Title:
PREPARATION METHOD FOR S-INDOXACARB
Document Type and Number:
WIPO Patent Application WO/2019/233209
Kind Code:
A1
Abstract:
A catalyst and a method for preparing S-indoxacarb using the catalyst. The catalyst is prepared using 3-tert-butyl-5-chloromethyl salicylaldehyde and cyclohexanediamine as raw materials, where an original quinine catalyst such as cinchonine is replaced with the catalyst for application in the asymmetric synthesis of tert-butyl hydroperoxide and 5-chloro-2-methoxycarbonyl-1-indanone ester, greatly improving selection in the asymmetric synthesis process, with the S-enantiomer content increasing from 75% to over 98%, achieving the recycling of a high-efficiency chiral catalyst, and greatly reducing production costs. The synthesis process of the catalyst is simple and is favorable for industrialization, and lays good foundations for the production of high-quality indoxacarb.
More Like This:
Inventors:
BO LEIFANG (CN)
CHENG DAOQUAN (CN)
LIU JIANCHENG (CN)
FENG PEILIANG (CN)
LIU HUAMIN (CN)
WANG ZHONGYANG (CN)
CHENG DAOQUAN (CN)
LIU JIANCHENG (CN)
FENG PEILIANG (CN)
LIU HUAMIN (CN)
WANG ZHONGYANG (CN)
Application Number:
PCT/CN2019/084224
Publication Date:
December 12, 2019
Filing Date:
April 25, 2019
Export Citation:
Assignee:
JINGBO AGROCHEMICALS TECH CO LTD (CN)
International Classes:
B01J31/22; C07B53/00; C07D237/04; C08G12/40
Foreign References:
CN101062903A | 2007-10-31 | |||
CN1630555A | 2005-06-22 | |||
CN106397351A | 2017-02-15 |
Other References:
See also references of EP 3804853A4
Attorney, Agent or Firm:
JINAN SHUNYUAN PATENT AGENCY CO., LTD. (CN)
Download PDF: