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Title:
PYROLYTIC WASTE TREATMENT SYSTEM
Document Type and Number:
WIPO Patent Application WO/1996/009357
Kind Code:
A1
Abstract:
A treatment unit for gasifying selected constituents of a composition of a starting material, the unit comprising: containment means for containing the starting material while gasification is taking place, said means having a cross-sectional geometry such that it can be bisected into two substantially symmetrical halves; means for introducing the starting material into one of said halves of said containment means; means for supplying energy to the interior of said containment means to initiate and sustain gasification of the selected constituents of the starting material; means for removing from said containment means any residual constituents of the starting material that are not gasified during treatment; and means for removing the gases resulting from gasification from said containment means.

Inventors:
HANSEN ANDREW H (US)
WALKER WILLIAM C (US)
Application Number:
PCT/US1995/011949
Publication Date:
March 28, 1996
Filing Date:
September 19, 1995
Export Citation:
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Assignee:
BALBOA PACIFIC CORP (US)
HANSEN ANDREW H (US)
WALKER WILLIAM C (US)
International Classes:
C10B7/10; C10B53/00; (IPC1-7): C10B53/00; C10B7/10
Domestic Patent References:
WO1992018214A21992-10-29
Foreign References:
US4439209A1984-03-27
DE3305161A11984-08-16
US4235676A1980-11-25
US5224432A1993-07-06
GB228749A1925-02-12
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Claims:
WHAT IS CLAIMED IS:
1. A treatment unit for gassifying seleαed constituents of a composition of a starting material, the unit comprising: containment means for containing the starting material while gassification is taking place, said means having a crossseαional geometry such that when the crosssection is biseαed by an imaginary line, said means is charaαerized by a first half and a second half; said first half and said second half being substantiaUy symmetrical with respeα to each other; means for introducing the starting material into one of said halves of said containment means; means for supplying energy to the interior of said containment means to initiate and sustain gassification of the seleαed constituents of the starting material; means for removing from said containment means any residual constituents of the starting material that are not gassifϊed during treatment; and means for removing the gases resulting from gassification from said containment means.
2. The treatment unit of claim 1, wherein said crosssection of said containment means is substantiaUy ellipsoidal.
3. The treatment unit of claim 1 or claim 2, wherein said means for supplying energy is a heating chamber which is coaxial with, and which substantiaUy surrounds said containment means.
4. The treatment unit of any of claims 13, wherein said heating chamber is provided with at least one aperture for injeαing fuel gases into said heating chamber for combustion to supply heat energy.
5. The treatment unit of any of claims 14, wherein said means for introducing the starting material comprises an input conduit fitted with a first valve and a second valve, each of said valves being capable of being retraαed only when the other of said valves is closed, whereby the metered flow of starting material into the unit occurs without concomitant introduαion of air into said containment means.
6. The treatment unit of any of claims 16, wherein said means for removing solid residue means comprises an output conduit fitted with a first valve and a second valve, each of said valves being capable of being retracted only when the other of said valves is closed, whereby the metered flow of solid residue out of the unit occurs without concomitant introduαion of air into said containment means.
7. The treatment unit of claim 1, wherein said containment means further includes a screw conveyor having an input end and an output end, which rotates to effect movement of the starting material through said containment means whUe pyrolysis is taking place, said screw conveyor having a center shaft about which is disposed a pluraUty of heUcal flights, one of more of said flights having a lifting tab.
8. The treatment unit of claim 7, wherein one or more of said flights further is provided with a sweeping brush.
9. A treatment unit for pyrol zing constituent elements of a starting material that are susceptible of pyrolysis, the unit comprising: a pyrolysis chamber in which pyrolysis is to take place, said pyrolysis chamber having an input aperture through which starting material is introduced, and at least one output aperture through which the products of pyrolysis can be discharged; and a heating chamber in which heat energy is generated to initiate and sustain pyrolysis in said pyrolysis chamber, said heating chamber being in communication with said pyrolysis chamber.
10. The treatment unit of claim 9, wherein said heating chamber is in communication with said pyrolysis chamber through a conduit.
11. The treatment unit of claim 10, wherein said conduit exits said heating chamber at a point proximal to one of said output apertures and enters said pyrolysis chamber at a point proximal to said input aperture.
12. The treatment unit of claim 10 or claim 11, wherein said conduit is provided with a pump for conveying heat energy from said heating chamber to said pyrolysis chamber.
13. The treatment unit of any of claims 1012, and further including at least one sensor within said conduit for deteαing the level of oxygen present in said conduit at any given time during operation.
14. The treatment unit of claim 9, wherein said heating chamber has a first value which seleαively communicates with said pyrolysis chamber.
15. The treatment unit of claim 9, where said heating chamber further is selectively in communication with said pyrolysis chamber by virtue of said first valve and is seleαively in communication with the atmosphere by virtue of a second value, whereby said first valve and said second valve can be operated to aUow heated gases from said heating chamber to flow into the pyrolysis chamber.
16. A treatment unit for pyrolyzing the constituents of a starting material that are susceptible of pyrolysis, the unit comprising: a pyrolysis chamber in which pyrolysis is to take place, said pyrolysis chamber having an input aperture through which starting material is introduced, a rotatable screw conveyor upon which the starting material is conveyed through said pyrolysis chamber, said screw conveyor provided with a center shaft having an input end and an output end, and at least one output aperture through which the produαs of pyrolysis can be discharged; a heating chamber in which heat energy is generated to initiate and sustain pyrolysis in said pyrolysis chamber; a sealing arrangement at the points where said input end and said output end of said screw conveyor extend out from said pyrolysis, said sealing arrangement having a winding of temperatureresistant cable about each said end of said screw conveyor, each winding being secured by an adjustable tension plate, said windings of cable aUo ing said screw conveyor to rotate wh e said tension plates prevent air from leaking into said pyrolysis chamber around said input end and said output end of said screw conveyor.
17. A treatment unit for gassifying seleαed constituents of a composition of a starting material, the unit comprising: containment means for contaming the starting material whUe gassification is taking place; means for introducing the starting material into said containment means; means for supplying energy to the interior of said containment means to initiate and sustain gassification of the seleαed constituents of the starting material; means for removing from said containment means any residual constituents of the starting material that are not gassified during treatment; and means for removing the gases resulting from gassification from said containment means, said means including an oxidation chamber, a channel through which gasses from said containment means are direαed by a pressure gradient to said oxidation chamber, said channel being in communication with a burner cone having a plurality of detachable gas injeαion ports that can be seleαably removed without disrupting operation of said burner cone.
18. A method for pyrolyzing the hydrocarbon constituents of a starting material in a treatment unit, the treatment unit having a pyrolysis chamber in which pyrolysis takes place with an input aperture through which starting material is introduced and at least one output aperture through which the products of pyrolysis can be discharged, and a heating chamber in which heat energy is generated to initiate and sustain pyrolysis in the pyrolysis chamber, the heating chamber being in communication with the pyrolysis chamber through a heatconveying conduit, the steps comprising: combusting a fuel gas in the heating chamber to supply heat to the pyrolysis chamber; conveying heat energy produced in the heating chamber into the pyrolysis chamber by conduction through the waUs of the pyrolysis chamber; conveying heat energy produced in the heating chamber directly into the pyrolysis chamber through the heatconveying conduit; continuously introducing the starting material into the treatment unit at a seleαable and controUable rate whUe preventing the entry of oxygen into the pyrolysis chamber; pyrolyzing the hydrocarbon constituents in the starting material; and removing the gaseous products and the solid residue produced by pyrolysis from the pyrolysis chamber at a rate consistent with the rate at which the starting material is being introduced.
19. A method for pyrolyzing the hydrocarbon constituents of a starting material in a treatment unit, the treatment unit having a pyrolysis chamber in which pyrolysis takes place with an input aperture through which starting material is introduced and an output aperture through which the produαs of pyrolysis can be discharged, and a heating chamber in which heat energy is generated to initiate and sustain pyrolysis in the pyroloysis chamber, the heating chamber being selectively in communication with the pyrolysis chamber, the steps comprising: combusting a fuel gas in the heating chamber to supply heat to the pyrolysis chamber; conveying heat energy produced in the heating chamber into the pyrolysis chamber by conduction through the walls of the pyrolysis chamber; conveying heat energy produced in the heating chamber directly into the pyrolysis chamber by opening a valve that is in communication with the heating chamber and the pyrolysis chamber; continuously introducing the starting material into the treatment unit at a seleαable and controUable rate whUe preventing the entry of oxygen into the pyrolysis chamber; pyrolyzing the hydrocarbon constituents in the starting material; and removing the gaseous products and the solid residue produced by pyrolysis from the pyrolysis chamber.
20. A method for pyrolyzing material in a treatment unit, the treatment unit having a pyrolysis chamber in which pyrolysis takes place with an input aperture through which starting material is introduced and at least one output aperture through which the products of treatment can be discharged, and a heating chamber in which heat energy is generated to initiate and gassification in the pyrolysis chamber, the heating chamber being in communication with the pyrolysis chamber through a bivalve system, the steps comprising: combusting a fuel gas in the heating chamber to supply heat to the pyrolysis chamber; conveying heat energy produced in the heating chamber into the pyrolysis chamber by conduαion through the waUs of the pyrolysis chamber; conveying heat energy produced in the heating chamber directly into the pyrolysis chamber by closing a first valve which prevents the heat energy from escaping to the atmosphere and then opening a second valve which aUows the heat energy to flow from the heating chamber into the pyrolysis chamber; introducing the starting material into the treatment unit; and pyrolyzing the starting material.
21. The method of claim 20 wherein said step of introducing the starting material further includes introducing the starting material continuously into the treatment unit at a seleαable and controUable rate.
22. The method of claim 21 further including the step of preventing the entry of any significant amount of oxygen into the pyrolytic chamber.
23. The method of claim 20 further including the step of removing the gaseous products and the solid residue produced by pyrolysis from the pyrolysis chamber.
Description:
PYROLYTIC WASTE TREATMENT SYSTEM

