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Title:
MAGNETOSTRICTIVE/PIEZO REMOTE POWER GENERATION, BATTERY AND METHOD
Document Type and Number:
WIPO Patent Application WO/2007/149516
Kind Code:
A3
Abstract:
A power generation device generates power by subjecting a composite of magnetostrictive material (12) and piezo material (14) to a magnetic field (H). The composite of magnetostrictive material (12) and piezo material (14) may be incorporated in a battery or other storage device.

Inventors:
CARROLL GARY T (US)
TUCKER RANDALL L (US)
Application Number:
US2007/014437
Publication Date:
November 20, 2008
Filing Date:
June 21, 2007
Export Citation:
Click for automatic bibliography generation   Help
Assignee:
COOPER TIRE & RUBBER CO. (701 Lima Avenue, Findlay, OH, 45840, US)
International Classes:
H01M14/00; H01L41/00; H01L41/08
Domestic Patent References:
WO2001091200A12001-11-29
Foreign References:
GB1339103A1973-11-28
US6809516B12004-10-26
US6807853B22004-10-26
US6437558B22002-08-20
US20080129147A12008-06-05
US20060255663A12006-11-16
Other References:
See also references of EP 2030282A2
Attorney, Agent or Firm:
PORCELLO, James, F. et al. (Emch, Schaffer Schaub & Porcello CO., L.P.A.,P.O.Box 91, Toledo OH, 43697-0916, US)
Download PDF:
Claims:

CLAIMS

We claim:

1. A battery comprising: a) a composite of (i) a magnetostrictive material and (ii) a piezo material which generates electricity when subjected to a pulsed or continuous magnetic field ; and b) a capacitor or ferro capacitor connected thereto.

2. A battery according to claim 1 wherein said piezo is lead zirconate titanate (PZT).

3. A battery according to claim 2 further including a voltage regulator positioned between said composite and said capacitor or ferro capacitor.

4. A battery according to claim 2 further including a flexible substrate supporting said composite and said capacitor or ferro capacitor. .

5. A battery according to claim 4 wherein said flexible substrate is formed from a material selected from the group consisting of polyester and polyimide.

6. A battery according to claim 3 further including a flexible substrate supporting said composite, said voltage regulator and said capacitor or ferro capacitor.

7. A battery according to claim 1 wherein said composite has been subjected to a magnetic field having a frequency within the range of 90% to 110% of the natural resonant frequency of the composite.

8. A multi-unit battery comprising a plurality of batteries according to claim 2 wired in parallel and mounted on a flexible substrate.

9. A multi-unit battery according to claim 8 wherein said flexible substrate with said plurality of batteries mounted therein is formed to a cylindrical shape.

10. A multi-unit battery according to claim 9 wherein said cylindrical shape has a first end and a second end and further including a pair of electrodes, one on said first end and the other on said second end.

11. A multi-unit battery according to claim 8 further including a voltage regulator positioned between said composite and said capacitor or ferro capacitor on at least some of said batteries.

12. A multi-unit battery according to claim 11 further including electrodes attached to one or more of said capacitors or ferro capacitors. .

13. A method for forming a battery comprising the steps of:

(a) providing a composite of (i) a magnetostrictive material and (ii) lead zirconate titanate (PZT) piezo material which generates electricity when subjected to magnetic field, said composite having a natural resonant frequency;

(b) connecting said composite to a capacitor or ferro capacitor; and

(c) subjecting said composite to a magnetic field having resonant frequency in the range of 90% to 110% of the natural resonant frequency of said composite.

14. The method according to claim 13 further including the step of positioning a voltage regulator between said composite and said capacitor or ferro capacitor.

15. The method according to claim 13 further including the step of mounting said composite and said capacitor or ferro capacitor on a flexible substrate.

16. The method according to claim 13 further including the step of mounting a plurality of said batteries on a flexible substrate and wiring at least some of said batteries in parallel with other of said batteries.

17. The method according to claim 16 further including the step of forming said flexible substrate with said plurality of batteries mounted thereon into one of a plurality of discrete shapes.

