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Title:
SOLID-SUPPORTED RUTHENIUM-DIAMINE COMPLEX, AND METHOD FOR MANUFACTURING OPTICALLY ACTIVE COMPOUND
Document Type and Number:
WIPO Patent Application WO/2016/056669
Kind Code:
A1
Abstract:
 Provided is a solid-supported ruthenium complex represented by general formula (1), (2) or (3). Further provided are: a method for manufacturing a reduction product by reducing an organic compound in the presence of the solid-supported ruthenium complex and a hydrogen donor; a method for manufacturing an optically active alcohol, characterized by reducing a carbonyl group in a carbonyl compound in the presence of the solid-supported ruthenium complex and a hydrogen donor; and a method for manufacturing an optically active amine, characterized by reducing an imino group of an imine compound in the presence of the solid-supported ruthenium complex and a hydrogen donor.

Inventors:
TOUGE Taichiro (4-11 Nishiyawata 1-chome, Hiratsuka-sh, Kanagawa 73, 〒2540073, JP)
NARA Hideki (4-11 Nishiyawata 1-chome, Hiratsuka-sh, Kanagawa 73, 〒2540073, JP)
Application Number:
JP2015/078923
Publication Date:
April 14, 2016
Filing Date:
October 13, 2015
Export Citation:
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Assignee:
TAKASAGO INTERNATIONAL CORPORATION (37-1, Kamata 5-chome Ota-k, Tokyo 21, 〒1448721, JP)
International Classes:
C07F15/00; B01J31/22; C07B53/00; C07C29/143; C07C33/30; C07C41/26; C07C43/23; C07B61/00; C07D215/04; C07D217/02; C07D307/42
Domestic Patent References:
WO2014068331A12014-05-08
WO2012153684A12012-11-15
WO2009132443A12009-11-05
Foreign References:
JP2012067071A2012-04-05
JP2012520865A2012-09-10
Other References:
JONAS DIMROTH ET AL.: "New Polymer-Supported Catalysts for the Asymmetric Transfer Hydrogenation of Acetophenone in Water - Kinetic and Mechanistic Investigations", ADVANCED SYNTHESIS & CATALYSIS, vol. 353, no. 8, 2011, pages 1335 - 1344, XP055427398
MIZUKI TADA ET AL.: "Alternative Selective Oxidation Pathways for Aldehyde Oxidation and Alkene Epoxidation on a Si02-Supported Ru- Monomer Complex Catalyst", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 132, no. 2, 2010, pages 713 - 724, XP055068999, DOI: doi:10.1021/ja9079513
MIZUKI TADA ET AL.: "Photoinduced reversible structural transformation and selective oxidation catalysis of unsaturated ruthenium complexes supported on SiO2", ANGEWANDTE CHEMIE , INTERNATIONAL EDITION, vol. 47, no. 48, 2008, pages 9252 - 9255, XP055427401
MIZUKI TADA ET AL.: "Selective formation of a coordinatively unsaturated metal complex at a surface: a SiO2-immobilized, three-coordinate ruthenium catalyst for alkene epoxidation", ANGEWANDTE CHEMIE , INTERNATIONAL EDITION, vol. 46, no. 38, 2007, pages 7220 - 7223, XP055427407
Attorney, Agent or Firm:
NISHIJIMA Takaki et al. (NAKAMURA & PARTNERS, Shin-Tokyo Bldg. 3-1, Marunouchi 3-chome, Chiyoda-k, Tokyo 55, 〒1008355, JP)
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