The present invention relates to a process for preparing a porous material, at least comprising the steps of providing a mixture (I) comprising a composition (A) comprising components suitable to form an organic gel and a solvent (B), reacting the components in the composition (A) in the presence of the solvent (B) to form a gel, and drying of the gel obtained in step b), wherein the composition (A) comprises at least one compound (af) comprising phosphorous and at least one functional group which is reactive towards isocyanates and at least one component (au) selected from the group consisting of urea, biuret, and derivatives of urea and biuret. The invention further relates to the porous materials which can be obtained in this way and the use of the porous materials as thermal insulation material and in vacuum insulation panels, as well as drying agent for gases, such as air, in filter systems, in adsorption heat pumps, as insulation material in damp and wet rooms, or to avoid mold formation.

Porous materials, for example polymer foams, having pores in the size range of a few microns or significantly below and a high porosity of at least 70 % are particularly good thermal insulators on the basis of theoretical considerations. Such porous materials having a small average pore diameter can be, for example, in the form of organic aerogels or xerogels which are produced with a sol-gel process and subsequent drying. In the sol-gel process, a sol based on a reactive organic gel precursor is first produced and the sol is then gelled by means of a crosslinking reaction to form a gel. To obtain a porous material, for example an aerogel, from the gel, the liquid has to be removed. This step will hereinafter be referred to as drying in the interests of simplicity.

WO 95/02009 A1 discloses isocyanate-based xerogels which are particularly suitable for applications in the field of vacuum insulation. The publication also discloses a sol-gel-based process for producing the xerogels, in which known, inter alia aromatic, polyisocyanates and an unreac- tive solvent are used. As further compounds having active hydrogen atoms, use is made of aliphatic or aromatic polyamines or polyols. The examples disclosed in the publication comprise ones in which a polyisocyanate is reacted with diaminodiethyltoluene. The xerogels disclosed generally have average pore sizes in the region of 50 μηη. In one example, mention is made of an average pore diameter of 10 μηη.

WO 2008/138978 A1 discloses xerogels which comprise from 30 to 90 % by weight of at least one polyfunctional isocyanate and from 10 to 70 % by weight of at least one polyfunctional aromatic amine and have a volume average pore diameter of not more than 5 microns. WO 201 1/069959 A1 , WO 2012/000917 A1 and WO 2012/059388 A1 describe porous materials based on polyfunctional isocyanates and polyfunctional aromatic amines, where the amine component comprises polyfunctional substituted aromatic amines. The porous materials described are produced by reacting isocyanates with the desired amount of amine in a solvent which is inert toward the isocyanates. The use of catalysts is known from WO 2012/000917 A1 and WO 2012/059388 A1 .

PCT/EP2017/05094 discloses a process for preparing a porous material, at least comprising the steps of providing a mixture (I) comprising a composition (A) comprising components suitable to form an organic gel and a solvent (B), reacting the components in the composition (A) in the presence of the solvent (B) to form a gel, and drying of the gel obtained in step b), wherein the composition (A) comprises at least one compound (af) comprising phosphorous and at least one functional group which is reactive towards isocyanates. The invention further relates to the porous materials which can be obtained in this way and the use of the porous materials as thermal insulation material and in vacuum insulation panels, in particular in interior or exterior thermal insulation systems as well as in water tank or ice maker insulation systems

However, the materials properties, in particular the mechanical stability and/or the compressive strength and also the thermal conductivity in combination with the water uptake of the porous materials, of the known porous materials based on polyurea are not satisfactory for all applications. In particular, the thermal conductivities in the ventilated state are not sufficiently low. In the case of open-cell materials, the ventilated state is the state under ambient pressure of air, whereas in the case of partially or completely closed-cell materials such as rigid polyurethane foams this state is reached only after aging, after the cell gas has gradually been completely replaced.

In particular for applications in the building sector, a high mechanical stability is necessary. Furthermore, for the insulation of interior rooms and for controlling the humidity, it is necessary that the materials remain stable upon water uptake and that the water uptake is reversible. Furthermore, they should have a good flame retardancy.

It was therefore an object of the invention to avoid the abovementioned disadvantages. In particular, a porous material which does not have the abovementioned disadvantages, or has them to a reduced extent, should be provided. The porous materials should have a low thermal conductivity in the ventilated state, i.e. at atmospheric pressure. Furthermore, the porous material should at the same time have a high porosity, a low density and a sufficiently high mechanical stability combined with good flame resistance and stability upon water uptake. According to the present invention, this object is solved by a process for preparing a porous material, at least comprising the steps of: a) providing a mixture (I) comprising

(i) a composition (A) comprising components suitable to form an organic gel and

(ii) a solvent (B),

b) reacting the components in the composition (A) in the presence of the solvent (B) to form a gel, and

c) drying of the gel obtained in step b), wherein the composition (A) comprises

at least one compound (af) comprising phosphorous and at least one functional group which is reactive towards isocyanates and

- at least one component (au) selected from the group consisting of urea, biuret, and derivatives of urea and biuret.

The porous materials of the present invention are preferably aerogels or xerogels.

Preferred embodiments may be found in the claims and the description. Combinations of preferred embodiments do not go outside the scope of the present invention. Preferred embodiments of the components used are described below. According to the present invention, in the process for preparing a porous material a mixture (I) comprising a composition (A) comprising components suitable to form an organic gel and a solvent (B) is provided in step a). Composition (A) comprises at least one compound (af) comprising phosphorous and at least one functional group which is reactive towards isocyanates at least one component (au) selected from the group consisting of urea, biuret, and derivatives of urea and biuret. According to step b) the components in composition (A) are reacted in the presence of the solvent (B) to form a gel. The gel is then dried according to step c) of the process of the present invention.

The process as disclosed above results in porous materials with improved properties, in particu- lar improved compressive strength, low thermal conductivity and good flame resistance. It was surprisingly found that the materials furthermore are stable upon water uptake and that the water uptake is reversible.

According to the present invention, compound (af) comprises phosphorous and at least one functional group which is reactive towards isocyanates. According to the present invention, the phosphorous can be present in the compound (af) in the form of a functional group comprising phosphorous or in any other part of the molecule, for example in the backbone of the molecule. The compound (af) further comprises at least one functional group which is reactive towards isocyanates. Compound (af) may also comprise two or more functional groups which are reac- tive towards isocyanates, in particular two groups which are reactive towards isocyanates.

Thus, according to a further embodiment, the present invention is directed to the process for preparing a porous material as disclosed above, wherein the compound (af) comprises phosphorous and at least two functional groups which are reactive towards isocyanates.

In the context of the present invention, urea, biuret or any suitable derivative of urea and biuret can be used as compound (au). Suitable derivatives are for example alkyl or aryl functionalized urea derivatives or alkyl or aryl functionalized biuret derivatives. Thus, according to a further embodiment, the present invention is directed to the process for preparing a porous material as disclosed above, wherein the compound (au) is selected from the group consisting of urea, dimethyl urea, diphenyl urea, ethylene urea, dihydroxy ethylene urea, propylene urea, and biuret.

According to a another embodiment, the present invention is directed to the process for preparing a porous material as disclosed above, wherein the composition (A) comprises the compound (au) in an amount in the range of from 0.1 to 15% by weight.

Typically, according to the present invention compound (af) is used in an amount which results in a phosphorous content in the porous material in a range of from 1 to 20 % by weight.

According to a another embodiment, the present invention is directed to the process for prepar- ing a porous material as disclosed above, wherein the compound (af) comprises at least one functional group comprising phosphorous.

Suitable functional groups which are reactive towards isocyanates are for example hydroxyl or amine groups. It is also possible in the context of the present invention, that composition (A) comprises two or more different compounds (af). Composition (A) may for example comprise one compound (af) which comprises phosphorous and at least one functional group which is reactive towards isocyanates and a second compound (af) which comprises phosphorous and at least two functional groups which are reactive towards isocyanates. Suitable functional groups comprising phosphorous are known to the person skilled in the art. The functional group comprising phosphorous may for example be selected from the group consisting of phosphates, phosphonates, phosphinates, phosphites, phosphonites, phos- phinites, and phosphine oxides. Thus, according to a further embodiment, the present invention is directed to the process for preparing a porous material as disclosed above, wherein the com- pound (af) comprises at least one functional group comprising phosphorous selected from the group consisting of phosphates, phosphonates, phosphinates, phosphites, phosphonites, phos- phinites, and phosphine oxides.

Composition (A) may also comprise a catalyst system (CS) which is also denoted as component (aO) in the following. The catalyst system (CS) preferably comprises a catalyst component (C1 ) and may comprise further components. According to the present invention, composition (A) may comprise a catalyst system (CS) comprising a catalyst component (C1 ) selected from the group consisting of alkali metal and earth alkali metal, ammonium, ionic liquid salts of a saturated or unsaturated carboxylic acid. Preferably, composition (A) comprises a catalyst system (CS) comprising a catalyst component (C1 ) selected from the group consisting of alkali metal and earth alkali metal, ammonium, ionic liquid salts of a saturated or unsaturated monocarboxylic acid. The catalyst component (C1 ) preferably is selected from the group consisting of alkali metal and earth alkali metal, ammonium, ionic liquid salts of a saturated or unsaturated carbox- ylic acid, preferably a monocarboxylic acid. In principle, any alkali metal or earth alkali metal salt of a saturated or unsaturated carboxylic acid, preferably a monocarboxylic acid or ammonium or ionic liquid salt can be used in the context of the present invention. It is also possible to use mixtures of two or more alkali metal or earth alkali metal salts of a saturated or unsaturated carbox- ylic acid, preferably a monocarboxylic acid in the context of the present invention.