18. The method according to claim 17 wherein said plurality of discrete shapes includes cylindrical and further including the step of fastening electrodes to said discrete shape.

19. The method according to claim 13 further including the steps of creating said magnetic field by:

(a) providing a coil driver system having an oscillator, a divider, a nand gate, an inverter and a coil-capacitor having a first end and a second end;

(b) transmitting a signal from said oscillator at a first frequency to said divider, said divider reducing the frequency of said signal;

(c) transmitting said reduced frequency to said nand gate and to said inverter, said inverter creating two phases of said reduced frequency signal; (d) transmitting said phases to first and second drivers; and f

(e) transmitting said signal from said first driver to the first end of said coil-capacitor and from said second driver to the second end of said coil- capacitor.

20. A method of forming a battery comprising the steps of:

(a) forming a structure having (i) a composite of magnetostrictive material and piezo material, (ii) a first terminal at a first location, (iii) a second terminal at a second location, and (iv) a capacitor or ferro capacitor, said capacitor or ferro capacitor being positioned between said composite and (A) said first terminal or (B) said second terminal; and

(b) subjecting said structure to a pulsed or continuous magnetic field.

21. A method according to claim 20 wherein said piezo material is lead zirconate titanate (PZT).

22. The method according to claim 20 wherein said composite has a natural resonant frequency and further including the step of subjecting said composite to a magnetic field having a frequency in the range of 90% to 110% of the natural resonant frequency of said composite.

23. The method according to claim 20 further including the step of positioning a voltage regulator between said composite and said capacitor or ferro capacitor.

24. A battery comprising a structure having a first terminal and a second terminal and formed by the process of:

(a) positioning on said structure a composite of (i) a first material which stretches, flexes or is otherwise displaced when subjected to a magnetic field and (ii) a material which generates electricity when subjected to strain;

(b) positioning a voltage regulator in said enclosure between said composite and either said first terminal or said second terminal; and

(c) positioning a capacitor or ferro capacitor on the opposite side of said voltage regulator from said composite; and (d) subjecting said composite to a magnetic field.

25. The battery according to claim 24 wherein the process of forming includes the step of subjecting said composite to a pulsed or continuous magnetic field having a frequency in the range of 90 to 110% of the natural resonant frequency of the composite.

26. A battery according to claim 24 wherein said material which generates electricity is lead zirconate titanate (PZT).

27. A power generation system comprising a composite of: (a) a magnetostrictive material which stretches, flexes or is otherwise displaced when subjected to a magnetic field, and

(b) a second material which generates electricity when subjected to strain, said second material being joined to said magnetostrictive material and placed in strain thereby upon stretching, flexing or other displacement of said magnetostrictive material.

28. A power generation system according to claim 27 wherein said second material is a compound of lead, zirconate and titanate (PZT).

29. A combination of the power generation system according to claim 27 and a coil driver system for creating an electromagnetic field, said coil driver system including: an oscillator transmitting a signal at a first frequency to a divider, said divider reducing the frequency of said signal and transmitting said reduced frequency signal to a nand gate , gated with data to toggle the signal output from an on to off position and from an off to on position, and an inverter for creating two phases of said reduced frequency signal received from said nand gate and transmitting said phases, respectively, to first and second drivers, said first driver transmitting said reduced frequency signal to a

first end of a coil-capacitor and said second driver transmitting said reduced frequency signal to a second end of said coil-capacitor.

Description:

Magnetostrictive / Piezo Remote Power Generation, Battery and Method

CROSS REFERENCE TO RELATED APPLICATION

The present application is based upon and claims the benefit of U.S. Provisional Application Nos. 60/816,010 filed June 22, 2006, and 60/831 ,619 filed July 18, 2006.

