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Title:
SOLAR WATER DISINFECTION
Document Type and Number:
WIPO Patent Application WO/2023/174912
Kind Code:
A1
Abstract:
A plastic container for solar water disinfection having a stiffness to preserve its shape in both empty state and in water-filled state, said container having an opening (110) for receiving water to be disinfected (120) where said opening can subsequently be closed and reopened, said container having at least 20% of its surface area available for UV radiation from incident sunlight and said container being made substantially of a UV transparent plastic material having a transmittance of UV-A radiation (400nm to 315nm) of at least 50% and a transmittance of UV-B radiation (310nm to 290nm) of at least 33%, and said UV transparent plastic material being sufficiently stable to UV radiation to enable the container to have an outdoor in-use period corresponding to a Kly of at least 300 GJ/m2.

Inventors:
LØCKE ALEXANDER (DK)
Application Number:
PCT/EP2023/056427
Publication Date:
September 21, 2023
Filing Date:
March 14, 2023
Export Citation:
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Assignee:
4LIFE SOLUTIONS APS (DK)
International Classes:
C02F1/32; B01D1/00; C02F1/14
Domestic Patent References:
WO2006059948A12006-06-08
WO2021148542A12021-07-29
WO2021018653A12021-02-04
Foreign References:
ITMI20091311A12011-01-24
US20110011808A12011-01-20
GB2040436A1980-08-28
Other References:
POLO-LÓPEZ M. INMACULADA ET AL: "Microbiological Evaluation of 5 L- and 20 L-Transparent Polypropylene Buckets for Solar Water Disinfection (SODIS)", MOLECULES, vol. 24, no. 11, 11 June 2019 (2019-06-11), pages 2193, XP093038968, DOI: 10.3390/molecules24112193
GARCÍA-GIL ÁNGELA ET AL: "Weathering of plastic SODIS containers and the impact of ageing on their lifetime and disinfection efficacy", CHEMICAL ENGENEERING JOURNAL, ELSEVIER, AMSTERDAM, NL, vol. 435, 26 January 2022 (2022-01-26), XP086965907, ISSN: 1385-8947, [retrieved on 20220126], DOI: 10.1016/J.CEJ.2022.134881
PANIWATER: "PANIWATER: project overview", 27 March 2020 (2020-03-27), XP093039098, Retrieved from the Internet [retrieved on 20230413]
TOTALENERGIES: "Polypropylene for extrusion blow moulding (EBM) and injection stretch blow moulding (ISBM)", 31 October 2007 (2007-10-31), pages 1 - 2, XP093039112, Retrieved from the Internet [retrieved on 20230414]
OZORES ET AL., WATER RESEARCH, vol. 186, 2020, pages 116387
GARCIA-GIL ET AL., MOLECULES, vol. 26, 2021, pages 3431
Attorney, Agent or Firm:
ZACCO DENMARK A/S (DK)
Download PDF:
Claims:
Claims

1. A plastic container for solar water disinfection (100) having a stiffness to preserve its shape in both empty state and in water-filled state, said container having an opening (110) for receiving water to be disinfected (120) where said opening can subsequently be closed and reopened, said container having at least 20% of its surface area available for UV radiation from incident sunlight and said container being made substantially of a UV transparent plastic material having a transmittance of UV-A radiation (400nm to 315nm) of at least 50% and a transmittance of UV- B radiation (310nm to 290nm) of at least 33%, and said UV transparent plastic material being sufficiently stable to UV radiation to enable the container to have an outdoor in-use period corresponding to a Kly of at least 300 GJ/m2.

2. The plastic container for solar water disinfection according to claim 1, wherein said plastic container is made substantially of polypropylene comprising at least one stabilizer.

3. The plastic container for solar water disinfection according to claim 2, wherein said at least one stabilizer comprises an antioxidant.

4. The plastic container for solar water disinfection according to claim 2, wherein said at least one stabilizer comprises a hindered amine light stabilizer (HAUS).

5. The plastic container for solar water disinfection according to any of the preceding claims, having a box-like shape, e.g. having distinct substantially flat surfaces (130, 131) connected by bends (140), said bends having a length of less than 15% of the length or width of any of said surfaces.

6. The plastic container for solar water disinfection according to any of the preceding claims, having two substantially flat opposing surfaces (130, 131), each of said two substantially flat opposing surfaces having an area of at least 20% of the total area of said plastic container.