BACKGROUND OF THE INVENπON This invention relates generally to waste treatment systems and, more specifically, to waste treatment systems whereby the waste is treated using pyrolytic processes.

Modernly, ways of dealing with material that is an undesirable result of an otherwise useful product or process of necessity, have become a serious concern of industrialized nations. As used here, the term "waste" is intended to encompass a wide variety of such material, for example, that material which is considered undesirable or not useful by reason of defects, or damage, or because the material is considered superfluous to, or an unwanted by-product of whatever process or product produced it. Waste is troublesome not only because of the fact it represents something that cannot be used for any beneficial purpose, but because it presents hazards to the environment in terms of the space it takes up and the deleterious effects it has on Uving organisms. For a considerable period, the disadvantages inherent in waste were largely ignored or, at least afforded little weight when a new process or new product that would produce waste was introduced, the benefits to society that the process or product would bestow being considered paramount. Inevitably, however, the increasing volume of waste and the dangerous conditions presented by it forced more attention to be paid to ways of dealing with the material, such that planning for waste treatment often today is an important consideration in the design of a new process or product.

Pyrolysis long has been known to those skilled in the an of waste treatment as an effective process for reducing the organic components of a variety of compositions of waste material, such as conventional industrial and municipal waste, to products which present no harm to the atmosphere and which can be used in whole or in part to provide a useful source of energy or a material that can be recycled into a product having commercial value.

The pyrolytic process employs high temperature in, most desirably, an atmosphere substantially free of oxygen (e.g.. in a practical vacuum), to convert the

soUd organic components of the waste to other states of matter, such as pyrosylates in a liquid or vapor phase. The solid residue remaining after pyrolysis commonly is referred to as char, but this material may contain some inorganic components, such as metals, as well as carbon components, depending on the nature of the starting waste. The vaporized product of pyrolysis further can be treated by a process promoting oxidation, which "cleans" the vapors to eliminate oils and other paniculate matter therefrom, allowing the resultant gases then to be safely released to the atmosphere.

A typical waste treatment system utilizing pyrolysis has an input structure for introducing the waste; a chamber or reton from which air can be purged and in which pyrolysis processing occurs; a feature for raising the temperature inside the chamber; an element that allows the vaporized waste material or "off-gases" to be vented to the environment, which element may or may not include some feature for cleaning or scrubbing the gases; and an assembly through which is discharged the solid or molten residue of the pyrolytic conversion process.

Systems that rely upon pyrolysis often are designed with principal attention being given to the criterion that the system be optimally efficient. For example, to encourage consistent results from the pyrolytic conversion process, various methods and apparatuses commonly are used to pre-treat the waste before it is introduced into the pyrolytic chamber. These include pre-soning or separating the waste into constituents on the basis of weight, shredding the material to make it of relatively uniform size and perhaps blending it with other pre-soned material to promote even distribution of the waste as it is introduced into the reton. Several techniques have been employed to reduce the level of moisture in the waste before introducing it into the machine, because the presence of moisture makes the pyrolytic process less efficient. Such techniques include drying by desiccation or through the application of microwave energy.

Other features often are provided to continuously move waste through the treatment unit while the system is being operated, such as a form of conveyance arrangement. Screw conveyors or conveyor belts oriented at an incline have been

used to ramp waste material, in units of a defined volume and at a defined rate of flow, up from a storage bin or pre-treatment assembly at the ground level to a charging hopper at the top of the treatment unit through which waste is metered into the pyrolytic chamber. Screw conveyors, auger screws and worm conveyors all have been used to impel waste through the reton while pyrolysis takes place, again, to encourage predictable results from the process.