BACKGROUND OF THE INVENTION

In the manufacture and use of RFID (Radio Frequency Identification) the technology is divided into two major groups; Passive Tags that gather their power from close coupling to a reader thus enabling them to transmit or reflect information back to the reader. The second group is Active Tags which have their own power storage capability like a battery, capacitor or other devices. The tag is queried with a RF signal generated by the reader requesting the tag to transmit the data, which is received by the reader. This Active tag has a limited life due to the storage device's limited shelf life. The magnetostrictive/piezo device of the present invention provides power to operate an attached electricaf device or to charge an electrical storage device that could be used by a multitude of sensors, receivers, transmitter or other electrical or electronic device. The new type of RFID using this power generating technology is hereinafter referred to as Network Powered Tag or NPRFID.

SUMMARY OF THE INVENTION

The present invention relates to a power generating device which is controlled from a natural or man-made pulsed or constant remotely operated magnetic or electromagnetic field, to a battery charged thereby and to a method for forming said battery. Magnetically affecting the magnetostrictive or similar material, causes a stretching, bending or displacement of a power producing crystal or material such as piezo which produces power each time a pulse of

magnetism is sensed. The new power generating device produces power from a PME (Passive Magnetostrictive Electro-Active) device or similar devices. A passive magnetic field sensor made of layers of Terfenol-D {Fe2(DyO.7TbO.3)> magnetostrictive material and ceramic PZT-5 will act as a generator to power electrical and electronic devices when in range of the querying transceiver magnetic field of (0.3 Oersted or larger). The magnetostrictive material or other material stretches, flexes or is physically distorted when in the presence of a magnetic field or pulsed magnetic field displaces the piezo type device attached thereto thereby, generating power for any electric or electronic device. Under a preferred embodiment, when the power is generated, it will be stored in a bank of ferroelectric capacitors, capacitors or a rechargeable battery type device. The battery could be a rolled-up sheet of up to a few thousand of ferroelectric capacitors, all hooked together in parallel. Building ferroelectric capacitors larger than a certain size has not heretofore been successful. Therefore, in order to create a large ferroelectric capacitor, large numbers of smaller capacitors are built and wired in parallel to equal one large capacitor. The process is similar to the manufacture of integrated circuits where layers of material are deposited on top of other material and then etch away that material that is not needed. By doing this, it is possible to make large capacitors on a sheet of polyester such as Mylar® or polyimide such as Kapton® which is then rolled up to make a package that can fit easily into a cylinder as used in normal battery packaging.

The PME power generator/battery will generate power with each pulse of a magnetic or electromagnetic field. Pulsing of the magnetic source will allow the device to charge up a battery or capacitor to a usable level of voltage or current. In order to obtain optimum power, the magnetic field should be generated at a frequency that matches the natural frequency of the magnetostrictive/piezo composite. Power close to optimum power can be obtained if the magnetic field is generated at a frequency in the range of 90% to 110% of the natural resonant frequency of such composite. Additionally, the new magnetostrictive/piezo device providing power to a battery, capacitor or other storage device could be

used in conjunction with a voltage regulator to provide a specific electrical voltage. The device could also function without the use of a regulator in some applications. This power generated would be encased in a typical or non-typical battery enclosure that could be used by all devices that utilize AAA, AA 1 C 1 D or other common battery forms. This new power generating battery would be called a NPB (Network Powered Battery). The battery could be powered by single or multiple magnetic generating devices. Additionally, a single magnetic generating device could power multiple NPBs. This new device could be configured to supply power to any number of battery powered devices and could also power and query a RFID tag at long distances.

The magnetic pulsed field could also be coded to provide instructions to the receiving device to turn-on, turn-off, or other specific task or operation such as store new data in memory, erase memory or go to sleep.

One preferred embodiment of the present invention can increase the capability over current battery technology by maintaining an ongoing charge to power the utilizing equipment, thereby providing a potentially infinite shelf life. This will have significant advantages in reliability of the utilizing equipment. The present invention could also provide a power source for medical, biomedical, night vision, GPS, radios, sensors, actuators and intelligence gathering technologies. The ability to transmit data to the battery can provide additional benefits such as power conservation, mode changes, data refresh and others.