7. The plastic container for solar water disinfection according to any of the preceding claims, having a height (H) larger than the width (W), and said width (W) larger than the depth (D), wherein the width (W) to depth (D) ratio is at least 1.5, such as at least 2.0, such as in the range from 1.5 to 3.0, such as in the range from 2.0 to 2.6.

8. The plastic container for solar water disinfection according to any of the preceding claims, having a height (H) larger than the width (W), and said width (W) larger than the depth (D), wherein the height (H) to width (W) ratio is in the range from 1.0 to 3.0, from 1.0 to 1.8, from 1.15 to 1.5, or from 1.2 to 1.4.

9. The plastic container for solar water disinfection according to any of claims 6-8, having a depth (D) in the range from about 5 cm to about 15 cm, in the range from about 7cm to about 12cm, or about 9cm.

10. The plastic container for solar water disinfection according to any of the preceding claims, wherein one surface (131) is being transparent to UV light, and the opposite surface (130) being reflective to incident UV light, e.g. by a label or coating on the outside of the container surface.

11. The plastic container for solar water disinfection according to any of the preceding claims, having at least 3 indentations (170) on a first surface (130) spanning the height-width plane which matches the same number of protrusions (180) on an opposing surface (131) also spanning the height-width plane.

12. The plastic container for solar water disinfection according to any of the preceding claims, configured with a label on the surface having the indentations indicating the surface upon which the container rests while the surface with the protrusions face the sun during disinfection of the water.

13. The plastic container for solar water disinfection according to any of the preceding claims, wherein said container has an average thickness of the UV transparent plastic material in the range from about 0.7 mm to about 2.0 mm.

14. The plastic container for solar water disinfection according to any of the preceding claims, which is manufactured by extrusion blow molding.

15. The plastic container for solar water disinfection according to any of the preceding claims, comprising an electronic device (200) configured to receive incident light and to provide an indication of the disinfection status.

16. Use of the plastic container as defined in any of claims 1-15 for solar disinfection of water.

Description:
Solar water disinfection

Technical field of the invention

The present invention relates to the field of water, specifically to the field of drinking water and the disinfection of water.

Background of the invention

Access to safe, potable water is widely recognized as a basic human right through a number of international treaties, providing a non-binding interpretation that access to water entitles every human to sufficient, safe, acceptable, physically accessible and affordable water for personal and domestic uses. Specifically, and as set forth by the World Health Organization, this basic access to water requires availability of a fresh water source that is at most 1000 meters or 20 minutes away and which affords the possibility of reliably obtaining at least 20 liters per day per family member.

A closely related basic human right is the access to hygienic sanitation, since the lack of sanitation near fresh water bodies reduces the quality of water downstream. However, in the past decade experts at the United Nations have expressed concern that absence of clean water or sanitation still exacts a human toll for almost a billion people suffering from lack of access to improved water sources, particularly with an estimated 1.5 million children under the age of five dying each year and 443 million school days lost because of water- and sanitation-related diseases.

The lack of proper water and sanitation infrastructure in developing countries makes providing safe drinking water to an entire population very challenging, especially in poor or sparsely populated areas. Centralization of drinking water supplies has the disadvantage of requiring the users to travel to and from remote dispensing stations, with some having to carry water many kilometers each day, and further increasing the risks of waterborne infectious diseases polluting the otherwise accessible water sources, thereby requiring additional infrastructure to treat the water before use. It is also evident that resorting to bottled water is not the solution, as it is cumbersome and expensive for the required amounts of water.

Ozores et al (Water Research, 186, 2020, 116387) assesses the use of 19 liters polycarbonate and 25 liters polyethylene terephthalate bottles for solar disinfection of water.

WO2021/148542 discloses a system for solar disinfection of water comprising a container and an electronic device indicating the status of the disinfection.

Garcia-Gil et al (Molecules, 26, 2021, 3431) reviews solar water disinfection and concludes on some of the factors limiting the use of solar disinfection, e.g. limited effectiveness of disinfection, cost restraints and the users overestimation of the required solar exposure time. ' WO 2021/018653 discloses water disinfection containers made up of fluoropolymer as the best choice for solar water disinfection.

Hence, there is a need for technical solutions for effectively guarding against waterborne infectious diseases in the drinking water supply, e.g. by offering cheap, safe, easy to use and decentralized alternatives.

