, 1995, pages 469 - 471, XP003017667
TAKEDA N. ET AL.: "A nanometre-sized hexahedral coordination capsule assembled from 24 components", NATURE, vol. 398, 1999, pages 794 - 796, XP003017668
Attorney, Agent or Firm:
MIZUNO, Katsufumi et al. (2-3, Marunouchi 2-chome,, Chiyoda-k, Tokyo05, JP)
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