Preferably, catalyst component (C1 ) is selected from the group consisting of alkali metal and earth alkali metal, ammonium, ionic liquid salts of a saturated or unsaturated carboxylic acid with 1 to 20 carbon atoms, more preferably, catalyst component (C1 ) is selected from the group consisting of alkali metal and earth alkali metal, ammonium, ionic liquid salts of saturated or unsaturated carboxylic acid with 1 to 8 carbon atoms. More preferably, catalyst component (C1 ) is selected from the group consisting of alkali metal and earth alkali metal, ammonium, ionic liquid salts of a saturated or unsaturated monocarboxylic acid with 1 to 20 carbon atoms, more preferably, catalyst component (C1 ) is selected from the group consisting of alkali metal and earth alkali metal, ammonium, ionic liquid salts of saturated or unsaturated monocarboxylic acid with 1 to 8 carbon atoms. Particularly preferably, catalyst component (C1 ) is selected from the group consisting of alkali metal and earth alkali metal salts of a saturated or unsaturated monocarboxylic acid with 1 to 20 carbon atoms, in particular, catalyst component (C1 ) is selected from the group consisting of alkali metal and earth alkali metal salts of saturated or unsaturated monocarboxylic acid with 1 to 8 carbon atoms, particularly (C1 ) is selected from the group consisting of alkali metal and earth alkali metal salts of a linear saturated or unsaturated monocarboxylic acid with 1 to 8 carbon atoms.

In the context of the present invention, alkali metal or earth alkali metal salts of saturated or un- saturated carboxylic acid, in particular a monocarboxylic acid monocarboxylic acids with 1 to 20 carbon atoms, in particular linear saturated and unsaturated monocarboxylic acids with 1 to 20 carbon atoms are preferably used. Suitable salts are for example sodium salts, potassium salts, or calcium salts of the respective monocarboxylic acid. Thus, according to a further embodiment, the present invention is directed to the process for preparing a porous material as disclosed above, wherein the catalyst component (C1 ) is selected from the group consisting of alkali metal and earth alkali metal, ammonium, ionic liquid salts of a saturated or unsaturated monocarboxylic acid with 1 to 20 carbon atoms. According to a further embodiment, the present invention is directed to the process for preparing a porous material as disclosed above, wherein the catalyst component (C1 ) is selected from the group consisting of alkali metal and earth alkali metal salts of a saturated or unsaturated monocarboxylic acid with 1 to 8, preferably 2 to 8 carbon atoms. Catalyst system (CS) can comprise further components as catalyst component (C2), for example a carboxylic acid. The amount of catalyst system (CS) used may vary in wide ranges. Suitable amount is for example in the range of from 0.1 to 30 % by weight, preferably of from 1 to 20 % by weight, more preferred of from 2 to 10 % by weight, in each case based on the total weight of the composition (A).

Thus, according to a further embodiment, the present invention is directed to the process for preparing a porous material as disclosed above, wherein the catalyst system (CS) is present in the composition (A) in an amount in the range of from 0.1 to 30 % by weight, based on the total weight of the composition (A).

The composition (A) may be any composition comprising components suitable to form an organic gel. Composition (A) comprises a compound (af) and compound (au) and may comprise a catalyst system (CS). Preferably, the composition (A) further comprises at least one polyfunc- tional isocyanate as component (a1 ) and possibly further components.

According to a further embodiment, the present invention thus is directed to the process for preparing a porous material as disclosed above, wherein the composition (A) comprises at least one polyfunctional isocyanate as component (a1 ). Composition (A) may also comprise further components, such as components which react with the polyfunctional isocyanate, one or more catalysts and optionally water. Preferably, the composition (A) comprises at least one polyfunctional isocyanate as component (a1 ), and at least one aromatic amine as component (a2), optionally comprises water as component (a3), and optionally comprises at least one catalyst as component (a4).

According to a further embodiment, the present invention therefore is directed to the process for preparing a porous material as disclosed above, wherein the composition (A) comprises at least one polyfunctional isocyanate as component (a1 ), and at least one aromatic amine as component (a2), optionally comprises water as component (a3), and optionally comprises at least one further catalyst as component (a4).

The polyfunctional isocyanates (a1 ) will hereinafter be referred to collectively as component (a1 ). Analogously, the aromatic amines (a2) will hereinafter be referred to collectively as component (a2). It will be obvious to a person skilled in the art that the monomer components men- tioned are present in reacted form in the porous material.

For the purposes of the present invention, the functionality of a compound is the number of reactive groups per molecule. In the case of the monomer component (a1 ), the functionality is the number of isocyanate groups per molecule. In the case of the amino groups of the monomer component (a2), the functionality is the number of reactive amino groups per molecule. A polyfunctional compound has a functionality of at least 2. If mixtures of compounds having different functionalities are used as component (a1 ) or (a2), the functionality of the components is in each case given by the number average of the functionality of the individual compounds. A polyfunctional compound comprises at least two of the abovementioned functional groups per molecule.

For the purposes of the present invention, a xerogel is a porous material which has been produced by a sol-gel process in which the liquid phase has been removed from the gel by drying below the critical temperature and below the critical pressure of the liquid phase ("subcritical conditions"). An aerogel is a porous material which has been produced by a sol-gel process in which the liquid phase has been removed from the gel under supercritical conditions.

Composition (A) may comprise further components such as for example at least one monool (am). In principle, any monool can be used in the context of the present invention. It is also possible according to the present invention that the composition (A) comprises two or more monools. The monool can be branched or linear. Primary, secondary or tertiary alcohols are suitable according to the present invention. Preferably, the monool (am) is a linear alcohol, more preferred a linear primary alcohol. The monool can be an aliphatic monool or an aromatic monool in the context of the present invention. Furthermore, the monool can also contain further functional groups as long as these do not react with the other components under the conditions of the process according to the present invention. The monool may for example contain C-C- double bonds or C-C triple bonds. The monool can for example be a halogenated monool, in particular a fluorinated monool such as a polyfluorinated monool or a perfluorinated monool.

According to a further embodiment, the present invention therefore is directed to the process for preparing a porous material as disclosed above, wherein the composition (A) comprises at least one monool (am).

In the context of the present invention, the monool may also be chosen from allyl alcohols, al- kylphenols, or propargyl alcohol. Furthermore, alkoxylates can be used in the context of the present invention such as fatty alcohol alkoxylates, oxo alcohol alkoxylates, or alkyl phenol alkoxylates.

According to a further preferred embodiment, the monool is selected from aliphatic or aromatic monools with 1 to 20 carbon atoms. Therefore, according to a further embodiment, the present invention is directed to the process for preparing a porous material as disclosed above, wherein the monool is selected from the group consisting of aliphatic monools with 1 to 20 carbon atoms and aromatic monools with 1 to 20 carbon atoms.

Suitable primary alcohols are for example linear alcohols such as methanol, ethanol, propanol, n-butanol, n-pentanol, n-hexanol, n-heptanol, n-octanol, n-nonanol, n-decanol, n-dodecanol, n- tetradecanol, n-hexadecanol, n-octadecanol and n-eicosanol. Suitable branched primary alcohols are for example isobutanol, isopentanol, isohexanol, isooctanol, isostearyl alcohol and iso- palmityl alcohol, 2-ethylhexyl alcohol, 3-n-propyl heptyl alcohol, 2-n-propyl heptyl alcohol, and 3- isopropyl heptyl alcohol.

Suitable secondary alcohols are for example isopropanol, sec-butanol, sec-pentanol (pentane- 2-ol), pentane-3-ol, cyclopentanol, cyclohexanol, sec-hexanol (hexane- 2-ol), hexane-3-ol, sec- heptanol (heptane-2-ol), heptane-3-ol, sec-decanol and decan-3-ol.

Examples of suitable tertiary alcohols are tert-butanol and tert-amyl alcohol. Generally, the amount of monool present in the composition (A) can vary in wide ranges. Preferably, the monool is present in the composition (A) in an amount of from 0.001 to 30 % by weight based on the composition (A), more preferable in an amount of from 0.005 to 25 % by weight based on the composition (A), in particular in an amount of from 0.01 to 22 % by weight based on the composition (A), for example in an amount of from 0.05 to 20 % by weight based on the composition (A).

According to a further embodiment, the present invention thus is directed to the process for preparing a porous material as disclosed above, wherein the monool is present in the composition (A) in an amount of from 0.001 to 30 % by weight based on the composition (A).

Composition (A) comprises components suitable to form an organic gel in suitable amounts. The composition (A) preferably comprises catalyst system (CS) as component (aO). The reaction is for example carried out using from 0.1 to 30 % by weight of catalyst system (CS) as component (aO), from 25 to 94.9 % by weight of component (a1 ), from 0.1 to 30 % by weight of component (a2), from 0 to 15 % by weight of water and from 0 to 29.9 % by weight of component (a4), in each case based on the total weight of the components (aO) to (a4), where the % by weight of the components (aO) to (a4) add up to 100 % by weight.

Typically, the component (af) is used in an amount in the range of 1 to 15 % by weight based on the sum of the weight of the components (aO) to (a4).

The reaction is preferably carried out using from 35 to 93.8 % by weight, in particular from 40 to 92.6 % by weight, of component (a1 ), from 0.2 to 25 % by weight, in particular from 0.4 to 23 % by weight, of component (a2), from 0.01 to 10 by weight, in particular from 0.1 to 9 % by weight, of water and from 0.1 to 30 % by weight, in particular from 1 to 28 % by weight, of component (a4), in each case based on the total weight of the components (aO) to (a4), where the % by weight of the components (aO) to (a4) add up to 100 % by weight.

The reaction is particularly preferably carried out using from 50 to 92.5 % by weight, in particular from 57 to 91.3 % by weight, of component (a1 ), from 0.5 to 18 % by weight, in particular from 0.7 to 16 % by weight, of component (a2), from 0.01 to 8 % by weight, in particular from 0.1 to 6 % by weight, of water and from 2 to 24 % by weight, in particular from 3 to 21 % by weight, of component (a4), in each case based on the total weight of the components (aO) to (a4), where the % by weight of the components (aO) to (a4) add up to 100 % by weight.

Within the abovementioned preferred ranges, the resulting gels are particularly stable and do not shrink or shrink only slightly in the subsequent drying step.

Component (a1 ) In the process of the invention, preferably at least one polyfunctional isocyanate is reacted as component (a1 ).

Preferably the amount of component (a1 ) used is at least 35 % by weight, in particular at least 40 % by weight, particularly preferably at least 45 % by weight, especially at least 57 % by weight. Preferably the amount of component (a1 ) used is at most 93.8 % by weight, in particular at most 92.6 % by weight, particularly preferably at most 92.5 % by weight, especially at most 91 .3 % by weight, in each case based on the total weight of the components (aO) to (a4).