It is well known that the efficiency of pyrolysis is negatively effected by the presence of oxygen. One of the adverse effects oxygen has is to increase the degree to which the chemical reactions taking place during conversion are explosive, which explosiveness, in turn, increases the turbulence in the chamber and tends to result in the recombination of the released gases with the solid material being processed, making the conversion less complete and thus inefficient. Accordingly, waste treatment systems have been provided with elements that guard against the introduction of oxygen from ambient air surrounding the treatment unit. For example, various air-lock arrangements are known which can be disposed at the point at which waste is introduced into the pyrolytic chamber and also at the point at which the solid residue is discharged from the unit, to insure the reton is kept free of appreciable amounts of oxygen. Vacuum purging elements also have been employed in various stages of the system to periodically remove gases from the pyrolytic chamber to eliminate any air that may have been introduced into it.

The manner in which the reton chamber is supplied with heat energy to sustain pyrolysis also can effect the efficiency with which the process can be carried out. For example, it has been found that uniform application of heat to the outer wall of the reton, through which it is conducted into the interior of the chamber, reduces the risk that the reton will buckle from uneven distribution of high temperatures and tends to encourage a more even distribution of heat and consistency of temperature throughout the chamber, which leads to consistent processing results. System features provided to address even heating have included those directed to the manner in which the primary source of heat energy, commonly fuel gases being

combusted in a heating chamber, is arranged with relation to the reton, and the number and placement of fuel gas injection ports, etc.

It further has been known to provide a feature which encourages the efficient use of heat to sustain the pyrolytic process, such as one that allows the recycling of gases that have once been combusted to supply heat energy to the pyrolytic chamber back through the gas injection port, where the gases can be ignited again with a fresh supply of oxygen or air.

Efficiency-promoting elements also can be provided for the processing and recycling of off-gases or vapor pyrosylate. For example, it is known that if a pressure gradient is maintained between the retort and the gas processing arrangement in the direction of the exhaust, the vapor pyrosylate naturally will tend to flow into the cleaning elements. To avoid wasting energy, the cleaned high temperature gases can be used to provide energy to some sort of generating station, such as to heat water in a boiler that supplies a steam generator. Efficiency considerations then, are of critical importance in designing a waste treatment system or in evaluating the practical value of a system already in existence. For obvious reasons, features that contribute to the safety and reliability with which a system functions also are of primary import. However, there is another criterion that is of great practical concern when a system is being designed or selected, and that is the relative ease with which a treatment unit can be maintained. The maintainability of the system must be considered in assessing for how long a treatment unit can be expected to be continuously operated and for how long it must be shut down to perform refurbishing or repair procedures. The useful life or mean- time-between-failure of individual unit components similarly must be considered in predicting how often operation will have to be disrupted to replace particular components, with attention being given to how easily the component can be accessed and how costly refurbishing, repair or replacement procedures are likely to be in terms of labor and material expenses. Accordingly, gains in efficiency afforded by certain features of prior art waste treatment systems can be overshadowed by the less- than-optimum maintainabihty of such systems, which leads to frequent, labor-

intensive, and compUcated maintenance routines that are associated with long periods of system downtime.

What has been needed, therefore, and heretofore has been unavailable is an improved pyrolytic waste treatment system that achieves both optimal maintainabihty and efficiency, and which nevertheless is safe, reliable and capable of operation with a wide variety of compositions of waste material. The present invention satisfies this need.

SUMMARY OF THE INVENTION Briefly, and in general terms, the present invention provides a waste treatment system having features that in combination result in an apparatus and method for waste treatment that is characterized by enhanced maintainability as well as by optimal efficiency, with the additional attribute that many of the products of the treatment process can be used beneficially; either while treatment is on-going, e.g.. to generate energy, or following processing, e.g.. to incorporate the residue of waste or portions thereof into building materials or other products having commercial or environmental value.

In a presently preferred embodiment of a system, by way of example and not necessarily by way of limitation, a waste treatment unit is provided having the following primary components: a main frame or superstructure; an input stage or in- feed element through which the waste material to be treated is introduced through an arrangement of valves or gates that can be controllably synchronized to prevent the unwanted incorporation of air or oxygen into the pyrolytic process; a pyrolytic assembly comprised of a thermally insulated outer housing coaxially surrounding an ellipsoidally-shaped retort or pyrolytic chamber in which is disposed a rotatable screw that, by virtue of a pluraUty of heUcally-oriented flights, is capable of conveying waste through the retort as pyrolysis is taking place, the space between the outer housing and the retort defining a heating chamber in which fuel gases supplied by gas jets in communication with the heating chamber through gas injection ports are combusted to provide a source of heat energy for pyrolysis; an arrangement of

elements through which gases Uberated from the feed material during pyrolysis are processed to draw off and/or eliminate poUutants contained therein, by a combination of condensation and thermal oxidation, and then either vented harmlessly to the atmosphere or routed to supply energy, such as to a steam generator or the like; and an output stage or discharge element, also characterized by an air-lock implemented by synchronized valves, through which the soUd residue of pyrolysis is discharged for immediate disposal or recycling, or post-pyrolysis sorting or processing.

One of the features of the system which contributes to improved maintain- abiUty is provided in the reton assembly. The assembly is comprised of an innermost, elongated eUipsoidal chamber that serves as the retort, which is open at both ends and receives a rotatable screw conveyor to move the waste through it; a thermal converter consisting of a generally cylindrical retort housing, which has a diameter substantiaUy greater than that of the retort and which surrounds the retort, the housing being equipped with a pluraUty of natural gas burners to provide heat energy for pyrolysis; and a pair of fittings affixed to the main frame of the unit, each of which is sized to fill an open end of the retort when the reton is bolted to it.

The ellipsoidal shape of the cross-section of the reton is such that if the retort were bisected along any axis, two halves would be created, each of which being a mirror image of the other. Therefore, when the chamber is bisected along an imaginary longitudinal axis at the center of the ellipse, a first retort half and a second retort half are created.

