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Title:
POSITIVE ELECTRODE ACTIVE MATERIAL FOR LITHIUM SECONDARY BATTERY
Document Type and Number:
WIPO Patent Application WO/2017/150522
Kind Code:
A1
Abstract:
Provided is a positive electrode active material for a lithium secondary battery, said material including active particles that are represented by the general formula Li1±xCoyM1-x-yO2 (In the formula, 0.95 ≤ 1±x ≤ 1.05, y ≥ 0.8, 1-x-y > 0, and M is any one or a combination of two or more elements from the group consisting of Mn, Ni, Na, Mg, Al, Si, P, K, Ca, Ti, V, Cr, Fe, Cu, Zn, Ga, Y, Zr, Nb, Mo, In, Ta, W, Re, and Ce), have a layered crystal structure, and are provided, on the surface thereof, with a surface part in which any one or a combination of two or more elements (referred to as "surface element A") from the group consisting of Al, Ti, and Zr is present, and being characterized in that the ratio (A/(Co+M)) of the atomic ratio of surface element A to the total of the atomic ratios of Co and M as measured by XPS is 0.07-0.8, the amount of surface lithium impurities is less than 0.15 wt%, and the peak integrated intensity ratio (003)/(104) as measured by XRD is 1.15-3.00.

Inventors:
MITSUMOTO TETSUYA (JP)
WASHIDA DAISUKE (JP)
MATSUSHIMA HIDEAKI (JP)
Application Number:
PCT/JP2017/007756
Publication Date:
September 08, 2017
Filing Date:
February 28, 2017
Export Citation:
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Assignee:
MITSUI MINING & SMELTING CO (JP)
International Classes:
H01M4/525; C01G51/00; H01M4/36; H01M4/505
Domestic Patent References:
WO2002054511A12002-07-11
WO2014136760A12014-09-12
Foreign References:
JP2001319652A2001-11-16
JP2003217659A2003-07-31
JP2003203634A2003-07-18
JP2005149957A2005-06-09
JP2004207034A2004-07-22
JP2015536558A2015-12-21
JP2015076397A2015-04-20
JP2014049309A2014-03-17
Attorney, Agent or Firm:
TAKEUCHI, ICHIZAWA & ASSOCIATES (JP)
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