Possible polyfunctional isocyanates are aromatic, aliphatic, cycloaliphatic and/or araliphatic iso- cyanates. Such polyfunctional isocyanates are known per se or can be prepared by methods known per se. The polyfunctional isocyanates can also be used, in particular, as mixtures, so that the component (a1 ) in this case comprises various polyfunctional isocyanates. Polyfunctional isocyanates which are possible as monomer building blocks (a1 ) have two (hereinafter referred to as diisocyanates) or more than two isocyanate groups per molecule of the monomer component.

Particularly suitable polyfunctional isocyanates are diphenylmethane 2,2'-, 2,4'- and/or 4,4'- diisocyanate (MDI), naphthylene 1 ,5-diisocyanate (NDI), tolylene 2,4- and/or 2, 6-diisocyanate (TDI), 3,3'-dimethylbiphenyl diisocyanate, 1 ,2-diphenylethane diisocyanate and/or p-phenylene diisocyanate (PPDI), trimethylene, tetramethylene, pentamethylene, hexamethylene, hep- tamethylene and/or octamethylene diisocyanate, 2-methylpentamethylene 1 ,5-diisocyanate, 2- ethylbutylene 1 ,4-diisocyanate, pentamethylene 1 ,5-diisocyanate, butylene 1 ,4-diisocyanate, 1 - isocyanato-3,3,5-trimethyl-5-isocyanatomethylcyclohexane (isophorone diisocyanate, IPDI), 1 ,4- and/or 1 ,3-bis(isocyanatomethyl)cyclohexane (HXDI), cyclohexane 1 ,4-diisocyanate, 1 - methylcyclohexane 2,4- and/or 2, 6-diisocyanate and dicyclohexylmethane 4,4'-, 2,4'- and/or 2,2'-diisocyanate.

As polyfunctional isocyanates (a1 ), preference is given to aromatic isocyanates. Particularly preferred polyfunctional isocyanates of the component (a1 ) are the following embodiments: i) polyfunctional isocyanates based on tolylene diisocyanate (TDI), in particular 2,4-TDI or 2,6-TDI or mixtures of 2,4- and 2,6-TDI; ii) polyfunctional isocyanates based on diphenylmethane diisocyanate (MDI), in particular 2,2'-MDI or 2,4'-MDI or 4,4'-MDI or oligomeric MDI, also referred to as polyphe- nylpolymethylene isocyanate, or mixtures of two or three of the abovementioned diphenylmethane diisocyanates or crude MDI which is obtained in the production of MDI or mix- tures of at least one oligomer of MDI and at least one of the abovementioned low molecular weight MDI derivatives;

iii) mixtures of at least one aromatic isocyanate according to embodiment i) and at least one aromatic isocyanate according to embodiment ii). Oligomeric diphenylmethane diisocyanate is particularly preferred as polyfunctional isocyanate. Oligomeric diphenylmethane diisocyanate (hereinafter referred to as oligomeric MDI) is an oligomeric condensation product or a mixture of a plurality of oligomeric condensation products and thus a derivative/derivatives of diphenylmethane diisocyanate (MDI). The polyfunctional isocyanates can preferably also be made up of mixtures of monomeric aromatic diisocyanates and oligomeric MDI.

Oligomeric MDI comprises one or more condensation products of MDI which have a plurality of rings and a functionality of more than 2, in particular 3 or 4 or 5. Oligomeric MDI is known and is frequently referred to as polyphenylpolymethylene isocyanate or as polymeric MDI. Oligomeric MDI is usually made up of a mixture of MDI-based isocyanates having various functionalities. Oligomeric MDI is usually used in admixture with monomeric MDI.

The (average) functionality of an isocyanate comprising oligomeric MDI can vary in the range from about 2.2 to about 5, in particular from 2.4 to 3.5, in particular from 2.5 to 3. Such a mixture of MDI-based polyfunctional isocyanates having various functionalities is, in particular, crude MDI which is obtained in the production of MDI.

Polyfunctional isocyanates or mixtures of a plurality of polyfunctional isocyanates based on MDI are known and are marketed, for example, by BASF Polyurethanes GmbH under the name Lu- pranat®.

The functionality of the component (a1 ) is preferably at least two, in particular at least 2.2 and particularly preferably at least 2.5. The functionality of the component (a1 ) is preferably from 2.2 to 4 and particularly preferably from 2.5 to 3.

The content of isocyanate groups in the component (a1 ) is preferably from 5 to 10 mmol/g, in particular from 6 to 9 mmol/g, particularly preferably from 7 to 8.5 mmol/g. A person skilled in the art will know that the content of isocyanate groups in mmol/g and the equivalent weight in g/equivalent have a reciprocal relationship. The content of isocyanate groups in mmol/g can be derived from the content in % by weight in accordance with ASTM D-5155-96 A.

In a preferred embodiment, the component (a1 ) comprises at least one polyfunctional isocyanate selected from among diphenylmethane 4,4'-diisocyanate, diphenylmethane 2,4'- diisocyanate, diphenylmethane 2,2'-diisocyanate and oligomeric diphenylmethane diisocyanate. In this preferred embodiment, the component (a1 ) particularly preferably comprises oligomeric diphenylmethane diisocyanate and has a functionality of at least 2.5. The viscosity of the component (a1 ) used can vary within a wide range. The component (a1 ) preferably has a viscosity of from 100 to 3000 mPa.s, particularly preferably from 200 to 2500 mPa.s.

Component (a2)

Composition (A) can further comprise at least one aromatic amine as component (a2). According to a further embodiment of the present invention, at least one aromatic amine is reacted as component (a2). The aromatic amine is a monofunctional amine or a polyfunctional amine.

According to a further embodiment, the present invention thus is directed to the process for preparing a porous material as disclosed above, wherein the at least one aromatic amine is a polyfunctional aromatic amine. Suitable monofunctional amines are for example substituted and unsubstituted aminobenzene, preferably substituted aniline derivatives having one or two alkyl residues, such as 2,6,- dimethylaniline, 2,6-diethylaniline, 2,6-diisopropylaninline, or 2-ethyl-6-isopropylaniline.

Preferably, the aromatic amine (a2) is a polyfunctional aromatic amine. According to a further embodiment, the present invention is directed to the process for preparing a porous material as disclosed above, wherein the at least one aromatic amine is a polyfunctional aromatic amine.

According to a further embodiment of the present invention, preferably at least one polyfunctional substituted aromatic amine (a2) having the general formula (I)

where R ¹ and R ² can be identical or different and are each selected independently from among hydrogen and linear or branched alkyl groups having from 1 to 6 carbon atoms and all substitu- ents Q ¹ to Q ⁵ and Q ¹ ' to Q ⁵ ' are identical or different and are each selected independently from among hydrogen, a primary amino group and a linear or branched alkyl group having from 1 to 12 carbon atoms, where the alkyl group can bear further functional groups, with the proviso that the compound having the general formula (I) comprises at least two primary amino groups, where at least one of Q ¹ , Q ³ and Q ⁵ is a primary amino group and at least one of Q ¹ ', Q ³ ' and Q ⁵ ' is a primary amino group, is/are reacted as component (a2) in the presence of a solvent (B).

In a preferred embodiment, Q ² , Q ⁴ , Q ² ' and Q ⁴ ' are selected so that the compound having the general formula (I) has at least one linear or branched alkyl group, which can bear further functional groups, having from 1 to 12 carbon atoms in the a position relative to at least one primary amino group bound to the aromatic ring. Component (a2) in this case comprises polyfunctional aromatic amines (a2-s). For the purposes of the present invention, polyfunctional amines are amines which have at least two amino groups which are reactive toward isocyanates per molecule. Here, primary and secondary amino groups are reactive toward isocyanates, with the reactivity of primary amino groups generally being significantly higher than that of secondary amino groups. The amount of component (a2) used is preferably at least 0.2 % by weight, in particular at least 0.4 % by weight, particularly preferably at least 0.7 % by weight, especially at least 1 % by weight. The amount of component (a2) used is preferably at most 25 % by weight, in particular at most 23 % by weight, particularly preferably at most 18 % by weight, especially at most 16 % by weight, in each case based on the total weight of the components (aO) to (a4).

According to a further embodiment, the present invention thus is directed to the process for preparing a porous material as disclosed above, wherein the at least one aromatic amine (a2) has the general formula (I)

where R ¹ and R ² can be identical or different and are each selected independently from among hydrogen and linear or branched alkyl groups having from 1 to 6 carbon atoms and all substitu- ents Q ¹ to Q ⁵ and Q ¹ ' to Q ⁵ ' are identical or different and are each selected independently from among hydrogen, a primary amino group and a linear or branched alkyl group having from 1 to 12 carbon atoms, where the alkyl group can bear further functional groups, with the proviso that the compound having the general formula (I) comprises at least two primary amino groups, where at least one of Q ¹ , Q ³ and Q ⁵ is a primary amino group and at least one of Q ¹ ', Q ³ ' and Q ⁵ ' is a primary amino group.

According to another further embodiment, the present invention is directed to the process for preparing a porous material as disclosed above, wherein composition (A) comprises (aO) from 0.1 to 30 % by weight of catalyst system (CS),

(a1 ) from 25 to 94.9 % by weight of at least one polyfunctional isocyanate, and

(a2) from 0.1 to 30 % by weight of at least one polyfunctional aromatic amine having the general formula I

where R ¹ and R ² can be identical or different and are each selected independently from among hydrogen and linear or branched alkyl groups having from 1 to 6 carbon atoms and all substituents Q ¹ to Q ⁵ and Q ¹ ' to Q ⁵ ' are identical or different and are each selected independently from among hydrogen, a primary amino group and a linear or branched alkyl group having from 1 to 12 carbon atoms, where the alkyl group can bear further functional groups, with the proviso that the compound having the general formula I comprises at least two primary amino groups, where at least one of Q ¹ , Q ³ and Q ⁵ is a primary amino group and at least one of Q ¹ ', Q ³ ' and Q ⁵ ' is a primary amino group, (a3) from 0 to 15 % by weight of water, and

(a4) from 0 to 29.9 % by weight of at least one further catalyst, in each case based on the total weight of the components (aO) to (a4), where the % by weight of the components (aO) to (a4) adds up to 100 % by weight and wherein the sum of the components (aO) and (a4) is in the range of from 0.1 to 30 % by weight based on the total weight of the components (aO) to (a4). According to the invention, R ¹ and R ² in the general formula (I) are identical or different and are each selected independently from among hydrogen, a primary amino group and a linear or branched alkyl group having from 1 to 6 carbon atoms. R ¹ and R ² are preferably selected from among hydrogen and methyl. Particular preference is given to R ¹ = R ² = H. Q ² , Q ⁴ , Q ² ' and Q ⁴ ' are preferably selected so that the substituted aromatic amine (a2-s) comprises at least two primary amino groups which each have one or two linear or branched alkyl groups having from 1 to 12 carbon atoms, which may bear further functional groups, in the a position. If one or more of Q ² , Q ⁴ , Q ² ' and Q ⁴ ' are selected so that they correspond to linear or branched alkyl groups which have from 1 to 12 carbon atoms and bear further functional groups, preference is given to amino groups and/or hydroxy groups and/or halogen atoms as such functional groups. The reduced reactivity brought about by the abovementioned alkyl groups in the a position leads, in combination with the use of the component (a4) described in more detail below, to particularly stable gels having particularly good thermal conductivities in the ventilated state.