Summary of the invention

It is an object of the present invention to provide a container for solar water disinfection which has the properties of being practical for handling, effective for UV disinfection of water inside the container, stable for prolonged use under exposure to sunlight, compatible with contact to drinking water and importantly, being very cost effective.

In a first aspect the present invention provides a plastic container for solar water disinfection (100) having a stiffness to preserve its shape in both empty state and in water-filled state, said container having an opening (110) for receiving water to be disinfected (120) where said opening can subsequently be closed and reopened, said container having at least 20% of its surface area available for UV radiation from incident sunlight and said container being made substantially of a UV transparent plastic material having a transmittance of UV-A radiation (400nm to 315nm) of at least 50% and a transmittance of UV-B radiation (310nm to 290nm) of at least 33%, and said UV transparent plastic material being sufficiently stable to UV radiation to enable the container to have an outdoor in-use period corresponding to a Kly of at least 300 GJ/m 2 .

In one embodiment the UV transparent plastic material is substantially made from polypropylene comprising at least one stabilizer.

In a second aspect the present invention provides a use of the plastic container as defined above for solar disinfection of water.

In an embodiment the use of the plastic container as defined herein for solar water disinfection comprises filling said plastic container with water to be disinfected and placing said plastic container outdoor in the sun for at least 4 hours or until said electronic device indicates that the water has been disinfected.

The present invention is further defined by the following items:

1. A plastic container for solar water disinfection (100) having a stiffness to preserve its shape in both empty state and in water-filled state, said container having an opening (110) for receiving water to be disinfected (120) where said opening can subsequently be closed and reopened, said container having at least 20% of its surface area available for UV radiation from incident sunlight and said container being made substantially of a UV transparent plastic material having a transmittance of UV-A radiation (400nm to 315nm) of at least 50% and a transmittance of UV- B radiation (310nm to 290nm) of at least 33%, and said UV transparent plastic material being sufficiently stable to UV radiation to enable the container to have an outdoor in-use period corresponding to a Kly of at least 300 GJ/m 2 .

2. The plastic container for solar water disinfection according to item 1, wherein said plastic container is made substantially of polypropylene comprising at least one stabilizer.

3. The plastic container for solar water disinfection according to item 2, wherein said at least one stabilizer comprises an antioxidant.

4. The plastic container for solar water disinfection according to item 2, wherein said at least one stabilizer comprises a hindered amine light stabilizer (HALS). 5. The plastic container for solar water disinfection according to any of the preceding items, having a box-like shape, e.g. having distinct substantially flat surfaces (130, 131) connected by bends (140), said bends having a length of less than 15% of the length or width of any of said surfaces.

6. The plastic container for solar water disinfection according to any of the preceding items, having two substantially flat opposing surfaces (130, 131), each of said two substantially flat opposing surfaces having an area of at least 20% of the total area of said plastic container.

7. The plastic container for solar water disinfection according to any of the preceding items, having a height (H) larger than the width (W), and said width (W) larger than the depth (D), wherein the width (W) to depth (D) ratio is at least 1.5, such as at least 2.0, such as in the range from 1.5 to 3.0, such as in the range from 2.0 to 2.6.

8. The plastic container for solar water disinfection according to any of the preceding items, having a height (H) larger than the width (W), and said width (W) larger than the depth (D), wherein the height (H) to width (W) ratio is in the range from 1.0 to 3.0, from 1.0 to 1.8, from 1.15 to 1.5, or from 1.2 to 1.4.

9. The plastic container for solar water disinfection according to any of items 6-8, having a depth (D) in the range from about 5cm to about 15cm, in the range from about 7cm to about 12cm, or about 9cm.

10. The plastic container for solar water disinfection according to any of the preceding items, which has a volume of about 2L to about 30L, from about 2L to about 20L, from about 2L to about 10L, from about 2L to about 8L, from about 4L to about 10L, from about 6L to about 25L, or from about 6L to about 15L.

11. The plastic container for solar water disinfection according to any of the preceding items, wherein one surface (131) is being transparent to UV light, and the opposite surface (130) being reflective to incident UV light, e.g. by a label or coating on the outside of the container surface.

12. The plastic container for solar water disinfection according to any of the preceding items, having at least 3 indentations (170) on a first surface (130) spanning the height-width plane which matches the same number of protrusions (180) on an opposing surface (131) also spanning the height-width plane.

13. The plastic container for solar water disinfection according to any of the preceding items, configured with a label on the surface having the indentations indicating the surface upon which the container rests while the surface with the protrusions face the sun during disinfection of the water.

