Title:
PROCESS FOR THE PREPARATION OF A VINYLIDENE CHLORIDE POLYMER COMPOSITE
Document Type and Number:
WIPO Patent Application WO/2013/092588
Kind Code:
A1
Abstract:
Process for the preparation of a vinylidene chloride polymer composite comprising a solid particulate encapsulated in the vinylidene chloride polymer. The process comprises providing a dispersion of a solid particulate material in a liquid phase, said dispersion comprising a RAFT/MADIX agent; providing vinylidene chloride and optionally one or more ethylenically unsaturated monomer copolymerisable therewith to said dispersion; and polymerising vinylidene chloride and said optionally present one or more ethylenically unsaturated monomer under the control of said RAFT/MADIX agent to form polymer at the surface of said solid particulate material.
Inventors:
VINAS JEROME (BE)
DUFILS PIERRE-EMMANUEL (FR)
GARNIER JEROME (FR)
LACROIX-DESMAZES PATRICK (FR)
VAN HERK ALEX (NL)
WARNANT JEROME (FR)
VANDERVEKEN YVES (BE)
DUFILS PIERRE-EMMANUEL (FR)
GARNIER JEROME (FR)
LACROIX-DESMAZES PATRICK (FR)
VAN HERK ALEX (NL)
WARNANT JEROME (FR)
VANDERVEKEN YVES (BE)
Application Number:
PCT/EP2012/075951
Publication Date:
June 27, 2013
Filing Date:
December 18, 2012
Export Citation:
Assignee:
SOLVAY (BE)
CENTRE NAT RECH SCIENT (FR)
ECOLE NALE SUP ARTES METIERS (FR)
UNIV MONTPELLIER 2 (FR)
CENTRE NAT RECH SCIENT (FR)
ECOLE NALE SUP ARTES METIERS (FR)
UNIV MONTPELLIER 2 (FR)
International Classes:
C08F114/08; C08F214/08; C08L27/08
Domestic Patent References:
| WO2005028557A1 | 2005-03-31 | |||
| WO2009130233A1 | 2009-10-29 | |||
| WO1998058974A1 | 1998-12-30 | |||
| WO1998001478A1 | 1998-01-15 | |||
| WO2006037161A1 | 2006-04-13 | |||
| WO2002090397A1 | 2002-11-14 |
Foreign References:
| US7230063B1 | 2007-06-12 | |||
| EP1801158A1 | 2007-06-27 |
Other References:
M.BEIJA,J.D. MARTY, M. DESTARAC: "RAFT/MADIX polymers for the preparation of polymer inorganic nanohybrids", PROGRESS IN POLYMER SCIENCE, vol. 36, 22 January 2011 (2011-01-22) - 22 January 2011 (2011-01-22), pages 845 - 886, XP002670059
SEVERAC R ET AL: "VINYLIDENE CHLORIDE COPOLYMERIZATION WITH METHYL ACRYLATE BY REVERSIBLE ADDITION-FRAGMENTATION CHAIN TRANSFER (RAFT) PROCESS", RAPRA ABSTRACTS, RAPRA TECHNOLOGY LTD., SHREWSBURY, GB, vol. 40, no. 9, 1 September 2003 (2003-09-01), pages 39, XP001178507, ISSN: 0033-6750
ULLMANN: "Encyclopedia of Industrial Chemistry. Poly(vinylidene chloride", 2005, WILEY VCH-VERLAG
PERRIER, S. ET AL.: "Macromolecular design via Reversible Addition-Fragmentation Chain Transfer (RAFT)/Xanthates (MADIX) polymerization", J. PO/YM. SCI.: PART A: POLYM. CHEM., vol. 43, 2005, pages 5347 - 5393, XP055032600, DOI: doi:10.1002/pola.20986
BEIJA, J. D. ET AL.: "RAFT/MADIX polymers for the preparation of polymer inorganic nanohybrids", PROGRESS IN POLYMER SCIENCE, vol. 36, 2011, pages 845 - 886, XP002670059, DOI: doi:10.1016/J.PROGPOLYMSCI.2011.01.002
FAVIER, A. ET AL.: "Experimental requirements for an efficient control of free-radical polymerizations via the Reversible-Addition Fragmentation chain Transfer (RAFT) process", MACROMOL. RAPID COMMUN., vol. 27, 2006, pages 653 - 692, XP055141044, DOI: doi:10.1002/marc.200500839
ALI ET AL., LANGMUIR, vol. 25, no. 18, 2009, pages 10523
RIBAUT, T. ET AL., J. POLYM. SCI., PARTA: POLYM. CHEM., vol. 47, 2009, pages 5448
S. MORI ET AL.: "Size Exclusion Chromatography", 1999, SPRINGER VERLAG
A. REVILLON ET AL., J. PO/YM. SCI., PARTA: POLYM. CHEM., vol. 14, 1976, pages 2263
SEVERAC R ET AL: "VINYLIDENE CHLORIDE COPOLYMERIZATION WITH METHYL ACRYLATE BY REVERSIBLE ADDITION-FRAGMENTATION CHAIN TRANSFER (RAFT) PROCESS", RAPRA ABSTRACTS, RAPRA TECHNOLOGY LTD., SHREWSBURY, GB, vol. 40, no. 9, 1 September 2003 (2003-09-01), pages 39, XP001178507, ISSN: 0033-6750
ULLMANN: "Encyclopedia of Industrial Chemistry. Poly(vinylidene chloride", 2005, WILEY VCH-VERLAG
PERRIER, S. ET AL.: "Macromolecular design via Reversible Addition-Fragmentation Chain Transfer (RAFT)/Xanthates (MADIX) polymerization", J. PO/YM. SCI.: PART A: POLYM. CHEM., vol. 43, 2005, pages 5347 - 5393, XP055032600, DOI: doi:10.1002/pola.20986
BEIJA, J. D. ET AL.: "RAFT/MADIX polymers for the preparation of polymer inorganic nanohybrids", PROGRESS IN POLYMER SCIENCE, vol. 36, 2011, pages 845 - 886, XP002670059, DOI: doi:10.1016/J.PROGPOLYMSCI.2011.01.002
FAVIER, A. ET AL.: "Experimental requirements for an efficient control of free-radical polymerizations via the Reversible-Addition Fragmentation chain Transfer (RAFT) process", MACROMOL. RAPID COMMUN., vol. 27, 2006, pages 653 - 692, XP055141044, DOI: doi:10.1002/marc.200500839
ALI ET AL., LANGMUIR, vol. 25, no. 18, 2009, pages 10523
RIBAUT, T. ET AL., J. POLYM. SCI., PARTA: POLYM. CHEM., vol. 47, 2009, pages 5448
S. MORI ET AL.: "Size Exclusion Chromatography", 1999, SPRINGER VERLAG
A. REVILLON ET AL., J. PO/YM. SCI., PARTA: POLYM. CHEM., vol. 14, 1976, pages 2263
Attorney, Agent or Firm:
BENVENUTI, Federica et al. (310, Bruxelles, BE)
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