The alkyl groups as substituents Q in the general formula (I) are preferably selected from among methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl and tert-butyl.

The amines (a2-s) are preferably selected from the group consisting of 3,3',5,5'-tetraalkyl-4,4'- diaminodiphenylmethane, 3,3',5,5'-tetraalkyl-2,2'-diaminodiphenylmethane and 3, 3', 5,5'- tetraalkyl-2,4'-diaminodiphenylmethane, where the alkyl groups in the 3, 3', 5 and 5' positions can be identical or different and are each selected independently from among linear or branched alkyl groups which have from 1 to 12 carbon atoms and can bear further functional groups. The abovementioned alkyl groups are preferably methyl, ethyl, n-propyl, i-propyl, n- butyl, sec-butyl or t-butyl (in each case unsubstituted). According to a further embodiment, the present invention therefore is directed to the process for preparing a porous material as disclosed above, wherein the amine component (a2) comprises at least one compound selected from the group consisting of 3,3',5,5'-tetraalkyl-4,4'- diaminodiphenylmethane, 3,3',5,5'-tetraalkyl-2,2'-diaminodiphenylmethane and 3, 3', 5,5'- tetraalkyl-2,4'-diaminodiphenylmethane, where the alkyl groups in the 3, 3', 5 and 5' positions can be identical or different and are selected independently from among linear or branched alkyl groups which have from 1 to 12 carbon atoms and can bear further functional groups.

In one embodiment, one, more than one or all hydrogen atoms of one or more alkyl groups of the substituents Q can have been replaced by halogen atoms, in particular chlorine. As an al- ternative, one, more than one or all hydrogen atoms of one or more alkyl groups of the substituents Q can have been replaced by NH2 or OH. However, the alkyl groups in the general formula (I) are preferably made up of carbon and hydrogen.

In a particularly preferred embodiment, component (a2) comprises 3,3',5,5'-tetraalkyl-4,4'- diaminodiphenylmethane, where the alkyl groups can be identical or different and are each selected independently from among linear or branched alkyl groups which have from 1 to 12 carbon atoms and can optionally bear functional groups. The abovementioned alkyl groups are preferably selected from among unsubstituted alkyl groups, in particular methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl and tert-butyl, particularly preferably methyl and ethyl. Very particu- lar preference is given to 3,3',5,5'-tetraethyl-4,4'-diaminodiphenylmethane and/or 3, 3', 5,5'- tetramethyl-4,4'-diaminodiphenylmethane. The abovementioned polyfunctional amines of the type (a2-s) are known per se to those skilled in the art or can be prepared by known methods. One of the known methods is the reaction of aniline or derivatives of aniline with formaldehyde in the presence of an acid catalyst, in particular the reaction of 2,4- or 2,6-dialkylaniline.

The component (a2) can optionally also comprise polyfunctional aromatic amines (a2-u) which differ from the amines of the structure (a2-s). The aromatic amines (a2-u) preferably have exclusively aromatically bound amino groups, but can also have both (cyclo)aliphatically and aro- matically bound reactive amino groups.

Suitable polyfunctional aromatic amines (a2-u) are, in particular, isomers and derivatives of di- aminodiphenylmethane. Isomers and derivatives of diaminodiphenylmethane which are preferred as constituents of component (a2) are, in particular, 4,4'-diaminodiphenylmethane, 2,4'- diaminodiphenylmethane, 2,2'-diaminodiphenylmethane and oligomeric diaminodiphenylme- thane.

Further suitable polyfunctional aromatic amines (a2-u) are, in particular, isomers and derivatives of toluenediamine. Isomers and derivatives of toluenediamine which are preferred as constituents of component (a2) are, in particular, toluene-2,4-diamine and/or toluene-2,6-diamine and diethyltoluenediamines, in particular 3,5-diethyltoluene-2,4-diamine and/or 3,5-diethyltoluene- 2,6-diamine.

In a first, particularly preferred embodiment, component (a2) consists exclusively of polyfunctional aromatic amines of the type (a2-s). In a second preferred embodiment, component (a2) comprises polyfunctional aromatic amines of the types (a2-s) and (a2-u). In the latter, second preferred embodiment, the component (a2) preferably comprises at least one polyfunctional aromatic amine (a2-u), of which at least one is selected from among isomers and derivatives of diaminodiphenylmethane (MDA). In the second preferred embodiment, component (a2) correspondingly particularly preferably comprises at least one polyfunctional aromatic amine (a2-u) selected from among 4,4'- diaminodiphenylmethane, 2,4'-diaminodiphenylmethane, 2,2'-diaminodiphenylmethane and oligomeric diaminodiphenylmethane. Oligomeric diaminodiphenylmethane comprises one or more methylene-bridged condensation products of aniline and formaldehyde having a plurality of rings. Oligomeric MDA comprises at least one oligomer, but in general a plurality of oligomers, of MDA having a functionality of more than 2, in particular 3 or 4 or 5. Oligomeric MDA is known or can be prepared by methods known per se. Oligomeric MDA is usually used in the form of mixtures with monomeric MDA.

The (average) functionality of a polyfunctional amine (a2-u) comprising oligomeric MDA can vary in the range from about 2.3 to about 5, in particular from 2.3 to 3.5 and in particular from 2.3 to 3. One such mixture of MDA-based polyfunctional amines having differing functionalities is, in particular, crude MDA which is formed, in particular, as intermediate in the condensation of aniline with formaldehyde, usually catalyzed by hydrochloric acid, in the production of crude MDI. In the abovementioned preferred second embodiment, particular preference is given to the component (a2) comprising oligomeric diaminodiphenylmethane as compound (a2-u) and having an overall functionality of at least 2.1.

The proportion of amines of type (a2-s) having the general formula (I) based on the total weight of all polyfunctional amines of the component (a2), which thus add up to a total of 100 % by weight, is preferably from 10 to 100 % by weight, in particular from 30 to 100 % by weight, very particularly preferably from 50 to 100 % by weight, in particular from 80 to 100 % by weight.

The proportion of polyfunctional aromatic amines (a2-u) which differ from the amines of type (a2-s) based on the total weight of all polyfunctional amines of the component (a2) is preferably from 0 to 90 % by weight, in particular from 0 to 70 % by weight, particularly preferably from 0 to 50 % by weight, in particular from 0 to 20 % by weight.

Component (a3)

Composition (A) can further comprise water as component (a3). If water is used, the preferred amount of water used is at least 0.01 % by weight, in particular at least 0.1 % by weight, particularly preferably at least 0.5 % by weight, in particular at least 1 % by weight. If water is used, the preferred amount of water used is at most 15 % by weight, in particular at most 13 % by weight, particularly preferably at most 1 1 % by weight, in particular at most 10 % by weight, very particularly preferably at most 9 % by weight, in particular at most 8 % by weight, in each case based on the total weight of the composition (A), which is 100 % by weight. In a particularly preferred embodiment, water is not used.

According to a further embodiment, the present invention is directed to the process for preparing a porous material as disclosed above, wherein no water is used.

According to an alternative further embodiment, the present invention is directed to the process for preparing a porous material as disclosed above, wherein at least 0.1 % by weight of water is added.

A calculated content of amino groups can be derived from the water content and the content of reactive isocyanate groups of the component (a1 ) by assuming complete reaction of the water with the isocyanate groups of the component (a1 ) to form a corresponding number of amino groups and adding this content to the content resulting from component (a2) (total n ^amine ). The resulting use ratio of the calculated remaining NCO groups n ^NCO to the amino groups calculated to have been formed and used will hereinafter be referred to as calculated use ratio n ^NCO /n ^amine and is an equivalence ratio, i.e. a molar ratio of the respective functional groups.

Water reacts with the isocyanate groups to form amino groups and liberate CO2. Polyfunctional amines are therefore partially produced as intermediate (in situ). In the further course of the reaction, they are reacted with isocyanate groups to form urea linkages. The production of amines as intermediate leads to porous materials having particularly high mechanical stability and low thermal conductivity. However, the CO2 formed must not disrupt gelling to such an extent that the structure of the resulting porous material is influenced in an undesirable way. This gives the abovementioned preferred upper limits for the water content based on the total weight of the composition (A).

In this case, the calculated use ratio (equivalence ratio) n ^NCO /n ^amine is preferably from 1.01 to 5. The equivalence ratio mentioned is particularly preferably from 1.1 to 3, in particular from 1 .1 to 2. An excess of n ^NCO over n ^amine leads, in this embodiment, to lower shrinkage of the porous material, in particular xerogel, in the removal of the solvent and as a result of synergistic interaction with the catalyst (a4) to an improved network structure and to improved final properties of the resulting porous material. The components (aO) to (a4) and if present (am) will hereinafter be referred to collectively as organic gel precursor (Α'). It will be obvious to a person skilled in the art that the partial reaction of the component (aO) to (a4) and (am) leads to the actual gel precursor (Α') which is subsequently converted into a gel.

