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Title:
POLYMERIZATION FLUID, PROCESS FOR PRODUCTION THEREOF, TRANSPARENT FILM MADE FROM THE POLYMERIZATION FLUID, AND TRANSPARENT ELECTRODE
Document Type and Number:
WIPO Patent Application WO/2011/108254
Kind Code:
A1
Abstract:
Provided is a polymerization fluid for electrolytic polymerization which exhibits a reduced environmental load and excellent economic efficiency and which can yield an electroconductive polymer film that has high electric conductivity and that is dense and highly transparent. The polymerization fluid is characterized by: comprising both surfactant-free water and at least one monomer that is dispersed therein in the form of oil particles, said monomer being selected from the group consisting of 3,4-disubstituted thiophenes; and being transparent. The polymerization fluid can be prepared by a process which comprises: an addition step of adding the monomer to surfactant-free water to prepare a phase-separated fluid where the phase of water and the phase of the monomer are separated from each other; a first dispersion step of irradiating the phase-separated fluid with an ultrasonic wave to make the monomer dispersed in the form of oil particles and thus prepare an opaque dispersion; and a second dispersion step of irradiating the opaque dispersion with an ultrasonic wave having a higher frequency than that of the ultrasonic wave used in the first dispersion step to reduce the mean size of the oil particles of the monomer and thus form a transparent dispersion.

Inventors:
ATOBE, Mahito (4259 Nagatsutacho, Midori-ku, Yokohama-sh, Kanagawa 03, 〒2268503, JP)
跡部 真人 (〒03 神奈川県横浜市緑区長津田町4259国立大学法人東京工業大学内 Kanagawa, 〒2268503, JP)
NAKABAYASHI, Koji (4259 Nagatsutacho, Midori-ku, Yokohama-sh, Kanagawa 03, 〒2268503, JP)
中林 康二 (〒03 神奈川県横浜市緑区長津田町4259国立大学法人東京工業大学 Kanagawa, 〒2268503, JP)
Application Number:
JP2011/001182
Publication Date:
September 09, 2011
Filing Date:
March 01, 2011
Export Citation:
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Assignee:
TOKYO INSTITUTE OF TECHNOLOGY (12-1, Ookayama 2-chome Meguro-k, Tokyo 50, 〒1528550, JP)
国立大学法人東京工業大学 (〒50 東京都目黒区大岡山二丁目12番1号 Tokyo, 〒1528550, JP)
NIPPON CHEMI-CON CORPORATION (6-4 Osaki 5-chome, Shinagawa-ku Tokyo, 05, 〒1418605, JP)
日本ケミコン株式会社 (〒05 東京都品川区大崎五丁目6番4号 Tokyo, 〒1418605, JP)
ATOBE, Mahito (4259 Nagatsutacho, Midori-ku, Yokohama-sh, Kanagawa 03, 〒2268503, JP)
跡部 真人 (〒03 神奈川県横浜市緑区長津田町4259国立大学法人東京工業大学内 Kanagawa, 〒2268503, JP)
International Classes:
C08G61/12; H01B1/12; H01B13/00; H01G9/028
Attorney, Agent or Firm:
SATAKE, Kazuko (14-11-5, Kamiookahigashi 1-chome Konan-ku, Yokohama-sh, Kanagawa 01, 〒2330001, JP)
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Claims: