Title:
RUTHENIUM COMPLEX, METHOD FOR PRODUCING SAME, AND USE OF SAME
Document Type and Number:
WIPO Patent Application WO/2015/163440
Kind Code:
A1
Abstract:
The present invention provides a novel ruthenium complex that is easy to produce and handle and that can be supplied relatively inexpensively, a method for producing this ruthenium complex, a method for producing alcohols and the like using this ruthenium complex as a catalyst, a method for producing carbonyl compounds using this ruthenium complex as a catalyst, and a method for producing N-alkylamine compounds using this ruthenium complex as a catalyst. The present invention pertains to a ruthenium complex represented by general formula (1) RuX1X2(PNP)(NHC)m(Solv)n (1) (in general formula (1), X1 and X2 each independently represent a monovalent anionic monodentate ligand; PNP represents a tridentate aminodiphosphine ligand, NHC represents an N-heterocyclic carbene derived from a nitrogen-containing heterocyclic ring, and Solv represents a coordinating solvent; and m represents an integer from 1 to 3, n represents an integer from 0 to 2, and 1 ≦ m + n ≦ 3.), a method for producing the same, a catalyst comprising the same, and methods for producing various organic compounds using this catalyst.
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Inventors:
OGATA OSAMU (JP)
NARA HIDEKI (JP)
NAKAYAMA YUJI (JP)
NARA HIDEKI (JP)
NAKAYAMA YUJI (JP)
Application Number:
PCT/JP2015/062492
Publication Date:
October 29, 2015
Filing Date:
April 24, 2015
Export Citation:
Assignee:
TAKASAGO PERFUMERY CO LTD (JP)
International Classes:
C07F19/00; B01J31/22; B01J31/24; C07C29/132; C07C29/141; C07C29/145; C07C29/149; C07C31/20; C07C33/22; C07C45/29; C07C49/78; C07C209/18; C07C211/48; C07D213/30; C07F9/50; C07F15/00; C07B61/00
Domestic Patent References:
| WO2011048727A1 | 2011-04-28 |
Foreign References:
| JP2010527316A | 2010-08-12 |
Other References:
DEMOTT, JESSICA C. ET AL.: "Frustrated Lewis pair-like splitting of aromatic C-H bonds and abstraction of halogen atoms by a cationic [(FPNP)Pt]+ species", CHEMICAL SCIENCE, vol. 4, no. 2, 2013, pages 642 - 649, XP055233304
PRECHTL, MARTIN H. G. ET AL.: "Ruthenium dihydrogen complex for C-H activation: catalytic H/D exchange under mild conditions", EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, pages 3493 - 3500, XP055030428
BIANCHINI, CLAUDIO ET AL.: "Concomitant coordination of vinylidene and carbene ligands made possible at ruthenium(II", INORGANICA CHIMICA ACTA, vol. 272, no. 1,2, 1998, pages 1 - 3, XP055233309
GREGOR, LAUREN C. ET AL.: "Heterolytic splitting of H-X bonds at a cationic (PNP)Pd center", DALTON TRANSACTIONS, vol. 39, no. 13, 2010, pages 3195 - 3202, XP055233313
BIANCHINI, CLAUDIO ET AL.: "A novel reaction of coordinated vinylidenes: coupling with hydrogen sulfide to give a eta1-thioaldehyde", JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS, 1994, pages 2219 - 20, XP055233318
See also references of EP 3135681A4
PRECHTL, MARTIN H. G. ET AL.: "Ruthenium dihydrogen complex for C-H activation: catalytic H/D exchange under mild conditions", EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, pages 3493 - 3500, XP055030428
BIANCHINI, CLAUDIO ET AL.: "Concomitant coordination of vinylidene and carbene ligands made possible at ruthenium(II", INORGANICA CHIMICA ACTA, vol. 272, no. 1,2, 1998, pages 1 - 3, XP055233309
GREGOR, LAUREN C. ET AL.: "Heterolytic splitting of H-X bonds at a cationic (PNP)Pd center", DALTON TRANSACTIONS, vol. 39, no. 13, 2010, pages 3195 - 3202, XP055233313
BIANCHINI, CLAUDIO ET AL.: "A novel reaction of coordinated vinylidenes: coupling with hydrogen sulfide to give a eta1-thioaldehyde", JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS, 1994, pages 2219 - 20, XP055233318
See also references of EP 3135681A4
Attorney, Agent or Firm:
SAEKI, Norio et al. (JP)
Norio Saeki (JP)
Norio Saeki (JP)
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