BOYINGTON ALLYSON (US)
CHANDRA AROOP (US)
ECKELBARGER JOSEPH (US)
KOHLER DANIEL (US)
MISHRA RAJESH (US)
WANG XUELIN (US)
ZHAO JINPENG (US)
| WO2022200208A1 | 2022-09-29 | |||
| WO2022268520A1 | 2022-12-29 |
| US20230071586W | 2023-08-03 | |||
| US7314849B2 | 2008-01-01 |
THE PESTICIDE MANUAL, 2016
"The Pesticide Manual", 2012
"The Pesticide Manual: A World Compendium", 2016, BCPC
"The Pesticide Manual, Seventeenth Edition, 2016"
| WHAT IS CLAIMED IS: 1. A molecule comprising the structure of Formula (I): Formula (I) wherein: X is selected from the group consisting of O and S; Y is selected from the group consisting of O, NR5, and S; R1 is selected from H or F; R2 is selected from methyl or cyclopropyl; R3 is selected from H, methyl, or methoxy; and R4 is selected from the group consisting of H, (C1-C16)-alkyl, (C3-C10)-cycloalkyl, (C3-C16)-alkenyl, (C3-C16)-alkynyl, (C1-C10)-alkyl-aryl, aryl, (C1-C10)-alkyl-heteroaryl, heteroaryl, (C1-C10)-alkyl-cyano, (C1-C16)-haloalkyl, (C1-C10)-alkoxy-(C1-C10)-alkyl, (C1- C10)-alkylthio-(C1-C10)-alkyl, (C1-C10)-alkyl-sulfonyl-(C1-C10)-alkyl, R72R73N, SiR75R76R77, (C1-C10)-alkyl-SiR75R76R77, R78R79C=N, (C1-C10)-alkyl-C(=O)QR70, aryl-(C1-C10)-alkyl- C(=O)QR70, heteroaryl-(C1-C10)-alkyl-C(=O)QR70, (C3-C10)-cycloalkyl-(C1-C10)-alkyl- C(=O)QR70, R70QC(=O)-(C1-C10)-alkyl-C(=O)QR71, R70QC(=O)Q-(C1-C10)-alkyl- C(=O)QR71, hydroxy-(C1-C10)-alkyl-C(=O)QR70, (C1-C10)-alkylthio-(C1-C10)-alkyl- C(=O)QR70, and (R80O)2P(=O)-(C1-C10)-alkyl; Q is selected from the group consisting of O, S, and NR71, R70, R71, R72, R73, R74, and R80 are independently selected from the group consisting of H, (C1-C16)-alkyl, aryl, heteroaryl, (C1-C16)-alkyl-aryl, and (C1-C16)-haloalkyl; R72 and R73 together form a substituted or unsubstituted ring; R75, R76, and R77 are independently selected from the group consisting of (C1-C16)- alkyl and aryl; R78 and R79 are independently selected from the group consisting of (C1-C16)-alkyl, (C1-C16)-alkyl-aryl, (C1-C16)-haloalkyl, aryl, and heteroaryl; R78 and R79 together form a substituted or unsubstituted ring; and R5 is selected from the group consisting of H, (C1-C16)-alkyl, (C3-C16)-alkenyl, (C3- C16)-alkynyl, (C1-C10)-alkyl-aryl, (C1-C10)-alkoxy, (C3-C10)-alkenyloxy, (C3-C10)-alkynyloxy, aryl-(C1-C10)-alkoxy, heterocyclyl-alkoxy, hydroxy, (C1-C10)-alkyl-sulfonyl, (C3-C8)- cycloalkyl-sulfonyl, (C3-C8)-cycloalkyl-(C1-C10)-alkyl-sulfonyl, aryl-sulfonyl, heteroaryl- sulfonyl, R72R73N-sulfonyl, (C1-C10)-alkoxy-NR74-sulfonyl, and aryl-oxy-sulfonyl; or an N-oxide or agriculturally acceptable salt thereof. 2. The molecule of claim 1 comprising the structure of Formula (II): wherein: R1 is selected from the group consisting of H and F; R2 is selected from the group consisting of methyl and cyclopropyl; R3 is selected from the group consisting of H, methyl, and methoxy; and R4 is selected from the group consisting of H, (C1-C16)-alkyl, (C3-C10)-cycloalkyl, (C3-C16)-alkenyl, (C3-C16)-alkynyl, (C1-C10)-alkyl-aryl, aryl, (C1-C10)-alkyl-heteroaryl, heteroaryl, (C1-C10)-alkyl-cyano, (C1-C16)-haloalkyl, (C1-C10)-alkoxy-(C1-C10)-alkyl, (C1- C10)-alkylthio-(C1-C10)-alkyl, (C1-C10)-alkyl-sulfonyl-(C1-C10)-alkyl, R72R73N, SiR75R76R77, (C1-C10)-alkyl-SiR75R76R77, R78R79C=N, (C1-C10)-alkyl-C(=O)QR70, aryl-(C1-C10)-alkyl- C(=O)QR70, heteroaryl-(C1-C10)-alkyl-C(=O)QR70, (C3-C10)-cycloalkyl-(C1-C10)-alkyl- C(=O)QR70, R70QC(=O)-(C1-C10)-alkyl-C(=O)QR71, R70QC(=O)Q-(C1-C10)-alkyl- C(=O)QR71, hydroxy-(C1-C10)-alkyl-C(=O)QR70, (C1-C10)-alkylthio-(C1-C10)-alkyl- C(=O)QR70, and (R80O)2P(=O)-(C1-C10)-alkyl; Q is selected from the group consisting of O, S, and NR71, R70, R71, R72, R73, R74, and R80 are independently selected from the group consisting of H, (C1-C16)-alkyl, aryl, heteroaryl, (C1-C16)-alkyl-aryl, and (C1-C16)-haloalkyl; R72 and R73 together form a substituted or unsubstituted ring; R75, R76, and R77 are independently selected from the group consisting of (C1-C16)- alkyl and aryl; R78 and R79 are independently selected from the group consisting of (C1-C16)-alkyl, (C1-C16)-alkyl-aryl, (C1-C16)-haloalkyl, aryl, and heteroaryl; and R78 and R79 together form a substituted or unsubstituted ring, or an N-oxide or agriculturally acceptable salt thereof. 3. The molecule of claim 1 or claim 2, wherein the molecule is chosen from Formula (V), Formula (VI), Formula (VII), or Formula ( Formula (V) Formula (VI) Formula (VII) Formula (VIII) wherein R4 is selected from the group consisting of H, (C1-C16)-alkyl, (C3-C10)- cycloalkyl, (C3-C16)-alkenyl, (C3-C16)-alkynyl, (C1-C10)-alkyl-aryl, aryl, (C1-C10)-alkyl- heteroaryl, heteroaryl, (C1-C10)-alkyl-cyano, (C1-C16)-haloalkyl, (C1-C10)-alkoxy-(C1-C10)- alkyl, (C1-C10)-alkylthio-(C1-C10)-alkyl, (C1-C10)-alkyl-sulfonyl-(C1-C10)-alkyl, R72R73N, SiR75R76R77, (C1-C10)-alkyl-SiR75R76R77, R78R79C=N, (C1-C10)-alkyl-C(=O)QR70, aryl-(C1- C10)-alkyl-C(=O)QR70, heteroaryl-(C1-C10)-alkyl-C(=O)QR70, (C3-C10)-cycloalkyl-(C1-C10)- alkyl-C(=O)QR70, R70QC(=O)-(C1-C10)-alkyl-C(=O)QR71, R70QC(=O)Q-(C1-C10)-alkyl- C(=O)QR71, hydroxy-(C1-C10)-alkyl-C(=O)QR70, (C1-C10)-alkylthio-(C1-C10)-alkyl- C(=O)QR70, and (R80O)2P(=O)-(C1-C10)-alkyl; Q is selected from the group consisting of O, S, and NR71, R70, R71, R72, R73, R74, and R80 are independently selected from the group consisting of H, (C1-C16)-alkyl, aryl, heteroaryl, (C1-C16)-alkyl-aryl, and (C1-C16)-haloalkyl; R72 and R73 together form a substituted or unsubstituted ring; R75, R76, and R77 are independently selected from the group consisting of (C1-C16)- alkyl and aryl; R78 and R79 are independently selected from the group consisting of (C1-C16)-alkyl, (C1-C16)-alkyl-aryl, (C1-C16)-haloalkyl, aryl, and heteroaryl; and R78 and R79 together form a substituted or unsubstituted ring, or an N-oxide or agriculturally acceptable salt thereof. 4. The molecule of any one of claims 1-3, wherein the molecule is chosen from Compound A, Compound B, Compound C, or Compound D: Compound A Compound B Compound C Compound D. 5. The molecule of any one of claims 1-3, wherein the molecule is chosen from Compound E, Compound F, Compound G, or Compound H: 6. The molecule of claim 1, comprising the structure of Formula (III): Formula (III), wherein R1 is selected from the group consisting of H and F; R4 is selected from the group consisting of H, (C1-C16)-alkyl, (C3-C10)-cycloalkyl, (C3-C16)-alkenyl, (C3-C16)-alkynyl, (C1-C10)-alkyl-aryl, aryl, (C1-C10)-alkyl-heteroaryl, heteroaryl, (C1-C10)-alkyl-cyano, (C1-C16)-haloalkyl, (C1-C10)-alkoxy-(C1-C10)-alkyl, (C1- C10)-alkylthio-(C1-C10)-alkyl, (C1-C10)-alkyl-sulfonyl-(C1-C10)-alkyl, R72R73N, SiR75R76R77, (C1-C10)-alkyl-SiR75R76R77, R78R79C=N, (C1-C10)-alkyl-C(=O)QR70, aryl-(C1-C10)-alkyl- C(=O)QR70, heteroaryl-(C1-C10)-alkyl-C(=O)QR70, (C3-C10)-cycloalkyl-(C1-C10)-alkyl- C(=O)QR70, R70QC(=O)-(C1-C10)-alkyl-C(=O)QR71, R70QC(=O)Q-(C1-C10)-alkyl- C(=O)QR71, hydroxy-(C1-C10)-alkyl-C(=O)QR70, (C1-C10)-alkylthio-(C1-C10)-alkyl- C(=O)QR70, and (R80O)2P(=O)-(C1-C10)-alkyl; Q is selected from the group consisting of O, S, and NR71; R70, R71, R72, R73, R74, and R80 are independently selected from the group consisting of H, (C1-C16)-alkyl, aryl, heteroaryl, (C1-C16)-alkyl-aryl, and (C1-C16)-haloalkyl; R72 and R73 together form a substituted or unsubstituted ring; R75, R76, and R77 are independently selected from the group consisting of (C1-C16)- alkyl and aryl; R78 and R79 are independently selected from the group consisting of (C1-C16)-alkyl, (C1-C16)-alkyl-aryl, (C1-C16)-haloalkyl, aryl, and heteroaryl; and R78 and R79 together form a substituted or unsubstituted ring, or an N-oxide or agriculturally acceptable salt thereof. 7. The molecule of claim 1 or claim 6, wherein the molecule is chosen from Formula (IX), or Formula (X): Formula (IX) Formula (X) wherein R4 is selected from the group consisting of H, (C1-C16)-alkyl, (C3-C10)- cycloalkyl, (C3-C16)-alkenyl, (C3-C16)-alkynyl, (C1-C10)-alkyl-aryl, aryl, (C1-C10)-alkyl- heteroaryl, heteroaryl, (C1-C10)-alkyl-cyano, (C1-C16)-haloalkyl, (C1-C10)-alkoxy-(C1-C10)- alkyl, (C1-C10)-alkylthio-(C1-C10)-alkyl, (C1-C10)-alkyl-sulfonyl-(C1-C10)-alkyl, R72R73N, SiR75R76R77, (C1-C10)-alkyl-SiR75R76R77, R78R79C=N, (C1-C10)-alkyl-C(=O)QR70, aryl-(C1- C10)-alkyl-C(=O)QR70, heteroaryl-(C1-C10)-alkyl-C(=O)QR70, (C3-C10)-cycloalkyl-(C1-C10)- alkyl-C(=O)QR70, R70QC(=O)-(C1-C10)-alkyl-C(=O)QR71, R70QC(=O)Q-(C1-C10)-alkyl- C(=O)QR71, hydroxy-(C1-C10)-alkyl-C(=O)QR70, (C1-C10)-alkylthio-(C1-C10)-alkyl- C(=O)QR70, and (R80O)2P(=O)-(C1-C10)-alkyl; Q is selected from the group consisting of O, S, and NR71, R70, R71, R72, R73, R74, and R80 are independently selected from the group consisting of H, (C1-C16)-alkyl, aryl, heteroaryl, (C1-C16)-alkyl-aryl, and (C1-C16)-haloalkyl; R72 and R73 together form a substituted or unsubstituted ring; R75, R76, and R77 are independently selected from the group consisting of (C1-C16)- alkyl and aryl; R78 and R79 are independently selected from the group consisting of (C1-C16)-alkyl, (C1-C16)-alkyl-aryl, (C1-C16)-haloalkyl, aryl, and heteroaryl; and R78 and R79 together form a substituted or unsubstituted ring, or an N-oxide or agriculturally acceptable salt thereof. 8. The molecule of any one of claims 1, 6, or 7, wherein the molecule is chosen from Compound I, Compound J, Compound K, or Compound L: 9. The molecule of claim 1, comprising the structure of Formula (IV): Formula (IV) wherein: R1 is selected from the group consisting of H and F; R4 is selected from the group consisting of H, (C1-C16)-alkyl, (C3-C10)-cycloalkyl, (C3-C16)-alkenyl, (C3-C16)-alkynyl, (C1-C10)-alkyl-aryl, aryl, (C1-C10)-alkyl-heteroaryl, heteroaryl, (C1-C10)-alkyl-cyano, (C1-C16)-haloalkyl, (C1-C10)-alkoxy-(C1-C10)-alkyl, (C1- C10)-alkylthio-(C1-C10)-alkyl, (C1-C10)-alkyl-sulfonyl-(C1-C10)-alkyl, R72R73N, SiR75R76R77, (C1-C10)-alkyl-SiR75R76R77, R78R79C=N, (C1-C10)-alkyl-C(=O)QR70, aryl-(C1-C10)-alkyl- C(=O)QR70, heteroaryl-(C1-C10)-alkyl-C(=O)QR70, (C3-C10)-cycloalkyl-(C1-C10)-alkyl- C(=O)QR70, R70QC(=O)-(C1-C10)-alkyl-C(=O)QR71, R70QC(=O)Q-(C1-C10)-alkyl- C(=O)QR71, hydroxy-(C1-C10)-alkyl-C(=O)QR70, (C1-C10)-alkylthio-(C1-C10)-alkyl- C(=O)QR70, and (R80O)2P(=O)-(C1-C10)-alkyl; Q is selected from the group consisting of O, S, and NR71, X is selected from the group consisting of O and S, R70, R71, R72, R73, R74, and R80 are independently selected from the group consisting of H, (C1-C16)-alkyl, aryl, heteroaryl, (C1-C16)-alkyl-aryl, and (C1-C16)-haloalkyl; R72 and R73 together form a substituted or unsubstituted ring; R75, R76, and R77 are independently selected from the group consisting of (C1-C16)- alkyl and aryl; R78 and R79 are independently selected from the group consisting of (C1-C16)-alkyl, (C1-C16)-alkyl-aryl, (C1-C16)-haloalkyl, aryl, and heteroaryl; and R78 and R79 together form a substituted or unsubstituted ring, or an N-oxide or agriculturally acceptable salt thereof. 10. The molecule of claim 1 or claim 9, wherein the molecule is selected from the group consisting of Compound M, Compound N, and Compound O: 11. The molecule of claim 1, wherein the molecule is selected from the group consisting of Compound P and Compound U: 12. A composition comprising a molecule from any one of claims 1-11, further comprising at least one additive. 13. The composition of claim 12, wherein the additive is selected from the group consisting of adjuvants, safeners, carriers, and combinations thereof. 14. A composition comprising: a first herbicide (a), wherein the first herbicide is a molecule from any one of claims 1-11; and a second herbicide (b), wherein (b) is selected from the group consisting of acetolactate synthase (ALS) inhibitors, acetohydroxy acid synthase (AHAS) inhibitors, photosystem II (PS-II) inhibitors, acetyl CoA carboxylase (ACCase) inhibitors, synthetic auxins, auxin transport inhibitors, photosystem I inhibitors, 5-enolpyruvylshikimate-3- phosphate (EPSP) synthase inhibitors, glutamine synthetase inhibitors, microtubule assembly inhibitors, mitosis inhibitors, very long chain fatty acid (VLCFA) inhibitors, fatty acid and lipid synthesis (FA/LSI) inhibitors, protoporphyrinogen oxidase (PPO) inhibitors, carotenoid biosynthesis inhibitors, phytoene desaturase (PDS) inhibitors, 4-hydroxyphenyl-pyruvate- dioxygenase (HPPD) inhibitors, cellulose biosynthesis inhibitors, herbicides with multiple modes-of-action, and unclassified herbicides. 15. The composition of claim 14, wherein the second herbicide (b) is a PPO inhibitor herbicide selected from the group consisting of acifluorfen, azafenidin, benzfendizone, bifenox, butafenacil, carfentrazone, chlomethoxyfen, cinidon, fluazolate, flufenpyr, flumiclorac, flumioxazin, fluoroglycofen, fluthiacet, fomesafen, halosafen, lactofen, oxadiargyl, oxadiazon, oxyfluorfen, pentoxazone, profluazol, pyraclonil, pyraflufen, saflufenacil, sulfentrazone, thidiazimin, tiafenacil, trifludimoxazin, agriculturally acceptable salts thereof, or combinations thereof. 16. The composition of claim 14, wherein the second herbicide (b) is an HPPD inhibitor herbicide selected from the group consisting of benzobicyclon, benzofenap, bicyclopyrone, fenquinotrione, isoxachlortole, isoxaflutole, lancotrione, mesotrione, pyraquinate, pyrasulfotole, pyrazolynate, pyrazoxyfen, sulcotrione, tefuryltrione, tembotrione, tolpyralate, topramezone, or an agriculturally acceptable salt or ester thereof, and combinations thereof. 17. The composition of claim 14, wherein the second herbicide (b) is a synthetic auxin herbicide or an auxin transport inhibitor herbicide selected from the group consisting 2,4-D; 2,4-DB; 2,3,6-TBA, aminocyclopyrachlor, aminopyralid, benazolin-ethyl, chloramben, clomeprop, clopyralid, dichlorprop, dichlorprop-P, dicamba, florpyrauxifen, florpyrauxifen- benzyl, fluchloraminopyr, fluroxypyr, fluroxypyr-MHE, halauxifen, halauxifen-methyl indolauxipyr, indolauxipyr-cyanomethyl, mecoprop, mecoprop-P, MCPA, MCPA-thioethyl, MCPB, picloram, quinclorac, quinmerac, triclopyr, agriculturally acceptable salts and esters thereof, and combinations thereof. 18. The composition of claim 17, wherein the auxin herbicide is 2,4-D or agriculturally acceptable salts and esters thereof. 19. The composition of claim 18, wherein the 2,4-D is 2,4-D choline. 20. The composition of claim 18, wherein the 2,4-D is 2,4-D trolamine. 21. The composition of claim 18, wherein the 2,4-D is selected from the group consisting 22. The composition of claim 14, wherein the second herbicide (b) is glyphosate or an agriculturally acceptable salt or ester thereof. 23. The composition of claim 14, wherein the second herbicide (b) is a glutamine synthetase inhibitor herbicide. 24. The composition of claim 23, wherein the glutamine synthetase inhibitor herbicide is glufosinate or an agriculturally acceptable salt or ester thereof. 25. The composition of claim 14, wherein the second herbicide (b) is an ALS inhibitor herbicide selected from the group consisting of amidosulfuron, azimsulfuron, bispyribac, bensulfuron, chlorimuron, chlorsulfuron, cinosulfuron, cloransulam, cyclosulfamuron, diclosulam, ethametsulfuron, ethoxysulfuron, flazasulfuron, florasulam, flucarbazone, flucetosulfuron, flumetsulam, flupyrsulfuron, foramsulfuron, halosulfuron, imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, imazosulfuron, iodosulfuron, iofensulfuron, mesosulfuron, metazosulfuron, metosulam, metsulfuron, nicosulfuron, orthosulfamuron, oxasulfuron, penoxsulam, primisulfuron, propoxycarbazone, propyrisulfuron, prosulfuron, pyrazosulfuron, pyribenzoxim, pyriftalid, pyriminobac, pyrimisulfan, pyrithiobac, pyroxsulam, rimsulfuron, sulfometuron, sulfosulfuron, thiencarbazone, thifensulfuron, triasulfuron, tribenuron, trifloxysulfuron, triflusulfuron, tritosulfuron, and agriculturally acceptable salts and esters thereof. 26. The composition of claim 14, wherein the second herbicide (b) is a PS II inhibitor herbicide selected from the group consisting of ametryne, amicarbazone, atrazine, bentazone, bromacil, bromofenoxim, bromoxynil, chlorbromuron, chloridazon, chlorotoluron, chloroxuron, cyanazine, desmedipham, desmetryn, dimefuron, dimethametryn, diuron, ethidimuron, ethiozin, fenuron, fluometuron, hexazinone, iodobonil, ioxynil, isocil, isomethiozin, isoproturon, isouron, karbutilate, lenacil, linuron, metamitron, methabenzthiazuron, metobromuron, metoxuron, metribuzin, monolinuron, neburon, pentanochlor, phenmedipham, prometon, prometryn, propanil, propazine, pyridafol, pyridate, siduron, simazine, simetryne, tebuthiuron, terbacil, terbumeton, terbuthylazine, terbutryn, trietazine, and combinations thereof. 27. The composition of claim 14, wherein the second herbicide (b) is an ACCase inhibitor herbicide selected from the group consisting of alloxydim, butroxydim, clethodim, clodinafop, cloproxydim, cycloxydim, cyhalofop, diclofop, fenoxaprop, fenthiaprop, fluazifop, haloxyfop, metamifop, pinoxaden, profoxydim, propaquizafop, quizalofop, sethoxydim, tepraloxydim, tralkoxydim, and agriculturally acceptable salts and esters thereof. 28. The composition of claim 14, wherein the second herbicide (b) is a VLCFA synthesis inhibitor herbicide selected from the group consisting of acetochlor, alachlor, anilofos, butachlor, cafenstrole, dimethachlor, dimethenamid, diphenamid, fentrazamide, flufenacet, ipfencarbazone, mefenacet, metazachlor, metolachlor, naproanilide, napropamide, pethoxamid, piperophos, pretilachlor, propachlor, propisochlor, pyroxasulfone, thenylchlor, and agriculturally acceptable salts and esters thereof. 29. The composition of claim 14, wherein the second herbicide (b) is a FA/LSI inhibitor herbicide selected from the group consisting of benfuresate, bensulide, butylate, cycloate, dalapon, EPTC, esprocarb, ethofumesate, flupropanate, molinate, orbencarb, prosulfocarb, thiobencarb, tiocarbazil, tri-allate, vernolate, and agriculturally acceptable salts or esters thereof. 30. The composition of claim 14, wherein the second herbicide (b) is a PDS inhibitor herbicide selected from the group consisting of beflubutamid, diflufenican, fluridone, flurochloridone, flurtamone, norflurazon, picolinafen, and agriculturally acceptable salts and esters thereof. 31. The composition of claim 14, wherein the second herbicide (b) is photosystem I inhibitor selected from the group consisting of paraquat and diquat. 32. The composition of any one of claims 14-31, wherein the ratio of (a) to (b) is from 30:1 to 1:30. 33. The composition of any one of the claims 14-31, wherein the ratio of (a) to (b) is from 20:1 to 1:20. 34. The composition of any one of the claims 14-31, wherein the ratio of (a) to (b) is from 7:1 to 1:7. 35. The composition of any one of the claims 14-31, wherein the ratio of (a) to (b) is from 5:1 to 1:1. 36. The composition of any one of the claims 14-31, wherein the ratio of (a) to (b) is from 10:1 to 1:10. 37. The composition of any one of claims 14-36, further comprising at least one additive selected from the group consisting of adjuvants, safeners, carriers, and combinations thereof. 38. The composition of claim 37, wherein the at least one additive is a safener. 39. The composition of claim 38, wherein the safener is an azole safener. 40. The composition of claim 38, wherein the safener is cloquintocet or an agriculturally ester or salt thereof. 41. The composition of claim 40, wherein the safener is cloquintocet-mexyl. 42. The composition of claim 38, wherein the safener is benoxacor, benthiocarb, brassinolide, cyometrinil, cyprosulfamide, daimuron, dichlormid, dicyclonon, dietholate, dimepiperate, disulfoton, fenchlorazole, fenchlorazole-ethyl, fenclorim, flurazole, fluxofenim, furilazole, harpin proteins, isoxadifen-ethyl, jiecaowan, jiecaoxi, mefenpyr, mefenpyr-diethyl, mephenate, naphthalic anhydride, 2,2,5-trimethyl-3-(dichloroacetyl)-1,3- oxazolidine, 4-(dichloroacetyl)-1-oxa-4-azaspiro [4.5]-decane, oxabetrinil, and N-phenyl- sulfonylbenzoic acid amides, or agriculturally acceptable salts thereof. 43. The composition of any one of claims 12-42, wherein the composition is in the form of an aqueous solution, an aqueous suspension, an aqueous dispersion, an aqueous emulsion, an aqueous microemulsion, an aqueous suspo-emulsion, an oil solution, an oil suspension, an oil dispersion, an oil emulsion, an oil microemulsion, an oil suspo-emulsion, a self- emulsifying formulation, a gel, a paste, a powder, a dust, a granular formulation, a material for spreading, or combinations thereof. 44. A method of controlling unwanted vegetation comprising applying the molecule of any one of claims 1-11 or the composition of any one of claims 12-43 to unwanted vegetation. 45. The method of claim 44, wherein the molecule or composition is applied to the unwanted vegetation or an area adjacent the unwanted vegetation or applied to soil or water around the unwanted vegetation by spraying, atomizing, dusting, sprinkling, spreading, or direct application of the molecule or composition. 46. The method of claim 44 or claim 45 wherein the molecule or composition is applied in crop plants that are resistant to herbicides, insecticides, fungicides, pathogens, insects, or combinations thereof. 47. The method of any one of claims 44-46, wherein the molecule or composition is applied to control undesirable vegetation comprising grasses, broadleaf weeds, sedge weeds, and combinations thereof. 48. The method of claims 44-47, wherein the molecule, molecule in the composition, or composition is applied in a range of 50 g ai/ha to 1,500 g ai/ha. 49. The method of claim 48, wherein the molecule, molecule in the composition, or composition is applied in a range of 80 g ai/ha to 1,200 g ai/ha. 50. A composition comprising: a first herbicide (a), selected from the compounds consisting of PYR-1, PYR-2, PYR- 3, PYR-4, PYR-5, PYR-6, PYR-7, PYR-8, PYR-9, PYR-10, PYR-11, PYR-12, PYR-13, PYR-14, PYR-15, PYR-16, PYR-17, PYR-18, PYR-19, PYR-20, and PYR-21: , , , , , a second herbicide (b), wherein (b) is selected from the group consisting of acetolactate synthase (ALS), acetohydroxy acid synthase (AHAS) inhibitors, photosystem II (PS-II) inhibitors, acetyl CoA carboxylase (ACCase) inhibitors, synthetic auxins, auxin transport inhibitors, photosystem I inhibitors, 5- enolpyruvylshikimate-3-phosphate (EPSP) synthase inhibitors, glutamine synthetase inhibitors, microtubule assembly inhibitors, mitosis inhibitors, very long chain fatty acid (VLCFA) inhibitors, fatty acid and lipid synthesis (FA/LSI) inhibitors, protoporphyrinogen oxidase (PPO) inhibitors, carotenoid biosynthesis inhibitors, phytoene desaturase (PDS) inhibitors, 4-hydroxyphenyl-pyruvate-dioxygenase (HPPD) inhibitors, cellulose biosynthesis inhibitors, herbicides with multiple modes-of-action, and unclassified herbicides, wherein the ratio of (a) to (b) is from 30:1 to 1:30. 51. The composition of claim 50, wherein (b) is an ACCase inhibitor. 52. The composition of claim 51, wherein the ACCase inhibitor is a cyclohexanedione. 53. The composition of claim 52, wherein the cyclohexanedione is clethodim. 54. The composition of claim 51, wherein the ACCase inhibitor is selected from the group consisting of clodinafop, cyhalofop, diclofop, fenoxaprop, fenthiaprop, fluazifop, haloxyfop, metamifop, propaquizafop, quizalofop, pinoxaden, and agriculturally acceptable salts or esters thereof, or combinations thereof. 55. The composition of any one of claims 51-54, wherein the ratio of (a) to (b) is from 15:1 to 1:15. 56. The composition of any one of claims 51-54, wherein the ratio of (a) to (b) is from 5:1 to 1:15. 57. The composition of claim 50, wherein (b) is an ALS inhibitor. 58. The composition of claim 57, wherein the ALS inhibitor is selected from the group consisting of florasulam, cloransulam, diclosulam, flumetsulam, metosulam, penoxsulam, or pyroxsulam, and agriculturally acceptable salts or esters thereof. 59. The composition of claim 57, wherein the ALS inhibitor is a sulfonylurea. 60. The composition of claim 57, wherein the ALS inhibitor is a triazolopyrimidine. 61. The composition of claim 60, wherein the triazolopyrimidine is a type 1 triazolopyrimidine. 62. The composition of any one of claims 50 and 57-61, wherein the ratio of (a) to (b) is from 30:1 to 1:20. 63. The composition of any one of claims 50 and 57-61, wherein the ratio of (a) to (b) is from 25:1 to 1:1. 64. The composition of any one of claims 50 and 57-61, wherein the ratio of (a) to (b) is from 20:1 to 5:1. 65. The composition of claim 50, wherein (b) is an auxin herbicide. 66. The composition of claim 65, wherein the auxin is a phenoxycarboxylic acid. 67. The composition of claim 66, wherein the phenoxycarboxylic acid is 2,4-D or agriculturally acceptable salts and esters thereof. 68. The composition of claim 67, wherein the 2,4-D is 2,4-D choline. 69. The composition of claim 67, wherein the 2,4-D is 2,4-D trolamine. 70. The composition of claim 67, wherein the 2,4-D is selected from the group consisting 71. The composition of claim 65, wherein the auxin is a benzoic acid. 72. The composition of claim 71, wherein the benzoic acid is dicamba and agriculturally acceptable salt and esters thereof. 73. The composition of claim 65, wherein the auxin is a pyridine carboxylate. 74. The composition of claim 65, wherein the auxin is selected from the group consisting of aminopyralid, halauxifen, clopyralid, picloram, florpyrauxifen, indolauxipyr, and agriculturally acceptable salts and esters thereof. 75. The composition of claim 65, wherein the auxin is selected from the group consisting of 2,4-D, 2,4-DB, 2,3,6-TBA, aminocyclopyrachlor, aminopyralid, benazolin-ethyl, chloramben, clomeprop, clopyralid, dichlorprop, dichlorprop-P, dicamba, florpyrauxifen, florpyrauxifen-benzyl, fluchloraminopyr, fluchloraminopyr-tefuryl, fluroxypyr, fluroxypyr- MHE, halauxifen, halauxifen-methyl, indolauxipyr, indolauxipyr-cyanomethyl, mecoprop, mecoprop-P, MCPA, MCPA-thioethyl, MCPB, picloram, quinclorac, quinmerac, triclopyr, and agriculturally acceptable salts and esters thereof. 76. The composition of any one of claims 50 and 65-75, wherein the ratio of (a) to (b) is from 7:100 to 1:5. 77. The composition of any one of claims 50 and 65-75, wherein the ratio of (a) to (b) is from 7:100 to 1:1. 78. The composition of any one of claims 50 and 65-75, wherein the ratio of (a) to (b) is from 7:100 to 5:1. 79. The composition of any one of claims 50-78, further comprising a safener. 80. The composition of claim 79, wherein the safener is cloquintocet or an agriculturally ester or salt thereof. 81. The composition of claim 80, wherein the safener is cloquintocet-mexyl. 82. The composition of claim 79, wherein the safener is benoxacor, benthiocarb, brassinolide, cyometrinil, cyprosulfamide, daimuron, dichlormid, dicyclonon, dietholate, dimepiperate, disulfoton, fenchlorazole, fenchlorazole-ethyl, fenclorim, flurazole, fluxofenim, furilazole, harpin proteins, isoxadifen-ethyl, jiecaowan, jiecaoxi, mefenpyr, mefenpyr-diethyl, mephenate, naphthalic anhydride, 2,2,5-trimethyl-3-(dichloroacetyl)-1,3- oxazolidine, 4-(dichloroacetyl)-1-oxa-4-azaspiro [4.5]-decane, oxabetrinil, and N-phenyl- sulfonylbenzoic acid amides, or agriculturally acceptable salts thereof. 83. The composition of claim 79, wherein the safener is an azole safener. 84. A method of controlling unwanted vegetation comprising applying the composition of any one of claims 50-83 to unwanted vegetation. 85. The method of claim 84, wherein the composition is applied to the unwanted vegetation or an area adjacent the unwanted vegetation or applied to soil or water around the unwanted vegetation by spraying, atomizing, dusting, sprinkling, spreading, or direct application of the molecule or composition. 86. The method of claim 84 or claim 85 wherein the composition is applied in crop plants that are resistant to herbicides, insecticides, fungicides, pathogens, insects, or combinations thereof. 87. The method of any one of claims 84-86, wherein the composition is applied to control undesirable vegetation comprising grasses, broadleaf weeds, sedge weeds, and combinations thereof. 88. The method of claims 86-87, wherein the composition is applied in a range of 50 g ai/ha to 1,500 g ai/ha. 89. The method of claim 88, wherein the composition is applied in a range of 80 g ai/ha to 1,200 g ai/ha. |
! ! Various substituted 5-membered rings, such as lactam-based or thiolactam-based molecules, of included in the present disclosure have been found to exhibit herbicidal activity against various key species of undesirable vegetation. The description below sets forth details of one or more aspects of the present disclosure. Other features, objects, and advantages will be apparent from the description and from the claims. BRIEF DESCRIPTION OF THE DRAWINGS The above mentioned and other features and objects of this disclosure, and the manner of attaining them, will become more apparent and the disclosure itself will be better understood by reference to the following description of exemplary embodiments of the disclosure taken in conjunction with the accompanying drawings, wherein: FIGs.1A and 1B illustrate Table 5A and 5B that contains exemplary post-emergent data; FIG.1C illustrates Table 5C that contains exemplary pre-emergent data; FIG.2 illustrates Tables 6A and 6B that contains exemplary isomer data; FIG.3 illustrates Table 7 that contains exemplary broad leaf crop data; FIGs. 4A-4D illustrate Tables 8A-8D respectively that contain various mixtures with ALS herbicides according to various aspects; FIGs. 5A-4D illustrate Tables 9A-9D respectively that contain various mixtures with auxin herbicides according to various aspects; FIGs. 6A and 6B illustrate Tables 10A and 10B respectively that contain various mixtures with HPPD herbicides according to various aspects; FIGs. 7A and 7B illustrate Tables 11A and 11B respectively that contain various mixtures with PPO herbicides according to various aspects; FIGs.8A-8D illustrate Tables 12A-12D respectively that contain various mixtures with ACCase herbicides according to various aspects; FIG. 9 illustrates Table 13 that contains various mixtures with MAI herbicides according to various aspects; FIG. 10 illustrates Table 14 that contains various mixtures with PSI herbicides according to various aspects; FIG. 11 illustrates Table 15 that contain various mixtures with PDS herbicides according to various aspects; FIG.12 illustrates Table 16 that contains various mixtures with VLCFA herbicides according to various aspects; FIG.13 illustrates Table 17 that contains various mixtures with DOXP herbicides according to various aspects; FIGs.14A and 14B illustrate Tables 18A and 18B respectively that contain various mixtures with PSII herbicides according to various aspects; FIG.15 illustrates Tables 19 that contains various mixtures with EPSPS herbicides according to various aspects; FIG. 16 illustrates Table 20 that contains various mixtures with GS herbicides according to various aspects; FIG. 17 illustrates Table 21 that contains comparative growth rated of various mixtures; and FIGs. 18A and 18B illustrates Table 22A and Table 22B that contain additional herbicidal mixture data. Although the FIGs. contain exemplary data for various aspects of the present disclosure—in various forms—such exemplifications are not to be construed as limiting the scope of the disclosure in any manner. DETAILED DESCRIPTION The present disclosure includes molecules that may be used as herbicides to control undesirable vegetation in various locations, such as croplands, lawns, pastures, gardens, and recreational areas. These substituted 5-membered ring molecules, such as lactams or thio- lactams, may be substituted with fluorinated benzyl groups and other groups, such as amino acid groups or derivatives thereof. The present disclosure also includes methods for using the molecules for controlling undesirable vegetation. In some aspects, the undesirable vegetation is in row crops. In some aspects, the undesirable vegetation is in maize, soy, canola, cotton, pulses, sunflower, sugar beet, wheat, barley, rice, sorghum, millet, or oats. In some aspects, the molecules are graminicides used to control undesirable vegetation including grass-type species. 1. Definitions Terms used herein will have their customary meaning in the art unless specified otherwise. The singular forms "a" and "the" include plural references unless stated otherwise. To the extent that the term "or" is employed (e.g., A or B) it is intended to mean "A or B or both." If this disclosure intends to indicate "only A or B but not both" then the term "only A or B but not both" will be employed. Thus, use of the term "or" herein is the inclusive and not the exclusive use. As used herein, the terms “herbicide” and “herbicidal active ingredient” refer to an active ingredient that kills, controls, or otherwise adversely modifies the growth of vegetation, particularly undesirable vegetation such as weed species, when applied in an appropriate amount. As used herein, the term “herbicidal effect” is an adversely modifying effect of an active ingredient on vegetation, including, for example, a deviation from natural growth or development, killing, regulation, desiccation, growth inhibition, growth reduction, and retardation. The term "herbicidal activity" refers generally to herbicidal effects of an active ingredient. As used herein, the term “herbicide resistance” refers to an inherited ability of an individual plant to survive an herbicide application that would kill a normal population of the same species of plant. Herbicide resistance in a plant species often arises due to the application of an herbicide on plants of that species in a specific location. As used herein, the term “herbicide tolerance” refers to the inherent ability of a species of plants to survive and reproduce after herbicide treatment at a normal use rate. Herbicide tolerance is therefore a natural tolerance within the normal population of the plant species, rather than resistance selected for in that species by the application of an herbicide. As used herein, a “composition” is a mixture comprising at least one herbicide, and also comprising other ingredients used to enhance the properties or effectiveness of the mixture in some way. The other ingredients may include, but are not limited to, diluents, surfactants, adjuvants, anti-foam agents, emulsifiers, colorants, dispersants, antifreeze agents, and other such ingredients. As used herein, "applying" an herbicide or herbicidal composition refers to delivering it directly to the targeted vegetation or to the locus thereof or to the area where control of undesirable vegetation is desired. Methods of application include, but are not limited to, pre-emergently contacting soil or water, post-emergently contacting the undesirable vegetation, or contacting the area adjacent to the undesirable vegetation. As used herein, the term “vegetation” can include, for instance, dormant seeds, germinating seeds, emerging seedlings, plants propagating from vegetative propagules, immature vegetation, and established vegetation. As used herein, the term "crop" refers to desired vegetation, for instance, plants that are grown to provide food, shelter, pasture, erosion control, etc. Example crops include cereals, legumes, vegetables, orchard and timber trees, grapevines, etc. Preferably, herbicides or herbicidal compositions have zero or minimal herbicidal effect on crops. As used herein, the term "undesirable vegetation" refers to vegetation that is not wanted in a given area, for instance, weed species. Herbicides or herbicidal compositions are used to control undesirable vegetation. Preferably, herbicides or herbicidal compositions have a large or complete herbicidal effect on undesirable vegetation. As used herein, unless otherwise specified, “acyl” refers to formyl, C1-C3 alkylcarbonyl, and C1-C3 haloalkylcarbonyl. C1-C6 acyl refers to formyl, C1-C5 alkylcarbonyl, and C1-C5 haloalkylcarbonyl (the group contains a total of 1 to 6 carbon atoms). As used herein, “alkyl” refers to saturated, straight-chained or branched saturated hydrocarbon moieties. Unless otherwise specified, C1-C16 alkyl groups are intended. Examples include methyl, ethyl, propyl, 1-methyl-ethyl, butyl, 1-methyl-propyl, 2-methyl- propyl, 1,1-dimethyl-ethyl, pentyl, 1-methyl-butyl, 2-methyl-butyl, 3-methyl-butyl, 2,2- dimethyl-propyl, 1-ethyl-propyl, hexyl, 1,1-dimethyl-propyl, 1,2-dimethyl-propyl, 1-methyl- pentyl, 2-methyl-pentyl, 3-methyl-pentyl, 4-methyl-pentyl, 1,1-dimethyl-butyl, 1,2-dimethyl- butyl, 1,3-dimethyl-butyl, 2,2-dimethyl-butyl, 2,3-dimethyl-butyl, 3,3-dimethyl-butyl, 1-ethyl- butyl, 2-ethyl-butyl, 1,1,2-trimethyl-propyl, 1,2,2-trimethyl-propyl, 1-ethyl-1-methyl-propyl, and 1-ethyl-2-methyl-propyl. As used herein, “haloalkyl” refers to straight-chained or branched alkyl groups, where in these groups the hydrogen atoms may be substituted partially or entirely with halogen atoms. Unless otherwise specified, C1-C16 groups are intended. Examples include chloromethyl, bromomethyl, dichloromethyl, trichloromethyl, fluoromethyl, difluoromethyl, trifluoromethyl, chlorofluoromethyl, dichlorofluoromethyl, chlorodifluoromethyl, 1- chloroethyl, 1-bromoethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2-difluoroethyl, 2,2-dichloro-2-fluoroethyl, 2,2,2- trichloroethyl, pentafluoroethyl, and 1,1,1-trifluoroprop-2-yl. As used herein, “alkenyl” refers to unsaturated, straight-chained, or branched hydrocarbon moieties containing a double bond. Unless otherwise specified, C3-C16 alkenyl are intended. Alkenyl groups may contain more than one unsaturated bond. Examples include ethenyl, 1-propenyl, 2-propenyl, 1-methylethenyl, 1-butenyl, 2-butenyl, 3-butenyl, 1-methyl- 1-propenyl, 2-methyl-1-propenyl, 1-methyl-2-propenyl, 2-methyl-2-propenyl, 1-pentenyl, 2- pentenyl, 3-pentenyl, 4-pentenyl, 1-methyl-1-butenyl, 2-methyl-1-butenyl, 3-methyl-1- butenyl, 1-methyl-2-butenyl, 2-methyl-2-butenyl, 3-methyl-2-butenyl, 1-methyl-3-butenyl, 2- methyl-3-butenyl, 3-methyl-3-butenyl, 1,1-dimethyl-2-propenyl, 1,2-dimethyl-1-propenyl, 1,2-dimethyl-2-propenyl, 1-ethyl-1-propenyl, 1-ethyl-2-propenyl, 1-hexenyl, 2-hexenyl, 3- hexenyl, 4-hexenyl, 5-hexenyl, 1-methyl-1-pentenyl, 2-methyl-1-pentenyl, 3-methyl-1- pentenyl, 4-methyl-1-pentenyl, 1-methyl-2-pentenyl, 2-methyl-2-pentenyl, 3-methyl-2- pentenyl, 4-methyl-2-pentenyl, 1-methyl-3-pentenyl, 2-methyl-3-pentenyl, 3-methyl-3- pentenyl, 4-methyl-3-pentenyl, 1-methyl-4-pentenyl, 2-methyl-4-pentenyl, 3-methyl-4- pentenyl, 4-methyl-4-pentenyl, 1,1-dimethyl-2-butenyl, 1,1-dimethyl-3-butenyl, 1,2-dimethyl- 1-butenyl, 1,2-dimethyl-2-butenyl, 1,2-dimethyl-3-butenyl, 1,3-dimethyl-1-butenyl, 1,3- dimethyl-2-butenyl, 1,3-dimethyl-3-butenyl, 2,2-dimethyl-3-butenyl, 2,3-dimethyl-1-butenyl, 2,3-dimethyl-2-butenyl, 2,3-dimethyl-3-butenyl, 3,3-dimethyl-1-butenyl, 3,3-dimethyl-2- butenyl, 1-ethyl-1-butenyl, 1-ethyl-2-butenyl, 1-ethyl-3-butenyl, 2-ethyl-1-butenyl, 2-ethyl-2- butenyl, 2-ethyl-3-butenyl, 1,1,2-trimethyl-2-propenyl, 1-ethyl-1-methyl-2-propenyl, 1-ethyl- 2-methyl-1-propenyl, and 1-ethyl-2-methyl-2-propenyl. Vinyl refers to a group having the strutcture –CH=CH2; 1-propenyl refers to a group with the structure–CH=CH-CH3; and 2- propenyl refers to a group with the structure –CH2-CH=CH2. As used herein, “alkynyl” represents straight-chained or branched hydrocarbon moieties containing a triple bond. Unless otherwise specified, C3-C16 alkynyl groups are intended. Alkynyl groups may contain more than one unsaturated bond. Examples include C2- C6-alkynyl, such as ethynyl, 1-propynyl, 2-propynyl (or propargyl), 1-butynyl, 2-butynyl, 3- butynyl, 1-methyl-2-propynyl, 1-pentynyl, 2-pentynyl, 3-pentynyl, 4-pentynyl, 3-methyl-1- butynyl, 1-methyl-2-butynyl, 1-methyl-3-butynyl, 2-methyl-3-butynyl, 1,1-dimethyl-2- propynyl, 1-ethyl-2-propynyl, 1-hexynyl, 2-hexynyl, 3-hexynyl, 4-hexynyl, 5-hexynyl, 3- methyl-1-pentynyl, 4-methyl-1-pentynyl, 1-methyl-2-pentynyl, 4-methyl-2-pentynyl, 1- methyl-3-pentynyl, 2-methyl-3-pentynyl, 1-methyl-4-pentynyl, 2-methyl-4-pentynyl, 3- methyl-4-pentynyl, 1,1-dimethyl-2-butynyl, 1,1-dimethyl-3-butynyl, 1,2-dimethyl-3-butynyl, 2,2-dimethyl-3-butynyl, 3,3-dimethyl-1-butynyl, 1-ethyl-2-butynyl, 1-ethyl-3-butynyl, 2- ethyl-3-butynyl, and 1-ethyl-1-methyl-2-propynyl. As used herein, “alkoxy” refers to a group of the formula R-O-, where R is alkyl as defined above. Unless otherwise specified, alkoxy groups wherein R is a C 1 -C 10 alkyl group are intended. Examples include methoxy, ethoxy, propoxy, 1-methyl-ethoxy, butoxy, 1- methyl-propoxy, 2-methyl-propoxy, 1,1-dimethyl-ethoxy, pentoxy, 1-methyl-butyloxy, 2- methyl-butoxy, 3-methyl-butoxy, 2,2-dimethyl-propoxy, 1-ethyl-propoxy, hexoxy, 1,1- dimethyl-propoxy, 1,2-dimethyl-propoxy, 1-methyl-pentoxy, 2-methyl-pentoxy, 3-methyl- pentoxy, 4-methyl-pentoxy, 1,1-dimethyl-butoxy, 1,2-dimethyl-butoxy, 1,3-dimethyl-butoxy, 2,2-dimethyl-butoxy, 2,3-dimethyl-butoxy, 3,3-dimethyl-butoxy, 1-ethyl-butoxy, 2-ethyl- butoxy, 1,1,2-trimethyl-propoxy, 1,2,2-trimethyl-propoxy, 1-ethyl-1-methyl-propoxy, and 1- ethyl-2-methyl-propoxy. As used herein, “haloalkoxy” refers to a group of the formula R-O-, where R is haloalkyl as defined above. Unless otherwise specified, haloalkoxy groups wherein R is a C 1 - C 10 alkyl group are intended. Examples include chloromethoxy, bromomethoxy, dichloromethoxy, trichloromethoxy, fluoromethoxy, difluoromethoxy, trifluoromethoxy, chlorofluoromethoxy, dichlorofluoromethoxy, chlorodifluoromethoxy, 1-chloroethoxy, 1- bromoethoxy, 1-fluoroethoxy, 2-fluoroethoxy, 2,2-difluoroethoxy, 2,2,2-trifluoroethoxy, 2- chloro-2-fluoroethoxy, 2-chloro-2,2-difluoroethoxy, 2,2-dichloro-2-fluoroethoxy, 2,2,2- trichloroethoxy, pentafluoroethoxy, and 1,1,1-trifluoroprop-2-oxy. As used herein, “alkylthio” refers to a group of the formula R-S- where R is alkyl as defined above. Unless otherwise specified, alkylthio groups wherein R is a C 1 -C 10 alkyl group are intended. Examples include methylthio, ethylthio, propylthio, 1-methylethylthio, butylthio, 1-methyl-propylthio, 2-methylpropylthio, 1,1-dimethylethylthio, pentylthio, 1- methylbutylthio, 2-methylbutylthio, 3-methylbutylthio, 2,2-dimethylpropylthio, 1- ethylpropylthio, hexylthio, 1,1-dimethylpropylthio, 1,2-dimethylpropylthio, 1- methylpentylthio, 2-methylpentylthio, 3-methylpentylthio, 4-methylpentylthio, 1,1- dimethylbutylthio, 1,2-dimethylbutylthio, 1,3-dimethylbutylthio, 2,2-dimethylbutylthio, 2,3- dimethylbutylthio, 3,3-dimethylbutylthio, 1-ethylbutylthio, 2-ethylbutylthio, 1,1,2- trimethylpropylthio, 1,2,2-trimethylpropylthio, 1-ethyl-1-methylpropylthio, and 1-ethyl-2- methylpropylthio. As used herein, “haloalkylthio” refers to an alkylthio group as defined above wherein the carbon atoms are substituted partially or entirely with halogen atoms. Unless otherwise specified, haloalkylthio groups wherein R is a C 1 -C 8 alkyl group are intended. Examples include chloromethylthio, bromomethylthio, dichloromethylthio, trichloromethylthio, fluoromethylthio, difluoromethylthio, trifluoromethylthio, chlorofluoromethylthio, dichlorofluoromethylthio, chlorodifluoromethylthio, 1- chloroethylthio, 1-bromoethylthio, 1-fluoroethylthio, 2-fluoroethylthio, 2,2-difluoroethylthio, 2,2,2-trifluoroethylthio, 2-chloro-2-fluoroethylthio, 2-chloro-2,2-difluoroethylthio, 2,2- dichloro-2-fluoroethylthio, 2,2,2-trichloroethylthio, pentafluoroethylthio, and 1,1,1- trifluoroprop-2-ylthio. As used herein, “aryl”, as well as derivative terms such as aryloxy, refers to a phenyl, indanyl or naphthyl group with phenyl being preferred. The term heteroaryl, as well as derivative terms such as heteroaryloxy, refers to a 5- or 6-membered aromatic ring containing one or more heteroatoms, viz., N, O or S; these aromatic and heteroaromatic rings may be fused to other aromatic and/or heteroaromatic systems. The aryl or heteroaryl substituents may be unsubstituted or substituted with one or more substituents selected from halogen, hydroxy, nitro, cyano, formyl, C 1 -C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkyl, C 1 -C 6 haloalkoxy, C 1 -C 6 acyl, C 1 -C 6 alkylthio, C 1 -C 6 alkylsulfinyl, C 1 -C 6 alkylsulfonyl, C 1 -C 6 alkoxycarbonyl, C 1 -C 6 carbamoyl, hydroxycarbonyl, C 1 -C 6 alkylcarbonyl, aminocarbonyl, C 1 - C 6 alkylaminocarbonyl, C 1 -C 6 dialkylaminocarbonyl, provided that the substituents are sterically compatible and the rules of chemical bonding and strain energy are satisfied. As used herein “alkylcarbonyl” refers to an alkyl group bonded to a carbonyl group. C1-C3 alkylcarbonyl and C1-C3 haloalkylcarbonyl refer to groups wherein a C1-C3 alkyl group is bonded to a carbonyl group (the group contains a total of 2 to 4 carbon atoms). O As used herein, “alkoxycarbonyl” refers to a group of the formula wherein R is alkyl. As used herein, “arylalkyl” refers to an alkyl group substituted with an aryl group. C 7 -C 10 arylalkyl refers to a group wherein the total number of carbon atoms in the group is 7 to 10. As used herein alkylamino refers to an amino group substituted with one or two alkyl groups, which may be the same or different. As used herein haloalkylamino refers to an alkylamino group wherein the alkyl carbon atoms are substituted partially or entirely with halogen atoms. As used herein, C1-C6 alkylaminocarbonyl refers to a group of the formula RNHC(O)- wherein R is C1-C6 alkyl, and C1-C6 dialkylaminocarbonyl refers to a group of the formula R2NC(O)- wherein each R is independently C1-C6 alkyl. As used herein alkylcarbamyl refers to a carbamyl group substituted on the nitrogen with an alkyl group. As used herein “alkyl-sulfonyl” refers to a group of the formula , where R is alkyl. As used herein carbamyl (also referred to as carbamoyl and aminocarbonyl) refers to a group of the formula . As used herein dialkylphosponyl refers to a group of the formula where R is independently alkyl in each occurrence. As used herein, C1-C6 trialkylsilyl refers to a group of the formula –SiR3 wherein each R is independently a C1-C6 alkyl group (the group contains a total of 3 to 18 carbon atoms). As used herein Me refers to a methyl group; OMe refers to a methoxy group; i-Pr refers to an isopropyl group. As used herein, the term halogen including derivative terms such as halo refers to fluorine, chlorine, bromine and iodine. As used herein, agriculturally acceptable salts and esters refer to salts and esters that exhibit herbicidal activity or that are or can be converted in plants, water, or soil to the referenced herbicide. Exemplary agriculturally acceptable esters are those that are or can by hydrolyzed, oxidized, metabolized, or otherwise converted, e.g., in plants, water, or soil, to the corresponding carboxylic acid which, depending on the pH, may be in the dissociated or undissociated form. As used herein, "active ingredient" or "ai" refers to a chemical compound or composition that has an effect on vegetation, for example, a herbicidal effect or a safening effect on the vegetation. As used herein, "acid equivalent" or "ae" refers to the amount of the acid form of an active ingredient that is calculated from the amount of a salt or ester form of that active ingredient. For example, if the acid form of an active ingredient "Z" has a molecular weight of 100 Dalton, and the salt form of Z has a molecular weight of 130 Dalton, an application of 130 grams of active ingredient per hectare (g ai/ha) of the Z salt would be equal to applying 100 grams of acid equivalent per hectare (g ae/ha) of the acid form of Z: 130 g ai/ha Z salt * (100 Da Z acid / 130 Da Z salt) = 100 g ae/ha Z acid. 2. Substituted 5-Membered Ring Molecules Disclosed herein are substituted 5-membered ring molecules, such as substituted lactam-molecules or thiolactam-molecules, that may be used as herbicides to control undesirable vegetation in various locations, such as croplands, lawns, pastures, gardens, and recreational areas. The molecules include molecules that are substituted with fluorinated benzyl groups and amino acid groups, and derivatives thereof. In some aspects, the substituted 5-membered ring molecules are molecules of Formula (I): Formula (I) wherein: X is selected from the group consisting of O and S; Y is selected from the group consisting of O, NR 5 , or S; R 1 is selected from the group consisting of H and F; R 2 is selected from the group consisting of methyl and cyclopropyl; R 3 is selected from the group consisting of H, methyl, and methoxy; R 4 is selected from the group consisting of H, (C 1 -C 16 )-alkyl, (C 3 -C 10 )-cycloalkyl, (C 3 -C 16 )-alkenyl, (C 3 -C 16 )-alkynyl, (C 1 -C 10 )-alkyl-aryl, aryl, (C 1 -C 10 )-alkyl-heteroaryl, heteroaryl, (C 1 -C 10 )-alkyl-cyano, (C 1 -C 16 )-haloalkyl, (C 1 -C 10 )-alkoxy-(C 1 -C 10 )-alkyl, (C 1 - C 10 )-alkylthio-(C 1 -C 10 )-alkyl, (C 1 -C 10 )-alkyl-sulfonyl-(C 1 -C 10 )-alkyl, R 72 R 73 N, SiR 75 R 76 R 77 , (C 1 -C 10 )-alkyl-SiR 75 R 76 R 77 , R 78 R 79 C=N, (C 1 -C 10 )-alkyl-C(=O)QR 70 , aryl-(C 1 -C 10 )-alkyl- C(=O)QR 70 , heteroaryl-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 3 -C 10 )-cycloalkyl-(C 1 -C 10 )-alkyl- C(=O)QR 70 , R 70 QC(=O)-(C 1 -C 10 )-alkyl-C(=O)QR 71 , R 70 QC(=O)Q-(C 1 -C 10 )-alkyl- C(=O)QR 71 , hydroxy-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 1 -C 10 )-alkylthio-(C 1 -C 10 )-alkyl- C(=O)QR 70 , and (R 80 O) 2 P(=O)-(C 1 -C 10 )-alkyl; Q is selected from the group consisting of O, S, and NR 71 , R 70 , R 71 , R 72 , R 73 , R 74 , and R 80 are independently selected from the group consisting of H, (C 1 -C 16 )-alkyl, aryl, heteroaryl, (C 1 -C 16 )-alkyl-aryl, and (C 1 -C 16 )-haloalkyl; R 72 and R 73 together form a substituted or unsubstituted ring; R 75 , R 76 , and R 77 are independently selected from the group consisting of (C 1 -C 16 )- alkyl and aryl; R 78 and R 79 are independently selected from the group consisting of (C 1 -C 16 )-alkyl, (C 1 -C 16 )-alkyl-aryl, (C 1 -C 16 )-haloalkyl, aryl, and heteroaryl; R 78 and R 79 together form a substituted or unsubstituted ring; and R 5 is selected from the group consisting of H, (C 1 -C 16 )-alkyl, (C 3 -C 16 )-alkenyl, (C 3 - C 16 )-alkynyl, (C 1 -C 10 )-alkyl-aryl, (C 1 -C 10 )-alkoxy, (C 3 -C 10 )-alkenyloxy, (C 3 -C 10 )-alkynyloxy, aryl-(C 1 -C 10 )-alkoxy, heterocyclyl-alkoxy, hydroxy, (C 1 -C 10 )-alkyl-sulfonyl, (C 3 -C 8 )- cycloalkyl-sulfonyl, (C 3 -C 8 )-cycloalkyl-(C 1 -C 10 )-alkyl-sulfonyl, aryl-sulfonyl, heteroaryl- sulfonyl, R 72 R 73 N-sulfonyl, (C 1 -C 10 )-alkoxy-NR 74 -sulfonyl, and aryl-oxy-sulfonyl. In some aspects, the lactam-based molecules are molecules of Formula (II): Formula (II) wherein: R 1 is selected from the group consisting of H and F; R 2 is selected from the group consisting of methyl and cyclopropyl; R 3 is selected from the group consisting of H, methyl, and methoxy; R 4 is selected from the group consisting of H, (C 1 -C 16 )-alkyl, (C 3 -C 10 )-cycloalkyl, (C 3 -C 16 )-alkenyl, (C 3 -C 16 )-alkynyl, (C 1 -C 10 )-alkyl-aryl, aryl, (C 1 -C 10 )-alkyl-heteroaryl, heteroaryl, (C 1 -C 10 )-alkyl-cyano, (C 1 -C 16 )-haloalkyl, (C 1 -C 10 )-alkoxy-(C 1 -C 10 )-alkyl, (C 1 - C 10 )-alkylthio-(C 1 -C 10 )-alkyl, (C 1 -C 10 )-alkyl-sulfonyl-(C 1 -C 10 )-alkyl, R 72 R 73 N, SiR 75 R 76 R 77 , (C 1 -C 10 )-alkyl-SiR 75 R 76 R 77 , R 78 R 79 C=N, (C 1 -C 10 )-alkyl-C(=O)QR 70 , aryl-(C 1 -C 10 )-alkyl- C(=O)QR 70 , heteroaryl-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 3 -C 10 )-cycloalkyl-(C 1 -C 10 )-alkyl- C(=O)QR 70 , R 70 QC(=O)-(C 1 -C 10 )-alkyl-C(=O)QR 71 , R 70 QC(=O)Q-(C 1 -C 10 )-alkyl- C(=O)QR 71 , hydroxy-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 1 -C 10 )-alkylthio-(C 1 -C 10 )-alkyl- C(=O)QR 70 , and (R 80 O) 2 P(=O)-(C 1 -C 10 )-alkyl; Q is selected from the group consisting of O, S, or NR 71 , R 70 , R 71 , R 72 , R 73 , R 74 , and R 80 are independently selected from the group consisting of H, (C 1 -C 16 )-alkyl, aryl, heteroaryl, (C 1 -C 16 )-alkyl-aryl, and (C 1 -C 16 )-haloalkyl; R 72 and R 73 together form a substituted or unsubstituted ring; R 75 , R 76 , and R 77 are independently selected from the group consisting of (C 1 -C 16 )- alkyl and aryl; R 78 and R 79 are independently selected from the group consisting of (C 1 -C 16 )-alkyl, (C 1 -C 16 )-alkyl-aryl, (C 1 -C 16 )-haloalkyl, aryl, and heteroaryl; and R 78 and R 79 together form a substituted or unsubstituted ring. In some aspects, the lactam-based molecules are molecules of Formula (III) Formula (III) wherein: R 1 is selected from the group consisting of H and F; R 4 is selected from the group consisting of H, (C 1 -C 16 )-alkyl, (C 3 -C 10 )-cycloalkyl, (C 3 -C 16 )-alkenyl, (C 3 -C 16 )-alkynyl, (C 1 -C 10 )-alkyl-aryl, aryl, (C 1 -C 10 )-alkyl-heteroaryl, heteroaryl, (C 1 -C 10 )-alkyl-cyano, (C 1 -C 16 )-haloalkyl, (C 1 -C 10 )-alkoxy-(C 1 -C 10 )-alkyl, (C 1 - C 10 )-alkylthio-(C 1 -C 10 )-alkyl, (C 1 -C 10 )-alkyl-sulfonyl-(C 1 -C 10 )-alkyl, R 72 R 73 N, SiR 75 R 76 R 77 , (C 1 -C 10 )-alkyl-SiR 75 R 76 R 77 , R 78 R 79 C=N, (C 1 -C 10 )-alkyl-C(=O)QR 70 , aryl-(C 1 -C 10 )-alkyl- C(=O)QR 70 , heteroaryl-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 3 -C 10 )-cycloalkyl-(C 1 -C 10 )-alkyl- C(=O)QR 70 , R 70 QC(=O)-(C 1 -C 10 )-alkyl-C(=O)QR 71 , R 70 QC(=O)Q-(C 1 -C 10 )-alkyl- C(=O)QR 71 , hydroxy-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 1 -C 10 )-alkylthio-(C 1 -C 10 )-alkyl- C(=O)QR 70 , and (R 80 O) 2 P(=O)-(C 1 -C 10 )-alkyl; Q is selected from the group consisting of O, S, or NR 71 , R 70 , R 71 , R 72 , R 73 , R 74 , and R 80 are independently selected from the group consisting of H, (C 1 -C 16 )-alkyl, aryl, heteroaryl, (C 1 -C 16 )-alkyl-aryl, and (C 1 -C 16 )-haloalkyl; R 72 and R 73 together form a substituted or unsubstituted ring; R 75 , R 76 , and R 77 are independently selected from the group consisting of (C 1 -C 16 )- alkyl and aryl; R 78 and R 79 are independently selected from the group consisting of (C 1 -C 16 )-alkyl, (C 1 -C 16 )-alkyl-aryl, (C 1 -C 16 )-haloalkyl, aryl, and heteroaryl; and R 78 and R 79 together form a substituted or unsubstituted ring. In some aspects, the thiolactam-based molecules are molecules of Formula (IV): wherein: X is selected from O or S; R 1 is selected from H or F; R 4 is selected from the group consisting of H, (C 1 -C 16 )-alkyl, (C 3 -C 10 )-cycloalkyl, (C 3 -C 16 )-alkenyl, (C 3 -C 16 )-alkynyl, (C 1 -C 10 )-alkyl-aryl, aryl, (C 1 -C 10 )-alkyl-heteroaryl, heteroaryl, (C 1 -C 10 )-alkyl-cyano, (C 1 -C 16 )-haloalkyl, (C 1 -C 10 )-alkoxy-(C 1 -C 10 )-alkyl, (C 1 - C 10 )-alkylthio-(C 1 -C 10 )-alkyl, (C 1 -C 10 )-alkyl-sulfonyl-(C 1 -C 10 )-alkyl, R 72 R 73 N, SiR 75 R 76 R 77 , (C 1 -C 10 )-alkyl-SiR 75 R 76 R 77 , R 78 R 79 C=N, (C 1 -C 10 )-alkyl-C(=O)QR 70 , aryl-(C 1 -C 10 )-alkyl- C(=O)QR 70 , heteroaryl-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 3 -C 10 )-cycloalkyl-(C 1 -C 10 )-alkyl- C(=O)QR 70 , R 70 QC(=O)-(C 1 -C 10 )-alkyl-C(=O)QR 71 , R 70 QC(=O)Q-(C 1 -C 10 )-alkyl- C(=O)QR 71 , hydroxy-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 1 -C 10 )-alkylthio-(C 1 -C 10 )-alkyl- C(=O)QR 70 , and (R 80 O) 2 P(=O)-(C 1 -C 10 )-alkyl; Q is selected from the group consisting of O, S, or NR 71 , X is selected from the group consisting of O and S, R 70 , R 71 , R 72 , R 73 , R 74 , and R 80 are independently selected from the group consisting of H, (C 1 -C 16 )-alkyl, aryl, heteroaryl, (C 1 -C 16 )-alkyl-aryl, and (C 1 -C 16 )-haloalkyl; R 72 and R 73 together form a substituted or unsubstituted ring; R 75 , R 76 , and R 77 are independently selected from the group consisting of (C 1 -C 16 )- alkyl and aryl; R 78 and R 79 are independently selected from the group consisting of (C 1 -C 16 )-alkyl, (C 1 -C 16 )-alkyl-aryl, (C 1 -C 16 )-haloalkyl, aryl, and heteroaryl; and R 78 and R 79 together form a substituted or unsubstituted ring. In some aspects, the substituted 5-membered ring molecules are molecules of Formula (V): Formula (V) wherein R 4 is selected from the group consisting of H, (C 1 -C 16 )-alkyl, (C 3 -C 10 )- cycloalkyl, (C 3 -C 16 )-alkenyl, (C 3 -C 16 )-alkynyl, (C 1 -C 10 )-alkyl-aryl, aryl, (C 1 -C 10 )-alkyl- heteroaryl, heteroaryl, (C 1 -C 10 )-alkyl-cyano, (C 1 -C 16 )-haloalkyl, (C 1 -C 10 )-alkoxy-(C 1 -C 10 )- alkyl, (C 1 -C 10 )-alkylthio-(C 1 -C 10 )-alkyl, (C 1 -C 10 )-alkyl-sulfonyl-(C 1 -C 10 )-alkyl, R 72 R 73 N, SiR 75 R 76 R 77 , (C 1 -C 10 )-alkyl-SiR 75 R 76 R 77 , R 78 R 79 C=N, (C 1 -C 10 )-alkyl-C(=O)QR 70 , aryl-(C 1 - C 10 )-alkyl-C(=O)QR 70 , heteroaryl-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 3 -C 10 )-cycloalkyl-(C 1 -C 10 )- alkyl-C(=O)QR 70 , R 70 QC(=O)-(C 1 -C 10 )-alkyl-C(=O)QR 71 , R 70 QC(=O)Q-(C 1 -C 10 )-alkyl- C(=O)QR 71 , hydroxy-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 1 -C 10 )-alkylthio-(C 1 -C 10 )-alkyl- C(=O)QR 70 , and (R 80 O) 2 P(=O)-(C 1 -C 10 )-alkyl; Q is selected from the group consisting of O, S, or NR 71 , R 70 , R 71 , R 72 , R 73 , R 74 , and R 80 are independently selected from the group consisting of H, (C 1 -C 16 )-alkyl, aryl, heteroaryl, (C 1 -C 16 )-alkyl-aryl, and (C 1 -C 16 )-haloalkyl; R 72 and R 73 together form a substituted or unsubstituted ring; R 75 , R 76 , and R 77 are independently selected from the group consisting of (C 1 -C 16 )- alkyl and aryl; R 78 and R 79 are independently selected from the group consisting of (C 1 -C 16 )-alkyl, (C 1 -C 16 )-alkyl-aryl, (C 1 -C 16 )-haloalkyl, aryl, and heteroaryl; and R 78 and R 79 together form a substituted or unsubstituted ring. In some aspects, the substituted 5-membered ring molecules are molecules of Formula (VI): Formula (VI) wherein R 4 is selected from the group consisting of H, (C 1 -C 16 )-alkyl, (C 3 -C 10 )- cycloalkyl, (C 3 -C 16 )-alkenyl, (C 3 -C 16 )-alkynyl, (C 1 -C 10 )-alkyl-aryl, aryl, (C 1 -C 10 )-alkyl- heteroaryl, heteroaryl, (C 1 -C 10 )-alkyl-cyano, (C 1 -C 16 )-haloalkyl, (C 1 -C 10 )-alkoxy-(C 1 -C 10 )- alkyl, (C 1 -C 10 )-alkylthio-(C 1 -C 10 )-alkyl, (C 1 -C 10 )-alkyl-sulfonyl-(C 1 -C 10 )-alkyl, R 72 R 73 N, SiR 75 R 76 R 77 , (C 1 -C 10 )-alkyl-SiR 75 R 76 R 77 , R 78 R 79 C=N, (C 1 -C 10 )-alkyl-C(=O)QR 70 , aryl-(C 1 - C 10 )-alkyl-C(=O)QR 70 , heteroaryl-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 3 -C 10 )-cycloalkyl-(C 1 -C 10 )- alkyl-C(=O)QR 70 , R 70 QC(=O)-(C 1 -C 10 )-alkyl-C(=O)QR 71 , R 70 QC(=O)Q-(C 1 -C 10 )-alkyl- C(=O)QR 71 , hydroxy-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 1 -C 10 )-alkylthio-(C 1 -C 10 )-alkyl- C(=O)QR 70 , and (R 80 O) 2 P(=O)-(C 1 -C 10 )-alkyl; Q is selected from the group consisting of O, S, or NR 71 , R 70 , R 71 , R 72 , R 73 , R 74 , and R 80 are independently selected from the group consisting of H, (C 1 -C 16 )-alkyl, aryl, heteroaryl, (C 1 -C 16 )-alkyl-aryl, and (C 1 -C 16 )-haloalkyl; R 72 and R 73 together form a substituted or unsubstituted ring; R 75 , R 76 , and R 77 are independently selected from the group consisting of (C 1 -C 16 )- alkyl and aryl; R 78 and R 79 are independently selected from the group consisting of (C 1 -C 16 )-alkyl, (C 1 -C 16 )-alkyl-aryl, (C 1 -C 16 )-haloalkyl, aryl, and heteroaryl; and R 78 and R 79 together form a substituted or unsubstituted ring. In some aspects, the lactam-based molecules are molecules of Formula (VII): Formula (VII) wherein R 4 is selected from the group consisting of H, (C 1 -C 16 )-alkyl, (C 3 -C 10 )- cycloalkyl, (C 3 -C 16 )-alkenyl, (C 3 -C 16 )-alkynyl, (C 1 -C 10 )-alkyl-aryl, aryl, (C 1 -C 10 )-alkyl- heteroaryl, heteroaryl, (C 1 -C 10 )-alkyl-cyano, (C 1 -C 16 )-haloalkyl, (C 1 -C 10 )-alkoxy-(C 1 -C 10 )- alkyl, (C 1 -C 10 )-alkylthio-(C 1 -C 10 )-alkyl, (C 1 -C 10 )-alkyl-sulfonyl-(C 1 -C 10 )-alkyl, R 72 R 73 N, SiR 75 R 76 R 77 , (C 1 -C 10 )-alkyl-SiR 75 R 76 R 77 , R 78 R 79 C=N, (C 1 -C 10 )-alkyl-C(=O)QR 70 , aryl-(C 1 - C 10 )-alkyl-C(=O)QR 70 , heteroaryl-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 3 -C 10 )-cycloalkyl-(C 1 -C 10 )- alkyl-C(=O)QR 70 , R 70 QC(=O)-(C 1 -C 10 )-alkyl-C(=O)QR 71 , R 70 QC(=O)Q-(C 1 -C 10 )-alkyl- C(=O)QR 71 , hydroxy-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 1 -C 10 )-alkylthio-(C 1 -C 10 )-alkyl- C(=O)QR 70 , and (R 80 O) 2 P(=O)-(C 1 -C 10 )-alkyl; Q is selected from the group consisting of O, S, or NR 71 , R 70 , R 71 , R 72 , R 73 , R 74 , and R 80 are independently selected from the group consisting of H, (C 1 -C 16 )-alkyl, aryl, heteroaryl, (C 1 -C 16 )-alkyl-aryl, and (C 1 -C 16 )-haloalkyl; R 72 and R 73 together form a substituted or unsubstituted ring; R 75 , R 76 , and R 77 are independently selected from the group consisting of (C 1 -C 16 )- alkyl and aryl; R 78 and R 79 are independently selected from the group consisting of (C 1 -C 16 )-alkyl, (C 1 -C 16 )-alkyl-aryl, (C 1 -C 16 )-haloalkyl, aryl, and heteroaryl; and R 78 and R 79 together form a substituted or unsubstituted ring. In some aspects, the lactam-based molecules are molecules of Formula (VIII): Formula (VIII) wherein R 4 is selected from the group consisting of H, (C 1 -C 16 )-alkyl, (C 3 -C 10 )- cycloalkyl, (C 3 -C 16 )-alkenyl, (C 3 -C 16 )-alkynyl, (C 1 -C 10 )-alkyl-aryl, aryl, (C 1 -C 10 )-alkyl- heteroaryl, heteroaryl, (C 1 -C 10 )-alkyl-cyano, (C 1 -C 16 )-haloalkyl, (C 1 -C 10 )-alkoxy-(C 1 -C 10 )- alkyl, (C 1 -C 10 )-alkylthio-(C 1 -C 10 )-alkyl, (C 1 -C 10 )-alkyl-sulfonyl-(C 1 -C 10 )-alkyl, R 72 R 73 N, SiR 75 R 76 R 77 , (C 1 -C 10 )-alkyl-SiR 75 R 76 R 77 , R 78 R 79 C=N, (C 1 -C 10 )-alkyl-C(=O)QR 70 , aryl-(C 1 - C 10 )-alkyl-C(=O)QR 70 , heteroaryl-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 3 -C 10 )-cycloalkyl-(C 1 -C 10 )- alkyl-C(=O)QR 70 , R 70 QC(=O)-(C 1 -C 10 )-alkyl-C(=O)QR 71 , R 70 QC(=O)Q-(C 1 -C 10 )-alkyl- C(=O)QR 71 , hydroxy-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 1 -C 10 )-alkylthio-(C 1 -C 10 )-alkyl- C(=O)QR 70 , and (R 80 O) 2 P(=O)-(C 1 -C 10 )-alkyl; Q is selected from the group consisting of O, S, or NR 71 , R 70 , R 71 , R 72 , R 73 , R 74 , and R 80 are independently selected from the group consisting of H, (C 1 -C 16 )-alkyl, aryl, heteroaryl, (C 1 -C 16 )-alkyl-aryl, and (C 1 -C 16 )-haloalkyl; R 72 and R 73 together form a substituted or unsubstituted ring; R 75 , R 76 , and R 77 are independently selected from the group consisting of (C 1 -C 16 )- alkyl and aryl; R 78 and R 79 are independently selected from the group consisting of (C 1 -C 16 )-alkyl, (C 1 -C 16 )-alkyl-aryl, (C 1 -C 16 )-haloalkyl, aryl, and heteroaryl; and R 78 and R 79 together form a substituted or unsubstituted ring. In some aspects, the lactam-based molecules are molecules of Formula (IX):
Formula (IX) wherein R 4 is selected from the group consisting of H, (C 1 -C 16 )-alkyl, (C 3 -C 10 )- cycloalkyl, (C 3 -C 16 )-alkenyl, (C 3 -C 16 )-alkynyl, (C 1 -C 10 )-alkyl-aryl, aryl, (C 1 -C 10 )-alkyl- heteroaryl, heteroaryl, (C 1 -C 10 )-alkyl-cyano, (C 1 -C 16 )-haloalkyl, (C 1 -C 10 )-alkoxy-(C 1 -C 10 )- alkyl, (C 1 -C 10 )-alkylthio-(C 1 -C 10 )-alkyl, (C 1 -C 10 )-alkyl-sulfonyl-(C 1 -C 10 )-alkyl, R 72 R 73 N, SiR 75 R 76 R 77 , (C 1 -C 10 )-alkyl-SiR 75 R 76 R 77 , R 78 R 79 C=N, (C 1 -C 10 )-alkyl-C(=O)QR 70 , aryl-(C 1 - C 10 )-alkyl-C(=O)QR 70 , heteroaryl-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 3 -C 10 )-cycloalkyl-(C 1 -C 10 )- alkyl-C(=O)QR 70 , R 70 QC(=O)-(C 1 -C 10 )-alkyl-C(=O)QR 71 , R 70 QC(=O)Q-(C 1 -C 10 )-alkyl- C(=O)QR 71 , hydroxy-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 1 -C 10 )-alkylthio-(C 1 -C 10 )-alkyl- C(=O)QR 70 , and (R 80 O) 2 P(=O)-(C 1 -C 10 )-alkyl; Q is selected from the group consisting of O, S, or NR 71 , R 70 , R 71 , R 72 , R 73 , R 74 , and R 80 are independently selected from the group consisting of H, (C 1 -C 16 )-alkyl, aryl, heteroaryl, (C 1 -C 16 )-alkyl-aryl, and (C 1 -C 16 )-haloalkyl; R 72 and R 73 together form a substituted or unsubstituted ring; R 75 , R 76 , and R 77 are independently selected from the group consisting of (C 1 -C 16 )- alkyl and aryl; R 78 and R 79 are independently selected from the group consisting of (C 1 -C 16 )-alkyl, (C 1 -C 16 )-alkyl-aryl, (C 1 -C 16 )-haloalkyl, aryl, and heteroaryl; and R 78 and R 79 together form a substituted or unsubstituted ring. In some aspects, the lactam-based molecules are molecules of Formula (X):
Formula (X) wherein R 4 is selected from the group consisting of H, (C 1 -C 16 )-alkyl, (C 3 -C 10 )- cycloalkyl, (C 3 -C 16 )-alkenyl, (C 3 -C 16 )-alkynyl, (C 1 -C 10 )-alkyl-aryl, aryl, (C 1 -C 10 )-alkyl- heteroaryl, heteroaryl, (C 1 -C 10 )-alkyl-cyano, (C 1 -C 16 )-haloalkyl, (C 1 -C 10 )-alkoxy-(C 1 -C 10 )- alkyl, (C 1 -C 10 )-alkylthio-(C 1 -C 10 )-alkyl, (C 1 -C 10 )-alkyl-sulfonyl-(C 1 -C 10 )-alkyl, R 72 R 73 N, SiR 75 R 76 R 77 , (C 1 -C 10 )-alkyl-SiR 75 R 76 R 77 , R 78 R 79 C=N, (C 1 -C 10 )-alkyl-C(=O)QR 70 , aryl-(C 1 - C 10 )-alkyl-C(=O)QR 70 , heteroaryl-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 3 -C 10 )-cycloalkyl-(C 1 -C 10 )- alkyl-C(=O)QR 70 , R 70 QC(=O)-(C 1 -C 10 )-alkyl-C(=O)QR 71 , R 70 QC(=O)Q-(C 1 -C 10 )-alkyl- C(=O)QR 71 , hydroxy-(C 1 -C 10 )-alkyl-C(=O)QR 70 , (C 1 -C 10 )-alkylthio-(C 1 -C 10 )-alkyl- C(=O)QR 70 , and (R 80 O) 2 P(=O)-(C 1 -C 10 )-alkyl; Q is selected from the group consisting of O, S, or NR 71 , R 70 , R 71 , R 72 , R 73 , R 74 , and R 80 are independently selected from the group consisting of H, (C 1 -C 16 )-alkyl, aryl, heteroaryl, (C 1 -C 16 )-alkyl-aryl, and (C 1 -C 16 )-haloalkyl; R 72 and R 73 together form a substituted or unsubstituted ring; R 75 , R 76 , and R 77 are independently selected from the group consisting of (C 1 -C 16 )- alkyl and aryl; R 78 and R 79 are independently selected from the group consisting of (C1-C 16 )-alkyl, (C 1 -C 16 )-alkyl-aryl, (C 1 -C 16 )-haloalkyl, aryl, and heteroaryl; and R 78 and R 79 together form a substituted or unsubstituted ring. In some aspects, the substituted 5-membered ring molecules include the molecules given below as Compound A to Compound O. Table 1B: Exemplary Substituted 5-Membered Ring Molecules E 小 The substituted 5-membered ring molecules of the present disclosure exist in specific chiral forms, as shown in the molecular structures shown above. However, the substituted 5-membered ring molecules may also exist in different geometric or optical isomeric forms at other locations within each molecule. It will be appreciated by those skilled in the art, with the benefit of this disclosure, that one stereoisomer may be more active than the other stereoisomers. Individual stereoisomers may be obtained by known selective synthetic procedures, by conventional synthetic procedures using resolved starting materials, or by conventional resolution procedures, using the procedures and compositions disclosed herein. This disclosure covers all such chiral forms, isomers, and mixtures thereof, in all proportions. For example, while FIGs.1A – 1C contain exemplary post-emergent data (Tables 5A and 5B) and pre-emergent data (Table 5C) respectively, FIG.2 contains Tables 6A and 6B contains comparative pre-emergent isomer, for example, from some of the isomers shown below in Table 2B. Table 2: Exemplary Isomers 3. Preparation of Substituted 5-membered Ring Molecules Substituted 5-membered ring molecules of the present disclosure were prepared in accordance with the procedures given below. Compound A: Methyl (2-((S)-1-(2,3-difluorobenzyl)-5-oxopyrrolidin-2-yl)acetyl)- L-valinate Compound A Compound A was prepared as follows: In a 250 mL round-bottomed flask charged with a magnetic stir bar were added (S)-2-(1-(2,3-difluorobenzyl)-5-oxopyrrolidin-2-yl)acetic acid (1.1 grams (g), 4.0 millimoles (mmol)) and methyl L-valinate hydrochloride (0.67 g, 4.0 mmol) in dichloromethane (CH 2 Cl 2 , 40 milliliters (mL)).3-(((Ethylimino)methylene)amino)- N,N-dimethylpropan-1-amine) hydrochloride (0.92 g, 4.8 mmol), triethylamine (0.67 mL, 4.8 mmol), and N,N-dimethylpyridin-4-amine (0.59 g, 4.8 mmol) were added sequentially. The reaction mixture was stirred at 20 °C for 18 hours (h). The reaction product, Compound A, was concentrated onto Celite ® and purified by silica column chromatography. The reaction product was isolated as a slightly yellow sticky oil (89% yield, 97% purity). The following data were generated to confirm the identity of Compound A: ESIMS m/z 383.2 ([M+H] + ); 1 H NMR (500 MHz, CDCl 3 ) δ 7.13 – 7.00 (m, 3H), 5.96 (d, J = 8.7 Hz, 1H), 4.86 (dd, J = 15.6, 1.7 Hz, 1H), 4.54 (dd, J = 8.6, 4.8 Hz, 1H), 4.25 (d, J = 15.6 Hz, 1H), 3.96 (tt, J = 8.7, 4.5 Hz, 1H), 3.75 (s, 3H), 2.69 (dd, J = 14.4, 4.2 Hz, 1H), 2.51 (ddd, J = 16.8, 9.7, 7.0 Hz, 1H), 2.40 (ddd, J = 17.1, 9.8, 5.9 Hz, 1H), 2.31 – 2.19 (m, 2H), 2.18 – 2.11 (m, 1H), 1.82 (dddd, J = 13.2, 9.6, 5.9, 4.6 Hz, 1H), 0.92 (d, J = 6.8 Hz, 3H), 0.89 (d, J = 6.9 Hz, 3H); 19 F NMR (471 MHz, CDCl3) δ -137.81 (d, J = 20.9 Hz), -144.12 (d, J = 20.8 Hz). Compound B: Methyl (S)-3-cyclopropyl-2-(2-((S)-1-(2,3-difluorobenzyl)-5- oxopyrrolidin-2-yl)acetamido)propanoate Compound B Compound B was prepared as follows: In a 45 mL reaction vial charged with a magnetic stir bar were added (S)-2-(1-(2,3-difluorobenzyl)-5-oxopyrrolidin-2-yl)acetic acid (0.40 g, 1.5 mmol) and methyl (S)-2-amino-3-cyclopropylpropanoate hydrochloride (0.27 g, 1.5 mmol) in CH 2 Cl 2 (15 mL). 3-(((Ethylimino)methylene)amino)-N,N-dimethylpropan-1- amine hydrochloride (0.35 g, 1.8 mmol), triethylamine (250 microliters (µL), 1.80 mmol) and N,N-dimethylpyridin-4-amine (0.22 g, 1.8 mmol) were added sequentially. The reaction mixture was stirred at 20 °C for 72 h. The reaction product, Compound B, was concentrated and purified by silica column chromatography. The reaction product was isolated as a clear oil (85% yield, 95% purity). The following data were generated to confirm the identity of Compound B: ESIMS m/z 395.2 ([M+H] + ); 1 H NMR (400 MHz, CDCl 3 ) δ 7.12 – 6.98 (m, 3H), 6.14 (d, J = 7.7 Hz, 1H), 4.86 (dd, J = 15.6, 1.7 Hz, 1H), 4.64 (dt, J = 7.8, 5.8 Hz, 1H), 4.25 (d, J = 15.6 Hz, 1H), 3.96 (tt, J = 8.6, 4.4 Hz, 1H), 3.75 (s, 3H), 2.67 (dd, J = 14.5, 4.4 Hz, 1H), 2.56 – 2.31 (m, 2H), 2.32 – 2.14 (m, 2H), 1.83 (dddd, J = 13.0, 10.0, 5.8, 4.5 Hz, 1H), 1.76 – 1.63 (m, 2H), 0.71 – 0.56 (m, 1H), 0.54 – 0.40 (m, 2H), 0.12 – 0.03 (m, 2H); 19 F NMR (376 MHz, CDCl 3 ) δ -137.83 (d, J = 21.2 Hz), -144.09 (d, J = 20.8 Hz). Compound C: Methyl (2-((S)-5-oxo-1-(2,3,5-trifluorobenzyl)pyrrolidin-2-yl)acety l)- L-valinate Compound C Compound C was prepared as follows: In a 20 mL reaction vial charged with a magnetic stir bar was added (S)-2-(1-(2,3,5-difluorobenzyl)-5-oxopyrrolidin-2-yl)acetic acid (290 mg, 1.0 mmol), methyl L-valinate hydrochloride (170 mg, 1.0 mmol), 3- (((ethylimino)methylene)amino)-N,N-dimethylpropan-1-amine hydrochloride (210 mg, 1.1 mmol), and N,N-dimethylpyridin-4-amine (130 mg, 1.1 mmol), followed by CH2Cl2 (5 mL) and then triethylamine (280 µl, 2.0 mmol). The reaction was stirred at 22 °C for 16 hr. The reaction product was isolated as a viscous colorless oil (71% yield, 95% purity). The following data were generated to confirm the identity of Compound C: ESIMS m/z 401.2 ([M+H] + ); 1 H NMR (500 MHz, CDCl 3 ) δ 6.90 – 6.81 (m, 1H), 6.77 (ddt, J = 7.7, 4.9, 2.5 Hz, 1H), 6.03 (d, J = 8.9 Hz, 1H), 4.79 (dt, J = 15.9, 1.1 Hz, 1H), 4.55 (dd, J = 8.7, 4.8 Hz, 1H), 4.27 (d, J = 15.8 Hz, 1H), 4.00 (tt, J = 7.9, 4.6 Hz, 1H), 3.75 (d, J = 1.2 Hz, 3H), 2.66 (dd, J = 14.6, 4.6 Hz, 1H), 2.57 – 2.48 (m, 1H), 2.47 – 2.38 (m, 1H), 2.36 – 2.23 (m, 2H), 2.17 – 2.12 (m, 1H), 1.83 (dddd, J = 13.0, 9.6, 6.0, 4.8 Hz, 1H), 0.91 (dd, J = 15.1, 6.9 Hz, 6H); 19 F NMR (471 MHz, CDCl 3 ) δ -114.27 – -114.34 (m), -132.93 (dd, J = 21.2, 3.1 Hz), -148.73 (dd, J = 21.0, 15.3 Hz). Compound D: Methyl (S)-3-cyclopropyl-2-(2-((S)-5-oxo-1-(2,3,5- trifluorobenzyl)pyrrolidin-2-yl)acetamido)propanoate Compound D Compound D was prepared as follows: In a 45 mL reaction vial charged with a magnetic stir bar were added (S)-2-(5-oxo-1-(2,3,5-trifluorobenzyl)pyrrolidin-2-yl)acetic acid (0.57 g, 2.0 mmol) and methyl (S)-2-amino-3-cyclopropylpropanoate hydrochloride (0.36 g, 2.0 mmol) in CH2Cl2 (20 mL). 3-(((Ethylimino)methylene)amino)-N,N-dimethylpropan-1- amine hydrochloride (0.46 g, 2.4 mmol), triethylamine (340 µL, 2.4 mmol) and N,N- dimethylpyridin-4-amine (290 mg, 2.4 mmol) were added. The reaction mixture was stirred at 20 °C for 18 h. The reaction product, Compound D, was concentrated and purified by silica column chromatography. The reaction product was isolated as a yellow oil (95% yield, 97% purity). The following data were generated to confirm the identity of Compound D: ESIMS m/z 413.3 ([M+H] + ]); 1 H NMR (500 MHz, CDCl3) δ 6.84 (dddd, J = 9.6, 7.9, 6.1, 3.1 Hz, 1H), 6.77 (ddt, J = 7.7, 4.9, 2.5 Hz, 1H), 6.18 (d, J = 7.7 Hz, 1H), 4.78 (dt, J = 15.9, 1.1 Hz, 1H), 4.64 (dt, J = 7.7, 5.8 Hz, 1H), 4.27 (d, J = 15.8 Hz, 1H), 4.00 (tt, J = 8.1, 4.7 Hz, 1H), 3.75 (s, 3H), 2.63 (dd, J = 14.6, 4.7 Hz, 1H), 2.56 – 2.46 (m, 1H), 2.41 (ddd, J = 17.1, 9.7, 5.9 Hz, 1H), 2.36 – 2.21 (m, 2H), 1.83 (dddd, J = 13.1, 9.6, 5.8, 4.6 Hz, 1H), 1.76 – 1.63 (m, 2H), 0.69 – 0.58 (m, 1H), 0.53 – 0.41 (m, 2H), 0.10 – 0.01 (m, 2H); 19 F NMR (471 MHz, CDCl3) δ -114.22 – -114.39 (m), -132.92 – -133.02 (m), -148.63 – -148.75 (m). Compound E: (2-((S)-1-(2,3-difluorobenzyl)-5-oxopyrrolidin-2-yl)acetyl)- L-valine Compound E was prepared as follows: In a 25 mL reaction vial charged with a magnetic stir bar was added methyl (2-((S)-1-(2,3-difluorobenzyl)-5-oxopyrrolidin-2- yl)acetyl)-L-valinate (0.15 g, 0.38 mmol) in a THF (1.1 mL)/Water (0.37 mL) solvent mixture. Lithium hydroxide (0.046 g, 1.9 mmol) was added, and the reaction mixture was stirred at 20 °C for 18 h. The reaction mixture was acidified with 1 molar (M) hydrochloric acid (HCl, 1.9 mL) and diluted with CH 2 Cl 2 (5 mL). The resulting mixture was concentrated and diluted with water and ethyl acetate. To the aqueous layer was added brine (10 mL), and the resulting mixture was extracted with additional ethyl acetate (50 mL x 3). The combined organic layers were dried over sodium sulfate and concentrated to give Compound E. The reaction product was isolated as a white solid (97% yield, 98% purity). The following data were generated to confirm the identity of Compound E: ESIMS m/z 369.2 ([M+H] + ); 1 H NMR (500 MHz, DMSO-d 6 ) δ 12.62 (br s, 1H), 8.17 (d, J = 8.6 Hz, 1H), 7.34 (dtd, J = 9.9, 8.0, 1.7 Hz, 1H), 7.18 (tdd, J = 8.2, 5.0, 1.5 Hz, 1H), 7.11 – 7.04 (m, 1H), 4.74 (d, J = 15.8 Hz, 1H), 4.24 (d, J = 15.9 Hz, 1H), 4.17 (dd, J = 8.6, 5.6 Hz, 1H), 3.77 (tt, J = 8.4, 4.3 Hz, 1H), 2.57 (dd, J = 13.7, 4.5 Hz, 1H), 2.42 – 2.32 (m, 2H), 2.24 (ddd, J = 16.7, 9.7, 5.0 Hz, 1H), 2.16 – 1.99 (m, 2H), 1.77 (ddt, J = 13.4, 9.3, 4.7 Hz, 1H), 0.89 – 0.83 (m, 6H); 19 F NMR (471 MHz, DMSO-d6) δ - 139.32 (d, J = 22.1 Hz), -144.08 (d, J = 22.1 Hz). Compound F: (S)-3-cyclopropyl-2-(2-((S)-1-(2,3-difluorobenzyl)-5-oxopyrr olidin-2- yl)acetamido)propanoic acid Compound F Compound F was prepared as followed: In a 25 mL reaction vial charged with a magnetic stir bar were added lithium hydroxide (0.097 g, 4.1 mmol) and methyl (S)-3- cyclopropyl-2-(2-((S)-1-(2,3-difluorobenzyl)-5-oxopyrrolidin -2-yl)acetamido)-propanoate (0.32 g, 0.81 mmol) in a THF (2.4 mL)/Water (0.8 mL) solvent mixture. The reaction mixture was stirred at 20 °C for 18 h. The reaction mixture was acidified with 1 normal (N) HCl (4.5 mL). The reaction mixture was diluted with CH 2 Cl 2 (5 mL) and saturated NaCl (20 mL) and extracted with ethyl acetate (50 mL x 3). The combined organic layers were dried with sodium sulfate and concentrated. The reaction product, Compound F, was isolated as a white solid (96% yield, 95% purity). The following data were generated to confirm the identity of Compound F: ESIMS m/z 381.1 ([M+H] + ); 1 H NMR (400 MHz, DMSO-d 6 ) δ 12.58 (br s, 1H), 8.33 (d, J = 7.9 Hz, 1H), 7.34 (dtd, J = 9.9, 8.0, 1.6 Hz, 1H), 7.18 (td, J = 8.1, 5.3 Hz, 1H), 7.07 (t, J = 7.0 Hz, 1H), 4.74 (d, J = 15.9 Hz, 1H), 4.29 – 4.20 (m, 2H), 3.78 (tt, J = 8.3, 4.2 Hz, 1H), 2.56 (dd, J = 13.8, 4.6 Hz, 1H), 2.43 – 2.17 (m, 3H), 2.10 (dt, J = 12.9, 8.5 Hz, 1H), 1.77 (ddt, J = 13.5, 9.3, 4.5 Hz, 1H), 1.61 – 1.45 (m, 2H), 0.73 (qq, J = 7.5, 4.9, 3.8 Hz, 1H), 0.38 (qq, J = 8.8, 4.4 Hz, 2H), 0.13 (dq, J = 7.5, 4.1, 3.7 Hz, 1H), 0.02 (dq, J = 7.7, 3.4, 2.9 Hz, 1H); 19 F NMR (376 MHz, DMSO-d 6 ) δ -139.32 (d, J = 22.1 Hz), -144.08 (d, J = 22.0 Hz). Compound G: (2-((S)-5-oxo-1-(2,3,5-trifluorobenzyl)pyrrolidin-2-yl)acety l)-L-valine Compound G Compound G was prepared as follows: In a 20 mL vial charged with a magnetic stir bar were added methyl (2-((S)-5-oxo-1-(2,3,5-trifluorobenzyl)pyrrolidin-2-yl)acety l)-L- valinate (0.50 g, 1.3 mmol) and sodium hydroxide (0.10 g, 2.5 mmol) in methanol (5.0 mL) under air. To this was added water (1.3 mL), and the reaction mixture was stirred at 70 °C for 16 h. The reaction mixture was diluted with water (5 mL) and acidified with concentrated HCl to pH 2. The reaction product, Compound G, began to precipitate as a white solid after a few moments. The acidified mixture was stirred for 5 minutes, and the precipitated reaction product was collected by filtration. The solid thus obtained was washed with water and dried under air. The reaction product was isolated as a white powder (88% yield, 95% purity). The following data were generated to verify the identity of Compound G: ESIMS m/z 387.1 ([M+H] + ); 1 H NMR (500 MHz, DMSO-d6) δ 12.68 (s, 1H), 8.16 (d, J = 8.6 Hz, 1H), 7.45 (dddd, J = 11.3, 8.9, 6.1, 3.1 Hz, 1H), 6.95 (dd, J = 5.7, 3.2 Hz, 1H), 4.70 (d, J = 16.1 Hz, 1H), 4.26 (d, J = 16.1 Hz, 1H), 4.17 (dd, J = 8.6, 5.6 Hz, 1H), 3.82 (ddd, J = 12.6, 8.3, 4.3 Hz, 1H), 2.58 (dd, J = 13.9, 4.7 Hz, 1H), 2.36 (ddd, J = 17.0, 8.9, 6.1 Hz, 2H), 2.26 (ddd, J = 16.6, 9.7, 5.2 Hz, 1H), 2.12 (ddt, J = 12.6, 9.8, 7.7 Hz, 1H), 2.04 (dq, J = 13.3, 6.7 Hz, 1H), 1.78 (dp, J = 13.8, 4.9 Hz, 1H), 0.86 (dd, J = 6.9, 4.0 Hz, 6H); 19 F NMR (471 MHz, DMSO-d 6 ) δ -114.86 (dd, J = 15.4, 3.3 Hz), -134.42 (dd, J = 21.8, 3.3 Hz), -148.01 (dd, J = 22.1, 15.2 Hz).