The screw is mounted in the end fittings such that it is disposed in only one of the two halves of the retort, leaving a void in the other half. When the screw rotates to evenly distribute the material for pyrolysis and to convey the waste through the retort chamber, the heUcal extensions on the screw shaft can carry waste to the chamber surface or can otherwise cause abrasion of that surface. Because the screw only functions in one-half of the retort during any given period of operation, the two halves do not become soiled with pyrolytic residue or abraded at the same rate. When one-half of the retort requires refurbishing, the unit can be shut down

and partiaUy dismantled to release the retort from the end fittings so that it can be rotated through 180 degrees. Thus, the other, cleaner half of the retort is presented to the screw conveyor, and the useful life of the chamber essentially is doubled over retorts of known design. The low maintenance aspect of the system further is enhanced by characteris¬ tics of the screw conveyor in the retort. Sweeping brushes and lifting tabs are provided on the heUcal extensions encircling the shaft of the conveyor, which will contact the floor of the chamber as the screw rotates to move waste through the retort. The brushes and tabs tend to keep waste-in-process or residue from pyrolysis from adhering to the surface of the retort and building up thereon, which build-up eventuaUy inhibits effective operation of the screw. The constant sweeping and lifting action of these elements further prolongs the need to shut down the system to open the retort for cleaning or repair.

Another aspect of the invention that contributes to maintainability is to be found in the arrangement by which the retort assembly is sealed from the housing, so that a practical vacuum can be maintained therein during pyrolysis and the unwanted introduction of air can be avoided. A graphite cable resistant to the very high temperatures established in the pyrolytic chamber is wrapped at four locations around the shaft of the screw conveyor, that is, at two locations on either side of where the screw conveyor wiU extend from the innermost chamber of the retort when the unit is fully assembled. Each cable is made to sealably fill the space between the retort outer housing and the screw shaft by the appUcation of force through an arrangement of nuts and bolts and other force-conveying elements to a tension plate that is in contact with the end of each piece of cable that is furthest from the innermost chamber. If any one of the four seals in the sealing scheme weakens, the bolt can be tightened to increase the tension applied to the cable and thus to reseal the chamber.

Because there are two distinct lengths of cable spaced apart from each other along the longitudinal axis of the screw shaft, with a pair of tension-applying elements provided for each length, the integrity of the seal between the inner

chamber of the retort and the other parts of the treatment unit is not compromised even if one of the two individual seal assembUes fails. Thus, the redundancy in the sealing scheme contributes to the safe operation of the system as weU as to maintainability. StiU another attribute of the invention prolongs the period over which the system can be operated continuaUy before shut down for refurbishment or repair, and this attribute is associated with the cleaning or scrubbing step applied to the gases drawn off from the pyrolytic chamber. Oils and other paniculate matter carried by the off-gases may not be completely oxidized during this step, and thus can accumulate in the gas injection ports that are used to ignite the vaporized pyrosylate, causing the ports to become clogged and thus unusable. In the treatment unit of the invention, a pluraUty of gas injection ports are provided at the base of the afterburner cone so that one of the ports can be removed from cleaning or replacement while the others are retained in place. Accordingly, a maintenance timetable can be established for periodicaUy refurbishing each of the three ports, leaving at least one port in position and functioning so that the system does not have to be entirely shut down to refurbish the gas injection elements.

Other features of the system improve the efficiency with which the unit can be operated. Most notably, a heat reclamation scheme is provided to convey some of the gas in the heating chamber in which combustion is occurring directly into the retort, thus contributing to the even distribution of heat in the retort and aUowing pyrolysis to be sustained with less fuel gas introduced by the natural gas burners. Two such heat reclamation schemes have been implemented with favorable results. In one such scheme, a heat pump forces combustion gases into the retort. Another scheme is implemented through a pair of valves. The first of these, a stack-damper valve, is situated so as to be in communication with the heating chamber, ije., the space defined by the outer housing and the reton. The second valve is an "internal" valve, which is selectively in communication both with the outer chamber and with the interior of the reton. The strategicaUy-timed opening and closing of the stack- damper valve and internal valve, by reason of the pressure gradient that exists

between the outer chamber and the retort, causes some of the high temperature burner exhaust gases, which are radiating around the exterior of the retort, to flow into the reton and penetrate the waste being fed into the system. In addition, the scheme of synchronized valves at both the input stage and the output stage at once aUow the rate of flow of material through the treatment unit to be controUed and prevent the introduction of air into the reton which, if present, could detract from the efficiency with which pyrolysis can be accomplished.

A preferred method for treating waste according to the system of the invention can be summarized as foUows: After the waste is pre-treated by a mixing arrangement which sons, shreds, crushes and dries the material to remove moisture from it, the waste is routed to the treatment unit by an inclined screw conveyor of conventional design. The conveyor feeds the material into a hopper at the input stage of the unit, where an arrangement of synchronized valves or gates open and close to meter waste into the unit without simultaneously introducing unwanted air into the system.

The material then is moved through the retort or pyrolytic chamber by another screw conveyor of novel design, which is rotatably suspended in one-half of the retort, which half is a mirror image of the other half of the chamber. The half of the retort in which the screw is not disposed serves as a void into which gases produced by pyrolysis of the organic components of the waste can be drawn off for cleaning and subsequent exhaust to the atmosphere or diversion for use by a generator. The existence of this void reduces the turbulence occurring in the retort around the screw conveyor which, if present to a significant degree, can result among other things in the recombination of off-gases with the waste. To prevent environmental poUution, the pyrosylate in vapor form is continuaUy drawn off from the retort and channeUed through a conduit to a combination of elements in which the gases are cleaned before being vented to the atmosphere through an exhaust chimney. The cleaning process entails injecting additional fuel gas and routing outside air into the gases passing through a burner cone, and then igniting the resultant mixture to eliminate the poUutants to the extent

necessary by the process of thermal oxidation. The cleaned gases can be used to supply energy in the form of heat to a boiler that, in turn, can be used to supply a steam generator. Meanwhile, the soUd pyrosylate residue, such as carbonaceous char or ash, is discharged from the unit through the output stage, which like the input stage is characterized by a bivalve arrangement to protect against the unwanted introduction of air into the pyrolytic chamber.

A system according to the invention thus provides a method and apparatus of treating a wide range of waste material with varied composition in a manner which optimizes the efficiency of the treatment process and accomplishes the same safely and reUably with a nominal requirement for maintainability.

Other features and advantages of the present invention wiU become apparent from the foUowing, more detailed description of the invention, when taken in conjunction with the accompanying exemplary drawings.