Catalyst (a4)

The composition (A) can further comprise at least one further catalyst as component (a4). The amount of component (a4) used is preferably at least 0.1 % by weight, in particular at least 0.2 % by weight, particularly preferably at least 0.5 % by weight, in particular at least 1 % by weight. The amount of component (a4) used is preferably at most 29.9 % by weight, in particular at most 28 % by weight, particularly preferably at most 24 % by weight, in particular at most 21 % by weight, in each case based on the total weight of the composition (A). Possible catalysts used as component (a4) are in principle all catalysts known to those skilled in the art which accelerate the trimerization of isocyanates (known as trimerization catalysts) and/or the reaction of isocyanates with amino groups (known as gelling catalysts) and/or the reaction of isocyanates with water (known as blowing catalysts). The corresponding catalysts are known per se and have different relative activities in respect of the abovementioned three reactions. Depending on the relative activity, they can thus be assigned to one or more of the abovementioned types. Furthermore, it will be known to a person skilled in the art that reactions other than those mentioned above can also occur. Corresponding catalysts can be characterized, inter alia, according to their gelling to blowing ratio, as is known, for example, from Polyurethane, 3 ^rd edition, G. Oertel, Hanser Verlag, Munich, 1993.

According to a further embodiment, the present invention is directed to the process for preparing a porous material as disclosed above, wherein the catalyst catalyzes the trimerization to form isocyanurate groups. According to another embodiment, the present invention is directed to the process for preparing a porous material as disclosed above, wherein component (a4) comprises at least one tertiary amino group.

Preferred catalysts (a4) have a balanced gelling to blowing ratio, so that the reaction of the component (a1 ) with water is not too strongly accelerated, leading to an adverse effect on the network structure, and at the same time results in a short gelling time so that the demolding time is advantageously short. Preferred catalysts at the same time have a significant activity in respect of trimerization. This favorably influences the homogeneity of the network structure, resulting in particularly advantageous mechanical properties.

The catalysts can be able to be incorporated as a monomer building block (incorporatable catalyst) or not be able to be incorporated.

Catalysts preferred as component (a4) are selected from the group consisting of primary, sec- ondary and tertiary amines, triazine derivatives, urea derivatives, organic metal compounds, metal chelates, organophosphorus compounds, in particular oxides of phospholenes, quaternary ammonium salts, ammonium hydroxides and also alkali metal and alkaline earth metal hydroxides, alkoxides and carboxylates. According to a further embodiment, the present invention thus is directed to the process for preparing a porous material as disclosed above, wherein component (a4) is selected from the group consisting of primary, secondary and tertiary amines, triazine derivatives, metal-organic compounds, metal chelates, oxides of phospholenes, quaternary ammonium salts, ammonium hydroxides and alkali metal and alkaline earth metal hydroxides, alkoxides and carboxylates.

Suitable organophosphorus compounds, in particular oxides of phospholenes, are, for example, 1 -methylphospholene oxide, 3-methyl-1 -phenylphospholene oxide, 1 -phenylphospholene oxide, 3-methyl-1 -benzylphospholene oxide. In the context of the present invention, for example those urea derivatives are used which are known as catalysts for polyurethane formation. Suitable urea-based compounds are urea and urea derivatives such as for example, dimethyl urea, diphenyl urea, ethylene urea, propylene urea, dihydroxy ethylene urea. The suitable catalysts (a4) are preferably trimerization catalysts. Suitable trimerization catalysts are in particular strong bases, for example quaternary ammonium hydroxides such as tetraalkylammonium hydroxides having from 1 to 4 carbon atoms in the alkyl radical and ben- zyltrimethylammonium hydroxide, alkali metal hydroxides such as potassium or sodium hydroxide and alkali metal alkoxides such as sodium methoxide, potassium and sodium ethoxide and potassium isopropoxide.

Further suitable trimerization catalysts are, in particular, alkali metal salts of carboxylic acids, e.g. potassium formate, sodium acetate, potassium acetate, caesium acetate, ammonium acetate, potassium propionate, potassium sorbate, potassium 2-ethylhexanoate, potassium oc- tanoate, potassium trifluoroacetate, potassium trichloroacetate, sodium chloroacetate, sodium dichloroacetate, sodium trichloroacetate, potassium adipate, potassium benzoate, sodium ben- zoate, alkali metal salts of saturated and unsaturated long-chain fatty acids having from 10 to 20 carbon atoms, and optionally lateral OH groups

Further suitable trimerization catalysts are, in particular, N-hydroxyalkyl quaternary ammonium carboxylates, e.g. trimethylhydroxypropylammonium formate. Further suitable trimerization catalysts are, in particular 1 -ethyl-3-methylimidazolium acetate (EMIM acetate) and 1 -butyl-3-methylimidazolium acetate (BMIM acetate), 1 -ethyl-3- methylimidazolium octanoate (EMIM octanoate) and 1 -butyl-3-methylimidazolium octanoate (BMIM octanoate). Tertiary amines are also known per se to those skilled in the art as trimerization catalysts. Tertiary amines, i.e. compounds having at least one tertiary amino group, are particularly preferred as catalysts (a4). Suitable tertiary amines having distinct properties as trimerization catalysts are, in particular, N,N',N"-tris(dialkylaminoalkyl)-s-hexahydrotriazines, such as Ν,Ν',Ν"- tris(dimethylaminopropyl)-s-hexahydrotriazine, tris(dimethylaminomethyl)phenol.

Metal-organic compounds are known per se as gel catalysts to a person skilled in the art. Tin- organic compounds such as tin 2-ethylhexanoate and dibutyltin dilaurate are particularly preferred. Tertiary amines are also known per se as gel catalysts to a person skilled in the art. As mentioned above, tertiary amines are particularly preferred as catalysts (a4). Suitable tertiary amines having good properties as gel catalysts are, in particular, N,N-dimethylbenzylamine, Ν,Ν'-dimethylpiperazine and Ν,Ν-dimethylcyclohexylamine, bis(2-dimethylaminoethyl) ether, Ν,Ν,Ν,Ν,Ν-pentamethyldiethylenetriamine, methylimidazole, dimethylimidazole, aminopropylim- idazole, dimethylbenzylamine, 1 ,6-diazabicyclo[5.4.0]undec-7-ene, triethylamine, triethylenedi- amine (1 ,4-diazabicyclo[2.2.2]octane), dimethylaminoethanolamine, dimethylaminopropylamine, N,N-dimethylaminoethoxyethanol, Ν,Ν,Ν-trimethylaminoethylethanolamine, triethanolamine, diethanolamine, triisopropanolamine, diisopropanolamine, methyldiethanolamine and butyldi- ethanolamine.

Catalysts which are particularly preferred as component (a4) are selected from the group con- sisting of dimethylcyclohexylamine, dimethylpiperazine, bis(2-dimethylaminoethyl) ether,

Ν,Ν,Ν,Ν,Ν-pentamethyldiethylenetriamine, methylimidazole, dimethylimidazole, aminopropylim- idazole, dimethylbenzylamine, 1 ,6-diazabicyclo[5.4.0]undec-7-ene, trisdimethylaminopropylhex- ahydrotriazine, triethylamine, tris(dimethylaminomethyl)phenol, triethylenediamine (diazabicy- clo[2.2.2]octane), dimethylaminoethanolamine, dimethylaminopropylamine, N,N- dimethylaminoethoxyethanol, Ν,Ν,Ν-trimethylaminoethylethanolamine, triethanolamine, diethanolamine, triisopropanolamine, diisopropanolamine, methyldiethanolamine, butyldiethanola- mine.

Very particular preference is given to dimethylcyclohexylamine, dimethylpiperazine, methylimid- azole, dimethylimidazole, dimethylbenzylamine, 1 ,6-diazabicyclo[5.4.0]undec-7-ene, trisdime- thylaminopropylhexahydrotriazine, triethylamine, tris(dimethylaminomethyl)phenol, triethylenediamine (diazabicyclo[2.2.2]octane), dimethylaminoethanolamine, dimethylaminopropylamine, Ν,Ν,Ν-trimethylaminoethylethanolamine, triethanolamine, diethanolamine, methyldiethanolamine, butyldiethanolamine, metal acetylacetonates, ammonium ethylhexanoates, metal ace- tates, propionates, sorbates, ethylhexanoates, octanoates and benzoates.

Therefore, according to a further embodiment, the present invention is directed to the process for preparing a porous material as disclosed above, wherein component (a4) is selected from the group consisting of dimethylcyclohexylamine, bis(2-dimethylaminoethyl) ether, Ν,Ν,Ν,Ν,Ν- pentamethyldiethylenetriamine, methylimidazole, dimethylimidazole, aminopropylimidazole, dimethylbenzylamine, 1 ,6-diazabicyclo[5.4.0]undec-7-ene, trisdimethylaminopropylhexa- hydrotriazine, triethylamine, tris(dimethylaminomethyl)phenol, triethylenediamine (diazabicy- clo[2.2.2]octane), dimethylaminoethanolamine, dimethylaminopropylamine, N,N- dimethylaminoethoxyethanol, Ν,Ν,Ν-trimethylaminoethylethanolamine, triethanolamine, dieth- anolamine, triisopropanolamine, diisopropanolamine, methyldiethanolamine, butyldiethanolamine, metal acetylacetonates, ammonium ethylhexanoates and metal acetates, propionates, sorbates, ethylhexanoates, octanoates and benzoates.

According to the present invention, it is possible to use the catalyst as such in the process of the invention. It is also possible to use the catalyst in form of a solution. Furthermore, the catalyst (a4) can be combined with catalyst system (CS).

Solvent (B)

According to the present invention, the reaction takes place in the presence of a solvent (B). For the purposes of the present invention, the term solvent (B) comprises liquid diluents, i.e. both solvents in the narrower sense and also dispersion media. The mixture can, in particular, be a true solution, a colloidal solution or a dispersion, e.g. an emulsion or suspension. The mixture is preferably a true solution. The solvent (B) is a compound which is liquid under the condi- tions of step (a), preferably an organic solvent.

The solvent (B) can in principle be any suitable compound or mixture of a plurality of compounds, with the solvent (B) being liquid under the temperature and pressure conditions under which the mixture is provided in step (a) (dissolution conditions for short). The composition of the solvent (B) is selected so that it is able to dissolve or disperse, preferably dissolve, the organic gel precursor. Preferred solvents (B) are those which are a solvent for the components (af), (au) and (a1 ) to (a4), i.e. ones which dissolve the components (af) and (a1 ) to (a4) completely under the reaction conditions. The reaction product of the reaction in the presence of the solvent (B) is initially a gel, i.e. a vis- coelastic chemical network which is swollen by the solvent (B). A solvent (B) which is a good swelling agent for the network formed in step (b) generally leads to a network having fine pores and a small average pore diameter, while a solvent (B) which is a poor swelling agent for the gel resulting from step (b) generally leads to a coarse-pored network having a large average pore diameter.