Compound H: (S)-3-cyclopropyl-2-(2-((S)-5-oxo-1-(2,3,5-trifluorobenzyl)- pyrrolidin-2-yl)acetamido)propanoic acid Compound H Compound H was prepared as follows: In a 25 mL reaction vial charged with a magnetic stir bar were added methyl (S)-3-cyclopropyl-2-(2-((S)-5-oxo-1-(2,3,5- trifluorobenzyl)pyrrolidin-2-yl)acetamido)propanoate (580 mg, 1.4 mmol) and lithium hydroxide (0.17 g, 7.0 mmol) in a THF (4.2 mL)/Water (1.4 mL) solvent mixture. The reaction mixture was stirred at 20 °C for 18 h. The reaction mixture was acidified with 1 M HCl (7.5 mL), diluted with water (10 mL), and extracted with ethyl acetate (50 mL x 3). The combined organic layers were dried with sodium sulfate and concentrated. The reaction product, Compound H, was isolated as a white solid (89% yield, 97% purity). The following data were generated to verify the identity of Compound H: ESIMS m/z 399.3 ([M+H] + ); 1 H NMR (400 MHz, DMSO-d 6 ) δ 12.61 (br s, 1H), 8.32 (d, J = 7.8 Hz, 1H), 7.46 (dddd, J = 11.2, 9.0, 6.2, 3.2 Hz, 1H), 6.95 (dp, J = 8.1, 2.4 Hz, 1H), 4.70 (d, J = 16.1 Hz, 1H), 4.29 – 4.19 (m, 2H), 3.82 (tt, J = 8.3, 4.4 Hz, 1H), 2.55 (dd, J = 13.9, 4.8 Hz, 1H), 2.42 – 2.19 (m, 3H), 2.12 (ddt, J = 12.7, 9.6, 7.7 Hz, 1H), 1.77 (ddt, J = 13.7, 9.5, 4.7 Hz, 1H), 1.62 – 1.43 (m, 2H), 0.73 (dtt, J = 12.2, 7.1, 3.7 Hz, 1H), 0.45 – 0.31 (m, 2H), 0.13 (dtd, J = 8.7, 4.5, 2.9 Hz, 1H), 0.06 – 0.00 (m, 1H); 19 F NMR (376 MHz, DMSO-d6) δ -114.83 – -114.96 (m), -134.34 – -134.54 (m), -148.01 (dd, J = 22.2, 15.3 Hz). Compound I: Methyl N-(2-((S)-1-(2,3-difluorobenzyl)-5-oxopyrrolidin-2-yl)acetyl )-O- methyl-L-threoninate Compound I Compound I was prepared as follows: In a 45 mL reaction vial charged with a magnetic stir bar were added (S)-2-(1-(2,3-difluorobenzyl)-5-oxopyrrolidin-2-yl)acetic acid (0.40 g, 1.5 mmol) and methyl O-methyl-L-threoninate hydrochloride (0.28 g, 1.5 mmol) in CH 2 Cl 2 (15.0 mL). 3-(((Ethylimino)methylene)amino)-N,N-dimethylpropan-1-amine hydrochloride (0.35 g, 1.8 mmol), triethylamine (0.25 mL, 1.8 mmol) and N,N- dimethylpyridin-4-amine (0.22 g, 1.8 mmol) were added to the reaction mixture. The reaction mixture was stirred at 20 °C for 18 h. The reaction product, Compound I, was concentrated and purified by silica column chromatography. The reaction product was isolated as a clear oil (85% yield, 97% purity). The following data were generated to verify the identity of Compound I: ESIMS m/z 399.2 ([M+H] + ); 1 H NMR (400 MHz, CDCl 3 ) δ 7.14 – 6.98 (m, 3H), 6.18 (d, J = 9.1 Hz, 1H), 4.88 (d, J = 15.7 Hz, 1H), 4.59 (dd, J = 9.1, 2.3 Hz, 1H), 4.25 (d, J = 15.6 Hz, 1H), 4.01 – 3.88 (m, 2H), 3.75 (s, 3H), 3.28 (s, 3H), 2.73 (dd, J = 14.4, 4.2 Hz, 1H), 2.51 (ddd, J = 16.8, 9.5, 7.0 Hz, 1H), 2.39 (ddd, J = 17.0, 9.7, 5.7 Hz, 1H), 2.32 – 2.19 (m, 2H), 1.90 – 1.78 (m, 1H), 1.15 (d, J = 6.3 Hz, 3H); 19 F NMR (376 MHz, CDCl 3 ) δ -137.86 (d, J = 20.8 Hz), -144.01 (d, J = 19.3 Hz).
Compound J: N-(2-((S)-1-(2,3-difluorobenzyl)-5-oxopyrrolidin-2-yl)acetyl )-O- methyl-L-threonine Compound J Compound J was prepared as follows: In a 25 mL reaction vial charged with a magnetic stir bar were added methyl N-(2-((S)-1-(2,3-difluorobenzyl)-5-oxopyrrolidin-2- yl)acetyl)-O-methyl-L-threoninate (0.40 g, 1.0 mmol) and lithium hydroxide (0.12 g, 5.1.0 mL) solvent mixture. The reaction mixture was stirred at 20 °C for 20 h. The reaction mixture was acidified with 1 M HCl (5.5 mL) and diluted with water (10 mL) and ethyl acetate (20 mL). The aqueous layer of the reaction mixture was extracted with ethyl acetate (30 mL x 4). The combined organic layers were dried with sodium sulfate and concentrated. The reaction product was isolated as a white solid (80% yield, 98% purity). The following data were generated to verify the identity of Compound J: ESIMS m/z 385.0 ([M+H] + ); 1 H NMR (400 MHz, DMSO-d 6 ) δ 12.71 (br s, 1H), 8.22 (d, J = 9.0 Hz, 1H), 7.35 (dtd, J = 9.8, 8.0, 1.7 Hz, 1H), 7.18 (tdd, J = 8.2, 5.0, 1.5 Hz, 1H), 7.15 – 7.03 (m, 1H), 4.74 (d, J = 15.9 Hz, 1H), 4.37 (dd, J = 9.0, 3.1 Hz, 1H), 4.25 (d, J = 15.9 Hz, 1H), 3.85 (qd, J = 6.2, 3.0 Hz, 1H), 3.76 (tt, J = 8.3, 4.1 Hz, 1H), 3.22 (s, 3H), 2.62 (dd, J = 13.5, 4.4 Hz, 1H), 2.38 (ddd, J = 17.0, 13.1, 8.7 Hz, 2H), 2.23 (ddd, J = 16.6, 9.6, 4.8 Hz, 1H), 2.14 – 2.00 (m, 1H), 1.79 (ddt, J = 13.4, 9.2, 4.5 Hz, 1H), 1.03 (d, J = 6.3 Hz, 3H); 19 F NMR (376 MHz, DMSO-d6) δ -139.37 (d, J = 22.1 Hz), -144.07 (d, J = 22.1 Hz). Compound K: Methyl O-methyl-N-(2-((S)-5-oxo-1-(2,3,5-trifluorobenzyl)pyrrolidin - 2-yl)acetyl)-L-threoninate Compound K Compound K was prepared as follows: In a 45 mL reaction vial charged with a magnetic stir bar were added (S)-2-(5-oxo-1-(2,3,5-trifluorobenzyl)pyrrolidin-2-yl)acetic acid (0.29 g, 1.0 mmol) and methyl O-methyl-L-threoninate hydrochloride (0.18 g, 1.0 mmol) in CH 2 Cl 2 (10 mL). 3-(((Ethylimino)methylene)amino)-N,N-dimethylpropan-1-amine hydrochloride (0.23 g, 1.2 mmol), triethylamine (170 µL, 1.2 mmol) and N,N-dimethylpyridin- 4-amine (0.15 g, 1.2 mmol) were added sequentially. The reaction mixture was stirred at 20 °C for 18 h. The reaction product, Compound K, was concentrated and purified by silica column chromatography. The reaction product was isolated as a clear oil (77% yield, 98% purity). The following data were generated to verify the identity of Compound K: ESIMS m/z 417.1 ([M+H] + ); 1 H NMR (400 MHz, CDCl 3 ) δ 6.90 – 6.72 (m, 2H), 6.15 (d, J = 9.1 Hz, 1H), 4.86 – 4.77 (m, 1H), 4.59 (dd, J = 9.1, 2.3 Hz, 1H), 4.27 (d, J = 15.9 Hz, 1H), 4.06 – 3.89 (m, 2H), 3.76 (s, 3H), 3.28 (s, 3H), 2.70 (dd, J = 14.5, 4.5 Hz, 1H), 2.53 (ddd, J = 16.7, 9.5, 7.0 Hz, 1H), 2.42 (ddd, J = 16.9, 9.6, 5.8 Hz, 1H), 2.36 – 2.24 (m, 2H), 1.85 (ddt, J = 13.0, 10.1, 5.3 Hz, 1H), 1.15 (d, J = 6.3 Hz, 3H); 19 F NMR (376 MHz, CDCl 3 ) δ -114.33 – -114.40 (m), -132.92 – -133.00 (m), -148.57 – -148.68 (m).
Compound L: O-methyl-N-(2-((S)-5-oxo-1-(2,3,5-trifluorobenzyl)pyrrolidin -2- yl)acetyl)-L-threonine Compound L Compound N was prepared as follows: In a 25 mL reaction vial charged with a magnetic stir bar were added lithium hydroxide (0.054 g, 2.3 mmol) and methyl O-methyl-N- (2-((S)-5-oxo-1-(2,3,5-trifluorobenzyl)pyrrolidin-2-yl)acety l)-L-threoninate (0.19 g, 0.45 mmol) in a THF (1.4 mL)/water (0.45 mL) solvent mixture. The reaction was stirred at 20 °C for 18 h. The reaction mixture was acidified with 1 M HCl (2.5 mL), then diluted with water (3 mL) and brine (3 mL). The aqueous layer was extracted with CH2Cl2 (10 mL x 5). The combined organic phase layers were passed through a phase separator and concentrated. The reaction product, Compound N, was isolated as a white solid (92% yield, 97% purity). The following data were generated to verify the identity of Compound N: ESIMS m/z 403.1 ([M+H] + ); 1 H NMR (400 MHz, DMSO-d 6 ) δ 12.71 (s, 1H), 8.21 (d, J = 9.0 Hz, 1H), 7.45 (dddd, J = 11.2, 9.0, 6.1, 3.2 Hz, 1H), 6.95 (qd, J = 5.1, 2.4 Hz, 1H), 4.70 (d, J = 16.1 Hz, 1H), 4.37 (dd, J = 9.0, 3.1 Hz, 1H), 4.27 (d, J = 16.2 Hz, 1H), 3.90 – 3.75 (m, 2H), 3.22 (s, 3H), 2.63 (dd, J = 13.6, 4.6 Hz, 1H), 2.43 – 2.32 (m, 2H), 2.25 (ddd, J = 16.7, 9.6, 5.1 Hz, 1H), 2.16 – 2.05 (m, 1H), 1.85 – 1.73 (m, 1H), 1.04 (d, J = 6.3 Hz, 3H); 19 F NMR (376 MHz, DMSO-d 6 ) δ -114.89 (dd, J = 15.2, 4.0 Hz), -134.49 (dd, J = 22.0, 3.8 Hz), -148.02 (dd, J = 22.3, 15.5 Hz).
Compound M: Methyl (2-((S)-1-(2,3-difluorobenzyl)-5-thioxopyrrolidin-2- yl)ethanethioyl)-L-valinate Compound M Compound M was prepared as follows: Lawesson reagent (0.58 g, 1.4 mmol) was added to a stirred solution of methyl (2-((S)-1-(2,3-difluorobenzyl)-5-oxopyrrolidin-2- yl)acetyl)-L-valinate (0.50 g, 1.3 mmol) in dry toluene (15 mL) at room temperature. The resulting yellow suspension was stirred at 65 °C for 2 h, and the progress of the reaction was monitored by ultra performance liquid chromatography (UPLC). The mono/bis thiolactam formation in a 4:1 ratio was observed. The reaction mixture was left stirring overnight. After 16 h, 80% of the desired product, Compound M, was observed by liquid chromatography–mass spectrometry (LCMS). The resulting reaction mixture was purified using flash column chromatography with 0%-100% acetone/hexanes and evaporative light scattering detector (ELSD) detection. The major ELSD peak was collected, concentrated, and dried to provide Compound M. The reaction product was isolated as a colorless oil (50% yield, 95% purity). The following data were generated to verify the identity of Compound M: ESIMS m/z 415.0 ([M+H] + ); 1 H NMR (400 MHz, CDCl3) δ 7.66 (d, J = 8.1 Hz, 1H), 7.22 – 6.82 (m, 3H), 5.60 (d, J = 15.2 Hz, 1H), 5.12 (dd, J = 8.1, 4.6 Hz, 1H), 4.66 (d, J = 15.3 Hz, 1H), 4.53 (tt, J = 8.5, 4.2 Hz, 1H), 3.78 (s, 3H), 3.24 – 2.93 (m, 3H), 2.69 (dd, J = 13.6, 9.2 Hz, 1H), 2.48 – 2.14 (m, 2H), 1.92 (ddt, J = 13.1, 8.9, 4.6 Hz, 1H), 1.03 (d, J = 7.0 Hz, 3H), 0.95 (d, J = 6.9 Hz, 3H); 19 F NMR (471 MHz, CDCl 3 ) δ -137.30 (ddd, J = 21.1, 10.1, 5.0 Hz), -143.22 (d, J = 20.9 Hz). Compound N: Methyl (2-((S)-1-(2,3-difluorobenzyl)-5-thioxopyrrolidin-2-yl)acety l)- L-valinate Compound N Compound N was prepared as follows: Lawesson reagent (0.29 g, 0.72 mmol) was added to a stirred solution of methyl (2-((S)-1-(2,3-difluorobenzyl)-5-oxopyrrolidin-2- yl)acetyl)-L-valinate (0.50 g, 1.3 mmol) in dry toluene (13 mL) at room temperature. The reaction mixture was left stirring overnight. After 16 h, 90% of the desired product, Compound N, was observed by UPLC. The resulting reaction mixture was purified by flash column chromatography with 0%-100% acetone/hexanes and ELSD detection. The major ELSD peak was collected, concentrated, and dried to provide Compound N. The reaction product was isolated as a colorless oil (56% yield, 90% purity). The following data were generated to confirm the identity of Compound N: ESIMS m/z 399.0 ([M+H] + ); 1 H NMR (500 MHz, CDCl 3 ) δ 7.20 – 6.96 (m, 3H), 5.93 (d, J = 8.7 Hz, 1H), 5.72 – 5.52 (m, 1H), 4.63 (d, J = 15.4 Hz, 1H), 4.54 (dd, J = 8.6, 4.8 Hz, 1H), 4.30 (tt, J = 8.7, 4.3 Hz, 1H), 3.76 (s, 3H), 3.21 – 2.99 (m, 2H), 2.74 (dd, J = 14.6, 4.3 Hz, 1H), 2.42 – 2.23 (m, 2H), 2.16 (pd, J = 6.9, 4.8 Hz, 1H), 1.88 (ddt, J = 13.5, 9.2, 5.0 Hz, 1H), 0.93 (d, J = 6.8 Hz, 3H), 0.90 (d, J = 6.9 Hz, 3H); 19 F NMR (471 MHz, CDCl3) δ -137.34 (d, J = 24.1 Hz), -143.55 (d, J = 20.3 Hz). Compound O: (2-((S)-1-(2,3-difluorobenzyl)-5-thioxopyrrolidin-2-yl)acety l)-L-valine Compound O Compound O was prepared as follows: In a 25 mL reaction vial charged with a magnetic stir bar was added methyl (2-((S)-1-(2,3-difluorobenzyl)-5-thioxopyrrolidin-2- yl)acetyl)-L-valinate (0.11 g, 0.28 mmol) in a THF (1.1 mL)/water (0.37 mL) solvent mixture. Lithium hydroxide (9.9 mg, 0.41 mmol) was added and the reaction mixture was stirred at 20 °C for 18 h. The THF layer of the reaction mixture was evaporated, and the remaining reaction mixture was acidified with 1 M HCl (1.5 mL) to pH 5. The acidified mixture was extracted with ethyl acetate (5 mL x 3). The combined organic layers were dried over sodium sulfate, filtered, and concentrated to give the reaction product, Compound O. The reaction product was isolated as a white solid (63% yield, 90% purity). The following data were generated to confirm the identity of Compound O: ESIMS m/z 385.0 ([M+H] + ); 1 H NMR (400 MHz, DMSO-d 6 ) δ 12.60 (s, 1H), 8.21 (dd, J = 17.5, 8.6 Hz, 1H), 7.38 (dtd, J = 10.2, 8.2, 1.7 Hz, 1H), 7.19 (dtd, J = 8.2, 5.8, 2.5 Hz, 1H), 7.07 (t, J = 7.0 Hz, 1H), 5.42 (d, J = 15.7 Hz, 1H), 4.70 (d, J = 15.9 Hz, 1H), 4.29 – 4.13 (m, 2H), 3.08 – 2.85 (m, 2H), 2.68 (dd, J = 13.9, 4.5 Hz, 1H), 2.52 – 2.44 (m, 1H), 2.31 – 2.09 (m, 1H), 2.05 (dq, J = 13.3, 6.9 Hz, 1H), 1.94 – 1.74 (m, 1H), 0.86 (dd, J = 6.8, 3.1 Hz, 6H). Compound P: Methyl (S)-3-cyclopropyl-2-(2-((S)-1-(2,3-difluorobenzyl)-5- thioxopyrrolidin-2-yl)ethanethioamido)propanoate Compound P Compound P was prepared as follows: Lawesson reagent (0.77 g, 1.9 mmol) was added to a stirred solution of methyl (S)-3-cyclopropyl-2-(2-((S)-1-(2,3-difluorobenzyl)-5- oxopyrrolidin-2-yl)acetamido)propanoate (1.0 g, 2.5 mmol) in dry toluene (25 mL) at room temperature. The resulting yellow suspension was stirred at 40 °C for 24 h, and the progress of the reaction was monitored by ultra performance liquid chromatography (UPLC). The mono/bis thiolactam formation in a 1.6:1 ratio was observed. The resulting reaction mixture was purified using flash column chromatography with 0%-100% acetone/hexanes and evaporative light scattering detector (ELSD) detection. The major ELSD peak was collected, concentrated, and dried to provide Compound P. The reaction product was isolated as a colorless oil (28% yield, 95% purity). The following data were generated to verify the identity of Compound P: ESIMS m/z 427 ([M+H] + ); 1 H NMR (400 MHz, CDCl 3 ) δ 7.09 (dt, J = 23.3, 7.9 Hz, 3H), 6.12 (d, J = 7.8 Hz, 1H), 5.59 (d, J = 15.4 Hz, 1H), 4.74 – 4.50 (m, 2H), 4.30 (dt, J = 8.6, 4.3 Hz, 1H), 3.76 (s, 3H), 3.25 – 2.93 (m, 2H), 2.72 (dd, J = 14.6, 4.4 Hz, 1H), 2.32 (dt, J = 13.0, 8.8 Hz, 2H), 2.04 – 1.79 (m, 1H), 1.70 (qt, J = 14.0, 6.4 Hz, 2H), 0.63 (d, J = 7.0 Hz, 1H), 0.48 (dd, J = 8.2, 2.8 Hz, 2H), 0.06 (t, J = 3.8 Hz, 2H). Compound Q: Methyl (S)-3-cyclopropyl-2-(2-((S)-1-(2,3-difluorobenzyl)-5- thioxopyrrolidin-2-yl)acetamido)propanoate Compound Q Compound Q was prepared as follows: Lawesson reagent (0.71 g, 1.8 mmol) was added to a stirred solution of methyl (S)-3-cyclopropyl-2-(2-((S)-1-(2,3-difluorobenzyl)-5- oxopyrrolidin-2-yl)acetamido)propanoate (1.3 g, 3.4 mmol) in dry toluene (25 mL) at room temperature. The reaction mixture was left stirring for 48 h. The resulting reaction mixture was purified by flash column chromatography with 0%-100% acetone/hexanes and ELSD detection. The major ELSD peak was collected, concentrated, and dried to provide Compound Q. The reaction product was isolated as a colorless oil (65% yield, 90% purity). The following data were generated to confirm the identity of Compound Q: ESIMS m/z 411 ([M+H] + ); 1 H NMR (500 MHz, CDCl 3 ) δ 7.20 – 6.98 (m, 3H), 6.24 – 6.07 (m, 1H), 5.59 (d, J = 15.4 Hz, 1H), 4.67-4.59 (m, 2H), 4.30 (tt, J = 8.6, 4.3 Hz, 1H), 3.76 (s, 3H), 3.22 – 3.01 (m, 2H), 2.72 (dd, J = 14.7, 4.4 Hz, 1H), 2.40 – 2.23 (m, 2H), 1.90 (ddt, J = 13.5, 9.3, 4.9 Hz, 1H), 1.80 – 1.58 (m, 2H), 0.63 (dtt, J = 14.8, 7.2, 3.7 Hz, 1H), 0.52 – 0.43 (m, 2H), 0.11 – 0.02 (m, 2H). 4. Compositions The present disclosure also includes compositions containing the substituted 5- membered ring molecule herbicides disclosed herein. A composition is a mixture comprising at least one substituted 5-membered ring molecule herbicide or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof) and further comprising other additives used to enhance the properties or effectiveness of the mixture in some way. Exemplary additives include but are not limited to adjuvants, safeners, carriers, and combinations thereof. Compositions may be in various physical states, including but not limited to as solutions, emulsions, suspensions, granules, powders, and other such states. 1. Adjuvants In some aspects, the additive includes an agriculturally acceptable adjuvant. Exemplary agriculturally acceptable adjuvants include, but are not limited to, antifreeze agents, antifoam agents, compatibilizing agents, sequestering agents, neutralizing agents and buffers, corrosion inhibitors, colorants, odorants, penetration aids, wetting agents, spreading agents, dispersing agents, thickening agents, freeze point depressants, antimicrobial agents, crop oil, adhesives (for instance, for use in seed formulations), surfactants, protective colloids, emulsifiers, tackifiers, and mixtures thereof. Exemplary agriculturally acceptable adjuvants include, but are not limited to, crop oil concentrates (e.g., 85% mineral oil + 15% emulsifiers); nonylphenol ethoxylates; benzylcocoalkyldimethyl quaternary ammonium salts; blends of petroleum hydrocarbon, alkyl esters, organic acids, and anionic surfactants; C 9 -C 11 alkylpolyglycoside; phosphate alcohol ethoxylates; natural primary alcohol (C 12 -C 16 ) ethoxylate; di-sec-butylphenol EO-PO block copolymers; polysiloxane-methyl cap; nonylphenol ethoxylate+urea ammonium nitrates; emulsified methylated seed oils; tridecyl alcohol (synthetic) ethoxylates (e.g., 8 EO); tallow amine ethoxylates (e.g., 15 EO); and PEG(400) dioleate-99. Exemplary surfactants (e.g., wetting agents, tackifiers, dispersants, emulsifiers) include, but are not limited to: the alkali metal salts, alkaline earth metal salts and ammonium salts of fatty acids or of aromatic sulfonic acids (e.g., lignosulfonic acids, phenolsulfonic acids, naphthalenesulfonic acids, and dibutylnaphthalenesulfonic acid); alkyl- and alkylarylsulfonates; alkyl sulfates, lauryl ether sulfates and fatty alcohol sulfates; salts of sulfated hexa-, hepta- and octadecanols; salts of fatty alcohol glycol ethers; condensates of sulfonated naphthalene and its derivatives with formaldehyde; condensates of naphthalene or of the naphthalene sulfonic acids with phenol and formaldehyde; polyoxyethylene octylphenol ether; ethoxylated isooctyl-, octyl- or nonylphenol, alkylphenyl or tributylphenyl polyglycol ether; alkyl aryl polyether alcohols; isotridecyl alcohol; fatty alcohol/ethylene oxide condensates; ethoxylated castor oil; polyoxyethylene alkyl ethers or polyoxypropylene alkyl ethers; lauryl alcohol polyglycol ether acetate; sorbitol esters; lignosulfite waste liquors and proteins; denatured proteins, polysaccharides (e.g., methylcellulose); hydrophobically modified starches; and polyvinyl alcohol, polycarboxylates, polyalkoxylates, polyvinyl amines, polyethyleneimine, polyvinylpyrrolidone, and copolymers thereof. Exemplary thickeners include, but are not limited to, polysaccharides (e.g., xanthan gum), organic and inorganic sheet minerals, and mixtures thereof. Exemplary antifoam agents include, but are not limited to, silicone emulsions, long- chain alcohols, fatty acids, fatty acid salts, organofluorine compounds, and mixtures thereof. Exemplary antimicrobial agents include, but are not limited to, bactericides based on dichlorophen and benzyl alcohol hemiformal; isothiazolinone derivatives, such as alkylisothiazolinones and benzisothiazolinones; and mixtures thereof. Exemplary antifreeze agents, include, but are not limited to ethylene glycol, propylene glycol, urea, glycerol, and mixtures thereof. Exemplary colorants include, but are not limited to, the dyes known under the names Rhodamine B, pigment blue 15:4, pigment blue 15:3, pigment blue 15:2, pigment blue 15:1, pigment blue 80, pigment yellow 1, pigment yellow 13, pigment red 112, pigment red 48:2, pigment red 48:1, pigment red 57:1, pigment red 53:1, pigment orange 43, pigment orange 34, pigment orange 5, pigment green 36, pigment green 7, pigment white 6, pigment brown 25, basic violet 10, basic violet 49, acid red 51, acid red 52, acid red 14, acid blue 9, acid yellow 23, basic red 10, basic red 108, and mixtures thereof. Exemplary adhesives include, but are not limited to, polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, tylose, and mixtures thereof. 2. Safeners In some aspects, the additive is a safener. Safeners are compounds leading to better crop plant compatibility when applied with a herbicide. In some aspects, the safener itself is herbicidally active. In some aspects, the safener acts as an antidote or antagonist in the crop plants and can protect the crop plants from damage that might otherwise occur from an applied herbicide. Exemplary safeners include, but are not limited to, AD-67 (MON 4660), benoxacor, benthiocarb, brassinolide, cloquintocet, cloquintocet-mexyl, cyometrinil, cyprosulfamide, daimuron, dichlormid, dicyclonon, dietholate, dimepiperate, disulfoton, fenchlorazole, fenchlorazole-ethyl, fenclorim, flurazole, fluxofenim, furilazole, harpin proteins, isoxadifen- ethyl, jiecaowan, jiecaoxi, mefenpyr, mefenpyr-diethyl, mephenate, naphthalic anhydride, 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine, 4-(dichloroacetyl)-1-oxa-4-azaspiro [4.5]- decane, oxabetrinil, R29148, and N-phenyl-sulfonylbenzoic acid amides, agriculturally acceptable salts as well as thereof and, provided they have a carboxyl group, their agriculturally acceptable derivatives. In some aspects, the safener can be cloquintocet or an ester or salt thereof, such as cloquintocet-mexyl. In some aspects, the safener can be mefenpyr or an ester or salt thereof, such as mefenpyr-diethyl. In some aspects, the safener is employed in rice, cereal, or maize. For example, mefenpyr or cloquintocet can be used to antagonize harmful effects of the compositions on rice, row crops, and cereals. 3. Carriers In some aspects, the additive includes a carrier. In some aspects, the additive includes a liquid or solid carrier. In some aspects, the additive includes an organic or inorganic carrier. Exemplary liquid carriers include, but are not limited to: water; petroleum fractions or hydrocarbons such as mineral oil, aromatic solvents, paraffinic oils, and the like; vegetable oils such as soybean oil, rapeseed oil, olive oil, castor oil, sunflower seed oil, coconut oil, corn oil, cottonseed oil, linseed oil, palm oil, peanut oil, safflower oil, sesame oil, tung oil and the like; esters of the above vegetable oils; esters of monoalcohols or dihydric, trihydric, or other lower polyalcohols (4-6 hydroxy containing), such as 2-ethyl hexyl stearate, n-butyl oleate, isopropyl myristate, propylene glycol dioleate, di-octyl succinate, di-butyl adipate, di-octyl phthalate and the like; esters of mono, di and polycarboxylic acids and the like; toluene; xylene; petroleum naphtha; crop oil; acetone; methyl ethyl ketone; cyclohexanone; trichloroethylene; perchloroethylene; ethyl acetate; amyl acetate; butyl acetate; propylene glycol monomethyl ether and diethylene glycol monomethyl ether; methyl alcohol; ethyl alcohol; isopropyl alcohol; amyl alcohol; ethylene glycol; propylene glycol; glycerin; N-methyl-2-pyrrolidinone; N;N-dimethyl alkylamides; dimethyl sulfoxide; and liquid fertilizers, as well as mixtures thereof. Exemplary solid carriers include, but are not limited to: silicas, silica gels, silicates, talc, kaolin, limestone, lime, chalk, bole, loess, clay, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, ground synthetic materials, pyrophyllite clay, attapulgus clay, kieselguhr, calcium carbonate, bentonite clay, Fuller's earth, cottonseed hulls, wheat flour, soybean flour, pumice, wood flour, walnut shell flour, lignin, ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, cereal meal, tree bark meal, wood meal and nutshell meal, cellulose powders, and mixtures thereof. 4. Physical States In some aspects, the compositions comprising the substituted 5-membered ring molecule herbicide may be present in suspended, emulsified, dissolved, or solid form. Exemplary compositions include, but are not limited to, aqueous solutions, aqueous suspensions, aqueous dispersions, aqueous emulsions, aqueous microemulsions, aqueous suspo-emulsions, oil solutions, oil suspensions, oil dispersions, oil emulsions, oil microemulsions, oil suspo-emulsions, self-emulsifying formulations, gels, pastes, powders, dusts, granules, and materials for spreading. In some aspects, the substituted 5-membered ring molecule herbicide is in an aqueous solution that can be diluted before use. In various aspects, the substituted 5-membered ring molecule herbicide may be provided as a high-strength formulation such as a concentrate. In some aspects, the concentrate is stable and retains potency during storage and shipping. In various aspects, the concentrate is a clear, homogeneous liquid that is stable at temperatures of 54 °C or greater. In some aspects, the concentrate does not exhibit any precipitation of solids at temperatures of 10 °C or higher. In some aspects, the concentrate does not exhibit separation, precipitation, or crystallization of any components at low temperatures. For example, the concentrate remains a clear solution at temperatures below 0 °C (e.g., below -5 °C, below -10 °C, below -15 °C). In some aspects, the concentrate exhibits a viscosity of less than 50 centipoise (50 megapascals), even at temperatures as low as 5 °C. In some aspects, the concentrate does not exhibit separation, precipitation, or crystallization of any components during storage for a period of 2 weeks or greater (e.g., 4 weeks, 6 weeks, 8 weeks, 3 months, 6 months, 9 months, or 12 months or greater). In some aspects, emulsions, gels, pastes, or oil dispersions can be prepared by homogenizing the substituted 5-membered ring molecule herbicide in water with a wetting agent, tackifier, dispersant, or emulsifier. In some aspects, concentrates suitable for dilution with water can be prepared, comprising the substituted 5-membered ring molecule herbicide, a wetting agent, a tackifier, and a dispersant or emulsifier. In some aspects, powders, materials for spreading, or dusts can be prepared by mixing or concomitant grinding the substituted 5-membered ring molecule herbicide and optionally other additives with a solid carrier. In some aspects, granules (e.g., coated granules, impregnated granules and homogeneous granules) can be prepared by binding the substituted 5-membered ring molecule herbicide to solid carriers. In some aspects, the compositions comprise, by total weight of the composition, from about 0.01% to about 99% of the substituted 5-membered ring molecule herbicide, including about 0.025%, 0.05%, 0.075%, 0.1%, 0.2%, 0.3%, 0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1%, 2%, 3%, 4%, 5%, 6%, 7%, 7.5%, 8%, 9%, 10%, 12.5%, 15%, 17.5%, 20%, 22.5%, 25%, 27.5%, 30%, 32.5%, 35%, 37.5%, 40%, 42.5%, 45%, 47.5%, 50%, 52.5%, 55%, 57.5%, 60%, 62.5%, 65%, 67.5%, 70%, 72.5%, 75%, 77.5%, 80%, 82.5%, 85%, 87.5%, 90%, 92.5%, 95%, 97.5%, or 98% of the substituted 5-membered ring molecule herbicide by total weight of the composition, or within any range defined between any two of the forgoing values, such as between about 1% to about 97%, between about 10% to about 90%, between about 20% to about 45%, and about 25% to about 50% based on the total weight of the composition. Concentrates can be diluted with an inert carrier, such as water, prior to application. The diluted compositions applied to undesirable vegetation or the locus of undesirable vegetation can contain from 0.0006 to 8.0 weight percent (wt %) of the total amount of the substituted 5- membered ring molecule herbicide (e.g., from 0.001 to 5.0 wt %), based on the total weight of the diluted composition. 5. Methods of Use The substituted 5-membered ring molecules or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof) disclosed herein can be formulated into compositions and applied in any known technique for applying herbicides. Exemplary application techniques include, but are not limited to, spraying, atomizing, dusting, sprinkling, spreading, or direct application. The method of application can vary depending on the intended purpose. In some aspects, the method of application can be chosen to ensure the finest possible distribution of the compositions disclosed herein. In some aspects, a method of controlling undesirable vegetation which comprises contacting the vegetation or the locus thereof with or applying to the soil or water to prevent the emergence or growth of vegetation any of the compositions is disclosed herein. The compositions containing a substituted 5-membered ring molecule disclosed herein can be applied pre-emergence (before the emergence of undesirable vegetation) or post- emergence (e.g., during and/or after emergence of the undesirable vegetation). In some aspects, the composition is applied postemergence to the undesirable vegetation. When the compositions are used in crops, the compositions can be applied after seeding and before or after the emergence of the crop plants. In some aspects, the compositions disclosed herein show good crop tolerance even when the crop has already emerged and can be applied during or after the emergence of the crop plants. In some aspects, when the compositions are used in crops, the compositions can be applied before seeding of the crop plants. In some aspects, the compositions disclosed herein are applied to vegetation or an area adjacent the vegetation or applying to soil or water to prevent the emergence or growth of vegetation by spraying (e.g., foliar spraying). In some aspects, the spraying techniques use, for example, water as carrier and spray volume rates of from 2 liters per hectare (L/ha) to 2000 L/ha (e.g., from 10–1000 L/ha or from 50–500 L/ha). In some aspects, the compositions disclosed herein are applied by the low-volume or the ultra-low-volume method, wherein the application is in the form of micro granules. In some aspects, wherein the compositions disclosed herein are less well tolerated by certain crop plants, the compositions can be applied with the aid of the spray apparatus in such a way that they come into little contact, if any, with the leaves of the sensitive crop plants while reaching the leaves of undesirable vegetation that grows underneath or on the bare soil (e.g., post-directed or lay-by). In some aspects, the compositions disclosed herein can be applied as dry compositions (e.g., granules, powders, or dusts). In some aspects, wherein the undesirable vegetation is treated post-emergence, the compositions disclosed herein are applied by foliar application. In some aspects, herbicidal activity is exhibited by the compounds of the mixture when they are applied directly to the plant or to the locus of the plant at any stage of growth or before planting or emergence. The effect observed can depend upon the type of undesirable vegetation to be controlled, the stage of growth of the undesirable vegetation, the application parameters of dilution and spray drop size, the particle size of solid components, the environmental conditions at the time of use, the specific compound employed, the specific adjuvants and carriers employed, the soil type, and the like, as well as the amount of chemical applied. In some aspects, these and other factors can be adjusted to promote non-selective or selective herbicidal action. The compositions and methods disclosed herein can be used to control undesirable vegetation in a variety of applications. The compositions and methods disclosed herein can be used for controlling undesirable vegetation in areas including, but not limited to, farmland, turfgrass, pastures, grasslands, rangelands, fallow land, rights-of-way, aquatic settings, tree and vine, wildlife management areas, or rangeland. In some aspects, the undesirable vegetation is controlled in a row crop. Exemplary crops include, but are not limited to, wheat, barley, triticale, rye, teff, oats, maize, cotton, soy, canola, pulses, sunflower, sugar beet, sorghum, rice, millet, sugarcane, and range land (e.g., pasture grasses). In some aspects, the compositions and methods disclosed herein can be used for controlling undesirable vegetation in maize, soy, canola, cotton, pulses, sunflower, sugar beet, wheat, barley, rice, sorghum, millet, oats, or combinations thereof. In some aspects, the compositions and methods disclosed herein can be used in industrial vegetation management (IVM) or for utility, pipeline, roadside, and railroad rights−of−way applications. In some aspects, the compositions and methods disclosed herein can also be used in forestry (e.g., for site preparation or for combating undesirable vegetation in plantation forests). In some aspects, the compositions and methods disclosed herein can be used to control undesirable vegetation in conservation reserve program lands (CRP), trees, vines, grasslands, and grasses grown for seeds. In some aspects, the compositions and methods disclosed herein can be used on lawns (e.g., residential, industrial, and institutional), golf courses, parks, cemeteries, athletic fields, and sod farms. The compositions and methods disclosed herein can also be used in crop plants that are resistant to, for instance, herbicides, insecticides, fungicides, pathogens, insects, or combinations thereof. In some aspects, the compositions and methods disclosed herein can be used in crop plants that are resistant to one or more herbicides because of genetic engineering or breeding. In some aspects, the compositions and methods disclosed herein can be used in crop plants that are resistant to one or more pathogens such as plant pathogenic fungi owing to genetic engineering or breeding. In some aspects, the compositions and methods disclosed herein can be used in crop plants that are resistant to attack by insects owing to genetic engineering or breeding. Exemplary resistant crops include, but are not limited to, crops that are resistant to photosystem II inhibitors, or crop plants that, owing to introduction of the gene for Bacillus thuringiensis (or Bt) toxin by genetic modification, are resistant to attack by certain insects. In some aspects, the compositions and methods described herein can be used in conjunction with glyphosate, glufosinate, dicamba, phenoxy auxins, pyridyloxy auxins, aryloxyphenoxypropionates, acetyl CoA carboxylase (ACCase) inhibitors, imidazolinones, acetolactate synthase (ALS) inhibitors, 4-hydroxyphenyl-pyruvate dioxygenase (HPPD) inhibitors, protoporphyrinogen oxidase (PROTOX) inhibitors, triazines, and bromoxynil to control vegetation in crops tolerant to glyphosate, glufosinate, dicamba, phenoxy auxins, pyridyloxy auxins, aryloxyphenoxypropionates, ACCase inhibitors, imidazolinones, synthetic auxin herbicides, HPPD inhibitors, PROTOX inhibitors, triazines, bromoxynil, or combinations thereof. In some aspects, the undesirable vegetation is controlled in glyphosate, glufosinate, dicamba, phenoxy auxins, pyridyloxy auxins, aryloxyphenoxypropionates, ACCase inhibitors, synthetic auxin herbicide, HPPD inhibitors, PROTOX inhibitors, triazines, and bromoxynil tolerant crops possessing single, multiple or stacked traits conferring tolerance to single or multiple chemistries and/or multiple modes of action. In some aspects, the undesirable vegetation can be controlled in a crop that is ACCase-tolerant, ALStolerant, or a combination thereof. In some aspects, the compositions described herein and other complementary herbicides are applied at the same time, either as a combination composition or as a tank mix, or as sequential applications. The compositions and methods may be used in controlling undesirable vegetation in crops possessing agronomic stress tolerance (including but not limited to drought, cold, heat, salt, water, nutrient, fertility, pH), pest tolerance (including but not limited to insects, fungi, and pathogens), and crop improvement traits (including but not limited to yield; protein, carbohydrate, or oil content; protein, carbohydrate, or oil composition; plant stature and plant architecture). The compounds and compositions described herein may be used to control plant species described, but not limited to, weeds species found in Randall, R.P. (2017). A Global Compendium of Weeds. 3rd Edition. Perth, Western Australia. In some aspects, the compositions disclosed herein can be used for controlling undesirable vegetation including grasses, broadleaf weeds, sedge weeds, and combinations thereof. In some aspects, the compositions disclosed herein can be used for controlling undesirable vegetation including, but not limited to, Acanthospermum species, Aegilops species, Agrostis species, Alopecurus species, Ambrosia species, Anthemis species, Apera species, Amaranthus species, Avena species, Brachiaria species, Bromus species, Chenopodium species, Cenchrus species, Cirsium species, Commelina species, Cyperus species, Datura species, Digitaria species, Echinochloa species, Eleusine species, Atriplex species, Brassica species, Convolvulus species, Conyza species, Cassia species, Euphorbia species, Geranium species, Galinsoga species, Ipomea species, Lamium species, Leptochloa species, Lolium species, Monochoria species, Malva species, Matricaria species, Panicum species, Phalaris species Polygonum species, Prosopis species, Rumex species, Setaria species, Sida species, Sisymbrium species, Solanum species, Sorghum species, Trifolium species, Xanthium species, Veronica species, and Viola species. In some aspects, the undesired vegetation includes blackgrass (Alopecurus myosuroides Huds.), wild oat (Avena fatua), barnyard grass (Echinochloa crus-galli) common chickweed (Stellaria media), velvetleaf (Abutilon theophrasti), hemp sesbania (Sesbania exaltata Cory), Anoda cristata, Bidens pilosa, Brassica kaber, shepherd’s purse (Capsella bursa-pastoris), cornflower (Centaurea cyanus or Cyanus segetum), hempnettle (Galeopsis tetrahit), cleavers (Galium aparine), common sunflower (Helianthus annuus), Desmodium tortuosum, Italian ryegrass (Lolium multiflorum), kochia (Kochia scoparia), Medicago arabica, Mercurialis annua, Myosotis arvensis, common poppy (Papaver rhoeas), Raphanus raphanistrum, broad- leaf dock (Rumex obtusifolius), Russian thistle (Salsola kali), wild mustard (Sinapis arvensis), Sonchus arvensis, Thlaspi arvense, Tagetes minuta, Richardia brasiliensis, Plantago major, Plantago lanceolata, bird’seye speedwell (Veronica persica), pigweed (Amaranthus retroflexus), winter rape (Brassica napus), lambsquarters (Chenopodium album), Canadian thistle (Cirsium arvense), nutsedge (Cyperus esculentus), poinsettia (Euphorbia heterophylla), prickly lettuce (Lactuca serriola), purple deadnettle (Lamium purpureum), wild chamomile (Matricaria chamomilla), false chamomile (Matricaria inodora), field chamomile (Anthemis arvensis), common buckwheat (Fagopyrum esculentum), wild buckwheat (Polygonum convulvus), giant foxtail (Setaria faberi), green foxtail (Setaria viridis), yellow foxtail (Setaria pumila) common sorghum (Sorghum vulgare), wild pansy (Viola tricolor), or combinations thereof. The compositions described herein can be used to control herbicide resistant or tolerant weeds. The methods employing the compositions described herein may also be employed to control herbicide resistant or tolerant weeds. Exemplary resistant or tolerant weeds include, but are not limited to, biotypes resistant or tolerant to acetolactate synthase (ALS) or acetohydroxy acid synthase (AHAS) inhibitors (e.g., imidazolinones, sulfonylureas, pyrimidinylthiobenzoates, triazolopyrimidines, sulfonylaminocarbonyltriazolinones), photosystem II inhibitors (e.g., phenylcarbamates, pyridazinones, triazines, triazinones, uracils, amides, ureas, benzothiadiazinones, nitriles, phenylpyridazines), acetyl CoA carboxylase (ACCase) inhibitors (e.g., aryloxyphenoxypropionates, cyclohexanediones, phenylpyrazolines), synthetic auxins (e.g., benzoic acids, phenoxycarboxylic acids, pyridine carboxylates, quinoline carboxylic acids), auxin transport inhibitors (e.g., phthalamates, semicarbazones), photosystem I inhibitors (e.g., bipyridyliums, such as paraquat and diquat), 5-enolpyruvylshikimate-3-phosphate (EPSP) synthase inhibitors (e.g., glyphosate), glutamine synthetase inhibitors (e.g., glufosinate, bilanafos), microtubule assembly inhibitors (e.g., benzamides, benzoic acids, dinitroanilines, phosphoramidates, pyridines), mitosis inhibitors (e.g., carbamates), very long chain fatty acid (VLCFA) inhibitors (e.g., acetamides, chloroacetamides, oxyacetamides, tetrazolinones), fatty acid and lipid synthesis inhibitors (e.g., phosphorodithioates, thiocarbamates, benzofuranes, chlorocarbonic acids), protoporphyrinogen oxidase (PROTOX) inhibitors (e.g., diphenylethers, N- phenylphthalimides, oxadiazoles, oxazolidinediones, phenylpyrazoles, pyrimidinediones, thiadiazoles, triazolinones), carotenoid biosynthesis inhibitors (e.g., clomazone, amitrole, aclonifen), phytoene desaturase (PDS) inhibitors (e.g., amides, anilidex, furanones, phenoxybutan-amides, pyridiazinones, pyridines), 4-hydroxyphenyl-pyruvate-dioxygenase (HPPD) inhibitors (e.g., callistemones, isoxazoles, pyrazoles, triketones), cellulose biosynthesis inhibitors (e.g., nitriles, benzamides, quinclorac, triazolocarboxamides), herbicides with multiple modes of action such as quinclorac, and unclassified herbicides such as arylaminopropionic acids, difenzoquat, endothall, and organoarsenicals. Exemplary resistant or tolerant weeds include, but are not limited to, biotypes with resistance or tolerance to multiple herbicides, biotypes with resistance or tolerance to multiple chemical classes, biotypes with resistance or tolerance to multiple herbicide modes of action, and biotypes with multiple resistance or tolerance mechanisms (e.g., target site resistance or metabolic resistance). By way of non-limiting illustration, examples of some aspects of the present disclosure are given below. Parts and percentages are on a per weight basis unless otherwise indicated. Examples The details of the compositions and the crops tested are specified in the following Examples. EVALUATION OF PESTICIDAL ACTIVITY As previously discussed, the compounds disclosed herein exhibit varying pesticidal activity. For example, the pesticidal activity may include herbicidal activity. Exemplified below are exemplification of various types of herbicidal activity, both pre-emergent and post- emergent herbicidal activity. In Tables 5A-5C are select post-emergent and pre-emergent herbicidal activity for some compounds on various weeds and crops. The following Table 3 lists the plants being evaluated with the various substituted 5-membered ring pesticides at the time of application for the results exemplified in Table 5A and 5B, shown in FIGs.1A and 1B respectively, and the pre-emergent control exemplified in Table 5C in FIG.1C. Also shown are select lists of plants for data represented in FIGs 2-18B, Tables 6A- 22B, which include mixture data of the substituted 5-membered rings with other herbicides and/or safeners and mixture data. Also included in FIGs. 18A-18B are some of the disclosed additional substituted 5-membered rings (shown below in Table 4) and other herbicides. Table 1: Plant Species Used in Evaluations
The following methods describe the various methods used to analyze pesticidal activity on various crops and weeds shown in FIGs.1-18B. METHOD 1: POSTEMERGENCE APPLICATION METHODS FOR HERBICIDE EVALUATIONS Seeds of the desired test plant species were planted in plastic pot with 64 square centimeter (cm 2 ) surface area filled with soil-less media planting mix containing PRO-MIX ® BX (Premier Tech Horticulture, Quakertown, PA, USA) and PROFILE ® GREENS GRADE™ (Profile Products LLC, Buffalo Grove, IL, USA) at pH of 5.2 to 6.2 and a minimum of 50% organic matter content. Echinochloa crus-galli (barnyard grass) and Setaria faberi (giant foxtail) were planted together 11 days prior to application. In a separate pot Alopecurus myosuroides (blackgrass) and Avena fatua (wild oat) was planted together and propagated 14 and 11 days prior to application respectively. Ipomea hederacea (ivyleaf morningglory) and Helianthus annuus (sunflower) were planted in a separate pot, 8 days prior to application. Plants were grown in a greenhouse set to 23 °C day and 22 °C night temperature regimen with a 16 hour photoperiod for the propagation period and returned to the same conditions after treatment. Plants were sub-irrigated as needed with water containing Jack’s Professional 15-5- 154 Ca 2Mg fertilizer. Compositions of each exemplified molecule were dissolved in 2.75 mL of formulation solvent containing by volume (59% deionized water, 24% acetone, 15% isopropanol, 0.75% DMSO, 1.5% crop oil concentrate, 0.02% Tergitol 15S-7) to deliver a spray rate of 2000 or 4000 grams of active ingredient per hectare (g ai/h). Samples were vortexed and sonicated if needed to dissolve the compound into solution. Formulated compounds were applied to all six species in 3 pots using a DeVilbiss® compressed air sprayer at 2–4 pounds per square inch (psi), allowed to dry then returned to the greenhouse. After 9-11 days, the condition of the test plants was compared with that of the control plants by visual assessment and evaluated based on a scoring scale of 0 to 100 percent where 0 corresponds to no injury and 100 corresponds to complete plant death. Visual assessments of plant injury were made based on growth inhibition, growth reduction, discoloration, leaf deformity and necrosis. METHOD 2: PRE-EMERGENCE APPLICATION METHODS FOR HERBICIDE EVALUATIONS Seeds of the desired test plant species were planted into 12.7 cm diameter round plastic pots containing a silt loam mineral soil. Compositions of each exemplified molecule were dissolved in 0.67 mL 97:3 v/v mixture of acetone and DMSO, then further diluted with 2.05 mL of solvent containing 78% D.I. H2O, 20% isopropanol, 2% AgriDex crop oil concentrate and 0.02% Tergitol 15S-7 surfactant. Samples were mixed vigorously (vortexed) and sonicated if needed to bring the compound into solution. Solution was mixed with 15 mL of D.I. H2O and poured evenly over the soil containing potted seeds. The vial was rinsed with an additional 15 mL of D.I. H2O which was again poured over the soil. Treated pots are moved to in a greenhouse with an approximate 16-hour (h) photoperiod and maintained at 23 °C during the day and 22 °C during the night. Pots were kept moist through over-the-top irrigation. After 14 days, the condition of the test plants was compared with that of the control plants by visual assessment and evaluated based on a scoring scale of 0 to 100 percent where 0 corresponds to no injury and 100 corresponds to no emergence or complete plant death after emergence. Visual assessments of plant injury were made based on growth inhibition, growth reduction, discoloration, leaf deformity and necrosis. METHOD 3: POSTEMERGENCE APPLICATION METHODS FOR HERBICIDE EVALUATIONS Seeds of the desired test plant species were planted in plastic pot with 64 square centimeter (cm 2 ) surface area filled with soil-less media planting mix containing PRO-MIX ® BX (Premier Tech Horticulture, Quakertown, PA, USA) and PROFILE ® GREENS GRADE™ (Profile Products LLC, Buffalo Grove, IL, USA) at pH of 5.2 to 6.2 and a minimum of 50% organic matter content. In some aspects or embodiments, to help ensure good germination and healthy plants, a fungicide treatment and/or other chemical or physical treatment was applied. The plants were grown for 7–36 days (d) in a greenhouse with an approximate 16-hour (h) photoperiod and set to 23 °C day and 22 °C night temperature regimen. Plants were sub- irrigated as needed with water containing Jack’s Professional 15-5-15 4 Ca 2Mg fertilizer. Supplemental lighting was provided as necessary. The plants were employed for testing when they reached the second or third true leaf stage. Compositions of each exemplified molecule was weighed to a known amount, determined by the highest rate to be tested, by placing in a 25 mL glass vial and was dissolved in 4 mL of a 97:3 v/v mixture of acetone and DMSO to obtain concentrated stock solutions. If the test compound did not dissolve readily, the mixture was warmed and/or sonicated. The concentrated stock solutions obtained were diluted with 20 mL of an aqueous mixture containing acetone, water, isopropyl alcohol, DMSO, AgriDex crop oil concentrate, and Tergitol 15S-7 surfactant in a 48.5:39:10:1.5:1.0:0.02 v/v ratio to obtain spray solutions at the application rate. Compound requirements are based upon a 12 mL application volume at a rate of 187 liters per hectare (L/ha). The spray solutions were applied to the plant material with an overhead DeVries track sprayer equipped with 8002E nozzles calibrated to deliver 187 L/ha over an application area of 0.503 square meters (m 2 ) at a spray height of 18 inches (43 centimeters (cm)) above the average plant canopy. Control or non-treated plants were sprayed in the same manner with the solvent blank or not treated. All herbicide application rates are given as grams acid equivalent per hectare (g ae/h) or grams active ingredient per hectare (g ai/h). The treated plants and control plants were placed in a greenhouse as described above and watered by subirrigation to prevent removal of the test compound. After 13-15 days, the condition of the test plants was compared with that of the control plants by visual assessment and evaluated based on a scoring scale of 0 to 100 percent where 0 corresponds to no injury and 100 corresponds to complete plant death. Visual assessments of plant injury were made based on growth reduction, discoloration, leaf deformity and necrosis. METHOD 4: POSTEMERGENCE APPLICATION METHODS FOR HERBICIDE EVALUATIONS Seeds of the desired test plant species were planted in plastic pot with 64 square centimeter (cm 2 ) surface area filled with soil-less media planting mix containing PRO-MIX ® BX (Premier Tech Horticulture, Quakertown, PA, USA) and PROFILE ® GREENS GRADE™ (Profile Products LLC, Buffalo Grove, IL, USA) at pH of 5.2 to 6.2 and a minimum of 50% organic matter content. In some aspects or embodiments, to help ensure good germination and healthy plants, a fungicide treatment and/or other chemical or physical treatment was applied. Prior to treatment, plants were grown in a chamber for 4-13 days (days) with a 16-hour (h) photoperiod and set to 25 °C or 28 °C day or 22 °C or 24 °C night temperature regimen dependent on species. Plants were delivered to a greenhouse with an approximate 14-hour (h) photoperiod and set to 27 °C day and 24 °C night temperature regimen for the duration of the experiment. Plants were sub-irrigated as needed with water containing Jack’s Professional 15- 5-154 Ca 2Mg fertilizer. Supplemental lighting was provided as necessary. The plants were employed for testing when they reached the second or third true leaf stage. Emulsifiable concentrates of 5-membered ring molecules were prepared at 100 grams active ingredient per liter (g ai/L). An aliquot of each emulsifiable concentrate was placed in a 25 mL glass vial and diluted with an aqueous mixture of 1.0% (v/v) Dyne-Amic ® (Helena ® ) to obtain spray solutions based upon a 12 mL application volume at a rate of 187 liters per hectare (L/ha). Spray solutions of the herbicide combinations (Compound A or Compound B) plus a second herbicide were prepared by adding weighed amounts or aliquots of the second herbicide to the spray solutions of Compound A or Compound B to form 12-mL spray solutions in two-way combinations. The spray solutions were applied to the plant material with an overhead DeVries track sprayer equipped with 8002E nozzles calibrated to deliver 187 L/ha over an application area of 0.503 square meters (m 2 ) at a spray height of 18 inches (43 centimeters (cm)) above the average plant canopy. Control or non-treated plants were sprayed in the same manner with the solvent blank or not treated. All herbicide application rates are given as grams acid equivalent per hectare (g ae/h) or grams active ingredient per hectare (g ai/h). The treated plants and control plants were placed in a greenhouse as described above and watered by subirrigation to prevent removal of the test compound. After 13-15 days, the condition of the test plants was compared with that of the control plants by visual assessment and evaluated based on a scoring scale of 0 to 100 percent where 0 corresponds to no injury and 100 corresponds to complete plant death. Visual assessments of plant injury were made based on growth reduction, discoloration, leaf deformity and necrosis. METHOD 5: POSTEMERGENCE APPLICATION METHODS FOR HERBICIDE EVALUATIONS Seeds of the desired test plant species were planted in plastic pot with 103.2 square centimeter (cm 2 ) surface area filled with soil-less media planting mix containing PRO-MIX ® BX (Premier Tech Horticulture, Quakertown, PA, USA) and PROFILE ® GREENS GRADE™ (Profile Products LLC, Buffalo Grove, IL, USA) at pH of 5.2 to 6.2 and a minimum of 50% organic matter content. In some aspects or embodiments, to help ensure good germination and healthy plants, a fungicide treatment and/or other chemical or physical treatment was applied. Prior to treatment, plants were grown in a chamber for 5-13 days (days) with a 16-hour (h) photoperiod and set to 24 °C or 28 °C day or 23 °C or 24 °C night temperature regimen dependent on species. Plants were delivered to a greenhouse with an approximate 14-hour (h) photoperiod and set to 28 °C day and 25 °C night temperature regimen for the duration of the experiment. Plants were sub-irrigated as needed with water containing Jack’s Professional 15- 5-154 Ca 2Mg fertilizer. Supplemental lighting was provided as necessary. The plants were employed for testing when they reached the second or third true leaf stage. Emulsifiable concentrates of 5-membered ring molecule were prepared at 100 grams active ingredient per liter (g ai/L). An aliquot of each emulsifiable concentrate was placed in a 25 mL glass vial and diluted with an aqueous mixture of 1.0% (v/v) Dyne-Amic ® (Helena ® ) to obtain spray solutions based upon a 12 mL application volume at a rate of 187 liters per hectare (L/ha). Spray solutions of the herbicide combinations (Compound A or Compound B) plus a second herbicide were prepared by adding weighed amounts or aliquots of the second herbicide to the spray solutions of Compound A or Compound B to form 12-mL spray solutions in two-way combinations. The spray solutions were applied to the plant material with an overhead DeVries track sprayer equipped with 8002E nozzles calibrated to deliver 187 L/ha over an application area of 0.503 square meters (m 2 ) at a spray height of 18 inches (43 centimeters (cm)) above the average plant canopy. Control or non-treated plants were sprayed in the same manner with the solvent blank or not treated. All herbicide application rates are given as grams acid equivalent per hectare (g ae/h) or grams active ingredient per hectare (g ai/h). The treated plants and control plants were returned to a greenhouse as described above and watered by subirrigation to prevent removal of the test compound. After 20-22 days, the condition of the test plants was compared with that of the control plants by visual assessment and evaluated based on a scoring scale of 0 to 100 percent where 0 corresponds to no injury and 100 corresponds to complete plant death. Visual assessments of plant injury were made based on growth reduction, discoloration, leaf deformity and necrosis. METHOD 6: POSTEMERGENCE APPLICATION METHODS FOR HERBICIDE EVALUATIONS Seeds of the desired test plant species were planted in plastic pot with 103.2 square centimeter (cm 2 ) surface area filled with soil-less media planting mix containing PRO-MIX ® BX (Premier Tech Horticulture, Quakertown, PA, USA) and PROFILE® GREENS GRADE™ (Profile Products LLC, Buffalo Grove, IL, USA) at pH of 5.2 to 6.2 and a minimum of 50% organic matter content. In some aspects or embodiments, to help ensure good germination and healthy plants, a fungicide treatment and/or other chemical or physical treatment was applied. Prior to treatment, plants were grown in a chamber for 5-13 days (days) with a 16-hour (h) photoperiod and set to 24 °C or 28 °C day or 23 °C or 24 °C night temperature regimen dependent on species. Plants were delivered to a greenhouse with an approximate 14-hour (h) photoperiod and set to 28 °C day and 25 °C night temperature regimen for the duration of the experiment. Plants were sub-irrigated as needed with water containing Jack’s Professional 15- 5-154 Ca 2Mg fertilizer. Supplemental lighting was provided as necessary. The plants were employed for testing when they reached the second or third true leaf stage. Compositions of each the 5-membered ring molecule being evaluated was weighed to a known amount, determined by the highest rate to be tested, by placing in a 25 mL glass vial and was dissolved in 4 mL of a 97:3 v/v mixture of acetone and DMSO to obtain concentrated stock solutions. If the compound did not dissolve readily, the mixture was warmed and/or sonicated. The concentrated stock solutions obtained were diluted with 20 mL of an aqueous mixture containing acetone, water, isopropyl alcohol, DMSO, AgriDex crop oil concentrate, and Tergitol 15S-7 surfactant in a 56.2:32.5:8.3:1.75:1.25:0.02 v/v ratio to obtain spray solutions at the application rate. Spray solutions of the 5-membered ring molecule being evaluated were combined with a second herbicide by adding weighed amounts or aliquots of the second herbicide to the spray solutions of the 5-membered ring molecule being evaluated to form 12-mL spray solutions in two-way combinations. The spray solutions were applied to the plant material with an overhead DeVries track sprayer equipped with 8002E nozzles calibrated to deliver 187 L/ha over an application area of 0.503 square meters (m 2 ) at a spray height of 18 inches (43 centimeters (cm)) above the average plant canopy. Control or non-treated plants were sprayed in the same manner with the solvent blank or not treated. All herbicide application rates are given as grams acid equivalent per hectare (g ae/h) or grams active ingredient per hectare (g ai/h). The treated plants and control plants were returned to a greenhouse as described above and watered by subirrigation to prevent removal of the test compound. After 20-22 days, the condition of the test plants was compared with that of the control plants by visual assessment and evaluated based on a scoring scale of 0 to 100 percent where 0 corresponds to no injury and 100 corresponds to complete plant death. Visual assessments of plant injury were made based on growth reduction, discoloration, leaf deformity and necrosis. The value “NT” indicate that this was not tested for FIGs.1-18B, Tables 5A-22B. As can be seen from the data contained in FIGs. 1-18B, Tables 5A-22B, (i) the substituted 5-membered rings and mixtures thereof and (ii) additional substituted 5-membered rings with various mixing partners have herbicidal activity and help to solve the aforementioned need for new herbicides and methods to control the growth of undesirable vegetation in various locations. COMPOSITIONS Disclosed herein include compositions comprising compounds according to Formula I be mixed with or applied in combination with another compound, such as another pesticide, additive, or combination thereof. For example, disclosed compositions may comprise (a) a compound according to Formula I and (b) another herbicide. Yet another example of disclosed compositions may comprise (a) a compound according to Formula I, (b) another herbicide, and (c) another safener. Also, disclosed in include compositions that can comprise other substituted 5- membered rings selected from the following compounds (PYR-1 through PYR-21 and including all stereoisomers thereof) below and mixed with or applied in combination with another compound, such as another pesticide, additive, or combination thereof. Additional substituted 5-membered rings include the following compounds: TABLE 4: ADDITIONAL SUBSTITUTED 5-MEMBERED RINGS (JAS)
For example, disclosed compositions may comprise (a) one of the aforementioned additional substituted 5-membered ring herbicides and (b) another herbicide in ratios surprisingly discovered. Yet another example of disclosed compositions may comprise (a) one of the aforementioned additional substituted 5-membered ring herbicides, (b) another herbicide, and (c) another safener in ratios also discovered. PYR-3: Methyl (S)-2-(1-(2,3-difluorobenzyl)-5-oxopyrrolidin-2-yl)acetate PYR-3 PYR-3 was prepared as follows: In a 250 mL round-bottomed flask charged with magnetic stir bar was added methyl (S)-2-(5-oxopyrrolidin-2-yl)acetate (3.1 g, 20 mmol) in THF (100 mL) under N 2 . Lithium bis(trimethylsilyl)amide solution (1M in THF, 20 mL, 20 mmol) added at 0 °C and kept at this temperature for 15 min. 1-(Bromomethyl)-2,3- difluorobenzene (6.2 g, 30 mmol) was added and then the reaction was stirred at 55 °C for 18 hr. The crude reaction mixture was diluted with MeOH (5 mL) and concentrated onto celite, then purified by silica gel chromatography. The reaction product was a yellow oil (93% yield, 87% purity). The following data was generated to confirm the identity of PYR-3: ESIMS^m/z^284.2 [(M+H)+]; 1 H NMR (400 MHz, Chloroform-d) δ 7.14 – 7.00 (m, 3H), 4.87 (dd, J = 15.5, 1.8 Hz, 1H), 4.24 (d, J = 15.5 Hz, 1H), 3.88 (tt, J = 8.7, 4.4 Hz, 1H), 3.66 (s, 3H), 2.71 (dd, J = 15.6, 4.1 Hz, 1H), 2.57 – 2.34 (m, 3H), 2.27 (ddt, J = 13.1, 9.7, 7.5 Hz, 1H), 1.83 (ddt, J = 13.0, 9.9, 5.1 Hz, 1H).; 19 F NMR (376 MHz, Chloroform-d) δ -137.87 (d, J = 21.7 Hz), -144.17 (d, J = 21.3 Hz). PYR-4: (S)-2-(1-(2,3-difluorobenzyl)-5-oxopyrrolidin-2-yl)acetic acid PYR-4 PYR-4 was prepared as follows: In a 100 mL round-bottomed flask charged with magnetic stir bar was added methyl (S)-2-(1-(2,3-difluorobenzyl)-5-oxopyrrolidin-2- yl)acetate (5.3 g, 19 mmol) and lithium hydroxide (2.2 g, 93 mmol) in a THF (27 mL)/water (9.3 mL) solvent mixture. The reaction was stirred at 20 °C for 18 hr. The crude reaction was acidified with 3M HCl (32 mL), and then the mixture was extracted with ethyl acetate (40 mL) for 3 times. The combined organic layer was dried over Na2SO4, filtered, and concentrated. Purified by silica column chromatography yield PYR-4 as a white solid (83% yield, 99% purity). The following data was generated to confirm the identity of PYR-4: ESIMS^m/z^270.1 [(M+H) + ]; 1 H NMR (400 MHz, DMSO-d6) δ 12.38 (br. s, 1H), 7.35 (dtd, J = 9.9, 8.0, 1.7 Hz, 1H), 7.18 (tdd, J = 8.2, 5.0, 1.5 Hz, 1H), 7.12 – 7.03 (m, 1H), 4.72 (d, J = 15.9 Hz, 1H), 4.23 (d, J = 15.9 Hz, 1H), 3.76 (tt, J = 8.4, 4.2 Hz, 1H), 2.68 (dd, J = 15.9, 4.1 Hz, 1H), 2.47 – 2.32 (m, 2H), 2.31 – 2.11 (m, 2H), 1.80 – 1.66 (m, 1H).; 19 F NMR (376 MHz, DMSO-d6) δ -139.32 (d, J = 22.1 Hz), -144.23 (d, J = 22.0 Hz). PYR-5: Methyl (S)-2-(1-(2,3,5-trifluorobenzyl)-5-oxopyrrolidin-2-yl)acetat e PYR-5 PYR-5 was prepared as follows: In a 250 mL round-bottomed flask charged with magnetic stir bar was added methyl (S)-2-(5-oxopyrrolidin-2-yl)acetate (1.6 g, 10 mmol) in THF (50 mL) under N2. lithium bis(trimethylsilyl)amide (10 mL, 10 mmol) added at 0 °C and kept at this temperature for 15 min.1-(bromomethyl)-2,3,5-trifluorobenzene (3.4 g, 15 mmol) was added and then the reaction was stirred at 55 °C for 16 hr. The crude reaction mixture was diluted with MeOH (5 mL) and concentrated onto celite, then purified by silica gel chromatography. The reaction product was a yellow oil (80% yield, 95% purity).The following data was generated to confirm the identity of PYR-5: ESIMSm/z302.2 [(M+H) + ]; 1 H NMR (500 MHz, Chloroform-d) δ 6.90 – 6.76 (m, 2H), 4.79 (dd, J = 15.8, 1.8 Hz, 1H), 4.25 (d, J = 15.8 Hz, 1H), 3.90 (tt, J = 8.5, 4.5 Hz, 1H), 3.67 (s, 3H), 2.69 (dd, J = 15.6, 4.3 Hz, 1H), 2.59 – 2.47 (m, 1H), 2.45 – 2.36 (m, 2H), 2.30 (dddd, J = 13.1, 9.8, 7.8, 7.1 Hz, 1H), 1.91 – 1.78 (m, 1H).; 19 F NMR (471 MHz, Chloroform-d) δ -114.16 – -114.31 (m), -132.87 – -132.96 (m), -148.79 (dd, J = 20.9, 15.2 Hz). PYR-6: (S)-2-(1-(2,3,5-trifluorobenzyl)-5-oxopyrrolidin-2-yl)acetic acid PYR-6 was prepared as follows: In a 500 mL round-bottomed flask charged with magnetic stir bar was added methyl (S)-2-(5-oxo-1-(2,3,5-trifluorobenzyl)pyrrolidin-2- yl)acetate (13 g, 43 mmol) and sodium hydroxide (23 mL, 47 mmol) solution in THF (200 mL). The reaction was stirred at 20 °C for 20 hr. The crude reaction was concentrated to remove most THF, then the obtained oil was dilute with ethyl acetate(150 mL) and acidified with 3M HCl (16 mL). The two phases were separated, and the aqueous layer was thrice extracted with ethyl acetate (50 mL). The combined organics were washed with brine (50 mL), dried over Na 2 SO 4 , filtered, and the concentrated to afford the product as an off-white solid (96% yield, 97% purity). The following data was generated to confirm the identity of PYR-6: ESIMSm/z288.1 [(M+H) + ]; 1 H NMR (400 MHz, DMSO-d 6 ) δ 12.38 (s, 1H), 7.45 (dddd, J = 11.2, 9.0, 6.1, 3.1 Hz, 1H), 6.96 (dp, J = 8.1, 2.4 Hz, 1H), 4.67 (d, J = 16.1 Hz, 1H), 4.26 (d, J = 16.1 Hz, 1H), 3.80 (tt, J = 8.5, 4.4 Hz, 1H), 2.68 (dd, J = 16.0, 4.3 Hz, 1H), 2.40 (ddd, J = 16.1, 10.4, 7.5 Hz, 2H), 2.32 – 2.14 (m, 2H), 1.81 – 1.67 (m, 1H).; 19 F NMR (376 MHz, DMSO- d 6 ) δ -114.83 – -114.90 (m), -134.47 (dd, J = 21.9, 3.2 Hz), -148.16 (dd, J = 21.8, 15.8 Hz). SAFENED COMPOSITIONS A safened composition comprising compounds according to Formula I may be mixed with or applied in combination with (b) a safener, such as an azole carboxylate safener or an agriculturally acceptable salt or ester thereof. Also, safened compositions comprising the aforementioned PYR-1 through PYR- 16 (AND ALL STEREOISOMERS THEREOF) compounds may be mixed in combination with (b) a safener. In some aspects, (a) and (b) are used in an amount sufficient to induce an enhanced herbicidal effect (e.g., increased damage or injury to undesirable vegetation) while still showing good crop compatibility (e.g., no increased damage to crops or minimal increased damage or injury to crops) when compared to the individual application of the herbicidal compounds (a) or (b). In some aspects, the damage or injury to undesirable vegetation caused by the safened compositions and methods disclosed herein is evaluated using a scale from 0% to 100%, when compared with the untreated control vegetation, wherein 0% indicates no damage to the undesirable vegetation and 100% indicates complete destruction of the undesirable vegetation. Similarly, in some aspects, the damage or injury to the crop caused by the safened compositions and methods disclosed herein is evaluated using a scale from 0% to 100%, when compared with control crops treated with only the herbicide or the safener, wherein 0% indicates no damage to the crop and 100% indicates complete destruction of the crop. In some aspects, the joint action of (a) the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof) and (b) the azole carboxylate safener or an agriculturally acceptable salt or ester thereof results in enhanced herbicidal effect against undesirable vegetation, even at application rates below those typically used for the herbicide to have a herbicidal effect on its own. In some aspects, the compositions and methods disclosed herein can, based on the individual components, be used at lower application rates to achieve a herbicidal effect comparable to the effect produced by the individual components at normal application rates. In some aspects, the joint action of (a) the compounds according to Formula I and (b) the azole carboxylate safener or an agriculturally acceptable salt or ester thereof results in protective effect for desired crops against damage to the crops that might be caused by the herbicide alone. In some aspects, the weight ratio of (a) the compounds according to Formula I (in g ae/ha) or (a) the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), to (b) the azole carboxylate safener or an agriculturally acceptable salt or ester thereof (in g ai/ha) can be 1:5 or more, such as 1:4.75 or more, 1:4.5 or more, 1:4.25 or more, 1:4 or more, 1:3.75 or more, 1:3.5 or more, 1:3.25 or more, 1:3 or more, 1:2.75 or more, 1:2.5 or more, 1:2.25 or more, 1:2 or more, 1:1.9 or more, 1:1.8 or more, 1:1.7 or more, 1:1.6 or more, 1:1.5 or more, 1:1.4 or more, 1:1.3 or more, 1:1.2 or more, 1:1.1 or more, 1:1 or more, 1.1:1 or more, 1.2:1 or more, 1.3:1 or more, 1.4:1 or more, 1.5:1 or more, 1.6:1 or more, 1.7:1 or more, 1.8:1 or more, 1.9:1 or more, 2:1 or more, 2.25:1 or more, 2.5:1 or more, 2.75:1 or more, 3:1 or more, 3.25:1 or more, 3.5:1 or more, 3.75:1 or more, 4:1 or more, 4.25:1 or more, 4.5:1 or more, 4.75:1 or more, or 5:1 or more; the weight ratio of (a) to (b) can be 5:1 or less, such as 4.75:1 or less, 4.5:1 or less, 4.25:1 or less, 4:1 or less, 3.75:1 or less, 3.5:1 or less, 3.25:1 or less, 3:1 or less, 2.75:1 or less, 2.5:1 or less, 2.25:1 or less, 2:1 or less, 1.9:1 or less, 1.8:1 or less, 1.7:1 or less, 1.6:1 or less, 1.5:1 or less, 1.4:1 or less, 1.3:1 or less, 1.2:1 or less, 1.1:1 or less, 1:1 or less, 1:1.1 or less, 1:1.2 or less, 1:1.3 or less, 1:1.4 or less, 1:1.5 or less, 1:1.6 or less, 1:1.7 or less, 1:1.8 or less, 1:1.9 or less, 1:2 or less, 1:2.25 or less, 1:2.5 or less, 1:2.75 or less, 1:3 or less, 1:3.25 or less, 1:3.5 or less, 1:3.75 or less, 1:4 or less, 1:4.25 or less, 1:4.5 or less, or 1:4.75 or less; or the weight ratio of (a) to (b) can range from any of the minimum ratios to any of the maximum ratios provided above, such as from 1:5 to 5:1, from 1:2 to 5:1, from 1:1 to 3:1, from 1:3 to 4:1, or from 1:1.5 to 3.5:1. In some aspects, (a) and (b), independently, can be employed in a purity of from 90% to 100% (e.g., from 95% to 100%) according to nuclear magnetic resonance (NMR) spectroscopy. AZOLE CARBOXYLATE SAFENERS In addition to the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), the compositions and methods of the present disclosure can include an azole carboxylate safener or an agriculturally acceptable salt or ester thereof. Herbicide safeners are molecules used in combination with herbicides to make them “safer” – that is, to reduce the herbicidal effect of the herbicide on crop plants and to improve selectivity between crops and the undesirable vegetation being targeted by the herbicide. Herbicide safeners can be used to pre-treat crop seeds prior to planting. Herbicide safeners may also be sprayed on plants as a mixture with the herbicide, or separately and sequentially with the herbicide. Azoles are a class of five-membered nitrogen heterocyclic ring compounds containing at least one additional heteroatom (e.g., nitrogen, sulfur, or oxygen) within the heterocyclic ring. Examples of azoles include, for example, pyrazoles, imidazoles, thiazoles, oxazoles, isoxazoles and triazoles. Azole carboxylate safeners are a class of safeners based on carboxylate-substituted azole moieties. Examples of azole carboxylate safeners include pyrazole carboxylate safeners, imidazole carboxylate safeners, thiazole carboxylate safeners, oxazole carboxylate safeners, isoxazole carboxylate safeners, and triazole carboxylate safeners. In some aspects, the composition can include an azole carboxylate safener selected from the group consisting of fenchlorazole, flurazole, furilazole, isoxadifen, mefenpyr, agriculturally acceptable salts or esters thereof, or combinations thereof. In some aspects, the azole carboxylate safener can include fenchlorazole-ethyl, isoxadifen-ethyl, mefenpyr-diethyl, or combinations thereof. In some aspects, the azole carboxylate safener can comprise fenchlorazole, shown below, or an agriculturally acceptable salt or ester thereof. Fenchlorazole’s safening activity is described in The Pesticide Manual, Eighteenth Edition, 2016. In some aspects, the fenchlorazole is provided as an agriculturally acceptable salt or ester. An exemplary agriculturally acceptable ester of fenchlorazole is fenchlorazole–ethyl, shown below. In some aspects, the azole carboxylate safener can comprise flurazole, shown below, or an agriculturally acceptable salt or ester thereof. Flurazole’s safening activity is described in The Pesticide Manual, Eighteenth Edition, 2016. In some aspects, the azole carboxylate safener can comprise furilazole, shown below, or an agriculturally acceptable salt or ester thereof. Furilazole’s safening activity is described in The Pesticide Manual, Eighteenth Edition, 2016. In some aspects, the azole carboxylate safener can comprise isoxadifen, shown below, or an agriculturally acceptable salt or ester thereof. Isoxadifen’s safening activity is described in The Pesticide Manual, Eighteenth Edition, 2016. In some aspects, the isoxadifen is provided as an agriculturally acceptable salt or ester. An exemplary agriculturally acceptable ester of isoxadifen is isoxadifen-ethyl, shown below. In some aspects, the azole carboxylate safener can comprise mefenpyr, shown below, or an agriculturally acceptable salt or ester thereof. Mefenpyr’s safening activity is described in The Pesticide Manual, Eighteenth Edition, 2016.