BRIEF DESCRIPTION OF THE DRAWINGS FIGURE 1 is a front elevational view of a waste treatment unit in accordance with the invention;

FIG. 2 is a rear elevational view of the treatment unit shown in FIG. 1;

FIG. 3 is a partial front elevational view of the valves or gates of the input assembly of a treatment unit according to the invention;

FIG. 4a is an end view of the input end of the pyrolytic assembly of the treatment unit of FIGS. 1 and 2;

FIG. 4b is an end view of the output end of the pyrolytic assembly of FIGS. 1 and 2;

FIG. 5a is a perspective view, partiaUy cut away, of the reton and screw conveyor of the pyrolytic assembly of the invention;

FIG. 5b is a cross-sectional view taken substantiaUy along the line 5-5 in FIG. 5a of the reton of FIG. 5a;

FIG. 6 is an enlarged, partial elevation view of the screw conveyor disposed in the retort of a treatment unit in accordance with the invention;

FIG. 7 is a partial, front elevational view of a heat reclamation arrangement according to the invention;

FIG. 7a is a front elevational view of a waste treatment unit according to the invention, partiaUy cut away, iUustrating an alternative heat reclamation arrangement;

FIG. 8 is a partial, front elevational view of the sealing arrangement of a treatment unit of the invention;

FIG. 9 is a partial, front elevational view of the valves of the discharge assembly of the treatment unit of FIGS. 1 and 2;

FIG. 10 is a partial plan view of the gas exhaust and cleaning assembly of a unit of the invention;

FIG. 11 is partial, elevational view of the burner cone and gas injection tubes of the gas processing arrangement of the invention;

FIG. 12 is a partial, end view of the burner cone of FIG. 10; and

FIG. 13 is a flow chart iUustrating some of the steps of a method according to the invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

In the foUowing description, the waste treatment unit of a pyrolytic waste treatment system according to the invention is described with reference to FIGURES

1-12 of the drawing, in which like reference numerals are used to refer to common elements or features among the FIGURES. A method according to the invention is described with reference to FIG. 13 of the drawing.

The interrelationship of the principle components of the waste treatment unit 10 perhaps is best understood with reference to FIGS. 1 and 2. A main frame or superstructure 15 supports an input assembly or in-feed stage 20, a pyrolytic assembly 25; an assembly 30 for exhausting and subsequently cleaning and venting the product of pyrolysis in the vapor state (gas or vapor pyrosylate) and an assembly 35 for discharging the products of pyrolysis in the soUd state (residue, char, ash or soUd pyrosylate).

As best observed in FIG. 2, a condenser 40 also can be provided to condense out oUs and other particulates in the off-gases, so the condensate can be coUected and stored as waste or otherwise recycled. A main control panel 43 and an anciUary control panel 103 are provided from which operation of the system of the invention can be regulated and adjusted.

It is noted here that the pyrolytic assembly 25, as weU as other components of the treatment unit 10, must be adequately insulated from the environment exterior to the unit to insure the safety of persons in the vicinity of the unit whUe it is being operated. Depending on the British thermal unit (BTU) value of certain composite elements of the waste material being pyrolyzed, temperatures ranging from 150 to 2000 °F (65.5 to 1093.3 °C) can be produced while the system is functioning. Even higher temperatures can exist in the assembly 30 provided for exhausting and then cleaning the vapor pyrosylate, by virtue of the thermal oxidation occurring therein. Accordingly, insulative layers may be provided throughout the unit at appropriate

loca ions, which locations would be readUy apparent to one skiUed in the an. It has been found that commerciaUy available insulators incorporating ceramic wool are particularly weU-suited when common compositions of industrial or municipal waste are being processed. An arrangement of conveyance elements 45 is employed to conduct the waste material to be pyrolyzed from a feed tank or storage bin 50 to the input assembly 20, via a conveyance tube 55. This tube has an inlet 60 at a first end 63 which is disposed in the feed tank and an outlet 65 at a second end 67 of the tube. A rotatable screw conveyor of conventional design (not shown) is provided within the tube that has a plurality of flights helicaUy disposed at regular intervals along its length. The flights controUably pick up and transfer waste material in a certain volume and at a selected rate to sequentiaUy move the material as the screw shaft is mechanicaUy rotated, as with an electric motor or other suitable means, towards the input assembly 20, depositing the waste through the outlet into charging hopper 70, from which it is metered by the synchronized operation of the two valves 75 and 80 into a conduit 85, which leads into the pyrolytic assembly 25.

As has been noted previously, pyrolysis is most efficiently carried out in an environment that is substantiaUy free of oxygen because the presence of oxygen causes the chemical reactions taking place to be more explosive in character, resulting in turbulence within the retort which encourages the recombination of the hydrocarbon off-gases with the molten or soUd material being processed. Not only does this effect make the Uberation process take longer, but it also can result in the production of pyrosylates that are less friendly to the environment and which require additional, more elaborate processing to neutralize the hazardous effects. Accordingly, the treatment unit 10 of the invention has several features to prevent the introduction of ambient air containing unwanted oxygen into the pyrolytic assembly 25.

First, the input assembly 20 through which waste is introduced to the treatment unit 10 is equipped with a pair of valves 75,80 that can be caused to sequentiaUy and temporarily seal off the conduit 85 at different locations as waste

material is passing through it, thus effectively providing an air-lock during the in-feed process.

As best shown in FIG. 3, each valve 75,80 is in communication with the conduit 85 through apertures 90 in the conduit waU and each is connected to the conduit by a series of nuts 93 and bolts 95. The valves are caused to move into the conduit to seal it, or to move out of the conduit to aUow free passage of the waste by actuating motors 100 that are energized by electrical signals originating from the control panel 103. Valves that are operated by pneumatic or hydraulic means also could be employed with success in a unit constructed in accordance with the invention. The operation of the valves is timed so that the first valve 75 never is open when the second valve 80 is open and vice versa.

Whenever the first valve 75 is open, a predetermined quantity of waste fills the section of the conduit 85 segmented by the closed second valve 80. The first valve then closes, and a limit switch 105 in series with the actuating motor 100 for that valve is the source of a signal that indicates to a control panel 103 that the valve is closed, whereupon a responsive signal is sent to the actuating motor of the second value, causing the second valve to open. OptionaUy, the conduit 85 is equipped in the area between the two valves 75,80 with an evacuation port 105 connected to a source capable of drawing a vacuum within the segment of the conduit that is defined when both valves are closed, to eliminate air completely from the waste material before the second valve 80 opens to aUow it to move further along the conduit to the pyrolytic assembly 25.

To take advantage of the force of gravity to propel the waste, the conduit of the input assembly 20 is oriented along a vertical axis of the treatment unit 10, and the valves 75,80 enter the conduit at an angle that is generaUy perpendicular to that axis. Other orientations of both the conduit and the valves are contemplated, however, which might be preferable given particular site requirements, such as space limitations. The beneficial effect of gravity could be substituted for by some mechanical force supphed by, for example, a motorized conveyor belt.

Similarly, although the pair of valves 75,80 has been found to be preferred in particular applications to create an air-lock effect at the input assembly 20 of the unit 10, a more complex arrangement including additional valves or other metering elements might be equaUy adequate in other situations, not only to prevent oxygen from entering the unit, but also to improve the abUity to control volumetric flow or to control pressure gradients in the system.

Other features for keeping oxygen out of the pyrolytic process are inherent in the configuration of the pyrolytic assembly 25 which has three primary elements, one of these being an important component of the treatment unit 10 which contributes to enhanced maintainabUity.

