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Title:
PROPYLENE POLYMERIZATION METHOD AND DEVICE
Document Type and Number:
WIPO Patent Application WO/2021/129432
Kind Code:
A1
Abstract:
Provided is a propylene polymerization method, comprising the following steps: 1) performing a pre-polymerization reaction: mixing and stirring a catalyst and liquid-phase propylene cooled to 5-10°C in a pre-polymerization reaction zone, and performing the pre-polymerization reaction, wherein the pre-polymerization reaction time is 12-17 min, and the pressure is 3.5-4.0 MPag; 2) performing a liquid-phase polymerization reaction: feeding a reaction material from the pre-polymerization reaction zone and newly supplemented monomers such as liquid-phase propylene, hydrogen, ethylene and butene into a liquid-phase polymerization reaction zone, and performing the liquid-phase polymerization reaction; and 3) performing a gas-phase polymerization reaction: feeding mixture material from the liquid-phase polymerization reaction zone to a gas-phase polymerization reaction zone, and performing the gas-phase polymerization reaction. A loop reactor is used as a liquid phase polymerization mode, and a horizontal stirring reactor is used as a gas phase polymerization mode. By means of the series operation of the two reactors, the production process is simplified, and homopolymerized polypropylene or random copolymerized polypropylene can be produced.

Inventors:
ZHENG BILEI (CN)
GAO JUN (CN)
YANG WEIDONG (CN)
FAN CHANGHAI (CN)
CHEN XIUPING (CN)
HONG RI (CN)
ZHOU YI (CN)
Application Number:
PCT/CN2020/135910
Publication Date:
July 01, 2021
Filing Date:
December 11, 2020
Export Citation:
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Assignee:
ZHEJIANG SATELLITE ENERGY CO LTD (CN)
International Classes:
C08F10/06; C08F2/01; C08F110/06; C08F210/02; C08F210/04; C08F210/06; C08F210/08; C08F210/16
Foreign References:
CN108794669A2018-11-13
CN108976329A2018-12-11
CN108586644A2018-09-28
CN108794669A2018-11-13
CN108976329A2018-12-11
CN108586644A2018-09-28
CN102020733A2011-04-20
CN102816269A2012-12-12
CN111116785A2020-05-08
EP2316863A12011-05-04
Attorney, Agent or Firm:
HANGZHOU WUZHOU PUHUA PATENT AGENCY FIRM (SPECIAL GENERAL PARTNERSHIP) (CN)
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