14. The plastic container for solar water disinfection according to any of the preceding items, wherein said container has an average thickness of the UV transparent plastic material in the range from about 0.7 mm to about 2.0 mm.

15. The plastic container for solar water disinfection according to any of the preceding items, wherein said container is made substantially from polypropylene comprising at least 90% polypropylene, at least 95% polypropylene, at least 98% polypropylene or at least 99% polypropylene.

16. The plastic container for solar water disinfection according to any of the preceding items, which is manufactured by blow molding.

17. The plastic container for solar water disinfection according to any of the preceding items, which is manufactured by extrusion blow molding.

18. The plastic container for solar water disinfection according to any of the preceding items, comprising an electronic device (200) configured to receive incident light and to provide an indication of the disinfection status.

19. Use of the plastic container as defined in any of items 1-18 for solar disinfection of water.

Brief description of the drawings

Figure 1 A-C. An embodiment of the plastic container for solar water disinfection depicted from different directions, said embodiment having matching indentations and protrusions.

Figure 2. An embodiment of the plastic container for solar water disinfection having an electronic device (200) to provide an indication of when the water in the container has been disinfected.

Figure 3A-B. An embodiment of the plastic container for solar water disinfection depicted from different directions.

Figure 4. Solar radiation (Kly) per year in different geographical locations. Description

The present invention provides a plastic container for solar water disinfection (100) having a stiffness to preserve its shape in both empty state and in water-filled state, said container having an opening (110) for receiving water to be disinfected (120) where said opening can subsequently be closed and reopened, said container having at least 20% of its surface area available for UV radiation from incident sunlight and said container being made substantially of a UV transparent plastic material having a transmittance of UV-A radiation (400nm to 315nm) of at least 50% and a transmittance of UV-B radiation (310nm to 290nm) of at least 33%, and said UV transparent plastic material being sufficiently stable to UV radiation to enable the container to have an outdoor in-use period corresponding to a Kly of at least 300 GJ/m 2 .

The disinfection of water borne pests includes the inactivation of bacteria, protozoa and virusses in the water. This may be achieved by UV radiation, in particular by UV-B radiation which penetrates the water wherein the water borne pests and pathogens may reside.

The term “UV transparency” of a plastic as used in the present context is intended to mean a plastic having a transmittance of UV-A radiation (400nm to 315nm) of at least 50% and a transmittance of UV-B radiation (310nm to 290nm) of at least 33%. Here it is to be understood that the %transmittance is the average for the different wavelengths of the respective radiation, e.g. for UV-A radiation the average is over the span of 400nm to 315nm.

In an embodiment the plastic container has a transmittance of UV-A radiation of at least 50% and a transmittance of UV-B radiation of at least 40%.

The solar radiation energy is usually expressed in Kly (Kilolangley) units (GJ/m 2 ). Plastic containers with a Kly value of 400 can resist the harmful effects of UV radiation for a minimum of about 4 to 5 years in normal sunny climate areas, and about 2 years in the most sunny parts of earth. Figure 4 depicts a map of the globe with an indication of the amount of Kly/year, e.g. central parts of Africa has 200 Kly per year. In a further embodiment at least 30% of the container is available for and transparent to UV radiation from incident sunlight.

In a preferred embodiment the UV transparent plastic material is substantially made from polypropylene comprising at least one stabilizer.

In another embodiment the UV transparent plastic material comprises at least 90% polypropylene, at least 95% polypropylene, at least 98% polypropylene or at least 99% polypropylene.

The opening (110) of the container may be furnished with a screw cap or a tap such that the container can be opened when filling water to be disinfected (120) into the container (100), and when upon being disinfected by exposure to incident sunlight using the disinfected water from the container.

In a preferred embodiment the plastic container (100) is substantially made from polypropylene. This satisfies the object of being made from a very low cost material which is transparent and allows UV radiation to penetrate into the contents, i.e. the water to be disinfected. Furthermore, polypropylene has a sufficient toughness, tensile strength and stiffness for a plastic container which is to be used multiple times under rugged conditions. However, polypropylene is among the plastics which are poorly photostable, i.e. having a limited lifetime when exposed to sunlight. Adding UV blockers is not desirable here since UV radiation must be transmitted through the container during the solar disinfection. In an embodiment, the polypropylene in the plastic container therefore comprises at least one stabilizer.

