The invention relates to a process for production of alco ^¬ hols from alcohol synthesis gas. In particular the inven- tion concerns purification of alcohols by conversion of ke ^¬ tones, aldehydes and esters present in the alcohols in presence of one or more catalysts being active in the con ^¬ version of ketones, esters, aldehydes and hydrogen to alco ^¬ hols.

During alcohol synthesis from hydrogen and carbon oxides comprising synthesis gas, by-products such as water, alde ^¬ hydes, esters and ketones are formed frequently. Species like acetone and methyl ethyl ketone with a boiling point close to that of the prepared alcohol are difficult to re ^¬ move and consequently the presence of these species will contribute to the demand for a larger and more costly dis ^¬ tillation column for the purification of the alcohol product .

It is thus a general object of the invention to provide a process for the production of an alcohol product by cata ^¬ lytic conversion of ¾, CO and CO ₂ , wherein the produced alcohol product has a substantially reduced content of oxo- compounds including aldehyde and ketone impurities.

Thus, the present invention provides a process for produc ^¬ tion of alcohol product, comprising the steps of (a) providing an alcohol synthesis gas comprising hydrogen and carbon monoxide; (b) converting the alcohol synthesis gas into a crude al ^¬ cohol product stream comprising one or more alcohols and unconverted alcohol synthesis gas in presence of one or more catalysts active in converting the alcohol synthesis gas into the one or more alcohols;

(c) cooling and separating the crude alcohol product with ^¬ drawn from step (b) into a gas phase comprising hydrogen, carbon monoxide and carbon dioxide and into a liquid prod- uct comprising the one or more alcohols and by-products comprising ketones, esters and aldehydes formed in the con ^¬ version of the alcohol synthesis gas;

(d) purging a part of the gas phase obtained in step (c) and recycling the remaining gas phase to step (a) ;

(e) prior to introduction of the remaining gas phase into step (a) mixing the recycled remaining gas phase product with fresh synthesis gas to form the alcohol synthesis gas; and

(f) subsequent to the cooling and separation in step (c) withdrawing the liquid phase and subjecting the liquid phase to a two phase catalytic hydrogenation of the ke- tones, esters and aldehydes by-products to corresponding alcohols , wherein the liquid phase is hydrogenated with the part of the gas phase being purged from step (d) . Catalysts for use in the alcohol synthesis and hydrogena ^¬ tion ketones, esters and aldehydes are known per se in the art . On a Cu-based catalyst, alcohol is produced from synthesis gas via the following reactions n CO + 2n H ₂ = CnH _2n+ iOH + (n-1) H ₂ 0 (1) .

The oxo -compound by-products such as acetone and methyl- ethyl ketone etc are formed in small quantities during al ^¬ cohol synthesis.

Hydrogenation of these by-products is possible on copper, nickel and/or noble metal based catalysts and follows e.g the reactions:

Methyl formate: C ₂ H ₄ 0 ₂ + 2H ₂ = 2CH ₃ OH

Acetone: C ₃ H ₆ 0 + H ₂ = C ₃ H ₈ 0

Methyl ethyl ketone: C ₄ H ₈ 0 + H ₂ = C ₃ H ₈ 0

Particular suitable catalysts for the hydrogenation contain noble metal including Pt and Pd. Base metal catalysts like a 10 wt% Ni-Cu catalyst have been mentioned in the art. E.g. US-patent No. 5,243,095 discloses a Cu, Fe, Mn, Al based catalyst for ketone hydrogenation and US Patent No. 3,925,490 claims a Cu, Cr catalyst.

In general, the Cu content in the Cu-containing hydrogena- tion catalysts is in the range of 10-95% by weight, pref ^¬ erably 40-70% by weight. The catalyst can be in form of pellets, extrudates or pow ^¬ der . Fig.l of the drawings shows a simplified flow sheet of a process according to an embodiment of the invention.

Referring to Fig. 1, alcohol synthesis gas is formed by mixing fresh synthesis gas 1 comprising carbon monoxide and hydrogen with recycle gas 2. Thus the formed synthesis gas 3 is introduced into alcohol synthesis reactor system 4.

The crude alcohol product from 5 from the alcohol synthesis reactor system 4 contains methanol, unconverted alcohol synthesis gas and traces of ketones, esters and aldehydes.

The crude alcohol product 5 is cooled (not shown) . The cooled product is then separated in the separator into a vapour and liquid phase, 7 and 8 respectively. A part of the gas phase is purged through line 9 to reduce the amount of inerts accumulating in the synthesis loop (eg. Ar, N2 and CH4) . The remainder of the gas forms recycle gas stream 2.

The liquid stream 8 is passed into two phase hydrogenation reactor 10. Ketones, aldehydes and esters contained in the liquid phase 8, are hydrogenated with purge gas 9 into al ^¬ cohol in presence of a hydrogenation catalyst.