Title:
RACEMOSELECTIVE PREPARATION OF BRIDGED METALLOCENE COMPLEXES HAVING UNSUBSTITUTED OR 2-SUBSTITUTED INDENYL LIGANDS
Document Type and Number:
WIPO Patent Application WO2004037834
Kind Code:
A3
Abstract:
The invention relates to a process for preparing racemic metallocene complexes by reacting transition metal complexes with cyclopentadienyl derivatives of alkali metals or alkaline earth metals and heating the reaction mixture obtained in this way to a temperature in the range from -78 to 250 DEG C, to the corresponding metallocene complexes themselves and to their use as catalysts or as constituents of catalysts for the polymerization of olefinically unsaturated compounds or as reagents or catalysts in stereoselective synthesis.
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Inventors:
DAMRAU HANS-ROBERT-HELLMUTH (DE)
MUELLER PATRIK (DE)
GARCIA VALERIE (FR)
SIDOT CHRISTIAN (FR)
TELLIER CHRISTIAN (FR)
LELONG JEAN-FRANCOIS (FR)
HURIEZ ERIC (FR)
MUELLER PATRIK (DE)
GARCIA VALERIE (FR)
SIDOT CHRISTIAN (FR)
TELLIER CHRISTIAN (FR)
LELONG JEAN-FRANCOIS (FR)
HURIEZ ERIC (FR)
Application Number:
PCT/EP2003/011678
Publication Date:
June 24, 2004
Filing Date:
October 22, 2003
Export Citation:
Assignee:
BASELL POLYOLEFINE GMBH (DE)
DAMRAU HANS-ROBERT-HELLMUTH (DE)
MUELLER PATRIK (DE)
GARCIA VALERIE (FR)
SIDOT CHRISTIAN (FR)
TELLIER CHRISTIAN (FR)
LELONG JEAN-FRANCOIS (FR)
HURIEZ ERIC (FR)
DAMRAU HANS-ROBERT-HELLMUTH (DE)
MUELLER PATRIK (DE)
GARCIA VALERIE (FR)
SIDOT CHRISTIAN (FR)
TELLIER CHRISTIAN (FR)
LELONG JEAN-FRANCOIS (FR)
HURIEZ ERIC (FR)
International Classes:
C07F17/00; C08F4/60; C08F4/64; C08F10/00; (IPC1-7): C08F4/60; C08F4/64; C07F17/00
Domestic Patent References:
| WO2002000672A1 | 2002-01-03 |
Foreign References:
| EP1275662A1 | 2003-01-15 | |||
| EP0997480A1 | 2000-05-03 |
Other References:
WARTCHOW, RUDOLF ET AL: "Synthesis and characterization of rac-[ethylene-1,2-bis(.eta.5-4,5,6,7- tetrahydro-1-indenyl)]zirconium bisamides (EBTHI)Zr(NHR)2", JOURNAL OF ORGANOMETALLIC CHEMISTRY (1998), 566(1-2), 287-291, XP004139820, ISSN: 0022-328X
BOCHMANN, MANFRED ET AL: "Base-free cationic zirconium benzyl complexes as highly active polymerization catalysts", ORGANOMETALLICS (1993), 12(3), 633-40, XP001165622, ISSN: 0276-7333
BOCHMANN, MANFRED ET AL: "Base-free cationic zirconium benzyl complexes as highly active polymerization catalysts", ORGANOMETALLICS (1993), 12(3), 633-40, XP001165622, ISSN: 0276-7333
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