In some aspects, the mefenpyr is provided as an agriculturally acceptable salt or ester. An exemplary agriculturally acceptable ester of mefenpyr is mefenpyr-diethyl, shown below. Azole carboxylate safeners include, for example, isoxadifen and agriculturally acceptable salts and esters thereof. Isoxadifen has the following chemical structure. This form of isoxadifen may also be referred to as "isoxadifen-acid." In some aspects, the safener may comprise isoxadifen-acid, an agriculturally acceptable salt of isoxadifen, an agriculturally acceptable ester of isoxadifen, or mixtures thereof. An exemplary agriculturally acceptable ester of isoxadifen is isoxadifen-ethyl, shown below. In some aspects, the azole carboxylate safener can be provided as an agriculturally acceptable ester. Suitable esters include, but are not limited to, methyl, ethyl, isopropyl, butyl, hexyl, heptyl, isoheptyl, mexyl, isooctyl, 2-ethylhexyl and butoxyethyl esters, and aryl esters such as benzyl. Exemplary agriculturally acceptable esters of the azole carboxylate safeners described herein include methyl, ethyl, and diethyl esters. In some aspects, the azole carboxylate safener can comprise an agriculturally acceptable salt of the azole carboxylate safener. Agriculturally acceptable salts of the azole carboxylate safener include, for example sodium, potassium, ammonium, monoethanolammonium, diethanolammonium, triethanolammonium, monoisopropanolammonium, diisopropanolammonium, triisopropanolammonium, choline, N,N-dimethylethanolammonium, diethylammonium, dimethylammonium, trimethylammonium, triethylammonium, and isopropylammonium salts of the azole carboxylate safener. An azole carboxylate safener, when applied in combination with herbicides, can be used to reduce phytotoxicity to crops such as wheat, barley, triticale, rye, teff, oats, maize, sorghum, millet, rice, millet, canola/oilseed rape, flax, soy, sunflower, sugar beet, cotton, sugarcane, and pasture grasses. The azole carboxylate safener or an agriculturally acceptable salt or ester thereof can be used in an amount sufficient to induce a safening effect. In some aspects, the azole carboxylate safener is selected from the group consisting of fenchlorazole, fenclorim, flurazole, furilazole, isoxadifen, mefenpyr, an agriculturally acceptable salt or ester thereof, or combinations thereof, and is applied to vegetation or an area adjacent the vegetation or applied to soil or water in an amount of 1 g active ingredient per hectare (ai/ha) or greater, such as 2 g ai/ha or greater, 3 g ai/ha or greater, 4 g ai/ha or greater, 5 g ai/ha or greater, 6 g ai/ha or greater, 7 g ai/ha or greater, 8 g ai/ha or greater, 9 g ai/ha or greater, 10 g ai/ha or greater, 11 g ai/ha or greater, 12 g ai/ha or greater, 13 g ai/ha or greater, 14 g ai/ha or greater, 15 g ai/ha or greater, 16 g ai/ha or greater, 17 g ai/ha or greater, 18 g ai/ha or greater, 19 g ai/ha or greater, 20 g ai/ha or greater, 22 g ai/ha or greater, 24 g ai/ha or greater, 25 g ai/ha or greater, 26 g ai/ha or greater, 28 g ai/ha or greater, 30 g ai/ha or greater, 32 g ai/ha or greater, 34 g ai/ha or greater, 35 g ai/ha or greater, 36 g ai/ha or greater, 38 g ai/ha or greater, 40 g ai/ha or greater, 42.5 g ai/ha or greater, 45 g ai/ha or greater, 47.5 g ai/ha or greater, 50 g ai/ha or greater, 52.5 g ai/ha or greater,55 g ai/ha or greater, 57.5 g ai/ha or greater, 60 g ai/ha or greater, 65 g ai/ha or greater, 70 g ai/ha or greater, 75 g ai/ha or greater, 80 g ai/ha or greater, 85 g ai/ha or greater, 90 g ai/ha or greater, 95 g ai/ha or greater, 100 g ai/ha or greater, 110 g ai/ha or greater, 120 g ai/ha or greater, 130 g ai/ha or greater, 140 g ai/ha or greater, 150 g ai/ha or greater, 160 g ai/ha or greater, 170 g ai/ha or greater, 180 g ai/ha or greater, 190 g ai/ha or greater, 200 g ai/ha or greater, 210 g ai/ha or greater, 220 g ai/ha or greater, 230 g ai/ha or greater, 240 g ai/ha or greater, 250 g ai/ha or greater, 260 g ai/ha or greater, 270 g ai/ha or greater, 280 g ai/ha or greater, or 290 g ai/ha or greater; in an amount of 300 g ai/ha or less, such as 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g a/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 57.5 g ai/ha or less, 55 g ai/ha or less, 52.5 g ai/ha or less, 50 g ai/ha or less, 47.5 g ai/ha or less, 45 g ai/ha or less, 42.5 g ai/ha or less, 40 g ai/ha or less, 38 g ai/ha or less, 36 g ai/ha or less, 35 g ai/ha or less, 34 g ai/ha or less, 32 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 25 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18 g ai/ha or less, 17 g ai/ha or less, 16 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, 11 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, or 2 g ai/ha or less; or in an amount within any range defined between any pair of the preceding values, such as from 1 g ai/ha to 300 g ai/ha, from 5 g ai/ha to 150 g ai/ha, from 10 g ai/ha to 200 g ai/ha, from 20 g ai/ha to 75 g ai/ha, or from 40 g ai/ha to 100 g ai/ha. FORMULATIONS The present disclosure also includes formulations of the compositions and methods disclosed herein. Additives The compositions and methods disclosed herein can also be mixed with or applied with an additive. In some aspects, the additive is added sequentially. In some aspects, the additive is added simultaneously. In some aspects, the additive is premixed with the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof). In some aspects, the additive is premixed with the azole carboxylate safener or agriculturally acceptable salt or ester thereof. OTHER PESTICIDES Some aspects of the disclosed safened compositions disclosed include adding one or more additional pesticide active ingredients to the safened compositions. These pesticide active ingredients may include one or more of an herbicide, an insecticide, a fungicide, a nematocide, a miticide, a arthropodicide, a bactericide, a plant growth regulator, or combinations thereof that are compatible with the compositions of the present disclosure. In some aspects, the additive is an additional herbicide. For example, the compositions described herein can be applied in conjunction with one or more additional herbicides to control undesirable vegetation. The composition can be formulated with the one or more additional herbicides, tank mixed with the one or more additional herbicides, or applied sequentially with the one or more additional herbicides, such as the exemplary herbicides described below. ALS Inhibitors In addition to the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), the compositions can include an acetolactate synthase (ALS) inhibitor. ALS inhibitors disrupt the production of amino acids in the plant, which eventually leads to inhibition of DNA synthesis. Examples of ALS inhibitors include sulfonylureas, imidazolinones, triazolopyrimidine sulfonamides, pyrimidinyl oxybenzoates and sulfonylaminocarbonyl triazolinones. In some aspects, the ALS inhibitor can contain a triazolopyrimidine sulfonamide herbicide. In some aspects, the ALS inhibitor can contain an imidazolinone herbicide. In some aspects, the ALS inhibitor can contain a pyrimidinyl oxybenzoate herbicide. In some aspects, the ALS inhibitor can contain a sulfonylaminocarbonyl triazolinone herbicide. In some aspects, the ALS inhibitor can contain a sulfonylurea herbicide. In some aspects, the composition can include an ALS inhibitor selected from the group of imidazolinones, triazolopyrimidine sulfonamides, pyrimidinyl oxybenzoates, sulfonylaminocarbonyl triazolinones, sulfonylureas, and combinations thereof. In some cases, the composition can include amidosulfuron, azimsulfuron, bispyribac, bensulfuron, chlorimuron, chlorsulfuron, cinosulfuron, cloransulam, cyclosulfamuron, diclosulam, ethametsulfuron, ethoxysulfuron, flazasulfuron, florasulam, flucarbazone, flucetosulfuron, flumetsulam, flupyrsulfuron, foramsulfuron, halosulfuron, imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, imazosulfuron, iodosulfuron, iofensulfuron, mesosulfuron, metazosulfuron, metosulam, metsulfuron, nicosulfuron, orthosulfamuron, oxasulfuron, penoxsulam, primisulfuron, propoxycarbazone, propyrisulfuron, prosulfuron, pyrazosulfuron, pyribenzoxim, pyriftalid, pyriminobac, pyrimisulfan, pyrithiobac, pyroxsulam, rimsulfuron, sulfometuron, sulfosulfuron, thiencarbazone, thifensulfuron, triasulfuron, tribenuron, trifloxysulfuron, triflusulfuron, tritosulfuron, agriculturally acceptable salts and esters thereof, and combinations thereof. The ALS inhibitor or agriculturally acceptable salt or ester thereof can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, the ALS inhibitor or agriculturally acceptable salt or ester thereof is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 0.25 grams active ingredient per hectare (g ai/ha) or more, such as 0.3 g ai/ha or more, 0.4 g ai/ha or more, 0.5 g ai/ha or more, 0.6 g ai/ha or more, 0.7 g ai/ha or more, 0.8 g ai/ha or more, 0.9 g ai/ha or more, 1 g ai/ha or more, 1.5 g ai/ha or more, 2 g ai/ha or more, 2.5 g ai/ha or more, 3 g ai/ha or more, 3.5 g ai/ha or more, 4 g ai/ha or more, 4.5 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1550 g ai/ha or more, 1600 g ai/ha or more, 1650 g ai/ha or more, 1675 g ai/ha or more, 1680 g ai/ha or more, or 1690 g ai/ha or more; in an amount of 1700 g ai/ha or less, such as 1690 g ai/ha or less, 1680 g ai/ha or less, 1675 g ai/ha or less, 1650 g ai/ha or less, 1600 g ai/ha or less, 1550 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4.5 g ai/ha or less, 4 g ai/ha or less, 3.5 g ai/ha or less, 3 g ai/ha or less, 2.5 g ai/ha or less, 2 g ai/ha or less, 1.5 g ai/ha or less, 1 g ai/ha or less, 0.9 g ai/ha or less, 0.8 g ai/ha or less, 0.7 g ai/ha or less, 0.6 g ai/ha or less, 0.5 g ai/ha or less, 0.4 g ai/ha or less, or 0.3 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 0.25–1700 g ai/ha, 0.25–1250 g ai/ha, 0.5–150 g ai/ha, 2–90 g ai/ha, 2.5–200 g ai/ha, 3–900 g ai/ha, 5–260 g ai/ha, 5–750 g ai/ha, 5–1000 g ai/ha, 6–280 g ai/ha, 7–100 g ai/ha, 10–560 g ai/ha, 10–1600 g ai/ha, 20–500 g ai/ha, 25–140 g ai/ha, 30–480 g ai/ha, 40–400 g ai/ha, 50–320 g ai/ha, 60–300 g ai/ha, 70–1250 g ai/ha, 100–140 g ai/ha, 140–520 g ai/ha, or 250–1700 g ai/ha. Triazolopyrimidine Sulfonamide Herbicides In some aspects, the composition contains a herbicidally effective amount of compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and (b) florasulam, cloransulam, diclosulam, flumetsulam, metosulam, penoxsulam, or pyroxsulam, or agriculturally acceptable salts or esters thereof. Florasulam Compositions and methods of the present disclosure can include florasulam or an agriculturally acceptable salt or ester thereof. Florasulam, shown below, is a triazolopyrimidine sulfonamide that provides broad-spectrum control of many broad-leaved weeds in cereals and maize. Florasulam, as well as methods of preparing florasulam, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Sixteenth Edition, 2012. Florasulam can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, florasulam is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 0.25 g ai/ha or more, such as 0.3 g ai/ha or more, 0.4 g ai/ha or more, 0.5 g ai/ha or more, 0.6 g ai/ha or more, 0.7 g ai/ha or more, 0.8 g ai/ha or more, 0.9 g ai/ha or more, 1 g ai/ha or more, 1.1 g ai/ha or more, 1.25 g ai/ha or more, 1.5 g ai/ha or more, 1.75 g ai/ha or more, 2 g ai/ha or more, 2.25 g ai/ha or more, 2.5 g ai/ha or more, 2.75 g ai/ha or more, 3 g ai/ha or more, 3.25 g ai/ha or more, 3.5 g ai/ha or more, 3.75 g ai/ha or more, 4 g ai/ha or more, 4.25 g ai/ha or more, 4.5 g ai/ha or more, 4.75 g ai/ha or more, 5 g ai/ha or more, 5.25 g ai/ha or more, 5.5 g ai/ha or more, 5.75 g ai/ha or more, 6 g ai/ha or more, 6.25 g ai/ha or more, 6.5 g ai/ha or more, 6.75 g ai/ha or more, 7 g ai/ha or more, 7.25 g ai/ha or more, 7.5 g ai/ha or more, 8 g ai/ha or more, 8.5 g ai/ha or more, 9 g ai/ha or more, or 9.5 g ai/ha, or more; in an amount of 10 g ai/ha or less, such as 9.5 g ai/ha or less, 9 g ai/ha or less, 8.5 g ai/ha or less, 8 g ai/ha or less 7.5 g ai/ha or less, 7.25 g ai/ha or less, 7 g ai/ha or less, 6.75 g ai/ha or less, 6.5 g ai/ha or less, 6.25 g ai/ha or less, 6 g ai/ha or less, 5.75 g ai/ha or less, 5.5 g ai/ha or less, 5.25 g ai/ha or less, 5 g ai/ha or less, 4.75 g ai/ha or less, 4.5 g ai/ha or less, 4.25 g ai/ha or less, 4 g ai/ha or less, 3.75 g ai/ha or less, 3.5 g ai/ha or less, 3.25 g ai/ha or less, 3 g ai/ha or less, 2.75 g ai/ha or less, 2.5 g ai/ha or less, 2.25 g ai/ha or less, 2 g ai/ha or less, 1.75 g ai/ha or less, 1.5 g ai/ha or less, 1.25 g ai/ha or less, 1 g ai/ha or less, 0.9 g ai/ha or less, 0.8 g ai/ha or less, 0.7 g ai/ha or less, 0.6 g ai/ha or less, 0.5 g ai/ha or less, 0.4 g ai/ha or less, or 0.3 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 0.25–10 g ai/ha, 0.25–7 g ai/ha, 0.4–6.5 g ai/ha, 0.5–6 g ai/ha, 0.6–9 g ai/ha, 0.7–8.5 g ai/ha, 0.8–4.5 g ai/ha, 1–4 g ai/ha, 1.1-7.5 g ai/ha, 1.5–5.75 g ai/ha, 2–7.25 g ai/ha, 2.25–10 g ai/ha, 3–8.5 g ai/ha, or 3.5–9.5 g ai/ha. Cloransulam Compositions and methods of the present disclosure can include cloransulam or an agriculturally acceptable salt or ester thereof. Cloransulam, as well as methods of preparing cloransulam, are known in the art. In some aspects, cloransulam can be provided as an agriculturally acceptable ester of cloransulam. Cloransulam-methyl, shown below, is a triazolopyrimidine sulfonamide that provides broad-spectrum control of many broadleaf weeds in soybeans and other broadleaf crops. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Cloransulam can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, cloransulam is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2.18 g ai/ha or more, such as 2.25 g ai/ha or more, 2.5 g ai/ha or more, 2.75 g ai/ha or more, 3 g ai/ha or more, 3.25 g ai/ha or more, 3.5 g ai/ha or more, 3.75 g ai/ha or more, 4 g ai/ha or more, 4.5 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9g ai/ha or more, 10 g ai/ha or more, 12 g ai/ha or more, 14 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 36 g ai/ha or more, 38 g ai/ha or more, 40 g ai/ha or more, 42 g ai/ha or more, 44 g ai/ha or more, 46 g ai/ha or more, 48 g ai/ha or more, 50 g ai/ha or more, 51 g ai/ha or more, 52 g ai/ha or more, 53 g ai/ha or more, 54 g ai/ha or more, 55 g ai/ha or more, 56 g ai/ha or more, 57 g ai/ha or more, 58 g ai/ha or more, or 59 g ai/ha or more; in an amount of 61 g ai/ha or less, such as 60 g ai/ha or less, 59 g ai/ha or less, 58 g ai/ha or less, 57 g ai/ha or less, 56 g ai/ha or less, 55 g ai/ha or less, 54 g ai/ha or less, 53 g ai/ha or less, 52 g ai/ha or less, 51 g ai/ha or less, 50 g ai/ha or less, 48 g ai/ha or less, 46 g ai/ha or less, 44 g ai/ha or less, 42 g ai/ha or less, 40 g ai/ha or less, 38 g ai/ha or less, 36 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 18 g ai/ha or less, 16 g ai/ha or less, 14 g ai/ha or less, 12 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4.5 g ai/ha or less, 4 g ai/ha or less, 3.75 g ai/ha or less, 3.5 g ai/ha or less, 3.25 g ai/ha or less, 3 g ai/ha or less, 2.75 g ai/ha or less, 2.5 g ai/ha or less, or 2.25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2.18–61 g ai/ha, 2.5–60 g ai/ha, 2.75–44 g ai/ha, 3–59 g ai/ha, 3.25–60 g ai/ha, 3.5–40 g ai/ha, 3.75–18 g ai/ha, 3.75–50 g ai/ha, 4–60 g ai/ha, 4–52 g ai/ha, 4.25–30 g ai/ha, 4.25–55 g ai/ha, 4.5–51 g ai/ha, or 5–38 g ai/ha. Diclosulam Compositions and methods of the present disclosure can include diclosulam or an agriculturally acceptable salt or ester thereof. Diclosulam, shown below, is a triazolopyrimidine sulfonamide that provides broad-spectrum control of many broadleaf weeds in soybeans and peanuts. Diclosulam, as well as methods of preparing diclosulam, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Diclosulam can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, diclosulam is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2.18 g ai/ha or more, such as 2.25 g ai/ha or more, 2.5 g ai/ha or more, 2.75 g ai/ha or more, 3 g ai/ha or more, 3.25 g ai/ha or more, 3.5 g ai/ha or more, 4 g ai/ha or more, 4.5 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12 g ai/ha or more, 14 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 27 g ai/ha or more, 28 g ai/ha or more, 29 g ai/ha or more, 30 g ai/ha or more, 31g ai/ha or more, 31.5 g ai/ha or more, 32 g ai/ha or more, 32.5 g ai/ha or more, 33 g ai/ha or more, 33.5 g ai/ha or more, 34 g ai/ha or more, 34.5 g ai/ha or more, or 34.75 g ai/ha or more; in an amount of 35 g ai/ha or less, such as 34.5 g ai/ha or less, 34 g ai/ha or less, 33.5 g ai/ha or less, 33 g ai/ha or less, 32.5 g ai/ha or less, 32 g ai/ha or less, 31.5 g ai/ha or less, 31 g ai/ha or less, 30 g ai/ha or less, 29 g ai/ha or less, 28 g ai/ha or less, 27 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 18 g ai/ha or less, 16 g ai/ha or less, 14 g ai/ha or less, 12 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4.5 g ai/ha or less, 4 g ai/ha or less, 3.5 g ai/ha or less, 2.75 g ai/ha or less, 2.5 g ai/ha or less, 2.25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2.18–35 g ai/ha, 2.5–34 g ai/ha, 2.75–22 g ai/ha, 3–29 g ai/ha, 3.25–34 g ai/ha, 3.25–32 g ai/ha, 3.5–30 g ai/ha, 3.75–27 g ai/ha, 4–35 g ai/ha, 4–30 g ai/ha, 4.5–18 g ai/ha, 4.5–33.5 g ai/ha, 5–32 g ai/ha, or 6–33 g ai/ha. Flumetsulam Compositions and methods of the present disclosure can include flumetsulam or an agriculturally acceptable salt or ester thereof. Flumetsulam, shown below, is a triazolopyrimidine sulfonamide that provides control of broadleaf weeds and greens in soybeans, field peas, and maize. Flumetsulam, as well as methods of preparing flumetsulam, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Flumetsulam can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, flumetsulam is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2.18 g ai/ha or more, such as 2.5 g ai/ha or more, 2.75 g ai/ha or more, 3 g ai/ha or more, 3.5 g ai/ha or more, 4 g ai/ha or more, 4.5 g ai/ha or more, 5 g ai/ha or more, 7 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 36 g ai/ha or more, 37 g ai/ha or more, 38 g ai/ha or more, 39 g ai/ha or more, 40 g ai/ha or more, 41 g ai/ha or more, 42 g ai/ha or more, 44 g ai/ha or more, 46 g ai/ha or more, 48 g ai/ha or more, 50 g ai/ha or more, 52 g ai/ha or more, 54 g ai/ha or more, 56 g ai/ha or more, 58 g ai/ha or more, 60 g ai/ha or more, 62 g ai/ha or more, 64 g ai/ha or more, 66 g ai/ha or more, 68 g ai/ha or more, 70 g ai/ha or more, 72 g ai/ha or more, 74 g ai/ha or more, or 77 g ai/ha or more; in an amount of 78 g ai/ha or less, such as 77 g ai/ha or less, 75 g ai/ha or less, 74 g ai/ha or less, 72 g ai/ha or less, 70 g ai/ha or less, 68 g ai/ha or less, 66 g ai/ha or less, 64 g ai/ha or less, 62 g ai/ha or less, 60 g ai/ha or less, 58 g ai/ha or less, 56 g ai/ha or less, 54 g ai/ha or less, 52 g ai/ha or less, 50 g ai/ha or less, 48 g ai/ha or less, 46 g ai/ha or less, 44 g ai/ha or less, 42 g ai/ha or less, 41 g ai/ha or less, 40 g ai/ha or less, 39 g ai/ha or less, 38 g ai/ha or less, 37 g ai/ha or less, 36 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 7 g ai/ha or less, 5 g ai/ha or less, 4.5 g ai/ha or less, 4 g ai/ha or less, 3.5 g ai/ha or less, 3 g ai/ha or less, 2.75 g ai/ha or less, 2.5 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2.18–78 g ai/ha, 2.5–75 g ai/ha, 2.75–54 g ai/ha, 3–46 g ai/ha, 3–78 g ai/ha, 3.5–39 g ai/ha, 3.5–72 g ai/ha, 4–60 g ai/ha, 4–75 g ai/ha, 4.5–25 g ai/ha, 4.5–66 g ai/ha, 5–58 g ai/ha, or 9–62 g ai/ha. Penoxsulam Compositions and methods of the present disclosure can include penoxsulam or an agriculturally acceptable salt or ester thereof. Penoxsulam, shown below, is a triazolopyrimidine sulfonamide that provides control of Echinochloa spp., as well as many broadleaf, sedge, and aquatic weeds in rice. Penoxsulam, as well as methods of preparing penoxsulam, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Penoxsulam can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, penoxsulam is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2.5 g ai/ha or more, such as 2.75 g ai/ha or more, 3 g ai/ha or more, 3.5 g ai/ha or more, 4 g ai/ha or more, 4.5 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12 g ai/ha or more, 14 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 32 g ai/ha or more, 34 g ai/ha or more, 36 g ai/ha or more, 38 g ai/ha or more, 40 g ai/ha or more, 41 g ai/ha or more, 42 g ai/ha or more, 43 g ai/ha or more, 44 g ai/ha or more, 45 g ai/ha or more, 46 g ai/ha or more, 47 g ai/ha or more, 48 g ai/ha or more, or 49 g ai/ha or more; in an amount of 50 g ai/ha or less, such as 49 g ai/ha or less, 48 g ai/ha or less, 47 g ai/ha or less, 46 g ai/ha or less, 45 g ai/ha or less, 44 g ai/ha or less, 43 g ai/ha or less, 42 g ai/ha or less, 41 g ai/ha or less, 40 g ai/ha or less, 38 g ai/ha or less, 36 g ai/ha or less, 34 g ai/ha or less, 32 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 18 g ai/ha or less, 16 g ai/ha or less, 14 g ai/ha or less, 12 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4.75 g ai/ha or less, 4.5 g ai/ha or less, 4.25 g ai/ha or less, 4 g ai/ha or less, 3.5 g ai/ha or less, 3 g ai/ha or less, or 2.75 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2.5– 50 g ai/ha, 3–28 g ai/ha, 3.5–40 g ai/ha, 4–34 g ai/ha, 4.25–50 g ai/ha, 4.5–47 g ai/ha, 5–45 g ai/ha, 6–36 g ai/ha, 8–22 g ai/ha, or 10–49 g ai/ha. Pyroxsulam Compositions and methods of the present disclosure can include pyroxsulam or an agriculturally acceptable salt or ester thereof. Pyroxsulam, shown below, is a triazolopyrimidine sulfonamide that provides broad spectrum post-emergence annual grass and broadleaf weeds control in cereals. Pyroxsulam, as well as methods of preparing pyroxsulam, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Pyroxsulam can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pyroxsulam is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1.9 g ai/ha or more, such as 2 g ai/ha or more, 2.25 g ai/ha or more, 2.5 g ai/ha or more, 2.75 g ai/ha or more, 3 g ai/ha or more, 3.25 g ai/ha or more, 3.5 g ai/ha or more, 3.75 g ai/ha or more, 4 g ai/ha or more, 4.5 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 9.5 g ai/ha or more, 10 g ai/ha or more, 10.5 g ai/ha or more, 11 g ai/ha or more, 11.5 g ai/ha or more, 12 g ai/ha or more, 12.5 g ai/ha or more, 13 g ai/ha or more, 13.5 g ai/ha or more, 14 g ai/ha or more, 14.5 g ai/ha or more, 15 g ai/ha or more, 15.25 g ai/ha or more, 15.5 g ai/ha or more, 15.75 g ai/ha or more, 16 g ai/ha or more, 16.25 g ai/ha or more, 16.5 g ai/ha or more, 16.75 g ai/ha or more, 17 g ai/ha or more, 17.25 g ai/ha or more, 17.5 g ai/ha or more, 17.75 g ai/ha or more, 18 g ai/ha or more, 18.25 g ai/ha or more, or 18.5 g ai/ha or more; in an amount of 18.75 g ai/ha or less, such as 18.5 g ai/ha or less, 18.25 g ai/ha or less, 18 g ai/ha or less, 17.75 g ai/ha or less, 17.5 g ai/ha or less, 17.25 g ai/ha or less, 17 g ai/ha or less, 16.75 g ai/ha or less, 16.5 g ai/ha or less, 16.25 g ai/ha or less, 16 g ai/ha or less, 15.75 g ai/ha or less, 15.5 g ai/ha or less, 15.25 g ai/ha or less, 15 g ai/ha or less, 14.5 g ai/ha or less, 14 g ai/ha or less, 13.5 g ai/ha or less, 13 g ai/ha or less, 12.5 g ai/ha or less, 12 g ai/ha or less, 11.5 g ai/ha or less, 11 g ai/ha or less, 10.5 g ai/ha or less, 10 g ai/ha or less, 9.5 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4.5 g ai/ha or less, 4 g ai/ha or less, 3.5 g ai/ha or less, 3.25 g ai/ha or less, 3 g ai/ha or less, 2.75 g ai/ha or less, 2.5 g ai/ha or less, or 2.25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1.9–18.75 g ai/ha, 2.25–18 g ai/ha, 2.5–14.5 g ai/ha, 2.75–12.5 g ai/ha, 2.75–18.5 g ai/ha, 3–13 g ai/ha, 3.25–10.5 g ai/ha, 3.5–16 g ai/ha, 4–15.25 g ai/ha, 5–18 g ai/ha, 6–17.75 g ai/ha, 8–16 g ai/ha, 9–18 g ai/ha, or 10–14.5 g ai/ha. IMIDAZOLINONE HERBICIDES In some aspects, the composition contains a herbicidally effective amount of compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and (b) imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, or agriculturally acceptable salts or esters thereof, or combinations thereof.
Imazamethabenz Compositions and methods of the present disclosure can include imazamethabenz or an agriculturally acceptable salt or ester thereof. Imazamethabenz, shown below, is a mixture of isomers and an imidazolinone that provides post-emergence control of Avena species, Alopecurus myosuroides, Apera spica-venti and dicotyledonous weeds in wheat, barley, rye and sunflowers. Imazamethabenz, as well as methods of preparing imazamethabenz, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Imazamethabenz can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, imazamethabenz is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 620 g ai/ha or more, 640 g ai/ha or more, 650 g ai/ha or more, 660 g ai/ha or more, 670 g ai/ha or more, 680 g ai/ha or more, or 690 g ai/ha or more; in an amount of 700 g ai/ha or less, such as 690 g ai/ha or less, 680 g ai/ha or less, 670 g ai/ha or less, 660 g ai/ha or less, 650 g ai/ha or less, 640 g ai/ha or less, 620 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, or 55 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–700 g ai/ha, 55–400 g ai/ha, 60–650 g ai/ha, 75–520 g ai/ha, 80–400 g ai/ha, 85–500 g ai/ha, 90–220 g ai/ha, 100–700 g ai/ha, 100– 500 g ai/ha, 110–640 g ai/ha, 120–420 g ai/ha, 120–500 g ai/ha, 140–670 g ai/ha, or 150–580 g ai/ha. Imazamox Compositions and methods of the present disclosure can include imazamox or an agriculturally acceptable salt or ester thereof. Imazamox, shown below, is an imidazolinone that provides pre- and post-emergence control of broadleaf and grass weeds, e.g., in rice, maize, rape, alfalfa, peas and beans. Imazamox, as well as methods of preparing imazamox, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Imazamox can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, imazamox is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 5 g ai/ha or more, such as 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 11 g ai/ha or more, 12 g ai/ha or more, 13 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 17 g ai/ha or more, 18 g ai/ha or more, 19 g ai/ha or more, 20 g ai/ha or more, 21 g ai/ha or more, 22 g ai/ha or more, 23 g ai/ha or more, 24 g ai/ha or more, 25 g ai/ha or more, 26 g ai/ha or more, 27 g ai/ha or more, 28 g ai/ha or more, 29 g ai/ha or more, 30 g ai/ha or more, 32 g ai/ha or more, 34 g ai/ha or more, 36 g ai/ha or more, 38 g ai/ha or more, 40 g ai/ha or more, 44 g ai/ha or more, 46 g ai/ha or more, 48 g ai/ha or more, 50 g ai/ha or more, 52 g ai/ha or more, 54 g ai/ha or more, 56 g ai/ha or more, or 58 g ai/ha or more; in an amount of 60 g ai/ha or less, such as 58 g ai/ha or less, 56 g ai/ha or less, 54 g ai/ha or less, 52 g ai/ha or less, 50 g ai/ha or less, 48 g ai/ha or less, 46 g ai/ha or less, 44 g ai/ha or less, 42 g ai/ha or less, 40 g ai/ha or less, 38 g ai/ha or less, 36 g ai/ha or less, 34 g ai/ha or less, 32 g ai/ha or less, 30 g ai/ha or less, 29 g ai/ha or less, 28 g ai/ha or less, 27 g ai/ha or less, 26 g ai/ha or less, 25 g ai/ha or less, 24 g ai/ha or less, 23 g ai/ha or less, 22 g ai/ha or less, 21 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18 g ai/ha or less, 17 g ai/ha or less, 16 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, 11 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, or 6 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 5–60 g ai/ha, 5–52 g ai/ha, 6–46 g ai/ha, 6–54 g ai/ha, 7–38 g ai/ha, 7–50 g ai/ha, 8–48 g ai/ha, 9–45 g ai/ha, 10–40 g ai/ha, 10–58 g ai/ha, 11–36 g ai/ha, 12–54 g ai/ha, 13–60 g ai/ha, or 15–48 g ai/ha. Imazapic Compositions and methods of the present disclosure can include imazapic or an agriculturally acceptable salt or ester thereof. Imazapic, shown below, is an imidazolinone that provides pre- and post-emergence control of a wide range of annual and perennial weeds in pasture, rangeland and non-cropland areas. Imazapic, as well as methods of preparing imazapic, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Imazapic can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, imazapic is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 17.5 g ai/ha or more, such as 18 g ai/ha or more, 19 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 155 g ai/ha or more, 160 g ai/ha or more, 165 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 185 g ai/ha or more, 190 g ai/ha or more, 195 g ai/ha or more, 200 g ai/ha or more, 205 g ai/ha or more, 210 g ai/ha or more, or 215 g ai/ha or more; in an amount of 220 g ai/ha or less, such as 215 g ai/ha or less, 210 g ai/ha or less, 205 g ai/ha or less, 200 g ai/ha or less, 195 g ai/ha or less, 190 g ai/ha or less, 185 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 165 g ai/ha or less, 160 g ai/ha or less, 155 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, or 18 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 17.5–220 g ai/ha, 17.5–210 g ai/ha, 18–200 g ai/ha, 19–120 g ai/ha, 20–210 g ai/ha, 20–170 g ai/ha, 22–190 g ai/ha, 24–175 g ai/ha, 26–210 g ai/ha, 26–160 g ai/ha, 30–190 g ai/ha, 30–140 g ai/ha, 35–220 g ai/ha, or 45–215 g ai/ha. Imazapyr Compositions and methods of the present disclosure can include imazapyr or an agriculturally acceptable salt or ester thereof. Imazapyr, shown below, is an imidazolinone that provides pre- and post-emergence control of annual and perennial grasses, broadleaf weeds, brush and trees. Imazapyr, as well as methods of preparing imazapyr, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Imazapyr can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, imazapyr is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 100 g ai/ha or more, such as 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 600 g ai/ha or more, 700 g ai/ha or more, 800 g ai/ha or more, 900 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1550 g ai/ha or more, 1600 g ai/ha or more, 1620 g ai/ha or more, 1640 g ai/ha or more, 1660 g ai/ha or more, or 1680 g ai/ha or more; in an amount of 1700 g ai/ha or less (e.g., 1680 g ai/ha or less, 1660 g ai/ha or less, 1640 g ai/ha or less, 1620 g ai/ha or less, 1600 g ai/ha or less, 1550 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 900 g ai/ha or less, 800 g ai/ha or less, 700 g ai/ha or less, 600 g ai/ha or less, 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, or 110 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 100–1700 g ai/ha, 125–850 g ai/ha, 130–700 g ai/ha, 150–1000 g ai/ha, 160–475 g ai/ha, 170–1660 g ai/ha, 180–1500 g ai/ha, 190– 1050 g ai/ha, 200–700 g ai/ha, 250–1500 g ai/ha, 325–1200 g ai/ha, 450–1500 g ai/ha, 500– 900 g ai/ha, or 110–1000 g ai/ha. Imazethapyr Compositions and methods of the present disclosure can include imazethapyr or an agriculturally acceptable salt or ester thereof. Imazethapyr, shown below, is an imidazolinone that controls many major annual and perennial grass and broadleaf weeds in most major crops. Imazethapyr, as well as methods of preparing imazethapyr, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Imazethapyr can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, imazethapyr is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 8.75 g ai/ha or more, such as 9 g ai/ha or more, 10 g ai/ha or more, 11 g ai/ha or more, 12 g ai/ha or more, 13 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 272 g ai/ha or more, 274 g ai/ha or more, 276 g ai/ha or more, or 278 g ai/ha or more; in an amount of 280 g ai/ha or less, such as 278 g ai/ha or less, 276 g ai/ha or less, 274 g ai/ha or less, 272 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 18 g ai/ha or less, 16 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, 11 g ai/ha or less, 10 g ai/ha or less, or 9 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 8.75–280 g ai/ha, 8.75–170 g ai/ha, 9–220 g ai/ha, 10–260 g ai/ha, 10–150 g ai/ha, 11-220 g ai/ha, 12–200 g ai/ha, 13–274 g ai/ha, 15–230 g ai/ha, 16–160 g ai/ha, 18–280 g ai/ha, 20–210 g ai/ha, 20– 190 g ai/ha, or 25–272 g ai/ha. PYRIMIDINYL OXYBENZOATE HERBICIDES In some aspects, the composition contains a herbicidally effective amount of compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and (b) bispyribac, pyribenzoxim, pyriftalid, pyriminobac, pyrimisulfan, pyrithiobac, or agriculturally acceptable salts or esters thereof, or combinations thereof. Bispyribac Compositions and methods of the present disclosure can include bispyribac or an agriculturally acceptable salt or ester thereof. Bispyribac-sodium, shown below, is a pyrimidinyl oxybenzoate that provides control of grasses, sedges and broadleaf weeds, e.g., in direct-seeded and water-seeded rice and in turf. Bispyribac-sodium, as well as methods of preparing bispyribac-sodium, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Bispyribac can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, bispyribac is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 5 g ai/ha or more, such as 7.5 g ai/ha or more, 10 g ai/ha or more, 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 22.5 g ai/ha or more, 25 g ai/ha or more, 27.5 g ai/ha or more, 30 g ai/ha or more, 32.5 g ai/ha or more, 35 g ai/ha or more, 37.5 g ai/ha or more, 40 g ai/ha or more, 42.5 g ai/ha or more, 45 g ai/ha or more, 47.5 g ai/ha or more, 50 g ai/ha or more, 52.5 g ai/ha or more, 55 g ai/ha or more, 57.5 g ai/ha or more, 60 g ai/ha or more, 62.5 g ai/ha or more, 65 g ai/ha or more, 67.5 g ai/ha or more, 70 g ai/ha or more, 72.5 g ai/ha or more, 75 g ai/ha or more, 77.5 g ai/ha or more, 80 g ai/ha or more, 82.5 g ai/ha or more, 85 g ai/ha or more, 87.5 g ai/ha or more, 90 g ai/ha or more, 92.5 g ai/ha or more, 95 g ai/ha or more, 97.5 g ai/ha or more; in an amount of 100 g ai/ha or less, such as 97.5 g ai/ha or less, 95 g ai/ha or less, 92.5 g ai/ha or less, 90 g ai/ha or less, 87.5 g ai/ha or less, 85 g ai/ha or less, 82.5 g ai/ha or less, 80 g ai/ha or less, 77.5 g ai/ha or less, 75 g ai/ha or less, 72.5 g ai/ha or less, 70 g ai/ha or less, 67.5 g ai/ha or less, 65 g ai/ha or less, 62.5 g ai/ha or less, 60 g ai/ha or less, 57.5 g ai/ha or less, 55 g ai/ha or less, 52.5 g ai/ha or less, 50 g ai/ha or less, 47.5 g ai/ha or less, 45 g ai/ha or less, 42.5 g ai/ha or less, 40 g ai/ha or less, 37.5 g ai/ha or less, 35 g ai/ha or less, 32.5 g ai/ha or less, 30 g ai/ha or less, 27.5 g ai/ha or less, 25 g ai/ha or less, 22.5 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, 12.5 g ai/ha or less, 10 g ai/ha or less, or 7.5 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 5–100 g ai/ha, 5–90 g ai/ha, 7.5–45 g ai/ha, 10–55 g ai/ha, 15–90 g ai/ha, 20– 50 g ai/ha, 22.5–90 g ai/ha, 25–52.5 g ai/ha, 25–80 g ai/ha, 25–65 g ai/ha, 27.5–60 g ai/ha, 27.5–47.5 g ai/ha, 30–85 g ai/ha, or 40–95 g ai/ha.
Pyribenzoxim Compositions and methods of the present disclosure can include pyribenzoxim or an agriculturally acceptable salt or ester thereof. Pyribenzoxim, shown below, is a pyrimidinyl oxybenzoate that provides post-emergence control of barnyard grass, blackgrass and Polygonum species in rice, wheat and zoysiagrass. Pyribenzoxim, as well as methods of preparing pyribenzoxim, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Pyribenzoxim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pyribenzoxim is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 7.5 g ai/ha or more, such as 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 11 g ai/ha or more, 12 g ai/ha or more, 13 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 17 g ai/ha or more, 18 g ai/ha or more, 19 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 32 g ai/ha or more, 34 g ai/ha or more, 36 g ai/ha or more, 38 g ai/ha or more, 40 g ai/ha or more, 42 g ai/ha or more, 44 g ai/ha or more, 46 g ai/ha or more, 48 g ai/ha or more, 50 g ai/ha or more, 52 g ai/ha or more, 54 g ai/ha or more, 56 g ai/ha or more, 58 g ai/ha or more, 60 g ai/ha or more, 62 g ai/ha or more, 64 g ai/ha or more, 66 g ai/ha or more, 68 g ai/ha or more, or 69 g ai/ha or more; in an amount of 70 g ai/ha or less, such as 69 g ai/ha or less, 68 g ai/ha or less, 66 g ai/ha or less, 64 g ai/ha or less, 62 g ai/ha or less, 60 g ai/ha or less, 58 g ai/ha or less, 56 g ai/ha or less, 54 g ai/ha or less, 52 g ai/ha or less, 50 g ai/ha or less, 48 g ai/ha or less, 46 g ai/ha or less, 44 g ai/ha or less, 42 g ai/ha or less, 40 g ai/ha or less, 38 g ai/ha or less, 36 g ai/ha or less, 34 g ai/ha or less, 32 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18 g ai/ha or less, 17 g ai/ha or less, 16 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, 11 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, or 8 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 7.5–70 g ai/ha, 7.5– 68 g ai/ha, 7.5–52 g ai/ha, 8–60 g ai/ha, 9–38 g ai/ha, 9–64 g ai/ha, 10–66 g ai/ha, 10–44 g ai/ha, 10–40 g ai/ha, 11–62 g ai/ha, 12–46 g ai/ha, 13–70 g ai/ha, 15–54 g ai/ha, or 20–64 g ai/ha. Pyriftalid Compositions and methods of the present disclosure can include pyriftalid or an agriculturally acceptable salt or ester thereof. Pyriftalid, shown below, is a pyrimidinyl oxybenzoate that provides control of grass weeds in rice. Pyriftalid, as well as methods of preparing pyriftalid, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Pyriftalid can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pyriftalid is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 20 g ai/ha or more, such as 22 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, or 345 g ai/ha or more; in an amount of 350 g ai/ha or less, such as 345 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, or 22 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 20-350 g ai/ha, 55–170 g ai/ha, 22–220 g ai/ha, 70–260 g ai/ha, 30–250 g ai/ha, 45-220 g ai/ha, 80–200 g ai/ha, 130–270 g ai/ha, 150–330 g ai/ha, 60–160 g ai/ha, 180–345 g ai/ha, 210–310 g ai/ha, 90–190 g ai/ha, or 22–340 g ai/ha. Pyriminobac Compositions and methods of the present disclosure can include pyriminobac or an agriculturally acceptable salt or ester thereof. Pyriminobac, shown below, is a pyrimidinyl oxybenzoate that provides post-emergence control of Echinochloa spp., in paddy rice. Pyriminobac, as well as methods of preparing pyriminobac, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Pyriminobac can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pyriminobac is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 20 g ai/ha or more, such as 22 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, or 170 g ai/ha or more; in an amount of 175 g ai/ha or less, such as 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, or 22 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 20–175 g ai/ha, 22–170 g ai/ha, 35–120 g ai/ha, 100–160 g ai/ha, 40–150 g ai/ha, 80-120 g ai/ha, 25–110 g ai/ha, 90–150 g ai/ha, 45–130 g ai/ha, 60–160 g ai/ha, 30–120 g ai/ha, 20–160 g ai/ha, or 22–100 g ai/ha. SULFONYLAMINOCARBONYL TRIAZOLINONE HERBICIDES In some aspects, the composition contains a herbicidally effective amount of compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and (b) flucarbazone, propoxycarbazone, thiencarbazone, or agriculturally acceptable salts or esters thereof, or combinations thereof. Flucarbazone Compositions and methods of the present disclosure can include flucarbazone or an agriculturally acceptable salt or ester thereof. Flucarbazone, shown below, is a sulfonylamino- carbonyl triazolinone that provides post-emergence control of annual grass weeds and some perennial grass weeds and some broad-leaved weeds. Flucarbazone, as well as methods of preparing flucarbazone, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Flucarbazone can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, flucarbazone is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 3.75 g ai/ha or more, such as 4 g ai/ha or more, 4.25 g ai/ha or more, 4.5 g ai/ha or more, 4.75 g ai/ha or more, 5 g ai/ha or more, 5.25 g ai/ha or more, 5.5 g ai/ha or more, 5.75 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 7.5 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 11 g ai/ha or more, 12 g ai/ha or more, 13 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 17 g ai/ha or more, 18 g ai/ha or more, 19 g ai/ha or more, 20 g ai/ha or more, 21 g ai/ha or more, 22 g ai/ha or more, 23 g ai/ha or more, 24 g ai/ha or more, 25 g ai/ha or more, 25.5 g ai/ha or more, 26 g ai/ha or more, 26.5 g ai/ha or more, 27 g ai/ha or more, 27.5 g ai/ha or more, 28 g ai/ha or more, 28.5 g ai/ha or more, 29 g ai/ha or more, 29.25 g ai/ha or more, 29.5 g ai/ha or more, or 29.75 g ai/ha or more; in an amount of 30 g ai/ha or less, such as 29.75 g ai/ha or less, 29.5 g ai/ha or less, 29.25 g ai/ha or less, 29 g ai/ha or less, 28.5 g ai/ha or less, 28 g ai/ha or less, 27.5 g ai/ha or less, 27 g ai/ha or less, 26.5 g ai/ha or less, 26 g ai/ha or less, 25 g ai/ha or less, 24 g ai/ha or less, 23 g ai/ha or less, 22 g ai/ha or less, 21 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18 g ai/ha or less, 17 g ai/ha or less, 16 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, 11 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7.5 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5.75 g ai/ha or less, 5.5 g ai/ha or less, 5.25 g ai/ha or less, 5 g ai/ha or less, 4.75 g ai/ha or less, 4.5 g ai/ha or less, 4.25 g ai/ha or less, or 4 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 3.75–30 g ai/ha, 3.75–27 g ai/ha, 4–28 g ai/ha, 4–20 g ai/ha, 5–29.5 g ai/ha, 5–21 g ai/ha, 5.5–28 g ai/ha, 6–26 g ai/ha, 7– 25 g ai/ha, 7.5–30 g ai/ha, 7.5–21 g ai/ha, 8–25 g ai/ha, 9–19 g ai/ha, or 10–28.5 g ai/ha. Propoxycarbazone Compositions and methods of the present disclosure can include propoxycarbazone or an agriculturally acceptable salt or ester thereof. Propoxycarbazone, shown below, is a sulfonylaminocarbonyl triazolinone that provides post-emergence control of grass weeds and some broad-leaved weeds. Propoxycarbazone, as well as methods of preparing propoxycarbazone, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Propoxycarbazone can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, propoxycarbazone is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 3.75 g ai/ha or more, such as 4 g ai/ha or more, 4.25 g ai/ha or more, 4.5 g ai/ha or more, 4.75 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12 g ai/ha or more, 14 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 32 g ai/ha or more, 34 g ai/ha or more, 36 g ai/ha or more, 38 g ai/ha or more, 40 g ai/ha or more, 42 g ai/ha or more, 44 g ai/ha or more, 46 g ai/ha or more, 48 g ai/ha or more, 50 g ai/ha or more, 52 g ai/ha or more, 54 g ai/ha or more, 56 g ai/ha or more, 58 g ai/ha or more, 60 g ai/ha or more, 61 g ai/ha or more, 62 g ai/ha or more, 63 g ai/ha or more, 64 g ai/ha or more, 65 g ai/ha or more, 66 g ai/ha or more, 67 g ai/ha or more, 68 g ai/ha or more, or 69 g ai/ha or more; in an amount of 70 g ai/ha or less, such as 69 g ai/ha or less, 68 g ai/ha or less, 67 g ai/ha or less, 66 g ai/ha or less, 65 g ai/ha or less, 64 g ai/ha or less, 63 g ai/ha or less, 62 g ai/ha or less, 61 g ai/ha or less, 60 g ai/ha or less, 58 g ai/ha or less, 56 g ai/ha or less, 54 g ai/ha or less, 52 g ai/ha or less, 50 g ai/ha or less, 48 g ai/ha or less, 46 g ai/ha or less, 44 g ai/ha or less, 42 g ai/ha or less, 40 g ai/ha or less, 38 g ai/ha or less, 36 g ai/ha or less, 34 g ai/ha or less, 32 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 28 g ai/ha or less, 16 g ai/ha or less, 14 g ai/ha or less, 12 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4.75 g ai/ha or less, 4.5 g ai/ha or less, 4.25 g ai/ha or less, or 4 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 3.75–70 g ai/ha, 4–68 g ai/ha, 4.25–56 g ai/ha, 4.5– 28 g ai/ha, 5–62 g ai/ha, 5–38 g ai/ha, 7–70 g ai/ha, 8–52 g ai/ha, 9–40 g ai/ha, 10–70 g ai/ha, 10–24 g ai/ha, 12–69 g ai/ha, 14–65 g ai/ha, or 20–58 g ai/ha. Thiencarbazone Compositions and methods of the present disclosure can include thiencarbazone or an agriculturally acceptable salt or ester thereof. Thiencarbazone-methyl, shown below, is a sulfonylaminocarbonyl triazolinone that provides post-emergence control of grass weeds and some broad-leaved weeds. Thiencarbazone, as well as methods of preparing thiencarbazone, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Thiencarbazone can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, thiencarbazone is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2.5 g ai/ha or more, such as 2.75 g ai/ha or more, 3 g ai/ha or more, 3.25 g ai/ha or more, 3.5 g ai/ha or more, 3.75 g ai/ha or more, 4 g ai/ha or more, 4.25 g ai/ha or more, 4.5 g ai/ha or more, 4.75 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12 g ai/ha or more, 14 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 31 g ai/ha or more, 32 g ai/ha or more, 33 g ai/ha or more, 34 g ai/ha or more, 35 g ai/ha or more, 36 g ai/ha or more, 37 g ai/ha or more, 38 g ai/ha or more, 39 g ai/ha or more, 40 g ai/ha or more, 41 g ai/ha or more, 42 g ai/ha or more, 43 g ai/ha or more, or 44 g ai/ha or more; in an amount of 45 g ai/ha or less, such as 44 g ai/ha or less, 43 g ai/ha or less, 42 g ai/ha or less, 41 g ai/ha or less, 40 g ai/ha or less, 39 g ai/ha or less, 38 g ai/ha or less, 37 g ai/ha or less, 36 g ai/ha or less, 35 g ai/ha or less, 34 g ai/ha or less, 33 g ai/ha or less, 32 g ai/ha or less, 31 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 18 g ai/ha or less, 16 g ai/ha or less, 14 g ai/ha or less, 12 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4.75 g ai/ha or less, 4.5 g ai/ha or less, 4.25 g ai/ha or less, 4 g ai/ha or less, 3.75 g ai/ha or less, 3.5 g ai/ha or less, 3.25 g ai/ha or less, 3 g ai/ha or less, or 2.75 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2.5–45 g ai/ha, 2.5–41 g ai/ha, 2.75–39 g ai/ha, 2.75–37 g ai/ha, 3–40 g ai/ha, 3–33 g ai/ha, 3.25–28 g ai/ha, 3.5–45 g ai/ha, 3.75–45 g ai/ha, 4–39 g ai/ha, 4.5–31 g ai/ha, 5–45 g ai/ha, 5–37 g ai/ha, or 8–36 g ai/ha. SULFONYLUREA HERBICIDES In some aspects, the composition contains a herbicidally effective amount of compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and (b) amidosulfuron, azimsulfuron, bensulfuron, chlorimuron, chlorsulfuron, cinosulfuron, cyclosulfamuron, ethametsulfuron, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron, foramsulfuron, halosulfuron, imazosulfuron, iodosulfuron, iofensulfuron, mesosulfuron, metazosulfuron, metsulfuron, nicosulfuron, orthosulfamuron, oxasulfuron, primisulfuron, propyrisulfuron, prosulfuron, pyrazosulfuron, rimsulfuron, sulfometuron, sulfosulfuron, triasulfuron, tribenuron, thifensulfuron, trifloxysulfuron, triflusulfuron, tritosulfuron, or agriculturally acceptable salts or esters thereof, or combinations thereof. Amidosulfuron Compositions and methods of the present disclosure can include amidosulfuron or an agriculturally acceptable salt or ester thereof. Amidosulfuron, shown below, is a sulfonylurea that provides post-emergence control of a wide range of broadleaf weeds, e.g., cleavers, in winter wheat, durum wheat, barley, rye, triticale and oats. Amidosulfuron, as well as methods of preparing amidosulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Amidosulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, amidosulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 3.75 g ai/ha or more, such as 4 g ai/ha or more, 4.25 g ai/ha or more, 4.5 g ai/ha or more, 4.75 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 11 g ai/ha or more, 12 g ai/ha or more, 13 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 17 g ai/ha or more, 18 g ai/ha or more, 19 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 32 g ai/ha or more, 34 g ai/ha or more, 36 g ai/ha or more, 38 g ai/ha or more, 40 g ai/ha or more, 42 g ai/ha or more, 44 g ai/ha or more, 46 g ai/ha or more, 48 g ai/ha or more, 50 g ai/ha or more, 51 g ai/ha or more, 52 g ai/ha or more, 53 g ai/ha or more, 54 g ai/ha or more, 55 g ai/ha or more, 56 g ai/ha or more, 57 g ai/ha or more, 58 g ai/ha or more, or 59 g ai/ha or more; in an amount of 60 g ai/ha or less, such as 59 g ai/ha or less, 58 g ai/ha or less, 57 g ai/ha or less, 56 g ai/ha or less, 55 g ai/ha or less, 54 g ai/ha or less, 53 g ai/ha or less, 52 g ai/ha or less, 51 g ai/ha or less, 50 g ai/ha or less, 48 g ai/ha or less, 46 g ai/ha or less, 44 g ai/ha or less, 42 g ai/ha or less, 40 g ai/ha or less, 38 g ai/ha or less, 36 g ai/ha or less, 34 g ai/ha or less, 32 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18 g ai/ha or less, 17 g ai/ha or less, 16 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, 11 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4.75 g ai/ha or less, 4.5 g ai/ha or less, or 4.25 g ai/ha or less, or 4 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 3.75–60 g ai/ha, 4–58 g ai/ha, 4.5–51 g ai/ha, 5–57 g ai/ha, 5–30 g ai/ha, 6–42 g ai/ha, 8–50 g ai/ha, 9–32 g ai/ha, 10–53 g ai/ha, 12–30 g ai/ha, or 13–40 g ai/ha. Azimsulfuron Compositions and methods of the present disclosure can include azimsulfuron or an agriculturally acceptable salt or ester thereof. Azimsulfuron, shown below, is a sulfonylurea that provides e.g., post-emergence control of annual and perennial broadleaf and sedge weeds in rice. Azimsulfuron, as well as methods of preparing azimsulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Azimsulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, azimsulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 3.125 g ai/ha or more, such as 3.25 g ai/ha or more, 3.5 g ai/ha or more, 3.75 g ai/ha or more, 4 g ai/ha or more, 4.25 g ai/ha or more, 4.5 g ai/ha or more, 4.75 g ai/ha or more, 5 g ai/ha or more, 5.5 g ai/ha or more, 6 g ai/ha or more, 6.5 g ai/ha or more, 7 g ai/ha or more, 7.5 g ai/ha or more, 8 g ai/ha or more, 8.5 g ai/ha or more, 9 g ai/ha or more, 9.5 g ai/ha or more, 10 g ai/ha or more, 11 g ai/ha or more, 12 g ai/ha or more, 13 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 17 g ai/ha or more, 18 g ai/ha or more, 19 g ai/ha or more, 20 g ai/ha or more, 20.5 g ai/ha or more, 21 g ai/ha or more, 21.5 g ai/ha or more, 22 g ai/ha or more, 22.5 g ai/ha or more, 22.75 g ai/ha or more, 23 g ai/ha or more, 23.25 g ai/ha or more, 23.5 g ai/ha or more, 23.75 g ai/ha or more, 24 g ai/ha or more, 24.25 g ai/ha or more, 24.5 g ai/ha or more, or 24.75 g ai/ha or more; in an amount of 25 g ai/ha or less, such as 24.75 g ai/ha or less, 24.5 g ai/ha or less, 24.25 g ai/ha or less, 24 g ai/ha or less, 23.75 g ai/ha or less, 23.5 g ai/ha or less, 23.25 g ai/ha or less, 23 g ai/ha or less, 22.75 g ai/ha or less, 22.5 g ai/ha or less, 22 g ai/ha or less, 21.5 g ai/ha or less, 21 g ai/ha or less, 20.5 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18 g ai/ha or less, 17 g ai/ha or less, 16 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, 11 g ai/ha or less, 10 g ai/ha or less, 9.5 g ai/ha or less, 9 g ai/ha or less, 8.5 g ai/ha or less, 8 g ai/ha or less, 7.5 g ai/ha or less, 7 g ai/ha or less, 6.5 g ai/ha or less, 6 g ai/ha or less, 5.5 g ai/ha or less, 5 g ai/ha or less, 4.75 g ai/ha or less, 4.5 g ai/ha or less, 4.25 g ai/ha or less, 4 g ai/ha or less, 3.75 g ai/ha or less, 3.5 g ai/ha or less, or 3.25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 3.125–25 g ai/ha, 3.125–23.5 g ai/ha, 3.125–19 g ai/ha, 3.25–22 g ai/ha, 3.5–24.5 g ai/ha, 3.5–19 g ai/ha, 3.75–22 g ai/ha, 4–25 g ai/ha, 4–23.25 g ai/ha, 4.25–20 g ai/ha, 4.5–18 g ai/ha, 4.75–22.75 g ai/ha, or 5–24 g ai/ha. Bensulfuron Compositions and methods of the present disclosure can include bensulfuron or an agriculturally acceptable salt or ester thereof. Bensulfuron-methyl, shown below, is a sulfonylurea that provides e.g., pre- and post-emergence control of annual and perennial broadleaf weeds and sedges in rice. Bensulfuron, as well as methods of preparing bensulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Bensulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, bensulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 8.75 g ai/ha or more, such as 9 g ai/ha or more, 10 g ai/ha or more, 11 g ai/ha or more, 12 g ai/ha or more, 13 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 17 g ai/ha or more, 18 g ai/ha or more, 19 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 32 g ai/ha or more, 34 g ai/ha or more, 36 g ai/ha or more, 38 g ai/ha or more, 40 g ai/ha or more, 42 g ai/ha or more, 44 g ai/ha or more, 46 g ai/ha or more, 48 g ai/ha or more, 50 g ai/ha or more, 52 g ai/ha or more, 54 g ai/ha or more, 56 g ai/ha or more, 58 g ai/ha or more, 60 g ai/ha or more, 62 g ai/ha or more, 64 g ai/ha or more, 66 g ai/ha or more, 68 g ai/ha or more, or 69 g ai/ha or more; in an amount of 70 g ai/ha or less, such as 69 g ai/ha or less, 68 g ai/ha or less, 66 g ai/ha or less, 64 g ai/ha or less, 62 g ai/ha or less, 60 g ai/ha or less, 58 g ai/ha or less, 56 g ai/ha or less, 54 g ai/ha or less, 52 g ai/ha or less, 50 g ai/ha or less, 48 g ai/ha or less, 46 g ai/ha or less, 44 g ai/ha or less, 42 g ai/ha or less, 40 g ai/ha or less, 38 g ai/ha or less, 36 g ai/ha or less, 34 g ai/ha or less, 32 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18 g ai/ha or less, 17 g ai/ha or less, 16 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, 11 g ai/ha or less, 10 g ai/ha or less, or 9 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 8.75–70 g ai/ha, 9–60 g ai/ha, 10–65 g ai/ha, 10–40 g ai/ha, 10–28 g ai/ha, 11–68 g ai/ha, 11–54 g ai/ha, 12–60 g ai/ha, 12–42 g ai/ha, 13–69 g ai/ha, 14–56 g ai/ha, 15–40 g ai/ha, 20–46 g ai/ha, or 20–69 g ai/ha. Chlorsulfuron Compositions and methods of the present disclosure can include chlorsulfuron or an agriculturally acceptable salt or ester thereof. Chlorsulfuron, shown below, is a sulfonylurea that provides control of e.g., broadleaf weeds and annual grasses in wheat, barley, oats, rye, triticale, flax and on non-crop land. Chlorsulfuron, as well as methods of preparing chlorsulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Chlorsulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, chlorsulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1.1 g ai/ha or more, such as 1.25 g ai/ha or more, ., 1.5 g ai/ha or more, 1.75 g ai/ha or more, 2 g ai/ha or more, 2.25 g ai/ha or more, 2.5 g ai/ha or more, 2.75 g ai/ha or more, 3 g ai/ha or more, 3.25 g ai/ha or more, 3.5 g ai/ha or more, 3.75 g ai/ha or more, 4 g ai/ha or more, 4.25 g ai/ha or more, 4.5 g ai/ha or more, 4.75 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 11 g ai/ha or more, 12 g ai/ha or more, 13 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 17 g ai/ha or more, 18 g ai/ha or more, 19 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 32 g ai/ha or more, 34 g ai/ha or more, 36 g ai/ha or more, 38 g ai/ha or more, 40 g ai/ha or more, 42 g ai/ha or more, 44 g ai/ha or more, 46 g ai/ha or more, 47 g ai/ha or more, 48 g ai/ha or more, 49 g ai/ha or more, 50 g ai/ha or more, 51 g ai/ha or more, or 51.5 g ai/ha or more; in an amount of 52 g ai/ha or less, such as 51.5 g ai/ha or less, 51 g ai/ha or less, 50 g ai/ha or less, 49 g ai/ha or less, 48 g ai/ha or less, 47 g ai/ha or less, 46 g ai/ha or less, 44 g ai/ha or less, 42 g ai/ha or less, 40 g ai/ha or less, 38 g ai/ha or less, 36 g ai/ha or less, 34 g ai/ha or less, 32 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18 g ai/ha or less, 17 g ai/ha or less, 16 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, 11 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4.75 g ai/ha or less, 4.5 g ai/ha or less, or 4.25 g ai/ha or less, ai/ha or less, 4 g ai/ha or less, 3.75 g ai/ha or less, 3.5 g ai/ha or less, 3.25 g ai/ha or less, 3 g ai/ha or less, 2.75 g ai/ha or less, 2.5 g ai/ha or less, 2.25 g ai/ha or less, 2 g ai/ha or less, 1.75 g ai/ha or less, 1.5 g ai/ha or less, or 1.25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1.1–52 g ai/ha,1.25–51.5 g ai/ha, 1.5–30 g ai/ha, 1.75–47 g ai/ha, 2–26 g ai/ha, 3–50 g ai/ha, 4–38 g ai/ha, 4.5–42 g ai/ha, 5–51 g ai/ha, 7–49 g ai/ha, 9–32 g ai/ha, 10–45 g ai/ha, 12–52 g ai/ha, or 15–48 g ai/ha. Ethoxysulfuron Compositions and methods of the present disclosure can include ethoxysulfuron or an agriculturally acceptable salt or ester thereof. Ethoxysulfuron, shown below, is a sulfonylurea that provides e.g., control of broadleaf and sedge weeds in cereals, rice and sugar cane. Ethoxysulfuron, as well as methods of preparing ethoxysulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Ethoxysulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, ethoxysulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 5 g ai/ha or more, such as 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 11 g ai/ha or more, 12 g ai/ha or more, 13 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 17 g ai/ha or more, 18 g ai/ha or more, 19 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 32 g ai/ha or more, 34 g ai/ha or more, 36 g ai/ha or more, 38 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 101 g ai/ha or more, 102 g ai/ha or more, 103 g ai/ha or more, 104 g ai/ha or more, 105 g ai/ha or more, 106 g ai/ha or more, 107 g ai/ha or more, 108 g ai/ha or more, 109 g ai/ha or more, 110 g ai/ha or more, 111 g ai/ha or more, 112 g ai/ha or more, 113 g ai/ha or more, 114 g ai/ha or more, 115 g ai/ha or more, 116 g ai/ha or more, 117 g ai/ha or more, 118 g ai/ha or more, or 119 g ai/ha or more; in an amount of 120 g ai/ha or less, such as 119 g ai/ha or less, 118 g ai/ha or less, 117 g ai/ha or less, 116 g ai/ha or less, 115 g ai/ha or less, 114 g ai/ha or less, 113g ai/ha or less, 112 g ai/ha or less, 111 g ai/ha or less, 110 g ai/ha or less, 109 g ai/ha or less, 108 g ai/ha or less, 107 g ai/ha or less, 106 g ai/ha or less, 105 g ai/ha or less, 104 g ai/ha or less, 103 g ai/ha or less, 102 g ai/ha or less, 101 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 38 g ai/ha or less, 36 g ai/ha or less, 34 g ai/ha or less, 32 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18 g ai/ha or less, 17 g ai/ha or less, 16 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, 11 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, or 6 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 5–120 g ai/ha, 5–90 g ai/ha, 5–75 g ai/ha, 6–114 g ai/ha, 8–108 g ai/ha, 9–113 g ai/ha, 10–80 g ai/ha, 10–55 g ai/ha, 12–112 g ai/ha, 13–85 g ai/ha, 15–106 g ai/ha, 20–100 g ai/ha, 24–105 g ai/ha, or 28–115 g ai/ha. Flupyrsulfuron Compositions and methods of the present disclosure can include flupyrsulfuron or an agriculturally acceptable salt or ester thereof. Flupyrsulfuron-methyl sodium, shown below, is a sulfonylurea that is used, e.g., for post-emergent control of grass and broadleaf weeds in cereals. Flupyrsulfuron, as well as methods of preparing flupyrsulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Flupyrsulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, flupyrsulfuron thereof is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2.5 g ai/ha or more, such as 2.6 g ai/ha or more, 2.7 g ai/ha or more, 2.8 g ai/ha or more, 2.9 g ai/ha or more, 3.0 g ai/ha or more, 3.2 g ai/ha or more, 3.4 g ai/ha or more, 3.6 g ai/ha or more, 3.8 g ai/ha or more, 4 g ai/ha or more, 4.2 g ai/ha or more, 4.4 g ai/ha or more, 4.6 g ai/ha or more, 4.8 g ai/ha or more, 5 g ai/ha or more, 5.2 g ai/ha or more, 5.4 g ai/ha or more, 5.6 g ai/ha or more, 5.8 g ai/ha or more, 6 g ai/ha or more, 6.2 g ai/ha or more, 6.4 g ai/ha or more, 6.6 g ai/ha or more, 6.8 g ai/ha or more, 7 g ai/ha or more, 7.2 ai/ha or more, 7.4 g ai/ha or more, 7.6 g ai/ha or more, 8 g ai/ha or more, 8.2 g ai/ha or more, 8.4 ai/ha or more, 8.6 g ai/ha or more, 8.8 g ai/ha or more, 9 g ai/ha or more, 9.1 g ai/ha or more, 9.2 g ai/ha or more,9.3 g ai/ha or more, 9.4 g ai/ha or more, 9.5 g ai/ha or more, 9.6 g ai/ha or more, 9.7 g ai/ha or more, 9.8 g ai/ha or more, or 9.9 g ai/ha or more; in an amount of 10 g ai/ha or less, such as 9.9 g ai/ha or less, 9.8 g ai/ha or less, 9.7 g ai/ha or less, 9.6 g ai/ha or less, 9.5 g ai/ha or less, 9.4 g ai/ha or less, 9.3 g ai/ha or less, 9.2 g ai/ha or less, 9.1 g ai/ha or less, 9 g ai/ha or less, 8.8 g ai/ha or less, 8.6 g ai/ha or less, 8.4 g ai/ha or less, 8.2 g ai/ha or less, 8 g ai/ha or less, 7.8 g ai/ha or less, 7.6 g ai/ha or less, 7.4 g ai/ha or less, 7.2 g ai/ha or less, 7 g ai/ha or less, 6.8 g ai/ha or less, 6.6 g ai/ha or less, 6.4 g ai/ha or less, 6.2 g ai/ha or less, 6 g ai/ha or less, 5.8 g ai/ha or less, 5.6 g ai/ha or less, 5.4 g ai/ha or less, 5.2 g ai/ha or less, 5 g ai/ha or less, 4.8 g ai/ha or less, 4.6 g ai/ha or less, 4.4 g ai/ha or less, 4.2 g ai/ha or less, 4 g ai/ha or less, 3.8 g ai/ha or less, 3.6 g ai/ha or less, 3.4 g ai/ha or less, 3.2 g ai/ha or less, 3 g ai/ha or less, 2.9 g ai/ha or less, 2.8 g ai/ha or less, 2.7 g ai/ha or less, or 2.6 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2.5–10 g ai/ha, 2.5–9.4 g ai/ha, 2.6–9 g ai/ha, 2.7–10 g ai/ha, 2.8–9.4 g ai/ha, 3–8.8 g ai/ha, 3.2–7.2 g ai/ha, 3.4–8.6 g ai/ha, 3.6–10 g ai/ha, 3.8–9.5 g ai/ha, 4–8.8 g ai/ha, 4.4–7 g ai/ha, 4.6–6.8 g ai/ha, or 5–9.5 g ai/ha. Foramsulfuron Compositions and methods of the present disclosure can include foramsulfuron or an agriculturally acceptable salt or ester thereof. Foramsulfuron, shown below, is a sulfonylurea that provides e.g., post-emergence control of grass and broadleaf weeds in maize. Foramsulfuron, as well as methods of preparing foramsulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Foramsulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, foramsulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 22.5 g ai/ha or more, such as 23 g ai/ha or more, 24 g ai/ha or more, 25 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 32 g ai/ha or more, 34 g ai/ha or more, 35 g ai/ha or more, 36 g ai/ha or more, 38 g ai/ha or more, 40 g ai/ha or more, 42 g ai/ha or more, 44 g ai/ha or more, 46 g ai/ha or more, 48 g ai/ha or more, 50 g ai/ha or more, 51 g ai/ha or more, 52 g ai/ha or more, 53 g ai/ha or more, 54 g ai/ha or more, 55 g ai/ha or more, 56 g ai/ha or more, 57 g ai/ha or more, or 58 g ai/ha or more; in an amount of 59 g ai/ha or less, such as 58 g ai/ha or less, 57 g ai/ha or less, 56 g ai/ha or less, 55 g ai/ha or less, 54 g ai/ha or less, 53 g ai/ha or less, 52 g ai/ha or less, 51 g ai/ha or less, 50 g ai/ha or less, 48 g ai/ha or less, 46 g ai/ha or less, 44 g ai/ha or less, 42 g ai/ha or less, 40 g ai/ha or less, 38 g ai/ha or less, 36 g ai/ha or less, 35 g ai/ha or less 34 g ai/ha or less, 32 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 25 g ai/ha or less, 24 g ai/ha or less, or 23 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 22.5–59 g ai/ha, 23–51 g ai/ha, 25–38 g ai/ha, 26–57 g ai/ha, 28–48 g ai/ha, 30–58 g ai/ha, 30–50 g ai/ha, 32–55 g ai/ha, 34–57 g ai/ha, or 35–58 g ai/ha.