In one embodiment the plastic container for solar water disinfection comprises at least one stabilizer comprising an antioxidant. Such an antioxidant is preferably classified as compatible with plastics for use in direct contact with drinking water. Non-limiting examples of antioxidants for plastics are Tetrakis (methylene-3-(3,5-di-tert-butyl-4-hydroxyphenyl-propionate)) methane) and distearyl thiodipropionate. In another embodiment the plastic container for solar water disinfection contains at least one stabilizer comprising a hindered amine light stabilizer (HALS). HALS compounds are derivatives of 2,2,6,6-tetramethylpiperidine and contain an amine functional group that are used as stabilizers in plastics and polymers. HALS are efficient scavengers and function by inhibiting degradation of polymers that have already formed free radicals, they do not absorb UV radiation but act to inhibit degradation of the plastic. They slow down the photochemically initiated degradation reactions, to some extent in a similar way to antioxidants. The difference in mechanism between antioxidant and HALS is that HALS reaction is cyclic while antioxidant is not.

Other options for light stabilizer than HALS are benzophenones and benzotriazoles.

Without wishing to be bound by theory it is believed that the geometry of the plastic container for solar water disinfection is important for optimal performance. As the water used for disinfection may not be entirely clear, e.g. because of suspended impurities such as fine clay particles and organic matter, the plastic container preferably has at least one dimension where the depth through the container is no more than about 8-11 cm.

In an embodiment the plastic container for solar water disinfection has a box-like shape, e.g. having distinct substantially flat surfaces (130, 131) connected by bends (140), said bends having a length of less than 15% of the length or width of any of said surfaces.

In another embodiment the plastic container for solar water disinfection has two substantially flat opposing surfaces (130, 131), each of said two substantially flat opposing surfaces having an area of at least 20% of the total area of said plastic container.

In another embodiment the plastic container for solar water disinfection has a height (H) larger than the width (W), and said width (W) larger than the depth (D), wherein the width (W) to depth (D) ratio is at least 1.5, such as at least 2.0, such as in the range from 1.5 to 3.0, such as in the range from 2.0 to 2.6. In another embodiment the plastic container for solar water disinfection has a height (H) larger than the width (W), and said width (W) larger than the depth (D), wherein the height (H) to width (W) ratio is in the range from 1.0 to 3.0, from 1.0 to 1.8, from 1.15 to 1.5, or from 1.2 to 1.4.

In another embodiment the plastic container for solar water disinfection has a depth (D) in the range from about 5cm to about 15cm, in the range from about 7cm to about 12cm, or about 9cm.

In another embodiment the plastic container for solar water disinfection has a volume of about 2L to about 30L, from about 2L to about 20L, from about 2L to about 10L, from about 2L to about 8L, from about 4L to about 10L, from about 6L to about 25L, or from about 6L to about 15L. In a preferred embodiment the plastic container for solar water disinfection has a volume in the range from about 4L to about 10L.

In another embodiment the plastic container for solar water disinfection has a visual path through the container having a length of from about 20 cm to about 24 cm for visual inspection of the water being clear enough for being suitable for solar disinfection, e.g. by looking from one end of said visual path towards a finger at the other end of said visual path.

For the practical use of the in the plastic container once it has been disinfected by exposure to incident sunlight it may be practical to have the container lying on a flat surface or hanging. Hence, in another embodiment the plastic container for solar water disinfection is configured for being able to be hanging on a hook or from a rope. This may be configured via the handle (190). In another embodiment the plastic container for solar water disinfection has a furnishing (150) for hanging said container on a hook or from a rope. In yet another embodiment the plastic container for solar water disinfection has a furnishing (150) for hanging said container on a hook or from a rope which is at an opposite face to the opening (110) of the container.

In another embodiment the plastic container for solar water disinfection comprises one surface (131) being transparent to UV light, and the opposite surface (130) being reflective to incident UV light, e.g. by a label or coating on the outside of the container surface. During the disinfection of water it is intended that the plastic container rests on the surface (130) and the opposite surface (131) faces the incident sunlight whereby UV radiation entering through surface (131) and passes through the water inside the container is partially or fully reflected by the opposite surface (130).

Transportation of the plastic containers for solar water disinfection is likely done both as empty containers and as water-filled containers. In an embodiment the plastic container for solar water disinfection has at least 3 indentations (170) on a first surface (130) spanning the height- width plane which matches the same number of protrusions (180) on an opposing surface (131) also spanning the height-width plane. These matching indentations and protrusions facilitates the stacking of plastic containers during storage and transportation.