The choice of the solvent (B) thus influences the desired pore size distribution and the desired porosity. The choice of the solvent (B) is also generally made in such a way that precipitation or flocculation due to formation of a precipitated reaction product does not occur to a significant extent during or after step (b) of the process of the invention.

When a suitable solvent (B) is chosen, the proportion of precipitated reaction product is usually less than 1 % by weight, based on the total weight of the mixture. The amount of precipitated product formed in a particular solvent (B) can be determined gravimetrically by filtering the reac- tion mixture through a suitable filter before the gelling point.

Possible solvents (B) are solvents known from the prior art for isocyanate-based polymers. Preferred solvents are those which are a solvent for the components (af), (au) and (a1 ) to (a4), i.e. solvents which dissolve the constituents of the components (af), (au) and (a1 ) to (a4) virtually completely under the reaction conditions. The solvent (B) is preferably inert, i.e. unreactive, toward component (a1 ). Furthermore, solvent (B) preferably is miscible with monool (am).

Possible solvents (B) are, for example, ketones, aldehydes, alkyl alkanoates, amides such as formamide, N-methylpyrollidone, N-ethylpyrollidone, sulfoxides such as dimethyl sulfoxide, ali- phatic and cycloaliphatic halogenated hydrocarbons, halogenated aromatic compounds and fluorine-containing ethers. Mixtures of two or more of the abovementioned compounds are likewise possible. Further possibilities as solvents (B) are acetals, in particular diethoxymethane, dimethox- ymethane and 1 ,3-dioxolane.

DialkyI ethers and cyclic ethers are likewise suitable as solvent (B). Preferred dialkyi ethers are, in particular, those having from 2 to 6 carbon atoms, in particular methyl ethyl ether, diethyl ether, methyl propyl ether, methyl isopropyl ether, propyl ethyl ether, ethyl isopropyl ether, di- propyl ether, propyl isopropyl ether, diisopropyl ether, methyl butyl ether, methyl isobutyl ether, methyl t-butyl ether, ethyl n-butyl ether, ethyl isobutyl ether and ethyl t-butyl ether. Preferred cyclic ethers are, in particular, tetrahydrofuran, dioxane and tetrahydropyran.

Aldehydes and/or ketones are particularly preferred as solvent (B). Aldehydes or ketones suitable as solvent (B) are, in particular, those corresponding to the general formula R ² -(CO)-R ¹ , where R ¹ and R ² are each hydrogen or an alkyl group having 1 , 2, 3, 4, 5, 6 or 7 carbon atoms. Suitable aldehydes or ketones are, in particular, acetaldehyde, propionaldehyde, n- butyraldehyde, isobutyraldehyde, 2-ethylbutyraldehyde, valeraldehyde, isopentaldehyde, 2- methylpentaldehyde, 2-ethylhexaldehyde, acrolein, methacrolein, crotonaldehyde, furfural, acrolein dimer, methacrolein dimer, 1 ,2,3,6-tetrahydrobenzaldehyde, 6-methyl-3- cyclohexenaldehyde, cyanoacetaldehyde, ethyl glyoxylate, benzaldehyde, acetone, diethyl ketone, methyl ethyl ketone, methyl isobutyl ketone, methyl n-butyl ketone, methyl pentylketone, dipropyl ketone, ethyl isopropyl ketone, ethyl butyl ketone, diisobutylketone, 5-methyl-2-acetyl furan, 2-acetylfuran, 2-methoxy-4-methylpentan-2-one, 5-methylheptan-3-one, 2-heptanone, octanone, cyclohexanone, cyclopentanone, and acetophenone. The abovementioned aldehydes and ketones can also be used in the form of mixtures. Ketones and aldehydes having alkyl groups having up to 3 carbon atoms per substituent are preferred as solvent (B).

Further preferred solvents are alkyl alkanoates, in particular methyl formate, methyl acetate, ethyl formate, isopropyl acetate, butyl acetate, ethyl acetate, glycerine triacetate and ethyl acetoacetate. Preferred halogenated solvents are described in WO 00/24799 A1 , page 4, line 12 to page 5, line 4.

Further suitable solvents (B) are organic carbonates such as for example dimethyl carbonate, diethyl carbonate, ethylene carbonate, propylene carbonate or butylene carbonate.

In many cases, particularly suitable solvents (B) are obtained by using two or more completely miscible compounds selected from the abovementioned solvents.

To obtain a sufficiently stable gel which does not shrink too much during drying in step (c) in step (b), the proportion of the composition (A) based on the total weight of the mixture (I) comprising composition (A) and the solvent (B), which is 100 % by weight, must generally be not less than 5 % by weight. The proportion of the composition (A) based on the total weight of the mixture (I) comprising composition (A) and the solvent (B), which is 100 % by weight, is preferably at least 6 % by weight, particularly preferably at least 8 % by weight, in particular at least 10 % by weight. On the other hand, the concentration of the composition (A) in the mixture provided must not be too high since otherwise no porous material having favorable properties is obtained. In general, the proportion of the composition (A) based on the total weight of the mixture (I) comprising composition (A) and the solvent (B), which is 100 % by weight, is not more than 40 % by weight. The proportion of the composition (A) based on the total weight of the mixture (I) comprising composition (A) and the solvent (B), which is 100 % by weight, is preferably not more than 35 % by weight, particularly preferably not more than 25 % by weight, in particular not more than 20 % by weight.

The total proportion by weight of the composition (A) based on the total weight of the mixture (I) comprising composition (A) and the solvent (B), which is 100 % by weight, is preferably from 8 to 25 % by weight, in particular from 10 to 20 % by weight, particularly preferably from 12 to 18 % by weight. Adherence to the amount of the starting materials in the range mentioned leads to porous materials having a particularly advantageous pore structure, low thermal conductivity and low shrinking during drying.

Before the reaction, it is necessary to mix the components used, in particular to mix them homogeneously. The rate of mixing should be high relative to the rate of the reaction in order to avoid mixing defects. Appropriate mixing methods are known per se to those skilled in the art.

According to the present invention, a solvent (B) is used. The solvent (B) can also be a mixture of two or more solvents, for example three or four solvents. Suitable solvents are for example mixtures of two or more ketones, for example mixtures of acetone and diethyl ketone, mixtures of acetone and methyl ethyl ketone or mixtures of diethyl ketone and methyl ethyl ketone.

Further preferred solvents are mixtures of propylene carbonate with one or more solvents, for example mixtures of propylene carbonate and diethyl ketone, or mixtures of propylene carbonate with two or more ketones, for example mixtures of propylene carbonate with acetone and diethyl ketone, mixtures of propylene carbonate with acetone and methyl ethyl ketone or mixtures of propylene carbonate with diethyl ketone and methyl ethyl ketone.

Preferred process for producing the porous materials

The process of the invention comprises at least the following steps:

(a) provision of the mixture comprising the composition (A) and the solvent (B) as described above,

(b) reaction of the components in composition (A) in the presence of the solvent (B) to form a gel and

(c) drying of the gel obtained in the preceding step. Preferred embodiments of steps (a) to (c) will be described in detail below. Step (a) According to the invention, a mixture comprising composition (A) and the solvent (B) are provided in step (a).

The components of composition (A), for example the components (a1 ) and (a2) are preferably provided separately from one another, each in a suitable partial amount of the solvent (B). The separate provision makes it possible for the gelling reaction to be optimally monitored or controlled before and during mixing.

Component (af) and (au) and optionally composition (CS), optionally (am), (a3) and (a4) are particularly preferably provided as a mixture with component (a2), i.e. separately from compo- nent (a1 ).

The mixture or mixtures provided in step (a) can also comprise customary auxiliaries known to those skilled in the art as further constituents. Mention may be made by way of example of surface-active substances, further flame retardants, nucleating agents, opacifiers, oxidation stabi- lizers, lubricants and mold release agents, dyes and pigments, stabilizers, e.g. against hydrolysis, light, heat or discoloration, inorganic and/or organic fillers, reinforcing materials and bio- cides.

Further information regarding the abovementioned auxiliaries and additives may be found in the specialist literature, e.g. in Plastics Additive Handbook, 5th edition, H. Zweifel, ed. Hanser Publishers, Munich, 2001 .

Step (b)

According to the invention, the reaction of the components of composition (A) takes place in the presence of the solvent (B) to form a gel in step (b). To carry out the reaction, a homogeneous mixture of the components provided in step (a) firstly has to be produced. The provision of the components provided in step (a) can be carried out in a conventional way. A stirrer or another mixing device is preferably used here in order to achieve good and rapid mixing. The time required for producing the homogeneous mixture should be short in relation to the time during which the gelling reaction leads to at least partial formation of a gel, in order to avoid mixing defects. The other mixing conditions are generally not critical; for example, mixing can be carried out at from 0 to 100 °C and from 0.1 to 10 bar (absolute), in particular at, for example, room temperature and atmospheric pressure. After a homogeneous mixture has been produced, the mixing apparatus is preferably switched off. The gelling reaction is a polyaddition reaction, in particular a polyaddition of isocyanate groups and amino groups.

For the purposes of the present invention, a gel is a crosslinked system based on a polymer which is present in contact with a liquid (known as solvogel or lyogel, or with water as liquid: aquagel or hydrogel). Here, the polymer phase forms a continuous three-dimensional network.

In step (b) of the process of the invention, the gel is usually formed by allowing to rest, e.g. by simply allowing the container, reaction vessel or reactor in which the mixture is present (herein- after referred to as gelling apparatus) to stand. The mixture is preferably no longer stirred or mixed during gelling (gel formation) because this could hinder formation of the gel. It has been found to be advantageous to cover the mixture during gelling or to close the gelling apparatus.

Gelling is known per se to a person skilled in the art and is described, for example, in WO 2009/027310 A1 on page 21 , line 19 to page 23, line 13.

Step (c)

According to the invention, the gel obtained in the previous step is dried in step (c).

Drying under supercritical conditions is in principle possible, preferably after replacement of the solvent by CO2 or other solvents suitable for the purposes of supercritical drying. Such drying is known per se to a person skilled in the art. Supercritical conditions characterize a temperature and a pressure at which CO2 or any solvent used for removal of the gelation solvent is present in the supercritical state. In this way, shrinkage of the gel body on removal of the solvent can be reduced.