Magnetostrictive Materials were discovered in the 1840s by James Prescott Joule, when he noticed that iron changed length in response to changes in magnetism and named the phenomenon the Joule Effect. How It Works:

Magnetostrictive materials expand when exposed to a magnetic field, exhibiting the Joule Effect or Magnetostriction. This occurs because magnetic domains in the material align with the magnetic field. Similarly, when the material is strained (stretched or compressed), its magnetic energy changes. This phenomenon is called magnetomechanical effect or Villari Effect.

Some examples of magnetostrictive materials:

* cobalt

* iron

* nickel

* ferrite

* terbium Alloys (Terfenol-D)

* Metglass

* Galfenol (Gallium and Iron)

Since magnetostriction involves a bi-directional energy exchange between magnetic and elastic states, magnetostrictive materials when put together with a piezo material, provide a mechanism to produce an AC voltage from an alternating electromagnetic field.

IN THE DRAWINGS

Fig. 1 is a schematic view showing the basic concept of magnetostrictive expansion. Fig. 2 is a perspective view of joined materials forming a composite of the present invention.

Fig. 3 is a schematic view showing the mechanism of magnetostriction. Fig. 4 is a wiring diagram showing prior art use of a coil for generating power. Fig. 5 is a wiring diagram showing generation of power by the magnetostricitve-piezo composite.

Fig. 6 is a diagram of a circuit that creates the electromagnetic field that can be modulated with commands and data.

Fig. 7 is a sectional view of one form of battery according to the present invention.

Figs. 8a and 8b are views of another embodiment of battery (Fig. 8a) and an array of such batteries mounted on a substrate (Fig. 8b).

DETAILED DESCRIPTION OF THE INVENTION

Figure 1 illustrates the Joule magnetostriction δL/L of a cylindrical sample 10, resulting from a magnetic field (H) being applied along the longitudinal axis X. The cylindrical sample 10 of magnetostrictive material is caused to stretch from a length L prior to application of a magnetic field to a length L + δL during application of a magnetic field.

Figure 2 illustrates a layer of magnetostrictive material 12 and a layer of piezoelectric material 14 bonded together forming a composite 20 of the magnetostrictive material and the piezo material. The composite, which could have a variety of configurations, is placed in a magnetic field H. When the magnetic field H is applied to the composite 20, the magnetostrictive material 12 stretches and thereby places a strain on the piezoelectric material 14 thus inducing a proportional voltage in the piezoelectric material 14. Depending on the configuration of the composite 20, the application of the magnetic field could cause the magnetostrictive material 12 to stretch, bend or be otherwise distorted.

Information regarding magnetoelectric laminate composites and magnetostrictive alloys may be found in Applied Physics Letter No. 87-222504 dated 28 November 2005 which is incorporated herein by reference.

Referring to Fig. 3, there is shown schematically a representation comparing (1) in the upper portion of Fig. 3, molecules M of the magnetostrictive material 12 positioned randomly when not subjected to a magnetic field H and (2), in the lower portion of Fig. 3, alignment of the molecules M when the magnetostrictive material 12 is subjected to a magnetic field H. As can be seen in Fig. 3, the length of the magnetostrictive material 12 increases as the molecules M align with the application of the magnetic field (H). The increase in length is designated by the letter e.

The mechanism of magnetostriction at an atomic level is relatively complex subject matter but on a macroscopic level may be segregated into two distinct processes. The first process is dominated by the migration of domain walls within the material in response to external magnetic fields. Second, is the

rotation of the domains. These two mechanisms allow the material to change the domain orientation which in turn causes a dimensional change. Since the deformation is isochoric, there is an opposite dimensional change in the orthogonal direction. Although there may be many mechanisms to the reorientation of the domains, the basic idea, represented in Fig. 3, remains that the rotation and movement of magnetic domains causes a physical length change in the material.

Fig. 4 is a wiring diagram showing the prior art use of a coil 16 for generating electricity. A typical prior art RFID device uses a coil-capacitor 16 to capture the electromagnetic field to power up the RFID device. This technique works well for ranges up to a meter. The electromagnetic field (H field) drops off at an exponential rate as the distance between the RFID device and the power source increases. Thus, the sensitivity of the coil-capacitor 16 cannot capture enough energy from a power source location beyond about one meter from the prior art RFID device and its coil capacitor 16.