In an embodiment the plastic container for solar water disinfection has 4, 5 or 6 sets of matching protrusions/indentations.

In another embodiment the plastic container for solar water disinfection is configured with a label on the surface having the indentations indicating the surface upon which the container rests while the surface with the protrusions face the sun during disinfection of the water. In a further embodiment this label is reflective to UV light.

Plastic containers may be manufactured by several processes commonly used in the plastics manufacturing industry. In one embodiment the plastic container for solar water disinfection is blow molded. In another embodiment the plastic container for solar water disinfection is extrusion blow molded.

As a consequence of the manufacturing process used for making the plastic containers, they may have a material thickness having some variation over the surface. Generally it is desirable to seek to obtain a uniform material thickness such that mechanical properties and UV transmittance is substantially the same over the whole surface of the plastic container. In an embodiment the plastic container for solar water disinfection comprises different parts of the surface of said container that has a polypropylene material thickness in the range from about 0.3 mm to about 3.0 mm. In another embodiment the container has an average thickness of the polypropylene material in the range from about 0.7 mm to about 2.0 mm. In yet another embodiment the container has a polypropylene material thickness wherein the thickest area of 1 cm 2 has less than 5 times the thickness of the thinnest area of 1 cm 2 .

The plastic container for solar water disinfection may further comprise an electronic device (190) configured to receive incident light and to provide an indication of the disinfection status. In an embodiment the electronic device comprises a photovoltaic component and a processor. The electronic device is placed in connection with the plastic container to receive incident sunlight, just as the remaining parts of the container. In another embodiment the electronic device further comprises a sensor for the temperature of the water inside the container.

In a further embodiment the plastic container for solar water disinfection comprises an electronic device additionally comprising a temperature sensor such that said processor determines the level of disinfection from the temperature and the dose of UV light transmitted through the container based on the photovoltaic output.

In another embodiment, a dose equivalent of UV light transmitted through at least part of the container being UV transparent may be determined based on the photovoltaic output indicative of a visible light intensity at the photovoltaic component using a predetermined constant of proportionality between the photovoltaic output and the corresponding dose equivalent of UV light. A constant of proportionality may for example be determined by calibration of the photovoltaic output against a reference measurement, such as a reference measurement obtained by a UV light intensity sensor, for example such as a UV light intensity calibration sensor, such as a UV light intensity sensor provided by a meteorological institute, atmospheric laboratory or the like.

The electronic device comprises the processor. The processor, being connected to the photovoltaic component and optionally the temperature sensor either through the electronic circuit or similar means of analogue or digital data exchange, is configured to receive the photovoltaic output and optionally the temperature signal, whereby a set of instructions can be provided which, when executed by the processor, allows the electronic device to determining the rate at which waterborne pathogens can be killed or made inactive inside the container during the treatment. Further, instead of or in addition to determining an instantaneous pathogen kill rate, the instructions may allow the processor to determine a water disinfection state by calculating a cumulative effect on the initial pathogen population in the water to be purified by numerical modelling. The water disinfection state may indicate the level of disinfection of the water in the container.

By configuring an electronic device to determine a water disinfection state, the water purification system may provide the advantage of making batch processing of multiple containers more feasible by relying on one or more containers with electronic devices to determine the water disinfection state and. e.g. provide an indication of the point in time when estimated 99.9% of pathogens have been killed in the water in each container. Examples of suitable electronic devices may be found in e.g. WO2021/148542.

In a further aspect the present invention provides the use of the plastic container as defined above for solar disinfection of water. In an embodiment the use of the plastic containers for solar disinfection of water comprises filling said plastic container with water to be purified and placing said plastic container outdoor in the sun for at least 4 hours or until said electronic device indicates that the water has been disinfected.

The filled containers are preferably placed on a support surface receiving incident sunlight, preferably such that the orientation of the container towards the sun exposes a maximal surface area to the incident sunlight. In particular, the container may be positioned on the support surface such that at least the UV transparent part of the container is exposed to the incident sunlight.