The pyrolytic assembly 25 comprises an outer housing 120 that coaxiaUy surrounds a pyrolytic chamber or retort 125, as is shown in FIG. 5a, in which a rotatable screw conveyor 130 is disposed. When the unit 10 is fuUy assembled as is hereinafter described, and as shown in FIG. 7, fuel gases are combusted in heating chamber 131 or the space defined by the inner surface 135 of the housing 120 and the outer surface 140 of the retort 125. The heat generated by this combustion provides a primary source of energy to initiate pyrolysis of waste material that is being impeUed through the retort 125 by the rotation of the screw conveyor 130. An exhaust port or chimney 133 is provided to vent combusted fuel gases generated in the outer housing 120 whenever necessary to relieve pressure in the pyrolytic assembly.

All of the elements of the treatment unit 10 that are operated under high temperature conditions, such as the outer housing 120, the retort 125, and the screw conveyor 130, desirably are manufactured from a material that is resistant to degradation during long periods of exposure to high temperatures. For obvious reasons, the material used for the retort 125 and the screw conveyor 130 also should be resistant to corrosion from the continuous pyrolysis occurring inside the retort. Various aUoys known to those skilled in the art are available that exhibit the characteristics of temperature-resistance and corrosion-resistance, for example, steel aUoys or aUoys containing proportions of nickel, chrome and silica.

The outer housing 120 is generaUy cylindrical, but could be provided with a cross-section that is other than circular in order to meet space requirements or to promote more even conduction of heat into the retort 125. After assembly, the longitudinal axis of the housing 120 is oriented so as to be approximately paraUel to the ground, although other orientations can be implemented without departing from the scope of the invention that may improve the efficiency of the process. The housing 120 is provided with one or more ports (not shown) along its length, to aUow the introduction of fuel gas through gas injection tubes into the heating chamber 131 to provide combustion. The ports and gas injection tubes, or combustion burners, are placed so as to best promote even conduction of heat energy through the waU of the retort 125, to discourage distortion of the shape of the retort, and to insure the efficiency of pyrolysis. During operation of the system, the mix of fuel gas and oxygen is set at sub-stoichiometric. The combusted gases, i__, the exhaust from the burners cycle around the retort and radiate heat about it, which is conducted through the retort waUs into the interior where the waste is being processed then through the internal value.

The housing has input end 145 and output end 150, the ends being shown in FIGS. 4a and 4b, respectively, at which the interior of the housing is sealed from the atmosphere. EUipsoidaUy-shaped fittings 155,157 are provided to which the ends 160,165 of the retort 125 ultimately wiU be affixed, and through which the ends 170,175 of the screw conveyor 130 eventuaUy wiU extend via apertures 180, 185 in the housing ends when the unit 10 is fuUy assembled.

Turning now to FIGS. 5a and 5b, the features of the retort 125 can be appreciated. The retort 125 has a generaUy elliptical cross-section, defining a first retort half 190 and a second retort half 195 when the eUipse is bisected with any imaginary line, which halves are symmetrical due to the geometry of the structure. In one embodiment of the invention, the retort 125 is manufactured from a single piece of material for convenience, however, circumstances are contemplated in which forming the retort from two or more pieces that are welded or bolted together also might be desirable. The retort 125 is situated inside the outer housing 120 so that a

longitudinal axis of the retort is coaxial with a longitudinal axis of the housing 120. The screw conveyor 130, having center shaft 200 and a pluraUty of flights 205 helicaUy-disposed about the shaft, next is mounted in the retort 125. The screw 130 also is aUgned so as to be coaxial with a longitudinal axis of both the retort and a outer housing 120. Importantly, as wiU become obvious from the discussion below, the entire structure of the screw conveyor 130, that is, both the center shaft 200 and the flights 205, is oriented so that it occupies only one of the two retort halves 190,195.

When the three elements of the outer housing 120, the retort 125, and the screw conveyor 130 are properly positioned, the terminal portions or ends 170,175 of the screw conveyor can be threaded through the apertures 180,185 in the fittings 155,157 of the input end 145 and the output end 150 of the housing. The retort 125 then can be bolted to the housing 120 at points of attachment 210 that are provided for that purpose. The input end 145 and the output end 150 subsequently can be sealed to the outer housing 120 by appropriate means such as with bolts or by welding. Alternatively, the outer housing 120 can be formed from a single piece of material, so that the input and output ends 145,150 are an inseparable part of the structure.

The significance to maintainabihty of the relative positions of the retort 125 and the screw conveyor 130 now wiU be described. Because the screw operates only in one of the two identical first and second halves 190,195 of the reton, only one-half is exposed to wear by the source waste material during a given period of operation. Accordingly, waste passing through the unit 10 on the screw conveyor 130 that comes in contact with the surface of the reton 125 and that is perhaps extraordinarily abrasive, wiU wear the surface of only one-half of the retort 125 at a time, leaving the other half relatively unworn. When the half of the retort in which the screw conveyor 130 is disposed becomes worn to the point at which the condition significantly detract from the efficiency of operation, the unit 10 can be disassembled and the retort 125 rotated through an angle of 180 degrees (°) to present the other, unworn half of the retort to the screw, and system operation can be resumed.

Without this feature, whenever the retort 125 becomes too worn to use effectively, the system would have to be shut down for a substantiaUy longer period of time, so that the retort 125 either could be completely refurbished, or alternatively, a new retort could be substituted for the worn structure. Either course of action would not efficiently maximize utilization and consumption of the costly reton.

In addition to enhancing maintainabihty, the structural arrangement of the retort 125 and the screw conveyor 130 also improve the efficiency of the pyrolytic process. More particularly, the half of the retort opposite the half in which the screw 130 is located at any given time presents a void that is useful in accommodating the large volume of vapor pyrosylate produced while the system is operational. It is not uncommon for a volume of gas to be generated by pyrolysis that is as much as fourteen hundred times greater than the volume occupied by the material when it was initiaUy introduced into the retort 125. The space afforded by the half of the retort not occupied by the screw thus counteracts the turbulence attendant upon the rapid generation of this great volume of gases, which has the effect of making the process more consistent and efficient. The void aUows the gases to be released in a manner closer to that which would be natural if the vapors were not contained by the treatment unit 10. Therefore, generated gases are discouraged from circulating about the turning screw conveyor 130 where the gases might recombine with constituents of the waste material being treated or of the residue being formed.