Halosulfuron Compositions and methods of the present disclosure can include halosulfuron or an agriculturally acceptable salt or ester thereof. Halosulfuron-methyl, shown below, is a sulfonylurea that has demonstrated activity for the control of annual broadleaf weeds and nutsedge species, in maize, sugar cane, rice, sorghum, nuts, and turf. Halosulfuron, as well as methods of preparing halosulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Halosulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, halosulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 4.375 g ai/ha or more, such as 4.75 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 105 g ai/ha or more, 110 g ai/ha or more, 115 g ai/ha or more, 120 g ai/ha or more, 122 g ai/ha or more, 124 g ai/ha or more, 126 g ai/ha or more, 128 g ai/ha or more, 130 g ai/ha or more, 131 g ai/ha or more, 132 g ai/ha or more, 133 g ai/ha or more, 134 g ai/ha or more, 135 g ai/ha or more, 136 g ai/ha or more, 137 g ai/ha or more, 138 g ai/ha or more, or 139 g ai/ha or more; in an amount of 139 g ai/ha or less, such as 138 g ai/ha or less, 137 g ai/ha or less, 136 g ai/ha or less, 135 g ai/ha or less, 134 g ai/ha or less, 133 g ai/ha or less, 132 g ai/ha or less, 131 g ai/ha or less, 130 g ai/ha or less, 129 g ai/ha or less, 128 g ai/ha or less, 126 g ai/ha or less, 124 g ai/ha or less, 122 g ai/ha or less, 120 g ai/ha or less, 115 g ai/ha or less, 110 g ai/ha or less, 105 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4.75 g ai/ha or less, or 4.5 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 4.375–140 g ai/ha, 4.5–120 g ai/ha, 4.75–100 g ai/ha, 5–95 g ai/ha, 5–131 g ai/ha, 6–80 g ai/ha, 7–130 g ai/ha, 8–122 g ai/ha, 9–75 g ai/ha, 10– 139 g ai/ha, 15–90 g ai/ha, 20–124 g ai/ha, 25–110 g ai/ha, or 25–75 g ai/ha. Iodosulfuron Compositions and methods of the present disclosure can include iodosulfuron or an agriculturally acceptable salt or ester thereof. Iodosulfuron-methyl-sodium, shown below, is a sulfonylurea that provides, e.g., post-emergence control of grass and broadleaf weeds in winter, spring and durum wheat, triticale, rye and spring barley. Iodosulfuron, as well as methods of preparing iodosulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Iodosulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, iodosulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 0.1 g ai/ha or more, such as 0.2 g ai/ha or greater, 0.3 g ai/ha or greater, 0.4 g ai/ha or greater, 0.5 g ai/ha or greater, 0.6 g ai/ha or greater, 0.7 g ai/ha or greater, 0.8 g ai/ha or greater, 0.9 g ai/ha or greater, 1 g ai/ha or greater, 1.1 g ai/ha or greater, 1.2 g ai/ha or greater, 1.3 g ai/ha or greater, 1.4 g ai/ha or more, 1.5 g ai/ha or more, 1.6 g ai/ha or more, 1.7 g ai/ha or more, 1.8 g ai/ha or more, 1.9 g ai/ha or more, 2.0 g ai/ha or more, 2.1 g ai/ha or more, 2.2 g ai/ha or more, 2.3 g ai/ha or more, 2.3 g ai/ha or more, 2.4 g ai/ha or more, 2.5 g ai/ha or more, 2.6 g ai/ha or more, 2.7 g ai/ha or more, 2.8 g ai/ha or more, 2.9 g ai/ha or more, 3.0 g ai/ha or more, 3.2 g ai/ha or more, 3.4 g ai/ha or more, 3.6 g ai/ha or more, 3.8 g ai/ha or more, 4 g ai/ha or more, 4.2 g ai/ha or more, 4.4 g ai/ha or more, 4.6 g ai/ha or more, 4.8 g ai/ha or more, 5 g ai/ha or more, 5.2 g ai/ha or more, 5.4 g ai/ha or more, 5.6 g ai/ha or more, 5.8 g ai/ha or more, 6 g ai/ha or more, 6.2 g ai/ha or more, 6.4 g ai/ha or more, 6.6 g ai/ha or more, 6.8 g ai/ha or more, 7 g ai/ha or more, 7.2 ai/ha or more, 7.4 g ai/ha or more, 7.6 g ai/ha or more, 8 g ai/ha or more, 8.2 g ai/ha or more, 8.4 ai/ha or more, 8.6 g ai/ha or more, 8.8 g ai/ha or more, 9 g ai/ha or more, 9.1 g ai/ha or more, 9.2 g ai/ha or more, 9.3 g ai/ha or more, 9.4 g ai/ha or more, 9.5 g ai/ha or more, 9.6 g ai/ha or more, 9.7 g ai/ha or more, 9.8 g ai/ha or more, or 9.9 g ai/ha or more; in an amount of 10 g ai/ha or less, such as 9.9 g ai/ha or less, 9.8 g ai/ha or less, 9.7 g ai/ha or less, 9.6 g ai/ha or less, 9.5 g ai/ha or less, 9.4 g ai/ha or less, 9.3 g ai/ha or less, 9.2 g ai/ha or less, 9.1 g ai/ha or less, 9 g ai/ha or less, 8.8 g ai/ha or less, 8.6 g ai/ha or less, 8.4 g ai/ha or less, 8.2 g ai/ha or less, 8 g ai/ha or less, 7.8 g ai/ha or less, 7.6 g ai/ha or less, 7.4 g ai/ha or less, 7.2 g ai/ha or less, 7 g ai/ha or less, 6.8 g ai/ha or less, 6.6 g ai/ha or less, 6.4 g ai/ha or less, 6.2 g ai/ha or less, 6 g ai/ha or less, 5.8 g ai/ha or less, 5.6 g ai/ha or less, 5.4 g ai/ha or less, 5.2 g ai/ha or less, 5 g ai/ha or less, 4.8 g ai/ha or less, 4.6 g ai/ha or less, 4.4 g ai/ha or less, 4.2 g ai/ha or less, 4 g ai/ha or less, 3.8 g ai/ha or less, 3.6 g ai/ha or less, 3.4 g ai/ha or less, 3.2 g ai/ha or less, 3 g ai/ha or less, 2.9 g ai/ha or less, 2.8 g ai/ha or less, 2.7 g ai/ha or less, 2.6 g ai/ha or less, 2.5 g ai/ha or less, 2.4 g ai/ha or less, 2.3 g ai/ha or less, 2.2 g ai/ha or less, 2.1 g ai/ha or less, 2.0 g ai/ha or less, 1.9 g ai/ha or less, 1.8 g ai/ha or less, 1.7 g ai/ha or less, 1.6 g ai/ha or less, 1.5 g ai/ha or less, 1.4 g ai/ha or less, 1.3 g ai/ha or less, 1.2 g ai/ha or less, 1.1 g ai/ha or less, 1 g ai/ha or less, 0.9 g ai/ha or less, 0.8 g ai/ha or less, 0.7 g ai/ha or less, 0.6 g ai/ha or less, 0.5 g ai/ha or less, 0.4 g ai/ha or less, 0.3 g ai/ha or less, or 0.2 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 0.1–10 g ai/ha, 0.4– 8.8 g ai/ha, 1.1–6.2 g ai/ha, 1.7–7.5 g ai/ha, 1.8–9.2 g ai/ha, 1.9–9 g ai/ha, 2–6.8 g ai/ha, 2.2– 9.5 g ai/ha, 2.5–10 g ai/ha, 2.8–7.6 g ai/ha, 3–9.4 g ai/ha, 3.2–7.2 g ai/ha, 3.4–10 g ai/ha, or 3.6–8 g ai/ha. Mesosulfuron Compositions and methods of the present disclosure can include mesosulfuron or an agriculturally acceptable salt or ester thereof. Mesosulfuron-methyl, shown below, is a sulfonylurea that provides, e.g., early- to mid-post-emergence control of grass and some broadleaf weeds in winter, spring and durum wheat, triticale and rye. Mesosulfuron, as well as methods of preparing mesosulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Mesosulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, mesosulfuron thereof is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1.5 g ai/ha or more, such as 1.6 g ai/ha or more, 1.7 g ai/ha or more, 1.8 g ai/ha or more, 1.9 g ai/ha or more, 2 g ai/ha or more, 2.1 g ai/ha or more, 2.25 g ai/ha or more, 2.5 g ai/ha or more, 2.75 g ai/ha or more, 3 g ai/ha or more, 3.25 g ai/ha or more, 3.5 g ai/ha or more, 3.75 g ai/ha or more, 4 g ai/ha or more, 4.25 g ai/ha or more, 4.5 g ai/ha or more, 4.75 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12 g ai/ha or more, 14 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 31 g ai/ha or more, 32 g ai/ha or more, 33 g ai/ha or more, 34 g ai/ha or more, 35 g ai/ha or more, 36 g ai/ha or more, 37 g ai/ha or more, 38 g ai/ha or more, 39 g ai/ha or more, 40 g ai/ha or more, 41 g ai/ha or more, 42 g ai/ha or more, 43 g ai/ha or more, or 44 g ai/ha or more; in an amount of 45 g ai/ha or less, such as 44 g ai/ha or less, 43 g ai/ha or less, 42 g ai/ha or less, 41 g ai/ha or less, 40 g ai/ha or less, 39 g ai/ha or less, 38 g ai/ha or less, 37 g ai/ha or less, 36 g ai/ha or less, 35 g ai/ha or less, 34 g ai/ha or less, 33 g ai/ha or less, 32 g ai/ha or less, 31 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 18 g ai/ha or less, 16 g ai/ha or less, 14 g ai/ha or less, 12 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4.75 g ai/ha or less, 4.5 g ai/ha or less, 4.25 g ai/ha or less, 4 g ai/ha or less, 3.75 g ai/ha or less, 3.5 g ai/ha or less, 3.25 g ai/ha or less, 3 g ai/ha or less, 2.75 g ai/ha or less, 2.5 g ai/ha or less, 2.25 g ai/ha or less, 2.1 g ai/ha or less, 2 g ai/ha or less, 1.9 g ai/ha or less, 1.8 g ai/ha or less, 1.7 g ai/ha or less, 1.6 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1.5–45 g ai/ha, 1.6– 42 g ai/ha, 1.5–40 g ai/ha, 1.7–43 g ai/ha, 1.8–35 g ai/ha, 2–37 g ai/ha, 2.25–41 g ai/ha, 2.5–32 g ai/ha, 2.75–45 g ai/ha, 3–40 g ai/ha, 3–33 g ai/ha, 3–24 g ai/ha, 3.5–45 g ai/ha, or 4–39 g ai/ha. Metsulfuron Compositions and methods of the present disclosure can include metsulfuron or an agriculturally acceptable salt or ester thereof. Metsulfuron-methyl, shown below, is a sulfonylurea that controls, e.g., grass and broadleaf weeds in wheat, barley, rice, oats and triticale. Metsulfuron, as well as methods of preparing metsulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Metsulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, metsulfuron thereof is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 1.1 g ai/ha or more,1.2 g ai/ha or more, 1.25 g ai/ha or more, 1.3 g ai/ha or more,1.4 g ai/ha or more, 1.5 g ai/ha or more, 1.6 g ai/ha or more, 1.7 g ai/ha or more, 1.8 g ai/ha or more, 1.9 g ai/ha or more, 2 g ai/ha or more, 2.1 g ai/ha or more, 2.2 g ai/ha or more, 2.3 g ai/ha or more, 2.3 g ai/ha or more, 2.4 g ai/ha or more, 2.5 g ai/ha or more, 2.6 g ai/ha or more, 2.7 g ai/ha or more, 2.8 g ai/ha or more, 2.9 g ai/ha or more, 3 g ai/ha or more, 3.2 g ai/ha or more, 3.4 g ai/ha or more, 3.6 g ai/ha or more, 3.8 g ai/ha or more, 4 g ai/ha or more, 4.2 g ai/ha or more, 4.4 g ai/ha or more, 4.6 g ai/ha or more, 4.8 g ai/ha or more, 5 g ai/ha or more, 5.2 g ai/ha or more, 5.4 g ai/ha or more, 5.6 g ai/ha or more, 5.8 g ai/ha or more, 6 g ai/ha or more, 6.2 g ai/ha or more, 6.4 g ai/ha or more, 6.6 g ai/ha or more, 6.8 g ai/ha or more, 7 g ai/ha or more, 7.2 ai/ha or more, 7.4 g ai/ha or more, 7.6 g ai/ha or more, 7.8 g ai/ha or more, 8 g ai/ha or more, 8.2 g ai/ha or more, 8.4 ai/ha or more, 8.6 g ai/ha or more, 8.8 g ai/ha or more, 9 g ai/ha or more, 9.2 g ai/ha or more, 9.4 g ai/ha or more, 9.6 g ai/ha or more, 9.8 g ai/ha or more, 10 g ai/ha or more, 10.2 g ai/ha or more, 10.4 g ai/ha or more, 10.6 g ai/ha or more, 10.8 g ai/ha or more, 11 g ai/ha or more, 11.1 g ai/ha or more, 11.2 g ai/ha or more, 11.3 g ai/ha or more, 11.4 g ai/ha or more, 11.5 g ai/ha or more, 11.6 g ai/ha or more, 11.7 g ai/ha or more, 11.8 g ai/ha or more, or 11.9 g ai/ha or more; in an amount of 12 g ai/ha or less, such as 11.9 g ai/ha or less, 11.8 g ai/ha or less, 11.7 g ai/ha or less, 11.6 g ai/ha or less, 11.5 g ai/ha or less, 11.4 g ai/ha or less, 11.3 g ai/ha or less, 11.2 g ai/ha or less, 11.1 g ai/ha or less, 11 g ai/ha or less, 10.8 g ai/ha or less, 10.6 g ai/ha or less, 10.4 g ai/ha or less, 10.2 g ai/ha or less, 10 g ai/ha or less, 9.8 g ai/ha or less, 9.6 g ai/ha or less, 9.4 g ai/ha or less, 9.2 g ai/ha or less, 9 g ai/ha or less, 8.8 g ai/ha or less, 8.6 g ai/ha or less, 8.4 g ai/ha or less, 8.2 g ai/ha or less, 8 g ai/ha or less, 7.8 g ai/ha or less, 7.6 g ai/ha or less, 7.4 g ai/ha or less, 7.2 g ai/ha or less, 7 g ai/ha or less, 6.8 g ai/ha or less, 6.6 g ai/ha or less, 6.4 g ai/ha or less, 6.2 g ai/ha or less, 6 g ai/ha or less, 5.8 g ai/ha or less, 5.6 g ai/ha or less, 5.4 g ai/ha or less, 5.2 g ai/ha or less, 5 g ai/ha or less, 4.8 g ai/ha or less, 4.6 g ai/ha or less, 4.4 g ai/ha or less, 4.2 g ai/ha or less, 4 g ai/ha or less, 3.8 g ai/ha or less, 3.6 g ai/ha or less, 3.4 g ai/ha or less, 3.2 g ai/ha or less, 3 g ai/ha or less, 2.9 g ai/ha or less, 2.8 g ai/ha or less, 2.7 g ai/ha or less, 2.6 g ai/ha or less, 2.5 g ai/ha or less, 2.4 g ai/ha or less, 2.3 g ai/ha or less, 2.2 g ai/ha or less, 2.1 g ai/ha or less, 2 g ai/ha or less, 1.9 g ai/ha or less, 1.8 g ai/ha, 1.7 g ai/ha or less, 1.6 g ai/ha or less, 1.5 g ai/ha or less, 1.4 g ai/ha or less, 1.3 g ai/ha or less, 1.25 g ai/ha or less, 1.2 g ai/ha or less, or 1.1 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–12 g ai/ha, 1–10 g ai/ha, 1.1–9.4 g ai/ha, 1.25–8.2 g ai/ha, 1.25–11 g ai/ha, 1.3–7 g ai/ha, 1.4–5.8 g ai/ha, 1.5–12 g ai/ha, 1.5–10.4 g ai/ha, 1.5–8.8 g ai/ha, 2–11.7 g ai/ha, 2.2–6.4 g ai/ha, 2.5–7.6 g ai/ha, 2.8–12 g ai/ha, or 3–8 g ai/ha. Nicosulfuron Compositions and methods of the present disclosure can include nicosulfuron or an agriculturally acceptable salt or ester thereof. Nicosulfuron, shown below, is a sulfonylurea that provides e.g., selective post-emergence control in maize of annual grass weeds, including Setaria, Echinochloa, Digitaria, Panicum, Lolium and Avena spp., broadleaf weeds, including Amaranthus spp. and Cruciferae, and perennials such as Sorghum halepense and Agropyron repens. Nicosulfuron, as well as methods of preparing nicosulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Nicosulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, nicosulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 8.75 g ai/ha or more, such as 9 g ai/ha or more, 10 g ai/ha or more, 11 g ai/ha or more, 12 g ai/ha or more, 13 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 17 g ai/ha or more, 18 g ai/ha or more, 19 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 32 g ai/ha or more, 34 g ai/ha or more, 36 g ai/ha or more, 38 g ai/ha or more, 40 g ai/ha or more, 42 g ai/ha or more, 44 g ai/ha or more, 46 g ai/ha or more, 48 g ai/ha or more, 50 g ai/ha or more, 52 g ai/ha or more, 54 g ai/ha or more, 56 g ai/ha or more, 58 g ai/ha or more, 60 g ai/ha or more, 62 g ai/ha or more, 64 g ai/ha or more, 66 g ai/ha or more, 68 g ai/ha or more, or 69 g ai/ha or more; in an amount of 70 g ai/ha or less, such as 69 g ai/ha or less, 68 g ai/ha or less, 66 g ai/ha or less, 64 g ai/ha or less, 62 g ai/ha or less, 60 g ai/ha or less, 58 g ai/ha or less, 56 g ai/ha or less, 54 g ai/ha or less, 52 g ai/ha or less, 50 g ai/ha or less, 48 g ai/ha or less, 46 g ai/ha or less, 44 g ai/ha or less, 42 g ai/ha or less, 40 g ai/ha or less, 38 g ai/ha or less, 36 g ai/ha or less, 34 g ai/ha or less, 32 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18 g ai/ha or less, 17 g ai/ha or less, 16 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, 11 g ai/ha or less, 10 g ai/ha or less, or 9 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 8.75–70 g ai/ha, 9–68 g ai/ha, 10–50 g ai/ha, 12–66 g ai/ha, 14–44 g ai/ha, 15–58 g ai/ha, 18–65 g ai/ha, 20–45 g ai/ha, 22–60 g ai/ha, 26–56 g ai/ha, or 30–70 g ai/ha. Orthosulfamuron Compositions and methods of the present disclosure can include orthosulfamuron or an agriculturally acceptable salt or ester thereof. Orthosulfamuron, shown below, is a sulfonylurea that provides e.g., early post-emergence control of annual and perennial broadleaf weeds and sedges in rice, cereals, pastures and sugar cane. Orthosulfamuron, as well as methods of preparing orthosulfamuron, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Orthosulfamuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, orthosulfamuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 7.5 g ai/ha or more, such as 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 11 g ai/ha or more, 12 g ai/ha or more, 13 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 17 g ai/ha or more, 18 g ai/ha or more, 19 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 32 g ai/ha or more, 34 g ai/ha or more, 36 g ai/ha or more, 38 g ai/ha or more, 40 g ai/ha or more, 42 g ai/ha or more, 44 g ai/ha or more, 46 g ai/ha or more, 48 g ai/ha or more, 50 g ai/ha or more, 52 g ai/ha or more, 54 g ai/ha or more, 56 g ai/ha or more, 58 g ai/ha or more, 60 g ai/ha or more, 62 g ai/ha or more, 64 g ai/ha or more, 66 g ai/ha or more, 68 g ai/ha or more, 70 g ai/ha or more, 71 g ai/ha or more, 72 g ai/ha or more, 73 g ai/ha or more, or 74 g ai/ha or more; in an amount of 75 g ai/ha or less, such as 74 g ai/ha or less, 72 g ai/ha or less, 70 g ai/ha or less, 68 g ai/ha or less, 66 g ai/ha or less, 64 g ai/ha or less, 62 g ai/ha or less, 60 g ai/ha or less, 58 g ai/ha or less, 56 g ai/ha or less, 54 g ai/ha or less, 52 g ai/ha or less, 50 g ai/ha or less, 48 g ai/ha or less, 46 g ai/ha or less, 44 g ai/ha or less, 42 g ai/ha or less, 40 g ai/ha or less, 38 g ai/ha or less, 36 g ai/ha or less, 34 g ai/ha or less, 32 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18 g ai/ha or less, 17 g ai/ha or less, 16 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, 11 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, or 8 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 7.5–75 g ai/ha, 7.5–60 g ai/ha, 8–58 g ai/ha, 9–42 g ai/ha, 10–70 g ai/ha, 10–56 g ai/ha, 11–40 g ai/ha, 13–64 g ai/ha, 15–75 g ai/ha, 17–46 g ai/ha, 20–65 g ai/ha, 20–52 g ai/ha, 22–48 g ai/ha, or 24–74 g ai/ha. Rimsulfuron Compositions and methods of the present disclosure can include rimsulfuron or an agriculturally acceptable salt or ester thereof. Rimsulfuron, shown below, is a sulfonylurea that provides post-emergence control of most annual and perennial grass weeds and several broad-leaved weeds in maize, tomatoes and potatoes, at 15 g/ha. Rimsulfuron, as well as methods of preparing rimsulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Rimsulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, rimsulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 5 g ai/ha or more, such as 5.5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 7.5 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12 g ai/ha or more, 14 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 27 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 32 g ai/ha or more, 34 g ai/ha or more, 36 g ai/ha or more, 38 g ai/ha or more, 40 g ai/ha or more, 42 g ai/ha or more, 44 g ai/ha or more, 46 g ai/ha or more, 48 g ai/ha or more, 50 g ai/ha or more, 52 g ai/ha or more, 54 g ai/ha or more, 56 g ai/ha or more, 58 g ai/ha or more, 60 g ai/ha or more, 62 g ai/ha or more, 64 g ai/ha or more, 66 g ai/ha or more, 68 g ai/ha or more, 69 g ai/ha or more, 70 g ai/ha or more, 71 g ai/ha or more, 72 g ai/ha or more, 73 g ai/ha or more, or 74 g ai/ha or more; in an amount of 75 g ai/ha or less, such as 74 g ai/ha or less, 73 g ai/ha or less, 72 g ai/ha or less, 71 g ai/ha or less, 70 g ai/ha or less, 69 g ai/ha or less, 68 g ai/ha or less, 66 g ai/ha or less, 64 g ai/ha or less, 62 g ai/ha or less, 60 g ai/ha or less, 58 g ai/ha or less, 56 g ai/ha or less, 54 g ai/ha or less, 52 g ai/ha or less, 50 g ai/ha or less, 48 g ai/ha or less, 46 g ai/ha or less, 44 g ai/ha or less, 42 g ai/ha or less, 40 g ai/ha or less, 38 g ai/ha or less, 36 g ai/ha or less, 34 g ai/ha or less, 32 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 27 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 18 g ai/ha or less, 16 g ai/ha or less, 14 g ai/ha or less, 12 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7.5 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5.5 g ai/ha or less, or 5 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 5–75 g ai/ha, 7.5–70 g ai/ha, 9–64 g ai/ha, 18–69 g ai/ha, 27–36 g ai/ha, 5.5–66 g ai/ha, 14–18 g ai/ha, 27- 69 g ai/ha, 7–38 g ai/ha, 12–52 g ai/ha, 9–44 g ai/ha, 10–38 g ai/ha, 16–75 g ai/ha, or 20–48 g ai/ha. Sulfosulfuron Compositions and methods of the present disclosure can include sulfosulfuron or an agriculturally acceptable salt or ester thereof. Sulfosulfuron, shown below, is a sulfonylurea that provides e.g., control of annual broadleaf weeds and grass weeds in cereals. Sulfosulfuron, as well as methods of preparing sulfosulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Sulfosulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, sulfosulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 4.375 g ai/ha or more, such as 4.75 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12 g ai/ha or more, 14 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 32 g ai/ha or more, 34 g ai/ha or more, 36 g ai/ha or more, 38 g ai/ha or more, 40 g ai/ha or more, 42 g ai/ha or more, 44 g ai/ha or more, 46 g ai/ha or more, 48 g ai/ha or more, 50 g ai/ha or more, 52 g ai/ha or more, 54 g ai/ha or more, 56 g ai/ha or more, 58 g ai/ha or more, 60 g ai/ha or more, 62 g ai/ha or more, 64 g ai/ha or more, 66 g ai/ha or more, 68 g ai/ha or more, 70 g ai/ha or more, 71 g ai/ha or more, 72 g ai/ha or more, 73 g ai/ha or more, or 74 g ai/ha or more; in an amount of 75 g ai/ha or less, such as 74 g ai/ha or less, 73 g ai/ha or less, 72 g ai/ha or less, 71 g ai/ha or less, 70 g ai/ha or less, 68 g ai/ha or less, 66 g ai/ha or less, 64 g ai/ha or less, 62 g ai/ha or less, 60 g ai/ha or less, 58 g ai/ha or less, 56 g ai/ha or less, 54 g ai/ha or less, 52 g ai/ha or less, 50 g ai/ha or less, 48 g ai/ha or less, 46 g ai/ha or less, 44 g ai/ha or less, 42 g ai/ha or less, 40 g ai/ha or less, 38 g ai/ha or less, 36 g ai/ha or less, 34 g ai/ha or less, 32 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 18 g ai/ha or less, 16 g ai/ha or less, 14 g ai/ha or less, 12 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, or 4.75 g ai/ha or less, or 4.5 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above such as 4.375–75 g ai/ha, 4.5–70 g ai/ha, 4.75–64 g ai/ha, 5–75 g ai/ha, 5–73 g ai/ha, 5–66 g ai/ha, 5–40 g ai/ha, 6–75 g ai/ha, 7–68 g ai/ha, 7–52 g ai/ha, 9–44 g ai/ha, 10– 50 g ai/ha, 16–75 g ai/ha, or 20–60 g ai/ha. Thifensulfuron Compositions and methods of the present disclosure can include thifensulfuron or an agriculturally acceptable salt or ester thereof. Thifensulfuron-methyl, shown below, is a sulfonylurea that provides e.g., control of annual weeds in cereals, maize and pasture. Thifensulfuron, as well as methods of preparing thifensulfuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Thifensulfuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, thifensulfuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 4.4 g ai/ha or more, such as 4.5 g ai/ha or more, 4.6 g ai/ha or more, 4.7 g ai/ha or more, 4.8 g ai/ha or more, 4.9 g ai/ha or more, 5 g ai/ha or more, 5.2 g ai/ha or more, 5.4 g ai/ha or more, 5.6 g ai/ha or more, 5.8 g ai/ha or more, 6 g ai/ha or more, 6.2 g ai/ha or more, 6.4 g ai/ha or more, 6.6 g ai/ha or more, 6.8 g ai/ha or more, 7 g ai/ha or more, 7.2 g ai/ha or more, 7.4 g ai/ha or more, 7.6 g ai/ha or more, 7.8 g ai/ha or more, 8 g ai/ha or more, 8.2 g ai/ha or more, 8.4 g ai/ha or more, 8.6 g ai/ha or more, 8.8 g ai/ha or more, 9 g ai/ha or more, 9.2 g ai/ha or more, 9.4 g ai/ha or more, 9.6 g ai/ha or more, 9.8 g ai/ha or more, 10 g ai/ha or more, 11 g ai/ha or more, 12 g ai/ha or more, 13 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 16.2 g ai/ha or more, 16.4 g ai/ha or more, 16.6 g ai/ha or more, 16.8 g ai/ha or more, 17 g ai/ha or more, 17.1 g ai/ha or more, 17.2 g ai/ha or more, 17.3 g ai/ha or more, or 17.4 g ai/ha or more; in an amount of 17.5 g ai/ha or less, such as 17.4 g ai/ha or less, 17.3 g ai/ha or less, 17.2 g ai/ha or less, 17.1 g ai/ha or less, 17 g ai/ha or less, 16.8 g ai/ha or less, 16.6 g ai/ha or less, 16.4 g ai/ha or less, 16.2 g ai/ha or less, 16 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, 11 g ai/ha or less, 10 g ai/ha or less, 9.8 g ai/ha or less, 9.6 g ai/ha or less, 9.4 g ai/ha or less, 9.2 g ai/ha or less, 9 g ai/ha or less, 8.8 g ai/ha or less, 8.6 g ai/ha or less, 8.4 g ai/ha or less, 8.2 g ai/ha or less, 8 g ai/ha or less, 7.8 g ai/ha or less, 7.6 g ai/ha or less, 7.4 g ai/ha or less, 7.2 g ai/ha or less, 7 g ai/ha or less, 6.8 g ai/ha or less, 6.6 g ai/ha or less, 6.4 g ai/ha or less, 6.2 g ai/ha or less, 6 g ai/ha or less, 5.8 g ai/ha or less, 5.6 g ai/ha or less, 5.4 g ai/ha or less, 5.2 g ai/ha or less, 5 g ai/ha or less, 4.9 g ai/ha or less, 4.8 g ai/ha or less, 4.7 g ai/ha or less, 4.6 g ai/ha or less, 4.5 g ai/ha or less, or 4.4 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 4.4–17.5 g ai/ha, 4.5– 16 g ai/ha, 4.8–11 g ai/ha, 5–17.3 g ai/ha, 5–16.2 g ai/ha, 5.4–13 g ai/ha, 5.8–10 g ai/ha, 6–12 g ai/ha, 6–16 g ai/ha, 7.4–16.4 g ai/ha, 7.8–15 g ai/ha, 8–15 g ai/ha, or 8–17.1 g ai/ha. Tribenuron Compositions and methods of the present disclosure can include tribenuron or an agriculturally acceptable salt or ester thereof. Tribenuron-methyl, shown below, is a sulfonylurea that provides e.g., post-emergence control of broadleaf weeds in cereal crops, including wheat, barley, oats, rye and triticale. Tribenuron, as well as methods of preparing tribenuron, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Tribenuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, tribenuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 3.75 g ai/ha or more, such as 4 g ai/ha or more, 4.25 g ai/ha or more, 4.5 g ai/ha or more, 4.75 g ai/ha or more, 5 g ai/ha or more, 5.25 g ai/ha or more, 5.5 g ai/ha or more, 5.75 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 7.5 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 11 g ai/ha or more, 12 g ai/ha or more, 13 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 17 g ai/ha or more, 18 g ai/ha or more, 19 g ai/ha or more, 20 g ai/ha or more, 21 g ai/ha or more, 22 g ai/ha or more, 23 g ai/ha or more, 24 g ai/ha or more, 25 g ai/ha or more, 25.5 g ai/ha or more, 26 g ai/ha or more, 26.5 g ai/ha or more, 27 g ai/ha or more, 27.5 g ai/ha or more, 28 g ai/ha or more, 28.5 g ai/ha or more, 29 g ai/ha or more, 29.25 g ai/ha or more, 29.5 g ai/ha or more, or 29.75 g ai/ha or more; in an amount of 30 g ai/ha or less, such as 29.75 g ai/ha or less, 29.5 g ai/ha or less, 29.25 g ai/ha or less, 29 g ai/ha or less, 28.5 g ai/ha or less, 28 g ai/ha or less, 27.5 g ai/ha or less, 27 g ai/ha or less, 26.5 g ai/ha or less, 26 g ai/ha or less, 25 g ai/ha or less, 24 g ai/ha or less, 23 g ai/ha or less, 22 g ai/ha or less, 21 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18 g ai/ha or less, 17 g ai/ha or less, 16 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, 11 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7.5 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5.75 g ai/ha or less, 5.5 g ai/ha or less, 5.25 g ai/ha or less, 5 g ai/ha or less, 4.75 g ai/ha or less, 4.5 g ai/ha or less, 4.25 g ai/ha or less, or 4 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above such as 3.75–30 g ai/ha, 4–27.5 g ai/ha, 4.25–23 g ai/ha, 4.5–17 g ai/ha, 5–25 g ai/ha, 6–29.5 g ai/ha, 7–28 g ai/ha, 7.5–23 g ai/ha, 7.5– 20 g ai/ha, 9–30 g ai/ha, 10–19 g ai/ha, or 10–27.5 g ai/ha. SYNTHETIC AUXIN HERBICIDES In addition to the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), the compositions can include a synthetic auxin herbicide. Synthetic auxin herbicides mimic natural plant hormones and can inhibit cell division and growth. Synthetic auxin herbicides include phenoxy herbicides, benzoic acid herbicides, aryl picolinate herbicides, quinoline carboxylic acid herbicides, pyrimidine carboxylic acid herbicides, and benzothiazole herbicides, as well as agriculturally acceptable salts and esters thereof. In some aspects, the composition can include a synthetic auxin herbicide selected from the group consisting of 2,4-D; 2,4-DB; 2,3,6-TBA, aminocyclopyrachlor, aminopyralid, benazolin-ethyl, chloramben, clomeprop, clopyralid, dichlorprop, dichlorprop-P, dicamba, florpyrauxifen (such as florpyrauxifen-benzyl), fluchloraminopyr (e.g., fluchloraminopyr- tefuryl), fluroxypyr, fluroxypyr-MHE, halauxifen (such as halauxifen-methyl), indolauxipyr (such as indolauxipyr-cyanomethyl), mecoprop, mecoprop-P, MCPA, MCPA-thioethyl, MCPB, picloram, quinclorac, quinmerac, triclopyr, agriculturally acceptable salts and esters thereof, and combinations thereof. In some aspects, the synthetic auxin herbicide can comprise 2,4-D, MCPA, aminopyralid, clopyralid, dicamba, florpyrauxifen, fluroxypyr, halauxifen, quinclorac, agriculturally acceptable salts and esters thereof, and combinations thereof. The synthetic auxin herbicide or agriculturally acceptable salt or ester thereof can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, the synthetic auxin herbicide or agriculturally acceptable salt or ester thereof is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 gram acid equivalent per hectare (g ai) or more, such as 1.5 g ai or more, 2 g ai or more, 2.5 g ai or more, 3 g ai or more, 3.5 g ai or more, 4 g ai or more, 4.5 g ai or more, 5 g ai or more, 6 g ai or more, 7 g ai or more, 8 g ai or more, 9 g ai or more, 10 g ai or more, 15 g ai or more, 20 g ai or more, 25 g ai or more, 30 g ai or more, 35 g ai or more, 40 g ai or more, 45 g ai or more, 50 g ai or more, 55 g ai or more, 60 g ai or more, 65 g ai or more, 70 g ai or more, 75 g ai or more, 80 g ai or more, 85 g ai or more, 90 g ai or more, 95 g ai or more, 100 g ai or more, 110 g ai or more, 120 g ai or more, 130 g ai or more, 140 g ai or more, 150 g ai or more, 160 g ai or more, 170 g ai or more, 180 g ai or more, 190 g ai or more, 200 g ai or more, 220 g ai or more, 240 g ai or more, 250 g ai or more, 260 g ai or more, 280 g ai or more, 300 g ai or more, 320 g ai or more, 340 g ai or more, 350 g ai or more, 360 g ai or more, 380 g ai or more, 400 g ai or more, 450 g ai or more, 500 g ai or more, 550 g ai or more, 600 g ai or more, 650 g ai or more, 700 g ai or more, 750 g ai or more, 800 g ai or more, 850 g ai or more, 900 g ai or more, 950 g ai or more, 1000 g ai or more, 1050 g ai or more, 1100 g ai or more, 1150 g ai or more, 1200 g ai or more, 1250 g ai or more, 1300 g ai or more, 1350 g ai or more, 1400 g ai or more, 1450 g ai or more, 1500 g ai or more, 1600 g ai or more, 1700 g ai or more, 1800 g ai or more, 1900 g ai or more, 2000 g ai or more, 2050 g ai or more, 2100 g ai or more, 2150 g ai or more, 2200 g ai or more, 2240 g ai or more, 2250 g ai or more, 2300 g ai or more, 2350 g ai or more, 2400 g ai or more, 2450 g ai or more, 2500 g ai or more, 2600 g ai or more, 2700 g ai or more, 2750 g ai or more, 2800 g ai or more, 2900 g ai or more, 3000 g ai or more, 3050 g ai or more, 3100 g ai or more, 3150 g ai or more, 3200 g ai or more, 3250 g ai or more, 3300 g ai or more, 3350 g ai or more, 3400 g ai or more, 3450 g ai or more, 3500 g ai or more, 3600 g ai or more, 3700 g ai or more, 3750 g ai or more, 3800 g ai or more, 3900 g ai or more, or 3950 g ai or more; in an amount of 4000 g ai or less, such as 3950 g ai or less, 3900 g ai or less, 3800 g ai or less, 3750 g ai or less, 3700 g ai or less, 3600 g ai or less, 3500 g ai or less, 3450 g ai or less, 3400 g ai or less, 3350 g ai or less, 3300 g ai or less, 3250 g ai or less, 3200 g ai or less, 3150 g ai or less, 3100 g ai or less, 3050 g ai or less, 3000 g ai or less, 2900 g ai or less, 2800 g ai or less, 2750 g ai or less, 2700 g ai or less, 2600 g ai or less, 2500 g ai or less, 2450 g ai or less, 2400 g ai or less, 2350 g ai or less, 2300 g ai or less, 2250 g ai or less, 2240 g ai or less, 2200 g ai or less, 2150 g ai or less, 2100 g ai or less, 2050 g ai or less, 2000 g ai or less, 1900 g ai or less, 1800 g ai or less, 1750 g ai or less, 1700 g ai or less, 1600 g ai or less, 1500 g ai or less, 1450 g ai or less, 1400 g ai or less, 1350 g ai or less, 1300 g ai or less, 1250 g ai or less, 1240 g ai or less, 1200 g ai or less, 1150 g ai or less, 1100 g ai or less, 1050 g ai or less, 1000 g ai or less, 950 g ai or less, 900 g ai or less, 850 g ai or less, 800 g ai or less, 750 g ai or less, 700 g ai or less, 650 g ai or less, 600 g ai or less, 550 g ai or less, 500 g ai or less, 450 g ai or less, 400 g ai or less, 380 g ai or less, 360 g ai or less, 350 g ai or less, 340 g ai or less, 320 g ai or less, 300 g ai or less, 280 g ai or less, 260 g ai or less, 250 g ai or less, 240 g ai or less, 220 g ai or less, 200 g ai or less, 190 g ai or less, 180 g ai or less, 170 g ai or less, 160 g ai or less, 150 g ai or less, 140 g ai or less, 130 g ai or less, 120 g ai or less, 110 g ai or less, 100 g ai or less, 95 g ai or less, 90 g ai or less, 85 g ai or less, 80 g ai or less, 75 g ai or less, 70 g ai or less, 65 g ai or less, 60 g ai or less, 55 g ai or less, 50 g ai or less, 45 g ai or less, 40 g ai or less, 35 g ai or less, 30 g ai or less, 25 g ai or less, 20 g ai or less, 15 g ai or less, 10 g ai or less, 9 g ai or less, 8 g ai or less, 7 g ai or less, 6 g ai or less, 5 g ai or less, 4.5 g ai or less, 4 g ai or less, 3.5 g ai or less, 3 g ai or less, 2.5 g ai or less, 2 g ai or less, 1.5 g ai or less, or 1 g ai or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–4000 g ai, 1–2240 g ai, 1-150 g ai, 1.5–3150 g ai, 2–900 g ai, 2.5–3200 g ai, 3–1250 g ai, 5–260 g ai, 6– 750 g ai, 7–2100 g ai, 10–2240 g ai, 20–3600 g ai, 40–3950 g ai, 50–400 g ai, 70–1250 g ai, 100–1400 g ai, or 250–1700 g ai. PHENOXYCARBOXYLIC ACIDS In some aspects, the composition contains compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and (b) 2,4-D, 2,4- DB2, clomeprop, dichlorprop, mecoprop, MCPA, MCPB, or agriculturally acceptable salts or esters thereof. 2,4-D In some aspects, the synthetic auxin herbicide can comprise 2,4-D or an agriculturally acceptable salt or ester thereof. 2,4-D, shown below, is a phenoxycarboxylic acid herbicide that provides broad spectrum control of many annual, biannual and perennial broad-leaved weeds and aquatic broad-leaved weeds in cereals, maize, sorghum, grasslands, established turf, grass seed crops, orchards (pome fruit and stone fruit), cranberries, asparagus, sugar cane, rice, forestry, and on non-crop land (including areas adjacent to water). 2,4- D, as well as methods of preparing 2,4-D, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. In some aspects, 2,4-D can be provided as an agriculturally acceptable salt or ester of 2,4-D. Exemplary agriculturally acceptable salts and esters of 2,4-D include, but are not limited to, 2,4-D-ammonium 2,4-D-butotyl, 2,4-D-2-butoxypropyl, 2,4-D-3-butoxypropyl, 2,4-D-butyl, 2,4-D choline, 2,4-D-diethylammonium, 2,4-D-dimethylammonium (2,4-D DMA), 2,4-D-diolamine, 2,4-D-dodecylammonium, 2,4-D-ethyl, 2,4-D-2-ethylhexyl (2,4-D EHE), 2,4-D-heptylammonium, 2,4-D-isobutyl, 2,4-D-isoctyl, 2,4-D-isopropyl, 2,4-D- isopropylammonium, 2,4-D-lithium, 2,4-D-meptyl, 2,4-D-methyl, 2,4-D-octyl, 2,4-D-pentyl, 2,4-D-propyl, 2,4-D-sodium, 2,4-D-tefuryl, 2,4-D-tetradecylammonium, 2,4-D- triethylammonium, 2,4-D-tris(2-hydroxypropyl)ammonium, 2,4-D-trolamine, and clacyfos. In some aspects, the 2,4-D can be provided as 2,4-D-2-ethylhexyl (2,4-D EHE), shown below. In some aspects, 2,4-D can be provided as 2,4-D DMA, shown below. In some aspects, the 2,4-D can be provided as 2,4-D choline, shown below. In some aspects, the 2,4-D can be provided as 2,4-D triethanolamine (2,4-D- trolamine), shown below. Also included herein are analogs of 2,4-D, such as 2,4-D diamers, aminoxy, amides, and esters. Exemplary analogs of 2,4-D include the analogs disclosed in PCT/US2023/071586 filed on August 3, 2023, the disclosure of which is incorporated by reference in its entirety herein. Exemplary 2,4-D analogs include the following: TABLE 23: 2,4-D ANALOGS Exemplary uses of 2,4-D, such as 2,4-D-choline or 2,4-D trolamine may include, but are not limited to, controlling annual and perennial broadleaf weeds, including, but not limited to, glyphosate-resistant broadleaf weeds. 2,4-D-Choline can be used in crops that have been made tolerant to 2,4-D, including, but not limited to, 2,4-D-tolerant soybeans, maize, and cotton. 2,4-D-Choline is generally, but is not required to be, applied post-emergent. 2,4-D- Choline can also be used for weed control in non-crop and perennial cropping systems. 2,4-D can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, 2,4-D is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 gram active ingredient per hectare (g ai/ha) or more, such as 2 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 125 g ai/ha or more, 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2240 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3750 g ai/ha or more, 3800 g ai/ha or more, 3850 g ai/ha or more, 3900 g ai/ha or more, or 3950 g ai/ha or more; in an amount of 4000 g ai/ha or less, such as 3950 g ai/ha or less, 3900 g ai/ha or less, 3850 g ai/ha or less, 3800 g ai/ha or less, 3750 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2240 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, 125 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, or 2 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–4000 g ai/ha, 1-150 g ai/ha, 2–3100 g ai/ha, 2–900 g ai/ha, 3–2600 g ai/ha, 3–1200 g ai/ha, 5–275 g ai/ha, 6–750 g ai/ha, 7–2100 g ai/ha, 10–2240 g ai/ha, 20–3300 g ai/ha, 40–3950 g ai/ha, 50–400 g ai/ha, 70–2400 g ai/ha, 100–950 g ai/ha, or 250–1700 g ai/ha. 2,4-DB In some aspects, the synthetic auxin herbicide can comprise 2,4-DB is a phenoxycarboxylic acid herbicide that provides post-emergence control of many annual and perennial broadleaf weeds in alfalfa, clovers, cereals, grassland, forage, legumes, soybeans, and peanuts. 2,4-DB, as well as methods of making 2,4-DB, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. In some aspects, 2,4-DB can be provided as an agriculturally acceptable salt or ester of 2,4-DB. Exemplary agriculturally acceptable salts and esters of 2,4-DB include, but are not limited to, 2,4-DB-butyl, 2,4-DB-dimethylammonium (2,4-DB DMA), 2,4-DB-isoctyl, 2,4- DB-potassium, and 2,4-DB-sodium. 2,4-DB can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, 2,4-DB is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 2 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 125 g ai/ha or more, 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2240 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3750 g ai/ha or more, 3800 g ai/ha or more, 3850 g ai/ha or more, 3900 g ai/ha or more, or 3950 g ai/ha or more; in an amount of 4000 g ai/ha or less, such as 3950 g ai/ha or less, 3900 g ai/ha or less, 3850 g ai/ha or less, 3800 g ai/ha or less, 3750 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2240 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, 125 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, or 2 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–4000 g ai/ha, 1-150 g ai/ha, 2–3100 g ai/ha, 2–900 g ai/ha, 3–2600 g ai/ha, 3–1200 g ai/ha, 5–275 g ai/ha, 6–750 g ai/ha, 7–2100 g ai/ha, 10–2240 g ai/ha, 20–3300 g ai/ha, 40–3950 g ai/ha, 50–400 g ai/ha, 70–2400 g ai/ha, 100–950 g ai/ha, or 250–1700 g ai/ha. Clomeprop In some aspects, the synthetic auxin herbicide can comprise clomeprop or an agriculturally acceptable salt or ester thereof. Clomeprop, shown below, is a phenoxycarboxylic acid herbicide that provides pre- to early post-emergence control of broad- leaf and sedge weeds in paddy rice. Clomeprop, as well as methods of preparing clomeprop, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Dichlorprop In some aspects, the synthetic auxin herbicide can comprise dichlorprop or an agriculturally acceptable salt or ester thereof. Dichlorprop, shown below, is a phenoxycarboxylic herbicide that provides broad-spectrum control of annual and perennial broad-leaved weeds in cereals and grasslands; brush control in non-crop land; control of broad- leaved aquatic weeds; and maintenance of embankments and roadside verges. Dichlorprop, as well as methods of making dichlorprop, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. In some aspects, dichlorprop can be provided as an agriculturally acceptable salt or ester of dichlorprop. Exemplary agriculturally acceptable salts and esters of dichlorprop include, but are not limited to, dichlorprop-butotyl, dichlorprop-dimethylammonium, dichlorprop-ethylammonium, dichlorprop-2-ethylhexyl, dichlorprop-isoctyl, dichlorprop- methyl, dichlorprop-potassium, dichlorprop-sodium, dichlorprop-P, dichlorprop-P- dimethylammonium, dichlorprop-P-2-ethylhexyl, dichlorprop-P-potassium, and dichlorprop- P-sodium. In some aspects, the dichlorprop can be provided as the stereoisomer dichlorprop- P, shown below. Dichlorprop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, dichlorprop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 2 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 125 g ai/ha or more, 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2240 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3750 g ai/ha or more, 3800 g ai/ha or more, 3850 g ai/ha or more, 3900 g ai/ha or more, or 3950 g ai/ha or more; in an amount of 4000 g ai/ha or less, such as 3950 g ai/ha or less, 3900 g ai/ha or less, 3850 g ai/ha or less, 3800 g ai/ha or less, 3750 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2240 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, 125 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, or 2 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–4000 g ai/ha, 1-150 g ai/ha, 2–3100 g ai/ha, 2–900 g ai/ha, 3–2600 g ai/ha, 3–1200 g ai/ha, 5–275 g ai/ha, 6–750 g ai/ha, 7–2100 g ai/ha, 10–2240 g ai/ha, 20–3300 g ai/ha, 40–3950 g ai/ha, 50–400 g ai/ha, 70–2400 g ai/ha, 100–950 g ai/ha, or 250– 1700 g ai/ha. Mecoprop In some aspects, the synthetic auxin herbicide can comprise mecoprop or an agriculturally acceptable salt or ester thereof. Mecoprop, shown below, is a phenoxy carboxylic acid herbicide that provides broad-spectrum control of broad-leaved weeds in wheat, barley, oats, herbage seed crops, grassland, and under fruit trees and vines. Mecoprop also provides control of docks (Rumex spp.) in meadows and pastures. Mecoprop, as well as methods of making mecoprop, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. In some aspects, mecoprop can be provided as an agriculturally acceptable salt or ester of mecoprop. Exemplary agriculturally acceptable salts and esters of mecoprop include, but are not limited to, mecoprop-butotyl, mecoprop-potassium, mecoprop-sodium, mecoprop- dimethylammonium, mecoprop-diolamine, mecoprop-ethadyl, mecoprop-2-ethylhexyl, mecoprop-isoctyl, mecoprop-methyl, mecoprop-trolamine, mecoprop-P, mecoprop-P-butotyl, mecoprop-P-dimethylammonium, mecoprop-P-ethylhexyl, and mecoprop-P-potassium. In some aspects, the mecoprop can be provided as the stereoisomer mecoprop-P, shown below. Mecoprop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, mecoprop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 2 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 125 g ai/ha or more, 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2240 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3750 g ai/ha or more, 3800 g ai/ha or more, 3850 g ai/ha or more, 3900 g ai/ha or more, or 3950 g ai/ha or more; in an amount of 4000 g ai/ha or less, such as 3950 g ai/ha or less, 3900 g ai/ha or less, 3850 g ai/ha or less, 3800 g ai/ha or less, 3750 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2240 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, 125 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, or 2 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–4000 g ai/ha, 1-150 g ai/ha, 2–3100 g ai/ha, 2–900 g ai/ha, 3–2600 g ai/ha, 3–1200 g ai/ha, 5–275 g ai/ha, 6–750 g ai/ha, 7–2100 g ai/ha, 10–2240 g ai/ha, 20–3300 g ai/ha, 40–3950 g ai/ha, 50–400 g ai/ha, 70–2400 g ai/ha, 100–950 g ai/ha, or 250– 1700 g ai/ha. MCPA In some aspects, the synthetic auxin herbicide can comprise MCPA or an agriculturally acceptable salt or ester thereof. MCPA, shown below, is a phenoxycarboxylic acid herbicide that provides broad-spectrum control of many annual, biannual, and perennial broad-leaved weeds, woody weeds, and aquatic broad-leaved weeds in cereals, herbage seed crops, flax, rice, vines, peas, potatoes, asparagus, grassland, turf, under fruit trees, forestry, and on roadside verges and embankments. MCPA, as well as methods of preparing MCPA, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. In some aspects, MCPA can be provided as an agriculturally acceptable salt or ester of MCPA. Exemplary agriculturally acceptable salts of MCPA include, but are not limited to, MCPA-butotyl, MCPA-butyl, MCPA-dimethylammonium (MCPA-DMA), MCPA- diolamine, MCPA-ethyl, MCPA-2-ethylhexyl (MCPA EHE), MCPA-isobutyl, MCPA-isoctyl, MCPA-isopropyl, MCPA-methyl, MCPA-olamine, MCPA-potassium, MCPA-sodium, MCPA-trolamine. In some aspects, the MCPA can be provided as MCPA-2-ethylhexyl (MCPA EHE), shown below. In some aspects, the MCPA can be provided as MCPA-dimethylammonium (MCPA-DMA), shown below. MCPA can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, MCPA is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more such as 2 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 125 g ai/ha or more, 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2240 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3750 g ai/ha or more, 3800 g ai/ha or more, 3850 g ai/ha or more, 3900 g ai/ha or more, or 3950 g ai/ha or more; in an amount of 4000 g ai/ha or less, such as 3950 g ai/ha or less, 3900 g ai/ha or less, 3850 g ai/ha or less, 3800 g ai/ha or less, 3750 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2240 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, 125 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, or 2 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–4000 g ai/ha, 1-150 g ai/ha, 2–3100 g ai/ha, 2–900 g ai/ha, 3–2600 g ai/ha, 3–1200 g ai/ha, 5–275 g ai/ha, 6–750 g ai/ha, 7–2100 g ai/ha, 10–2240 g ai/ha, 20–3300 g ai/ha, 40–3950 g ai/ha, 50–400 g ai/ha, 70–2400 g ai/ha, 100–950 g ai/ha, or 250–1700 g ai/ha. MCPB In some aspects, the synthetic auxin herbicide can comprise MCPB or an agriculturally acceptable salt or ester thereof. MCPB, shown below, is a phenoxycarboxylic acid herbicide that provides broad-spectrum control of many broad-leaved weeds, woody weeds, and aquatic broad-leaved weeds in rice, cereals, clovers, sainfoin, peas, peanuts, grassland, turf, and forestry. MCPB, as well as methods of preparing MCPB, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. In some aspects, MCPB can be provided as an agriculturally acceptable salt or ester of MCPB. Exemplary agriculturally acceptable salts of MCPB include, but are not limited to, MCPB-ethyl, MCPB-potassium, and MCPB-sodium. MCPB can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, MCPB is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 2 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 125 g ai/ha or more, 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2240 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3750 g ai/ha or more, 3800 g ai/ha or more, 3850 g ai/ha or more, 3900 g ai/ha or more, or 3950 g ai/ha or more; in an amount of 4000 g ai/ha or less, such as 3950 g ai/ha or less, 3900 g ai/ha or less, 3850 g ai/ha or less, 3800 g ai/ha or less, 3750 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2240 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, 125 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, or 2 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–4000 g ai/ha, 1-150 g ai/ha, 2–3100 g ai/ha, 2–900 g ai/ha, 3–2600 g ai/ha, 3–1200 g ai/ha, 5–275 g ai/ha, 6–750 g ai/ha, 7–2100 g ai/ha, 10–2240 g ai/ha, 20–3300 g ai/ha, 40–3950 g ai/ha, 50–400 g ai/ha, 70–2400 g ai/ha, 100–950 g ai/ha, or 250–1700 g ai/ha. BENZOIC ACIDS In some aspects, the composition contains compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and (b) chloramben, dicamba, TBA, or agriculturally acceptable salts or esters thereof. Chloramben In some aspects, the synthetic auxin herbicide can comprise chloramben or an agriculturally acceptable salt or ester thereof. Chloramben, shown below, is a benzoic acid herbicide that provides pre-planting and pre-emergence control of grasses and broad-leaved weeds in asparagus, navy beans, peanuts, maize, sweet potatoes, pumpkins, soybeans, squash, sunflowers, and certain ornamentals. Chloramben, as well as methods of preparing chloramben, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Dicamba In some aspects, the synthetic auxin herbicide can comprise dicamba or an agriculturally acceptable salt or ester thereof. Dicamba, shown below, is a benzoic acid herbicide that provides broad-spectrum control of annual and perennial broad-leaved weeds and brush species in cereals, maize, sorghum, sugar cane, asparagus, perennial seed grasses, turf, pastures, rangeland, and non-crop land. Dicamba, as well as methods of making dicamba, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. In some aspects, dicamba can be provided as an agriculturally acceptable salt or ester of dicamba. Exemplary agriculturally acceptable salts and esters of dicamba include, but are not limited to, dicamba-diglycolammonium, dicamba-dimethylammonium, dicamba- diolamine, dicamba-isopropylammonium, dicamba-methyl, dicamba-olamine, dicamba- potassium, dicamba-sodium, dicamba-trolamine, and cambendichlor. In some aspects, dicamba can be provided as dicamba-diglycolammonium, shown below. Dicamba can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, dicamba is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 560 g ai/ha or more, 570 g ai/ha or more, 575 g ai/ha or more, 580 g ai/ha or more, 590 g ai/ha or more, or 600 g ai/ha or more; in an amount of 600 g ai/ha or less such as 590 g ai/ha or less, 580 g ai/ha or less, 575 g ai/ha or less, 570 g ai/ha or less, 560 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, or 55 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–600 g ai/ha, 55-150 g ai/ha, 60–310 g ai/ha, 65–190 g ai/ha, 80–560 g ai/ha, 85–300 g ai/ha, 100–275 g ai/ha, 120–475 g ai/ha, 140–390 g ai/ha, 150–250 g ai/ha, or 250–400 g ai/ha. 2,3,6-TBA In some aspects, the synthetic auxin herbicide can comprise 2,3,6-TBA or an agriculturally acceptable salt or ester thereof. 2,3,6-TBA, shown below, is a benzoic acid herbicide that provides post-emergence control of certain broad-leaved annual and perennial weeds in cereals and grass seed crops. 2,3,6-TBA, as well as methods of preparing 2,3,6-TBA, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. C. ARYL PICOLINATES In some aspects, the composition contains compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and (b) florpyrauxifen, halauxifen, or agriculturally acceptable salts or esters thereof. Florpyrauxifen In some aspects, the synthetic auxin herbicide can comprise florpyrauxifen or an agriculturally acceptable salt or ester thereof. Florpyrauxifen is aryl picolinic acid that has been described in U.S. Patent 7,314,849 B2. Exemplary uses of florpyrauxifen include controlling undesirable vegetation, including grass, broadleaf and sedge weeds, in multiple non-crop and cropping situations. In some aspects, florpyrauxifen can be provided as an agriculturally acceptable salt or ester of florpyrauxifen. Exemplary agriculturally acceptable salts and esters of florpyrauxifen include, but are not limited to, florpyrauxifen-benzyl, shown below. . Florpyrauxifen can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, florpyrauxifen is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 2 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 142.5 g ai/ha or more, 145 g ai/ha or more, 147.5 g ai/ha or more, or 149 g ai/ha or more; in an amount of 150 g ai/ha or less, such as 149 g ai/ha or less, 147.5 g ai/ha or less, 145 g ai/ha or less, 142.5 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, 12.5 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, or 2 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–150 g ai/ha, 2–130 g ai/ha, 2–45 g ai/ha, 3–70 g ai/ha, 4-147.5 g ai/ha, 5–100 g ai/ha, 6–75 g ai/ha, 7–50 g ai/ha, 10–149 g ai/ha, 20–120 g ai/ha, 25–90 g ai/ha, 30–60 g ai/ha, 50–150 g ai/ha, 60–130 g ai/ha, or 100–145 g ai/ha. Halauxifen In some aspects, the synthetic auxin herbicide can comprise halauxifen or an agriculturally acceptable salt or ester thereof. Halauxifen, shown below, is a aryl picolinic acid herbicide that provides broad-spectrum control of broad-leaved weeds in cereal crops. In some aspects, halauxifen can be provided as an agriculturally acceptable salt or ester of halauxifen. Exemplary agriculturally acceptable salts and esters of halauxifen include, but are not limited to, halauxifen-methyl. In some aspects, the halauxifen is provided as halauxifen-methyl, shown below. Halauxifen can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, halauxifen is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 2 g ai/ha or more, 2.5 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 142.5 g ai/ha or more, 145 g ai/ha or more, 147.5 g ai/ha or more, or 149 g ai/ha or more; in an amount of 150 g ai/ha or less, such as 149 g ai/ha or less, 147.5 g ai/ha or less, 145 g ai/ha or less, 142.5 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, 12.5 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, 2.5 g ai/ha or less, or 2 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–150 g ai/ha, 2–130 g ai/ha, 2.5–45 g ai/ha, 3–70 g ai/ha, 4-147.5 g ai/ha, 5–100 g ai/ha, 6–75 g ai/ha, 7–50 g ai/ha, 10–149 g ai/ha, 20–120 g ai/ha, 25–90 g ai/ha, 30–60 g ai/ha, 50–150 g ai/ha, 60–130 g ai/ha, or 100– 145 g ai/ha. PYRIDINE CARBOXYLATES In some aspects, the composition contains compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and (b) aminopyralid, clopyralid, fluroxypyr, picloram, triclopyr, or agriculturally acceptable salts or esters thereof. Aminopyralid In some aspects, the synthetic auxin herbicide can comprise aminopyralid or an agriculturally acceptable salt or ester thereof. Aminopyralid is a compounds according to that provides pre- and post-emergence control of certain annual and perennial broadleaf weeds in grasslands. Aminopyralid, as well as methods of making aminopyralid, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. In some aspects, aminopyralid can be provided as an agriculturally acceptable salt or ester of aminopyralid. Exemplary agriculturally acceptable salts and esters of aminopyralid include, but are not limited to, for example, aminopyralid-triisopropanolammonium (TIPA), shown below. Aminopyralid can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, aminopyralid is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 2 g ai/ha or more, 2.5 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 142.5 g ai/ha or more, 145 g ai/ha or more, 147.5 g ai/ha or more, or 149 g ai/ha or more; in an amount of 150 g ai/ha or less, such as 149 g ai/ha or less, 147.5 g ai/ha or less, 145 g ai/ha or less, 142.5 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, 12.5 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, 2.5 g ai/ha or less, or 2 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–150 g ai/ha, 2–130 g ai/ha, 2.5–45 g ai/ha, 3–70 g ai/ha, 4-147.5 g ai/ha, 5–100 g ai/ha, 6–75 g ai/ha, 7–50 g ai/ha, 10–149 g ai/ha, 20–120 g ai/ha, 25–90 g ai/ha, 30–60 g ai/ha, 50–150 g ai/ha, 60–130 g ai/ha, or 100– 145 g ai/ha. Clopyralid In some aspects, the synthetic auxin herbicide can comprise clopyralid or an agriculturally acceptable salt or ester thereof. Clopyralid, shown below, is a compound that provides post-emergence control of many annual and perennial broad-leaved weeds in sugar beet, fodder beet, oilseed rape, maize, cereals, brassicas, onions, leeks, strawberries, flax, grassland, and non-crop lands. Clopyralid, as well as methods of making clopyralid, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. In some aspects, clopyralid can be provided as an agriculturally acceptable salt or ester of clopyralid. Exemplary agriculturally acceptable salts and esters of clopyralid include, but are not limited to, clopyralid-methyl, clopyralid-potassium, clopyralid-tris(2- hydroxypropyl)ammonium, and clopyralid-olamine, shown below. Clopyralid can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, clopyralid is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 25 g ai/ha or more, such as 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, or 390 g ai/ha or more; in an amount of 400 g ai/ha or less, such as 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, or 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, or 30 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 25–400 g ai/ha, 55-150 g ai/ha, 60–310 g ai/ha, 65–190 g ai/ha, 80–260 g ai/ha, 85–300 g ai/ha, 100–275 g ai/ha, 120–330 g ai/ha, 140–390 g ai/ha, 150–250 g ai/ha, or 30–400 g ai/ha. Fluroxypyr In some aspects, the synthetic auxin herbicide can comprise fluroxypyr or an agriculturally acceptable salt or ester thereof. Fluroxypyr, shown below, is a compound that provides post-emergence control against certain broad-leaved weeds in small grain crops, pastures, grasslands, orchards, plantation crops, maize, and forestry. Fluroxypyr, as well as methods of making fluroxypyr, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. In some aspects, fluroxypyr can be provided as an agriculturally acceptable salt or ester of fluroxypyr. Exemplary agriculturally acceptable salts and esters of fluroxypyr include, but are not limited to, fluroxypyr-2-butoxy-1-methylethyl (fluroxypyr-butometyl) and fluroxypyr-meptyl (fluroxypyr-MHE). In some aspects, the fluroxypyr can be provided as fluroxypyr-meptyl (fluroxypyr-MHE), shown below. Fluroxypyr can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, fluroxypyr is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 35 g ai/ha or more, such as 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, or 390 g ai/ha or more; in an amount of 400 g ai/ha or less, such as 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, or 35 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 35–400 g ai/ha, 55-150 g ai/ha, 60–310 g ai/ha, 45–190 g ai/ha, 80–260 g ai/ha, 85– 300 g ai/ha, 100–275 g ai/ha, 120–330 g ai/ha, 140–390 g ai/ha, 150–250 g ai/ha, or 250–400 g ai/ha. Picloram In some aspects, the synthetic auxin herbicide can comprise picloram or an agriculturally acceptable salt or ester thereof. Picloram is a compounds that provides management of unwanted vegetation in rangeland, grass pastures, forestry, as well as non-crop land and right-of-way sites. Picloram, as well as methods of making picloram, is known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. In some aspects, picloram can be provided as an agriculturally acceptable salt or ester of picloram. Exemplary agriculturally acceptable salts and esters of picloram include, but are not limited to, picloram-dimethylammonium, picloram-isoctyl, picloram-potassium, picloram-triethylammonium, picloram-triisopropanolammonium (TIPA), picloram- triisopropylammonium, and picloram-trolamine (triethanolammonium). In some aspects, the picloram can be provided as picloram-potassium, shown below. In some aspects, the picloram can be provided as picloram-TIPA, shown below. Picloram can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, picloram is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 10 g ai/ha or more, such as 12 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 125 g ai/ha or more, 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, or 2220 g ai/ha or more; in an amount of 22400 g ai/ha or less, such as 2220 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, 125 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 18 g ai/ha or less, 16 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, or 12 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 10–2240 g ai/ha, 12- 1500 g ai/ha, 14–2100 g ai/ha, 15–900 g ai/ha, 18–1600 g ai/ha, 30–1200 g ai/ha, 50–275 g ai/ha, 70–1000 g ai/ha, 100–2220 g ai/ha, 250–1300 g ai/ha, 450–2000 g ai/ha, or 500–1900 g ai/ha. Triclopyr In some aspects, the synthetic auxin herbicide can comprise triclopyr or an agriculturally acceptable salt or ester thereof. Triclopyr is a compound that provides control of woody plants and broadleaf weed species in grassland, rangeland, industrial areas, coniferous forests, rice, and plantation crops. Triclopyr, as well as methods of making triclopyr, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. In some aspects, triclopyr can be provided as an agriculturally acceptable salt or ester of triclopyr. Exemplary agriculturally acceptable salts and esters of triclopyr include, but are not limited to, for example, triclopyr-triethylammonium (TEA), triclopyr choline, and triclopyr-butotyl (butoxyethyl or BEE). In some aspects, the triclopyr can be provided as triclopyr-triethylammonium (TEA), shown below. In some aspects, the triclopyr can be provided as triclopyr-choline, shown below. In some aspects, the triclopyr can be provided as triclopyr-BEE, shown below. Triclopyr can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, triclopyr is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 10 g ai/ha or more, such as 12 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 125 g ai/ha or more, 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, or 2220 g ai/ha or more; in an amount of 22400 g ai/ha or less, such as 2220 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, 125 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 18 g ai/ha or less, 16 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, or 12 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 10–2240 g ai/ha, 12- 1500 g ai/ha, 14–2100 g ai/ha, 15–900 g ai/ha, 18–1600 g ai/ha, 30–1200 g ai/ha, 50–275 g ai/ha, 70–1000 g ai/ha, 100–2220 g ai/ha, 250–1300 g ai/ha, 450–2000 g ai/ha, or 500–1900 g ai/ha. QUINOLINE CARBOXYLIC ACIDS In some aspects, the composition contains compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and (b) quinclorac, quinmerac, or agriculturally acceptable salts or esters thereof. Quinclorac In some aspects, the synthetic auxin herbicide can comprise quinclorac or an agriculturally acceptable salt or ester thereof. Quinclorac, shown below, is a quinoline carboxylic acid herbicide that provides pre- and post-emergence control of certain grass weeds and other weeds in direct-seeded and transplanted rice. Quinclorac, as well as methods of making quinclorac, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. In some aspects, quinclorac can be provided as an agriculturally acceptable salt or ester of quinclorac. Exemplary agriculturally acceptable salts and esters of quinclorac include, but are not limited to, quinclorac-dimethylammonium. Quinclorac can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, quinclorac is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 10 g ai/ha or more, such as 12 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 125 g ai/ha or more, 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, or 2220 g ai/ha or more; in an amount of 22400 g ai/ha or less, such as 2220 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, 125 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 18 g ai/ha or less, 16 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, or 12 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 10– 2240 g ai/ha, 12-1500 g ai/ha, 14–2100 g ai/ha, 15–900 g ai/ha, 18–1600 g ai/ha, 30–1200 g ai/ha, 50–275 g ai/ha, 70–1000 g ai/ha, 100–2220 g ai/ha, 250–1300 g ai/ha, 450–2000 g ai/ha, or 500–1900 g ai/ha. Quinmerac In some aspects, the synthetic auxin herbicide can comprise quinmerac or an agriculturally acceptable salt or ester thereof. Quinmerac, shown below, is a quinoline carboxylic acid herbicide that provides control of certain broad-leaved weeds in cereals, oilseed rape, and sugar beets. Quinmerac, as well as methods of making quinmerac, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Quinmerac can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, quinmerac is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 10 g ai/ha or more, such as 12 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 125 g ai/ha or more, 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, or 2220 g ai/ha or more; in an amount of 22400 g ai/ha or less, such as 2220 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, 125 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 18 g ai/ha or less, 16 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, or 12 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 10– 2240 g ai/ha, 12-1500 g ai/ha, 14–2100 g ai/ha, 15–900 g ai/ha, 18–1600 g ai/ha, 30–1200 g ai/ha, 50–275 g ai/ha, 70–1000 g ai/ha, 100–2220 g ai/ha, 250–1300 g ai/ha, 450–2000 g ai/ha, or 500–1900 g ai/ha. OTHER SYNTHETIC AUXIN HERBICIDES In some aspects, the composition contains compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and (b) aminocyclopyrachlor, benazolin, or agriculturally acceptable salts or esters thereof. Aminocyclopyrachlor In some aspects, the synthetic auxin herbicide can comprise aminocyclopyrachlor or an agriculturally acceptable salt or ester thereof. Aminocyclopyrachlor, shown below, is a pyrimidine carboxylic acid herbicide that provides control of certain broadleaf weeds and woody species, e.g., in rights-of-way, industrial sites, rangeland, permanent grass pastures and natural areas. Aminocyclopyrachlor, as well as methods of making aminocyclopyrachlor, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. In some aspects, aminocyclopyrachlor can be provided as an agriculturally acceptable salt or ester of aminocyclopyrachlor. Exemplary agriculturally acceptable salts and esters of aminocyclopyrachlor include, but are not limited to, aminocyclopyrachlor-potassium and aminocyclopyrachlor-methyl. Aminocyclopyrachlor can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, aminocyclopyrachlor is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 20 g ai/ha or more, such as 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, or 390 g ai/ha or more; in an amount of 400 g ai/ha or less, such as 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, or 25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 20–400 g ai/ha, 55-150 g ai/ha, 40–310 g ai/ha, 65– 190 g ai/ha, 80–260 g ai/ha, 85–300 g ai/ha, 100–275 g ai/ha, 120–330 g ai/ha, 140–390 g ai/ha, 150–250 g ai/ha, or 25–400 g ai/ha. Benazolin In some aspects, the synthetic auxin herbicide can comprise benazolin or an agriculturally acceptable salt or ester thereof. Benazolin, shown below, is a benzothiazole herbicide that provides post-emergence control of certain annual broad-leaved weeds in cereals, oilseed rape, grassland, clover, alfalfa, and flax. Benazolin, as well as methods of making benazolin, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. In some aspects, benazolin can be provided as an agriculturally acceptable salt or ester of benazolin. Exemplary agriculturally acceptable salts and esters of benazolin include, but are not limited to, benazolin-ethyl. AUXIN TRANSPORT INHIBITORS In addition, the pyridine carboxylic acid herbicide or agriculturally acceptable N- oxide, salt or ester thereof, the compositions can include an auxin transport inhibitor. Auxin transport inhibitors inhibit polar transport of naturally occurring auxin, indole acetic acid (IAA), and synthetic auxin-mimicking herbicides in sensitive plants. Examples of auxin transport inhibitors include phthalamate herbicides, semicarbazone herbicides and others. In some aspects, the composition can include an auxin transport inhibitor selected from the group consisting of: chlorflurenol; diflufenzopyr; naptalam; 2,3,5-triiodobenzoic acid (2,3,5-TIBA); agriculturally acceptable salts and esters thereof; and combinations thereof. Chlorflurenol In some aspects, the auxin transport inhibitor can comprise chlorflurenol or an agriculturally acceptable salt or ester thereof. Chlorflurenol, shown below, is a herbicide that is a growth retardant and weed suppressant in amenity grass, roadsides, railways, ditch banks, etc. Chlorflurenol, as well as methods of preparing chlorflurenol, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Chlorflurenol can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, chlorflurenol is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 100 g ai/ha or greater, such as 110 g ai/ha or greater, 120 g ai/ha or greater, 130 g ai/ha or greater, 140 g ai/ha or greater, 150 g ai/ha or greater, 160 g ai/ha or greater, 170 g ai/ha or greater, 180 g ai/ha or greater, 190 g ai/ha or greater, 200 g ai/ha or greater, 220 g ai/ha or greater, 240 g ai/ha or greater, 250 g ai/ha or greater, 260 g ai/ha or greater, 280 g ai/ha or greater, 300 g ai/ha or greater, 320 g ai/ha or greater, 340 g ai/ha or greater, 350 g ai/ha or greater, 360 g ai/ha or greater, 380 g ai/ha or greater, 400 g ai/ha or greater, 420 g ai/ha or greater, 440 g ai/ha or greater, 460 g ai/ha or greater, 480 g ai/ha or greater, 500 g ai/ha or greater, 525 g ai/ha or greater, 550 g ai/ha or greater, 575 g ai/ha or greater, 600 g ai/ha or greater, 625 g ai/ha or greater, 650 g ai/ha or greater, 675 g ai/ha or greater, 700 g ai/ha or greater, 725 g ai/ha or greater, 750 g ai/ha or greater, 775 g ai/ha or greater, 800 g ai/ha or greater, 825 g ai/ha or greater, 850 g ai/ha or greater, 875 g ai/ha or greater, 900 g ai/ha or greater, 925 g ai/ha or greater, 950 g ai/ha or greater, 975 g ai/ha or greater, 1000 g ai/ha or greater, 1100 g ai/ha or greater, 1200 g ai/ha or greater, 1300 g ai/ha or greater, 1400 g ai/ha or greater, 1500 g ai/ha or greater, 1600 g ai/ha or greater, 1700 g ai/ha or greater, 1800 g ai/ha or greater, 1900 g ai/ha or greater, 2000 g ai/ha or greater, 2200 g ai/ha or greater, 2400 g ai/ha or greater, 2600 g ai/ha or greater, 2800 g ai/ha or greater, 3000 g ai/ha or greater, 3200 g ai/ha or greater, 3400 g ai/ha or greater, 3600 g ai/ha or greater, 3800 g ai/ha or greater, 3850 g ai/ha or greater, 3900 g ai/ha or greater, or 3950 g ai/ha or greater; in an amount of 4000 g ai/ha or less, such as 3950 g ai/ha or less, 3900 g ai/ha or less, 3850 g ai/ha or less, 3800 g ai/ha or less, 3600 g ai/ha or less, 3400 g ai/ha or less, 3200 g ai/ha or less, 3000 g ai/ha or less, 2800 g ai/ha or less, 2600 g ai/ha or less, 2400 g ai/ha or less, 2200 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, or 110 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as from 100–4000 g ai/ha, from 130–750 g ai/ha, from 320–2000 g ai/ha, from 240–1500 g ai/ha, from 450–650 g ai/ha, from 120–600 g ai/ha, from 140-3300 g ai/ha, from 300–4500 g ai/ha, from 1400-3400 g ai/ha, from 750–2900 g ai/ha, or from 110–3950 g ai/ha. Diflufenzopyr In some aspects, the auxin transport inhibitor can comprise diflufenzopyr or an agriculturally acceptable salt or ester thereof. Diflufenzopyr, shown below, is a semicarbazone herbicide that provides post-emergence control of annual and perennial broad-leaved weeds in maize, pastures, rangeland, and non-crop areas. Diflufenzopyr, as well as methods of preparing diflufenzopyr, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary forms of diflufenzopyr include its sodium salt. Diflufenzopyr can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, diflufenzopyr is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or greater, such as 1.5 g ai/ha or greater, 2 g ai/ha or greater, 2.5 g ai/ha or greater, 3 g ai/ha or greater, 3.5 g ai/ha or greater, 4 g ai/ha or greater, 5 g ai/ha or greater, 6 g ai/ha or greater, 7 g ai/ha or greater, 8 g ai/ha or greater, 9 g ai/ha or greater, 10 g ai/ha or greater, 15 g ai/ha or greater, 20 g ai/ha or greater, 25 g ai/ha or greater, 30 g ai/ha or greater, 35 g ai/ha or greater, 40 g ai/ha or greater, 45 g ai/ha or greater, 50 g ai/ha or greater, 55 g ai/ha or greater, 60 g ai/ha or greater, 65 g ai/ha or greater, 70 g ai/ha or greater, 75 g ai/ha or greater, 80 g ai/ha or greater, 85 g ai/ha or greater, 90 g ai/ha or greater, 95 g ai/ha or greater, 100 g ai/ha or greater, 110 g ai/ha or greater, 120 g ai/ha or greater, 130 g ai/ha or greater, 140 g ai/ha or greater, 150 g ai/ha or greater, 160 g ai/ha or greater, 170 g ai/ha or greater, 180 g ai/ha or greater, 190 g ai/ha or greater, 200 g ai/ha or greater, 210 g ai/ha or greater, 220 g ai/ha or greater, 230 g ai/ha or greater, 240 g ai/ha or greater, 250 g ai/ha or greater, 260 g ai/ha or greater, 270 g ai/ha or greater, 280 g ai/ha or greater, 290 g ai/ha or greater, 300 g ai/ha or greater, 310 g ai/ha or greater, 320 g ai/ha or greater, 330 g ai/ha or greater, 340 g ai/ha or greater, 350 g ai/ha or greater, 360 g ai/ha or greater, 370 g ai/ha or greater, 380 g ai/ha or greater, 390 g ai/ha or greater, 400 g ai/ha or greater, 420 g ai/ha or greater, 440 g ai/ha or greater, 460 g ai/ha or greater, 480 g ai/ha or greater, 500 g ai/ha or greater, 520 g ai/ha or greater, 540 g ai/ha or greater, 560 g ai/ha or greater, 580 g ai/ha or greater, 600 g ai/ha or greater, 625 g ai/ha or greater, 650 g ai/ha or greater, 675 g ai/ha or greater, 700 g ai/ha or greater, 725 g ai/ha or greater, 750 g ai/ha or greater, 775 g ai/ha or greater, 800 g ai/ha or greater, 825 g ai/ha or greater, 850 g ai/ha or greater, 875 g ai/ha or greater, 900 g ai/ha or greater, 925 g ai/ha or greater, 950 g ai/ha or greater, or 975 g ai/ha or greater; in an amount of 1000 g ai/ha or less, such as 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3.5 g ai/ha or less, 3 g ai/ha or less, 2.5 g ai/ha or less, 2 g ai/ha or less, or 1.5 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as from 1–1000 g ai/ha, from 1–750 g ai/ha, from 3.5–750 g ai/ha, from 3.5–700 g ai/ha, from 3.5–650 g ai/ha, from 3.5–460 g ai/ha, from 3–280 g ai/ha, from 5–260 g ai/ha, from 35–240 g ai/ha, from 7–220 g ai/ha, from 2.5–500 g ai/ha, from 20–750 g ai/ha, from 1–50 g ai/ha, from 10–560 g ai/ha, from 20–500 g ai/ha, from 30–460 g ai/ha, from 40– 400 g ai/ha, from 90–875 g ai/ha, from 60–300 g ai/ha, from 70–700 g ai/ha, from 100–140 g ai/ha, from 100–280 g ai/ha, or from 1.5–975 g ai/ha. Naptalam In some aspects, the auxin transport inhibitor can comprise naptalam or an agriculturally acceptable salt or ester thereof. Naptalam is a phthalamate herbicide that provides pre-emergence control of many broad-leaved weeds and some grasses in cucurbits, asparagus, peanuts, soybeans, and established woody ornamentals. It is described in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary forms of naptalam include its sodium salt. Naptalam can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce an herbicidal effect. In some aspects, naptalam is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 140 g ai/ha or greater, such as 150 g ai/ha or greater, 200 g ai/ha or greater, 300 g ai/ha or greater, 400 g ai/ha or greater, 500 g ai/ha or greater, 600 g ai/ha or greater, 700 g ai/ha or greater, 750 g ai/ha or greater, 800 g ai/ha or greater, 900 g ai/ha or greater, 1000 g ai/ha or greater, 1100 g ai/ha or greater, 1200 g ai/ha or greater, 1250 g ai/ha or greater, 1300 g ai/ha or greater, 1400 g ai/ha or greater, 1500 g ai/ha or greater,1600 g ai/ha or greater, 1700 g ai/ha or greater, 1800 g ai/ha or greater, 1900 g ai/ha or greater, 2000 g ai/ha or greater, 2200 g ai/ha or greater, 2400 g ai/ha or greater, 2600 g ai/ha or greater, 2800 g ai/ha or greater, 3000 g ai/ha or greater, 3200 g ai/ha or greater, 3400 g ai/ha or greater, 3600 g ai/ha or greater, 3800 g ai/ha or greater, 3850 g ai/ha or greater, 3900 g ai/ha or greater, 3950 g ai/ha or greater, 4000 g ai/ha or greater, 4050 g ai/ha or greater, 4100 g ai/ha or greater, 4150 g ai/ha or greater, 4200 g ai/ha or greater, 4250 g ai/ha or greater, 4300 g ai/ha or greater, 4350 g ai/ha or greater, 4400 g ai/ha or greater, 4450 g ai/ha or greater, 4500 g ai/ha or greater, 4550 g ai/ha or greater, 4600 g ai/ha or greater, 4650 g ai/ha or greater, 4700 g ai/ha or greater, 4750 g ai/ha or greater, 4800 g ai/ha or greater, 4850 g ai/ha or greater, 4900 g ai/ha or greater, 4950 g ai/ha or greater, 5000 g ai/ha or greater, 5050 g ai/ha or greater, 5100 g ai/ha or greater, 5150 g ai/ha or greater, 5200 g ai/ha or greater, 5250 g ai/ha or greater, 5300 g ai/ha or greater, 5350 g ai/ha or greater, 5400 g ai/ha or greater, or 5450 g ai/ha or greater; in an amount of 5500 g ai/ha or less, such as 5450 g ai/ha or less, 5400 g ai/ha or less, 5350 g ai/ha or less, 5300 g ai/ha or less, 5250 g ai/ha or less, 5200 g ai/ha or less, 5150 g ai/ha or less, 5100 g ai/ha or less, 5050 g ai/ha or less, 5000 g ai/ha or less, 4950 g ai/ha or less, 4900 g ai/ha or less, 4850 g ai/ha or less, 4800 g ai/ha or less, 4750 g ai/ha or less, 4700 g ai/ha or less, 4650 g ai/ha or less, 4600 g ai/ha or less, 4550 g ai/ha or less, 4500 g ai/ha or less, 4450 g ai/ha or less, 4400 g ai/ha or less, 4350 g ai/ha or less, 4300 g ai/ha or less, 4250 g ai/ha or less, 4200 g ai/ha or less, 4150 g ai/ha or less, 4100 g ai/ha or less, 4050 g ai/ha or less, 4000 g ai/ha or less, 3950 g ai/ha or less, 3900 g ai/ha or less, 3850 g ai/ha or less, 3800 g ai/ha or less, 3600 g ai/ha or less, 3400 g ai/ha or less, 3200 g ai/ha or less, 3000 g ai/ha or less, 2800 g ai/ha or less, 2600 g ai/ha or less, 2400 g ai/ha or less, 2200 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 900 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 600 g ai/ha or less, 500 g ai/ha or less, 400 g ai/ha or less, 300 g ai/ha or less, 200 g ai/ha or less, 150 g ai/ha or less, or 140 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as from 140–5500 g ai/ha, 2400–3000 g ai/ha, 3000–5500 g ai/ha, 700–1700 g ai/ha, 300–3500 g ai/ha, 750–4000 g ai/ha, 4250–5400 g ai/ha, 2600–4400 g ai/ha, 3000–4000 g ai/ha, 1600–2800 g ai/ha, 1900–4100 g ai/ha, 1500–3600 g ai/ha, or 150–5450 g ai/ha. Triiodobenzoic acid (2,3,5-TIBA) In some aspects, the auxin transport inhibitor can comprise 2,3,5-triiodobenzoic acid (2,3,5-TIBA) or an agriculturally acceptable salt or ester thereof. 