The incident UV light may provide that the water inside the filled container receives an accumulating dose of UV light through the UV-transparent part of the container. Exposing the water to be disinfection to UV light while inside the container is advantageous because waterborne pathogens can be killed or made inactive while preventing recontamination. Placing the filled container in incident sunlight may further provide a heating effect on the water to be disinfected, which provides an elevated water temperature relative to the ambient temperature of the environment. Further, the heating effect may assist in ensuring a uniform reduction of the pathogen population by promoting convection in the water as warmer water rises and cooler water descends, effectively mixing the water inside the container. The mixing effect may provide the advantage that no part of the water is left untreated. Particularly, this mixing is also advantageous if the water is turbid.

In a further embodiment the use of the plastic container for solar water disinfection comprises the steps of filling said plastic container with water to be disinfected and placing said plastic container outdoor in the sun for at least 4 hours or until said electronic device indicates that the water has been disinfected.

Description of Examples

Various examples are described hereinafter with reference to the figures. Like reference numerals refer to like elements throughout. Thus, like elements will not be described in detail with respect to the description of each figure. It should also be noted that the figures are only intended to facilitate the description of the examples. They are not intended as an exhaustive description of the claimed invention or as a limitation on the scope of the claimed invention. In addition, an illustrated example needs not have all the aspects or advantages shown. An aspect or an advantage described in conjunction with a particular example is not necessarily limited to that example and can be practiced in any other examples even if not so illustrated, or if not so explicitly described.

The present examples may have different forms and should not be construed as being limited to the descriptions set forth herein. Accordingly, the examples are merely described below, by referring to the figures, to explain aspects. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items. Expressions such as "at least one of," when preceding a list of elements, modify the entire list of elements and do not modify the individual elements of the list. The spatially relative terms “lower” or “bottom” and “upper” or “top”, "below", "beneath", "less", "above", and the like, may be used herein for ease of description to describe the relationship between one element or component and another element or component as illustrated in the drawings. It will be understood that the spatially relative terms are intended to encompass different orientations of the device in use or operation, in addition to the orientation depicted in the drawings.

For example, in the case where a container illustrated in the drawings is turned over, elements described as being on the “lower” side of other elements, or "below" or "beneath" another element would then be oriented on “upper” sides of the other elements, or "above" another element. Accordingly, the illustrative term "below" or “beneath” may include both the “lower” and “upper” orientation positions, depending on the particular orientation of the figure. Similarly, if the device in one of the figures is turned over, elements described as “below” or “beneath” other elements would then be oriented ’’above” the other elements. The exemplary terms “below” or “beneath” can, therefore, encompass both an orientation of above and below, and thus the spatially relative terms may be interpreted differently depending on the orientations described.

Throughout the specification, when an element is referred to as being “connected” to another element, the element is “directly connected” to the other element, or “electrically connected” to the other element with one or more intervening elements interposed there between.

The terminology used herein is for the purpose of describing particular examples only and is not intended to be limiting. As used herein, the singular forms “a,” “an,” and “the” are intended to include the plural forms, including “at least one,” unless the content clearly indicates otherwise. “At least one” is not to be construed as limiting “a” or “an.” It will be further understood that the terms “comprises," "comprising," "includes" and/or "including," when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof. It will be understood that, although the terms “first”, “second” and “opposite” and the like may be used herein to describe various elements, these elements should not be limited by these terms. These terms are only used to distinguish one element from another element. Thus, “a first element” discussed below could be termed “a second element” without departing from the teachings herein.

"About", "approximately" or “substantially” as used herein is inclusive of the stated value and means within an acceptable range of deviation for the particular value as determined by one of ordinary skill in the art, considering the measurement in question and the error associated with measurement of the particular quantity (i.e., the limitations of the measurement system). For example, "about" may mean within one or more standard deviations, or within ± 20%, 10% or 5% of the stated value.

Unless otherwise defined, all terms used herein (including technical and scientific terms) have the same meaning as commonly understood by those skilled in the art to which this invention pertains. It will be further understood that terms, such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the relevant art and will not be interpreted in an idealized or overly formal sense unless expressly so defined in the present specification.

Some examples are described herein with reference to cross section illustrations that are schematic illustrations of idealized examples, wherein like reference numerals refer to like elements throughout the specification. As such, variations from the shapes of the illustrations as a result, for example, of manufacturing techniques and/or tolerances, are to be expected. Thus, examples described herein should not be construed as limited to the particular shapes of regions as illustrated herein but are to include deviations in shapes that result, for example, from manufacturing. For example, a region illustrated or described as flat may have rough and/or nonlinear features. Moreover, sharp angles that are illustrated may be rounded. Thus, the regions illustrated in the figures are schematic in nature and their shapes are not intended to illustrate the precise shape of a region and are not intended to limit the scope of the present claims. Some of the parts which are not associated with the description may not be provided in order to specifically describe exemplary examples of the present disclosure.