The screw conveyor 130 also has features which contribute to a longer term of useful life than is the case with waste treatment systems of the prior art, and these features are shown in FIG. 6. The flights 205 disposed in heUcal fashion about the center shaft 200 of the screw conveyor 130 are provided with sweeping brushes 220 and lifting tabs 225. As the screw 130 rotates, the brushes 220 scrape against the inner surface of the half of the retort 125 in which the screw is disposed during any particular period of operation, to dislodge any soUd waste material or pyrolytic residue that otherwise would tend to accumulate thereon. The tabs 225 keep the substances swept by the brushes 220 moving through the retort 125 by lifting the material or residue while the screw is turning. Thus, the features of the brushes 220

and the lifting tabs 225 cooperate to keep the retort 125 clean and free of debris that would detract from the efficiency of pyrolysis for longer periods, leading to less frequent maintenance procedures.

As best observed in FIGS. 4a and 7, and 7a a treatment unit 10 in accordance with the invention has aspects that aUows some of the heat energy created or present in the heating chamber 131 to be introduced directly into the retort 125, rather than exclusively by conduction through the walls of the retort, in a further effort to maintain optimal efficiency of the system. In one such aspect, a first end 230 of a gas-conducting tube 235 is in communication with the heating chamber 131 via an aperture 240 and a fitting 243. This aperture 240 preferably is located near the output end 150 of the housing, for example, adjacent the exhaust port or chimney 133, because the off-gases will tend to flow towards the output end 150 due to a pressure differential to be described in more detail below. The second end 245 of the tube is in communication with the interior of the retort 125, through an aperture 250 and a fitting 255 in the retort fitting 155 at the input end 145 of the housing 120. A heat pump 260 is disposed in the tube 235 near the aperture 240 in the housing, to force gases present in the heating chamber through the tube and into the reton. In a currently preferred embodiment of a system according to the invention, a heat reclamation scheme that obviates the need for a heat pump is implemented by a pair of synchronously operated valves 261,262, as is best shown in FIG. 7a. In this arrangement, a first stack-damper valve 261 is provided in the exhaust port, chimney or stack 133. This valve normaUy is open so that the gases produced by combustion can be vented to the atmosphere. When heat reclamation is desired, however, the valve can be closed to keep the combustion gases radiating about the retort 125. Then, a second, "internal," valve 262, which is in communication with the heating chamber 131 defined by the outer housing 120 and the retort 125, and with the interior of the retort itself, is opened. The operation of the stack-damper valve 261 and the internal valve 262 in this manner results in a pressure gradient between the heating chamber 131 and the interior of the retort. That is, the pressure existing in the interior of the retort, as regulated by a system draft fan, is slightly negative with

respect to the positive pressure in the heating chamber that exists by virtue of manipulation of the two valves 261,262.

To insure that no significant amounts of oxygen that are present in the gases being injected from the heating chamber 131, oxygen sensors 265 are provided within the gas conduction tube 235 which, when a certain level of oxygen is detected, wiU send a signal via the control panel 43 or 103 that wiU cease the operation of the heat pump and prevent further transfer of the oxygen into the retort 125.

The heat introduced by the heat pump 260 or the bivalve system 261,262 tends to flow with the other gases present in the retort 125 towards the output end 165 due to the pressure gradient, and thus the added gases aid in carrying the vapor pyrosylate out to the series of elements 30 provided for exhausting and cleaning the gases prior to venting the gases to the atmosphere. The direct introduction into the retort 125 of heat energy also has been found to help sustain pyrolysis, leading to a lower consumption of fuel gases freshly provided by the gas injection tubes supplying the heating chamber 131. Further, the feature appears to aid in maintaining an even distribution of heat throughout the retort while pyrolysis is taking place.

Referring now to FIG. 8, another feature of the treatment unit 10 of the invention is described which at once contributes to the maintainab ity, safety and efficiency of the system. The feature is directed to the manner in which the retort 125 is sealed off from other structures of the unit that are in continuous contact with or which transiently came into contact with the outside, oxygen-laden, environment.

A sealing scheme or sealing arrangement 280 is provided at both the input and output ends 160,165 of the retort 125, where the portions of the center shaft 200 of the input and output ends 170,175 of the screw conveyor 130 extend out through the apertures 180,185 of the fittings 155,157 at the ends 145,150 of the outer housing 120. Because the sealing scheme 280 employed at both of the ends 160,165 of the retort is identical, the scheme is described with reference only to FIG. 8, which depicts the location at the retort input end 160.

In the course of assembling the screw conveyor 130 into the retort 125, the end 170 of its shaft 200 is encircled or wrapped at two locations 290,295 with a

length of cable 300 that has the characteristic of being resistant to the high temperatures generated during combustion of fuel gases in the heating chamber 131 or during pyrolysis in the retort. Graphite is one material that has been found to have this temperature resistant quaUty. Tension plates 310 then are oriented about the cable 300 at four locations 320,325,330,335 with an appropriate securing arrangement of nuts 340 and bolts 345. Adjustment screws 350 can be turned to cause the plates 310 to press against the cable, resulting in a seal that is resistant to high temperature between the retort 125 and the exterior of the retort. The two locations at which the cable 300 is wrapped and the four tension plates provide redundancy for safety and decrease the frequency with which the unit 10 must be disassembled completely for component replacement. As the cable 300 wears and the integrity of the seal at that length of cable is jeopardized, one or both of the tension plates 310 can be tightened to maintain the seal.

As best observed in FIG. 9, the assembly 35 for discharging the soUd pyrosylate, residue, char or ash of the pyrolytic process that occurs in a treatment unit 10 according to the invention is characterized by an arrangement of valves 370,375 the opening and closing of which is synchronized to prevent the seepage of oxygen in the ambient air into the retort 125 in which pyrolysis is taking place. Reference is made to the description hereon of the operation of the valves 75,80 of the input assembly 20 to best appreciate the manner in which the discharge assembly 35 functions as an air-lock to discourage oxygen from entering the retort.

Discharge conduit 365 receives soUd residue or ash from the output end 165 of the retort 125 as it faUs, assisted by gravitational force, from the output end 175 of the rotating screw conveyor 130. Synchronized valves 370,375 then function in a manner substantiaUy identical to that in which the valves of the input assembly 20 function, resulting in the discharge of the residue from the treatment unit 10 at a controUable rate, without the concomitant introduction of air from the environment exterior to the unit into the retort. Limit switches 380 control the opening and closing of the valves 370,375 so that neither of the valves can open unless the other is fuUy closed. A purging port 385 also is provided in the conduit 365 which can be

connected to a vacuum source, to remove air before the valve 370 most proximal to the retort is opened.

Turning attention now to FIGS. 10, 11 and 12, now described is the arrangement of elements 30 provided to first exhaust gases from the retort 125 and then to clean or scrub the gases to free them of poUutants before venting the same to the atmosphere.

The arrangement 30 is comprised of four principal elements, namely, an input channel 400 that carries off-gases from pyrolysis away from the retort 125; an afterburner or burner cone 410 having a plurality of fresh air inlets or ports 415 and a pluraUty of gas injeαion ports 420; gas injection tubes 425 corresponding to each of the gas injeαion ports; and a chamber 430 in which the gases are retained until thermal oxidation of the poUutants therein has been accomplished prior to venting the gases to the atmosphere.

