Title:
PRODUCTION METHOD FOR HALOGENATED PYRAZOLECARBOXYLIC ACID
Document Type and Number:
WIPO Patent Application WO/2018/180944
Kind Code:
A1
Abstract:
The present invention provides an industrially excellent production method by which a halogenated pyrazolecarboxylic acid useful as an intermediate for medicines and agricultural chemicals can be more easily and efficiently produced.
The present invention relates to a method for producing a compound represented by formula (b), the method comprising reacting a compound represented by formula (a) with oxygen in the presence of a compound containing a transition metal atom to thereby obtain the compound represented by formula (b).
(The symbols in the formulae are as described in the description.)
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Inventors:
SHIMIZU SHOTA (JP)
SAWAGUCHI MASANORI (JP)
SAWAGUCHI MASANORI (JP)
Application Number:
PCT/JP2018/011583
Publication Date:
October 04, 2018
Filing Date:
March 23, 2018
Export Citation:
Assignee:
AGC INC (JP)
International Classes:
C07D231/14
Domestic Patent References:
| WO2016152886A1 | 2016-09-29 | |||
| WO2001058845A1 | 2001-08-16 | |||
| WO2013036911A1 | 2013-03-14 | |||
| WO2016152886A1 | 2016-09-29 |
Foreign References:
| JPH04217639A | 1992-08-07 | |||
| JPH03236344A | 1991-10-22 | |||
| JP2015160831A | 2015-09-07 | |||
| JP2017061336A | 2017-03-30 |
Other References:
XU, W. ET AL.: "Highly Linear Selective Cobalt- Catalyzed Addition of Aryl Imines to Styrenes: Reversing Intrinsic Regioselectivity by Ligand Elaboration", ANGEWANDTE CHEMIE, vol. 53, no. 51, 2014, pages 14166 - 14170, XP055558450, ISSN: 1433-7851
XU, B. ET AL.: "C-Aryl glucosides substituted at the 4'-position as potent and selective renal sodium-dependent glucose co-transporter 2 (SGLT2) inhibitors for the treatment of type 2 diabetes", BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, vol. 21, no. 15, 2011, pages 4465 - 4470, XP028237575, ISSN: 0960-894X
XU, W. ET AL.: "Ortho-C-H Benzy lat ion of Aryl Imines with Benzyl Phosphates under Cobalt-Pyphos Catalysis", ORGANIC LETTERS, vol. 17, no. 17, 2015, pages 4192 - 4195, XP055558453, ISSN: 1523-7052
NAKAMURA, R. ET AL.: "Selective Oxidation of Acetophenones Bearing Various Functional Groups to Benzoic Acid Derivatives with Molecular Oxygen", ADVANCED SYNTHESIS & CATALYSIS, vol. 351, no. 10, July 2009 (2009-07-01), pages 1677 - 1684, XP055495946, ISSN: 1615-4169
LIU, H. ET AL.: "New protocol of copper-catalyzed oxidative C (CO)-C bond cleavage of aryl and aliphatic ketones to organic acids using 02 as the terminal oxidant", JOURNAL OF CATALYSIS, vol. 346, 17 January 2017 (2017-01-17), pages 170 - 179, XP029898796, ISSN: 0021-9517
BJORSVIK, H. ET AL.: "Carboxylic acids from methyl aryl ketones by means of a new composite aerobic oxidation process", TETRAHEDRON LETTERS, vol. 43, no. 28, 2002, pages 4985 - 4987, XP004366672, ISSN: 0040-4039
BIOORGANIC & MEDICINAL CHEMISTRY, vol. 24, 2016, pages 317 - 341
CHEM. REV., vol. 114, 2014, pages 7079
See also references of EP 3604283A4
XU, B. ET AL.: "C-Aryl glucosides substituted at the 4'-position as potent and selective renal sodium-dependent glucose co-transporter 2 (SGLT2) inhibitors for the treatment of type 2 diabetes", BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, vol. 21, no. 15, 2011, pages 4465 - 4470, XP028237575, ISSN: 0960-894X
XU, W. ET AL.: "Ortho-C-H Benzy lat ion of Aryl Imines with Benzyl Phosphates under Cobalt-Pyphos Catalysis", ORGANIC LETTERS, vol. 17, no. 17, 2015, pages 4192 - 4195, XP055558453, ISSN: 1523-7052
NAKAMURA, R. ET AL.: "Selective Oxidation of Acetophenones Bearing Various Functional Groups to Benzoic Acid Derivatives with Molecular Oxygen", ADVANCED SYNTHESIS & CATALYSIS, vol. 351, no. 10, July 2009 (2009-07-01), pages 1677 - 1684, XP055495946, ISSN: 1615-4169
LIU, H. ET AL.: "New protocol of copper-catalyzed oxidative C (CO)-C bond cleavage of aryl and aliphatic ketones to organic acids using 02 as the terminal oxidant", JOURNAL OF CATALYSIS, vol. 346, 17 January 2017 (2017-01-17), pages 170 - 179, XP029898796, ISSN: 0021-9517
BJORSVIK, H. ET AL.: "Carboxylic acids from methyl aryl ketones by means of a new composite aerobic oxidation process", TETRAHEDRON LETTERS, vol. 43, no. 28, 2002, pages 4985 - 4987, XP004366672, ISSN: 0040-4039
BIOORGANIC & MEDICINAL CHEMISTRY, vol. 24, 2016, pages 317 - 341
CHEM. REV., vol. 114, 2014, pages 7079
See also references of EP 3604283A4
Attorney, Agent or Firm:
TAKASHIMA, Hajime et al. (JP)
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