However, in view of the simple process conditions, preference is given to drying the gels obtained by conversion of the liquid comprised in the gel into the gaseous state at a temperature and a pressure below the critical temperature and the critical pressure of the liquid comprised in the gel.

The drying of the gel obtained is preferably carried out by converting the solvent (B) into the gaseous state at a temperature and a pressure below the critical temperature and the critical pressure of the solvent (B). Accordingly, drying is preferably carried out by removing the solvent (B) which was present in the reaction without prior replacement by a further solvent.

Such methods are likewise known to those skilled in the art and are described in

WO 2009/027310 A1 on page 26, line 22 to page 28, line 36.

According to a further embodiment, the present invention is directed to the process for preparing a porous material as disclosed above, wherein the drying according to step c) is carried out by converting the liquid comprised in the gel into the gaseous state at a temperature and a pressure below the critical temperature and the critical pressure of the liquid comprised in the gel.

According to a further embodiment, the present invention is directed to the process for prepar- ing a porous material as disclosed above, wherein the drying according to step c) is carried out under supercritical conditions.

Properties of the porous materials and use

The present invention further provides the porous materials which can be obtained by the process of the invention. Xerogels and aerogels are preferred as porous materials for the purposes of the present invention, i.e. the porous material which can be obtained according to the invention is preferably an aerogel or a xerogel.

The porous materials according to the present invention are mechanically stable and have a low thermal conductivity in combination with a reversible uptake and excellent fire properties.

Furthermore, the present invention therefore is directed to a porous material which is obtained or obtainable by the process for preparing a porous material as disclosed above. In particular, the present invention is directed to a porous material which is obtained or obtainable by the process for preparing a porous material as disclosed above, wherein the drying according to step c) is carried out under subcritical conditions. The average pore diameter is determined by scanning electron microscopy and subsequent image analysis using a statistically significant number of pores. Corresponding methods are known to those skilled in the art.

The volume average pore diameter of the porous material can vary in wide ranges and is pref- erably not more than 4 microns.

Although a very small pore size combined with a high porosity is desirable from the point of view of a low thermal conductivity, from the point of view of production and to obtain a sufficiently mechanically stable porous material, there is a practical lower limit to the volume average pore diameter. In general, the volume average pore diameter is at least 20 nm, preferably at least 50 nm.

The porous material which can be obtained according to the invention preferably has a porosity of at least 70 % by volume, in particular from 70 to 99 % by volume, particularly preferably at least 80 % by volume, very particularly preferably at least 85 % by volume, in particular from 85 to 95 % by volume. The porosity in % by volume means that the specified proportion of the total volume of the porous material comprises pores. Although a very high porosity is usually desira- ble from the point of view of a minimal thermal conductivity, an upper limit is imposed on the porosity by the mechanical properties and the processability of the porous material.

The components of composition (A), for example the components (af), (au) and (aO) to (a3) and optionally (am) and (a4), as long as the catalyst can be incorporated, are present in reactive (polymer) form in the porous material which can be obtained according to the invention. Owing to the composition according to the invention, the monomer building blocks (a1 ) and (a2) are predominantly bound via urea linkages and/or via isocyanurate linkages in the porous material, with the isocyanurate groups being formed by trimerization of isocyanate groups of the mono- mer building blocks (a1 ). If the porous material comprises further components, further possible linkages are, for example, urethane groups formed by reaction of isocyanate groups with alcohols or phenols.

The determination of the mol% of the linkages of the monomer building blocks in the porous material is carried out by means of NMR spectroscopy (nuclear magnetic resonance) in the solid or in the swollen state. Suitable methods of determination are known to those skilled in the art.

The density of the porous material which can be obtained according to the invention is usually from 20 to 600 g/l, preferably from 50 to 500 g/l and particularly preferably from 60 to 300 g/l.

The process of the invention gives a coherent porous material and not only a polymer powder or particles. Here, the three-dimensional shape of the resulting porous material is determined by the shape of the gel which is in turn determined by the shape of the gelling apparatus. Thus, for example, a cylindrical gelling vessel usually gives an approximately cylindrical gel which can then be dried to give a porous material having a cylindrical shape.

The porous materials which can be obtained according to the invention have a low thermal conductivity, a high porosity and a low density combined with high mechanical stability. In addition, the porous materials have a small average pore size. It has been surprisingly found that the porous materials obtained have a high reversible water uptake and remain stable after water uptake and drying. The combination of the abovementioned properties allows the materials to be used as insulation material in the field of thermal insulation, in particular for applications in the ventilated state as building materials, in particular for removing humidity and to reduce mold.

The porous materials which can be obtained according to the invention have advantageous thermal properties and also further advantageous properties such as simple processability and high mechanical stability, for example low brittleness. In comparison to materials known from the state of the art, the porous materials according to the present invention have a reduced density and improved compressive strength. The present invention is also directed to the use of porous materials as disclosed above or a porous material obtained or obtainable according to a process as disclosed above as thermal insulation material or for vacuum insulation panels. The thermal insulation material is for example insulation material which is used for insulation in the interior or the exterior of a building. The porous material according to the present invention can advantageously be used in thermal insulation systems such as for example composite materials.

According to a further embodiment, the present invention therefore is directed to the use of porous materials as disclosed above, wherein the porous material is used in interior or exterior thermal insulation systems.

Due to the good adsorption properties, already thin layers of the porous material can be used as adsorption material making the porous material in particular suitable for the use as drying agent for gases, such as air, in filter systems, in adsorption heat pumps, as insulation material in damp and wet rooms, or to avoid mold formation.

According to a further embodiment, the present invention is also directed to the use of porous materials as disclosed above, wherein the porous material is used for the removal of mold.

The present invention includes the following embodiments, wherein these include the specific combinations of embodiments as indicated by the respective interdependencies defined therein.

Process for preparing a porous material, at least comprising the steps of: a) providing a mixture (I) comprising

(i) a composition (A) comprising components suitable to form an organic gel and

(ii) a solvent (B),

b) reacting the components in the composition (A) in the presence of the solvent (B) to form a gel, and

c) drying of the gel obtained in step b), wherein the composition (A) comprises

at least one compound (af) comprising phosphorous and at least one functional group which is reactive towards isocyanates and

at least one component (au) selected from the group consisting of urea, biuret, and derivatives of urea and biuret.

The process according to embodiment 1 , wherein the compound (au) is selected from the group consisting of urea, dimethyl urea, diphenyl urea, ethylene urea, dihydroxy ethylene urea, propylene urea, and biuret.

3. Process for preparing a porous material, at least comprising the steps of: a) providing a mixture (I) comprising

(i) a composition (A) comprising components suitable to form an organic gel and

(ii) a solvent (B),

b) reacting the components in the composition (A) in the presence of the solvent (B) to form a gel, and

c) drying of the gel obtained in step b), wherein the composition (A) comprises

at least one compound (af) comprising phosphorous and at least one functional group which is reactive towards isocyanates and

at least one component (au) selected from the group consisting of urea, dimethyl urea, diphenyl urea, ethylene urea, dihydroxy ethylene urea, propylene urea, and biuret.

The process according to embodiment or 2 or 3, wherein the composition (A) comprises the compound (af) in an amount which results in a phosphorous content in the porous material in a range of from 1 to 20 % by weight.

The process according to any of embodiments 1 to 4, wherein the composition (A) comprises the compound (au) in an amount in the range of from 0.1 to 15% by weight.

Process for preparing a porous material, at least comprising the steps of: a) providing a mixture (I) comprising

(i) a composition (A) comprising components suitable to form an organic gel and

(ii) a solvent (B),

b) reacting the components in the composition (A) in the presence of the solvent (B) to form a gel, and

c) drying of the gel obtained in step b), wherein the composition (A) comprises

at least one compound (af) comprising phosphorous and at least one functional group which is reactive towards isocyanates and

at least one component (au) selected from the group consisting of urea, dimethyl urea, diphenyl urea, ethylene urea, dihydroxy ethylene urea, propylene urea, and biuret, wherein the composition (A) comprises the compound (af) in an amount which results in a phosphorous content in the porous material in a range of from 1 to 20 % by weight.

Process for preparing a porous material, at least comprising the steps of: a) providing a mixture (I) comprising

(i) a composition (A) comprising components suitable to form an organic gel and

(ii) a solvent (B),

b) reacting the components in the composition (A) in the presence of the solvent (B) to form a gel, and

c) drying of the gel obtained in step b), wherein the composition (A) comprises

at least one compound (af) comprising phosphorous and at least one functional group which is reactive towards isocyanates and

at least one component (au) selected from the group consisting of urea, dimethyl urea, diphenyl urea, ethylene urea, dihydroxy ethylene urea, propylene urea, and biuret, wherein the composition (A) comprises the compound (au) in an amount in the range of from 0.1 to 15% by weight.

The process according to any of embodiments 1 to 7, wherein the compound (af) comprises at least one functional group comprising phosphorous.

The process according to embodiment 8, wherein the compound (af) comprises at least one functional group comprising phosphorous selected from the group consisting of phosphates, phosphonates, phosphinates, phosphites, phosphonites, phosphinites, and phos- phine oxides. The process according to any of embodiments 1 to 9, wherein the composition (A) comprises a catalyst system (CS) at least comprising a catalyst component (C1 ) selected from the group consisting of alkali metal and earth alkali metal, ammonium, ionic liquid salts of a saturated or unsaturated monocarboxylic acids. The process according to embodiment 10, wherein the catalyst system (CS) comprises a carboxylic acid as catalyst component (C2). The process according to any of embodiments 1 to 1 1 , wherein the composition (A) comprises at least one monool (am). The process according to any of embodiments 1 to 12, wherein the composition (A) comprises at least one polyfunctional isocyanate as component (a1 ), and at least one aromatic amine as component (a2), optionally comprises water as component (a3), and optionally comprises at least one further catalyst as component (a4). The process according to any of embodiments 1 to 13, wherein the drying according to step c) is carried out by converting the liquid comprised in the gel into the gaseous state at a temperature and a pressure below the critical temperature and the critical pressure of the liquid comprised in the gel.

15. The process according to any of embodiments 1 to 14, wherein the drying according to step c) is carried out under supercritical conditions.