2,3,5-TIBA is an auxin transport inhibitor that inhibits plant top growth, dwarves plants, promotes the growth of lateral buds, accelerates bud formation and flowering, and promotes rooting. 2,3,5-TIBA can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce an herbicidal effect. In some aspects, 2,3,5-TIBA is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 140 g ai/ha or greater, such as 150 g ai/ha or greater, 200 g ai/ha or greater, 300 g ai/ha or greater, 400 g ai/ha or greater, 500 g ai/ha or greater, 600 g ai/ha or greater, 700 g ai/ha or greater, 750 g ai/ha or greater, 800 g ai/ha or greater, 900 g ai/ha or greater, 1000 g ai/ha or greater, 1100 g ai/ha or greater, 1200 g ai/ha or greater, 1250 g ai/ha or greater, 1300 g ai/ha or greater, 1400 g ai/ha or greater, 1500 g ai/ha or greater, 1600 g ai/ha or greater, 1700 g ai/ha or greater, 1800 g ai/ha or greater, 1900 g ai/ha or greater, 2000 g ai/ha or greater, 2200 g ai/ha or greater, 2400 g ai/ha or greater, 2600 g ai/ha or greater, 2800 g ai/ha or greater, 3000 g ai/ha or greater, 3200 g ai/ha or greater, 3400 g ai/ha or greater, 3600 g ai/ha or greater, 3800 g ai/ha or greater, 3850 g ai/ha or greater, 3900 g ai/ha or greater, 3950 g ai/ha or greater, 4000 g ai/ha or greater, 4050 g ai/ha or greater, 4100 g ai/ha or greater, 4150 g ai/ha or greater, 4200 g ai/ha or greater, 4250 g ai/ha or greater, 4300 g ai/ha or greater, 4350 g ai/ha or greater, 4400 g ai/ha or greater, 4450 g ai/ha or greater, 4500 g ai/ha or greater, 4550 g ai/ha or greater, 4600 g ai/ha or greater, 4650 g ai/ha or greater, 4700 g ai/ha or greater, 4750 g ai/ha or greater, 4800 g ai/ha or greater, 4850 g ai/ha or greater, 4900 g ai/ha or greater, 4950 g ai/ha or greater, 5000 g ai/ha or greater, 5050 g ai/ha or greater, 5100 g ai/ha or greater, 5150 g ai/ha or greater, 5200 g ai/ha or greater, 5250 g ai/ha or greater, 5300 g ai/ha or greater, 5350 g ai/ha or greater, 5400 g ai/ha or greater, or 5450 g ai/ha or greater; in an amount of 5500 g ai/ha or less, such as 5450 g ai/ha or less, 5400 g ai/ha or less, 5350 g ai/ha or less, 5300 g ai/ha or less, 5250 g ai/ha or less, 5200 g ai/ha or less, 5150 g ai/ha or less, 5100 g ai/ha or less, 5050 g ai/ha or less, 5000 g ai/ha or less, 4950 g ai/ha or less, 4900 g ai/ha or less, 4850 g ai/ha or less, 4800 g ai/ha or less, 4750 g ai/ha or less, 4700 g ai/ha or less, 4650 g ai/ha or less, 4600 g ai/ha or less, 4550 g ai/ha or less, 4500 g ai/ha or less, 4450 g ai/ha or less, 4400 g ai/ha or less, 4350 g ai/ha or less, 4300 g ai/ha or less, 4250 g ai/ha or less, 4200 g ai/ha or less, 4150 g ai/ha or less, 4100 g ai/ha or less, 4050 g ai/ha or less, 4000 g ai/ha or less, 3950 g ai/ha or less, 3900 g ai/ha or less, 3850 g ai/ha or less, 3800 g ai/ha or less, 3600 g ai/ha or less, 3400 g ai/ha or less, 3200 g ai/ha or less, 3000 g ai/ha or less, 2800 g ai/ha or less, 2600 g ai/ha or less, 2400 g ai/ha or less, 2200 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 900 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 600 g ai/ha or less, 500 g ai/ha or less, 400 g ai/ha or less, 300 g ai/ha or less, 200 g ai/ha or less, 150 g ai/ha or less, or 140 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as from 140–5500 g ai/ha, 2400–3000 g ai/ha, 300–5500 g ai/ha, 700–2000 g ai/ha, 1250–4500 g ai/ha, 2800–5000 g ai/ha, 4250–5400 g ai/ha, 2600–4400 g ai/ha, 3000–4000 g ai/ha, 600–2800 g ai/ha, 1900–4100 g ai/ha, 1500–3600 g ai/ha, or 150–5450 g ai/ha. PPO INHIBITOR HERBICIDES In addition to the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), the compositions can include an inhibitor of a protoporphyrinogen oxidase (PPO), which is an enzyme involved in the biosynthesis of both heme and chlorophyll. It is believed that PPO inhibitors generate large amounts of singlet oxygen, which leads to the peroxidation of the lipids in cell membranes. Examples of PPO inhibitors include acifluorfen, azafenidin, benzfendizone, bifenox, butafenacil, carfentrazone, chlomethoxyfen, cinidon, fluazolate, flufenpyr, flumiclorac, flumioxazin, fluoroglycofen, fluthiacet, fomesafen, halosafen, lactofen, oxadiargyl, oxadiazon, oxyfluorfen, pentoxazone, profluazol, pyraclonil, pyraflufen, saflufenacil, sulfentrazone, thidiazimin, tiafenacil, trifludimoxazin, ethyl [3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-diox o-1,2,3,4- tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate (CAS 353292-31-6; S-3100), N- ethyl-3-(2,6-dichloro-4-trifluoromethylphenoxy)-5-methyl-1H- pyrazole-1- carboxamide (CAS 452098-92-9), N-tetrahydrofurfuryl-3-(2,6-dichloro-4-trifluoromethylphenox y)-5- methyl-1-H-pyrazole-1-carboxamide (CAS 915396-43-9), N-ethyl-3-(2-chloro-6-fluoro-4- trifluoromethylphenoxy)-5-methyl-1H-pyrazo-le-1-carboxamide (CAS 452099-05-7), N- tetrahydrofurfuryl-3-(2-chloro-6-fluoro-4-trifluoromethylphe noxy)-5-methyl-1H-pyrazole-1- carboxamide (CAS 45100-03-7), 3-[7-fluoro-3-oxo-4-(prop-2-ynyl)-3,4-dihydro-2H- benzo[1,4]oxazin-6-yl]-1,5-dimethyl-6-thioxo[1,3,5]triazinan -2,4-dione, agriculturally acceptable esters thereof, or combinations thereof. The PPO inhibitor herbicides or agriculturally acceptable salt or ester thereof can be applied to vegetation or an area adjacent to the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, the PPO inhibitor or agriculturally acceptable salt or ester thereof is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 0.5 grams active ingredient per hectare (g ai/ha) or more, such as 1 g ai/ha or more, 1.25 g ai/ha or more, 1.5 g ai/ha or more, 1.75 g ai/ha or more, 2 g ai/ha or more, 2.5 g ai/ha or more, 3 g ai/ha or more, 3.5 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 11 g ai/ha or more, 12 g ai/ha or more, 13 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 17 g ai/ha or more, 18 g ai/ha or more, 19 g ai/ha or more, 20 g ai/ha or more, 21 g ai/ha or more, 22 g ai/ha or more, 23 g ai/ha or more, 24 g ai/ha or more, 25 g ai/ha or more, 26 g ai/ha or more, 27 g ai/ha or more, 28 g ai/ha or more, 29 g ai/ha or more, 30 g ai/ha or more, 31 g ai/ha or more, 32 g ai/ha or more, 33 g ai/ha or more, 34 g ai/ha or more, 35 g ai/ha or more, 36 g ai/ha or more, 37 g ai/ha or more, 38 g ai/ha or more, 39 g ai/ha or more, 40 g ai/ha or more, 41 g ai/ha or more, 42 g ai/ha or more, 43 g ai/ha or more, 44 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, or 975 g ai/ha or more; in an amount of 1000 g ai/ha or less, such as 975 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 44 g ai/ha or less, 43 g ai/ha or less, 42 g ai/ha or less, 41 g ai/ha or less, 40 g ai/ha or less, 39 g ai/ha or less, 38 g ai/ha or less, 37 g ai/ha or less, 36 g ai/ha or less, 35 g ai/ha or less, 34 g ai/ha or less, 33 g ai/ha or less, 32 g ai/ha or less, 31 g ai/ha or less, 30 g ai/ha or less, 29 g ai/ha or less, 28 g ai/ha or less, 27 g ai/ha or less, 26 g ai/ha or less, 25 g ai/ha or less, 24 g ai/ha or less, 23 g ai/ha or less, 22 g ai/ha or less, 21 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18 g ai/ha or less, 17 g ai/ha or less, 16 ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, 11 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3.5 g ai/ha or less, 3 g ai/ha or less, 2.5 g ai/ha or less, 2 g ai/ha or less, 1.75 g ai/ha or less, 1.5 g ai/ha or less, 1.25 g ai/ha or less, or 1 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 0.5-1000 g ai/ha, 2–900 g ai/ha, 1.75-300 g ai/ha, 75–550 g ai/ha, 90–900 g ai/ha, 55–400 g ai/ha, 36–250 g ai/ha, 80–650 g ai/ha, 120–360 g ai/ha, 65– 170 g ai/ha, 34–700 g ai/ha, 12–200 g ai/ha, 5–220 g ai/ha, 1.5-25 g ai/ha, 70–450 g ai/ha, 39– 110 g ai/ha, or 1–975 g ai/ha. In some aspects, the herbicidal composition contains a herbicidally effective amount of compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and (b) acifluorfen, azafenidin, benzfendizone, bifenox, butafenacil, carfentrazone, chlomethoxyfen, cinidon, fluazolate, flufenpyr, flumiclorac, flumioxazin, fluoroglycofen, fluthiacet, fomesafen, halosafen, lactofen, oxadiargyl, oxadiazon, oxyfluorfen, pentoxazone, profluazol, pyraclonil, pyraflufen, saflufenacil, sulfentrazone, thidiazimin, tiafenacil, trifludimoxazin, agriculturally acceptable salts or esters thereof, or combinations thereof. Acifluorfen Compositions and methods of the present disclosure can include acifluorfen or an agriculturally acceptable salt or ester thereof. Acifluorfen, as well as methods of preparing acifluorfen, are known in the art. Acifluorfen, shown below, is 5-[2-chloro-4- (trifluoromethyl)phenoxy]-2-nitrobenzoic acid. Its herbicidal activity is exemplified in Turner, J. A., Ed., The Pesticide Manual: A World Compendium, 17 th ed.; BCPC: Alton, Hampshire, UK, 2016 (hereafter “The Pesticide Manual”). Exemplary uses of acifluorfen include its use for post-emergence control of broadleaf weeds, with some control of grass weeds, in soybeans, peanuts, and rice. Acifluorfen can be applied to the foliage and roots of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, acifluorfen is applied to the foliage and roots of undesirable vegetation in an amount of 100 g ai/ha or more, such as 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 350g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, or 700 g ai/ha or more; in an amount of 700 g ai/ha or less, such as 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, or 100 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 100–700 g ai/ha, 120–700 g ai/ha, 225–700 g ai/ha, 200–600 g ai/ha, 100–525 g ai/ha, 160–340 g ai/ha, 200–425 g ai/ha, 140–250 g ai/ha, 200–340 g ai/ha, 110–525 g ai/ha, 125–200 g ai/ha, 100– 165 g ai/ha, 120–150 g ai/ha, 125–450 g ai/ha, 100–145 g ai/ha, or 110–675 g ai/ha. Azafenidin Compositions and methods of the present disclosure can include azafenidin or an agriculturally acceptable salt or ester thereof. Azafenidin, as well as methods of preparing azafenidin, are known in the art. Azafenidin, shown below, is 2-[2,4-dichloro-5-(2-propyn-1- yloxy)phenyl]-5,6,7,8-tetrahydro-1,2,4-triazolo[4,3-a]pyridi n-3(2H)-one. According to the online edition of The Pesticide Manual, azafenidin is a herbicide that was evaluated by DuPont for use as a pre-emergence and, in mixtures, post-emergence control of annual and perennial weeds in citrus, grapes, olives, sugar cane, and other perennial crops. Benzfendizone Compositions and methods of the present disclosure can include benzfendizone or an agriculturally acceptable salt or ester thereof. Benzfendizone, as well as methods of preparing benzfendizone, are known in the art. Benzfendizone, shown below, is methyl 2-[2- [[4-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H )- pyrimidinyl]phenoxy]methyl]-5-ethylphenoxy]propanoate. According to the online edition of The Pesticide Manual, benzfendizone is a herbicide that was evaluated by FMC for post- emergence control of grass and broadleaf weeds in orchards and no-till situations, and also as a cotton defoliant and potato desiccant. Bifenox Compositions and methods of the present disclosure can include bifenox or an agriculturally acceptable salt or ester thereof. Bifenox, as well as methods of preparing bifenox, are known in the art. Bifenox, shown below, is methyl 5-(2,4-dichlorophenoxy)-2- nitrobenzoate. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of bifenox include its use for pre-emergence, pre-plant incorporated, or directed post- emergence control of annual broadleaf weeds and some grass weeds in cereals, maize, sorghum, soybeans, rice, etc. Bifenox can be applied to the foliage, emerging shoots, and roots of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, bifenox is applied to the foliage, emerging shoots, and roots of undesirable vegetation in an amount of 50 g ai/ha or more, such as 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 125 g ai/ha or more, 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 350 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, or 1000 g ai/ha or more; in an amount of 1001 g ai/ha or less, such as 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, 125 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, or 60 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–1000 g ai/ha, 100–700 g ai/ha, 225–350 g ai/ha, 300–600 g ai/ha, 70–500 g ai/ha, 500–950 g ai/ha, 750–1000 g ai/ha, 60–800 g ai/ha, 75–750 g ai/ha, 150–450 g ai/ha, 200–900 g ai/ha, 325–650 g ai/ha, 90–500 g ai/ha, 175–250 g ai/ha, 140–800 g ai/ha, 450–500 g ai/ha, 125–850 g ai/ha, 65–140 g ai/ha, or 50–950 g ai/ha. Butafenacil Compositions and methods of the present disclosure can include butafenacil or an agriculturally acceptable salt or ester thereof. Butafenacil, as well as methods of preparing butafenacil, are known in the art. Butafenacil, shown below, is 1,1-dimethyl-2-oxo-2-(2- propenyloxy)ethyl-2-chloro-5-[3,6-dihydro-3-methyl-2,6-dioxo -4-(trifluoromethyl)-1(2H)- pyrimidinyl]benzoate. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of butafenacil include its use for post-emergence control of annual and perennial broadleaf weeds in fruit, vineyards, citrus, and non-crop land. Carfentrazone Compositions and methods of the present disclosure can include carfentrazone or an agriculturally acceptable salt or ester thereof. Carfentrazone, as well as methods of preparing carfentrazone, are known in the art. Carfentrazone-ethyl, shown below, is a commonly used ester form of carfentrazone with the structure ethyl α,2-dichloro-5-[4- (difluoromethyl)-4,5-dihydro-3-methyl-5-oxo-1H-1,2,4-triazol -1-yl]-4- fluorobenzenepropanoate. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of carfentrazone-ethyl include its use for post-emergence control of broadleaf weeds in cereals and for the desiccation of potatoes. Carfentrazone can be applied to the foliage of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, carfentrazone is applied to the foliage of undesirable vegetation in an amount of 0.5 g ai/ha or more, such as 0.6 g ai/ha or more, 0.8 g ai/ha or more, 1 g ai/ha or more, 2 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 11 g ai/ha or more, 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 22.5 g ai/ha or more, 25g ai/ha or more, 27.5 g ai/ha or more, 30 g ai/ha or more, 32.5 g ai/ha or more, 35 g ai/ha or more, 37.5 g ai/ha or more, 39 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, or 75 g ai/ha or more; in an amount of 80 g ai/ha or less, such as 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 37.5 g ai/ha or less, 35 g ai/ha or less, 32.5 g ai/ha or less, 30 g ai/ha or less, 27.5 g ai/ha or less, 25 g ai/ha or less, 22.5 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, 12.5 g ai/ha or less, 11 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, 2 g ai/ha or less, 1 g ai/ha or less, 0.8 g ai/ha or less, or 0.6 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 0.5–80 g ai/ha, 1–40 g ai/ha, 3–55 g ai/ha, 5–32.5 g ai/ha, 0.8– 70 g ai/ha, 15–70 g ai/ha, 7.5–40 g ai/ha, 20–30 g ai/ha, 0.6–37.5 g ai/ha, 3–30 g ai/ha, 10–25 g ai/ha, 2–17.5 g ai/ha, 40–75 g ai/ha, 4–10 g ai/ha, or 0.6–75 g ai/ha. Chlomethoxyfen Compositions and methods of the present disclosure can include chlomethoxyfen or an agriculturally acceptable salt or ester thereof. Chlomethoxyfen, as well as methods of preparing chlomethoxyfen, are known in the art. Chlomethoxyfen, shown below, is 2,4- dichloro-1-(3-methoxy-4-nitrophenoxy)benzene. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of chlomethoxyfen include its use for pre-emergence control of annual weeds in transplanted rice, applied at 1.5-2.5 kg ai/ha. Chlomethoxyfen can be applied to the leaves and stems of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, chlomethoxyfen is applied to the leaves and stems of undesirable vegetation in an amount of 250 g ai/ha or more, such as 275 g ai/ha or more, 300 g ai/ha or more, 350 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, or 1000 g ai/ha or more; ,in an amount of 1001 g ai/ha or less, such as 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, or 250 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 250–1000 g ai/ha, 300–600 g ai/ha, 450–550 g ai/ha, 850–1000 g ai/ha, 250–750 g ai/ha, 275–900 g ai/ha, 300–400 g ai/ha, 475–500 g ai/ha, 250–475 g ai/ha, 275–350 g ai/ha, 300–325 g ai/ha, or 275–950 g ai/ha. Cinidon Compositions and methods of the present disclosure can include cinidon or an agriculturally acceptable salt or ester thereof. Cinidon, as well as methods of preparing cinidon, are known in the art. Cinidon-ethyl, shown below, is a commonly used ester of cinidon with the structure ethyl (2Z)-chloro-3-[2-chloro-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo-2 H-isoindol-2- yl)phenyl]-2-propenoate. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of cinidon include its use for post-emergence control of annual broadleaf weeds in winter and spring small grain cereals. Cinidon can be applied to the foliage of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, cinidon is applied to the foliage of undesirable vegetation in an amount of 0.5 g ai/ha or more, such as 0.6 g ai/ha or more, 0.8 g ai/ha or more, 1 g ai/ha or more, 2 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 22.5 g ai/ha or more, 25g ai/ha or more, 27.5 g ai/ha or more, 30 g ai/ha or more, 32.5 g ai/ha or more, 35 g ai/ha or more, 37.5 g ai/ha or more, 39 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, or 75 g ai/ha or more; in an amount of 80 g ai/ha or less, such as 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 37.5 g ai/ha or less, 35 g ai/ha or less, 32.5 g ai/ha or less, 30 g ai/ha or less, 27.5 g ai/ha or less, 25 g ai/ha or less, 22.5 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, 12.5 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, 2 g ai/ha or less, 1 g ai/ha or less, 0.8 g ai/ha or less, or 0.6 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 0.5– 80 g ai/ha, 7–70 g ai/ha, 40–60 g ai/ha, 0.6–45 g ai/ha, 37.5–70 g ai/ha, 15–55 g ai/ha, 1–35 g ai/ha, 9–30 g ai/ha, 3–45 g ai/ha, 10–65 g ai/ha, 20–25 g ai/ha, 8–20 g ai/ha, 12–60 g ai/ha, 0.6–12.5 g ai/ha, or 1–75 g ai/ha. Fluazolate Compositions and methods of the present disclosure can include fluazolate or an agriculturally acceptable salt or ester thereof. Fluazolate, as well as methods of preparing fluazolate, are known in the art. Fluazolate, shown below, is 1-methylethyl 5-[4-bromo-1- methyl-5-(trifluoromethyl)-1H-pyrazol-3-yl]-2-chloro-4-fluor obenzoate. According to the online edition of The Pesticide Manual, fluazolate is a herbicide under development for use as pre-emergence control of grasses and broadleaf weeds on cereals. Fluazolate can be applied to undesirable vegetation or applied to soil to prevent the emergence or growth of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, fluazolate is applied to undesirable vegetation or applied to soil to prevent the emergence or growth of undesirable vegetation in an amount of 50 g ai/ha or more, such as 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, or 250 g ai/ha or more; in an amount of 250 g ai/ha or less, such as 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, or 55 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–250 g ai/ha, 65– 175 g ai/ha, 100–230 g ai/ha, 150–210 g ai/ha, 200–250 g ai/ha, 55–200 g ai/ha, 90–230 g ai/ha, 60–190 g ai/ha, 125–175 g ai/ha, 80–150 g ai/ha, 90–145 g ai/ha, 100–125 g ai/ha, 80–115 g ai/ha, or 55–240 g ai/ha. Flufenpyr Compositions and methods of the present disclosure can include flufenpyr or an agriculturally acceptable salt or ester thereof. Flufenpyr, as well as methods of preparing flufenpyr, are known in the art. Flufenpyr-ethyl, shown below, is a commonly-used ester of flufenpyr, whose structure is ethyl [2-chloro-4-fluoro-5-[5-methyl-6-oxo-4-(trifluoromethyl)- 1(6H)-pyridazinyl]phenoxy]acetate. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of flufenpyr include its use for control of velvetleaf and morningglory in maize, soybeans, and sugar cane. Flufenpyr can be applied to the foliage of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, flufenpyr is applied to the foliage of undesirable vegetation in an amount of 0.5 g ai/ha or more, such as 0.6 g ai/ha or more, 0.8 g ai/ha or more, 1 g ai/ha or more, 2 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 22.5 g ai/ha or more, 25g ai/ha or more, 27.5 g ai/ha or more, 30 g ai/ha or more, 32.5 g ai/ha or more, 35 g ai/ha or more, 37.5 g ai/ha or more, 39 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, or 70 g ai/ha or more; in an amount of 75 g ai/ha or less, such as 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 37.5 g ai/ha or less, 35 g ai/ha or less, 32.5 g ai/ha or less, 30 g ai/ha or less, 27.5 g ai/ha or less, 25 g ai/ha or less, 22.5 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, 12.5 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, 2 g ai/ha or less, 1 g ai/ha or less, 0.8 g ai/ha or less, or 0.6 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 0.5–75 g ai/ha, 4–45 g ai/ha, 15–70 g ai/ha, 5–60 g ai/ha, 8–40 g ai/ha, 1–25 g ai/ha, 2–32.5 g ai/ha, 0.6–20 g ai/ha, 10–30 g ai/ha, 0.5–17.5 g ai/ha, 9–15 g ai/ha, 7–55 g ai/ha, 9–15 g ai/ha, 1–9 g ai/ha, 4–10 g ai/ha, or 0.6–70 g ai/ha. Flumiclorac Compositions and methods of the present disclosure can include flumiclorac-pentyl or an agriculturally acceptable salt or ester thereof. Flumiclorac, as well as methods of preparing flumiclorac, are known in the art. Flumiclorac-pentyl, shown below, is a commonly- used ester of flumiclorac, whose structure is pentyl 2-[2-chloro-4-fluoro-5-(1,3,4,5,6,7- hexahydro-1,3-dioxo-2H-isoindol-2-yl)-phenoxy]acetate. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of flumiclorac include its use for pre- and post- emergence control of broadleaf weeds in maize and soybeans, applied at 30-60 g ai/ha. Flumiclorac can be applied to the foliage of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, flumiclorac is applied to the foliage of undesirable vegetation in an amount of 0.5 g ai/ha or more, such as 0.6 g ai/ha or more, 0.8 g ai/ha or more, 1 g ai/ha or more, 2 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 22.5 g ai/ha or more, 25g ai/ha or more, 27.5 g ai/ha or more, 30 g ai/ha or more, 32.5 g ai/ha or more, 35 g ai/ha or more, 37.5 g ai/ha or more, 39 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, or 75 g ai/ha or more; in an amount of 80 g ai/ha or less, such as 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 37.5 g ai/ha or less, 35 g ai/ha or less, 32.5 g ai/ha or less, 30 g ai/ha or less, 27.5 g ai/ha or less, 25 g ai/ha or less, 22.5 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, 12.5 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, 2 g ai/ha or less, 1 g ai/ha or less, 0.8 g ai/ha or less, or 0.6 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 0.5– 80 g ai/ha, 9–75 g ai/ha, 30–60 g ai/ha, 2–50 g ai/ha, 15–70 g ai/ha, 0.5–32.5 g ai/ha, 1–25 g ai/ha, 10–65 g ai/ha, 4–20 g ai/ha, 0.8–17.5 g ai/ha, 11–35 g ai/ha, 27.5–50 g ai/ha, or 0.6–75 g ai/ha. Flumioxazin Compositions and methods of the present disclosure can include flumioxazin or an agriculturally acceptable salt or ester thereof. Flumioxazin, as well as methods of preparing flumioxazin, are known in the art. Flumioxazin, shown below, is 2-[7-fluoro-3,4-dihydro-3- oxo-4-(2-propynyl)-2H-1,4-benzoxazin-6-yl]-4,5,6,7-tetrahydr o-1H-isoindole-1,3(2H)-dione. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of flumioxazin include its use for pre-emergence control of annual broadleaf weeds and some annual grass weeds in soybeans, peanuts, orchards, vines, and other crops. Flumioxazin can be applied to the undesirable vegetation or applied to soil to prevent the emergence or growth of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, is applied to the undesirable vegetation or applied to soil to prevent the emergence or growth of undesirable vegetation in an amount of 50 g ai/ha or more, such as 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, or 450 g ai/ha or more; in an amount of 500 g ai/ha or less, such as 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, or 60 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–500 g ai/ha, 125–300 g ai/ha, 225–500 g ai/ha, 250–500 g ai/ha, 275–475 g ai/ha, 400–450 g ai/ha, 75–200 g ai/ha, 125–260 g ai/ha, 300–375 g ai/ha, ai/ha, 60–375 g ai/ha, 80–300 g ai/ha, 90–170 g ai/ha, 125–400 g ai/ha, 100–250 g ai/ha, 50–240 g ai/ha, 90–200 g ai/ha, 110– 190 g ai/ha, 75–175 g ai/ha, 60–160 g ai/ha, 90–450 g ai/ha, 100–110 g ai/ha, or 60–475 g ai/ha. Fluoroglycofen Compositions and methods of the present disclosure can include fluoroglycofen or an agriculturally acceptable salt or ester thereof. Fluoroglycofen, as well as methods of preparing fluoroglycofen, are known in the art. Fluoroglycofen-ethyl, shown below, is a commonly-used ester of fluoroglycofen, whose structure is carboxymethyl 5-[2-chloro-4- (trifluoromethyl)phenoxy]-2-nitrobenzoate. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of fluoroglycofen include its use for post-emergence control of broadleaf weeds and grass weeds in wheat, barley, oats, peanuts, rice, and soybeans. Fluoroglycofen thereof can be applied to the foliage or roots of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, fluoroglycofen is applied to the foliage or roots of undesirable vegetation in an amount of 0.5 g ai/ha or more, such as 0.6 g ai/ha or more, 0.8 g ai/ha or more, 1 g ai/ha or more, 2 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 22.5 g ai/ha or more, 25g ai/ha or more, 27.5 g ai/ha or more, 30 g ai/ha or more, 32.5 g ai/ha or more, 35 g ai/ha or more, 37.5 g ai/ha or more, 39 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, or 75 g ai/ha or more; in an amount of 80 g ai/ha or less, such as 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 37.5 g ai/ha or less, 35 g ai/ha or less, 32.5 g ai/ha or less, 30 g ai/ha or less, 27.5 g ai/ha or less, 25 g ai/ha or less, 22.5 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, 12.5 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, 2 g ai/ha or less, 1 g ai/ha or less, 0.8 g ai/ha or less, or 0.6 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 0.5–80 g ai/ha, 3–20 g ai/ha, 40–70 g ai/ha, 2–65 g ai/ha, 5–50 g ai/ha, 1–45 g ai/ha, 7–25 g ai/ha, 5–37.5 g ai/ha, 8–60 g ai/ha, 1–17.5 g ai/ha, 6– 30 g ai/ha, 2–9 g ai/ha, 0.6–75 g ai/ha. Fluthiacet Compositions and methods of the present disclosure can include fluthiacet or an agriculturally acceptable salt or ester thereof. Fluthiacet, as well as methods of preparing fluthiacet, are known in the art. Fluthiacet-methyl, shown below, is a commonly-used ester of fluthiacet, whose structure is methyl 2-[[2-chloro-4-fluoro-5-[(tetrahydro-3-oxo-1H,3H- [1,3,4]thiadiazolo[3,4-a]pyridazin-1-ylidene)amino]-phenyl]t hio]acetate. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of fluthiacet-methyl include its use for post-emergence control of broadleaf weeds in maize and soybeans, applied at 4-15 g ai/ha. Fluthiacet can be applied to the foliage of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, fluthiacet is applied to the foliage of undesirable vegetation in an amount of 0.5 g ai/ha or more, such as 0.6 g ai/ha or more, 0.8 g ai/ha or more, 1 g ai/ha or more, 2 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 22.5 g ai/ha or more, 25g ai/ha or more, 27.5 g ai/ha or more, 30 g ai/ha or more, 32.5 g ai/ha or more, 35 g ai/ha or more, 37.5 g ai/ha or more, 39 g ai/ha or more, 40 g ai/ha or more, or 45 g ai/ha or more; in an amount of 50 g ai/ha or less, such as 45 g ai/ha or less, 40 g ai/ha or less, 37.5 g ai/ha or less, 35 g ai/ha or less, 32.5 g ai/ha or less, 30 g ai/ha or less, 27.5 g ai/ha or less, 25 g ai/ha or less, 22.5 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, 12.5 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, 2 g ai/ha or less, 1 g ai/ha or less, 0.8 g ai/ha or less, or 0.6 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 0.5– 50 g ai/ha, 0.8–20 g, 9–45 g ai/ha, 5–37.5 g ai/ha, 10–15 g ai/ha, 20–30 g ai/ha, 7–25 g ai/ha, 1–20 g ai/ha, 3–30 g ai/ha, 12.5–45 g ai/ha, 1–10 g ai/ha, 6–40 g ai/ha, or 0.6–45 g ai/ha. Fomesafen Compositions and methods of the present disclosure can include fomesafen or an agriculturally acceptable salt or ester thereof. Fomesafen, as well as methods of preparing fomesafen, are known in the art. Fomesafen, shown below, is 5-[2-chloro-4- (trifluoromethyl)phenoxy]-N-(methylsulfonyl)-2-nitrobenzamid e. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of fomesafen include its use for early post-emergence control of broadleaf weeds in soybeans, applied at 200-400 g ai/ha. Fomesafen can be applied to the foliage and roots of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, fomesafen is applied to the foliage and roots of undesirable vegetation in an amount of 100 g ai/ha or more, such as 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 350g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, or 475 g ai/ha or more; in an amount of 500 g ai/ha or less, such as 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, or 110 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 100–500 g ai/ha, 175–300 g ai/ha, 225–475 g ai/ha, 100–400 g ai/ha, 170–375 g ai/ha, 120–250 g ai/ha, 180–300 g ai/ha, 110–250 g ai/ha, 130–210 g ai/ha, 160–200 g ai/ha, 100–180 g ai/ha, 210–375 g ai/ha, 150–275 g ai/ha, 190– 450 g ai/ha, 120–140 g ai/ha, or 110–475 g ai/ha. Halosafen Compositions and methods of the present disclosure can include halosafen or an agriculturally acceptable salt or ester thereof. Halosafen, as well as methods of preparing halosafen, are known in the art. Halosafen, shown below, is 5-[2-chloro-6-fluoro-4- (trifluoromethyl)phenoxy]-N-(ethylsulfonyl)-2-nitrobenzamide . According to the online edition of The Pesticide Manual, halosafen is a herbicide that was evaluated by ICI Agrochemicals. Lactofen Compositions and methods of the present disclosure can include lactofen or an agriculturally acceptable salt or ester thereof. Lactofen, as well as methods of preparing lactofen, are known in the art. Lactofen, shown below, is 2-ethoxy-1-methyl-2-oxoethyl 5-[2- chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoate. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of lactofen include its use for post-emergence control of broadleaf weeds cotton, soybeans, and snap beans, applied at 220 g ai/ha. Lactofen can be applied to the foliage of undesirable vegetation in an amount sufficient to induce an herbicidal effect. In some aspects, lactofen is applied to the foliage of undesirable vegetation in an amount of 50 g ai/ha or more, such as 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, or 450 g ai/ha or more; in an amount of 500 g ai/ha or less, such as 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, or 60 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–500 g ai/ha, 175–350 g ai/ha, 220–450 g ai/ha, 75–400 g ai/ha, 60–375 g ai/ha, 80–250 g ai/ha, 90–220 g ai/ha, 110–280 g ai/ha, 70–190 g ai/ha, 160–200 g ai/ha, 50–180 g ai/ha, 120–150 g ai/ha, 80–240 g ai/ha, 75– 350 g ai/ha, 50–130 g ai/ha, or 60–475 g ai/ha. Oxadiargyl Compositions and methods of the present disclosure can include oxadiargyl or an agriculturally acceptable salt or ester thereof. Oxadiargyl, as well as methods of preparing oxadiargyl, are known in the art. Oxadiargyl, shown below, is 3-[2,4-dichloro-5-(2-propyn-1- yloxy)phenyl]-5-(1,1-dimethylethyl)-1,3,4-oxadiazol-2(3H)-on e. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of oxadiargyl include its use for pre- and early post-emergence control of broadleaf weeds, grass weeds, and annual sedge weeds in rice, applied at 50-150 g ai/ha, sunflowers, potatoes, vegetables, and sugar cane, applied at 300- 500 g ai/ha, and fruit and citrus, applied at 500-1500 g ai/ha. Oxadiargyl thereof can be applied to undesirable vegetation or applied to soil or water to prevent the emergence or growth of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, oxadiargyl is applied to undesirable vegetation or applied to soil or water to prevent the emergence or growth of undesirable vegetation in an amount of 25 g ai/ha or more, such as 40 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 80 g ai/ha or more, 100 g ai/ha or more, 125 g ai/ha or more, 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 350 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, or 950 g ai/ha or more; in an amount of 1001 g ai/ha or less, such as 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, 125 g ai/ha or less, 100 g ai/ha or less, 80 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 40 g ai/ha or less, or 30 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 25–1000 g ai/ha, 250–500 g ai/ha, 100–800 g ai/ha, 325–750 g ai/ha, 600–800 g ai/ha, 50–550 g ai/ha, 90–900 g ai/ha, 150–600 g ai/ha, 350–700 g ai/ha, 400–500 g ai/ha, 25–425 g ai/ha, 50–375 g ai/ha, 450–900 g ai/ha, 200–600 g ai/ha, 80–225 g ai/ha, 25–175 g ai/ha, 100–150 g ai/ha, 25–80 g ai/ha, or 30–950 g ai/ha. Oxadiazon Compositions and methods of the present disclosure can include oxadiazon or an agriculturally acceptable salt or ester thereof. Oxadiazon, as well as methods of preparing oxadiazon, are known in the art. Oxadiazon, shown below, is 3-[2,4-dichloro-5-(1- methylethoxy)phenyl]-5-(1,1-dimethylethyl)-1,3,4-oxadiazol-2 (3H)-one. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of oxadiazon include: its use for pre-emergence control of bindweed, annual broadleaf weeds, and grass weeds; post- emergence control of bindweed and annual broadleaf weeds in carnations, roses, ornamental trees and shrubs, tree fruit, bush fruit, citrus, vines, hops, cotton, rice, soybeans, sunflowers, onions, and turf; and pre-emergent or post-emergent control of annual broadleaf and grass weeds in orchards and vineyards. Oxadiazon can be applied to undesirable vegetation or applied to soil or water to prevent the emergence or growth of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, oxadiazon is applied to undesirable vegetation or applied to soil or water to prevent the emergence or growth of undesirable vegetation in an amount of 250 g ai/ha or more, such as 275 g ai/ha or more, 300 g ai/ha or more, 350 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, or 950 g ai/ha or more; in an amount of 1001 g ai/ha or less, such as 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, or 275 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 250–1000 g ai/ha, 600–1000 g ai/ha, 350–900 g ai/ha, 275– 750 g ai/ha, 400–950 g ai/ha, 650–800 g ai/ha, 250–550 g ai/ha, 325–700 g ai/ha, 450–850 g ai/ha, 250–375 g ai/ha, 300–600 g ai/ha, 250–400 g ai/ha, or 275–950 g ai/ha. Oxyfluorfen Compositions and methods of the present disclosure can include oxyfluorfen or an agriculturally acceptable salt or ester thereof. Oxyfluorfen, as well as methods of preparing oxyfluorfen, are known in the art. Oxyfluorfen, shown below, is 2-chloro-1-(3-ethoxy-4- nitrophenoxy)-4-(trifluoromethyl)benzene. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of oxyfluorfen include its use for pre- and post-emergence control of annual broadleaf and grass weeds in tree fruit, citrus, vines, nuts, cereals, maize, soybeans, peanuts, rice, cotton, bananas, peppermint, onions, garlic, ornamentals, and conifer seedbeds, applied at 250-2000 g ai/ha. Oxyfluorfen can be applied to the foliage and shoots of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, oxyfluorfen is applied to the foliage and shoots of undesirable vegetation in an amount of 50 g ai/ha or more, such as 75 g ai/ha or more, 100 g ai/ha or more, 125 g ai/ha or more, 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 250 g ai/ha or more, 300 g ai/ha or more, 350 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 900 g ai/ha or more, or 950 g ai/ha or more; in an amount of 1001 g ai/ha or less, such as 1000 g ai/ha or less, 900 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 350 g ai/ha or less, 300 g ai/ha or less, 250 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, 125 g ai/ha or less, 100 g ai/ha or less, 75 g ai/ha or less, or 60 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–1000 g ai/ha, 750–1000 g ai/ha, 100–900 g ai/ha, 150–750 g ai/ha, 500–800 g ai/ha, 50–600 g ai/ha, 125–500 g ai/ha, 250–900 g ai/ha, 60–450 g ai/ha, 175–300 g ai/ha, 125–250 g ai/ha, 75–200 g ai/ha, 100–175 g ai/ha, 150–800 g ai/ha, 75–550 g ai/ha, 50–125 g ai/ha, or 60–900 g ai/ha. Pentoxazone Compositions and methods of the present disclosure can include pentoxazone or an agriculturally acceptable salt or ester thereof. Pentoxazone, as well as methods of preparing pentoxazone, are known in the art. Pentoxazone, shown below, is 3-(4-chloro-5- (cyclopentyloxy)-2-fluorophenyl]-5-(1-methylethylidene)-2,4- oxazolidinedione. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of pentoxazone include its use for pre- and post-emergence control of Echinochloa spp. and Monochoria vaginalis in paddy rice. Pentoxazone thereof can be applied to undesirable vegetation or applied to soil or water to prevent the emergence or growth of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pentoxazone is applied to undesirable vegetation or applied to soil or water to prevent the emergence or growth of undesirable vegetation in an amount of 50 g ai/ha or more, such as 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, or 475 g ai/ha or more; in an amount of 500 g ai/ha or less, such as 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, or 60 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–500 g ai/ha, 70–200 g ai/ha, 210–350 g ai/ha, 60–425 g ai/ha, 100–400 g ai/ha, 90–375 g ai/ha, 120–400 g ai/ha, 220–450 g ai/ha, 100–250 g ai/ha, 160–350 g ai/ha, 190–400 g ai/ha, 50–240 g ai/ha, 70–210 g ai/ha, 180–400 g ai/ha, 125–375 g ai/ha, 90–150 g ai/ha, 250–400 g ai/ha, or 60–475 g ai/ha. Profluazol Compositions and methods of the present disclosure can include profluazol or an agriculturally acceptable salt or ester thereof. Profluazol, as well as methods of preparing profluazol, are known in the art. Profluazol, shown below, is 1-chloro-N-[2-chloro-4-fluoro- 5-[(6S,7aR)-6-fluorotetrahydro-1,3-dioxo-1H-pyrrolo[1,2-c]im idazol-2(3H)- yl]phenyl]methanesulfonamide. According to the online edition of The Pesticide Manual, profluazol is a herbicide developed by DuPont. Pyraclonil Compositions and methods of the present disclosure can include pyraclonil or an agriculturally acceptable salt or ester thereof. Pyraclonil, as well as methods of preparing pyraclonil, are known in the art. Pyraclonil, shown below, is 1-(3-chloro-4,5,6,7- tetrahydropyrazolo[1,5-a]pyridin-2-yl)-5-[methyl-2-propynyla mino]-1H-pyrazole-4- carbonitrile. According to the online edition of The Pesticide Manual, pyraclonil is being evaluated for pre-emergence control of broadleaf and sedge weeds in rice. Pyraclonil can be applied to undesirable vegetation or applied to soil or water to prevent the emergence or growth of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pyraclonil is applied to undesirable vegetation or applied to soil or water to prevent the emergence or growth of undesirable vegetation in an amount of 5 g ai/ha or more, such as 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 22.5 g ai/ha or more, 25g ai/ha or more, 27.5 g ai/ha or more, 30 g ai/ha or more, 32.5 g ai/ha or more, 35 g ai/ha or more, 37.5 g ai/ha or more, 39 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, or 95 g ai/ha or more; in an amount of 100 g ai/ha or less, such as 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 37.5 g ai/ha or less, 35 g ai/ha or less, 32.5 g ai/ha or less, 30 g ai/ha or less, 27.5 g ai/ha or less, 25 g ai/ha or less, 22.5 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, 12.5 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, or 6 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 5–100 g ai/ha, 40–70 g ai/ha, 8–90 g ai/ha, 6–75 g ai/ha, 15–55 g ai/ha, 50–80 g ai/ha, 25–65 g ai/ha, 15–90 g ai/ha, 9–45 g ai/ha, 5–32.5 g ai/ha, 12.5–65 g ai/ha, 20–25 g ai/ha, 6–20 g ai/ha, 10–17.5 g ai/ha, 22.5–55 g ai/ha, or 6–90 g ai/ha. Pyraflufen Compositions and methods of the present disclosure can include pyraflufen or an agriculturally acceptable salt or ester thereof. Pyraflufen as well as methods of preparing pyraflufen-ethyl, are known in the art. Pyraflufen-ethyl, shown below, is a commonly used ester of pyraflufen, whose structure is ethyl 2-chloro-5-[4-chloro-5-(difluoromethoxy)-1- methyl-1H-pyrazol-3-yl]-4-fluorophenoxyacetate. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of pyraflufen include its use for post-emergence control of broadleaf weeds in cereals. Pyraflufen can be applied to the foliage of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pyraflufen is applied to the foliage of undesirable vegetation in an amount of 0.5 g ai/ha or more, such as 0.6 g ai/ha or more, 0.8 g ai/ha or more, 1 g ai/ha or more, 2 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 22.5 g ai/ha or more, 25g ai/ha or more, 27.5 g ai/ha or more, 30 g ai/ha or more, 32.5 g ai/ha or more, 35 g ai/ha or more, 37.5 g ai/ha or more, or 39 g ai/ha or more; in an amount of 40 g ai/ha or less, such as 37.5 g ai/ha or less, 35 g ai/ha or less, 32.5 g ai/ha or less, 30 g ai/ha or less, 27.5 g ai/ha or less, 25 g ai/ha or less, 22.5 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, 12.5 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, 2 g ai/ha or less, 1 g ai/ha or less, 0.8 g ai/ha or less, or 0.6 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 0.5–40 g ai/ha, 0.8–10 g, 7–40 g ai/ha, 5–37.5 g ai/ha, 1–25 g ai/ha, 15–32.5 g ai/ha, 0.6–22.5 g ai/ha, 10–20 g ai/ha, 3–15 g ai/ha, 9–30 g ai/ha, 2–10 g ai/ha, 8–35 g ai/ha, 1–5 g ai/ha, or 0.6–37.5 g ai/ha. Saflufenacil Compositions and methods of the present disclosure can include saflufenacil or an agriculturally acceptable salt or ester thereof. Saflufenacil, as well as methods of preparing saflufenacil, are known in the art. Saflufenacil, shown below, is 2-chloro-5-[3,6-dihydro-3- methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-4-fl uoro-N-[[methyl(1- methylethyl)-amino]sulfonyl]benzamide. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of saflufenacil include: pre-emergence control of broadleaf weeds in maize and sorghum; pre-plant foliar burn-down in soybeans, cereals, cotton, and legumes; and post-directed foliar burn-down in tree fruit and nuts. Saflufenacil can be applied to the foliage or roots of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, saflufenacil is applied to the foliage or roots of undesirable vegetation in an amount of 0.5 g ai/ha or more, such as 0.6 g ai/ha or more, 0.8 g ai/ha or more, 1 g ai/ha or more, 2 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 22.5 g ai/ha or more, 25g ai/ha or more, 27.5 g ai/ha or more, 30 g ai/ha or more, 32.5 g ai/ha or more, 35 g ai/ha or more, 37.5 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, or 75 g ai/ha or more; in an amount of 80 g ai/ha or less, such as 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 37.5 g ai/ha or less, 35 g ai/ha or less, 32.5 g ai/ha or less, 30 g ai/ha or less, 27.5 g ai/ha or less, 25 g ai/ha or less, 22.5 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, 12.5 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, 2 g ai/ha or less, 1 g ai/ha or less, 0.8 g ai/ha or less, or 0.6 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 0.5– 80 g ai/ha, 30–75 g ai/ha, 6–70 g ai/ha, 10–65 g ai/ha, 20–50 g ai/ha, 15–80 g ai/ha, 3–45 g ai/ha, 12.5–37.5 g ai/ha, 7–35 g ai/ha, 9–32.5 g ai/ha, 1–25 g ai/ha, 8–65 g ai/ha, 4–22.5 g ai/ha, 0.5–20 g ai/ha, 0.8–17.5 g ai/ha, 22.5–55 g ai/ha, 10–40 g ai/ha, 0.5–5 g ai/ha, or 0.6–75 g ai/ha. Sulfentrazone Compositions and methods of the present disclosure can include sulfentrazone or an agriculturally acceptable salt or ester thereof. Sulfentrazone, as well as methods of preparing sulfentrazone, are known in the art. Sulfentrazone, shown below, is N-[2,4-dichloro- 5-[4-(difluoromethyl)-4,5-dihydro-3-methyl-5-oxo-1H-1,2,4-tr iazol-1-yl]phenyl]-methane- sulfonamide. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of sulfentrazone include its use for pre-plant incorporated or pre-emergence control of annual broadleaf weeds, some grass weeds, and Cyperus spp. in soybeans, sugar cane, and tobacco. Sulfentrazone can be applied to the foliage and roots of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, sulfentrazone is applied to the foliage and roots of undesirable vegetation in an amount of 100 g ai/ha or more, such as 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 350g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, or 475 g ai/ha or more; in an amount of 500 g ai/ha or less, such as 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, or 100 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 100–500 g ai/ha, 250– 400 g ai/ha, 120–210 g ai/ha, 375–500 g ai/ha, 200–475 g ai/ha, 360–450 g ai/ha, 120–250 g ai/ha, 110–380 g ai/ha, 125–375 g ai/ha, 170–350 g ai/ha, 220–425 g ai/ha, 150–300 g ai/ha, 120–275 g ai/ha, 160–250 g ai/ha, 280–450 g ai/ha, 130–280 g ai/ha, 110–170 g ai/ha, 120– 450 g ai/ha, 100–140 g ai/ha, or 110–475 g ai/ha. Thidiazimin Compositions and methods of the present disclosure can include thidiazimin or an agriculturally acceptable salt or ester thereof. Thidiazimin, as well as methods of preparing thidiazimin, are known in the art. Thidiazimin, shown below, is 6-[(Z)-(6,7-dihydro-6,6- dimethyl-3H,5H-pyrrolo[2,1-c][1,2,4]thiadiazol-3-ylidene)ami no]-7-fluoro-4-(2-propyn-1- yl)-2H-1,4-benzoxazin-3(4H)-one. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of thidiazimin include its use for post-emergence control of broadleaf weeds in winter cereals, applied at 20-40 g ai/ha. Thidiazimin can be applied to the foliage of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, thidiazimin thereof is applied to the foliage of undesirable vegetation in an amount of 0.5 g ai/ha or more, such as 0.6 g ai/ha or more, 0.8 g ai/ha or more, 1 g ai/ha or more, 2 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 22.5 g ai/ha or more, 25g ai/ha or more, 27.5 g ai/ha or more, 30 g ai/ha or more, 32.5 g ai/ha or more, 35 g ai/ha or more, 37.5 g ai/ha or more, 39 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, or 55 g ai/ha or more; in an amount of 60 g ai/ha or less, such as 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 37.5 g ai/ha or less, 35 g ai/ha or less, 32.5 g ai/ha or less, 30 g ai/ha or less, 27.5 g ai/ha or less, 25 g ai/ha or less, 22.5 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, 12.5 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, 2 g ai/ha or less, 1 g ai/ha or less, 0.8 g ai/ha or less, or 0.6 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 0.5–60 g ai/ha, 0.8–20 g ai/ha, 1–50 g ai/ha, 5–32.5 g ai/ha, 12.5–40 g ai/ha, 5–55 g ai/ha, 10–50 g ai/ha, 0.8– 45 g ai/ha, 9–37.5 g ai/ha, 3–35 g ai/ha, 10–30 g ai/ha, 2–25 g ai/ha, 20–35 g ai/ha, 2–20 g ai/ha, 5–15 g ai/ha, 9–50 g ai/ha, 17.5–40 g ai/ha, or 0.6–55 g ai/ha. Tiafenacil Compositions and methods of the present disclosure can include tiafenacil or an agriculturally acceptable salt or ester thereof. Tiafenacil, as well as methods of preparing tiafenacil, are known in the art. Tiafenacil, shown below, is methyl N-[2-[[2-chloro-5-[3,6- dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimid inyl]-4-fluorophenyl]thio]-1- oxopropyl-ß-alaninate. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of tiafenacil include its use for none-selective post-emergence burn down control in row crops and permanent crops. Tiafenacil can be applied to the foliage and roots of undesirable vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, tiafenacil is applied to the foliage and roots of undesirable vegetation in an amount of 10 g ai/ha or more, such as 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, or 75 g ai/ha or more, 100 g ai/ha or more, 125 g ai/ha or more, 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, or 275 g ai/ha or more; in an amount of 300 g ai/ha or less, such as 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, 125 g ai/ha or less, 100 g ai/ha or less, 75 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, or 12.5 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 10–300 g ai/ha, 12.5–100 g ai/ha, 40–250 g ai/ha, 275–300 g ai/ha, 10–250 g ai/ha, 50–150 g ai/ha, 175–250 g ai/ha, 17.5–225 g ai/ha, 75–200 g ai/ha, 150–250 g ai/ha, 20–175 g ai/ha, 40–150 g ai/ha, 125– 150 g ai/ha, 30–200 g ai/ha, 40–125 g ai/ha, 25–100 g ai/ha, 35–275 g ai/ha, 60–150 g ai/ha, 10–75 g ai/ha, 15–70 g ai/ha, 150–225 g ai/ha, or 12.5–275 g ai/ha. Trifludimoxazin Compositions and methods of the present disclosure can include mixtures of the compounds of Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and trifludimoxazin, a PPO inhibitor. Exemplary uses of trifludimoxazin can include pre- and/or post-emergent control of broadleaf and grass weeds. It can be applied by aircraft on citrus fruits, pome fruits, cereal grain (except rice), tree nuts, peanuts, and foliage of legume vegetables. Non-agricultural use sites include tree plantations, industrial landscaping, native grass openings, and conifer and hardwood plantations. A composition comprising compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof) may be mixed with or applied in combination with (b) a protoporphyrinogen oxidase (PPO) inhibitors, an agriculturally acceptable salt or ester thereof, or mixtures thereof. In some aspects, (a) and (b) are used in an amount sufficient to induce an enhanced herbicidal effect (e.g., increased damage or injury to undesirable vegetation) while still showing good crop compatibility (e.g., no increased damage to crops or minimal increased damage or injury to crops) when compared to the individual application of the herbicidal compounds (a) or (b). In some aspects, the damage or injury to undesirable vegetation caused by the compositions and methods disclosed herein is evaluated using a scale from 0% to 100%, when compared with the untreated control vegetation, wherein 0% indicates no damage to the undesirable vegetation and 100% indicates complete destruction of the undesirable vegetation. In some aspects, the joint action of (a) the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and (b) the PPO inhibitor herbicide or an agriculturally acceptable salt or ester thereof results in enhanced herbicidal effect against undesirable vegetation, even at application rates below those typically used for the herbicide to have a herbicidal effect on its own. In some aspects, the compositions and methods disclosed herein can, based on the individual components, be used at lower application rates to achieve a herbicidal effect comparable to the effect produced by the individual components at normal application rates. In some aspects, the weight ratio of (a) the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof) (in g ae/ha) to (b) the PPO inhibitor herbicide or an agriculturally acceptable salt or ester thereof (in g ai/ha) can be 1:2000 or more, such as 1:1900 or more, 1:1500 or more, 1:1000 or more, 1: 900 or more, 1:800 or more, 1:700 or more, 1:600 or more, 1:500 or more, 1:400 or more, 1:300 or more, 1:200 or more, 1:100 or more, 1:90 or more, 1:80 or more, 1:70 or more, 1:60 or more, 1:50 or more, 1:40 or more, 1:30 or more, 1:24 or more, 1:20 or more, 1:18 or more, 1:15 or more, 1:12 or more, 1:10 or more, 1:9 or more, 1:8 or more, 1:7 or more, 1:6 or more, 1:5 or more, 1:4 or more, 1:3 or more, 1:2 or more, 1:1.9 or more, 1:1.8 or more, 1:1.7 or more, 1:1.6 or more, 1:1.5 or more, 1:1.4 or more, 1:1.3 or more, 1:1.2 or more, 1:1.1 or more, 1:1 or more, 1.1:1 or more, 1.2:1 or more, 1.3:1 or more, 1.4:1 or more, 1.5:1 or more, 1.6:1 or more, 1.7:1 or more, 1.8:1 or more, 1.9:1 or more, 2:1 or more, 3:1 or more, 4:1 or more, 5:1 or more, 6:1 or more, 7:1 or more, 8:1 or more, 9:1 or more, 10:1 or more, 12:1 or more, 14:1 or more, 15:1 or more, 16:1 or more, 18:1 or more, 20:1 or more, 22:1 or more, 24:1 or more, 25:1 or more, 26:1 or more, 28:1 or more, 30:1 or more, 35:1 or more, 40:1 or more, 45:1 or more, 50:1 or more, 60:1 or more, 70:1 or more, 75:1 or more, 80:1 or more, 90:1 or more, 100:1 or more, 110:1 or more, 120:1 or more, 125:1 or more, 130:1 or more, 140:1 or more, 150:1 or more, 160:1 or more, 170:1 or more, 175:1 or more, 180:1 or more, 190:1 or more, 200:1 or more, 225:1 or more, 250:1 or more, 275:1 or more, 300:1 or more, 325:1 or more, 350:1 or more, 375:1 or more, 400:1 or more, 425:1 or more, 450:1 or more, 475:1 or more, 500:1 or more, 525:1 or more, 550:1 or more, 575:1 or more, or 590:1 or more; the weight ratio of (a) to (b) can be 600:1 or less, such as 590:1 or less, 575:1 or less, 550:1 or less, 525:1 or less, 500:1 or less, 475:1 or less, 450:1 or less, 425:1 or less, 400:1 or less, 375:1 or less, 350:1 or less, 325:1 or less, 300:1 or less, 275:1 or less, 250:1 or less, 225:1 or less, 200:1 or less, 190:1 or less, 180:1 or less, 175:1 or less, 170:1 or less, 160:1 or less, 150:1 or less, 140:1 or less, 130:1 or less, 125:1 or less, 120:1 or less, 110:1 or less, 100:1 or less, 90:1 or less, 80:1 or less, 75:1 or less, 70:1 or less, 60:1 or less, 50:1 or less, 45:1 or less, 40:1 or less, 35:1 or less, 30:1 or less, 28:1 or less, 26:1 or less, 25:1 or less, 24:1 or less, 22:1 or less, 20:1 or less, 18:1 or less, 16:1 or less, 15:1 or less, 14:1 or less, 12:1 or less,10:1 or less, 9:1 or less, 8:1 or less, 7:1 or less, 6:1 or less, 5:1 or less, 4:1 or less, 3:1 or less, 2:1 or less, 1.9:1 or less, 1.8:1 or less, 1.7:1 or less, 1.6:1 or less, 1.5:1 or less, 1.4:1 or less, 1.3:1 or less, 1.2:1 or less, 1.1:1 or less, 1:1 or less, 1:1.1 or less, 1:1.2 or less, 1:1.3 or less, 1:1.4 or less, 1:1.5 or less, 1:1.6 or less, 1:1.7 or less, 1:1.8 or less, 1:1.9 or less, 1:2 or less, 1:3 or less, 1:4 or less, 1:5 or less, 1:6 or less, 1:7 or less, 1:8 or less, 1:9 or less, 1:10 or less, 1:20 or less, 1:30 or less, 1:40 or less, 1:50 or less, 1:60 or less, 1:70 or less, 1:80 or less, 1:90 or less, 1:100 or less, 1:200 or less, 1:300 or less, 1:400 or less, 1:500 or less, 1:1000 or less, 1:1500 or less, or 1:1900 or less; or the weight ratio of (a) to (b) can range from any of the minimum ratios to any of the maximum ratios provided above, such as from 1:2000 to 600:1, from 1:700 to 100:1, from 1:40 to 90:1, from 1:10 to 16:1, from 1:14 to 10:1, from 1:8 to 1:6, or from 1:5 to 5:1. . In some aspects, the active ingredients in the compositions disclosed herein consist of compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof) and (b) a PPO inhibitor herbicide or an agriculturally acceptable salt or ester thereof. In some aspects, the composition may include other components, such as safeners or adjuvants, but does not include a herbicidal active ingredient in addition to (a) and (b). In some aspects, (a) and (b), independently, can be employed in a purity of from 90% to 100% (e.g., from 95% to 100%) according to nuclear magnetic resonance (NMR) spectroscopy. PDS INHIBITOR HERBICIDES In addition to the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), the compositions can include a phytoene desaturase (PDS) inhibitor herbicide or agriculturally acceptable salt or ester thereof. PDS inhibitors block carotenoid biosynthesis by inhibition of phytoene desaturase, a key enzyme in the carotenoid biosynthesis pathway. An absence of carotenoids leads to destruction of membrane fatty acid and chlorophyll by excessive energy. Examples of PDS inhibitors include, but are not limited to, beflubutamid, diflufenican, fluridone, flurochloridone, flurtamone, norflurazon, and picolinafen. In some aspects, the composition can include a PDS inhibitor herbicide selected from the group consisting of beflubutamid, diflufenican, fluridone, flurochloridone, flurtamone, norflurazon, picolinafen, agriculturally acceptable salts and esters thereof, and combinations thereof. The PDS inhibitor herbicide or agriculturally acceptable salt or ester thereof can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, the PDS inhibitor herbicide or agriculturally acceptable salt or ester thereof is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 12.5 gram active ingredient per hectare (g ai/ha) or more, such as 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, 2240 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2350 g ai/ha or more, 2400 g ai/ha or more, 2450 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2750 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3750 g ai/ha or more, 3800 g ai/ha or more, 3900 g ai/ha or more, 3950 g ai/ha or more, 4000 g ai/ha or more, 4100 g ai/ha or more, 4200 g ai/ha or more, 4250 g ai/ha or more, 4300 g ai/ha or more, 4400 g ai/ha or more, or 4450 g ai/ha or more; in an amount of 4500 g ai/ha or less, such as 4450 g ai/ha or less, 4400 g ai/ha or less, 4300 g ai/ha or less, 4250 g ai/ha or less, 4100 g ai/ha or less, 4000 g ai/ha or less, 3950 g ai/ha or less, 3900 g ai/ha or less, 3800 g ai/ha or less, 3750 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2750 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2450 g ai/ha or less, 2400 g ai/ha or less, 2350 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2240 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1240 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, or 15 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 12.5–4500 g ai/ha, 15–2250 g ai/ha, 20-2500 g ai/ha, 25–3150 g ai/ha, 30–900 g ai/ha, 45–4200 g ai/ha, 50–1200 g ai/ha, 50–4100 g ai/ha, 60–750 g ai/ha, 75–2100 g ai/ha, 100–4000 g ai/ha, 200–3600 g ai/ha, 250–3000 g ai/ha, 250–1000 g ai/ha, 700–4250 g ai/ha, 800–1400 g ai/ha, or 1000–3700 g ai/ha. In some aspects, the composition contains compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and (b) diflufenican, flurtamone, picolinafen, or mixtures thereof. Beflubutamid In some aspects, the PDS inhibitor herbicide can comprise beflubutamid or an agriculturally acceptable salt or ester thereof. Beflubutamid, shown below, is 2-[4-fluoro-3- (trifluoromethyl)phenoxy]-N-(phenylmethyl)butanamide. Its herbicidal activity is exemplified in Tomlin, C. D. S., Ed. The Pesticide Manual: A World Compendium, 17 th ed.; BCPC: Alton, 2016 (hereafter “The Pesticide Manual, Seventeenth Edition, 2016”). Exemplary uses of beflubutamid include its use alone, and in mixture with isoproturon, for pre- and early post- emergence control of broadleaf weeds, such as Veronica persica, Lamium amplexicaule and Viola arvensis, in wheat and barley. Beflubutamid can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, beflubutamid is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 25 g ai/ha or more, such as 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 42.5 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more,160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 255 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, or 290 g ai/ha or more; in an amount of 300 g ai/ha or less, such as 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 255 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 42.5 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, or 30 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 25-300 g ai/ha, 45–250 g ai/ha, 60-275 g ai/ha, 120–255 g ai/ha, 90–200 g ai/ha, 130–260 g ai/ha, 150–275 g ai/ha, or 42.5–300 g ai/ha. Diflufenican In some aspects, the PDS inhibitor herbicide can comprise diflufenican or an agriculturally acceptable salt or ester thereof. Diflufenican, as well as methods of preparing diflufenican, are known in the art. Diflufenican, shown below, is N-(2,4-difluorophenyl)-2-[3- (trifluoromethyl)phenoxy]-3-pyridinecarboxamide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of diflufenican include its use as a selective contact and residual herbicide that is used pre- and early post-emergence in autumn-sown wheat and barley to control grass and broadleaf weeds. Diflufenican can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, diflufenican is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 105 g ai/ha or more, 110 g ai/ha or more, 115 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 135 g ai/ha or more, 140 g ai/ha or more, 145 g ai/ha or more, 150 g ai/ha or more, 155 g ai/ha or more, 160 g ai/ha or more, 165 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, or 185 g ai/ha or more; in an amount of 187.5 g ai/ha or less, such as 185 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 165 g ai/ha or less, 160 g ai/ha or less, 155 g ai/ha or less, 150 g ai/ha or less, 145 g ai/ha or less, 140 g ai/ha or less, 135 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 115 g ai/ha or less, 110 g ai/ha or less, 105 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, or 55 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–187.5 g ai/ha, 55–180 g ai/ha, 60–175 g ai/ha, 65–150 g ai/ha, 70–175 g ai/ha, 75–160 g ai/ha, 80–180 g ai/ha, 80–175 g ai/ha, 85–185 g ai/ha, 85–150 g ai/ha, 90–185 g ai/ha, 90–180 g ai/ha, 90– 175 g ai/ha, or 90–170 g ai/ha. Fluridone In some aspects, the PDS inhibitor herbicide can comprise fluridone or an agriculturally acceptable salt or ester thereof. Fluridone, shown below, is 1-methyl-3-phenyl- 5-[3-(trifluoromethyl)- phenyl]-4(1H)-pyridinone. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of fluridone include its use as an aquatic herbicide for control of most submerged and emerged aquatic plants (including Utricularia spp., Ceratophyllum demersum, Elodea canadensis, Myriophyllum spp., Najas guadalupensis, Potamogeton spp., Hydrilla verticillata and Panicum purpurascens) in ponds, lakes, reservoirs, irrigation ditches. CH 3 N Fluridone can be applied to vegetation or an area adjacent the vegetation or applied to water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, fluridone can be applied to water to prevent the emergence or growth of vegetation in an amount of 200 g ai/ha or more, such as 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, or 850 g ai/ha or more; in an amount of 900 g ai/ha or less, such as 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, or 220 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 200-900 g ai/ha, 280-750 g ai/ha, 250–800 g ai/ha, 450–600 g ai/ha, 350–700 g ai/ha, 250–650 g ai/ha, 400–700 g ai/ha, or 220–900 g ai/ha. Flurochloridone In some aspects, the PDS inhibitor herbicide can comprise flurochloridone or an agriculturally acceptable salt or ester thereof. Flurochloridone, shown below, is 3-chloro-4- (chloromethyl)-1-[3-(trifluoromethyl)phenyl]-2-pyrrolidinone . Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of flurochloridone include its use for pre-emergence control of a wide range of broadleaf and grass weeds in sunflowers, carrots and other umbelliferous crops, winter wheat, winter rye, and potatoes. Flurochloridone can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, flurochloridone is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 200 g ai/ha or more, such as 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, or 850 g ai/ha or more; in an amount of 900 g ai/ha or less, such as 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, or 220 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 200-900 g ai/ha, 220- 750 g ai/ha, 250–800 g ai/ha, 450–900 g ai/ha, 350–700 g ai/ha, 250–600 g ai/ha, 400–700 g ai/ha, or 500–900 g ai/ha. Flurtamone In some aspects, the PDS inhibitor herbicide can comprise flurtamone or an agriculturally acceptable salt or ester thereof. Flurtamone, shown below, is (±)-5- (methylamino)-2-phenyl-4-[3-(trifluoromethyl)phenyl]-3(2H)-f uranone. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of flurtamone include its use for pre-plant incorporated, pre-emergence or post emergence control of broadleaf and some grass weeds in small grains, peanuts, cotton, peas and sunflowers. Flurtamone can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, flurtamone is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 40 g ai/ha or more, such as 42.5 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more,160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 255 g ai/ha or more, 260 g ai/ha or more, 265 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 285 g ai/ha or more, 290 g ai/ha or more, 295 g ai/ha or more, 300 g ai/ha or more, 305 g ai/ha or more, 310 g ai/ha or more, 315 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 335 g ai/ha or more, 340 g ai/ha or more, 345 g ai/ha or more, 350 g ai/ha or more, 355 g ai/ha or more, 360 g ai/ha or more, 365 g ai/ha or more, or 370 g ai/ha or more; in an amount of 375 g ai/ha or less, such as 370 g ai/ha or less, 365 g ai/ha or less, 360 g ai/ha or less, 355 g ai/ha or less, 350 g ai/ha or less, 345 g ai/ha or less, 340 g ai/ha or less, 335 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 315 g ai/ha or less, 310 g ai/ha or less, 305 g ai/ha or less, 300 g ai/ha or less, 295 g ai/ha or less, 290 g ai/ha or less, 285 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 265 g ai/ha or less, 260 g ai/ha or less, or 255 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, or 42.5 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 40–375 g ai/ha, 125–355 g ai/ha, 60–335 g ai/ha, 80–300 g ai/ha, 265–375 g ai/ha, 170–325 g ai/ha, 45–300 g ai/ha, 190–375 g ai/ha, 120–295 g ai/ha, 180–355 g ai/ha, 220–335 g ai/ha, or 42.5–325 g ai/ha. Norflurazon In some aspects, the PDS inhibitor herbicide can comprise norflurazon or an agriculturally acceptable salt or ester thereof. Norflurazon, shown below, is 4-chloro-5- (methylamino)-2-[3-(trifluoromethyl)phenyl]-3(2H)-pyridazino ne. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of norflurazon include its use for pre-emergence control of grasses and sedges, including Digitaria spp. (crabgrasses), Echinochloa spp. (barnyard grasses), Setaria spp. (foxtails) and Eleocharis acicularis (spikerush), as well as broadleaf weeds, such as Sida spinosa (prickly sida), Portulaca oleracea (purslane), Salsola spp. (Russian thistle), and Capsella bursa- pastoris (shepherd’s purse), in cotton, soybeans, peanuts, hops, orchards, ornamentals, and industrial areas. Norflurazon can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, norflurazon is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 500 g ai/ha or more, such as 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, 2240 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2350 g ai/ha or more, 2400 g ai/ha or more, 2450 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2750 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3750 g ai/ha or more, 3800 g ai/ha or more, 3900 g ai/ha or more, or 3950 g ai/ha or more; in an amount of 4000 g ai/ha or less, such as 3950 g ai/ha or less, 3900 g ai/ha or less, 3800 g ai/ha or less, 3750 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2750 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2450 g ai/ha or less, 2400 g ai/ha or less, 2350 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2240 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1240 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, or 550 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 500–4000 g ai/ha, 600–3600 g ai/ha, 1250–3000 g ai/ha, 2000–4000 g ai/ha, 1700–3250 g ai/ha, 2800–3950 g ai/ha, or 1000–3700 g ai/ha. Picolinafen In some aspects, the PDS inhibitor herbicide can comprise picolinafen or an agriculturally acceptable salt or ester thereof. Picolinafen, shown below, is N-(4- fluorophenyl)-6-[3-(trifluoromethyl)phenoxy]-2-pyridinecarbo xamide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of picolinafen include its use as a post-emergence herbicide either alone or in mixtures for broad- spectrum weed control in cereals. Picolinafen can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, picolinafen is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 12.5 g ai/ha or more, such as 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 22.5 g ai/ha or more, 25 g ai/ha or more, 27.5 g ai/ha or more, 30 g ai/ha or more, 32.5 g ai/ha or more, 35 g ai/ha or more, 37.5 g ai/ha or more, 40 g ai/ha or more, 42.5 g ai/ha or more, 45 g ai/ha or more, 47.5 g ai/ha or more, 50 g ai/ha or more, 52.5 g ai/ha or more, 55 g ai/ha or more, 57.5 g ai/ha or more, 60 g ai/ha or more, 62.5 g ai/ha or more, 65 g ai/ha or more, 67.5 g ai/ha or more, 70 g ai/ha or more, 72.5 g ai/ha or more, 75 g ai/ha or more, 77.5 g ai/ha or more, 80 g ai/ha or more, 82.5 g ai/ha or more, 85 g ai/ha or more, 87.5 g ai/ha or more, 90 g ai/ha or more, 92.5 g ai/ha or more, 95 g ai/ha or more, or 97.5 g ai/ha or more; in an amount of 100 g ai/ha or less, such as 95 g ai/ha or less, 92.5 g ai/ha or less, 90 g ai/ha or less, 87.5 g ai/ha or less, 85 g ai/ha or less, 82.5 g ai/ha or less, 80 g ai/ha or less, 77.5 g ai/ha or less, 75 g ai/ha or less, 72.5 g ai/ha or less, 70 g ai/ha or less, 67.5 g ai/ha or less, 65 g ai/ha or less, 62.5 g ai/ha or less, 60 g ai/ha or less, 57.5 g ai/ha or less, 55 g ai/ha or less, 52.5 g ai/ha or less, 50 g ai/ha or less, 47.5 g ai/ha or less, 45 g ai/ha or less, 42.5 g ai/ha or less, 40 g ai/ha or less, 37.5 g ai/ha or less, 35 g ai/ha or less, 32.5 g ai/ha or less, 30 g ai/ha or less, 27.5 g ai/ha or less, 25 g ai/ha or less, 22.5 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 12.5–100 g ai/ha, 15–90 g ai/ha, 20–80 g ai/ha, 25– 75 g ai/ha, 25–95 g ai/ha, 25–80 g ai/ha, 30–75 g ai/ha, 35–90 g ai/ha, 40–95 g ai/ha, 40–75 g ai/ha, 45–95 g ai/ha, 45–90 g ai/ha, 50–80 g ai/ha, or 50–75 g ai/ha. GLYPHOSATE AND GLUFOSINATE In addition to the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), the compositions can include glyphosate, glufosinate, an agriculturally acceptable salt thereof, or mixtures thereof. Glyphosate In some aspects, compositions and methods of the present disclosure can include glyphosate or an agriculturally acceptable salt thereof. Glyphosate, as well as methods of preparing glyphosate, are known in the art. Glyphosate, shown below, is N- (phosphonomethyl)glycine. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of glyphosate include its use for control of annual and perennial grasses and broadleaf weeds, particularly in crops that have been genetically modified to be tolerant of glyphosate. Exemplary chemical forms of glyphosate include, but are not limited to, for example, glyphosate potassium salt, glyphosate sodium salt, glyphosate monoammonium salt, glyphosate diammonium salt, glyphosate isopropylamine (IPA) salt, glyphosate monoethanolamine (MEA) salt, glyphosate monomethylamine (MMA) salt, and glyphosate dimethylamine (DMA) salt. As used herein, glyphosate salt or salt of glyphosate generally refers to the reaction product of glyphosate with a moiety that can act as a base. Typically, the reaction is an acid-base reaction. Glyphosate can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, glyphosate is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 25 g ai/ha or more, such as 30 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 105 g ai/ha or more, 110 g ai/ha or more, 115 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 135 g ai/ha or more, 140 g ai/ha or more, 145 g ai/ha or more, 150 g ai/ha or more, 155 g ai/ha or more, 160 g ai/ha or more, 165 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 500 g ai/ha or more, 600 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 900 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3800 g ai/ha or more, 3900 g ai/ha or more, 4000 g ai/ha or more, 4100 g ai/ha or more, 4200 g ai/ha or more, or 4250 g ai/ha or more, in an amount of 4300 g ai/ha or less, such as 4250 g ai/ha or less, 4200 g ai/ha or less, 4100 g ai/ha or less, 4000 g ai/ha or less, 3900 g ai/ha or less, 3800 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 900 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 600 g ai/ha or less, 500 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 165 g ai/ha or less, 160 g ai/ha or less, 155 g ai/ha or less, 150 g ai/ha or less, 145 g ai/ha or less, 140 g ai/ha or less, 135 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 115 g ai/ha or less, 110 g ai/ha or less, 105 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, or 30 g ai/ha or less, in an amount within any range defined between any pair of the preceding values, such as 25–4300 g ai/ha, such as 50–1800 g ai/ha, 60–375 g ai/ha, 125–2500 g ai/ha, 170–1700 g ai/ha, 95–350 g ai/ha, 800–3800 g ai/ha, 185–4000 g ai/ha, 390–3700 g ai/ha, 100–420 g ai/ha, 1200–3300 g ai/ha, or 750–4250 g ai/ha. Glufosinate In some aspects, compositions and methods of the present disclosure can include glufosinate or an agriculturally acceptable salt thereof. Glufosinate, shown below, is 2-amino- 4-(hydroxy(methyl)phosphinyl)butanoic acid. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of glufosinate include its use for control of annual and perennial grasses and broadleaf weeds, particularly in crops that have been genetically modified to be tolerant of glufosinate. An exemplary salt of glufosinate is glufosinate-ammonium, which is also known as 2-amino-4-(hydroxy(methyl)phosphinyl)butanoic acid ammonium salt, and which has the following structure: . Glufosinate-ammonium is registered for controlling a wide variety of broad-leaved weeds and grasses particularly in glufosinate-tolerant crops like canola, maize, soybean, rice, cotton, and sugar beet. As used herein, glufosinate salt or salt of glufosinate generally refers to the reaction product of glufosinate with a moiety that can act as a base. Typically, the reaction is an acid-base reaction. Other chemical forms of glufosinate include bilanafos, also known as bialaphos, which has the following structure: . Bilanafos also can be used in the salt form such as bilanafos sodium. Exemplary uses are described in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses include its use to control annual and perennial broadleaf weeds and grasses. Glufosinate can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, glufosinate is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 25 g ai/ha or more, such as 50 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 90 g ai/ha or more,100 g ai/ha or more, 112.5 g ai/ha or more, 125 g ai/ha or more, 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, or 2200 g ai/ha or more, in an amount of 2250 g ai/ha or less (e.g., 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, 125 g ai/ha or less, 112.5 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, or 50 g ai/ha or less, or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as in an amount of 25–2250 g ai/ha, such as 50–900 g ai/ha, 70–1800 g ai/ha, 125–475 g ai/ha, 112.5–1600 g ai/ha, 200–1300 g ai/ha, 350–2150 g ai/ha, 275–1900 g ai/ha, 400–1400 g ai/ha, 450–750 g ai/ha, 475–1100 g ai/ha, 500–2200 g ai/ha, or 650–1700 g ai/ha). PHOTOSYSTEM II INHIBITOR HERBICIDES In addition to the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), the compositions can include a photosystem II (PS II) inhibitor herbicide or agriculturally acceptable salt or ester thereof. Photosystem II inhibitors inhibit photosynthesis by binding to the photosystem II complex in the chloroplast. Examples of photosystem II inhibitors include phenylcarbamate herbicides, pyridazinone herbicides, triazolinone herbicides, triazine herbicides, urea herbicides, uracil herbicides, amide herbicides, nitrile herbicides, and phenylpyridazine herbicides. In some aspects, the composition can include a PS II inhibitor herbicide selected from the group consisting of ametryne, amicarbazone, atrazine, bentazone, bromacil, bromofenoxim, bromoxynil, chlorbromuron, chloridazon, chlorotoluron, chloroxuron, cyanazine, desmedipham, desmetryn, dimefuron, dimethametryn, diuron, ethidimuron, ethiozin, fenuron, fluometuron, hexazinone, iodobonil, ioxynil, isocil, isomethiozin, isoproturon, isouron, karbutilate, lenacil, linuron, metamitron, methabenzthiazuron, metobromuron, metoxuron, metribuzin, monolinuron, neburon, pentanochlor, phenmedipham, prometon, prometryn, propanil, propazine, pyridafol, pyridate, siduron, simazine, simetryne, tebuthiuron, terbacil, terbumeton, terbuthylazine, terbutryn, trietazine, and combinations thereof. The PS II inhibitor herbicide or agriculturally acceptable salt or ester thereof can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, the PS II inhibitor herbicide or agriculturally acceptable salt or ester thereof is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 5 grams active ingredient per hectare (g ai/ha) or more, such as 10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3800 g ai/ha or more, 3900 g ai/ha or more, 4000 g ai/ha or more, 5000 g ail/ha or more, 6000 g ai/ha or more, 7000 g ail/ha or more, 8000 g ai/ha or more, 9000 g ail/ha or more, 10,000 g ai/ha or more, 12,000 g ail/ha or more, 14,000 g ai/ha or more, 15,000 g ail/ha or more, 16000 g ai/ha or more, or 17,000 g ail/ha or more; in an amount of 18,000 g ai/ha or less, such as 17,000 g ai/ha or less, 16,000 g ai/ha or less, 15,000 g ai/ha or less, 14,000 g ai/ha or less, 12,000 g ai/ha or less, 10,000 g ai/ha or less, 9000 g ai/ha or less, 8000 g ai/ha or less, 7000 g ai/ha or less, 6000 g ai/ha or less, 5000 g ai/ha or less, 4000 g ai/ha or less, 3900 g ai/ha or less, 3800 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, or 10 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 5– 4000 g ai/ha, 5–3000 g ai/ha, 3000–4000 g ai/ha, 5–2900 g ai/ha, 5–2800 g ai/ha, 5–2700 g ai/ha, 5–2600 g ai/ha, 5–2500 g ai/ha, 5–2400 g ai/ha, 5–2300 g ai/ha, 5–2200 g ai/ha, 5–2100 g ai/ha, 5–2000 g ai/ha, 5–1800 g ai/ha, 5–1600 g ai/ha, 5–1400 g ai/ha, 5–1200 g ai/ha, 5– 1000 g ai/ha, 5–900 g ai/ha, 5–800 g ai/ha, 5–700 g ai/ha, 5–600 g ai/ha, 5–500 g ai/ha, 10– 4000 g ai/ha, 10–3000 g ai/ha, 10–2000 g ai/ha, 20–4000 g ai/ha, 20–3000 g ai/ha, 20–2000 g ai/ha, 20–1500 g ai/ha, 30–4000 g ai/ha, 30–3000 g ai/ha, 30–2000 g ai/ha, 50–4000 g ai/ha, 50–3000 g ai/ha, 50–2000 g ai/ha, 50–1500 g ai/ha, 70–4000 g ai/ha, 70–3000 g ai/ha, 70–2500 g ai/ha, 70–2000 g ai/ha, 70–1500 g ai/ha, 100–3000 g ai/ha, 100–2500 g ai/ha, or 100–2000 g ai/ha. In some aspects, the photosystem II inhibitor or agriculturally acceptable salt or ester thereof is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of from 30-1000 g ai/ha. In some aspects, the composition contains compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and (b) ametryne, amicarbazone, atrazine, bentazone, bromacil, bromofenoxim, bromoxynil, chlorbromuron, chloridazon, chlorotoluron, chloroxuron, cyanazine, desmedipham, desmetryn, dimefuron, dimethametryn, diuron, ethidimuron, ethiozin, fenuron, fluometuron, hexazinone, iodobonil, ioxynil, isocil, isomethiozin, isoproturon, isouron, karbutilate, lenacil, linuron, metamitron, methabenzthiazuron, methoprotryne, metobromuron, metoxuron, metribuzin, monolinuron, neburon, pentanochlor, phenmedipham, prometon, prometryn, propanil, propazine, pyridafol, pyridate, siduron, simazine, simetryne, tebuthiuron, terbacil, terbumeton, terbuthylazine, terbutryn, trietazine, or mixtures thereof. Ametryn In some aspects, the PS II inhibitor herbicide can comprise ametryn or an agriculturally acceptable salt or ester thereof. Ametryn, shown below, is N 2 -ethyl-N 4 - isopropyl-6-(methylthio)-1,3,4-triazine-2,4-diamine. Its herbicidal activity is exemplified in Tomlin, C. D. S., Ed. The Pesticide Manual: A World Compendium, 17 th ed.; BCPC: Alton, 2016 (hereafter “The Pesticide Manual, Seventeenth Edition, 2016”). Exemplary uses of ametryn include its use for pre- and early post-emergence control of annual grass and broadleaf weeds in pineapples, sugar cane, maize, bananas, cassava, sisal, and orchards. Ametryn can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, ametryn is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2000 g ai/ha or more, such as 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3800 g ai/ha or more, or 3900 g ai/ha or more; in an amount of 4000 g ai/ha or less, such as 3900 g ai/ha or less, 3800 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, or 2100 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2000-4000 g ai/ha, 2100–2500 g ai/ha, 2600-3700 g ai/ha, 2500–4000 g ai/ha, 2900–3600 g ai/ha, 3200–3800 g ai/ha, 2300–3700 g ai/ha, or 2200–3900 g ai/ha. Amicarbazone In some aspects, the PDS inhibitor herbicide can comprise amicarbazone or an agriculturally acceptable salt or ester thereof. Amicarbazone, shown below, is 4-amino-N-tert- butyl-4,5-dihydro-3-isopropyl-5-oxo-1H-1,2,4-triazole-1-carb oxamide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of amicarbazone include its use for pre-emergence control of annual broadleaf weeds in maize, pre- and post-emergence control of annual broadleaf and grass weeds in sugar cane, and post- emergence control of annual broadleaf and grass weeds in turf, and conifers. Amicarbazone can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, amicarbazone is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 100 g ai/ha or more, such as 105 g ai/ha or more, 110 g ai/ha or more, 115 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 135 g ai/ha or more, 140 g ai/ha or more, 145 g ai/ha or more, 150 g ai/ha or more, 155 g ai/ha or more, 160 g ai/ha or more, 165 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 185 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, or 975 g ai/ha or more; in an amount of 1000 g ai/ha or less, such as 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less,185 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 165 g ai/ha or less, 160 g ai/ha or less, 155 g ai/ha or less, 150 g ai/ha or less, 145 g ai/ha or less, 140 g ai/ha or less, 135 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 115 g ai/ha or less, 110 g ai/ha or less, or 105 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 100–1000 g ai/ha, 125–750 g ai/ha, 160–675 g ai/ha, 220–850 g ai/ha, 370–900 g ai/ha, 275–650 g ai/ha, 480–800 g ai/ha, 340–900 g ai/ha, 520–925 g ai/ha, 290–560 g ai/ha, 390– 825 g ai/ha, or 105–975 g ai/ha. Atrazine In some aspects, the PDS inhibitor herbicide can comprise atrazine or an agriculturally acceptable salt or ester thereof. Atrazine, shown below, is 6-chloro-N 2 -ethyl-N 4 - isopropyl-1,3,5-triazine-2,4-diamine. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of atrazine include its use as a pre- and post-emergence control of annual broadleaf and grass weeds in maize, sorghum, sugar cane, pineapples, chemical fallow, grassland, macadamia nuts, conifers, and industrial weed control. Atrazine can be applied to vegetation or an area adjacent the vegetation or applied to water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, atrazine can be applied to water to prevent the emergence or growth of vegetation in an amount of 300 g ai/ha or more, such as 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3800 g ai/ha or more, or 3900 g ai/ha or more; in an amount of 4000 g ai/ha or less, such as 3900 g ai/ha or less, 3800 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, or 320 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 300-4000 g ai/ha, 480-2700 g ai/ha, 850– 3800 g ai/ha, 600–2600 g ai/ha, 1300–3100 g ai/ha, 1500–3000 g ai/ha, 2400–3700 g ai/ha, or 340–3900 g ai/ha. Bentazone In some aspects, the PDS inhibitor herbicide can comprise bentazone or an agriculturally acceptable salt or ester thereof. Bentazone, shown below, is 3-isopropyl-1H- 2,1,3-benzothiadiazin-4(3H)-one 2,2-dioxide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of bentazone include its use for post-emergence control of broadleaf weeds in winter and spring cereals, peanuts, maize, peas, beans, rice, and soybeans. Bentazone can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, bentazone is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 100 g ai/ha or more, 150 g ai/ha or more, 200 g ai/ha or more, 250 g ai/ha or more, 300 g ai/ha or more, 350 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, or 2100 g ai/ha or more; in an amount of 2200 g ai/ha or less, such as 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 350 g ai/ha or less, 300 g ai/ha or less, 250 g ai/ha or less, 200 g ai/ha or less, 150 g ai/ha or less, or 100 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50-2200 g ai/ha, 100-1700 g ai/ha, 300–1800 g ai/ha, 150–1900 g ai/ha, 450–2100 g ai/ha, 250–1600 g ai/ha, 700–1900 g ai/ha, or 100–2100 g ai/ha. Bromacil In some aspects, the PDS inhibitor herbicide can comprise bromacil or an agriculturally acceptable salt or ester thereof. Bromacil, shown below, is 5-bromo-3-sec-butyl- 6-methyluracil. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of bromacil include its use for pre- and post-emergence control of broadleaf and grass weeds in citrus, pineapple, and total weed and brush control in non-crop lands. Bromacil can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, bromacil is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1500 g ai/ha or more, such as 1600 g ai/ha or more, 1750 g ai/ha or more, 2000 g ai/ha or more, 2250 g ai/ha or more, 2500 g ai/ha or more, 2750 g ai/ha or more, 3000 g ai/ha or more, 3500 g ai/ha or more, 4000 g ai/ha or more, 4500 g ai/ha or more, 5000 g ai/ha or more, 6000 g ai/ha or more, 7000 g ai/ha or more, 7500 g ai/ha or more, 8000 g ai/ha or more, 9000 g ai/ha or more, 10,000 g ai/ha or more, 11,000 g ai/ha or more, 12,000 g ai/ha or more, 13,000 g ai/ha or more, 14,000 g ai/ha or more, or 14,500 g ai/ha or more; in an amount of 15,000 g ai/ha or less, such as 14,500 g ai/ha or less, 14,000 g ai/ha or less, 13,000 g ai/ha or less, 12,000 g ai/ha or less, 11,000 g ai/ha or less, 10,000 g ai/ha or less, 9000 g ai/ha or less, 8000 g ai/ha or less, 7500 g ai/ha or less, 7000 g ai/ha or less, 6000 g ai/ha or less, 5000 g ai/ha or less, 4500 g ai/ha or less, 4000 g ai/ha or less, 3500 g ai/ha or less, 3000 g ai/ha or less, 2750 g ai/ha or less, 2500 g ai/ha or less, 2250 g ai/ha or less, 2000 g ai/ha or less, 1750 g ai/ha or less, or 1600 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1500-15,000 g ai/ha, 2500– 13,000 g ai/ha, 6000–9000 g ai/ha, 8000–14,000 g ai/ha, 4500–11,000 g ai/ha, 2750–7500 g ai/ha, 3000–12,000 g ai/ha, 7000–10,000 g ai/ha, 4000–12,000 g ai/ha, or 1600–14,500 g ai/ha. Bromofenoxim In some aspects, the PDS inhibitor herbicide can comprise bromofenoxim or an agriculturally acceptable salt or ester thereof. Bromofenoxim, shown below, is 3,5-dibromo- 4-hydroxybenzaldehyde 2,4-dinitrophenyloxime. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of bromofenoxim include its use for post-emergence control of many annual broadleaf weeds in cereals, maize, grass-seed crops, grassland, and new-seeded turf. Bromofenoxim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, bromofenoxim is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1000 g ai/ha or more, such as 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more,1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more,1400 g ai/ha or more, 1450 g ai/ha or more,1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more,1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more,2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, or 2250 g ai/ha or more; in an amount of 2300 g ai/ha or less such as 2250 g ai/ha or less, 2240 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1240 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, or 1050 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1000–2300 g ai/ha, 1200–1600 g ai/ha, 1450–2100 g ai/ha, 1100–1900 g ai/ha, 1700–2200 g ai/ha, 1300–2050 g ai/ha, or 1050–2200 g ai/ha. Bromoxynil In some aspects, the PDS inhibitor herbicide can comprise bromoxynil or an agriculturally acceptable salt or ester thereof. Bromoxynil, shown below, is 3,5-dibromo-4- hydroxbenzonitrile. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of bromoxynil include its use as in post-emergence control of annual broadleaf weeds in cereals, ryegrass seed crops, turf and non-crop land, maize, and sorghum. Bromoxynil can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, bromoxynil is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, or 490 g ai/ha or more; in an amount of 500 g ai/ha or less, such as 490 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, or 55 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–500 g ai/ha. 80–490 g ai/ha, 60–380 g ai/ha, 200–440 g ai/ha, 130–370 g ai/ha, 260–490 g ai/ha, 320–500 g ai/ha, 400–480 g ai/ha, 240–460 g ai/ha, or 55–490 g ai/ha. Chlorbromuron In some aspects, the PS-II inhibitor herbicide can comprise chlorbromuron or an agriculturally acceptable salt or ester thereof. Chlorbromuron, shown below, is 3-(4-bromo-3- chlorophenyl)-1-methoxy-1-methylurea. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of chlorbromuron include pre-emergence use on carrots, peas, potatoes, soybeans, and sunflowers. Chlorbromuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, chlorbromuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1000 g ai/ha or more, such as 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, or 2450 g ai/ha or more; in an amount of 2500 g ai/ha or less, such as 2450 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, or 1100 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1000-2500 g ai/ha, 1300-2100 g ai/ha, 1200–1900 g ai/ha, 1500–2400 g ai/ha, 1100–2200 g ai/ha, 1200–2500 g ai/ha, 1600–2300 g ai/ha, or 1100–2450 g ai/ha. Chloridazon In some aspects, the PS-II inhibitor herbicide can comprise chloridazon or an agriculturally acceptable salt or ester thereof. Chloridazon, shown below, is 5-amino-4-chloro- 2-phenylpyridazin-3(2H)-one. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of chloridazon include its use for pre- and post- emergence or pre-plant control of annual broadleaf weeds in sugar beets, fodder beets, and beetroot. Chloridazon can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, chloridazon is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1300 g ai/ha or more, such as 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1550 g ai/ha or more, 1600 g ai/ha or more, 1650 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more, 1800 g ai/ha or more, 1850 g ai/ha or more, 1900 g ai/ha or more, 1950 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, 2240 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2350 g ai/ha or more, 2400 g ai/ha or more, 2450 g ai/ha or more, 2500 g ai/ha or more, 2550 g ai/ha or more, 2600 g ai/ha or more, 2650 g ai/ha or more, 2700 g ai/ha or more, 2750 g ai/ha or more, 2800 g ai/ha or more, 2850 g ai/ha or more, 2900 g ai/ha or more, 2950 g ai/ha or more, 3000 g ai/ha or more, 3050 g ai/ha or more, 3100 g ai/ha or more, 3150 g ai/ha or more, or 3200 g ai/ha or more; in an amount of 3250 g ai/ha or less, such as 3200 g ai/ha or less, 3150 g ai/ha or less, 3100 g ai/ha or less, 3050 g ai/ha or less, 3000 g ai/ha or less, 2950 g ai/ha or less, 2900 g ai/ha or less, 2850 g ai/ha or less, 2800 g ai/ha or less, 2750 g ai/ha or less, 2700 g ai/ha or less, 2650 g ai/ha or less, 2600 g ai/ha or less, 2550 g ai/ha or less, 2500 g ai/ha or less, 2450 g ai/ha or less, 2400 g ai/ha or less, 2350 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1950 g ai/ha or less, 1900 g ai/ha or less, 1850 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1650 g ai/ha or less, 1600 g ai/ha or less, 1550 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, or 1350 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1300-3250 g ai/ha, 1500–2450 g ai/ha, 1400-2800 g ai/ha, 2050–3100 g ai/ha, 1900–2950 g ai/ha, 2000–2600 g ai/ha, 2400–3000 g ai/ha, 2250–3050 g ai/ha, or 1350–3200 g ai/ha. Chlorotoluron In some aspects, the PS-II inhibitor herbicide can comprise chlorotoluron or an agriculturally acceptable salt or ester thereof. Chlorotoluron, shown below, is 3-(3-chloro-p- tolyl)-1,1-dimethylurea. Its herbicidal activity is exemplified in the online edition of The Pesticide Manual. Exemplary uses of chlorotoluron include its use for pre- and post- emergence control of many broadleaf and grass weeds in winter cereals. Chlorotoluron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, chlorotoluron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1500 g ai/ha or more, such as 1550 g ai/ha or more, 1600 g ai/ha or more, 1650 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more, 1800 g ai/ha or more, 1850 g ai/ha or more, 1900 g ai/ha or more, 1950 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, 2240 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2350 g ai/ha or more, 2400 g ai/ha or more, 2450 g ai/ha or more, 2500 g ai/ha or more, 2550 g ai/ha or more, 2600 g ai/ha or more, 2650 g ai/ha or more, 2700 g ai/ha or more, 2750 g ai/ha or more, 2800 g ai/ha or more, 2850 g ai/ha or more, 2900 g ai/ha or more, or 2950 g ai/ha or more; in an amount of 3000 g ai/ha or less, such as 2950 g ai/ha or less, 2900 g ai/ha or less, 2850 g ai/ha or less, 2800 g ai/ha or less, 2750 g ai/ha or less, 2700 g ai/ha or less, 2650 g ai/ha or less, 2600 g ai/ha or less, 2550 g ai/ha or less, 2500 g ai/ha or less, 2450 g ai/ha or less, 2400 g ai/ha or less, 2350 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1950 g ai/ha or less, 1900 g ai/ha or less, 1850 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1650 g ai/ha or less, 1600 g ai/ha or less, or 1550 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1500-3000 g ai/ha, 1650–2750 g ai/ha, 1700-2300 g ai/ha, 2100–2800 g ai/ha, 2050–2600 g ai/ha, 2200–2950 g ai/ha, 1850–2400 g ai/ha, or 1550–2950 g ai/ha. Chloroxuron In some aspects, the PS-II inhibitor herbicide can comprise chloroxuron or an agriculturally acceptable salt or ester thereof. Chloroxuron, shown below, is 3-[4-(4- chlorophenoxy)phenyl]-1,1-dimethylurea. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of chloroxuron include its use for pre- and post-emergence control of annual broadleaf weeds and some grasses in peas, beans, carrots, celery, celeriac, onions, leeks, garlic, chives, fennel, parsley, dill, tomatoes, cucurbits, soybeans, strawberries, fruit trees, ornamentals, and conifers, and control of mosses in ornamental and sports turf, on paths and non-crop lands, and in glass houses. Chloroxuron may be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount from 1 kg/ha to 4 kg/ha. Cyanazine In some aspects, the PS-II inhibitor herbicide can comprise cyanazine or an agriculturally acceptable salt or ester thereof. Cyanazine is 2-(4-chloro-6-(ethylamino)-1,3,5- triazin-2-ylamino)-2-methylpropiononitrile. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of cyanazine include its use for pre- or post-emergence control of grass and broadleaf weeds in broad beans, maize, peas, barley, wheat, cotton, oilseed rape, forestry, potatoes, soybeans, and sugar cane. Cyanazine can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, cyanazine is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 250 g ai/ha or more, such as 260 g ai/ha or more, 270 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, or 2900 g ai/ha or more; in an amount of 3000 g ai/ha or less, such as 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, or 260 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 250-3000 g ai/ha, 625-1400 g ai/ha, 390–2300 g ai/ha, 1100–2100 g ai/ha, 1300–2700 g ai/ha, 1000-1900 g ai/ha, or 260–2900 g ai/ha. Desmedipham In some aspects, the PS-II inhibitor herbicide can comprise desmedipham or an agriculturally acceptable salt or ester thereof. Desmedipham, shown below, is 3- ethoxycarbonylaminophenyl phenylcarbamate. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of desmedipham include its use in post-emergence control of broadleaf weeds in beets. Desmedipham can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, desmedipham is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 300 g ai/ha or more, such as 310 g ai/ha or more, 320 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more,575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, or 1200 g ai/ha or more; in an amount of 1250 g ai/ha or less, such as 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 320 g ai/ha or less, or 310 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 300-1250 g ai/ha, 340–850 g ai/ha, 370-600 g ai/ha, 410–1050 g ai/ha, 440–900 g ai/ha, 450–750 g ai/ha, 500– 1150 g ai/ha, 600–1200 g ai/ha, 350–950 g ai/ha, or 310-1200 g ai/ha. Desmetryn In some aspects, the PS-II inhibitor herbicide can comprise desmetryn or an agriculturally acceptable salt or ester thereof. Desmetryn, shown below, is N 2 -isopropyl-N 4 - methyl-6-methylthio-1,3,5-triazine-2,4-diamine. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of desmetryn include its use for pre-emergence control of fat-hen and other annual broadleaf weeds and some grasses in brassicas (except cauliflower and broccoli), herbs, onions, leeks, and conifer seedbeds. Desmetryn can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, desmetryn is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 200 g ai/ha or more, such as 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 550 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, or 625 g ai/ha or more; in an amount of 650 g ai/ha or less, such as 625 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 550 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, or 210 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 200- 650 g ai/ha, 220–540 g ai/ha, 260-380 g ai/ha, 250–450 g ai/ha, 300–600 g ai/ha, 440–580 g ai/ha, or 210–625 g ai/ha. Dimefuron In some aspects, the PS-II inhibitor herbicide can comprise dimefuron or an agriculturally acceptable salt or ester thereof. Dimefuron, shown below, is 3-[4-(5-tert-butyl- 2,3-dihydro-2-oxo-1,3,4-oxadiazol-3-yl)-3-chlorophenyl]-1,1- dimethylurea. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Dimefuron is used for pre- and post-emergence control of difficult annual broadleaf weeds (e.g., Stellaria media, Chamomilla, and Matricaria spp.) in beans, certain cereals, cotton, peanuts, dormant alfalfa, oilseed rape, and peas. Dimefuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, dimefuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 200 g ai/ha or more, such as 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, or 1900 g ai/ha or more; in an amount of 2000 g ai/ha or less, such as 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, or 225 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 200-2000 g ai/ha, 350–1800 g ai/ha, 425–1600 g ai/ha, 575–1100 g ai/ha, 400–1700 g ai/ha, 600–925 g ai/ha, or 225–1900 g ai/ha. Dimethametryn In some aspects, the PS-II inhibitor herbicide can comprise dimethametryn or an agriculturally acceptable salt or ester thereof. Dimethametryn, shown below, is (RS)-N 2 -(1,2- dimethylpropyl)-N 4 -ethyl-6-(methylthio)-1,3,5-triazine-2,4-diamine. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of dimethametryn include its use in control of annual broadleaf weeds in rice. Dimethametryn can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, dimethametryn is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, or 145 g ai/ha or more; in an amount of 150 g ai/ha or less, such as 145 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, or 55 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50-150 g ai/ha, 60–120 g ai/ha, 55-95 g ai/ha, 85-140 g ai/ha, 65-120 g ai/ha, 55-110 g ai/ha, 70-130 g ai/ha, or 55–145 g ai/ha. Diuron In some aspects, the PS-II inhibitor herbicide can comprise diuron or an agriculturally acceptable salt or ester thereof. Diuron, shown below, is 3-(3,4-dichlorophenyl)- 1,1-dimethylurea. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Diuron provides pre- and early post-emergence control of germinating grasses and broadleaf weeds in asparagus, tree fruit, bush fruit, citrus, vines, olives, pineapples, bananas, sugar cane, cotton, peppermint, alfalfa, forage legumes, cereals, maize, sorghum, and perennial grass seed crops, as well as total control of weeds and mosses in non-crop areas. Diuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, diuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 600 g ai/ha or more, such as 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3800 g ai/ha or more, 3900 g ai/ha or more, 4000 g ai/ha or more, 4100 g ai/ha or more, 4200 g ai/ha or more, 4300 g ai/ha or more, 4400 g ai/ha or more, 4500 g ai/ha or more, 4600 g ai/ha or more, 4700 g ai/ha or more, or 4750 g ai/ha or more; in an amount of 4800 g ai/ha or less, such as 4750 g ai/ha or less, 4700 g ai/ha or less, 4600 g ai/ha or less, 4500 g ai/ha or less, 4400 g ai/ha or less, 4300 g ai/ha or less, 4200 g ai/ha or less, 4100 g ai/ha or less, 4000 g ai/ha or less, 3900 g ai/ha or less, 3800 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, or 625 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 600–4800 g ai/ha, 700-3900 g ai/ha, 875– 2200 g ai/ha, 650–3100 g ai/ha, 950–2700 g ai/ha, 1500–2600 g ai/ha, 1300–3200 g ai/ha, 850– 4000 g ai/ha, 2500–4400 g ai/ha, 1400–3200 g ai/ha, or 625–4750 g ai/ha. Ethidimuron In some aspects, the PS-II inhibitor herbicide can comprise ethidimuron or an agriculturally acceptable salt or ester thereof. Ethidimuron, shown below, is 1-(5- ethylsulfonyl-1,3,4-thiadiazol-2-yl)-1,3-dimethylurea. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of ethidimuron include its use for total herbicidal control on uncultivated land and in sugar cane plantations. Ethidimuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, ethidimuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 4000 g ai/ha or more, such as 4250 g ai/ha or more, 4500 g ai/ha or more, 4750 g ai/ha or more, 5000 g ai/ha or more, 5250 g ai/ha or more, 5500 g ai/ha or more, 5750 g ai/ha or more, 6000 g ai/ha or more, 6250 g ai/ha or more, 6500 g ai/ha or more, 6750 g ai/ha or more, 7000 g ai/ha or more, or 7250 g ai/ha or more; in an amount of 7500 g ai/ha or less, such as 7250 g ai/ha or less, 7000 g ai/ha or less, 6750 g ai/ha or less, 6500 g ai/ha or less, 6250 g ai/ha or less, 6000 g ai/ha or less, 5750 g ai/ha or less, 5500 g ai/ha or less, 5250 g ai/ha or less, 5000 g ai/ha or less, 4750 g ai/ha or less, 4500 g ai/ha or less, or 4250 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 4000-7500 g ai/ha, 4500-6750 g ai/ha, 5250-6500 g ai/ha, 4250-5500 g ai/ha, 5000-7250 g ai/ha, 6250-7000 g ai/ha, 5500–7500 g ai/ha, or 4250– 7250 g ai/ha. Ethiozin In some aspects, the PS-II inhibitor herbicide can comprise ethiozin or an agriculturally acceptable salt or ester thereof. Ethiozin, shown below, is 4-amino-6-tert-butyl- 3-ethylthio-1,2,4-triazin-5(4H)-one. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of ethiozin include its use in pre- emergence control of grasses and some broadleaf weeds in cereals and tomatoes. Ethiozin can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, ethiozin is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 500 g ai/ha or more, such as 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, or 1700 g ai/ha or more; in an amount of 1750 g ai/ha or less, such as 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, or 525 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 500-1750 g ai/ha, 550–1500 g ai/ha, 625–1600 g ai/ha, 675–1100 g ai/ha, 700–1300 g ai/ha, 600–925 g ai/ha, or 525–1700 g ai/ha. Fenuron In some aspects, the PS-II inhibitor herbicide can comprise fenuron or an agriculturally acceptable salt or ester thereof. Fenuron, shown below, is 1,1-dimethyl-3- phenylurea. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of fenuron include its use in pre-emergence control of woody plants and perennial weeds in non-crop lands. Fluometuron In some aspects, the PS-II inhibitor herbicide can comprise fluometuron or an agriculturally acceptable salt or ester thereof. Fluometuron, shown below, is 1,1-dimethyl-3- (α,α,α-trifluoro-m-tolyl)-urea. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of fluometuron include its use in control of annual broadleaf and grass weeds in cotton and sugar cane. Fluometuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, fluometuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 800 g ai/ha or more, such as 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, or 1450 g ai/ha or more; in an amount of 1500 g ai/ha or less, such as 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, or 825 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 800-1500 g ai/ha, 950–1300 g ai/ha, 825–1150 g ai/ha, 975–1100 g ai/ha, 1000–1400 g ai/ha, 900–1350 g ai/ha, or 825–1450 g ai/ha. Hexazinone In some aspects, the PS-II inhibitor herbicide can comprise hexazinone or an agriculturally acceptable salt or ester thereof. Hexazinone, shown below, is 3-cyclohexyl-6- dimethylamino-1-methyl-1,3,5-triazine-2,4-(1H,3H)-dione. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of hexazinone include its use in post-emergence control of annual, biennial, and most perennial weeds in alfalfa, pineapples, sugar can, coniferous species, and non-crop areas at 6,000-12,000 g/ha. Iodobonil In some aspects, the PS-II inhibitor herbicide can comprise iodobonil or an agriculturally acceptable salt or ester thereof. Iodobonil, shown below, is 4-(allyloxy- carbonyloxy)-3,5-diiodobenzonitrile. Its chemical properties are given in The Pesticide Manual, Seventeenth Edition, 2016. Ioxynil In some aspects, the PS-II inhibitor herbicide can comprise ioxynil or an agriculturally acceptable salt or ester thereof. Ioxynil, shown below, is 4-hydroxy-3,5- diiodobenzonitrile. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of ioxynil include its use in post-emergence control of broadleaf weeds in cereals, onions, leeks, garlic, shallots, flax, sugar cane, forage grasses, lawns, and newly-sown turf. Ioxynil can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, ioxynil is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 300 g ai/ha or more, such as 310 g ai/ha or more, 320 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 550 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, or 625 g ai/ha or more; in an amount of 650 g ai/ha or less, such as 625 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 550 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 320 g ai/ha or less, or 310 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 300-650 g ai/ha, 320–540 g ai/ha, 360-580 g ai/ha, 350–450 g ai/ha, 310–520 g ai/ha, 440–600 g ai/ha, or 310–625 g ai/ha. Isocil In some aspects, the PS-II inhibitor herbicide can comprise isocil or an agriculturally acceptable salt or ester thereof. Isocil, shown below, is 3- ethoxycarbonylaminophenyl phenylcarbamate. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of isocil include its use as a total herbicide in control of perennial grasses and on non-cropped lands at 13-18 kg/ha. Isomethiozin In some aspects, the PS-II inhibitor herbicide can comprise isomethiozin or an agriculturally acceptable salt or ester thereof. Isomethiozin, shown below, is 6-tert-butyl-4- [(EZ)-isobutylideneamino]-3-methylthio-1,2,4-triazin-5(4H)-o ne. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of isomethiozin include its use in post-emergence control of areas with a heavy infestation of grass, and in winter wheat and spring cereals. Isoproturon In some aspects, the PS-II inhibitor herbicide can comprise isoproturon or an agriculturally acceptable salt or ester thereof. Isoproturon, shown below, is 3-(4- isopropylphenyl)-1,1-dimethylurea. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of isoproturon include its use in pre- and post-emergence control of annual grass weeds and many broadleaf weeds in spring and winter wheat (except durum wheat), spring and winter barley, winter rye, and triticale. Isoproturon can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, isoproturon is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 800 g ai/ha or more, such as 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, or 1450 g ai/ha or more; in an amount of 1500 g ai/ha or less, such as 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, or 825 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 800-1500 g ai/ha, 950–1300 g ai/ha, 825–1150 g ai/ha, 975–1100 g ai/ha, 1000–1400 g ai/ha, 900–1350 g ai/ha, or 825–1450 g ai/ha. Isouron In some aspects, the PS-II inhibitor herbicide can comprise isouron or an agriculturally acceptable salt or ester thereof. Isouron, shown below, is 3-(5-tert-butylisoxazol- 3-yl)-1,1-dimethylurea. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of isouron include its use in pre- and post- emergence control of broadleaf and grass weeds in sugar cane and pineapples. Isouron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, isouron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 400 g ai/ha or more, such as 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, or 1450 g ai/ha or more; in an amount of 1500 g ai/ha or less, such as 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, or 425 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 400-1500 g ai/ha, 450–1300 g ai/ha, 525–1150 g ai/ha, 475–1050 g ai/ha, 600–1400 g ai/ha, 750–1250 g ai/ha, or 425–1450 g ai/ha. Karbutilate In some aspects, the PS-II inhibitor herbicide can comprise karbutilate or an agriculturally acceptable salt or ester thereof. Karbutilate, shown below, is 3-(3,3- dimethylureido)phenyl tert-butylcarbamate. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of karbutilate include its use in control of annual and perennial broadleaf and grass weeds and woody species in non-crop areas at up to 12,000 g/ha. Lenacil In some aspects, the PS-II inhibitor herbicide can comprise lenacil or an agriculturally acceptable salt or ester thereof. Lenacil, shown below, is 3-cyclohexyl-1,5,6,7- tetrahydrocyclopentapyrimidine-2,4(3H)-dione. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of lenacil include its use in pre- plant and pre-emergence control of annual grass and broadleaf weeds in sugar beets, fodder beets, beetroot, sweet potatoes, spinach, strawberries, flax, black salsify, and ornamentals. Lenacil can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, lenacil is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 100 g ai/ha or more, such as 125 g ai/ha or more, 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, or 2600 g ai/ha or more; in an amount of 2700 g ai/ha or less, such as 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less,1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, or 125 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 100-2700 g ai/ha, 150–1800 g ai/ha, 225–2000 g ai/ha, 375–2300 g ai/ha, 400– 1700 g ai/ha, 600–925 g ai/ha, 900–1400 g ai/ha, 1300–2500 g ai/ha, or 125–2600 g ai/ha. Linuron In some aspects, the PS-II inhibitor herbicide can comprise linuron or an agriculturally acceptable salt or ester thereof. Linuron, shown below, is 3-(3,4- dichlorophenyl)-1-methoxy-1-methyurea. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of linuron include its use in pre- and post-emergence control of annual grass and broadleaf weeds in asparagus, artichokes, carrots, parsley, fennel, parsnips, herbs, celery, celeriac, onions, lees, garlic, potatoes, peas, field beans, soybeans, cereals, maize, sorghum, cotton, flax, sunflowers, sugar cane, ornamentals, established vines, bananas, cassava, coffee, tea, rice, peanuts, and other crops. Metamitron In some aspects, the PS-II inhibitor herbicide can comprise metamitron or an agriculturally acceptable salt or ester thereof. Metamitron, shown below, is 4-amino-3-methyl- 6-phenyl-1,2,4-triazin-5(4H)-one. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of metamitron include its use in pre- and post-emergence control or pre-plant control of broadleaf and grass weeds in sugar beets, fodder beets, red beets, chard, and some strawberry varieties. Metamitron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, metamitron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 300 g ai/ha or more, such as 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3800 g ai/ha or more, 3900 g ai/ha or more, 4000 g ai/ha or more, or 4100 g ai/ha or more; in an amount of 4200 g ai/ha or less, such as 4100 g ai/ha or less, 4000 g ai/ha or less, 3900 g ai/ha or less, 3800 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, or 325 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 300–4200 g ai/ha, 400-3900 g ai/ha, 375–2200 g ai/ha, 650–3100 g ai/ha, 950–2700 g ai/ha, 500–3300 g ai/ha, 1300–4000 g ai/ha, 850–3000 g ai/ha, 2100–3600 g ai/ha, 475–3200 g ai/ha, or 325–4100 g ai/ha. Methabenzthiazuron In some aspects, the PS-II inhibitor herbicide can comprise methabenzthiazuron or an agriculturally acceptable salt or ester thereof. Methabenzthiazuron, shown below, is 1-(1,3- benzothiazol-2-yl)-1,3-dimethylurea. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of methabenzthiazuron include its use in control of broadleaf and grass weeds in cereals, legumes, maize, garlic, and onions. Methabenzthiazuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, methabenzthiazuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1250 g ai/ha or more, such as 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1550 g ai/ha or more, 1600 g ai/ha or more, 1650 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more, 1800 g ai/ha or more, 1850 g ai/ha or more, 1900 g ai/ha or more, 1950 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, or 2700 g ai/ha or more, 2800 g ai/ha or more, or 2900 g ai/ha or more; in an amount of 3000 g ai/ha or less, such as 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1950 g ai/ha or less, 1900 g ai/ha or less, 1850 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less,1700 g ai/ha or less, 1650 g ai/ha or less, 1600 g ai/ha or less, 1550 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, or 1300 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1250-3000 g ai/ha, 1650-2400 g ai/ha, 1450–2300 g ai/ha, 1500–2100 g ai/ha, 1300–2700 g ai/ha, 1700-1900 g ai/ha, or 1300– 2900 g ai/ha. Methoprotryne In some aspects, the PS-II inhibitor herbicide can comprise methoprotryne or an agriculturally acceptable salt or ester thereof. Methoprotryne, shown below, is N 2 -isopropyl- N 4 -(3-methoxypropyl)-6-methylthio-1,3,5-triazine-2,4-dia mine. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of methoprotryne include its use in post-emergence control of annual broadleaf weeds and grasses in winter-sown cereals. Methoprotryne can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, methoprotryne is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1200 g ai/ha or more, such as 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1550 g ai/ha or more, 1600 g ai/ha or more, 1650 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more, 1800 g ai/ha or more, 1850 g ai/ha or more, 1900 g ai/ha or more, 1950 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, or 2200 g ai/ha or more; in an amount of 2250 g ai/ha or less, such as 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1950 g ai/ha or less, 1900 g ai/ha or less, 1850 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 11650 g ai/ha or less, 1600 g ai/ha or less, 1550 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, or 1250 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1200-2250 g ai/ha, 1350–1800 g ai/ha, 1400–1600 g ai/ha, 1550–2100 g ai/ha, 1400–1900 g ai/ha, 1650–2050 g ai/ha, or 1250–2200 g ai/ha. Metobromuron In some aspects, the PS-II inhibitor herbicide can comprise metobromuron or an agriculturally acceptable salt or ester thereof. Metobromuron, shown below, is 3-(4- bromophenyl)-1-methoxy-1-methylurea. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of metobromuron include its use in pre- emergence control of annual broadleaf and grass weeds in beans, potatoes, tomatoes, tobacco, soybeans, maize, artichokes, and sugar beets. Metobromuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, metobromuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1200 g ai/ha or more, such as 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1550 g ai/ha or more, 1600 g ai/ha or more, 1650 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more, 1800 g ai/ha or more, 1850 g ai/ha or more, 1900 g ai/ha or more, 1950 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2350 g ai/ha or more, 2400 g ai/ha or more, 2450 g ai/ha or more, or 2500 g ai/ha or more; in an amount of 2550 g ai/ha or less, such as 2500 g ai/ha or less, 2450 g ai/ha or less, 2400 g ai/ha or less, 2350 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1950 g ai/ha or less, 1900 g ai/ha or less, 1850 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 11650 g ai/ha or less, 1600 g ai/ha or less, 1550 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, or 1250 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1200-2550 g ai/ha, 1350–2400 g ai/ha, 1450–1950 g ai/ha, 1550–2100 g ai/ha, 1600–2400 g ai/ha, 1750–2350 g ai/ha, or 1250–2500 g ai/ha. Metoxuron In some aspects, the PS-II inhibitor herbicide can comprise metoxuron or an agriculturally acceptable salt or ester thereof. Metoxuron, shown below, is 3-(3-chloro-4- methoxyphenyl)-1,1-dimethylurea. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of metoxuron include its use in pre- and post-emergence control of some grasses and annual broadleaf weeds in winter wheat, winter barley, winter rye, carrots, some varieties of spring wheat, for desiccation of potato plants, and pre-harvest defoliation in hemp, flax, and tomatoes. Metoxuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, metoxuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2200 g ai/ha or more, such as 2250 g ai/ha or more, 2300 g ai/ha or more, 2350 g ai/ha or more, 2400 g ai/ha or more, 2450 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3800 g ai/ha or more, 3850 g ai/ha or more, 3900 g ai/ha or more, or 3950 g ai/ha or more; in an amount of 4000 g ai/ha or less, such as 3950 g ai/ha or less, 3900 g ai/ha or less, 3850 g ai/ha or less, 3800 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2450 g ai/ha or less, 2400 g ai/ha or less, 2350 g ai/ha or less, 2300 g ai/ha or less, or 2250 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2200–4000 g ai/ha, 2300-3900 g ai/ha, 2450– 3200 g ai/ha, 2600–3300 g ai/ha, 2500–3800 g ai/ha, 2350–3200 g ai/ha, 2900–4000 g ai/ha, 2200–3600 g ai/ha, 2800–3700 g ai/ha, 2400–3200 g ai/ha, or 2250–3950 g ai/ha. Metribuzin In some aspects, the PS-II inhibitor herbicide can comprise metribuzin or an agriculturally acceptable salt or ester thereof. Metribuzin, shown below, is 4-amino-6-tert- butyl-3-methythio-1,2,4-triazin-5(4H)-one. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of metribuzin include its use in pre- and post-emergence control of grass and broadleaf weeds in soybeans, potatoes, tomatoes, sugar cane, alfalfa, asparagus, maize, and cereals. Metribuzin can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, metribuzin is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 20 g ai/ha or more, such as 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, or 1450 g ai/ha or more; in an amount of 1500 g ai/ha or less, such as 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, or 25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 20-1500 g ai/ha, 25–800 g ai/ha, 65–200 g ai/ha, 75–1300 g ai/ha, 80–700 g ai/ha, 200–925 g ai/ha, 120–1050 g ai/ha, 150–1250 g ai/ha, or 25– 1450 g ai/ha. Monolinuron In some aspects, the PS-II inhibitor herbicide can comprise monolinuron or an agriculturally acceptable salt or ester thereof. Monolinuron, shown below, is 3-(4- chlorophenyl)-1-methoxy-1-methylurea. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of monolinuron include its use in pre- and post-emergence control of annual broadleaf and some grass weeds in asparagus, berries, maize, dwarf French beans, field beans, vines, leeks, onions, potatoes, herbs, alfalfa, flowers and ornamentals, and trees. Neburon In some aspects, the PS-II inhibitor herbicide can comprise neburon or an agriculturally acceptable salt or ester thereof. Neburon, shown below, is 1-butyl-3-(3,4- dichlorophenyl)-1-methylurea. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of neburon include its use in pre-emergence control of annual broadleaf and grass weeds in beans, peas, alfalfa, garlic, cereals, beets, strawberries, ornamentals, and forestry. Neburon can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, neburon is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1750 g ai/ha or more, such as 1800 g ai/ha or more, 1850 g ai/ha or more, 1900 g ai/ha or more, 1950 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2350 g ai/ha or more, 2400 g ai/ha or more, 2450 g ai/ha or more, 2500 g ai/ha or more, 2550 g ai/ha or more, 2600 g ai/ha or more, 2650 g ai/ha or more, 2700 g ai/ha or more, 2750 g ai/ha or more, 2800 g ai/ha or more, 2850 g ai/ha or more, 2900 g ai/ha or more, 2950 g ai/ha or more, 3000 g ai/ha or more, 3050 g ai/ha or more, 3100 g ai/ha or more, 3150 g ai/ha or more, or 3200 g ai/ha or more; in an amount of 3250 g ai/ha or less, such as 3200 g ai/ha or less, 3150 g ai/ha or less, 3100 g ai/ha or less, 3050 g ai/ha or less, 3000 g ai/ha or less, 2950 g ai/ha or less, 2900 g ai/ha or less, 2850 g ai/ha or less, 2800 g ai/ha or less, 2750 g ai/ha or less, 2700 g ai/ha or less, 2650 g ai/ha or less, 2600 g ai/ha or less, 2550 g ai/ha or less, 2500 g ai/ha or less, 2450 g ai/ha or less, 2400 g ai/ha or less, 2350 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1950 g ai/ha or less, 1900 g ai/ha or less, 1850 g ai/ha or less, or 1800 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1750-3250 g ai/ha, 1850–2400 g ai/ha, 1950–2700 g ai/ha, 1800–2400 g ai/ha, 2000–2800 g ai/ha, 2050–2650 g ai/ha, or 1800–3200 g ai/ha. Pentanochlor In some aspects, the PS-II inhibitor herbicide can comprise pentanochlor or an agriculturally acceptable salt or ester thereof. Pentanochlor, shown below, is (RS)-3'-chloro- 2-methylvalero-p-toluidide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of pentanochlor include its use in selective pre- and post-emergence herbicidal control in carrots, celeriac, celery, fennel, parsley, parsnips, peas, tomatoes, some flower crops, fruit trees, and ornamentals at less than 4000 g/ha. Phenmedipham In some aspects, the PS-II inhibitor herbicide can comprise phenmedipham or an agriculturally acceptable salt or ester thereof. Phenmedipham, shown below, is 3- methoxycarbonylaminophenyl 3'-methylcarbanilate. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of phenmedipham include its use in post-emergence control of broadleaf weeds in sugar beets, strawberries, spinach, peas, chard, and red beets. Phenmedipham can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, phenmedipham is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 150 g ai/ha or more, such as 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, or 975 g ai/ha or more; in an amount of 1000 g ai/ha or less, such as 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, or 175 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 150-1000 g ai/ha, 200–800 g ai/ha, 175–700 g ai/ha, 525–900 g ai/ha, 250–750 g ai/ha, 300– 925 g ai/ha, 450–850 g ai/ha, 400–650 g ai/ha, or 175–975 g ai/ha. Prometon In some aspects, the PS-II inhibitor herbicide can comprise prometon or an agriculturally acceptable salt or ester thereof. Prometon, shown below, is N 2 ,N 4 -diisopropyl- 6-methoxy-1,3,5-triazine-2,4-diamine. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of prometon include its use in pre- or early post-emergence control of annual and perennial paddy weeds in direct-seeded and transplanted rice. Prometon can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, prometon is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 100 g ai/ha or more, such as 125 g ai/ha or more, 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, or 325 g ai/ha or more; in an amount of 350 g ai/ha or less, such as 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, or 125 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 100-350 g ai/ha, 150–300 g ai/ha, 225–325 g ai/ha, 175–300 g ai/ha, 200–275 g ai/ha, 150–225 g ai/ha, or 125–325 g ai/ha. Prometryn In some aspects, the PS-II inhibitor herbicide can comprise prometryn or an agriculturally acceptable salt or ester thereof. Prometryn, shown below, is N 2 ,N 4 -diisopropyl- 6-methylthio-1,3,5-triazine-2,4-diamine. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of prometryn include its use in pre- or post-emergence control of annual grass and broadleaf weeds in cotton, sunflowers, peanuts, potatoes, carrots, peas, beans, celery, and leeks. Prometryn can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, prometryn is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 500 g ai/ha or more, such as 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1550 g ai/ha or more, 1600 g ai/ha or more, 1650 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more, 1800 g ai/ha or more, 1850 g ai/ha or more, 1900 g ai/ha or more, 1950 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, or 2700 g ai/ha or more; in an amount of 2750 g ai/ha or less, such as 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1950 g ai/ha or less, 1900 g ai/ha or less, 1850 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less,1700 g ai/ha or less, 1650 g ai/ha or less, 1600 g ai/ha or less, 1550 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, or 550 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 500-2750 g ai/ha, 650-2400 g ai/ha, 750–1800 g ai/ha, 900–2100 g ai/ha, 1300– 2500 g ai/ha, 700-1700 g ai/ha, or 550–2700 g ai/ha. Propanil In some aspects, the PS-II inhibitor herbicide can comprise propanil or an agriculturally acceptable salt or ester thereof. Propanil, shown below, is 3',4'- dichloropropionanilide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of propanil include its use in post-emergence control of broadleaf and grass weeds in rice. Propanil can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, propanil is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 5 g ai/ha or more, such as 10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 120 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 180 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3800 g ai/ha or more, or 3900 g ai/ha or more; in an amount of 4000 g ai/ha or less, such as 3900 g ai/ha or less, 3800 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 180 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 120 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, or 10 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 5–4000 g ai/ha, 20-3700 g ai/ha, 250–1200 g ai/ha, 600–2300 g ai/ha, 45–800 g ai/ha, 350–3200 g ai/ha, 75–2200 g ai/ha, 850–2500 g ai/ha, 1600–3700 g ai/ha, 180–2800 g ai/ha, or 10–3950 g ai/ha. Propazine In some aspects, the PS-II inhibitor herbicide can comprise propazine or an agriculturally acceptable salt or ester thereof. Propazine, shown below, is 6-chloro-N 2 ,N 4 - diisopropyl-1,3,5-triazine-2,4-diamine. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of propazine include its use in pre-plant, pre-, or post-emergence control of grass and broadleaf weeds in sorghum, carrots, chervil, parsley, and glasshouse ornamentals. Propazine can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, propazine is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 250 g ai/ha or more, such as 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more, or 3400 g ai/ha or more; in an amount of 3500 g ai/ha or less, such as 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, or 275 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 275–3500 g ai/ha, 300-3000 g ai/ha, 450–1200 g ai/ha, 600–2300 g ai/ha, 325–800 g ai/ha, 850–2600 g ai/ha, 750–2200 g ai/ha, 500–1500 g ai/ha, 1600–3100 g ai/ha, 900–3300 g ai/ha, or 275–3400 g ai/ha. Pyridafol In some aspects, the PS-II inhibitor herbicide can comprise pyridafol or an agriculturally acceptable salt or ester thereof. Pyridafol, shown below, is 6-chloro-3- phenylpyridazin-4-ol. According to The Pesticide Manual, Seventeenth Edition, 2016, pyridafol was evaluated by Novartis Crop Protection AG. Pyridate In some aspects, the PS-II inhibitor herbicide can comprise pyridate or an agriculturally acceptable salt or ester thereof. Pyridate, shown below, is O-6-chloro-3- phenylpyridazin-4-yl S-octyl thiocarbonate. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of pyridate include its use in post-emergence control of annual broadleaf weeds and some grass weeds in maize, oilseed rape, cereals, rice, peanuts, and vegetables. Pyridate can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pyridate is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 100 g ai/ha or more, such as 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, or 1450 g ai/ha or more; in an amount of 1500 g ai/ha or less, such as 1450 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, or 110 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 100–1500 g ai/ha, 120-700 g ai/ha, 250–1100 g ai/ha, 300–800 g ai/ha, 450–1000 g ai/ha, 350–1200 g ai/ha, 210–900 g ai/ha, 125–500 g ai/ha, 375–1400 g ai/ha, 180–600 g ai/ha, or 110–1450 g ai/ha. Siduron In some aspects, the PS-II inhibitor herbicide can comprise siduron or an agriculturally acceptable salt or ester thereof. Siduron, shown below, is 1-(2- methylcyclohexyl)-3-phenylurea. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of siduron include its use in pre- emergence control of Digitaria spp. and annual grass weeds in turf farms, grass seed production, and established turf. Siduron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, siduron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2000 g ai/ha or more, such as 2100 g ai/ha or more, 2250 g ai/ha or more, 2500 g ai/ha or more, 2750 g ai/ha or more, 3000 g ai/ha or more, 3500 g ai/ha or more, 4000 g ai/ha or more, 4500 g ai/ha or more, 5000 g ai/ha or more, 6000 g ai/ha or more, 7000 g ai/ha or more, 7500 g ai/ha or more, 8000 g ai/ha or more, 9000 g ai/ha or more, 10,000 g ai/ha or more, 11,000 g ai/ha or more, 12,000 g ai/ha or more, 13,000 g ai/ha or more, 14,000 g ai/ha or more, or 14,500 g ai/ha or more; in an amount of 15,000 g ai/ha or less, such as 14,500 g ai/ha or less, 14,000 g ai/ha or less, 13,000 g ai/ha or less, 12,000 g ai/ha or less, 11,000 g ai/ha or less, 10,000 g ai/ha or less, 9000 g ai/ha or less, 8000 g ai/ha or less, 7500 g ai/ha or less, 7000 g ai/ha or less, 6000 g ai/ha or less, 5000 g ai/ha or less, 4500 g ai/ha or less, 4000 g ai/ha or less, 3500 g ai/ha or less, 3000 g ai/ha or less, 2750 g ai/ha or less, 2500 g ai/ha or less, 2250 g ai/ha or less, or 2100 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2000-15,000 g ai/ha, 2500–13,000 g ai/ha, 6000–9000 g ai/ha, 8000–14,000 g ai/ha, 4500–11,000 g ai/ha, 2750– 7500 g ai/ha, 3000–12,000 g ai/ha, 7000–10,000 g ai/ha, 4000–12,000 g ai/ha, or 2100–14,500 g ai/ha. Simazine In some aspects, the PS-II inhibitor herbicide can comprise simazine or an agriculturally acceptable salt or ester thereof. Simazine, shown below, is 6-chloro-N 2 ,N 4 - diethyl-1,3,5-triazine-2,4-diamine. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of simazine include its use in pre- emergence control of broadleaf and annual grass weeds in pome fruit, stone fruit, bush and cane fruits, citrus, vines, strawberries, nuts, olives, pineapples, field beans, French beans, peas, maize, asparagus, hops, alfalfa, lupins, oilseed rape, artichokes, sugar cane, plantation trees, turf, and ornamentals. Simazine can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, simazine is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1250 g ai/ha or more, such as 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1550 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more, or 3400 g ai/ha or more; in an amount of 3500 g ai/ha or less, such as 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1550 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, or 1300 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1250–3500 g ai/ha, 1300-3000 g ai/ha, 1450–1900 g ai/ha, 1600–2300 g ai/ha, 1100–2800 g ai/ha, 1550–2000 g ai/ha, 2100– 2600 g ai/ha, 1500–2500 g ai/ha, 1600–3100 g ai/ha, 2400–3300 g ai/ha, or 1300–3400 g ai/ha. Symetryn In some aspects, the PS-II inhibitor herbicide can comprise symetryn or an agriculturally acceptable salt or ester thereof. Symetryn, shown below, is N 2 ,N 4 -diethyl-6- methylthio-1,3,5-triazine-2,4-diamine. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of symetryn include its use in control of broadleaf weeds in rice. Tebuthiuron In some aspects, the PS-II inhibitor herbicide can comprise tebuthiuron or an agriculturally acceptable salt or ester thereof. Tebuthiuron, shown below, is 1-(5-tert-butyl- 1,3,4-thiadiazol-2-yl)-1,3-dimethylurea. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of tebuthiuron include its use in pre- emergence control of herbaceous and woody plants, annual weeds, and perennial grass and broadleaf weeds in non-crop sites, pastures, rangeland, and sugar cane. Tebuthiuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, tebuthiuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 500 g ai/ha or more, such as 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2250 g ai/ha or more, 2500 g ai/ha or more, 2750 g ai/ha or more, 3000 g ai/ha or more, 3500 g ai/ha or more, 4000 g ai/ha or more, 4500 g ai/ha or more, 5000 g ai/ha or more, 6000 g ai/ha or more, or 6500 g ai/ha or more; in an amount of 7000 g ai/ha or less, such as 6500 g ai/ha or less, 6000 g ai/ha or less, 5000 g ai/ha or less, 4500 g ai/ha or less, 4000 g ai/ha or less, 3500 g ai/ha or less, 3000 g ai/ha or less, 2750 g ai/ha or less, 2500 g ai/ha or less, 2250 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, or 520 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 500-7000 g ai/ha, 2500–5000 g ai/ha, 600–900 g ai/ha, 825–1400 g ai/ha, 4500–7000 g ai/ha, 750–5000 g ai/ha, 1000–3500 g ai/ha, 975–4000 g ai/ha, 700–1200 g ai/ha, or 520– 6500 g ai/ha. Terbacil In some aspects, the PS-II inhibitor herbicide can comprise terbacil or an agriculturally acceptable salt or ester thereof. Terbacil, shown below, is 3-tert-butyl-5-chloro- 6-methyluracil. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of terbacil include its use in pre- and post-emergence control of annual and some perennial grass, broadleaf, and sedge weeds in apples, citrus, alfalfa, tree fruit, strawberries, blueberries, mint, and sugar cane. Terbacil can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, terbacil is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 300 g ai/ha or more, such as 310 g ai/ha or more, 320 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1400 g ai/ha or more, 1600 g ai/ha or more, 1800 g ai/ha or more, 2000 g ai/ha or more, 2200 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2800 g ai/ha or more, 3000 g ai/ha or more, 3200 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3800 g ai/ha or more, 4000 g ai/ha or more, 4200 g ai/ha or more, or 4400 g ai/ha or more; in an amount of 4500 g ai/ha or less, such as 4400 g ai/ha or less, 4200 g ai/ha or less, 4000 g ai/ha or less, 3800 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3200 g ai/ha or less, 3000 g ai/ha or less, 2800 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2200 g ai/ha or less, 2000 g ai/ha or less, 1800 g ai/ha or less, 1600 g ai/ha or less, 1400 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 320 g ai/ha or less, or 310 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 300-4500 g ai/ha, 370–4000 g ai/ha, 1400–2600 g ai/ha, 600–3800 g ai/ha, 540–2600 g ai/ha, 1100–2800 g ai/ha, 1600–2500 g ai/ha, 2000–3200 g ai/ha, 2500–4200 g ai/ha, 700–1500 g ai/ha, 350–3400 g ai/ha, or 310–4400 g ai/ha. Terbumeton In some aspects, the PS-II inhibitor herbicide can comprise terbumeton or an agriculturally acceptable salt or ester thereof. Terbumeton, shown below, is N 2 -tert-butyl-N 4 - ethyl-6-methoxy-1,3,5-triazine-2,4-diamine. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of terbumeton include its use in pre-emergence control of annual and perennial grass and broadleaf weeds in citrus, vineyards, apples, and forestry. Terbumeton can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, terbumeton is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2700 g ai/ha or more, such as 2750 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3800 g ai/ha or more, 3900 g ai/ha or more 4000 g ai/ha or more, 4100 g ai/ha or more, 4200 g ai/ha or more, 4300 g ai/ha or more, 4400 g ai/ha or more, 4500 g ai/ha or more, 4600 g ai/ha or more, 4700 g ai/ha or more, 4800 g ai/ha or more, 4900 g ai/ha or more, 5000 g ai/ha or more, 5100 g ai/ha or more, 5200 g ai/ha or more, 5300 g ai/ha or more, 5400 g ai/ha or more, 5500 g ai/ha or more, 5600 g ai/ha or more, 5700 g ai/ha or more, 5800 g ai/ha or more, 5900 g ai/ha or more, 6000 g ai/ha or more, 6100 g ai/ha or more, 6250 g ai/ha or more, 6500 g ai/ha or more, or 6750 g ai/ha or more; in an amount of 7000 g ai/ha or less, such as 6750 g ai/ha or less, 6500 g ai/ha or less, 6250 g ai/ha or less, 6100 g ai/ha or less, 6000 g ai/ha or less, 5900 g ai/ha or less, 5800 g ai/ha or less, 5700 g ai/ha or less, 5600 g ai/ha or less, 5500 g ai/ha or less, 5400 g ai/ha or less, 5300 g ai/ha or less, 5200 g ai/ha or less, 5100 g ai/ha or less, 5000 g ai/ha or less, 4900 g ai/ha or less, 4800 g ai/ha or less, 4700 g ai/ha or less, 4600 g ai/ha or less, 4500 g ai/ha or less, 4400 g ai/ha or less, 4300 g ai/ha or less, 4200 g ai/ha or less, 4100 g ai/ha or less, 4000 g ai/ha or less, 3900 g ai/ha or less, 3800 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, or 2750 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2700-7000 g ai/ha, 3500–6000 g ai/ha, 4600–6900 g ai/ha, 2800–4400 g ai/ha, 5700–6100 g ai/ha, 3700–5000 g ai/ha, 3000–5500 g ai/ha, 2900–6300 g ai/ha, 3600–4900 g ai/ha, or 2750–6750 g ai/ha. Terbuthylazine In some aspects, the PS-II inhibitor herbicide can comprise terbuthylazine or an agriculturally acceptable salt or ester thereof. Terbuthylazine, shown below, is N 2 -tert-butyl- 6-chloro-N 4 -ethyl-1,3,5-triazine-2,4-diamine. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of terbuthylazine include its use in pre- and post-emergence control of broadleaf and grass weeds in maize, sorghum, tree fruits, citrus, vines, coffee, oil palms, cocoa, potatoes, olives, peas, beans, sugar cane, rubber, tree nurseries, and new plantings. Terbuthylazine can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, terbuthylazine is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 500 g ai/ha or more, such as 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2250 g ai/ha or more, 2500 g ai/ha or more, or 2750 g ai/ha or more; in an amount of 3000 g ai/ha or less, such as 2750 g ai/ha or less, 2500 g ai/ha or less, 2250 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, or 520 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 500- 3000 g ai/ha, 540–2000 g ai/ha, 600–900 g ai/ha, 825–2250 g ai/ha, 700–2100 g ai/ha, 750– 1700 g ai/ha, 1000–2500 g ai/ha, 975–1300 g ai/ha, 600–1900 g ai/ha, or 520–2750 g ai/ha. Terbutryn In some aspects, the PS-II inhibitor herbicide can comprise terbutryn or an agriculturally acceptable salt or ester thereof. Terbutryn, shown below, is N 2 -tert-butyl-N 4 - ethyl-6-methylthio-1,3,5-triazine-2,4-diamine. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of terbutryn include its use in pre-emergence control of broadleaf and grass weeds in winter cereals, beans, peas, maize, sugar cane, sunflowers, potatoes, cotton, and peanuts. Terbutryn can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, terbutryn is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 150 g ai/ha or more, such as 175 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, or 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more; in an amount of 3000 g ai/ha or less, such as 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less,1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, or 175 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 150-3000 g ai/ha, 325–2800 g ai/ha, 575–2900 g ai/ha, 275–1300 g ai/ha, 850–1700 g ai/ha, 2000–2800 g ai/ha, 600–1050 g ai/ha, 450–1450 g ai/ha, or 175–2900 g ai/ha. Trietazine In some aspects, the PS-II inhibitor herbicide can comprise trietazine or an agriculturally acceptable salt or ester thereof. Trietazine, shown below, is 6-chloro-N 2 ,N 2 ,N 4 - triethyl-1,3,5-triazine-2,4-diamine. