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Title:
PROCESS FOR PRODUCING LIQUEFIED PETROLEUM GAS
Document Type and Number:
WIPO Patent Application WO/2006/030828
Kind Code:
A1
Abstract:
An olefin-containing gas comprising propylene and/or butene as a major ingredient and containing ethylene and pentene is produced from at least one of methanol and dimethyl ether. The olefin-containing gas obtained and the gas obtained in the subsequent step of olefin conversion reaction are separated into a propylene/butene-containing fraction, an ethylene-containing fraction, and a pentene-containing fraction. The ethylene-containing fraction and pentene-containing fraction obtained are subjected to an olefin conversion reaction to yield a gas comprising propylene and/or butene as a major ingredient, and this gas is fed to a separation step. On the other hand, a liquefied petroleum gas is produced from the propylene/butene-containing fraction and hydrogen.

Inventors:
ASAOKA SACHIO (JP)
JIN YINGJIE (JP)
LI XIAOHONG (JP)
ASAMI KENJI (JP)
FUJIMOTO KAORU (JP)
Application Number:
PCT/JP2005/016945
Publication Date:
March 23, 2006
Filing Date:
September 14, 2005
Export Citation:
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Assignee:
JAPAN GAS SYNTHESIZE LTD (JP)
ASAOKA SACHIO (JP)
JIN YINGJIE (JP)
LI XIAOHONG (JP)
ASAMI KENJI (JP)
FUJIMOTO KAORU (JP)
International Classes:
C10L3/12; B01J29/10; B01J29/20; B01J29/40; B01J29/72; B01J29/88; C07C1/02; C07C9/08; C07C9/10
Domestic Patent References:
WO2004074410A12004-09-02
WO2004074411A12004-09-02
WO2004076600A12004-09-10
WO2005037962A12005-04-28
Other References:
KANEKO HIROSHI.: "LP Gas Gosei Gijutsu no Kaihatsu (Jo)-Mokuteki to Genri.", JOURNAL OF THE HIGH PRESSURE GAS SAFETY INSTITUTE OF JAPAN., vol. 39, no. 7, 1 July 2002 (2002-07-01), pages 25 - 30, XP002982540
KANEKO TETSUYA ET AL: "Tennen Gas Kara no Methanol/DME Keiyu deno LPG Gosei (1), Genryo to Shokubai no Saiteki na Kumiawase. (LPG Synthesis via Methanol/DME from Natural Gas)", DAI 33 KAI SEKIYU SEKIYU KAGAKU TORONKAI KOEN YOSHI., 14 November 2003 (2003-11-14), pages 175 - 176, XP002982543
JIN YINGJIE ET AL: "LPG Synthesis via Methanol/DME from Natural Gas (2) How to Control the Process Product.", DAI 33 KAI SEKIYU SEKIYU KAGAKU TORONKAI KOEN YOSHISHU., 17 November 2003 (2003-11-17), pages 177 - 178, XP002982544
ZHANG QIANWEN ET AL: "The Role of Zeolite in Direct Synthesis of LPG from Synthesis Gas.", DAI 29 KAI SHOKUBAI TORONKAI TORONKAI A YOKOSHU., 18 September 2003 (2003-09-18), pages 321, 4G22, XP002982546
JIN YINGJIE ET AL: "Methanol/Dimethyl Ether Conversion on Zeolite Catalysts for INdirect Synthesis of LPG from Natural Gas.", DAI 29 KAI SHOKUBAI TORONKAI TORONKAI A YOKOSHU., 18 September 2003 (2003-09-18), pages 322, 4G23, XP002982547
ZHANG QIANWEN ET AL: "Synthesis of LPG fromSynthesis Gas with Hybrid Catalyst.", DAI 33 KAI SEKIYU SEKIYU KAGAKU TORONKAI KOEN YOSHISHU., 17 November 2003 (2003-11-17), pages 179 - 180, XP002982545
ZHANG QIANWEN ET AL: "Synthesis of LPG from syngas with hybrid catalyst Based on Supported Palladium and Zeolite.", THE JAPAN PETROLEUM INSTITUTE DAI 47 KAI NENKAI (JYUSHO KOEN DAI 53 KAI KENKYU HAPPYOKAI)., 19 May 2004 (2004-05-19), pages 96 - 97, XP002996888
ASAMI KENJI ET AL: "Selective synthesis of LPG from DME.", THE JAPAN PETROLEUM INSTITUTE DAI 47 KAI NENKAI (JYUSHO KOEN DAI 53 KAI KENKYU HAPPYOKAI)., 19 May 2004 (2004-05-19), pages 98 - 99, XP002993040
FUJIMOTO KAORU ET AL: "Selective Synthesis of LPG from Synthesis Gas.", BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN., vol. 58, no. 10, 15 October 1985 (1985-10-15), pages 3059 - 3060, XP002982542
JIN YINGJIE ET AL: "Synthesis of Liquefied Petroleum Gas Via Methanol/Dimethyl Ether from Natural Gas (PART I) Catalysts ad Reaction Behaviors Associated with Methanol and/or Demethyl Ether Conversion.", JOURNAL OF THE JAPAN PETROLEUM INSTITUTE., vol. 47, no. 6, 1 November 2004 (2004-11-01), pages 394 - 402, XP002996889
JIN YINGJIE ET AL: "Synthesis of Liquefied Petroleum Gas Via Methanol/Dimethyl Ether from Natural Gas (Part 2) Improvements in Catalysts for Methanol and Dimethyl Ether Coversion.", JOURNAL OF THE JAPAN PETROLEUM INSTITUTE., vol. 48, no. 1, 1 January 2005 (2005-01-01), pages 45 - 52, XP002996890
JIN YINGJIE ET AL: "Synthesis of Liquefied Petroleum Gas Via Methanol/Dimethyl Ether from Natural Gas(Part 3) Investigation of Reaction Variables, Ethene Recycling and Catalysts Regeneration at High Conversion from Methanol and/or Dimethyl Ether to LPG.", JOURNAL OF THE JAPAN PETROLEUM INSTITUTE., vol. 48, no. 2, 1 March 2005 (2005-03-01), pages 97 - 105, XP002996891
Attorney, Agent or Firm:
Ito, Katsuhiro (3-11-8 Hacchobori,, Chuou-k, Tokyo32, JP)
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