Figure 1 A-C shows an example embodiment of the present invention, in the form of a plastic container for solar water disinfection (100) having a stiffness to preserve its shape in both empty state and in water-filled state, said container having an opening (110) for receiving water to be disinfected (120) where said opening can subsequently be closed and reopened, said container having at least 20% of its surface area available for UV radiation from incident sunlight and said container being made substantially of a UV transparent plastic material having a transmittance of UV-A radiation (400nm to 315nm) of at least 50% and a transmittance of UV-B radiation (310nm to 290nm) of at least 33%, and said UV transparent plastic material being sufficiently stable to UV radiation to enable the container to have an outdoor in-use period corresponding to a Kly of at least 300 GJ/m 2

The plastic container is substantially made of polypropylene comprising stabilizers to postpone the degradation of the material from exposure to sunlight.

The plastic container (100) has an opening (100) with a screw cap such that water can be filled into the container prior to disinfection and the disinfected water subsequently can be drained from the container during use. The container is also furnished with a handle (190) and a furnishing (190) in the opposite end of the container which enables to hang the container from a rope or a hook. Those features facilitates the handling of the container during filling, transport and subsequent use of the disinfected water.

The plastic container has 6 matching sets of indentations (170) and protrusions (180) which serves to facilitate the stacking of plastic containers during storage and transportation. It has also been found that the orientation of the matching indentations and protrusions may be selected such that the protrusions are at the surface intended to face the incident sunlight during disinfection as the surface with the protrusions has the better UV transmittance of the two opposing surfaces once the plastic container is reused and gets worn and scratched from transportation or laying on the ground or other surfaces, e.g. during transport between the water source, the place where disinfection takes place and the place where the disinfected water is used.

The plastic container of Figure 1 has a box-like shape with Fig 1A-B indicating the height (H), width (W) and depth (D) of the container. This container is designed to be filled with water and placed on a surface in a way that the substantially flat surface having the indentations face downwards. This allows exposure to sunlight on the surface having the protrusions as well as several of the sides of the container.

Figure 2 shows another example embodiment of the invention. The plastic container for solar water disinfection (100) having a stiffness to preserve its shape in both empty state and in water- filled state, said container having an opening (110) for receiving water to be disinfected (120) where said opening can subsequently be closed and reopened, said container having at least 20% of its surface area available for UV radiation from incident sunlight and said container being made substantially of a UV transparent plastic material having a transmittance of UV-A radiation (400nm to 315nm) of at least 50% and a transmittance of UV-B radiation (310nm to 290nm) of at least 33%, and said UV transparent plastic material being sufficiently stable to UV radiation to enable the container to have an outdoor in-use period corresponding to a Kly of at least 300 GJ/m 2 , and comprising an electronic device (200) configured to receive incident light and to provide an indication of the disinfection status. This container is substantially made of polypropylene comprising stabilizers to postpone the degradation of the material from exposure to sunlight. The electronic device in the example embodiment comprises a photovoltaic component, a temperature sensor and a processor, the electronic device being placed on the exterior side of the surface of the plastic container having the protrusions (180).

Figure 3 shows yet another example embodiment of the invention. The plastic container for solar water disinfection (100) havs a stiffness to preserve its shape in both empty state and in water- filled state, said container having an opening (110) for receiving water to be disinfected (120) where said opening can subsequently be closed and reopened, said container having at least 20% of its surface area available for UV radiation from incident sunlight and said container being made substantially of a UV transparent plastic material having a transmittance of UV-A radiation (400nm to 315nm) of at least 50% and a transmittance of UV-B radiation (310nm to 290nm) of at least 33%, and said UV transparent plastic material being sufficiently stable to UV radiation to enable the container to have an outdoor in-use period corresponding to a Kly of at least 300 GJ/m 2 The particular UV transparent plastic material is polypropylene comprising stabilizers such that the container can be exposed to sunlight over a prolonged period.

Reference numbers and letters

100 Container

110 Opening

120 Water to be disinfected

130 First substantially flat surface

131 Second substantially flat surface

140 Bend

150 Furnishing for hanging of container

170 Indentation

180 Protrusion

190 Handle

200 Electronic device

H Height

W Width

D Depth