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of trietazine include its use in control of weeds in potatoes, field beans, and peas. Trietazine can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, trietazine is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1500 g ai/ha or more, such as 1550 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2200 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2800 g ai/ha or more, 3000 g ai/ha or more, 3200 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3800 g ai/ha or more, 4000 g ai/ha or more, 4200 g ai/ha or more, 4300 g ai/ha or more, or 4400 g ai/ha or more; in an amount of 4500 g ai/ha or less, such as 4400 g ai/ha or less, 4300 g ai/ha or less, 4200 g ai/ha or less, 4000 g ai/ha or less, 3800 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3200 g ai/ha or less, 3000 g ai/ha or less, 2800 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2200 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, or 1550 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1500-4500 g ai/ha, 1600–4000 g ai/ha, 1900–2600 g ai/ha, 2600–3800 g ai/ha, 2200– 3200 g ai/ha, 1900–2800 g ai/ha, 2100–2500 g ai/ha, 2000–3200 g ai/ha, 2500–4200 g ai/ha, 1500–3500 g ai/ha, or 1550–4400 g ai/ha. HPPD INHIBITOR HERBICIDES In addition to the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), the compositions can optionally include a 4- hydroxyphenyl-pyruvate dioxygenase (HPPD) inhibitor herbicide. HPPD inhibitor herbicides interfere with an oxygenase enzyme involved in the creation of energy in plants and higher order eukaryotes. Examples of HPPD inhibitors include benzobicyclon, benzofenap, bicyclopyrone, fenquinotrione, isoxachlortole, isoxaflutole, lancotrione, mesotrione, pyraquinate, pyrasulfotole, pyrazolynate, pyrazoxyfen, sulcotrione, tefuryltrione, tembotrione, tolpyralate, topramezone, or an agriculturally acceptable salt or ester thereof, and combinations thereof. In some aspects, the composition can include a HPPD inhibitor herbicide selected from the group consisting of benzobicyclon, benzofenap, bicyclopyrone, fenquinotrione, isoxachlortole, isoxaflutole, lancotrione, mesotrione, pyrasulfotole, pyrazolynate, pyrazoxyfen, sulcotrione, tefuryltrione, tembotrione, tolpyralate, topramezone, an agriculturally acceptable salt or ester thereof, and combinations thereof. The HPPD inhibitor herbicide or agriculturally acceptable salt or ester thereof can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, the HPPD inhibitor herbicide or agriculturally acceptable salt or ester thereof is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 1.1 g ai/ha or more, 1.25 g ai/ha or more, 1.5 g ai/ha or more, 1.75 g ai/ha or more, 2 g ai/ha or more, 2.5 g ai/ha or more, 3 g ai/ha or more, 3.5 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 11 g ai/ha or more, 12 g ai/ha or more, 13 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 17 g ai/ha or more, 18 g ai/ha or more, 19 g ai/ha or more, 20 g ai/ha or more, 21 g ai/ha or more, 22 g ai/ha or more, 23 g ai/ha or more, 24 g ai/ha or more, 25 g ai/ha or more, 26 g ai/ha or more, 27 g ai/ha or more, 28 g ai/ha or more, 29 g ai/ha or more, 30 g ai/ha or more, 31 g ai/ha or more, 32 g ai/ha or more, 33 g ai/ha or more, 34 g ai/ha or more, 35 g ai/ha or more, 36 g ai/ha or more, 37 g ai/ha or more, 38 g ai/ha or more, 39 g ai/ha or more, 40 g ai/ha or more, 41 g ai/ha or more, 42 g ai/ha or more, 43 g ai/ha or more, 44 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, 2240 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2350 g ai/ha or more, 2400 g ai/ha or more, 2450 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2750 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3750 g ai/ha or more, 3800 g ai/ha or more, 3900 g ai/ha or more, 3950 g ai/ha or more, 4000 g ai/ha or more, 4100 g ai/ha or more, 4200 g ai/ha or more, 4250 g ai/ha or more, 4300 g ai/ha or more, or 4350 g ai/ha or more, or 4400 g ai/ha or more; in an amount of 4500 g ai/ha or less, such as 4450 g ai/ha or less, 4400 g ai/ha or less, 4350 g ai/ha or less, 4300 g ai/ha or less, 4250 g ai/ha or less, 4100 g ai/ha or less, 4000 g ai/ha or less, 3950 g ai/ha or less, 3900 g ai/ha or less, 3800 g ai/ha or less, 3750 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2750 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2450 g ai/ha or less, 2400 g ai/ha or less, 2350 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2240 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1240 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 44 g ai/ha or less, 43 g ai/ha or less, 42 g ai/ha or less, 41 g ai/ha or less, 40 g ai/ha or less, 39 g ai/ha or less, 38 g ai/ha or less, 37 g ai/ha or less, 36 g ai/ha or less, 35 g ai/ha or less, 34 g ai/ha or less, 33 g ai/ha or less, 32 g ai/ha or less, 31 g ai/ha or less, 30 g ai/ha or less, 29 g ai/ha or less, 28 g ai/ha or less, 27 g ai/ha or less, 26 g ai/ha or less, 25 g ai/ha or less, 24 g ai/ha or less, 23 g ai/ha or less, 22 g ai/ha or less, 21 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18 g ai/ha or less, 17 g ai/ha or less, 16 ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, 11 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3.5 g ai/ha or less, 3 g ai/ha or less, 2.5 g ai/ha or less, 2 g ai/ha or less, 1.75 g ai/ha or less, 1.5 g ai/ha or less, 1.25 g ai/ha or less, or 1.1 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–4500 g ai/ha, 4–3900 g ai/ha, 1.75-2500 g ai/ha, 75–3100 g ai/ha, 90–900 g ai/ha, 55–4200 g ai/ha, 50–2350 g ai/ha, 80–2900 g ai/ha, 120–4100 g ai/ha, 65–2700 g ai/ha, 300–4000 g ai/ha, 1200–3600 g ai/ha, 250–2000 g ai/ha, 1.75-250 g ai/ha, 700–4250 g ai/ha, 39–1100 g ai/ha, or 1.1–4450 g ai/ha. In some aspects, the composition contains: compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof); (b) a PS-II inhibitor herbicide selected from ametryne, amicarbazone, atrazine, bentazone, bromacil, bromofenoxim, bromoxynil, chlorbromuron, chloridazon, chlorotoluron, chloroxuron, cyanazine, desmedipham, desmetryn, dimefuron, dimethametryn, diuron, ethidimuron, ethiozin, fenuron, fluometuron, hexazinone, iodobonil, ioxynil, isocil, isomethiozin, isoproturon, isouron, karbutilate, lenacil, linuron, metamitron, methabenzthiazuron, methoprotryne, metobromuron, metoxuron, metribuzin, monolinuron, neburon, pentanochlor, phenmedipham, prometon, prometryn, propanil, propazine, pyridafol, pyridate, siduron, simazine, simetryne, tebuthiuron, terbacil, terbumeton, terbuthylazine, terbutryn, trietazine, or mixtures thereof; and (c) an HPPD herbicide selected from benzobicyclon, benzofenap, bicyclopyrone, fenquinotrione, isoxachlortole, isoxaflutole, lancotrione, mesotrione, pyrasulfotole, pyrazolynate, pyrazoxyfen, sulcotrione, tefuryltrione, tembotrione, tolpyralate, topramezone, an agriculturally acceptable salt or ester thereof, or combinations thereof. Benzobicyclon In some aspects, the HPPD inhibitor herbicide can comprise benzobicyclon or an agriculturally acceptable salt or ester thereof. Benzobicyclon, shown below, is 3-[2-chloro-4- (methylsulfonyl)benzoyl]-4-(phenylthio)bicyclo[3.2.1]oct-3-e n-2-one. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of benzobicyclon include its use for pre- to early post-emergence control of annual and perennial paddy weeds in direct-seeded and transplanted rice. Benzobicyclon can be applied to vegetation or an area adjacent to the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, benzobicyclon is applied to vegetation or an area adjacent to the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, or 400 g ai/ha or more; in an amount of 401 g ai/ha or less, such as 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, or 50 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50– 401 g ai/ha, 75–360 g ai/ha, 100–240 g ai/ha, 150–300 g ai/ha, 170–280 g ai/ha, 140–360 g ai/ha, 200–320 g ai/ha, 80–260 g ai/ha, or 55–400 g ai/ha. Benzofenap In some aspects, the HPPD inhibitor herbicide can comprise benzofenap or an agriculturally acceptable salt or ester thereof. Benzofenap, shown below, is 2-[[4-(2,4- dichloro-3-methylbenzoyl)-1,3-dimethyl-1H-pyrazol-5-yl]oxy]- 1-(4-methylphenyl) ethanone. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of benzofenap include its use for control of broadleaf weeds in rice. Benzofenap can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, benzofenap is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 300 g ai/ha or more, such as 310 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, or 1000 g ai/ha or more; in an amount of 1001 g ai/ha or less, such as 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, or 310 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 300–1001 g ai/ha, 450–1000 g ai/ha, 380–825 g ai/ha, 400–900 g ai/ha, 450–925 g ai/ha, 550–775 g ai/ha, 600–850 g ai/ha, 475– 950 g ai/ha, 340–925 g ai/ha, 650–975 g ai/ha, 725–1000 g ai/ha, 450–850 g ai/ha, 800–950 g ai/ha, or 310–975 g ai/ha. Bicyclopyrone In some aspects, the HPPD inhibitor herbicide can comprise bicyclopyrone or an agriculturally acceptable salt or ester thereof. Bicyclopyrone, shown below, is 4-hydroxy-3- [[2-[(2-methoxyethoxy)methyl]-6-(trifluoromethyl)-3-pyridiny l]carbonyl] bicyclo[3.2.1]oct- 3-en-2-one. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of bicyclopyrone include its use for pre- and early post- emergence control of broadleaf and grass weeds in maize and cereals. Bicyclopyrone can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, bicyclopyrone is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 20 g ai/ha or more, such as 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, or 400 g ai/ha; in an amount of 401 g ai/ha or less, such as 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, or 20 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 20–401 g ai/ha, 30–260 g ai/ha, 40–380 g ai/ha, 55–300 g ai/ha, 60–340 g ai/ha, 45–320 g ai/ha, 25–300 g ai/ha, 100–190 g ai/ha, 200–380 g ai/ha, 50– 200 g ai/ha, 30–300 g ai/ha, 85–220 g ai/ha, 30–65 g ai/ha, or 25–400 g ai/ha. Fenquinotrione In some aspects, the HPPD inhibitor herbicide can comprise fenquinotrione or an agriculturally acceptable salt or ester thereof. Fenquinotrione, shown below, is 2-[[8-chloro- 3,4-dihydro-4-(4-methoxyphenyl)-3-oxo-2-quinoxalinyl]carbony l]-1,3-cyclohexanedione. According to the online edition of The Pesticide Manual, fenquinotrione is a herbicide under development for use on rice. Isoxachlortole In some aspects, the HPPD inhibitor herbicide can comprise isoxachlortole or an agriculturally acceptable salt or ester thereof. Isoxachlortole, shown below, is [4-chloro-2- (methylsulfonyl)phenyl](5-cyclopropyl-4-isoxazolyl) methanone. According to the online edition of The Pesticide Manual, isoxachlortole is a herbicide that was evaluated by Rhône- Poulenc. Isoxaflutole In some aspects, the HPPD inhibitor herbicide can comprise isoxaflutole or an agriculturally acceptable salt or ester thereof. Isoxaflutole, shown below, is (5-cyclopropyl-4- isoxazolyl)[2-(methylsulfonyl)-4-(trifluoromethyl)phenyl] methanone. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of isoxaflutole include its use for pre- emergence or pre-plant control of grass and broadleaf weed in maize and sugar cane. Isoxaflutole can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, isoxaflutole is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 20 g ai/ha or more, such as 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, or 300 g ai/ha or more; in an amount of 301 g ai/ha or less, such as 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, or 25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 20–301 g ai/ha, 30–300 g ai/ha, 40–170 g ai/ha, 25–260 g ai/ha, 60–120 g ai/ha, 70–190 g ai/ha, 75–240 g ai/ha, 35–200 g ai/ha, 65–220 g ai/ha, 85–140 g ai/ha, 100–300 g ai/ha, 150–280 g ai/ha, 200–301 g ai/ha, 130–200 g ai/ha, 25–100 g ai/ha, 70–90 g ai/ha, or 25–300 g ai/ha. Lancotrione In some aspects, the HPPD inhibitor herbicide can comprise lancotrione or an agriculturally acceptable salt or ester thereof. Lancotrione, shown below, is 2-[2-chloro-3-[2- (1,3-dioxolan-2-yl)ethoxy]-4-(methylsulfonyl)benzoyl]-3-hydr oxy-2-cyclohexen-1-one. According to the online edition of The Pesticide Manual, lancotrione is a herbicide under development by Ishihara Sangyo Kaisha, Ltd. Mesotrione In some aspects, the HPPD inhibitor herbicide can comprise mesotrione or an agriculturally acceptable salt or ester thereof. Mesotrione, shown below, is 2-[4- (methylsulfonyl)-2-nitrobenzoyl]-1,3-cyclohexanedione. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of mesotrione include its use for pre- and post- emergence control of broadleaf weeds and some grass weeds in maize. Mesotrione can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, mesotrione is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 20 g ai/ha or more, such as 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, or 300 g ai/ha or more; in an amount of 301 g ai/ha or less, such as 300 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 125 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, or 25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 20–301 g ai/ha, 30–275 g ai/ha, 40–140 g ai/ha, 50–250 g ai/ha, 60–301 g ai/ha, 25–280 g ai/ha, 60–125 g ai/ha, 70–250 g ai/ha, 90–225 g ai/ha, 110–220 g ai/ha, 40–175 g ai/ha, 65–160 g ai/ha, 70–200 g ai/ha, 80–180 g ai/ha, 90–250 g ai/ha, 140–225 g ai/ha, 110– 240 g ai/ha, 120–175 g ai/ha, 110–150 g ai/ha, 25-85 g ai/ha, or 25–300 g ai/ha. Pyrasulfotole In some aspects, the HPPD inhibitor herbicide can comprise pyrasulfotole or an agriculturally acceptable salt or ester thereof. Pyrasulfotole, shown below, is (5-hydroxy-1,3- dimethyl-1H-pyrazol-4-yl)[2-(methylsulfonyl)-4-(trifluoromet hyl) phenyl]methanone. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of pyrasulfotole include its use in mixture with mefenpyr-diethyl and bromoxynil or MCPA ester, for post- emergence control of broadleaf weeds in cereals. Pyrasulfotole can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pyrasulfotole is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 1.1 g ai/ha or more, 1.25 g ai/ha or more, 1.4 g ai/ha or more, 1.5 g ai/ha or more, 1.6 g ai/ha or more, 1.75 g ai/ha or more, 1.9 g ai/ha or more, 2 g ai/ha or more, 2.25 g ai/ha or more, 2.5 g ai/ha or more, 2.75 g ai/ha or more, 3 g ai/ha or more, 3.25 g ai/ha or more, 3.5 g ai/ha or more, 3.75 g ai/ha or more, 4 g ai/ha or more, 4.5 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 9.5 g ai/ha or more, 10 g ai/ha or more, 10.5 g ai/ha or more, 11 g ai/ha or more, 11.5 g ai/ha or more, 12 g ai/ha or more, 12.5 g ai/ha or more, 13 g ai/ha or more, 13.5 g ai/ha or more, 14 g ai/ha or more, 14.5 g ai/ha or more, 15 g ai/ha or more, 15.5 g ai/ha or more, 16 g ai/ha or more, 16.5 g ai/ha or more, 17 g ai/ha or more, 17.5 g ai/ha or more, 18 g ai/ha or more, 18.5 g ai/ha or more, 20 g ai/ha or more, 21 g ai/ha or more, 22 g ai/ha or more, 23 g ai/ha or more, 24 g ai/ha or more, 25 g ai/ha or more, 26 g ai/ha or more, 27 g ai/ha or more, 28 g ai/ha or more, 29 g ai/ha or more, 30 g ai/ha or more, 31 g ai/ha or more, 32 g ai/ha or more, 33 g ai/ha or more, 34 g ai/ha or more, 35 g ai/ha or more, 36 g ai/ha or more, 37 g ai/ha or more, 38 g ai/ha or more, 39 g ai/ha or more, 40 g ai/ha or more, 41 g ai/ha or more, 42 g ai/ha or more, 43 g ai/ha or more, 44 g ai/ha or more, 45 g ai/ha or more, or 47 g ai/ha or more; in an amount of 50 g ai/ha or less, such as 47 g ai/ha or less, 45 g ai/ha or less, 44 g ai/ha or less, 43 g ai/ha or less, 42 g ai/ha or less, 41 g ai/ha or less, 40 g ai/ha or less, 39 g ai/ha or less, 38 g ai/ha or less, 37 g ai/ha or less, 36 g ai/ha or less, 35 g ai/ha or less, 34 g ai/ha or less, 33 g ai/ha or less, 32 g ai/ha or less, 31 g ai/ha or less, 30 g ai/ha or less, 29 g ai/ha or less, 28 g ai/ha or less, 27 g ai/ha or less, 26 g ai/ha or less, 25 g ai/ha or less, 24 g ai/ha or less, 23 g ai/ha or less, 22 g ai/ha or less, 21 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18.5 g ai/ha or less, 18 g ai/ha or less, 17.5 g ai/ha or less, 17 g ai/ha or less, 16.5 g ai/ha or less, 16 g ai/ha or less, 15.5 g ai/ha or less, 15 g ai/ha or less, 14.5 g ai/ha or less, 14 g ai/ha or less, 13.5 g ai/ha or less, 13 g ai/ha or less, 12.5 g ai/ha or less, 12 g ai/ha or less, 11.5 g ai/ha or less, 11 g ai/ha or less, 10.5 g ai/ha or less, 10 g ai/ha or less, 9.5 g ai/ha or less, 9 g ai/ha or less, 8.5 g ai/ha or less,8 g ai/ha or less, 7.5 g ai/ha or less, 7 g ai/ha or less, 6.5 g ai/ha or less, 6 g ai/ha or less, 5.5 g ai/ha or less, 5 g ai/ha or less, 4.5 g ai/ha or less, 4 g ai/ha or less, 3.75 g ai/ha or less, 3.5 g ai/ha or less, 3.25 g ai/ha or less, 3 g ai/ha or less, 2.75 g ai/ha or less, 2.5 g ai/ha or less, 2.25 g ai/ha or less, 2 g ai/ha or less, 1.9 g ai/ha or less, 1.75 g ai/ha or less, 1.6 g ai/ha or less, 1.5 g ai/ha or less, 1.4 g ai/ha or less, 1.25 g ai/ha or less, or 1.1 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–50 g ai/ha, 1.4–45 g ai/ha, 1.2–42 g ai/ha, 2.5–35 g ai/ha, 4– 30 g ai/ha, 6.5–29 g ai/ha, 1.25–24 g ai/ha, 3.75–18.5 g ai/ha, 2.5–38 g ai/ha, 11–17 g ai/ha, 8– 16 g ai/ha, 2.75–19 g ai/ha, 3–25 g ai/ha, 7–23 g ai/ha, 3.5–16 g ai/ha, 10–41 g ai/ha, 25–50 g ai/ha, 14–44 g ai/ha, 35–45 g ai/ha, 40–51 g ai/ha, or 1.1–47 g ai/ha. Pyrazolynate In some aspects, the HPPD inhibitor herbicide can comprise pyrazolynate or an agriculturally acceptable salt or ester thereof. Pyrazolynate, shown below, is (2,4- dichlorophenyl)[1,3-dimethyl-5-[[(4-methylphenyl) sulfonyl]oxy]-1H-pyrazol-4- yl]methanone. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of pyrazolynate include its use to control grasses, sedges, Potamogeton distinctus, Sagittaria pygmaea, Sagittaria trifolia and Alisma canaliculatum in paddy rice. Pyrazolynate can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pyrazolynate is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1000 g ai/ha or more, such as 1100 g ai/ha or more, 1200 g ai/ha or more, 1400 g ai/ha or more, 1600 g ai/ha or more, 1800 g ai/ha or more, 2000 g ai/ha or more, 2200 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2800 g ai/ha or more, 3000 g ai/ha or more, 3200 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3800 g ai/ha or more, 4000 g ai/ha or more, 4200 g ai/ha or more, or 4400 g ai/ha or more; in an amount of 4500 g ai/ha or less, such as 4400 g ai/ha or less, 4200 g ai/ha or less, 4000 g ai/ha or less, 3800 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3200 g ai/ha or less, 3000 g ai/ha or less, 2800 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2200 g ai/ha or less, 2000 g ai/ha or less, 1800 g ai/ha or less, 1600 g ai/ha or less, 1400 g ai/ha or less, 1200 g ai/ha or less, or 1100 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1000-4500 g ai/ha, 2000–4000 g ai/ha, 1400–2600 g ai/ha, 1600–3800 g ai/ha, 1100–3000 g ai/ha, 1000–2800 g ai/ha, 1600–2500 g ai/ha, 2000–3200 g ai/ha, 2500–4200 g ai/ha, 1200–3500 g ai/ha, 3500–4000 g ai/ha, or 1100– 4400 g ai/ha. Pyrazoxyfen In some aspects, the HPPD inhibitor herbicide can comprise pyrazoxyfen or an agriculturally acceptable salt or ester thereof. Pyrazoxyfen, shown below, is 2-[[4-(2,4- dichlorobenzoyl)-1,3-dimethyl-1H-pyrazol-5-yl]oxy]-1-phenyle thanone. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of pyrazoxyfen include pre- or post-emergence control of annual and perennial weeds in transplanted or direct-seeded paddy rice. Pyrazoxyfen can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pyrazoxyfen is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1000 g ai/ha or more, such as 1100 g ai/ha or more, 1200 g ai/ha or more, 1400 g ai/ha or more, 1600 g ai/ha or more, 1800 g ai/ha or more, 2000 g ai/ha or more, 2200 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2800 g ai/ha or more, 3000 g ai/ha or more, 3200 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3800 g ai/ha or more, 4000 g ai/ha or more, 4200 g ai/ha or more, or 4400 g ai/ha or more; in an amount of 4500 g ai/ha or less, such as 4400 g ai/ha or less, 4200 g ai/ha or less, 4000 g ai/ha or less, 3800 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3200 g ai/ha or less, 3000 g ai/ha or less, 2800 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2200 g ai/ha or less, 2000 g ai/ha or less, 1800 g ai/ha or less, 1600 g ai/ha or less, 1400 g ai/ha or less, 1200 g ai/ha or less, or 1100 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1000-4500 g ai/ha, 1100–4000 g ai/ha, 1400–3600 g ai/ha, 1200–1800 g ai/ha, 1800–4000 g ai/ha, 2200–4500 g ai/ha, 1500–3200 g ai/ha, 2000–3500 g ai/ha, 2500–3400 g ai/ha, or 1100–4400 g ai/ha. Sulcotrione In some aspects, the HPPD inhibitor herbicide can comprise sulcotrione or an agriculturally acceptable salt or ester thereof. Sulcotrione, shown below, is 2-[2-chloro-4- (methylsulfonyl)benzoyl]-1,3-cyclohexanedione. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of sulcotrione include its use to control broadleaf weeds and grasses post-emergence in maize and sugar cane. Sulcotrione can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, sulcotrione is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 20 g ai/ha or more, such as 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, or 580 g ai/ha or more; in an amount of 600 g ai/ha or less, such as 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, or 25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 20–600 g ai/ha, 40–400 g ai/ha, 65–420 g ai/ha, 120–240 g ai/ha, 300–460 g ai/ha, 400–580 g ai/ha, 30–500 g ai/ha, 250–560 g ai/ha, 250–440 g ai/ha, 75–520 g ai/ha, 35–300 g ai/ha, 90– 540 g ai/ha, 150–400 g ai/ha, 400–560 g ai/ha, 50–300 g ai/ha, 110–480 g ai/ha, 75–420 g ai/ha, 65–360 g ai/ha, 170–300 g ai/ha, 200–300 g ai/ha, 220–600 g ai/ha, or 25–580 g ai/ha. Tefuryltrione In some aspects, the HPPD inhibitor herbicide can comprise tefuryltrione or an agriculturally acceptable salt or ester thereof. Tefuryltrione, shown below, is 2-[2-chloro-4- (methylsulfonyl)-3-[[(tetrahydro-2-furanyl)methoxy] methyl]benzoyl]-1,3-cyclohexandione. According to the online edition of The Pesticide Manual, tefuryltrione is a herbicide jointly developed by Bayer CropScience, Hokko Chemical, and Zen-Noh for pre-and post-emergence control of annual and perennial broadleaf weeds in rice and cereals. Tembotrione In some aspects, the HPPD inhibitor herbicide can comprise tembotrione or an agriculturally acceptable salt or ester thereof. Tembotrione, shown below, is 2-[2-chloro-4- (methylsulfonyl)-3-[(2,2,2-trifluoroethoxy) methyl]benzoyl]-1,3-cyclohexanedione. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of tembotrione include its use for post-emergence control of grass and broadleaf weed species in maize. Tembotrione can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, tembotrione is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 1.1 g ai/ha or more, 1.25 g ai/ha or more, 1.4 g ai/ha or more, 1.5 g ai/ha or more, 1.6 g ai/ha or more, 1.75 g ai/ha or more, 1.9 g ai/ha or more, 2 g ai/ha or more, 2.25 g ai/ha or more, 2.5 g ai/ha or more, 2.75 g ai/ha or more, 3 g ai/ha or more, 3.25 g ai/ha or more, 3.5 g ai/ha or more, 3.75 g ai/ha or more, 4 g ai/ha or more, 4.5 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 9.5 g ai/ha or more, 10 g ai/ha or more, 10.5 g ai/ha or more, 11 g ai/ha or more, 11.5 g ai/ha or more, 12 g ai/ha or more, 12.5 g ai/ha or more, 13 g ai/ha or more, 13.5 g ai/ha or more, 14 g ai/ha or more, 14.5 g ai/ha or more, 15 g ai/ha or more, 15.5 g ai/ha or more, 16 g ai/ha or more, 16.5 g ai/ha or more, 17 g ai/ha or more, 17.5 g ai/ha or more, 18 g ai/ha or more, 18.5 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, or 200 g ai/ha or more; in an amount of 200 g ai/ha or less, such as 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18.5 g ai/ha or less, 18 g ai/ha or less, 17.5 g ai/ha or less, 17 g ai/ha or less, 16.5 g ai/ha or less, 16 g ai/ha or less, 15.5 g ai/ha or less, 15 g ai/ha or less, 14.5 g ai/ha or less, 14 g ai/ha or less, 13.5 g ai/ha or less, 13 g ai/ha or less, 12.5 g ai/ha or less, 12 g ai/ha or less, 11.5 g ai/ha or less, 11 g ai/ha or less, 10.5 g ai/ha or less, 10 g ai/ha or less, 9.5 g ai/ha or less, 9 g ai/ha or less, 8.5 g ai/ha or less,8 g ai/ha or less, 7.5 g ai/ha or less, 7 g ai/ha or less, 6.5 g ai/ha or less, 6 g ai/ha or less, 5.5 g ai/ha or less, 5 g ai/ha or less, 4.5 g ai/ha or less, 4 g ai/ha or less, 3.75 g ai/ha or less, 3.5 g ai/ha or less, 3.25 g ai/ha or less, 3 g ai/ha or less, 2.75 g ai/ha or less, 2.5 g ai/ha or less, 2.25 g ai/ha or less, 2 g ai/ha or less, 1.9 g ai/ha or less, 1.75 g ai/ha or less, 1.6 g ai/ha or less, 1.5 g ai/ha or less, 1.4 g ai/ha or less, 1.25 g ai/ha or less, or 1.1 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–200 g ai/ha, 1.4–75 g ai/ha, 3.5–150 g ai/ha, 10– 140 g ai/ha, 6–75 g ai/ha, 8–180 g ai/ha, 1.5–25 g ai/ha, 2.5–15 g ai/ha, 2.25–10 g ai/ha, 25– 120 g ai/ha, 1.9–130 g ai/ha, 20–40 g ai/ha, 30–180 g ai/ha, 45–190 g ai/ha, 3.5–70 g ai/ha, 6– 130 g ai/ha, 70–90 g ai/ha, 15–110 g ai/ha, 120–140 g ai/ha, or 1.1–190 g ai/ha. Tolpyralate In some aspects, the HPPD inhibitor herbicide can comprise tolpyralate or an agriculturally acceptable salt or ester thereof. Tolpyralate, shown below, is 1-[[1-ethyl-4-[3- (2-methoxyethoxy)-2-methyl-4-(methylsulfonyl)benzoyl]-1H-pyr azol-5-yl]oxy]ethyl methyl carbonate. According to the online edition of The Pesticide Manual, tefuryltrione is a herbicide developed by Ishihara Sangyo Kaisha Ltd. for pre-and post-emergence control of broadleaf and grass weeds, including Palmer amaranth, water hemp, giant ragweed, and giant foxtail in maize. Topramezone In some aspects, the HPPD inhibitor herbicide can comprise topramezone or an agriculturally acceptable salt or ester thereof. Topramezone, shown below, is [3-(4,5-dihydro- 3-isoxazolyl)-2-methyl-4-(methylsulfonyl)phenyl](5-hydroxy-1 -methyl-1H-pyrazol-4- yl)methanone. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of topramezone include its use for post-emergence weed control in maize. Topramezone can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, topramezone is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 1.1 g ai/ha or more, 1.25 g ai/ha or more, 1.4 g ai/ha or more, 1.5 g ai/ha or more, 1.6 g ai/ha or more, 1.75 g ai/ha or more, 1.9 g ai/ha or more, 2 g ai/ha or more, 2.25 g ai/ha or more, 2.5 g ai/ha or more, 2.75 g ai/ha or more, 3 g ai/ha or more, 3.25 g ai/ha or more, 3.5 g ai/ha or more, 3.75 g ai/ha or more, 4 g ai/ha or more, 4.5 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 9.5 g ai/ha or more, 10 g ai/ha or more, 10.5 g ai/ha or more, 11 g ai/ha or more, 11.5 g ai/ha or more, 12 g ai/ha or more, 12.5 g ai/ha or more, 13 g ai/ha or more, 13.5 g ai/ha or more, 14 g ai/ha or more, 14.5 g ai/ha or more, 15 g ai/ha or more, 15.5 g ai/ha or more, 16 g ai/ha or more, 16.5 g ai/ha or more, 17 g ai/ha or more, 17.5 g ai/ha or more, 18 g ai/ha or more, 18.5 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, or 100 g ai/ha or more; in an amount of 100 g ai/ha or less, such as 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18.5 g ai/ha or less, 18 g ai/ha or less, 17.5 g ai/ha or less, 17 g ai/ha or less, 16.5 g ai/ha or less, 16 g ai/ha or less, 15.5 g ai/ha or less, 15 g ai/ha or less, 14.5 g ai/ha or less, 14 g ai/ha or less, 13.5 g ai/ha or less, 13 g ai/ha or less, 12.5 g ai/ha or less, 12 g ai/ha or less, 11.5 g ai/ha or less, 11 g ai/ha or less, 10.5 g ai/ha or less, 10 g ai/ha or less, 9.5 g ai/ha or less, 9 g ai/ha or less, 8.5 g ai/ha or less,8 g ai/ha or less, 7.5 g ai/ha or less, 7 g ai/ha or less, 6.5 g ai/ha or less, 6 g ai/ha or less, 5.5 g ai/ha or less, 5 g ai/ha or less, 4.5 g ai/ha or less, 4 g ai/ha or less, 3.75 g ai/ha or less, 3.5 g ai/ha or less, 3.25 g ai/ha or less, 3 g ai/ha or less, 2.75 g ai/ha or less, 2.5 g ai/ha or less, 2.25 g ai/ha or less, 2 g ai/ha or less, 1.9 g ai/ha or less, 1.75 g ai/ha or less, 1.6 g ai/ha or less, 1.5 g ai/ha or less, 1.4 g ai/ha or less, 1.25 g ai/ha or less, or 1.1 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–100 g ai/ha, 2–90 g ai/ha, 4–80 g ai/ha, 2.5–75 g ai/ha, 9–60 g ai/ha, 10–55 g ai/ha, 3–25 g ai/ha, 8–15 g ai/ha, 1.5–10 g ai/ha, 5–80 g ai/ha, 6.5–45 g ai/ha, 15–85 g ai/ha, 20–90 g ai/ha, 2.5–40 g ai/ha, 3–30 g ai/ha, 9–85 g ai/ha, or 1.5–95 g ai/ha. HPPD INHIBITOR HERBICIDES In addition to the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), the compositions can include an inhibitor of 4-hydroxyphenylpyruvate dioxygenase (HPPD), an oxygenase enzyme involved in the creation of energy in plants and higher order eukaryotes. Examples of HPPD inhibitors include benzobicyclon, benzofenap, bicyclopyrone, fenquinotrione, isoxachlortole, isoxaflutole, lancotrione, mesotrione, pyrasulfotole, pyrazolynate, pyrazoxyfen, sulcotrione, tefuryltrione, tembotrione, tolpyralate, topramezone, or an agriculturally acceptable salt or esters thereof, and combinations thereof. The HPPD inhibitor or agriculturally acceptable salt or ester thereof can be applied to vegetation or an area adjacent to the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, the HPPD inhibitor or agriculturally acceptable salt or ester thereof is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 grams active ingredient per hectare (g ai/ha) or more, such as 1.1 g ai/ha or more, 1.25 g ai/ha or more, 1.5 g ai/ha or more, 1.75 g ai/ha or more, 2 g ai/ha or more, 2.5 g ai/ha or more, 3 g ai/ha or more, 3.5 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 11 g ai/ha or more, 12 g ai/ha or more, 13 g ai/ha or more, 14 g ai/ha or more, 15 g ai/ha or more, 16 g ai/ha or more, 17 g ai/ha or more, 18 g ai/ha or more, 19 g ai/ha or more, 20 g ai/ha or more, 21 g ai/ha or more, 22 g ai/ha or more, 23 g ai/ha or more, 24 g ai/ha or more, 25 g ai/ha or more, 26 g ai/ha or more, 27 g ai/ha or more, 28 g ai/ha or more, 29 g ai/ha or more, 30 g ai/ha or more, 31 g ai/ha or more, 32 g ai/ha or more, 33 g ai/ha or more, 34 g ai/ha or more, 35 g ai/ha or more, 36 g ai/ha or more, 37 g ai/ha or more, 38 g ai/ha or more, 39 g ai/ha or more, 40 g ai/ha or more, 41 g ai/ha or more, 42 g ai/ha or more, 43 g ai/ha or more, 44 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, 2240 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2350 g ai/ha or more, 2400 g ai/ha or more, 2450 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2750 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3750 g ai/ha or more, 3800 g ai/ha or more, 3900 g ai/ha or more, 3950 g ai/ha or more, 4000 g ai/ha or more, 4100 g ai/ha or more, 4200 g ai/ha or more, 4250 g ai/ha or more, 4250 g ai/ha or more, 4300 g ai/ha or more, or 4350 g ai/ha or more, or 4400 g ai/ha or more; in an amount of 4500 g ai/ha or less, such as 4450 g ai/ha or less, 4400 g ai/ha or less, 4350 g ai/ha or less, 4300 g ai/ha or less, 4250 g ai/ha or less, 4100 g ai/ha or less, 4000 g ai/ha or less, 3950 g ai/ha or less, 3900 g ai/ha or less, 3800 g ai/ha or less, 3750 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2750 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2450 g ai/ha or less, 2400 g ai/ha or less, 2350 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2240 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1240 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 44 g ai/ha or less, 43 g ai/ha or less, 42 g ai/ha or less, 41 g ai/ha or less, 40 g ai/ha or less, 39 g ai/ha or less, 38 g ai/ha or less, 37 g ai/ha or less, 36 g ai/ha or less, 35 g ai/ha or less, 34 g ai/ha or less, 33 g ai/ha or less, 32 g ai/ha or less, 31 g ai/ha or less, 30 g ai/ha or less, 29 g ai/ha or less, 28 g ai/ha or less, 27 g ai/ha or less, 26 g ai/ha or less, 25 g ai/ha or less, 24 g ai/ha or less, 23 g ai/ha or less, 22 g ai/ha or less, 21 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18 g ai/ha or less, 17 g ai/ha or less, 16 ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, 11 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3.5 g ai/ha or less, 3 g ai/ha or less, 2.5 g ai/ha or less, 2 g ai/ha or less, 1.75 g ai/ha or less, 1.5 g ai/ha or less, 1.25 g ai/ha or less, or 1.1 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–4500 g ai/ha, 4–3900 g ai/ha, 1.75-2500 g ai/ha, 75–3100 g ai/ha, 90–900 g ai/ha, 55–4200 g ai/ha, 50–2350 g ai/ha, 80–2900 g ai/ha, 120–4100 g ai/ha, 65–2700 g ai/ha, 300–4000 g ai/ha, 1200–3600 g ai/ha, 250–2000 g ai/ha, 1.75-250 g ai/ha, 700–4250 g ai/ha, 39–1100 g ai/ha, or 1.1–4450 g ai/ha. In some aspects, the herbicidal composition contains a herbicidally effective amount of compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and (b) benzobicyclon, benzofenap, bicyclopyrone, fenquinotrione, isoxachlortole, isoxaflutole, lancotrione, mesotrione, pyrasulfotole, pyrazolynate, pyrazoxyfen, sulcotrione, tefuryltrione, tembotrione, tolpyralate, topramezone, agriculturally acceptable salts or esters, or combinations thereof. Benzobicyclon In some aspects, the HPPD inhibitor herbicide can comprise benzobicyclon or an agriculturally acceptable salt or ester thereof. Benzobicyclon, shown below, is 3-[2-chloro-4- (methylsulfonyl)benzoyl]-4-(phenylthio)bicyclo[3.2.1]oct-3-e n-2-one. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of benzobicyclon include its use for pre- to early post-emergence control of annual and perennial paddy weeds in direct-seeded and transplanted rice. Benzobicyclon can be applied to vegetation or an area adjacent to the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, benzobicyclon is applied to vegetation or an area adjacent to the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, or 400 g ai/ha or more; in an amount of 401 g ai/ha or less, such as 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, or 50 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50– 401 g ai/ha, 75–360 g ai/ha, 100–240 g ai/ha, 150–300 g ai/ha, 170–280 g ai/ha, 140–360 g ai/ha, 200–320 g ai/ha, 80–260 g ai/ha, or 55–400 g ai/ha. Benzofenap In some aspects, the HPPD inhibitor herbicide can comprise benzofenap or an agriculturally acceptable salt or ester thereof. Benzofenap, shown below, is 2-[[4-(2,4- dichloro-3-methylbenzoyl)-1,3-dimethyl-1H-pyrazol-5-yl]oxy]- 1-(4-methylphenyl) ethanone. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of benzofenap include its use for control of broadleaf weeds in rice. Benzofenap can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, benzofenap is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 300 g ai/ha or more, such as 310 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, or 1000 g ai/ha or more; in an amount of 1001 g ai/ha or less, such as 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, or 310 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 300–1001 g ai/ha, 450–1000 g ai/ha, 380–825 g ai/ha, 400–900 g ai/ha, 450–925 g ai/ha, 550–775 g ai/ha, 600–850 g ai/ha, 475– 950 g ai/ha, 340–925 g ai/ha, 650–975 g ai/ha, 725–1000 g ai/ha, 450–850 g ai/ha, 800–950 g ai/ha, or 310–975 g ai/ha. Bicyclopyrone In some aspects, the HPPD inhibitor herbicide can comprise bicyclopyrone or an agriculturally acceptable salt or ester thereof. Bicyclopyrone, shown below, is 4-hydroxy-3- [[2-[(2-methoxyethoxy)methyl]-6-(trifluoromethyl)-3-pyridiny l]carbonyl] bicyclo[3.2.1]oct- 3-en-2-one. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of bicyclopyrone include its use for pre- and early post- emergence control of broadleaf and grass weeds in maize and cereals. Bicyclopyrone can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, bicyclopyrone is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 20 g ai/ha or more, such as 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, or 400 g ai/ha; in an amount of 401 g ai/ha or less, such as 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, or 20 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 20–401 g ai/ha, 30–260 g ai/ha, 40–380 g ai/ha, 55–300 g ai/ha, 60–340 g ai/ha, 45–320 g ai/ha, 25–300 g ai/ha, 100–190 g ai/ha, 200–380 g ai/ha, 50– 200 g ai/ha, 30–300 g ai/ha, 85–220 g ai/ha, 30–65 g ai/ha, or 25–400 g ai/ha. Fenquinotrione In some aspects, the HPPD inhibitor herbicide can comprise fenquinotrione or an agriculturally acceptable salt or ester thereof. Fenquinotrione, shown below, is 2-[[8-chloro- 3,4-dihydro-4-(4-methoxyphenyl)-3-oxo-2-quinoxalinyl]carbony l]-1,3-cyclohexanedione. According to the online edition of The Pesticide Manual, fenquinotrione is a herbicide under development for use on rice. Isoxachlortole In some aspects, the HPPD inhibitor herbicide can comprise isoxachlortole or an agriculturally acceptable salt or ester thereof. Isoxachlortole, shown below, is [4-chloro-2- (methylsulfonyl)phenyl](5-cyclopropyl-4-isoxazolyl) methanone. According to the online edition of The Pesticide Manual, isoxachlortole is a herbicide that was evaluated by Rhône- Poulenc. Isoxaflutole In some aspects, the HPPD inhibitor herbicide can comprise isoxaflutole or an agriculturally acceptable salt or ester thereof. Isoxaflutole, shown below, is (5-cyclopropyl-4- isoxazolyl)[2-(methylsulfonyl)-4-(trifluoromethyl)phenyl] methanone. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of isoxaflutole include its use for pre- emergence or pre-plant control of grass and broadleaf weed in maize and sugar cane. Isoxaflutole can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, isoxaflutole is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 20 g ai/ha or more, such as 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, or 300 g ai/ha or more; in an amount of 301 g ai/ha or less, such as 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, or 25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 20–301 g ai/ha, 30–300 g ai/ha, 40–170 g ai/ha, 25–260 g ai/ha, 60–120 g ai/ha, 70–190 g ai/ha, 75–240 g ai/ha, 35–200 g ai/ha, 65–220 g ai/ha, 85–140 g ai/ha, 100–300 g ai/ha, 150–280 g ai/ha, 200–301 g ai/ha, 130–200 g ai/ha, 25–100 g ai/ha, 70–90 g ai/ha, or 25–300 g ai/ha. Lancotrione In some aspects, the HPPD inhibitor herbicide can comprise lancotrione or an agriculturally acceptable salt or ester thereof. Lancotrione, shown below, is 2-[2-chloro-3-[2- (1,3-dioxolan-2-yl)ethoxy]-4-(methylsulfonyl)benzoyl]-3-hydr oxy-2-cyclohexen-1-one. According to the online edition of The Pesticide Manual, lancotrione is a herbicide under development by Ishihara Sangyo Kaisha, Ltd. Mesotrione In some aspects, the HPPD inhibitor herbicide can comprise mesotrione or an agriculturally acceptable salt or ester thereof. Mesotrione, shown below, is 2-[4- (methylsulfonyl)-2-nitrobenzoyl]-1,3-cyclohexanedione. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of mesotrione include its use for pre- and post- emergence control of broadleaf weeds and some grass weeds in maize. Mesotrione can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, mesotrione is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 20 g ai/ha or more, such as 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, or 300 g ai/ha or more; in an amount of 301 g ai/ha or less, such as 300 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 125 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, or 25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 20–301 g ai/ha, 30–275 g ai/ha, 40–140 g ai/ha, 50–250 g ai/ha, 60–301 g ai/ha, 25–280 g ai/ha, 60–125 g ai/ha, 70–250 g ai/ha, 90–225 g ai/ha, 110–220 g ai/ha, 40–175 g ai/ha, 65–160 g ai/ha, 70–200 g ai/ha, 80–180 g ai/ha, 90–250 g ai/ha, 140–225 g ai/ha, 110– 240 g ai/ha, 120–175 g ai/ha, 110–150 g ai/ha, 25-85 g ai/ha, or 25–300 g ai/ha. Pyrasulfotole In some aspects, the HPPD inhibitor herbicide can comprise pyrasulfotole or an agriculturally acceptable salt or ester thereof. Pyrasulfotole, shown below, is (5-hydroxy-1,3- dimethyl-1H-pyrazol-4-yl)[2-(methylsulfonyl)-4-(trifluoromet hyl) phenyl]methanone. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of pyrasulfotole include its use in mixture with mefenpyr-diethyl and bromoxynil or MCPA ester, for post- emergence control of broadleaf weeds in cereals. Pyrasulfotole can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pyrasulfotole is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 1.1 g ai/ha or more, 1.25 g ai/ha or more, 1.4 g ai/ha or more, 1.5 g ai/ha or more, 1.6 g ai/ha or more, 1.75 g ai/ha or more, 1.9 g ai/ha or more, 2 g ai/ha or more, 2.25 g ai/ha or more, 2.5 g ai/ha or more, 2.75 g ai/ha or more, 3 g ai/ha or more, 3.25 g ai/ha or more, 3.5 g ai/ha or more, 3.75 g ai/ha or more, 4 g ai/ha or more, 4.5 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 9.5 g ai/ha or more, 10 g ai/ha or more, 10.5 g ai/ha or more, 11 g ai/ha or more, 11.5 g ai/ha or more, 12 g ai/ha or more, 12.5 g ai/ha or more, 13 g ai/ha or more, 13.5 g ai/ha or more, 14 g ai/ha or more, 14.5 g ai/ha or more, 15 g ai/ha or more, 15.5 g ai/ha or more, 16 g ai/ha or more, 16.5 g ai/ha or more, 17 g ai/ha or more, 17.5 g ai/ha or more, 18 g ai/ha or more, 18.5 g ai/ha or more, 20 g ai/ha or more, 21 g ai/ha or more, 22 g ai/ha or more, 23 g ai/ha or more, 24 g ai/ha or more, 25 g ai/ha or more, 26 g ai/ha or more, 27 g ai/ha or more, 28 g ai/ha or more, 29 g ai/ha or more, 30 g ai/ha or more, 31 g ai/ha or more, 32 g ai/ha or more, 33 g ai/ha or more, 34 g ai/ha or more, 35 g ai/ha or more, 36 g ai/ha or more, 37 g ai/ha or more, 38 g ai/ha or more, 39 g ai/ha or more, 40 g ai/ha or more, 41 g ai/ha or more, 42 g ai/ha or more, 43 g ai/ha or more, 44 g ai/ha or more, 45 g ai/ha or more, or 47 g ai/ha or more; in an amount of 50 g ai/ha or less, such as 47 g ai/ha or less, 45 g ai/ha or less, 44 g ai/ha or less, 43 g ai/ha or less, 42 g ai/ha or less, 41 g ai/ha or less, 40 g ai/ha or less, 39 g ai/ha or less, 38 g ai/ha or less, 37 g ai/ha or less, 36 g ai/ha or less, 35 g ai/ha or less, 34 g ai/ha or less, 33 g ai/ha or less, 32 g ai/ha or less, 31 g ai/ha or less, 30 g ai/ha or less, 29 g ai/ha or less, 28 g ai/ha or less, 27 g ai/ha or less, 26 g ai/ha or less, 25 g ai/ha or less, 24 g ai/ha or less, 23 g ai/ha or less, 22 g ai/ha or less, 21 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18.5 g ai/ha or less, 18 g ai/ha or less, 17.5 g ai/ha or less, 17 g ai/ha or less, 16.5 g ai/ha or less, 16 g ai/ha or less, 15.5 g ai/ha or less, 15 g ai/ha or less, 14.5 g ai/ha or less, 14 g ai/ha or less, 13.5 g ai/ha or less, 13 g ai/ha or less, 12.5 g ai/ha or less, 12 g ai/ha or less, 11.5 g ai/ha or less, 11 g ai/ha or less, 10.5 g ai/ha or less, 10 g ai/ha or less, 9.5 g ai/ha or less, 9 g ai/ha or less, 8.5 g ai/ha or less,8 g ai/ha or less, 7.5 g ai/ha or less, 7 g ai/ha or less, 6.5 g ai/ha or less, 6 g ai/ha or less, 5.5 g ai/ha or less, 5 g ai/ha or less, 4.5 g ai/ha or less, 4 g ai/ha or less, 3.75 g ai/ha or less, 3.5 g ai/ha or less, 3.25 g ai/ha or less, 3 g ai/ha or less, 2.75 g ai/ha or less, 2.5 g ai/ha or less, 2.25 g ai/ha or less, 2 g ai/ha or less, 1.9 g ai/ha or less, 1.75 g ai/ha or less, 1.6 g ai/ha or less, 1.5 g ai/ha or less, 1.4 g ai/ha or less, 1.25 g ai/ha or less, or 1.1 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–50 g ai/ha, 1.4–45 g ai/ha, 1.2–42 g ai/ha, 2.5–35 g ai/ha, 4– 30 g ai/ha, 6.5–29 g ai/ha, 1.25–24 g ai/ha, 3.75–18.5 g ai/ha, 2.5–38 g ai/ha, 11–17 g ai/ha, 8– 16 g ai/ha, 2.75–19 g ai/ha, 3–25 g ai/ha, 7–23 g ai/ha, 3.5–16 g ai/ha, 10–41 g ai/ha, 25–50 g ai/ha, 14–44 g ai/ha, 35–45 g ai/ha, 40–51 g ai/ha, or 1.1–47 g ai/ha. Pyrazolynate In some aspects, the HPPD inhibitor herbicide can comprise pyrazolynate or an agriculturally acceptable salt or ester thereof. Pyrazolynate, shown below, is (2,4- dichlorophenyl)[1,3-dimethyl-5-[[(4-methylphenyl) sulfonyl]oxy]-1H-pyrazol-4- yl]methanone. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of pyrazolynate include its use to control grasses, sedges, Potamogeton distinctus, Sagittaria pygmaea, Sagittaria trifolia and Alisma canaliculatum in paddy rice. Pyrazolynate can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pyrazolynate is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 200 g ai/ha or more, such as 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 350 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1400 g ai/ha or more, 1600 g ai/ha or more, 1800 g ai/ha or more, 2000 g ai/ha or more, 2200 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2800 g ai/ha or more, 3000 g ai/ha or more, 3200 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3800 g ai/ha or more, 4000 g ai/ha or more, 4200 g ai/ha or more, or 4400 g ai/ha or more; in an amount of 4500 g ai/ha or less, such as 4400 g ai/ha or less, 4200 g ai/ha or less, 4000 g ai/ha or less, 3800 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3200 g ai/ha or less, 3000 g ai/ha or less, 2800 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2200 g ai/ha or less, 2000 g ai/ha or less, 1800 g ai/ha or less, 1600 g ai/ha or less, 1400 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 350 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, or 225 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 200-4500 g ai/ha, 2000–4000 g ai/ha, 400–1600 g ai/ha, 1600–3800 g ai/ha, 750–3000 g ai/ha, 500–2200 g ai/ha, 1600–2500 g ai/ha, 250–800 g ai/ha, 2500–3400 g ai/ha, 1200–3500 g ai/ha, 350–1000 g ai/ha, or 225–4400 g ai/ha. Pyrazoxyfen In some aspects, the HPPD inhibitor herbicide can comprise pyrazoxyfen or an agriculturally acceptable salt or ester thereof. Pyrazoxyfen, shown below, is 2-[[4-(2,4- dichlorobenzoyl)-1,3-dimethyl-1H-pyrazol-5-yl]oxy]-1-phenyle thanone. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of pyrazoxyfen include pre- or post-emergence control of annual and perennial weeds in transplanted or direct-seeded paddy rice. Pyrazoxyfen can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pyrazoxyfen is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1000 g ai/ha or more, such as 1100 g ai/ha or more, 1200 g ai/ha or more, 1400 g ai/ha or more, 1600 g ai/ha or more, 1800 g ai/ha or more, 2000 g ai/ha or more, 2200 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2800 g ai/ha or more, 3000 g ai/ha or more, 3200 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3800 g ai/ha or more, 4000 g ai/ha or more, 4200 g ai/ha or more, or 4400 g ai/ha or more; in an amount of 4500 g ai/ha or less, such as 4400 g ai/ha or less, 4200 g ai/ha or less, 4000 g ai/ha or less, 3800 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3200 g ai/ha or less, 3000 g ai/ha or less, 2800 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2200 g ai/ha or less, 2000 g ai/ha or less, 1800 g ai/ha or less, 1600 g ai/ha or less, 1400 g ai/ha or less, 1200 g ai/ha or less, or 1100 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1000-4500 g ai/ha, 1100–4000 g ai/ha, 1400–3600 g ai/ha, 1200–1800 g ai/ha, 1800–4000 g ai/ha, 2200–4500 g ai/ha, 1500–3200 g ai/ha, 2000–3500 g ai/ha, 2500–3400 g ai/ha, or 1100–4400 g ai/ha. Sulcotrione In some aspects, the HPPD inhibitor herbicide can comprise sulcotrione or an agriculturally acceptable salt or ester thereof. Sulcotrione, shown below, is 2-[2-chloro-4- (methylsulfonyl)benzoyl]-1,3-cyclohexanedione. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of sulcotrione include its use to control broadleaf weeds and grasses post-emergence in maize and sugar cane. Sulcotrione can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, sulcotrione is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 20 g ai/ha or more, such as 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, or 580 g ai/ha or more; in an amount of 600 g ai/ha or less, such as 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, or 25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 20–600 g ai/ha, 40–400 g ai/ha, 65–420 g ai/ha, 120–240 g ai/ha, 300–460 g ai/ha, 400–580 g ai/ha, 30–500 g ai/ha, 250–560 g ai/ha, 250–440 g ai/ha, 75–520 g ai/ha, 35–300 g ai/ha, 90– 540 g ai/ha, 150–400 g ai/ha, 400–560 g ai/ha, 50–300 g ai/ha, 110–480 g ai/ha, 75–420 g ai/ha, 65–360 g ai/ha, 170–300 g ai/ha, 200–300 g ai/ha, 220–600 g ai/ha, or 25–580 g ai/ha. Tefuryltrione In some aspects, the HPPD inhibitor herbicide can comprise tefuryltrione or an agriculturally acceptable salt or ester thereof. Tefuryltrione, shown below, is 2-[2-chloro-4- (methylsulfonyl)-3- [[(tetrahydro-2-furanyl)-methoxy]-methyl]-benzoyl]- 1,3- cyclohexandione. According to the online edition of The Pesticide Manual, tefuryltrione is a herbicide jointly developed by Bayer CropScience, Hokko Chemical, and Zen-Noh for pre-and post-emergence control of annual and perennial broadleaf weeds in rice and cereals. Tembotrione In some aspects, the HPPD inhibitor herbicide can comprise tembotrione or an agriculturally acceptable salt or ester thereof. Tembotrione, shown below, is 2-[2-chloro-4- (methylsulfonyl)-3-[(2,2,2-trifluoroethoxy) methyl]benzoyl]-1,3-cyclohexanedione. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of tembotrione include its use for post-emergence control of grass and broadleaf weed species in maize. Tembotrione can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, tembotrione is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 1.1 g ai/ha or more, 1.25 g ai/ha or more, 1.4 g ai/ha or more, 1.5 g ai/ha or more, 1.6 g ai/ha or more, 1.75 g ai/ha or more, 1.9 g ai/ha or more, 2 g ai/ha or more, 2.25 g ai/ha or more, 2.5 g ai/ha or more, 2.75 g ai/ha or more, 3 g ai/ha or more, 3.25 g ai/ha or more, 3.5 g ai/ha or more, 3.75 g ai/ha or more, 4 g ai/ha or more, 4.5 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 9.5 g ai/ha or more, 10 g ai/ha or more, 10.5 g ai/ha or more, 11 g ai/ha or more, 11.5 g ai/ha or more, 12 g ai/ha or more, 12.5 g ai/ha or more, 13 g ai/ha or more, 13.5 g ai/ha or more, 14 g ai/ha or more, 14.5 g ai/ha or more, 15 g ai/ha or more, 15.5 g ai/ha or more, 16 g ai/ha or more, 16.5 g ai/ha or more, 17 g ai/ha or more, 17.5 g ai/ha or more, 18 g ai/ha or more, 18.5 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, or 200 g ai/ha or more; in an amount of 200 g ai/ha or less, such as 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18.5 g ai/ha or less, 18 g ai/ha or less, 17.5 g ai/ha or less, 17 g ai/ha or less, 16.5 g ai/ha or less, 16 g ai/ha or less, 15.5 g ai/ha or less, 15 g ai/ha or less, 14.5 g ai/ha or less, 14 g ai/ha or less, 13.5 g ai/ha or less, 13 g ai/ha or less, 12.5 g ai/ha or less, 12 g ai/ha or less, 11.5 g ai/ha or less, 11 g ai/ha or less, 10.5 g ai/ha or less, 10 g ai/ha or less, 9.5 g ai/ha or less, 9 g ai/ha or less, 8.5 g ai/ha or less,8 g ai/ha or less, 7.5 g ai/ha or less, 7 g ai/ha or less, 6.5 g ai/ha or less, 6 g ai/ha or less, 5.5 g ai/ha or less, 5 g ai/ha or less, 4.5 g ai/ha or less, 4 g ai/ha or less, 3.75 g ai/ha or less, 3.5 g ai/ha or less, 3.25 g ai/ha or less, 3 g ai/ha or less, 2.75 g ai/ha or less, 2.5 g ai/ha or less, 2.25 g ai/ha or less, 2 g ai/ha or less, 1.9 g ai/ha or less, 1.75 g ai/ha or less, 1.6 g ai/ha or less, 1.5 g ai/ha or less, 1.4 g ai/ha or less, 1.25 g ai/ha or less, or 1.1 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–200 g ai/ha, 1.4–75 g ai/ha, 3.5–150 g ai/ha, 10– 140 g ai/ha, 6–75 g ai/ha, 8–180 g ai/ha, 1.5–25 g ai/ha, 2.5–15 g ai/ha, 2.25–10 g ai/ha, 25– 120 g ai/ha, 1.9–130 g ai/ha, 20–40 g ai/ha, 30–180 g ai/ha, 45–190 g ai/ha, 3.5–70 g ai/ha, 6– 130 g ai/ha, 70–90 g ai/ha, 15–110 g ai/ha, 120–140 g ai/ha, or 1.1–190 g ai/ha. Tolpyralate In some aspects, the HPPD inhibitor herbicide can comprise tolpyralate or an agriculturally acceptable salt or ester thereof. Tolpyralate, shown below, is 1-[[1-ethyl-4-[3- (2-methoxyethoxy)-2-methyl-4-(methylsulfonyl)benzoyl]-1H-pyr azol-5-yl]oxy]ethyl methyl carbonate. According to the online edition of The Pesticide Manual, tefuryltrione is a herbicide developed by Ishihara Sangyo Kaisha Ltd. for pre-and post-emergence control of broadleaf and grass weeds, including Palmer amaranth, water hemp, giant ragweed, and giant foxtail in maize. Topramezone In some aspects, the HPPD inhibitor herbicide can comprise topramezone or an agriculturally acceptable salt or ester thereof. Topramezone, shown below, is [3-(4,5-dihydro- 3-isoxazolyl)-2-methyl-4-(methylsulfonyl) phenyl] (5-hydroxy-1-methyl- 1H-pyrazol-4-yl) methanone. Its herbicidal activity is exemplified in The Pesticide Manual. Exemplary uses of topramezone include its use for post-emergence weed control in maize. Topramezone can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, topramezone is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 1.1 g ai/ha or more, 1.25 g ai/ha or more, 1.4 g ai/ha or more, 1.5 g ai/ha or more, 1.6 g ai/ha or more, 1.75 g ai/ha or more, 1.9 g ai/ha or more, 2 g ai/ha or more, 2.25 g ai/ha or more, 2.5 g ai/ha or more, 2.75 g ai/ha or more, 3 g ai/ha or more, 3.25 g ai/ha or more, 3.5 g ai/ha or more, 3.75 g ai/ha or more, 4 g ai/ha or more, 4.5 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 9.5 g ai/ha or more, 10 g ai/ha or more, 10.5 g ai/ha or more, 11 g ai/ha or more, 11.5 g ai/ha or more, 12 g ai/ha or more, 12.5 g ai/ha or more, 13 g ai/ha or more, 13.5 g ai/ha or more, 14 g ai/ha or more, 14.5 g ai/ha or more, 15 g ai/ha or more, 15.5 g ai/ha or more, 16 g ai/ha or more, 16.5 g ai/ha or more, 17 g ai/ha or more, 17.5 g ai/ha or more, 18 g ai/ha or more, 18.5 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, or 100 g ai/ha or more; in an amount of 100 g ai/ha or less, such as 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 19 g ai/ha or less, 18.5 g ai/ha or less, 18 g ai/ha or less, 17.5 g ai/ha or less, 17 g ai/ha or less, 16.5 g ai/ha or less, 16 g ai/ha or less, 15.5 g ai/ha or less, 15 g ai/ha or less, 14.5 g ai/ha or less, 14 g ai/ha or less, 13.5 g ai/ha or less, 13 g ai/ha or less, 12.5 g ai/ha or less, 12 g ai/ha or less, 11.5 g ai/ha or less, 11 g ai/ha or less, 10.5 g ai/ha or less, 10 g ai/ha or less, 9.5 g ai/ha or less, 9 g ai/ha or less, 8.5 g ai/ha or less,8 g ai/ha or less, 7.5 g ai/ha or less, 7 g ai/ha or less, 6.5 g ai/ha or less, 6 g ai/ha or less, 5.5 g ai/ha or less, 5 g ai/ha or less, 4.5 g ai/ha or less, 4 g ai/ha or less, 3.75 g ai/ha or less, 3.5 g ai/ha or less, 3.25 g ai/ha or less, 3 g ai/ha or less, 2.75 g ai/ha or less, 2.5 g ai/ha or less, 2.25 g ai/ha or less, 2 g ai/ha or less, 1.9 g ai/ha or less, 1.75 g ai/ha or less, 1.6 g ai/ha or less, 1.5 g ai/ha or less, 1.4 g ai/ha or less, 1.25 g ai/ha or less, or 1.1 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–100 g ai/ha, 2–90 g ai/ha, 4–80 g ai/ha, 2.5–75 g ai/ha, 9–60 g ai/ha, 10–55 g ai/ha, 3–25 g ai/ha, 8–15 g ai/ha, 1.5–10 g ai/ha, 5–80 g ai/ha, 6.5–45 g ai/ha, 15–85 g ai/ha, 20–90 g ai/ha, 2.5–40 g ai/ha, 3–30 g ai/ha, 9–85 g ai/ha, or 1.5–95 g ai/ha. ACCASE INHIBITOR HERBICIDES In addition to the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), the compositions include an acetyl CoA carboxylase (ACCase) inhibitor herbicide or an agriculturally acceptable salt or ester thereof. ACCase inhibitor herbicides inhibit lipid biosynthesis in the plant. Examples of ACCase inhibitor herbicides include aryloxyphenoxypropionates, cyclohexanediones, and phenylpyrazolines. In some aspects, the ACCase inhibitor herbicide can include an aryloxyphenoxypropionate herbicide. In some aspects, the ACCase inhibitor herbicide can include a cyclohexanedione herbicide. In some aspects, the ACCase inhibitor herbicide can include a phenylpyrazoline herbicide. In some aspects, the composition can include an ACCase inhibitor selected from the group of cyclohexanediones, aryloxyphenoxypropionates, phenylpyrazolines, or combinations thereof. In some cases, the composition can include clodinafop, cyhalofop, diclofop, fenoxaprop, fenthiaprop, fluazifop, haloxyfop, metamifop, propaquizafop, quizalofop, agriculturally acceptable salts or esters thereof, or combinations thereof. In some cases, the composition can include, alloxydim, butroxydim, clethodim, cloproxydim, cycloxydim, profoxydim, pyriflubenzoxim, sethoxydim, tepraloxydim, tralkoxydim, agriculturally acceptable salts or esters thereof, or combinations thereof. In some cases, the composition can include pinoxaden. In some aspects, the composition can include an ACCase inhibitor herbicide selected from the group consisting of alloxydim, butroxydim, clethodim, clodinafop, cloproxydim, cycloxydim, cyhalofop, diclofop, fenoxaprop, fenthiaprop, fluazifop, haloxyfop, metamifop, pinoxaden, profoxydim, propaquizafop, quizalofop, sethoxydim, tepraloxydim, tralkoxydim, agriculturally acceptable salts and esters thereof, and combinations thereof. The ACCase inhibitor herbicide or agriculturally acceptable salt or ester thereof can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, the ACCase inhibitor herbicide or agriculturally acceptable salt or ester thereof is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2 g ai/ha or more, such as 2.5 g ai/ha or more, 3 g ai/ha or more, 3.5 g ai/ha or more, 4 g ai/ha or more, 4.5 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, or 1450 g ai/ha or more; in an amount of 1500 g ai/ha or less, such as 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1240 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4.5 g ai/ha or less, 4 g ai/ha or less, 3.5 g ai/ha or less, 3 g ai/ha or less, or 2.5 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2-1500 g ai/ha, 5–1300 g ai/ha, 6-250 g ai/ha, 75–1240 g ai/ha, 90–900 g ai/ha, 55–290 g ai/ha, 7–600 g ai/ha, 20–700 g ai/ha, 190–1450 g ai/ha, 65–1100 g ai/ha, 320–1000 g ai/ha, 250–750 g ai/ha, 700–1200 g ai/ha, 850–1400 g ai/ha, or 2.5–1450 g ai/ha. In some aspects, the composition contains: compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof); and (b) alloxydim, butroxydim, clethodim, clodinafop, cloproxydim, cycloxydim, cyhalofop, diclofop, fenoxaprop, fenthiaprop, fluazifop, haloxyfop, metamifop, pinoxaden, profoxydim, propaquizafop, quizalofop, sethoxydim, tepraloxydim, tralkoxydim, agriculturally acceptable salts and esters thereof, and combinations thereof. Alloxydim Compositions and methods of the present disclosure can include alloxydim or an agriculturally acceptable salt or ester thereof. Alloxydim, shown below, is a cyclohexanedione herbicide that provides post-emergence control of grass weeds and volunteer cereals in sugar beet, vegetables and broad-leaved crops. Alloxydim, as well as methods of preparing alloxydim, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Alloxydim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, alloxydim is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 299 g ai/ha or more, such as 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 620 g ai/ha or more, 640 g ai/ha or more, 660 g ai/ha or more, 680 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, or 1500 g ai/ha or more; in an amount of 1501 g ai/ha or less, such as 1500 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 680 g ai/ha or less, 660 g ai/ha or less, 640 g ai/ha or less, 620 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, or 300 g ai/ha or less; or from any of the minimum values described above to any of the maximum values described above, such as 299–1501 g ai/ha, 380–1250 g ai/ha, 440–850 g ai/ha, 700– 1000 g ai/ha, 320–950 g ai/ha, 680–1350 g ai/ha, 400–1050 g ai/ha, 500–1000 g ai/ha, 600– 900 g ai/ha, 700–1300 g ai/ha, 500–700 g ai/ha, or 320-1400 g ai/ha. Butroxydim Compositions and methods of the present disclosure can include butroxydim or an agriculturally acceptable salt or ester thereof. Butroxydim, shown below, is a cyclohexanedione herbicide that provides post-emergence control of annual grasses in many broad-leaved crops. Butroxydim, as well as methods of preparing butroxydim, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Butroxydim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, butroxydim is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 9 g ai/ha or more, such as10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 105 g ai/ha or more, 110 g ai/ha or more, 115 g ai/ha or more, or 120 g ai/ha or more; in an amount of 121 g ai/ha or less, such as 120 g ai/ha or less, 115 g ai/ha or less, 110 g ai/ha or less, 105 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, or 10 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 9–121 g ai/ha, 10–115 g ai/ha, 20–110 g ai/ha, 15–85 g ai/ha, 30–100 g ai/ha, 50–95 g ai/ha, 15–60 g ai/ha, 25–85 g ai/ha, 40–80 g ai/ha, 20–75 g ai/ha, 35–110 g ai/ha, 25–105 g ai/ha, 15–55 g ai/ha, or 10–120 g ai/ha. Clethodim Compositions and methods of the present disclosure can include clethodim or an agriculturally acceptable salt or ester thereof. Clethodim, shown below, is a cyclohexanedione herbicide that provides post-emergence control of annual and perennial grasses in a wide range of broad-leaved crops, including such field crops as canola/oilseed rape, soybean, cotton, flax, sunflowers, alfalfa, peanuts, sugar beet, tobacco, and potatoes, as well as vegetable crops, trees, and vines. Clethodim, as well as methods of preparing clethodim, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Clethodim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, clethodim is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2 g ai/ha or more, such as 3 g ai/ha or more, 4 g ai/ha or more, 6 g ai/ha or more, 8 g ai/ha or more, 10 g ai/ha or more, 12 g ai/ha or more, 14 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 620 g ai/ha or more, 640 g ai/ha or more, 660 g ai/ha or more, 680 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, or 875 g ai/ha or more; in an amount of 900 g ai/ha or less, such as 875 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 680 g ai/ha or less, 660 g ai/ha or less, 640 g ai/ha or less, 620 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 235 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 215 g ai/ha or less, 210 g ai/ha or less, 205 g ai/ha or less, 200 g ai/ha or less, 195 g ai/ha or less, 190 g ai/ha or less, 185 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 165 g ai/ha or less, 160 g ai/ha or less, 155 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 18 g ai/ha or less, 16 g ai/ha or less, 14 g ai/ha or less, 12 g ai/ha or less, 10 g ai/ha or less, 8 g ai/ha or less, 6 g ai/ha or less, 4 g ai/ha or less, or 3 g ai/ha or less, or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2–900 g ai/ha, 3–800 g ai/ha, 6–700 g ai/ha, 22–500 g ai/ha, 12–600 g ai/ha, 5–500 g ai/ha, 40–440 g ai/ha, 20–700 g ai/ha, 80–400 g ai/ha, 60–270 g ai/ha, 80–750 g ai/ha, 100–290 g ai/ha, 175–750 g ai/ha, 300–900 g ai/ha, 3–100 g ai/ha, 35–320 g ai/ha, 3–205 g ai/ha, 4–50 g ai/ha, or 3–875 g ai/ha. Clodinafop Compositions and methods of the present disclosure can include clodinafop or an agriculturally acceptable salt or ester thereof. Clodinafop-propargyl, shown below, is prop-2- ynyl (R)-2-[4-(5-chloro-3-fluoropyridin-2-yloxy)phenoxy]propionat e and is used for post- emergence control of annual grasses, including Avena, Lolium, Setaria, Phalaris, and Alopecurus spp., in cereals. . Clodinafop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, clodinafop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 10 g ai/ha or more, such as 11 g ai/ha or more, 12 g ai/ha or more, 13 g ai/ha or more, 14 g ai/ha or more,15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, or 95 g ai/ha or more; in an amount of 100 g ai/ha or less, such as 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, or 11 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 10– 100 g ai/ha, 15–90 g ai/ha, 12–80 g ai/ha, 25–70 g ai/ha, 14–40 g ai/ha, 20–85 g ai/ha, 30–60 g ai/ha, 40–90 g ai/ha, 50–100 g ai/ha, 20–90 g ai/ha, 50–95 g ai/ha, 30–90 g ai/ha, 20–60 g ai/ha, 30–80 g ai/ha, 13–75 g ai/ha, or 11–95 g ai/ha. Cloproxydim Compositions and methods of the present disclosure can include cloproxydim or an agriculturally acceptable salt or ester thereof. Cloproxydim, shown below, is a cyclohexanedione herbicide that has been evaluated by the Chevron Chemical Company. Cloproxydim provides post-emergence control of a wide range of annual and perennial grasses in beans, cotton, potatoes, sugar beets, and most vegetable crops. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Cycloxydim Compositions and methods of the present disclosure can include cycloxydim or an agriculturally acceptable salt or ester thereof. Cycloxydim, shown below, is a cyclohexanedione herbicide that provides post-emergence control of annual and perennial grasses (except red fescue and Poa spp.) in canola/oilseed rape, beans, potatoes, brassicas, cotton, celery, fennel, beetroot, sugar beets, fodder beets, sunflowers, soybeans, flax, alfalfa, crucifers, and alliums. Cycloxydim, as well as methods of preparing cycloxydim, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Cycloxydim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, cycloxydim is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 55 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, or 675 g ai/ha or more;in an amount of 700 g ai/ha or less, such as 675 g ai/ha or less, 650 g ai/ha or less, 640 g ai/ha or less, 620 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 195 g ai/ha or less, 190 g ai/ha or less, 185 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 165 g ai/ha or less, 160 g ai/ha or less, 155 g ai/ha or less, 150 g ai/ha or less, 145 g ai/ha or less, 140 g ai/ha or less, 135 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 115 g ai/ha or less, 110 g ai/ha or less, 105 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, or 55 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–700 g ai/ha, 60–600 g ai/ha, 90–400 g ai/ha, 100–580 g ai/ha, 50–300 g ai/ha, 75–460 g ai/ha, 110–620 g ai/ha, 190–280 g ai/ha, 140–400 g ai/ha, 95– 660 g ai/ha, 80–580 g ai/ha, 200–700 g ai/ha, 250–300 g ai/ha, 65–400 g ai/ha, 90–320 g ai/ha, or 55–675 g ai/ha. Cyhalofop Compositions and methods of the present disclosure can include cyhalofop or an agriculturally acceptable salt or ester thereof. Cyhalofop, as well as methods of preparing cyhalofop, are known in the art. Cyhalofop is an aryloxyphenoxypropionate ester that is used for post-emergence control of grass weeds in rice. Cyhalofop-butyl, shown below, is an ester of cyhalofop. Cyhalofop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, cyhalofop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 20 g ai/ha or more, such as 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 120 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 180 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, or 500 g ai/ha or more; in an amount of 500 g ai/ha or less, such as 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 180 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 120 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, or 25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 20–500 g ai/ha, 20–450 g ai/ha, 25–200 g ai/ha, 40–400 g ai/ha, 60–375 g ai/ha, 40–350 g ai/ha, 50–250 g ai/ha, 60–325 g ai/ha, 90–275 g ai/ha, 70–325 g ai/ha, 40–225 g ai/ha, 140–300 g ai/ha, 35-160 g ai/ha, 80–350 g ai/ha, 150–450 g ai/ha, 200–425 g ai/ha, or 25–475 g ai/ha. Diclofop Compositions and methods of the present disclosure can include diclofop or an agriculturally acceptable salt or ester thereof. Diclofop-methyl, shown below, is an aryloxyphenoxypropionate that is used for post-emergence control of wild oats, wild millets, and other annual grass weeds in wheat, barley, rye, red fescue, and broad-leaved crops such as soybeans, sugar beets, fodder beets, flax, legumes, canola/oilseed rape, sunflowers, clover, alfalfa, peanuts, brassicas, carrots, celery, parsnips, lettuce, spinach, potatoes, cucumbers, peas, beans, tomatoes, fennel, alliums, and herbs. Diclofop, as well as methods of preparing diclofop, are known in the art. Diclofop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, diclofop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount 100 g ai/ha or more, such as 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 620 g ai/ha or more, 640 g ai/ha or more, 660 g ai/ha or more, 680 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, or 1200 g ai/ha or more; in an amount of 1200 g ai/ha or less, such as 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 680 g ai/ha or less, 660 g ai/ha or less, 640 g ai/ha or less, 620 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, or 101 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 100–1200 g ai/ha, 120–1200 g ai/ha, 140–1100 g ai/ha, 150–900 g ai/ha, 175–1000 g ai/ha, 200–1150 g ai/ha, 360–1050 g ai/ha, 220–640 g ai/ha, 240–800 g ai/ha, 110–700 g ai/ha, 300–440 g ai/ha, 750– 1000 g ai/ha, 360–950 g ai/ha, 175–850 g ai/ha, 400–650 g ai/ha, 150–280 g ai/ha, 500–600 g ai/ha, or 110–1150 g ai/ha). Fenoxaprop Compositions and methods of the present disclosure can include fenoxaprop or an agriculturally acceptable salt or ester thereof. Fenoxaprop is an aryloxyphenoxypropionate that is used for post-emergence control of annual and perennial grass weeds in potatoes, beans, soybeans, beets, vegetables, peanuts, and cotton; and (when applied with the herbicide safener fenchlorazole-ethyl) annual and perennial grass weeds and wild oats in wheat, rye, and triticale. Fenoxaprop-P-ethyl, shown below, is an ester of fenoxaprop. Fenoxaprop, as well as methods of preparing fenoxaprop, are known in the art. Fenoxaprop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, fenoxaprop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 25 g ai/ha or more, such as 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 105 g ai/ha or more, 110 g ai/ha or more, 115 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 135 g ai/ha or more, 140 g ai/ha or more, 145 g ai/ha or more, or 150 g ai/ha or more; in an amount of 151 g ai/ha or less, such as 150 g ai/ha or less, 145 g ai/ha or less, 140 g ai/ha or less, 135 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 115 g ai/ha or less, 110 g ai/ha or less, 105 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, or 25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 25–151 g ai/ha, 30–150 g ai/ha, 35–140 g ai/ha, 50–130 g ai/ha, 30–125 g ai/ha, 85–150 g ai/ha, 45–145 g ai/ha, 25–110 g ai/ha, 40–90 g ai/ha, 55–120 g ai/ha, 40–115 g ai/ha, 60–110 g ai/ha, 30–105 g ai/ha, 90–151 g ai/ha, 25–95 g ai/ha, 50–80 g ai/ha, 60–125 g ai/ha, or 25–145 g ai/ha. Fenthiaprop Compositions and methods of the present disclosure can include fenthiaprop or an agriculturally acceptable salt or ester thereof. Fenthiaprop, shown below, is an aryloxyphenoxypropionate herbicide that is used for post-emergence control of many annual and perennial grasses and volunteer cereals in canola/oilseed rape, potatoes, and sugar beets. Fenthiaprop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, fenthiaprop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount 150 g ai/ha or more, such as 160 g ai/ha or more,170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 550 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 620 g ai/ha or more, 640 g ai/ha or more, 650 g ai/ha or more, 660 g ai/ha or more, 680 g ai/ha or more, 700 g ai/ha or more, or 725 g ai/ha or more; in an amount of 750 g ai/ha or less, such as 725 g ai/ha or less, 700 g ai/ha or less, 680 g ai/ha or less, 660 g ai/ha or less, 650 g ai/ha or less, 640 g ai/ha or less, 620 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 550 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, or 160 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 150–750 g ai/ha, 180–600 g ai/ha, 170–650 g ai/ha, 250–700 g ai/ha, 280–450 g ai/ha, 360– 580 g ai/ha, 220–640 g ai/ha, 240–725 g ai/ha, 340–440 g ai/ha, 260–550 g ai/ha, 170–250 g ai/ha, 400–650 g ai/ha, 190–580 g ai/ha, 500–600 g ai/ha, or 160–725 g ai/ha. Fluazifop Compositions and methods of the present disclosure can include fluazifop or an agriculturally acceptable salt or ester thereof. Fluazifop is an aryloxyphenoxypropionate that is used for post-emergence control of annual and perennial grass weeds in broad-leaved crops, including control of volunteer cereals and other grass weeds in canola/oilseed rape, sugar beet, fodder beet, potatoes, cotton, soybeans, peanuts, pome fruit, bush fruit, vines, citrus fruit, pineapples, bananas, strawberries, sunflowers, alfalfa, coffee, ornamentals and many vegetables. Fluazifop-P-butyl, shown below, is an ester of fluazifop. Fluazifop, as well as methods of preparing fluazifop, are known in the art. Fluazifop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, fluazifop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 100 grams active ingredient per hectare (g ai/ha) or more, such as 105 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, or 1350 g ai/ha or more; in an amount of 1400 g ai/ha or less, such as 1350 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less or 105 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, e.g., 100–1400 g ai/ha, 140–1300 g ai/ha, 180–1200 g ai/ha, 200–950 g ai/ha, 300–800 g ai/ha, 250– 700 g ai/ha, 130–450 g ai/ha, 100–500 g ai/ha, 190–850 g ai/ha, 110–375 g ai/ha, 225–475 g ai/ha, 130–600 g ai/ha, 150–1200 g ai/ha, 190-700 g ai/ha, 175–350 g ai/ha, 500–1100 g ai/ha, or 105–1350 g ai/ha. Haloxyfop Compositions and methods of the present disclosure can include haloxyfop or an agriculturally acceptable salt or ester thereof. Haloxyfop is an aryloxyphenoxypropionate that is used post-emergence for control of annual and perennial grasses in sugar beets, fodder beets, canola/oilseed rape, potatoes, leafy vegetables, onions, flax, sunflowers, soybeans, vines, strawberries and other crops. Haloxyfop-P-methyl, shown below, is an ester of haloxyfop; haloxyfop-R-methyl is the racemic form of this herbicide. Haloxyfop, as well as methods of preparing haloxyfop, are known in the art. Haloxyfop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, haloxyfop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 24 g ai/ha or more, such as 25 g ai/ha or more, 30 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, or 245 g ai/ha or more; in an amount of 250 g ai/ha or less, such as 245 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, or 25 g ai/ha or less; in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 24–250 g ai/ha, 25–225 g ai/ha, 35–200 g ai/ha, 55–190 g ai/ha, 25–180 g ai/ha, 30–175 g ai/ha, 30–230 g ai/ha, 130–220 g ai/ha, 60–160 g ai/ha, 75–150 g ai/ha, 35–150 g ai/ha, 60–140 g ai/ha, 80–230 g ai/ha, 90–210 g ai/ha, 55–110 g ai/ha, 70–240 g ai/ha, or 25– 245 g ai/ha. Metamifop Compositions and methods of the present disclosure can include metamifop. Metamifop, shown below, is an aryloxyphenoxypropionate that is used for post-emergence control of annual and perennial grass weeds (including Echinochloa spp., Leptochloa chinensis, Digitaria spp. and Eleusine indica) in rice, wheat, soybeans, cotton, and turf grass. Metamifop, as well as methods of preparing metamifop, are known in the art. Metamifop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, metamifop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 105 g ai/ha or more, 110 g ai/ha or more, 115 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 135 g ai/ha or more, 140 g ai/ha or more, 145 g ai/ha or more, 150 g ai/ha or more, 155 g ai/ha or more, 160 g ai/ha or more, 165 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 185 g ai/ha or more, 190 g ai/ha or more, 195 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, or 295 g ai/ha or more; in an amount of 300 g ai/ha or less, such as 295 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 195 g ai/ha or less, 190 g ai/ha or less, 185 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 165 g ai/ha or less, 160 g ai/ha or less, 155 g ai/ha or less, 150 g ai/ha or less, 145 g ai/ha or less, 140 g ai/ha or less, 135 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 115 g ai/ha or less, 110 g ai/ha or less, 105 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, or 55 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–300 g ai/ha, 60–275 g ai/ha, 80–250 g ai/ha, 55–125 g ai/ha, 60–200 g ai/ha, 70–160 g ai/ha, 80–210 g ai/ha, 90–270 g ai/ha, 100– 175 g ai/ha, 120–230 g ai/ha, 145–250 g ai/ha, or 55–295 g ai/ha. Pinoxaden Compositions and methods of the present disclosure can include pinoxaden or an agriculturally acceptable salt or ester thereof. Pinoxaden, shown below, is a phenylpyrazoline herbicide that provides post-emergence control of grass weeds in wheat, barley, lawns, and turf. Pinoxaden, as well as methods of preparing pinoxaden, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Pinoxaden can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pinoxaden is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2 g ai/ha or more, such as 2.5 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 8 g ai/ha or more, 10 g ai/ha or more, 12 g ai/ha or more, 14 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, or 490 g ai/ha or more; in an amount of 500 g ai/ha or less, such as 490 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 