Title:
PRODUCTION DEVICE FOR HYDROCARBONS AND PRODUCTION METHOD FOR HYDROCARBONS
Document Type and Number:
WIPO Patent Application WO/2020/116476
Kind Code:
A1
Abstract:
The present invention provides a production device and production method capable of producing hydrocarbons including aromatic hydrocarbons and lower olefins including propylene from CH4 and CO2 through CO and H2 with high activity and high selectivity. This production device is provided with: a synthetic gas generation unit to which a gas containing CH4 and CO2 is supplied from a first supply unit, and which generates a synthetic gas containing CO and H2 while heating a first catalyst structure; a generation unit to which the synthetic gas is supplied and which generates hydrocarbons including aromatic hydrocarbons having 6-10 carbon atoms and lower olefins including propylene while heating a second catalyst structure; and a detection unit which detects propylene and aromatic hydrocarbons discharged from the generation unit, wherein the first catalyst structure comprises a first carrier having a porous structure and first metal fine particles in the first carrier, the first carrier has a first passage, the first metal fine particles are present in the first passage, the second catalyst structure comprises a second carrier having a porous structure and second metal fine particles in the second carrier, the second carrier has a second passage, and a portion of the second passage has an average inner diameter of 0.95 nm or less.
Inventors:
BANBA YUICHIRO (JP)
SEKINE KAORI (JP)
NAKAI YUKAKO (JP)
NISHII MAI (JP)
FUKUSHIMA MASAYUKI (JP)
KATO SADAHIRO (JP)
SEKINE KAORI (JP)
NAKAI YUKAKO (JP)
NISHII MAI (JP)
FUKUSHIMA MASAYUKI (JP)
KATO SADAHIRO (JP)
Application Number:
PCT/JP2019/047299
Publication Date:
June 11, 2020
Filing Date:
December 03, 2019
Export Citation:
Assignee:
FURUKAWA ELECTRIC CO LTD (JP)
International Classes:
C07C1/04; C07C11/02; C07C11/06; C07C15/02; C10G2/00; B01J29/072; B01J35/04; C01B3/40; C07B61/00
Domestic Patent References:
| WO2018221700A1 | 2018-12-06 | |||
| WO2018221697A1 | 2018-12-06 | |||
| WO2020027321A1 | 2020-02-06 | |||
| WO2015072573A1 | 2015-05-21 | |||
| WO2014142282A1 | 2014-09-18 |
Foreign References:
| JPS59132940A | 1984-07-31 | |||
| JP2014534902A | 2014-12-25 | |||
| JP2005015423A | 2005-01-20 | |||
| JP2013255911A | 2013-12-26 | |||
| JP2016002527A | 2016-01-12 | |||
| JPH04227847A | 1992-08-17 | |||
| JPS59102440A | 1984-06-13 |
Other References:
CARVALHO, ALEXANDRE ET AL.: "Design of nanocomposites with cobalt encapsulated in the zealite micropores for selective synthesis of isoparaffins in Fischer-Tropsch reaction", CATALYSIS SCIENCE & TECHNOLOGY, vol. 7, no. 21, 2017, pages 5019 - 5027, XP055682801, ISSN: 2044-4753, DOI: 10.1039/C7CY01945A
LAPRUNE, DAVID ET AL.: "Highly Ilispersed Nickel Particles Encapsulated in Multi-hollow Silicalite- 1 Single Crystal Nanoboxes: Effects of Silicous Deposits and Phosphorous Species on the Catalytic Performances", CHEMCATCHEM, vol. 9, no. 12, 2017, pages 2297 - 2307, XP055391961, ISSN: 1867-3880, DOI: 10.1002/cctc.201700233
See also references of EP 3892603A4
LAPRUNE, DAVID ET AL.: "Highly Ilispersed Nickel Particles Encapsulated in Multi-hollow Silicalite- 1 Single Crystal Nanoboxes: Effects of Silicous Deposits and Phosphorous Species on the Catalytic Performances", CHEMCATCHEM, vol. 9, no. 12, 2017, pages 2297 - 2307, XP055391961, ISSN: 1867-3880, DOI: 10.1002/cctc.201700233
See also references of EP 3892603A4
Attorney, Agent or Firm:
SAITO Takuya et al. (JP)
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