16. A porous material, which is obtained or obtainable by the process according to any of embodiments 1 to 15. 17. A porous material, which is obtained or obtainable by a process for preparing a porous material, at least comprising the steps of: a) providing a mixture (I) comprising

(i) a composition (A) comprising components suitable to form an organic gel and (ii) a solvent (B),

b) reacting the components in the composition (A) in the presence of the solvent (B) to form a gel, and

c) drying of the gel obtained in step b), wherein the composition (A) comprises

at least one compound (af) comprising phosphorous and at least one functional group which is reactive towards isocyanates and

at least one component (au) selected from the group consisting of urea, biuret, and derivatives of urea and biuret.

18. The porous material according to embodiment 17, wherein the compound (au) is selected from the group consisting of urea, dimethyl urea, diphenyl urea, ethylene urea, dihydroxy ethylene urea, propylene urea, and biuret. 19. The porous material according to embodiment 17 or 18, wherein the composition (A) comprises the compound (af) in an amount which results in a phosphorous content in the porous material in a range of from 1 to 20 % by weight.

20. The porous material according to any of embodiments 17 to 19, wherein the composition (A) comprises the compound (au) in an amount in the range of from 0.1 to 15% by weight.

21 . The porous material according to any of embodiments 17 to 20, wherein the compound (af) comprises at least one functional group comprising phosphorous. 22. The porous material according to embodiment 22, wherein the compound (af) comprises at least one functional group comprising phosphorous selected from the group consisting of phosphates, phosphonates, phosphinates, phosphites, phosphonites, phosphinites, and phosphine oxides. The porous material according to any of embodiments 17 to 22, wherein the composition (A) comprises a catalyst system (CS) at least comprising a catalyst component (C1 ) selected from the group consisting of alkali metal and earth alkali metal, ammonium, ionic liquid salts of a saturated or unsaturated monocarboxylic acids.

24. The porous material according to embodiment 23, wherein the catalyst system (CS) comprises a carboxylic acid as catalyst component (C2). 25. The porous material according to any of embodiments 17 to 24, wherein the composition (A) comprises at least one monool (am).

26. The porous material according to any of embodiments 17 to 25, wherein the composition (A) comprises at least one polyfunctional isocyanate as component (a1 ), and at least one aromatic amine as component (a2), optionally comprises water as component (a3), and optionally comprises at least one further catalyst as component (a4).

The porous material according to any of embodiments 17 to 26, wherein the drying according to step c) is carried out by converting the liquid comprised in the gel into the gaseous state at a temperature and a pressure below the critical temperature and the critical pressure of the liquid comprised in the gel.

28. The porous material according to any of embodiments 17 to 27, wherein the drying

cording to step c) is carried out under supercritical conditions.

29. The use of porous materials according to any of embodiment 16 to 28 or a porous material obtained or obtainable by the process according to any of embodiments 1 to 15 as insulation material or as adsorption material. 30. The use according to embodiment 29, wherein the porous material is used in interior or exterior insulation systems.

31 . The use according to embodiment 29, wherein the porous material is used for the remov- al of mold.

Examples will be used below to illustrate the invention.

EXAMPLES

1. Methods Determination of Thermal Conductivity

The thermal conductivity was measured according to DIN EN 12667 with a heat flow meter from Hesto (Lambda Control A50).

Determination of compressive strength and E modulus

The compressive strength and the elastic modulus was measured according to DIN 53421 with 10 % strain.

Determination of the water uptake

The mass of a sample was determined before and after soaking it completely under water for 24 hours. The water uptake was calculated accordingly in relation to the weight of the sample. After drying the sample for 24 hours at room temperature the shrinkage and the surface appearance was investigated.

Materials

Component a1 : oligomeric MDI (Lupranat M200) having an NCO content of 30.9 g per

100 g accordance with ASTM D-5155-96 A, a functionality in the region of three and a viscosity of 2100 mPa.s at 25 °C in accordance with DIN 53018 (hereafter "M200")

Component a2: 3,3',5,5'-Tetraethyl-4,4'diaminodiphenylmethane (hereinafter "MDEA")

Catalyst: Triethanolamine

Urea dissolved in monoethylene glycol (20%)

Flame redardant: Exolit OP560

(Examples

Water uptake values for all examples are shown in Table 1. Furthermore, data regarding the compressive strength and density are included for several examples. Example 1 (comparative) In a polypropylene container, 48 g M200 were dissolved under stirring in 210 g acetone at 20 °C leading to a clear solution. Similarly, 2 g MDEA, 4 g TEOA, 2 g urea solution and 4 g water were dissolved in 210 g acetone to obtain a second solution. The solutions were combined in a rectangular container (20 x 20 cm x 5 cm height) by pouring one solution into the other, which led to a homogeneous mixture of low viscosity. The container was closed with a lid and the mixture was gelled at room temperature for 24 h. The resulting monolithic gel slab was dried for 7 days at ambient conditions leading to a porous material. 3.2 Example 2 (comparative)

In a polypropylene container, 48 g M200 were dissolved under stirring in 210 g acetone at 20 °C leading to a clear solution. Similarly, 2 g MDEA, 4 g TEOA and 4 g water were dissolved in 210 g acetone to obtain a second solution. The solutions were combined in a rectangular container (20 x 20 cm x 5 cm height) by pouring one solution into the other, which led to a homogeneous mixture of low viscosity. The container was closed with a lid and the mixture was gelled at room temperature for 24 h. The resulting monolithic gel slab was dried for 7 days at ambient conditions leading to a porous material. 3.3 Example 3 (comparative)

In a polypropylene container, 48 g M200 were dissolved under stirring in 210 g acetone at 20 °C leading to a clear solution. Similarly, 2 g MDEA, 4 g TEOA, 1 g OP 560 and 4 g water were dissolved in 210 g acetone to obtain a second solution. The solutions were com- bined in a rectangular container (20 x 20 cm x 5 cm height) by pouring one solution into the other, which led to a homogeneous mixture of low viscosity. The container was closed with a lid and the mixture was gelled at room temperature for 24 h. The resulting monolithic gel slab was dried for 7 days at ambient conditions leading to a porous material. 3.4 Example 4

In a polypropylene container, 48 g M200 were dissolved under stirring in 210 g acetone at 20 °C leading to a clear solution. Similarly, 2 g MDEA, 4 g TEOA, 2 g urea solution, 1 g OP560 and 4 g water were dissolved in 210 g acetone to obtain a second solution. The solutions were combined in a rectangular container (20 x 20 cm x 5 cm height) by pouring one solution into the other, which led to a homogeneous mixture of low viscosity. The container was closed with a lid and the mixture was gelled at room temperature for 24 h. The resulting monolithic gel slab was dried for 7 days at ambient conditions leading to a porous material.

3.5 Example 5 In a polypropylene container, 48 g M200 were dissolved under stirring in 210 g acetone at 20 °C leading to a clear solution. Similarly, 2 g MDEA, 4 g TEOA, 2 g urea solution, 2 g OP560 and 4 g water were dissolved in 210 g acetone to obtain a second solution. The solutions were combined in a rectangular container (20 x 20 cm x 5 cm height) by pouring one solution into the other, which led to a homogeneous mixture of low viscosity. The container was closed with a lid and the mixture was gelled at room temperature for 24 h. The resulting monolithic gel slab was dried for 7 days at ambient conditions leading to a porous material. Example 6

In a polypropylene container, 48 g M200 were dissolved under stirring in 210 g acetone at 20 °C leading to a clear solution. Similarly, 2 g MDEA, 4 g TEOA, 4 g urea solution, 2 g OP560 and 4 g water were dissolved in 210 g acetone to obtain a second solution. The solutions were combined in a rectangular container (20 x 20 cm x 5 cm height) by pouring one solution into the other, which led to a homogeneous mixture of low viscosity. The container was closed with a lid and the mixture was gelled at room temperature for 24 h. The resulting monolithic gel slab was dried for 7 days at ambient conditions leading to a porous material. Example 7

In a polypropylene container, 48 g M200 were dissolved under stirring in 210 g acetone at 20 °C leading to a clear solution. Similarly, 2 g MDEA, 4 g TEOA, 2 g urea solution, 8 g OP560 and 4 g water were dissolved in 210 g acetone to obtain a second solution. The solutions were combined in a rectangular container (20 x 20 cm x 5 cm height) by pouring one solution into the other, which led to a homogeneous mixture of low viscosity. The container was closed with a lid and the mixture was gelled at room temperature for 24 h. The resulting monolithic gel slab was dried for 7 days at ambient conditions leading to a porous material.

Results

Table 1. Results.

Density Compressive Water uptake [kg/m ³ ] strength [kPa] [wt%]

E modulus [N/mm ² ]

Example 1 (comparative) 105 251 43

2g MDEA, 2g TEOA, 2g urea solution, 1 ,62

4g water)

Example 2 (comparative) 109 297 3

2g MDEA, 2g TEOA, 4g water 2,92 Example 3 (comparative) 106 295 10

2g MDEA, 2g TEOA, 4g water + 1 g 3,02

OP560

Example 4 1 13 384 140

2g MDEA, 2g TEOA, 2g urea solution, 8,98

4g Wasser + 1 g OP560

Example 5 1 15 383 322

2g MDEA, 2g TEOA, 2g urea solution, 9,75

4g Wasser + 2g OP560

Example 6 1 19 377 590

2g MDEA, 2g TEOA, 2g urea solution, 9,55

4g Wasser + 4g OP560

Example 7 125 379 728

2g MDEA, 2g TEOA, 2g urea solution, 8,19

4g Wasser + 8g OP560

Abbreviations

H ₂ 0 Water

TEOA Triethanolamine (PUR catalyst)

Urea solution urea dissolved in monoethylene glycol

M200 Lupranate M200 (polyisocyanate)

MEK Methyl ethyl ketone

MDEA 4,4'-Methylene-bis(2,6-diethylaniline)

Literature cited

WO 95/02009 A1

WO 2008/138978 A1

WO 201 1/069959 A1

WO 2012/000917 A1

WO 2012/059388 A1

PCT/EP2017/05094

Polyurethane, 3 ^rd edition, G. Oertel, Hanser Verlag, Munich, 1993

WO 00/24799 A1

Plastics Additive Handbook, 5th edition, H. Zweifel, ed. Hanser Publishers, Munich, 2001 WO 2009/027310 A1