Fig. 5 is a wiring diagram showing short-medium-long range powering by a magnetostrictive-piezo composite 20 as set forth in the present invention.

The present invention takes advantage of a highly efficient mechanism that creates electrical energy from a weak magnetic field. Due to the fact that the composite 20 is much more efficient than a coil capacitor, the composite 20 will operate at a much lower magnetic field thereby a longer range. Also, as the device that contains composite 20 is moved through the earth's magnetic field, a voltage will be generated. This will allow device to be recharged by simply moving it. A magnetostrictive-piezo device utilizing the composite 20 in a size of approximately one cm square can produce one volt per Oersted of magnetic field strength. (The earth's magnetic field is approximately one half Oersted.)

Referring to Fig. 6 there is shown a circuit that creates the electromagnetic field that can be modulated with commands and data. An oscillator 101 runs at a frequency 4.00 MHz. The oscillator 101 can also be the oscillator for the microprocessor (not shown). In most microprocessor designs, a crystal is used

to clock the microprocessor. The crystal used for the microprocessor can be shared for the coil drive 105 hereinafter described. The output of the oscillator 101 drives a counter/divider 102 that receives the 4.00 MHz signal and divides it by 32. The counter/divider 102 creates a 125 kHz square wave signal. If the microprocessor crystal was 8 MHz, it would be necessary to divide the frequency by 64 in order to obtain the required 125 kHz signal. A nand gate 103 is provided that can turn on and off the 125 kHz signal depending on the level of the data input. If the data input is a one, the 125 kHz will pass through. If the data input is a zero, the 125 kHz signal will be blocked and no signal will pass through to the inverter 104. The inverter 104 creates two phases of the 125 kHz signal to drive a coil-capacitor 106 from both ends. Two drives 105 that are heavy current devices are provided. They can drive the coil-capacitor 106 from both ends. By driving the coil-capacitor 106 this way with the heavy current drivers 105, less voltage is required from the power supply. If the coil were driven from a single side, the result would be one-half of what can be obtained by driving the coil- capacitor 106 on both sides. The end result is an electromagnetic field emanating from the coil-capacitor 106 and radiating into the area around the coil capacitor 106.

Referring to Fig. 7, there is shown a battery 30 formed according to the present invention. Although the battery 30 shown in Fig. 7 has an exterior shape of a typical flashlight, penlight, battery, for example, with a size of A 1 AA, AAA, C or D, such battery 30 could have a wide variety of shapes and constructions. All battery types could be a candidate for replacement with this type of device.

As shown in Fig. 7, there is provided a battery 30 or other storage device such as a ferro-capacitor device having a substantially cylindrical casing 32 with a positive terminal 34 at one end and a negative terminal 36 at the other end. A voltage regulator 38 is shown positioned slightly below the midpoint of the casing 32. The voltage regulator 38 could be one such as that sold by National Semiconductor, San Jose, California, as its item No. LM78L05. The upper area 39 between the voltage regulator 38 and the positive terminal 34 has positioned therein a capacitor or a ferro capacitor. Capacitors and ferro capacitors are well

known in the art of integrated circuits. Between the voltage regulator 38 and the negative terminal 36 are one or more magnetostrictive/piezo cells 20. If desired, the magnetostrictive/piezo cell composite could be positioned between the voltage regulator 38 and the positive terminal 34 and the PZT positioned between the voltage regulator 38 and the negative terminal. Additionally, for some applications where regulation of voltage is not a factor, the voltage regulator could be omitted.