The off-gases naturaUy tend to flow in the channel 400 in the direαion of the burner cone 410, because the pressure at the output end 165 of the retort 125 commonly is higher than the pressure in the thermal oxidation chamber 430. However, the movement of gases in the appropriate direαion further can be encouraged by providing a blower or induαor fan 435 that tends to draw the gases into the burner cone 410. The blower 435 also facilitates bringing fresh air into the burner cone through air inlets 415. The gas injeαion tubes 425 have injeαion apertures 440 through which a fuel gas such as natural gas is introduced. Each tube 425 is removably mounted by screw-type fittings of conventional design (not shown) so as to extend into the burner cone 410 through gas injeαion ports 420.

During system operation, off-gases entering the chamber 430 are thermaUy oxidized after combination with air and ignition by the fuel gases coming in through the gas injection ports 420. The oxidation process wiU remove dirty oils and other matter that has not been eliminated by pyrolysis from the gases. The temperature at which thermal oxidation is carried out, and the amount of time the gases are retained in the oxidation chamber 430 prior to being vented through chimney 441, both vary depending on the known or prediαed constituents of the starting waste

material. For example, higher oxidation temperatures and longer pre-venting chamber retention times are required when the vapor pyrosylate is generated from waste that contains toxic organic compounds such as polychlorinated biphenyls (PCBs), dioxins, or furans. Importantly, the gas injeαion tubes 425 contribute to the enhanced maintainabihty of the treatment unit 10 by virtue of the fact that each can be removed independently of the other for cleaning or replacement without disrupting system operation. The ends 443 of the tubes 425 that extend into the burner cone 410 can become closed off when the unit has been functioning for sustained periods, for example, because the injection apertures become clogged with oUs and other material that condenses out of the off-gases prior to oxidation. Because each tube 425 can be unscrewed independently of any other tube 425, the elements each can be removed without disrupting the supply of fuel gases entering the burner cone 410 through the other ports. Accordingly, the unit does not have to be completely shut down whenever periodic maintenance is required.

Referring now to FIG. 13, there is shown a flow diagram 500 of a preferred method in accordance with the invention. A quantity of municipal waste is pre¬ sorted at step 510 to remove most metals and other inorganic materials that wiU not be gassified by pyrolysis. The material next is moved through an incoming pit at step 515 to a shredder at step 520, which cuts the waste into portions of relatively uniform size. Next at step 525, the material is blended to make it of relatively uniform consistency and, at step 530, most of the moisture is removed from the material in a solar- or waste-heated dryer. The water vapor produced by the drying of the waste can be recycled as indicated by steps 535 and 540, through a solar condenser and then into a waste water treatment system. From the solar dryer, the waste is conveyed at step 545 to a storage bin at the treatment unit. At step 550, a conveyance arrangement such as a conveyor belt is used to take up waste from the storage bin and carry it to the input of the treatment unit, where at step 555, it is metered by the synchronized operation of valves onto the input end of the screw conveyor of the retort assembly in the pyrolytic converter. As the screw rotates, the

organic constituents of waste material being carried along through the retort is converted by pyrolysis to hydrocarbon gases at step 560. SoUd residue or ash remaining after pyrolysis is carried out of the retort and discharged at step 565 through an output assembly charaαerized by the same sort of synchronized valve operation as is the input assembly. The off-gases or vapor pyrosylate resulting from pyrolysis is conduαed from the retort through an afterburner at step 570, where it is retained in a chamber until thermal oxidation has eliminated the harmful components of the gas before any gases are vented to the atmosphere, or as is depiαed at step 575, before being routed to a waste heat boUer which, in turn, creates steam to supply a generator at step 580.

EXPOSITIVE EXAMPLE OF THE METHOD OF THE INVENTION The waste material to be processed by pyrolysis in this example is the sludge generated by the hot roU process used in the formation of steel plates. Oxidized metal flakes from the surface of the plates during manufacture, which is immersed in an oU bath composed of hydrocarbons and animal fats. Accordingly, the resultant sludge is extremely heavy, on the order of 196 pounds (lbs.) per cubic foot (3139 kg per cubic meter). The sludge typicaUy is composed of approximately seventy-five percent (75%) iron, of approximately twenty-four percent (24%) petroleum hydrocarbons and fatty acids, and a trace amount, on the order of one percent (1%), of metals.

To pre-treat the waste before it is introduced into a treatment unit of the invention, the sludge first is deposited on a vibrating screen which shakes out from the material rocks, shards of metals, and the like which are larger than about three- quarters of an inch ( 3 A n ) in diameter. The sorted material then is placed by means of a front-end loader into a blender that tends to equalize the consistency of the sludge. After the temperature of the retort has been brought up to a specified temperature, for example, 1250 °F (676.7 °C), the material is metered from the blender, in pre-determined amounts into the screw conveyor in the conveyance tube that feeds waste to the charging hopper of the input stage to the retort. From the

charging hopper, the material is fed through the synchronized valves to the screw conveyor disposed in the retort, which is energized by its variable speed motor at whatever rate of rotation has been set at the control panel, the rate having been calculated to achieve the most complete gassification of the organic components of the waste that is possible.

The solid residue or carbon ash is discharged through the output assembly of the retort and then either is aUowed to oxidize in air or is covered until it is cooled, when it is desirable to retain the residue in a non-oxidized state.

The gassified organic material is moved to the gas outlet at the output end of the retort due to positive pressure, and additional suαion is suppUed with an inductor fan at the output to insure that any flame from the burner cone supplying the thermal oxidizer wiU not enter the retort. The inductor fan also draws ambient air into the afterburner to sustain oxidation thus cleaning of the off-gases. The thermal oxidizer of the gas exhaust and cleaning arrangement normaUy is operated in the range of 1450 - 1500 °F (787.8-815.6 °C), when the starting waste material is known to be free of PCBs, dioxins, or furans. However, if the material contains any of those contaminants, the temperature of the thermal oxidizer should be raised to about 2250 °F (1232.2 °C), and the gases being treated should be retained in the oxidizer for at least two seconds. From the foregoing, it wiU be appreciated that the waste treatment system of the invention provides enhanced maintainabihty without any adverse effeα on the safety and efficiency with which it can be operated, thus improving the throughput and increasing the time period over which the system can funαion continuously.

While particular forms of the invention have been illustrated and described, it wiU be apparent to those of ordinary skiU in the an that other modifications can be made without departing from the spirit and scope of the invention. For example, the nature of the invention would aUow it to be adapted for processing materials other than that which can be properly charaαerized as waste. Accordingly, it is not intended that the invention be limited, except as by the appended claims.