Referring to Figs. 8a and 8b there is shown a modified embodiment of battery/capacitor 50 which is flat and could be quite small, for example, if rectangular in shape, as small as 100 millimeters long and 10 millimeters wide with a thickness in the range of 1/2 to 1 millimeters. A single modified battery/capacitor 50 is shown in Fig. 8a and includes a substrate of thin flexible plastic such as Mylar® or Kapton®, a first electrode 52, a second electrode 54 and a discrete unit of PZT 58. The first electrode 52 is mounted directly on the substrate 51. The discreet unit of PZT 58 is also positioned directly on the substrate 51 with the second electrode 54 being positioned on the discreet unit of PZT 58. A magnetostrictive/piezo cell 56 is spaced from the battery/capacitor 50 and is connected thereto through a voltage regulator 53 via wires 55 and 57. Referring to Fig. 8b, there is shown a multitude of modified batteries/capacitors 50 mounted on a flat sheet or substrate 60 of Mylar® or Kapton®. Although Fig. 8b shows 48 batteries/capacitors 50 mounted on the substrate 60, there could be hundreds or even more than a thousand batteries/capacitors 50 mounted on the substrate 60. The batteries/capacitors 50 could have a voltage on the order of 1.5 volts and generate amperage of Imilliamp each. Thus, assuming 100 batteries/capacitors 50 were mounted on the substrate 60 and wired in parallel, they could generate a current as high as 2 amps. A single magnetostrictive/piezo cell 56 can power many batteries/capacitors 50, possible as many as 10,000.

The substrate 60 of Mylar® or Kapton® should be thin enough so that the substrate 60 with the batteries 50 mounted thereon could be rolled into a

cylindrical form for convenience of usage. A thickness of 0.5 to 1 millimeters for the substrate 60 would be suitable.

One type of passive magnetic magnetostrictive electroactive device is a vibration energy harvester sold by Ferro Solutions, Inc., Cambridge, MA which is believed to incorporate features described in U.S. Patent No. 6,984,902. Other prior art includes U.S. Patent No. 6,725,713 which discloses the use of piezoelectric materials for generating power from a rotating tire.

Features of the magnetostrictive/piezo device and its use include: • The device generates electrical power with the use of magnetic fields

• The device uses magnetic or electromagnetic pulses to generate a pulse of electrical power. The magnetic source can be from a local or distant source. • Electrical power can be generated from the device by rotating the device in a magnetic field or within the earth's magnetic field. Power can also be generated by transmitting an electromagnetic field to the device at most frequencies but is most efficient at the resonant frequency of the device. • The electrical power voltage and current is proportional to the piezo or similar material.

• When the piezo is flexed, distorted or displaced by any material, specifically a magnetostrictive material, the piezo material will produce a voltage. • The device's power can be used as a one time pulse or accumulated in a battery or capacitor to attain larger voltages or current.

• The device could be utilized to power medical devices, sensors, transmitters and other small devices that require minimal or no maintenance or battery replacement.

• The device can be used to power RFID devices using remote magnetic field generation equipment.

• Data can be transmitted on the pulsed power sources carrier signal to the device to interrogate or direct the device to a response. This information could be EPC 1 SKU or other serial data.

• The device generates electrical power with the use of magnetic fields and stores the power in a bank of ferroelectric capacitors or a rechargeable battery. Electrical power can be generated from the device by rotating the device in a magnetic field or within the earth's magnetic field. Power can also be

generated by transmitting an electromagnetic field to the device at most frequencies but is most efficient at the resonant frequency of the composite 20. A magnetic field outside such resonant frequency will activate the magnetostrictive material but not as efficiently as if it were at the natural resonant frequency of the composite or in the range of 90% to

110% of such resonant frequency. Sending the magnetic field at the resonant frequency of the composite will allow the transfer of energy at a factor of 1Ox or more as compared to a non-resonant frequency.

• The electrical power voltage and current is proportional to the piezo or similar materials characteristics. As would be expected, a larger piece of piezo material will produce more energy than a smaller one.

• When the piezo is flexed, distorted or displaced by any material, specifically a magnetostrictive material, the piezo material will produce a voltage.

• The device's power can be accumulated in a battery or capacitor to attain larger voltages or current.

• The battery being charged could be a rolled up sheet of up to thousands of ferroelectric capacitor all hooked together in parallel.

The above detailed description of the present invention is given for explanatory purposes. It will be apparent to those skilled in the art that numerous changes and modifications can be made without departing from the scope of the invention. Accordingly, the whole of the foregoing description is to be construed in an illustrative and not a limitative sense, the scope of the invention being defined solely by the appended claims.