235 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 215 g ai/ha or less, 210 g ai/ha or less, 205 g ai/ha or less, 200 g ai/ha or less, 195 g ai/ha or less, 190 g ai/ha or less, 185 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 165 g ai/ha or less, 160 g ai/ha or less, 155 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 18 g ai/ha or less, 16 g ai/ha or less, 14 g ai/ha or less, 12 g ai/ha or less, 10 g ai/ha or less, 8 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, or 2.5 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2–500 g ai/ha, 3–400 g ai/ha, 5–300 g ai/ha, 8–100 g ai/ha, 5–500 g ai/ha, 10–120 g ai/ha, 22–190 g ai/ha, 40–300 g ai/ha, 30–400 g ai/ha, 80–270 g ai/ha, 100–480 g ai/ha, 150–250 g ai/ha, 110–380 g ai/ha, 8–235 g ai/ha, 30–260 g ai/ha, 24–50 g ai/ha, 10–300 g ai/ha, 16–180 g ai/ha, or 2.5–490 g ai/ha. Profoxydim Compositions and methods of the present disclosure can include profoxydim or an agriculturally acceptable salt or ester thereof. Profoxydim, shown below, is a cyclohexanedione herbicide. Profoxydim is used for control of grass weeds, including Echinochloa spp., Brachiaria spp., Digitaria spp., Eleusine spp., Leptochloa spp., Setaria spp., Ischaemum rugosum and Rottboellia exaltata, in rice. Profoxydim, as well as methods of preparing profoxydim, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Profoxydim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, profoxydim is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 105 g ai/ha or more, 110 g ai/ha or more, 115 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 135 g ai/ha or more, 140 g ai/ha or more, 145 g ai/ha or more, 150 g ai/ha or more, 155 g ai/ha or more, 160 g ai/ha or more, 165 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 185 g ai/ha or more, 190 g ai/ha or more, 195 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 280 g ai/ha or more, or 290 g ai/ha or more; in an amount of 300 g ai/ha or less (e.g., 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 195 g ai/ha or less, 190 g ai/ha or less, 185 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 165 g ai/ha or less, 160 g ai/ha or less, 155 g ai/ha or less, 150 g ai/ha or less, 145 g ai/ha or less, 140 g ai/ha or less, 135 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 115 g ai/ha or less, 110 g ai/ha or less, 105 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, or 55 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–300 g ai/ha., 60–275 g ai/ha, 85–250 g ai/ha, 60–220 g ai/ha, 120–280 g ai/ha, 150– 180 g ai/ha, 70–160 g ai/ha, 55–240 g ai/ha, 90–290 g ai/ha, 75–100 g ai/ha, 115–270 g ai/ha, 70–200 g ai/ha, or 55–290 g ai/ha. Propaquizafop Compositions and methods of the present disclosure can include propaquizafop. Propaquizafop, shown below, is an aryloxyphenoxypropionate that is to control a wide range of annual and perennial grasses in soybeans, cotton, sugar beets, potatoes, peanuts, peas, canola/oilseed rape and vegetables. Propaquizafop, as well as methods of preparing propaquizafop, are known in the art. Propaquizafop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, propaquizafop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 29 g ai/ha or more, such as 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 280 g ai/ha or more, or 290 g ai/ha or more; in an amount of 300 g ai/ha or less (e.g., 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, or 30 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 29–300 g ai/ha, 30–290 g ai/ha, 35–180 g ai/ha, 40–270 g ai/ha, 45–200 g ai/ha, 50–250 g ai/ha, 60–140 g ai/ha, 80–230 g ai/ha, 40–220 g ai/ha, 65–290 g ai/ha, 35–200 g ai/ha, 80–180 g ai/ha, 60–260 g ai/ha, 30–120 g ai/ha, 80–190 g ai/ha, 160–270 g ai/ha, or 30–290 g ai/ha. Quizalofop Compositions and methods of the present disclosure can include quizalofop or an agriculturally acceptable salt or ester thereof. Quizalofop is an aryloxyphenoxypropionate that is used for selective post-emergence control of annual and perennial grass weeds in potatoes, soybeans, sugar beets, peanuts, canola/oilseed rape, sunflowers, vegetables, cotton and flax. Quizalofop-P-ethyl, shown below, is an ester of quizalofop. Quizalofop, as well as methods of preparing quizalofop, are known in the art. Quizalofop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, quizalofop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 24 g ai/ha or more, such as 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, or 245 g ai/ha or more; in an amount of 250 g ai/ha or less (e.g., 245 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, or 25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 24–250 g ai/ha, 25–225 g ai/ha, 55–200 g ai/ha, 40–190 g ai/ha, 25–80 g ai/ha, 60–175 g ai/ha, 110–225 g ai/ha, 75–160 g ai/ha, 45–220 g ai/ha, 80–150 g ai/ha, 30–90 g ai/ha, 40–100 g ai/ha, 50–180 g ai/ha, 60–230 g ai/ha, 60–120 g ai/ha, 40–100 g ai/ha, or 25–245 g ai/ha. Sethoxydim Compositions and methods of the present disclosure can include sethoxydim or an agriculturally acceptable salt or ester thereof. Sethoxydim, shown below, is a cyclohexanedione herbicide that is used for controlling annual and perennial grasses in broad- leaved crops, including canola/oilseed rape, soybean, cotton, fodder beets, sunflowers, spinach, potatoes, tobacco, peanuts, strawberries, alfalfa, flax, vegetables, and sugar beet. Sethoxydim, as well as methods of preparing sethoxydim, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Sethoxydim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, sethoxydim is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2 g ai/ha or more, such as 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 8 g ai/ha or more, 10 g ai/ha or more, 12 g ai/ha or more, 14 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 620 g ai/ha or more, 640 g ai/ha or more, 660 g ai/ha or more, 680 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, or 900 g ai/ha or more; in an amount of 900 g ai/ha or less, such as 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 680 g ai/ha or less, 660 g ai/ha or less, 640 g ai/ha or less, 620 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 235 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 215 g ai/ha or less, 210 g ai/ha or less, 205 g ai/ha or less, 200 g ai/ha or less, 195 g ai/ha or less, 190 g ai/ha or less, 185 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 165 g ai/ha or less, 160 g ai/ha or less, 155 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 18 g ai/ha or less, 16 g ai/ha or less, 14 g ai/ha or less, 12 g ai/ha or less, 10 g ai/ha or less, 8 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or more, 4 g ai/ha or less, or 3 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2–900 g ai/ha, 3–500 g ai/ha, 5–270 g ai/ha, 10–600 g ai/ha, 22-440 g ai/ha, 35–560 g ai/ha, 10–400 g ai/ha, 20–700 g ai/ha, 40–280 g ai/ha, 60–680 g ai/ha, 100–750 g ai/ha, 90–300 g ai/ha, 200–700 g ai/ha, 300–500 g ai/ha, 3–100 g ai/ha, 5–90 g ai/ha, 12–105 g ai/ha, or 3–850 g ai/ha. Tepraloxydim Compositions and methods of the present disclosure can include tepraloxydim or an agriculturally acceptable salt or ester thereof. Tepraloxydim, shown below, is a cyclohexanedione herbicide that is used for broad-spectrum post-emergence grass weed control, especially Poa annua and volunteer maize, and also Sorghum halepense and Elymus repens, in broad-leaved crops. Tepraloxydim, as well as methods of preparing tepraloxydim, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Tepraloxydim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, tepraloxydim is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 25 g ai/ha or more, such as 27.5 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, or 195 g ai/ha or more; in an amount of 200 g ai/ha or less, such as 195 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, or 27.5 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 25–200 g ai/ha, 25–190 g ai/ha, 60–180 g ai/ha, 35–170 g ai/ha, 45–120 g ai/ha, 25–65 g ai/ha, 90–160 g ai/ha, 75–195 g ai/ha, 25–150 g ai/ha, 30–190 g ai/ha, 35–130 g ai/ha, 50–120 g ai/ha, 65–180 g ai/ha, or 27.5–195 g ai/ha. Tralkoxydim Compositions and methods of the present disclosure can include tralkoxydim or an agriculturally acceptable salt or ester thereof. Tralkoxydim is a cyclohexanedione herbicide that has the chemical name 2-[1-(ethoxyimino)propyl]-3-hydroxy-5-mesitylcyclohex-2-enon e, and has the following structure: Tralkoxydim is used for post-emergence control of annual grass weeds (including Avena spp., Lolium spp., Setaria viridis, Phalaria spp., Alopecurus myosuroides, and Apera spica-venti) in wheat and barley. Tralkoxydim, as well as methods of preparing tralkoxydim, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Tralkoxydim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 95 g ai/ha or more, such as 100 g ai/ha or more, 105 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, or 500 g ai/ha or more; in an amount of 501 g ai/ha or less, such as 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, or 100 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 95–501 g ai/ha., 100–475 g ai/ha, 120–450 g ai/ha, 110–425 g ai/ha, 225–400 g ai/ha, 150–425 g ai/ha, 180–375 g ai/ha, 190–350 g ai/ha, 110–225 g ai/ha, 180–500 g ai/ha, or 100–500 g ai/ha. PLANT GROWTH REGULATORS In addition to the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), the compositions can include a plant growth regulator (PGR), an agriculturally acceptable salt or ester thereof, or mixtures thereof. PGRs, also called plant hormones, act as chemical messengers for intercellular communication. PGRs can be classified into a number of modes of action that may influence, for example, the growth, division, elongation, or differentiation of plant cells. Examples of PGRs include 1,4- dimethylnapththalene, 1-methylcyclopropene, 1-napthylacetic acid, 2,6- diisopropylnaphthalene, 2-naphthyloxyacetic acid, 4-chlorophenoxyacetic acid (4-CPA), 6- benzylaminopurine, abscisic acid, amidochlor, ancymidol, aviglycine, butralin, carbaryl, chlorflurenol, chlormequat, chlorphonium chloride, chlorpropham, clofencet, cloprop, cloxyfonac, cuprous chloride, cyanamide, cyclanilide, cycloheximide, cytokinins, daminozide, decan-1-ol, dikegulac, dimethipin, dimexano, endothal, etacelasil, ethephon, ethychlozate, fenoprop, fenridazon, flumetralin, flurenol, flurprimidol, forchlorfenuron, gibberellins, glyphosine, heptamaloxyloglucan, heptopargil, hexafluoroacetone trihydrate, inabenfide, indol-3-butyric acid (IBA), indol-3-ylacetic acid (IAA), isoprothiolane, maleic hydrazide, mefluidide, mepiquat, N-acetylthiazolidine-4-carboxylic acid, naphthaleneacetamide, N-m- tolylphthalamic acid, N-phenylphthalamic acid, nitrophenolates, paclobutrazol, pelargonic acid, piproctanyl bromide, prohexadione, prohydrojasmon, propham, propyl-3-tert- butylphenoxyacetate, sintofen, tetcyclacis, thidiazuron, triacontanol, triapenthenol, trinexapac, and uniconazole. In some aspects, the composition can include a PGR selected from the group consisting of 1,4-dimethylnapththalene, 1-methylcyclopropene, 1-napthylacetic acid, 2,6- diisopropylnaphthalene, 2-naphthyloxyacetic acid, 4-chlorophenoxyacetic acid (4-CPA), 6- benzylaminopurine, abscisic acid, amidochlor, ancymidol, aviglycine, butralin, carbaryl, chlorflurenol, chlormequat, chlorphonium chloride, chlorpropham, clofencet, cloprop, cloxyfonac, cuprous chloride, cyanamide, cyclanilide, cycloheximide, cytokinins, daminozide, decan-1-ol, dikegulac, dimethipin, dimexano, endothal, etacelasil, ethephon, ethychlozate, fenoprop, fenridazon, flumetralin, flurenol, flurprimidol, forchlorfenuron, gibberellins, glyphosine, heptamaloxyloglucan, heptopargil, hexafluoroacetone trihydrate, inabenfide, indol-3-butyric acid (IBA), indol-3-ylacetic acid (IAA), isoprothiolane, maleic hydrazide, mefluidide, mepiquat, N-acetylthiazolidine-4-carboxylic acid, naphthaleneacetamide, N-m- tolylphthalamic acid, N-phenylphthalamic acid, nitrophenolates, paclobutrazol, pelargonic acid, piproctanyl bromide, prohexadione, prohydrojasmon, propham, propyl-3-tert- butylphenoxyacetate, sintofen, tetcyclacis, thidiazuron, triacontanol, triapenthenol, trinexapac, uniconazole, agriculturally acceptable salts or esters thereof, and mixtures thereof. PGRs can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, the PGR is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 20 g ai/ha or more, such as 0.020 g ai/ha or more, such as 0.025 g ai/ha or more, 0.03 g ai/ha or more, 0.04 g ai/ha or more, 0.05 g ai/ha or more, 0.06 g ai/ha or more, 0.07 g ai/ha or more, 0.08 g ai/ha or more, 0.09 g ai/ha or more, 0.1 g ai/ha or more, 0.11 g ai/ha or more, 0.125 g ai/ha or more, 0.15 g ai/ha or more, 0.175 g ai/ha or more, 0.20 g ai/ha or more, 0.25 g ai/ha or more, 0.3 g ai/ha or more, 0.4 g ai/ha or more, 0.5 g ai/ha or more, 0.6 g ai/ha or more, 0.7 g ai/ha or more, 0.8 g ai/ha or more, 0.9 g ai/ha or more, 1 g ai/ha or more, 1.1 g ai/ha or more, 1.25 g ai/ha or more, 1.5 g ai/ha or more, 1.75 g ai/ha or more, 2 g ai/ha or more, 2.25 g ai/ha or more, 2.5 g ai/ha or more, 2.75 g ai/ha or more, 3 g ai/ha or more, 3.25 g ai/ha or more, 3.5 g ai/ha or more, 3.75 g ai/ha or more, 4 g ai/ha or more, 4.25 g ai/ha or more, 4.5 g ai/ha or more, 4.75 g ai/ha or more, 5 g ai/ha or more, 5.25 g ai/ha or more, 5.5 g ai/ha or more, 5.75 g ai/ha or more, 6 g ai/ha or more, 6.25 g ai/ha or more, 6.5 g ai/ha or more, 6.75 g ai/ha or more, 7 g ai/ha or more, 7.25 g ai/ha or more, 7.5 g ai/ha or more, 8 g ai/ha or more, 8.5 g ai/ha or more, 9 g ai/ha or more, 9.5 g ai/ha, or more, 10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3750 g ai/ha or more, 4000 g ai/ha or more, 4250 g ai/ha or more, 4500 g ai/ha or more, 4750 g ai/ha or more, 5000 g ai/ha or more, 5250 g ai/ha or more, 5500 g ai/ha or more, 5750 g ai/ha or more, 6000 g ai/ha or more, 6250 g ai/ha or more, 6500 g ai/ha or more, 6750 g ai/ha or more, 7000 g ai/ha or more, 7250 g ai/ha or more, 7500 g ai/ha or more, 7750 g ai/ha or more, 8000 g ai/ha or more, 8250 g ai/ha or more, 8500 g ai/ha or more, 8750 g ai/ha or more, 9000 g ai/ha or more, 9250 g ai/ha or more, 9500 g ai/ha or more, 9750 g ai/ha or more, 10 kg ai/ha or more, 10.5 kg ai/ha or more, 11 kg ai/ha or more, 11.5 kg ai/ha or more, 12k g ai/ha or more, 12.5 kg ai/ha or more, 13 kg ai/ha or more, 13.5 kg ai/ha or more, 14 kg ai/ha or more, 14.5 kg ai/ha or more, 15 kg ai/ha or more, 15.5 kg ai/ha or more, 16 kg ai/ha or more, 16.5 kg ai/ha or more, 16.75 kg ai/ha or more, 17 kg ai/ha or more, or 17.5 kg ai/ha or more; in an amount of 17.5 kg ai/ha or less, such as 17 kg ai/ha or less, 16.5 kg ai/ha or less, 16 kg ai/ha or less, 15.5 kg ai/ha or less, 15 kg ai/ha or less, 14.5k g ai/ha or less, 14 kg ai/ha or less, 13.5 kg ai/ha or less, 13 kg ai/ha or less, 12.5 kg ai/ha or less, 12 kg ai/ha or less, 11.5 kg ai/ha or less, 11 kg ai/ha or less, 10.5 kg ai/ha, 10 kg ai/ha or less, 9750 g ai/ha or less, 9500 g ai/ha or less, 9250 g ai/ha or less, 9000 g ai/ha or less, 8750 g ai/ha or less, 8500 g ai/ha or less, 8250 g ai/ha or less, 8000 g ai/ha or less, 7750 g ai/ha or less, 7500 g ai/ha or less, 7250 g ai/ha or less, 7000 g ai/ha or less, 6750 g ai/ha or less, 6500 g ai/ha or less, 6250 g ai/ha or less, 6000 g ai/ha or less, 5750 g ai/ha or less, 5500 g ai/ha or less, 5250 g ai/ha or less, 5000 g ai/ha or less, 4750 g ai/ha or less, 4500 g ai/ha or less, 4250 g ai/ha or less, 4000 g ai/ha or less, 3750 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 10 g ai/ha or less, 9.5 g ai/ha or less, 9 g ai/ha or less, 8.5 g ai/ha or less, 8 g ai/ha or less, 7.5 g ai/ha or less, 7.25 g ai/ha or less, 7 g ai/ha or less, 6.75 g ai/ha or less, 6.5 g ai/ha or less, 6.25 g ai/ha or less, 6 g ai/ha or less, 5.75 g ai/ha or less, 5.5 g ai/ha or less, 5.25 g ai/ha or less, 5 g ai/ha or less, 4.75 g ai/ha or less, 4.5 g ai/ha or less, 4.25 g ai/ha or less, 4 g ai/ha or less, 3.75 g ai/ha or less, 3.5 g ai/ha or less, 3.25 g ai/ha or less, 3 g ai/ha or less, 2.75 g ai/ha or less, 2.5 g ai/ha or less, 2.25 g ai/ha or less, 2 g ai/ha or less, 1.75 g ai/ha or less, 1.5 g ai/ha or less, 1.25 g ai/ha or less, 1.1 g ai/ha or less, 1 g ai/ha or less, 0.9 g ai/ha or less, 0.8 g ai/ha or less, 0.7 g ai/ha or less, 0.6 g ai/ha or less, 0.5 g ai/ha or less, 0.4 g ai/ha or less, 0.3 g ai/ha or less, 0.2 g ai/ha or less, 0.175 g ai/ha or less, 0.15 g ai/ha or less, 0.125 g ai/ha or less, 0.11 g ai/ha or less, 0.1 g ai/ha or less, 0.09 g ai/ha or less, 0.08 g ai/ha or less, 0.07 g ai/ha or less, 0.06 g ai/ha or less, 0.05 g ai/ha or less, 0.04 g ai/ha or less, 0.03 g ai/ha or less, or 0.025 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 0.020 g – 17.5 kg ai/ha, 950–6500 g ai/ha, 0.7–8.5 g ai/ha, 460–3750 g ai/ha, 600–2500 g ai/ha, 50– 5000 g ai/ha, 110–450 g ai/ha, 11.5-16 kg ai/ha, 1900–4000 g ai/ha, 1–4 g ai/ha, 750–2200 g ai/ha, 380–5250 g ai/ha, 0.2–17.25 g ai/ha, 500–1400 g ai/ha, 3.25–950 g ai/ha, 440–2900 g ai/ha, or 0.025 g –17 kg ai/ha. 1,4-Dimethylnaphthalene Compositions and methods of the present disclosure can include 1,4- dimethylnaphthalene or an agriculturally acceptable salt or ester thereof. 1,4- Dimethylnaphthalene, shown below, is an aromatic hydrocarbon that provides inhibition of sprouting in potatoes after packaging, during shipping and in storage or in seed potatoes, at a spray rate of 5-20 mg/kg of potatoes. 1,4-Dimethylnaphthalene, as well as methods of preparing 1,4-dimethylnaphthalene, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. 1-Methylcyclopropene Compositions and methods of the present disclosure can include 1- methylcyclopropene or an agriculturally acceptable salt or ester thereof. 1- Methylcyclopropene, shown below, is a cyclic hydrocarbon that extends the life of cut and potted flowering plants and of harvested fruit and vegetables. It is formulated as a powder and released as a gas when the product is added to water. 1-Methylcyclopropene, as well as methods of preparing 1-methylcyclopropene, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. 1-Methylcyclopropene can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, 1-methylcyclopropene is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 5 g ai/ha or more, such as 5.25 g ai/ha or more, 5.5 g ai/ha or more, 5.75 g ai/ha or more, 6 g ai/ha or more, 6.25 g ai/ha or more, 6.5 g ai/ha or more, 6.75 g ai/ha or more, 7 g ai/ha or more, 7.25 g ai/ha or more, 7.5 g ai/ha or more, 8 g ai/ha or more, 8.5 g ai/ha or more, 9 g ai/ha or more, 9.5 g ai/ha, or more, 10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, or 47.5 g ai/ha or more; in an amount of such as 50 g ai/ha or less, such as 47.5 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 10 g ai/ha or less, 9.5 g ai/ha or less, 9 g ai/ha or less, 8.5 g ai/ha or less, 8 g ai/ha or less 7.5 g ai/ha or less, 7.25 g ai/ha or less, 7 g ai/ha or less, 6.75 g ai/ha or less, 6.5 g ai/ha or less, 6.25 g ai/ha or less, 6 g ai/ha or less, 5.75 g ai/ha or less, 5.5 g ai/ha or less, 5.25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 15–50 g ai/ha, 9.5–30 g ai/ha, 5–25 g ai/ha, 20–45 g ai/ha, 5.25–9.5 g ai/ha, or 7.5–47.5 g ai/ha. 1-Naphthylacetic acid Compositions and methods of the present disclosure can include 1-naphthylacetic acid or an agriculturally acceptable salt or ester thereof. 1-Naphthylacetic acid, shown below, is a naphthylacetic acid that: stimulates root formation in cuttings of woody and herbaceous plants and vines at 0.1-0.6 g/plant; prevents premature flower and fruit drop in apples, pears, grapes, guavas, mangoes, watermelons, pawpaws, citrus, aubergines, cucumbers, cotton, soybeans, etc.; increases fruit setting; provides thinning of fruit in apples, pears, olives, citrus and other fruit; and induces flowering in pineapples. 1-Naphthylacetic acid, as well as methods of preparing 1-naphthylacetic acid, are known in the art. Exemplary salts of 1-Naphthylacetic acid include ammonium 1-Naphthylacetic acetate, sodium 1-Naphthylacetic acetate, and potassium 1-Naphthylacetic acetate, while esters include ethyl 1-Naphthylacetic acetate. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. 1-Naphthylacetic acid can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, 1-naphthylacetic acid is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 100 g ai/ha or more, such as 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, or 390 g ai/ha or more; in an amount of 400 g ai/ha or less, such as 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 100–400 g ai/ha, 130–275 g ai/ha, 260–370 g ai/ha, 200–250 g ai/ha, 190–380 g ai/ha, 110–320 g ai/ha, 310–400 g ai/ha, 140–220 g ai/ha, 260–360 g ai/ha, or 110–390 g ai/ha. 2,6-Diisopropylnaphthalene Compositions and methods of the present disclosure can include 2,6- diisopropylnaphthalene or an agriculturally acceptable salt or ester thereof. 2,6- Diisopropylnaphthalene, shown below, is an aromatic hydrocarbon that inhibits sprouting in potatoes, at a spray rate of 2.5-25 mg/kg of potatoes. 2,6-Diisopropylnaphthalene, as well as methods of preparing 2,6-diisopropylnaphthalene, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. 2-Naphthyloxyacetic acid Compositions and methods of the present disclosure can include 2- naphthyloxyacetic acid or an agriculturally acceptable salt or ester thereof. 2- Naphthyloxyacetic acid, shown below, is a phenoxycarboxylic acid that increases fruit setting in tomatoes, strawberries, blackberries, peppers, aubergines, grapes and pineapples. 2- Naphthyloxyacetic acid, as well as methods of preparing 2-naphthyloxyacetic acid, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. 4-Chlorophenoxyacetic acid (4-CPA) Compositions and methods of the present disclosure can include 4- chlorophenoxyacetic acid (4-CPA) or an agriculturally acceptable salt or ester thereof. 4-CPA, shown below, is a phenoxycarboxylic acid that improves fruit setting in tomatoes, by application to the flowers, at 1.5–3 g/hl of spray solution; inhibition of sprout formation in mung beans; thinning of fruit in peaches. 4-CPA, as well as methods of preparing 4-CPA, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. 6-Benzylaminopurine Compositions and methods of the present disclosure can include 6- benzylaminopurine or an agriculturally acceptable salt or ester thereof. 6-Benzylaminopurine, shown below, is a aminopurine that stimulates lateral bud emergence in apples, pears and oranges, formation of basal shoots in roses and orchids, flowering in cyclamens and cacti, fruit set in grapes, oranges and melons, fruit thinning, flower bud formation and regular bearing in tree fruit, inhibition of senescence in rice seedlings, enhancement of lateral bud break and shoot growth in white pine trees, uniform bolting and increased seed production in spinach, all by foliar application, soaking, or painting, at 75 g/ha in apples. 6-Benzylaminopurine, as well as methods of preparing 6-benzylaminopurine, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. 6-Benzylaminopurine can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, 6-benzylaminopurine is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 10 g ai/ha or more, such as 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, or 490 g ai/ha or more; in an amount of 500 g ai/ha or less, such as 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, or 15 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 10–500 g ai/ha, 95–340 g ai/ha, 400–475 g ai/ha, 60–250 g ai/ha, 75–375 g ai/ha, 110–460 g ai/ha, 180–430 g ai/ha, 15–220 g ai/ha, 35–350 g ai/ha, 160– 410 g ai/ha, 40–230 g ai/ha, or 15–490 g ai/ha. Abscisic acid Compositions and methods of the present disclosure can include abscisic acid or an agriculturally acceptable salt or ester thereof. Abscisic acid, shown below, is a plant hormone that reduces drought stress and controls wilting in ornamental plants; decreases water requirements during shipping of ornamental plants; accelerates and enhances the color development of grapes, using a spray solution at 7.5-50 g/hl concentration. Abscisic acid, as well as methods of preparing abscisic acid, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Abscisic acid can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, abscisic acid is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 75 g ai/ha or more, such as 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, or 950 g ai/ha or more; in an amount of 1000 g ai/ha or less, such as 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, or 80 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 75–1000 g ai/ha, 95–650 g ai/ha, 460–850 g ai/ha, 220–575 g ai/ha, 450–500 g ai/ha, 110–325 g ai/ha, 330–490 g ai/ha, 750–950 g ai/ha, 380–700 g ai/ha, 500–1000 g ai/ha, 240–600 g ai/ha, or 80– 950 g ai/ha. Ancymidol Compositions and methods of the present disclosure can include ancymidol or an agriculturally acceptable salt or ester thereof. Ancymidol, shown below, is a pyrimidine carbinol used to reduce internode elongation to produce more compact greenhouse plants, by application to either foliage or soil, at 0.6–6.6 g/hl for bedding plants, 0.3–3.5 g/hl for bedding plant plugs, 2–5 g/hl for flowering and foliage plants, 2.5–5 g/hl for bulbs. Ancymidol, as well as methods of preparing ancymidol, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Aviglycine Compositions and methods of the present disclosure can include aviglycine or an agriculturally acceptable salt or ester thereof. Aviglycine, shown below, is an amino acid used to reduce fruit drop, reduce delay of fruit maturity, reduce delay or extension of harvest, improve harvest management, maintain fruit quality (e.g. fruit firmness), enhance size and color as a result of delayed harvest, reduce incidence and/or severity of watercore and superficial scald, enhance storage potential in apples, pears, stone fruit and walnuts and increase nut set in walnut cultivars affected by pistillate flower abortion. Aviglycine, as well as methods of preparing aviglycine, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Aviglycine can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, aviglycine is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 200 g ai/ha or more, such as 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, or 725 g ai/ha or more; in an amount of 750 g ai/ha or less, such as 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, or 210 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 200– 750 g ai/ha, 275–525 g ai/ha, 460–550 g ai/ha, 300–700 g ai/ha, 210–450 g ai/ha, 400–600 g ai/ha, 330–725 g ai/ha, 380–550 g ai/ha, 425–575 g ai/ha, 440–750 g ai/ha, or 210–725 g ai/ha. Butralin Compositions and methods of the present disclosure can include butralin or an agriculturally acceptable salt or ester thereof. Butralin, shown below, is a dinitroaniline used for pre-emergence control of annual broad-leaved and grass weeds in cotton, soybeans, rice, barley, beans, alliums, vines, ornamentals, fruit and nut trees, at 1120–3400 g/ha; control of suckers in tobacco, at 125 mg/plant. Butralin, as well as methods of preparing butralin, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Butralin can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, butralin is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1100 g ai/ha or more, such as 1120 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more or 3400 g ai/ha or more; in an amount of 3500 g ai/ha or less, such as 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, or 1120 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1100–3500 g ai/ha, 1450–2900 g ai/ha, 1300–3200 g ai/ha, 1600–2500 g ai/ha, 1250–3000 g ai/ha, 1800–2400 g ai/ha, 1900–3400 g ai/ha, 1350–2700 g ai/ha, 1120–3100 g ai/ha, 1500–3500 g ai/ha, 2200–2900 g ai/ha, or 1120–3400 g ai/ha. Chlorflurenol Compositions and methods of the present disclosure can include chlorflurenol or an agriculturally acceptable salt or ester thereof. Chlorflurenol, shown below, is a polycyclic aromatic carboxylic acid used as a growth retardant, at 2000–4000 g/ha, and for weed suppression, at 500–1500 g/ha as a soil application, in amenity grass, roadsides, railways, ditch banks, etc. Chlorflurenol also increases yield and improve size grading in pickling cucumbers, and induces vegetative planting material in pineapples. Chlorflurenol, as well as methods of preparing chlorflurenol, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Chlorflurenol can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, chlorflurenol is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 500 g ai/ha or more, such as 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3250 g ai/ha or more, 3500 g ai/ha or more, or 3750 g ai/ha or more; in an amount of 4000 g ai/ha or less, such as 3750 g ai/ha or less, 3500 g ai/ha or less, 3250 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, or 525 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 500–4000 g ai/ha, 950–2500 g ai/ha, 675–3250 g ai/ha, 800– 2100 g ai/ha, 550–2000 g ai/ha, 1100–2700 g ai/ha, 1900–2600 g ai/ha, 750–1200 g ai/ha, 3000–3250 g ai/ha, 600–1400 g ai/ha, 850–2300 g ai/ha, or 525–3750 g ai/ha. Chlormequat chloride Compositions and methods of the present disclosure can include chlormequat chloride. Chlormequat chloride, shown below, is a quaternary ammonium salt used to: increase resistance to lodging and increase yields in wheat, rye, oats and triticale, at 800–1600 g/ha; promote lateral branching and flowering in azaleas, fuchsias, begonias, poinsettias, geraniums, pelargoniums and other ornamental plants; promote flower formation and improve fruit setting in pears, almonds, vines, olives and tomatoes; and prevent premature fruit drop in pears, apricots and plums. Chlormequat chloride, as well as methods of preparing chlormequat chloride, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Chlormequat chloride can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, chlormequat chloride is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 500 g ai/ha or more, such as 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, or 1550 g ai/ha or more; in an amount of 1600 g ai/ha or less, such as 1550 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, or 525 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 500–1600 g ai/ha, 750–1500 g ai/ha, 675–1100 g ai/ha, 600–1300 g ai/ha, 650–1000 g ai/ha, 1100–1400 g ai/ha, 900–1200 g ai/ha, 700–1550 g ai/ha, 500–800 g ai/ha, 800–1200 g ai/ha, or 525–1550 g ai/ha. Chlorpropham Compositions and methods of the present disclosure can include chlorpropham or an agriculturally acceptable salt or ester thereof. Chlorpropham, shown below, is a quaternary ammonium salt used to inhibit sprouting in stored potatoes, at 8–64 g/t and control suckers in tobacco. Chlorpropham is also used for pre-emergence control of annual grass and some broad- leaved weeds in onions, leeks, garlic, shallots, alfalfa, clover, sugar beets, spinach, lettuce, endive, chicory, herbs, peas, beans, carrots, celery, black salsify, fennel, soybeans, cotton, rice, safflowers, sunflowers, cranberries, cane berries, ornamentals, ornamental trees and shrubs, perennial grass seed crops, etc., at up to 240 g/ha. Chlorpropham, as well as methods of preparing chlorpropham, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Chlorpropham can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, chlorpropham is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 15 g ai/ha or more, such as 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, or 245 g ai/ha or more; in an amount of 250 g ai/ha or less, such as 245 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, or 20 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 15–250 g ai/ha, 30–65 g ai/ha, 40–175 g ai/ha, 65–250 g ai/ha, 50–150 g ai/ha, 110–190 g ai/ha, 120–230 g ai/ha, 75–220 g ai/ha, 80–230 g ai/ha, 100–140 g ai/ha, 95–160 g ai/ha, or 20–245 g ai/ha. Clofencet Compositions and methods of the present disclosure can include clofencet or an agriculturally acceptable salt or ester thereof. Clofencet, shown below, is a pyridazinecarboxylic acid used as a chemical hybridizing agent for wheat, at 3000-5000 g/h as the potassium salt. Clofencet, as well as methods of preparing clofencet, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Cloprop Compositions and methods of the present disclosure can include cloprop or an agriculturally acceptable salt or ester thereof. Cloprop, shown below, is a phenoxycarboxylic acid used to reduce crown growth in pineapples, in order to increase the fruit size and weight and to delay maturation, and also for thinning of fruit in certain plum varieties. Cloprop, as well as methods of preparing cloprop, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Cloprop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, cloprop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 100 g ai/ha or more, such as 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, or 390 g ai/ha or more; in an amount of 400 g ai/ha or less, such as 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, or 110 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 100–400 g ai/ha, 310–380 g ai/ha, 160–375 g ai/ha, 120–250 g ai/ha, 175–350 g ai/ha, 140–240 g ai/ha, 190–370 g ai/ha, 200–220 g ai/ha, 340– 400 g ai/ha, 130–375 g ai/ha, 240–380 g ai/ha, or 110–390 g ai/ha. Cloxyfonac Compositions and methods of the present disclosure can include cloxyfonac or an agriculturally acceptable salt or ester thereof. Cloxyfonac, shown below, is a phenoxycarboxylic acid used for fruit setting in tomatoes and aubergines at flowering, producing fruit of uniform size. Cloxyfonac, as well as methods of preparing cloxyfonac, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Cyanamide Compositions and methods of the present disclosure can include cyanamide or an agriculturally acceptable salt or ester thereof. Cyanamide, shown below, is an inorganic compound used for early post-emergence control of broad-leaved weeds in alliums (onions, leeks, chives, shallots and garlic) and bulb flowers. Cyanamide is also used for promotion of bud break and increase of flowering in kiwifruit and apples, and removal of side shoots and inhibition of sprouting in hops and vines. Cyanamide, as well as methods of preparing cyanamide, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Cyanamide can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, cyanamide is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 kg ai/ha or more, such as 1.1 kg ai/ha or more, 1.25 kg ai/ha or more, 1.5 kg ai/ha or more, 1.75 kg ai/ha or more, 2 kg ai/ha or more, 2.25 kg ai/ha or more, 2.5 kg ai/ha or more, 2.75 kg ai/ha or more, 3 kg ai/ha or more, 3.25 kg ai/ha or more, 3.5 kg ai/ha or more, 3.75 kg ai/ha or more, 4 kg ai/ha or more, 4.25 kg ai/ha or more, 4.5 kg ai/ha or more, or 4.75 kg ai/ha or more; in an amount of 5 kg ai/ha or less, such as 4.75 kg ai/ha or less, 4.5 kg ai/ha or less, 4.25 kg ai/ha or less, 4 kg ai/ha or less, 3.75 kg ai/ha or less, 3.5 kg ai/ha or less, 3.25 kg ai/ha or less, 3 kg ai/ha or less, 2.75 kg ai/ha or less, 2.5 kg ai/ha or less, 2.25 kg ai/ha or less, 2 kg ai/ha or less, 1.75 kg ai/ha or less, 1.5 kg ai/ha or less, 1.25 kg ai/ha or less, or 1.1 kg ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–5 kg ai/ha, 1.25–4 kg ai/ha, 1.1-3.25 kg ai/ha, 2.5–3.75 kg ai/ha, 2–4.25 kg ai/ha, 3.25–4 kg ai/ha, 3–4.5 kg ai/ha, or 1.1– 4.75 kg ai/ha. Cyclanilide Compositions and methods of the present disclosure can include cyclanilide or an agriculturally acceptable salt or ester thereof. Cyclanilide, shown below, is cyclopropane carboxylic acid used for promotion of boll opening, defoliation and inhibition of terminal foliar regrowth in cotton. Cyclanilide, as well as methods of preparing cyclanilide, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Cyclanilide can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, cyclanilide is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 3 g ai/ha or more, such as 3.25 g ai/ha or more, 3.5 g ai/ha or more, 3.75 g ai/ha or more, 4 g ai/ha or more, 4.25 g ai/ha or more, 4.5 g ai/ha or more, 4.75 g ai/ha or more, 5 g ai/ha or more, 5.25 g ai/ha or more, 5.5 g ai/ha or more, 5.75 g ai/ha or more, 6 g ai/ha or more, 6.25 g ai/ha or more, 6.5 g ai/ha or more, 6.75 g ai/ha or more, 7 g ai/ha or more, 7.25 g ai/ha or more, 7.5 g ai/ha or more, 8 g ai/ha or more, 8.5 g ai/ha or more, 9 g ai/ha or more, 9.5 g ai/ha, or more, 10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, or 140 g ai/ha or more; in an amount of 150 g ai/ha or less, such as 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 10 g ai/ha or less, 9.5 g ai/ha or less, 9 g ai/ha or less, 8.5 g ai/ha or less, 8 g ai/ha or less 7.5 g ai/ha or less, 7.25 g ai/ha or less, 7 g ai/ha or less, 6.75 g ai/ha or less, 6.5 g ai/ha or less, 6.25 g ai/ha or less, 6 g ai/ha or less, 5.75 g ai/ha or less, 5.5 g ai/ha or less, 5.25 g ai/ha or less, 5 g ai/ha or less, 4.75 g ai/ha or less, 4.5 g ai/ha or less, 4.25 g ai/ha or less, 4 g ai/ha or less, 3.75 g ai/ha or less, 3.5 g ai/ha or less, or 3.25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 3–150 g ai/ha, 9.5–65 g ai/ha, 40–130 g ai/ha, 6–25 g ai/ha, 50–120 g ai/ha, 110–150 g ai/ha, 15–40 g ai/ha, 75–125 g ai/ha, 30–85 g ai/ha, 100– 140 g ai/ha, 4.5–20 g ai/ha, or 3.25–140 g ai/ha. Cytokinins Compositions and methods of the present disclosure can include the cytokinins, such as 6-isopentenylaminopurine, zeatin, and kinetin, or agriculturally acceptable salts or esters thereof. These cytokinins, shown below, are purines that enhance germination, flowering, fruit and seed set, induction of callus initiation, reduction of apical dominance, breaking lateral bud dormancy and retarding of aging in vegetables, peas, beans, tree fruit, vines, ornamentals, flowers, containerized plants, lawn and turf. Cytokinins, as well as methods of preparing cytokinins, are known in the art. Their plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Cytokinins can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, cytokinins are applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 0.02 g ai/ha or more, such as 0.025 g ai/ha or more, 0.03 g ai/ha or more, 0.04 g ai/ha or more, 0.05 g ai/ha or more, 0.06 g ai/ha or more, 0.07 g ai/ha or more, 0.08 g ai/ha or more, 0.09 g ai/ha or more, 0.1 g ai/ha or more, 0.11 g ai/ha or more, 0.125 g ai/ha or more, 0.15 g ai/ha or more, 0.175 g ai/ha or more, 0.20 g ai/ha or more, 0.25 g ai/ha or more, 0.3 g ai/ha or more, 0.4 g ai/ha or more, 0.5 g ai/ha or more, 0.6 g ai/ha or more, 0.7 g ai/ha or more, 0.8 g ai/ha or more, 0.9 g ai/ha or more, 1 g ai/ha or more, 1.1 g ai/ha or more, 1.25 g ai/ha or more, 1.5 g ai/ha or more, 1.75 g ai/ha or more, 2 g ai/ha or more, 2.25 g ai/ha or more, 2.5 g ai/ha or more, 2.75 g ai/ha or more, 3 g ai/ha or more, 3.25 g ai/ha or more, 3.5 g ai/ha or more, 3.75 g ai/ha or more, 4 g ai/ha or more, 4.25 g ai/ha or more, 4.5 g ai/ha or more, 4.75 g ai/ha or more, 5 g ai/ha or more, 5.25 g ai/ha or more, 5.5 g ai/ha or more, 5.75 g ai/ha or more, 6 g ai/ha or more, 6.25 g ai/ha or more, 6.5 g ai/ha or more, 6.75 g ai/ha or more, 7 g ai/ha or more, or 7.25 g ai/ha or more; in an amount of 7.5 g ai/ha or less, such as 7.25 g ai/ha or less, 7 g ai/ha or less, 6.75 g ai/ha or less, 6.5 g ai/ha or less, 6.25 g ai/ha or less, 6 g ai/ha or less, 5.75 g ai/ha or less, 5.5 g ai/ha or less, 5.25 g ai/ha or less, 5 g ai/ha or less, 4.75 g ai/ha or less, 4.5 g ai/ha or less, 4.25 g ai/ha or less, 4 g ai/ha or less, 3.75 g ai/ha or less, 3.5 g ai/ha or less, 3.25 g ai/ha or less, 3 g ai/ha or less, 2.75 g ai/ha or less, 2.5 g ai/ha or less, 2.25 g ai/ha or less, 2 g ai/ha or less, 1.75 g ai/ha or less, 1.5 g ai/ha or less, 1.25 g ai/ha or less, 1 g ai/ha or less, 0.9 g ai/ha or less, 0.8 g ai/ha or less, 0.7 g ai/ha or less, 0.6 g ai/ha or less, 0.5 g ai/ha or less, 0.4 g ai/ha or less, 0.3 g ai/ha or less, 0.2 g ai/ha or less, 0.175 g ai/ha or less, 0.15 g ai/ha or less, 0.125 g ai/ha or less, 0.11 g ai/ha or less, 0.1 g ai/ha or less, 0.09 g ai/ha or less, 0.08 g ai/ha or less, 0.07 g ai/ha or less, 0.06 g ai/ha or less, 0.05 g ai/ha or less, 0.04 g ai/ha or less, 0.03 g ai/ha or less, or 0.025 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 0.02– 7.0 g ai/ha, 0.25–4 g ai/ha, 0.09–6.25 g ai/ha, 0.5–2.25 g ai/ha, 0.06–0.9 g ai/ha, 0.7–4.75 g ai/ha, 1.5–4.5 g ai/ha, 0.1–2 g ai/ha, 1-6 g ai/ha, 0.15–3.75 g ai/ha, 2–5.5 g ai/ha, 3.25–6.5 g ai/ha, 0.3–2.5 g ai/ha, or 0.025–7.25 g ai/ha. Daminozide Compositions and methods of the present disclosure can include daminozide or an agriculturally acceptable salt or ester thereof. Daminozide, shown below, is succinamic acid used for inhibition of internodal elongation, to produce more compact plants, in chrysanthemums, azaleas, hydrangeas, poinsettias and other ornamentals, at 106–425 g/ha. Daminozide, as well as methods of preparing daminozide, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Daminozide can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, daminozide is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 100 g ai/ha or more, such as 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, or 490 g ai/ha or more; in an amount of 500 g ai/ha or less, such as 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, or 110 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 100–500 g ai/ha, 350– 470 g ai/ha, 160–375 g ai/ha, 180–250 g ai/ha, 150–380 g ai/ha, 110–270 g ai/ha, 190–420 g ai/ha, 140–240 g ai/ha, 380–425 g ai/ha, 210–400 g ai/ha, 440–490 g ai/ha, or 110–480 g ai/ha. Decan-1-ol Compositions and methods of the present disclosure can include decan-1-ol or an agriculturally acceptable salt or ester thereof. Decan-1-ol, shown below, is a fatty alcohol used for control of sucker growth in tobacco, at 11000–17000 g/ha. Decan-1-ol, as well as methods of preparing decan-1-ol, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Decan-1-ol can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, decan-1-ol is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 10 kg ai/ha or more, such as 10.5 kg ai/ha or more, 11 kg ai/ha or more, 11.5 kg ai/ha or more, 12 kg ai/ha or more, 12.5 kg ai/ha or more, 13 kg ai/ha or more, 13.5 kg ai/ha or more, 14 kg ai/ha or more, 14.5 kg ai/ha or more, 15 kg ai/ha or more, 15.5 kg ai/ha or more, 16 kg ai/ha or more, 16.5 kg ai/ha or more, or 16.75 kg ai/ha or more; in an amount of 17 kg ai/ha or less, such as 16.75 kg ai/ha or less, 16.5 kg ai/ha or less, 16 kg ai/ha or less, 15.5 kg ai/ha or less, 15 kg ai/ha or less, 14.5 kg ai/ha or less, 14 kg ai/ha or less, 13.5 kg ai/ha or less, 13 kg ai/ha or less, 12.5 kg ai/ha or less, 12 kg ai/ha or less, 11.5 kg ai/ha or less, 11 kg ai/ha or less, or 10.5 kg ai/ha; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 10–17 kg ai/ha, 11.5–16.5 kg ai/ha, 15.5–17 kg ai/ha, 11–12.5 kg ai/ha, 14–16 kg ai/ha, 11–14.5 kg ai/ha, 12– 15 kg ai/ha, 13–13.5 kg ai/ha, 11.5–13 kg ai/ha, or 10.5–16.75 kg ai/ha. Dikegulac Compositions and methods of the present disclosure can include dikegulac or an agriculturally acceptable salt or ester thereof. Dikegulac, shown below, is a plant growth regulator used for reducing apical dominance and promotion of side-branching and flower-bud formation in azaleas, fuchsias and other ornamental plants, and to temporarily retard longitudinal growth in hedges and ornamental shrubs; also for growth retardant in trees by trunk injection. Dikegulac, as well as methods of preparing dikegulac, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Dimethipin Compositions and methods of the present disclosure can include dimethipin or an agriculturally acceptable salt or ester thereof. Dimethipin, shown below, is a dithiine used for: defoliation of cotton, nursery stock, rubber trees and vines, at 260-720 g/ha; destruction of potato haulm, at 480-720 g/ha; and reduction of seed moisture content at harvest in maize, rice, oilseed rape, flax and sunflowers, at 240-720 g/ha. Dimethipin, as well as methods of preparing dimethipin, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Dimexano Compositions and methods of the present disclosure can include dimexano or an agriculturally acceptable salt or ester thereof. Dimexano, shown below, is a thiocarbamate used for: pre-emergence control of broad-leaved weeds in drilled crops, at 9000 g/ha; pre- harvest desiccant for onions and peas, at 28000 g/ha; and control of growth and splitting of carrots. Dimexano, as well as methods of preparing dimexano, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Endothall Compositions and methods of the present disclosure can include endothall or an agriculturally acceptable salt or ester thereof. Endothall, shown below, is a bicyclocarboxylic acid used for: pre- and post-emergence control of annual grass and broad-leaved weeds in sugar beets, fodder beets, beetroot, spinach and turf, at 2000–6000 g/ha; control of algae and aquatic weeds at 1-5 ppm; desiccant for alfalfa, clover and hops; defoliant in cotton; and destruction of potato haulms. Endothall, as well as methods of preparing endothall, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Endothall can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, endothall is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 600 g ai/ha or more, such as 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3250 g ai/ha or more, 3500 g ai/ha or more, 3750 g ai/ha or more, 4000 g ai/ha or more, 4250 g ai/ha or more, 4500 g ai/ha or more, 4750 g ai/ha or more, 5000 g ai/ha or more, 5250 g ai/ha or more, 5500 g ai/ha or more, or 5750 g ai/ha or more; in an amount of 6000 g ai/ha or less, such as 5750 g ai/ha or less, 5500 g ai/ha or less, 5250 g ai/ha or less, 5000 g ai/ha or less, 4750 g ai/ha or less, 4500 g ai/ha or less, 4250 g ai/ha or less, 4000 g ai/ha or less, 3750 g ai/ha or less, 3500 g ai/ha or less, 3250 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, or 625 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 600–6000 g ai/ha, 950–4500 g ai/ha, 850–3750 g ai/ha, 800–2500 g ai/ha, 3250–5000 g ai/ha, 1100–4750 g ai/ha, 1900–4000 g ai/ha, 2700–5250 g ai/ha, 1800–3250 g ai/ha, 2500– 4500 g ai/ha, or 625–5750 g ai/ha. Ethephon Compositions and methods of the present disclosure can include ethephon or an agriculturally acceptable salt or ester thereof. Ethephon, shown below, is a phosphonate used for; promotion of pre-harvest ripening in apples, currants, blackberries, blueberries, cranberries, morello cherries, citrus, figs, tomatoes, sugar beet and fodder beet seed crops, coffee and peppers; acceleration of post-harvest ripening in bananas, mangoes and citrus; loosening of fruit in currants, gooseberries, cherries and apples; increase flower bud development in apples; prevention of lodging in cereals, maize and flax; induction of flowering in Bromeliads; stimulation of lateral branching in azaleas, geraniums and roses; shortening of stem length in forced daffodils; induction of flowering and regulation of ripening in pineapples; accelerate of boll opening in cotton; modification of sex expression in cucumbers and squash; increase fruit setting and yield in cucumbers; improvement of sturdiness in onion seed crops; hasten yellowing in mature tobacco leaves; stimulation of latex flow in rubber trees and resin flow in pine trees: and stimulation of early uniform hull split in walnuts, at 2180 g/ha in cotton, 720 g/ha in cereals and 1440 g/ha in fruit. Ethephon, as well as methods of preparing ethephon, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Ethephon can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, ethephon is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 125 g ai/ha or more, such as 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, or 2400 g ai/ha or more; in an amount of 2500 g ai/ha or less, such as 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, or 130 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 125–2500 g ai/ha, 950–2000 g ai/ha, 1200–2200 g ai/ha, 350–1500 g ai/ha, 1150–2100 g ai/ha, 700–1400 g ai/ha, 260–1100 g ai/ha, 1050–1800 g ai/ha, 1600–2500 g ai/ha, 175–400 g ai/ha, 900–1900 g ai/ha, or 150–2400 g ai/ha. Fenoprop Compositions and methods of the present disclosure can include fenoprop or an agriculturally acceptable salt or ester thereof. Fenoprop, shown below, is a phenoxycarboxylic acid used for postemergence brush control, at 2000-4000 g/hl spray solution; control of aquatic weeds; control of broad-leaved weeds in maize and sugar cane; and reduction of pre-harvest apple drop, at 1400 g ae/hl of amine salt spray solution 7-14 d prior to harvest. Fenoprop, as well as methods of preparing fenoprop, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Flumetralin Compositions and methods of the present disclosure can include flumetralin or an agriculturally acceptable salt or ester thereof. Flumetralin, shown below, is a dinitroaniline used for control of sucker growth in tobacco. Flumetralin, as well as methods of preparing flumetralin, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Flumetralin can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, flumetralin is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 650 g ai/ha or more, such as 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, or 1300 g ai/ha or more; in an amount of 1350 g ai/ha or less, such as 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, or 675 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 650–1350 g ai/ha, 850–1100 g ai/ha, 1200–1300 g ai/ha, 700–1050 g ai/ha, 750–1000 g ai/ha, 1100–1150 g ai/ha, 900–1250 g ai/ha, 650–1200 g ai/ha, 800–1000 g ai/ha, 1050–1300 g ai/ha, 700–1200 g ai/ha, or 675–1300 g ai/ha. Flurenol Compositions and methods of the present disclosure can include flurenol or an agriculturally acceptable salt or ester thereof. Flurenol, shown below, is a carboxylic acid used for post-emergence control of broad-leaved weeds in cereals, including wheat, barley, rye, oats, and rice. Flurenol, as well as methods of preparing flurenol, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Flurenol can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, flurenol is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 200 g ai/ha or more, such 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, or 950 g ai/ha or more; in an amount of 1000 g ai/ha or less, such as 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, or 210 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 200–1000 g ai/ha, 250–650 g ai/ha, 460–750 g ai/ha, 600–900 g ai/ha, 380–500 g ai/ha, 210–450 g ai/ha, 390–480 g ai/ha, 750–950 g ai/ha, 325– 525 g ai/ha, 500–750 g ai/ha, 440–800 g ai/ha, or 210–950 g ai/ha. Flurprimidol Compositions and methods of the present disclosure can include flurprimidol or an agriculturally acceptable salt or ester thereof. Flurprimidol, shown below, is a pyrimidine carbinol used to decrease the rate of growth of plants, including perennial turf grasses, ornamental cover species, herbaceous and woody ornamentals and deciduous and coniferous trees, at 140–1100 g/ha in turf grasses, 560–1100 g/ha in flowering and foliage plants, 1100– 3400 g/ha in woody ornamentals. Flurprimidol, as well as methods of preparing flurprimidol, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Flurprimidol can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, flurprimidol is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 125 g ai/ha or more, such as 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, or 3400 g ai/ha or more; in an amount of 3500 g ai/ha or less, such as 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, or 130 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 125–3500 g ai/ha, 950–2500 g ai/ha, 460–1700 g ai/ha, 1600– 2500 g ai/ha, 550–1800 g ai/ha, 210–470 g ai/ha, 1300–3300 g ai/ha, 340–2200 g ai/ha, 650– 3250 g ai/ha, 1000–1400 g ai/ha, 440–2900 g ai/ha, or 130–3400 g ai/ha. Forchlorfenuron Compositions and methods of the present disclosure can include forchlorfenuron or an agriculturally acceptable salt or ester thereof. Forchlorfenuron, shown below, is a phenyl urea used for: increasing the size of kiwifruit, table grapes and peaches; promotion of fruit set in melons, pumpkins and cucumbers; promotion of branching in apples; increasing yields in potatoes, rice and wheat. Forchlorfenuron, as well as methods of preparing forchlorfenuron, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Forchlorfenuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, forchlorfenuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 4 g ai/ha or more, such as 4.25 g ai/ha or more, 4.5 g ai/ha or more, 4.75 g ai/ha or more, 5 g ai/ha or more, 5.25 g ai/ha or more, 5.5 g ai/ha or more, 5.75 g ai/ha or more, 6 g ai/ha or more, 6.25 g ai/ha or more, 6.5 g ai/ha or more, 6.75 g ai/ha or more, 7 g ai/ha or more, 7.25 g ai/ha or more, 7.5 g ai/ha or more, 8 g ai/ha or more, 8.5 g ai/ha or more, 9 g ai/ha or more, 9.5 g ai/ha, or more, 10 g ai/ha or more, 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 22.5 g ai/ha or more, 25 g ai/ha or more, or 27.5 g ai/ha or more; in an amount of 30 g ai/ha or less, such as 27.5 g ai/ha or less, 25 g ai/ha or less, 22.5 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, 12.5 g ai/ha or less, 10 g ai/ha or less, 9.5 g ai/ha or less, 9 g ai/ha or less, 8.5 g ai/ha or less, 8 g ai/ha or less, 7.5 g ai/ha or less, 7.25 g ai/ha or less, 7 g ai/ha or less, 6.75 g ai/ha or less, 6.5 g ai/ha or less, 6.25 g ai/ha or less, 6 g ai/ha or less, 5.75 g ai/ha or less, 5.5 g ai/ha or less, 5.25 g ai/ha or less, 5 g ai/ha or less, 4.75 g ai/ha or less, 4.5 g ai/ha or less, or 4.25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 4–30 g ai/ha, 5.25– 7.5 g ai/ha, 12–27.5 g ai/ha, 8.5–20 g ai/ha, 6.25–9.5 g ai/ha, 17.5–27.5 g ai/ha, 8–25 g ai/ha, 10–20 g ai/ha, 4.25-7.5 g ai/ha, 9.5–15 g ai/ha, 7–15 g ai/ha, 4–8.5 g ai/ha, or 4.25–27.5 g ai/ha. Gibberellins Compositions and methods of the present disclosure can include gibberellins, including gibberellic acid, gibberellin A4, and gibberellin A7, or an agriculturally acceptable salt or ester thereof. Gibberellins, shown below, are natural plant compounds used to: improve fruit setting in clementines and pears; loosen and elongate clusters and increase berry size in grapes; control fruit maturity by delaying development of the yellow color in lemons; reduce rind stain and retard rind ageing in navel oranges; promote uniform seedling growth in rice; promote elongation in winter celery; induce uniform bolting and increase seed production in lettuce; stimulate sprouting in seed potatoes; hasten maturation in artichokes; increase yields in forced rhubarb; increase malting quality in barley; produce brighter-colored, firmer fruit and increase fruit size in sweet cherries; increase yields and aid harvesting in hops; reduce internal browning and increase yields in Italian prunes; increase fruit set and yields in tangelos and tangerines; improve fruit setting in blueberries; promote flowering and increase yield in strawberries, all at up to 200 g/ha. Gibberellins, as well as methods of preparing gibberellins, are known in the art. Their plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. gibberellic acid Gibberellins can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, gibberellins are applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 1.1 g ai/ha or more, 1.25 g ai/ha or more, 1.5 g ai/ha or more, 1.75 g ai/ha or more, 2 g ai/ha or more, 2.25 g ai/ha or more, 2.5 g ai/ha or more, 2.75 g ai/ha or more, 3 g ai/ha or more, 3.25 g ai/ha or more, 3.5 g ai/ha or more, 3.75 g ai/ha or more, 4 g ai/ha or more, 4.25 g ai/ha or more, 4.5 g ai/ha or more, 4.75 g ai/ha or more, 5 g ai/ha or more, 5.25 g ai/ha or more, 5.5 g ai/ha or more, 5.75 g ai/ha or more, 6 g ai/ha or more, 6.25 g ai/ha or more, 6.5 g ai/ha or more, 6.75 g ai/ha or more, 7 g ai/ha or more, 7.25 g ai/ha or more, 7.5 g ai/ha or more, 8 g ai/ha or more, 8.5 g ai/ha or more, 9 g ai/ha or more, 9.5 g ai/ha, or more, 10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, or 340 g ai/ha or more; in an amount of 350 g ai/ha or less, such as 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 10 g ai/ha or less, 9.5 g ai/ha or less, 9 g ai/ha or less, 8.5 g ai/ha or less, 8 g ai/ha or less, 7.5 g ai/ha or less, 7.25 g ai/ha or less, 7 g ai/ha or less, 6.75 g ai/ha or less, 6.5 g ai/ha or less, 6.25 g ai/ha or less, 6 g ai/ha or less, 5.75 g ai/ha or less, 5.5 g ai/ha or less, 5.25 g ai/ha or less, 5 g ai/ha or less, 4.75 g ai/ha or less, 4.5 g ai/ha or less, 4.25 g ai/ha or less, 4 g ai/ha or less, 3.75 g ai/ha or less, 3.5 g ai/ha or less, 3.25 g ai/ha or less, 3 g ai/ha or less, 2.75 g ai/ha or less, 2.5 g ai/ha or less, 2.25 g ai/ha or less, 2 g ai/ha or less, 1.75 g ai/ha or less, 1.5 g ai/ha or less, 1.25 g ai/ha or less, or 1.1 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–350 g ai/ha, 9.5–70 g ai/ha, 4.5–150 g ai/ha, 60–220 g ai/ha, 5–130 g ai/ha, 10–250 g ai/ha, 25–140 g ai/ha, 75–300 g ai/ha, 8–55 g ai/ha, 30–160 g ai/ha, 110–290 g ai/ha, or 1.1–340 g ai/ha. Heptamaloxyloglucan Compositions and methods of the present disclosure can include heptamaloxyloglucan or an agriculturally acceptable salt or ester thereof. Heptamaloxyloglucan, shown below, is a polysaccharide used as a plant elicitor for protection of grapes from spring frost damage. Heptamaloxyloglucan, as well as methods of preparing heptamaloxyloglucan, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Indol-3-butyric acid (IBA) and Indol-3-ylacetic acid (IAA) Compositions and methods of the present disclosure can include indol-3-butyric acid (IBA), indol-3-ylacetic acid (IAA) or an agriculturally acceptable salt or ester thereof. IBA and IAA, shown below, are plant hormones used to stimulate rooting of cuttings of herbaceous and woody ornamentals. IBA and IAA, as well as methods of preparing IBA and IAA, are known in the art. Their plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. IBA or IAA can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, IBA or IAA are applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 105 g ai/ha or more, 110 g ai/ha or more, 115 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 135 g ai/ha or more, 140 g ai/ha or more, or 145 g ai/ha or more; in an amount of 150 g ai/ha or less, 145 g ai/ha or less, 140 g ai/ha or less, 135 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 115 g ai/ha or less, 110 g ai/ha or less, 105 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, or 55 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–150 g ai/ha, 95–130 g ai/ha, 60–140 g ai/ha, 70–125 g ai/ha, 100–150 g ai/ha, 55–115 g ai/ha, 75–100 g ai/ha, 85–120 g ai/ha, 90–125 g ai/ha, or 55– 145 g ai/ha. Isoprothiolane Compositions and methods of the present disclosure can include isoprothiolane or an agriculturally acceptable salt or ester thereof. Isoprothiolane, shown below, is a dithiolane used to accelerate rooting, promote root elongation, and control non-parasitic damping-off in rice. Isoprothiolane, as well as methods of preparing isoprothiolane, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Maleic hydrazide Compositions and methods of the present disclosure can include maleic hydrazide or an agriculturally acceptable salt or ester thereof. Maleic hydrazide, shown below, is a pyridazine used for: suppression of grass growth in lawns, roadside verges, embankments and amenity areas and of growth of shrubs and trees; inhibition of sprouting in potatoes, onions, beets, swedes, parsnips and carrots in storage; prevention of sucker development in tobacco; induction of dormancy in citrus, at 1200–5400 g/ha. Maleic hydrazide, as well as methods of preparing maleic hydrazide, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Maleic hydrazide can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, maleic hydrazide is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1000 g ai/ha or more, such as 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3750 g ai/ha or more, 4000 g ai/ha or more, 4250 g ai/ha or more, 4500 g ai/ha or more, 4750 g ai/ha or more, 5000 g ai/ha or more, 5250 g ai/ha or more; in an amount of 5500 g ai/ha or less, such as 5250 g ai/ha or less, 5000 g ai/ha or less, 4750 g ai/ha or less, 4500 g ai/ha or less, 4250 g ai/ha or less, 4000 g ai/ha or less, 3750 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, or 1050 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1000–5500 g ai/ha, 1250–4500 g ai/ha, 4500–5250 g ai/ha, 1600–2500 g ai/ha, 1150–3100 g ai/ha, 1350–1700 g ai/ha, 1900–3000 g ai/ha, 2400–4250 g ai/ha, 3200–5000 g ai/ha, 1400–4000 g ai/ha, 1800– 2800 g ai/ha, or 1050–5250 g ai/ha. Mefluidide Compositions and methods of the present disclosure can include mefluidide or an agriculturally acceptable salt or ester thereof. Mefluidide, shown below, is a sulfonanilide used for: inhibition of growth and suppression of seed production of perennial grasses in turf, lawns, grassland, industrial areas, amenity areas, roadside verges and embankments; inhibition of growth of ornamental trees and shrubs; enhancement of the sucrose content of sugar cane, at 300 to 1100 g/ha; and control of growth and seed production of weeds, particularly Sorghum halepense and volunteer cereals, in soybeans and other crops. Mefluidide, as well as methods of preparing mefluidide, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Mefluidide can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, mefluidide is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 200 g ai/ha or more, such as 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, or 1200 g ai/ha or more; in an amount of 1250 g ai/ha or less, such as 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, or 210 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 200– 1250 g ai/ha, 250–650 g ai/ha, 460–950 g ai/ha, 300–700 g ai/ha, 370–800 g ai/ha, 210–575 g ai/ha, 290–400 g ai/ha, 750–1050 g ai/ha, 230–525 g ai/ha, 425–1100 g ai/ha, 340–850 g ai/ha, or 210–1200 g ai/ha. Mepiquat Compositions and methods of the present disclosure can include the mepiquat ion or an agriculturally acceptable salt thereof. Mepiquat, shown below as the chloride or pentaborate salt, is a quaternary ammonium ion used for: reduction of vegetative growth and promotion of boll maturation in cotton, at up to 75 g/ha; inhibition of sprouting in onions, garlic and leeks; prevention of lodging, by shortening the stem and strengthening the stem wall, in cereals, grass seed crops and flax, at up to 762.5 g/ha. Mepiquat, as well as methods of preparing mepiquat, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Mepiquat can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, mepiquat is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 5 g ai/ha or more, such as 6 g ai/ha or more, 7 g ai/ha or more, 7.5 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, or 750 g ai/ha or more; in an amount of 800 g ai/ha or less, such as 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7.5 g ai/ha or less, 7 g ai/ha or less, or 6 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 5–800 g ai/ha, 9–65 g ai/ha, 40–375 g ai/ha, 120–250 g ai/ha, 50–550 g ai/ha, 110–450 g ai/ha, 230–400 g ai/ha, 700–800 g ai/ha, 380–525 g ai/ha, 25–140 g ai/ha, 340–675 g ai/ha, or 6–750 g ai/ha. N-Acetylthiazolidine-4-carboxylic acid Compositions and methods of the present disclosure can include N- acetylthiazolidine-4-carboxylic acid or an agriculturally acceptable salt or ester thereof. N- Acetylthiazolidine-4-carboxylic acid, shown below, is a carboxylic acid used to increase size of fruit, berries and kernels, increase yield, increase vitamins and improve skin color, using a spray solution at 20-75 ppm concentration. N-Acetylthiazolidine-4-carboxylic acid, as well as methods of preparing N-acetylthiazolidine-4-carboxylic acid, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Naphthaleneacetamide Compositions and methods of the present disclosure can include naphthaleneacetamide or an agriculturally acceptable salt or ester thereof. Naphthaleneacetamide, shown below, is an aromatic amide used to: stimulate root production at 0.1-0.6 g/plant; thin fruit in apples and pears; and prevent premature fruit fall in apples and cherries. Naphthaleneacetamide, as well as methods of preparing naphthaleneacetamide, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Nitrophenolates Compositions and methods of the present disclosure can include the nitrophenolate mixture (sodium 5-nitroguaiacolate, sodium o-nitrophenolate, and sodium p-nitrophenolate) or an agriculturally acceptable salt or ester thereof. Nitrophenolates, shown below, are a mixture of phenolate salts used to increase nutrient uptake in cotton, cereals, cucumbers, grapes, melons, paprika, rice, soybeans, sugar beets and vegetables, at 3–6 g/ha. Nitrophenolates, as well as methods of preparing nitrophenolates, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Nitrophenolates can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, nitrophenolates are applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 1.1 g ai/ha or more, 1.25 g ai/ha or more, 1.5 g ai/ha or more, 1.75 g ai/ha or more, 2 g ai/ha or more, 2.25 g ai/ha or more, 2.5 g ai/ha or more, 2.75 g ai/ha or more, 3 g ai/ha or more, 3.25 g ai/ha or more, 3.5 g ai/ha or more, 3.75 g ai/ha or more, 4 g ai/ha or more, 4.25 g ai/ha or more, 4.5 g ai/ha or more, 4.75 g ai/ha or more, 5 g ai/ha or more, 5.25 g ai/ha or more, 5.5 g ai/ha or more, 5.75 g ai/ha or more, 6 g ai/ha or more, 6.25 g ai/ha or more, 6.5 g ai/ha or more, 6.75 g ai/ha or more, 7 g ai/ha or more, 7.25 g ai/ha or more, 7.5 g ai/ha or more, 8 g ai/ha or more, 8.5 g ai/ha or more, 9 g ai/ha or more, or 9.5 g ai/ha, or more; in an amount of 10 g ai/ha or less, 9.5 g ai/ha or less, 9 g ai/ha or less, 8.5 g ai/ha or less, 8 g ai/ha or less, 7.5 g ai/ha or less, 7.25 g ai/ha or less, 7 g ai/ha or less, 6.75 g ai/ha or less, 6.5 g ai/ha or less, 6.25 g ai/ha or less, 6 g ai/ha or less, 5.75 g ai/ha or less, 5.5 g ai/ha or less, 5.25 g ai/ha or less, 5 g ai/ha or less, 4.75 g ai/ha or less, 4.5 g ai/ha or less, 4.25 g ai/ha or less, 4 g ai/ha or less, 3.75 g ai/ha or less, 3.5 g ai/ha or less, 3.25 g ai/ha or less, 3 g ai/ha or less, 2.75 g ai/ha or less, 2.5 g ai/ha or less, 2.25 g ai/ha or less, 2 g ai/ha or less, 1.75 g ai/ha or less, 1.5 g ai/ha or less, 1.25 g ai/ha or less, or 1.1 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–10 g ai/ha, 2.25–7 g ai/ha, 4.5–6.5 g ai/ha, 1.75–6 g ai/ha, 3–9 g ai/ha, 5.25–8.5 g ai/ha, 1.5–4.5 g ai/ha, 1–4 g ai/ha, 1.75-7.25 g ai/ha, 1.5–5.75 g ai/ha, 2–3.75 g ai/ha, 2.25–10 g ai/ha, 3–8.5 g ai/ha, or 1.1–9.5 g ai/ha. Paclobutrazol Compositions and methods of the present disclosure can include paclobutrazol or an agriculturally acceptable salt or ester thereof. Paclobutrazol, shown below, is triazole used for: inhibition of vegetative growth and enhancement of fruit set in tree fruit; inhibition of growth in pot-grown ornamentals and flowers, e.g. chrysanthemums, begonias, freesias, poinsettias and bulbs, as a spray at a concentration of 1-200 ppm; prevent lodging and increase yield in rice; growth retardation in turf and reduction of height and prevention of lodging in grass seed crops and oilseed rape. Paclobutrazol, as well as methods of preparing paclobutrazol, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Paclobutrazol can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, paclobutrazol is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 40 g ai/ha or more, such as 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, or 950 g ai/ha or more; in an amount of 1000 g ai/ha or less, such as 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, or 45 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 40–1000 g ai/ha, 95–650 g ai/ha, 460– 750 g ai/ha, 80–250 g ai/ha, 50–850 g ai/ha, 110–450 g ai/ha, 230–400 g ai/ha, 750–1000 g ai/ha, 380–525 g ai/ha, 320–600 g ai/ha, 65–290 g ai/ha, or 45–950 g ai/ha. Pelargonic acid Compositions and methods of the present disclosure can include pelargonic acid or an agriculturally acceptable salt or ester thereof. Pelargonic acid, shown below, is fatty acid used for: thinning of blossoms in apples and pears; control of annual weeds in potatoes and peanuts; total weed control in non-crop areas; control of mosses in lawns and other domestic areas. Pelargonic acid, as well as methods of preparing pelargonic acid, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Pelargonic acid can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pelargonic acid is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 750 g ai/ha or more, such as 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3750 g ai/ha or more, 4000 g ai/ha or more, 4250 g ai/ha or more, 4500 g ai/ha or more, 4750 g ai/ha or more, 5000 g ai/ha or more, 5250 g ai/ha or more, 5500 g ai/ha or more, 5750 g ai/ha or more, 6000 g ai/ha or more, 6250 g ai/ha or more, 6500 g ai/ha or more, 6750 g ai/ha or more, 7000 g ai/ha or more, 7250 g ai/ha or more, 7500 g ai/ha or more, 7750 g ai/ha or more, 8000 g ai/ha or more, 8250 g ai/ha or more, 8500 g ai/ha or more, 8750 g ai/ha or more, 9000 g ai/ha or more, 9250 g ai/ha or more, 9500 g ai/ha or more, 9750 g ai/ha or more, 10 kg ai/ha or more, 10.5 kg ai/ha or more, 11 kg ai/ha or more, 11.5 kg ai/ha or more, 12k g ai/ha or more, 12.5 kg ai/ha or more, 13 kg ai/ha or more, 13.5 kg ai/ha or more, 14 kg ai/ha or more, or 14.5 kg ai/ha or more; in an amount of 15 kg ai/ha or less, such as 14.5k g ai/ha or less, 14 kg ai/ha or less, 13.5 kg ai/ha or less, 13 kg ai/ha or less, 12.5 kg ai/ha or less, 12 kg ai/ha or less, 11.5 kg ai/ha or less, 11 kg ai/ha or less, 10.5 kg ai/ha, 10 kg ai/ha or less, 9750 g ai/ha or less, 9500 g ai/ha or less, 9250 g ai/ha or less, 9000 g ai/ha or less, 8750 g ai/ha or less, 8500 g ai/ha or less, 8250 g ai/ha or less, 8000 g ai/ha or less, 7750 g ai/ha or less, 7500 g ai/ha or less, 7250 g ai/ha or less, 7000 g ai/ha or less, 6750 g ai/ha or less, 6500 g ai/ha or less, 6250 g ai/ha or less, 6000 g ai/ha or less, 5750 g ai/ha or less, 5500 g ai/ha or less, 5250 g ai/ha or less, 5000 g ai/ha or less, 4750 g ai/ha or less, 4500 g ai/ha or less, 4250 g ai/ha or less, 4000 g ai/ha or less, 3750 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, or 800 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 750 g – 15 kg ai/ha, 950–6500 g ai/ha, 4000–9750 g ai/ha, 10– 14 kg ai/ha, 3500 g – 12.5 kg ai/ha, 11–12.5 kg ai/ha, 9500 g – 15 kg ai/ha, 4750–8750 g ai/ha, 6500–9250 g ai/ha, 5000 g –14 kg ai/ha, 10.5–13.5 kg ai/ha, or 800 g –14.5 kg ai/ha. Prohexadione Compositions and methods of the present disclosure can include prohexadione or an agriculturally acceptable salt or ester thereof, particularly the calcium salt. Prohexadione, shown below, is fatty acid used for: control of lodging in small-grain cereals, at 75–100 g/ha; growth retardant in turf, at 200–400 g/ha, peanuts, at 100–300 g/ha, and flowers, at 50–100 g/ha; inhibition of new twig elongation in tree fruit, at 200–400 g/ha. Prohexadione, as well as methods of preparing prohexadione, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Prohexadione can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, prohexadione is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 15 g ai/ha or more, such as 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, or 675 g ai/ha or more; in an amount of 700 g ai/ha or less, such as 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, or 20 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 15–700 g ai/ha, 45–650 g ai/ha, 30–375 g ai/ha, 160–250 g ai/ha, 220–550 g ai/ha, 110– 450 g ai/ha, 290–490 g ai/ha, 70–430 g ai/ha, 300–525 g ai/ha, 500–650 g ai/ha, 340–575 g ai/ha, or 20–675 g ai/ha. Prohydrojasmon Compositions and methods of the present disclosure can include prohydrojasmon or an agriculturally acceptable salt or ester thereof. Prohydrojasmon, shown below, is a synthetic plant hormone used for: prevention of rind puffing in Satsuma mandarin oranges and promotion of red color development in apples. Prohydrojasmon, as well as methods of preparing prohydrojasmon, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Propham Compositions and methods of the present disclosure can include propham or an agriculturally acceptable salt or ester thereof. Propham, shown below, is a carbamate used for control of annual grass and some broad-leaved weeds in alfalfa, clover, sugar beets, spinach, lettuce, peas, beans, flax, safflowers, beetroot, fodder beets, lettuce, chard, lentils and perennial grass seed crops, at 2300–5000 g/ha, and as a sprouting inhibitor in potatoes. Propham, as well as methods of preparing propham, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Propham can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, propham is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2000 g ai/ha or more, such as 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3750 g ai/ha or more, 4000 g ai/ha or more, 4250 g ai/ha or more, 4500 g ai/ha or more, 4750 g ai/ha or more, 5000 g ai/ha or more, 5250 g ai/ha or more, 5500 g ai/ha or more, 5750 g ai/ha or more, 6000 g ai/ha or more, 6250 g ai/ha or more, 6500 g ai/ha or more, or 6750 g ai/ha or more; in an amount of 7000 g ai/ha or less, such as 6750 g ai/ha or less, 6500 g ai/ha or less, 6250 g ai/ha or less, 6000 g ai/ha or less, 5750 g ai/ha or less, 5500 g ai/ha or less, 5250 g ai/ha or less, 5000 g ai/ha or less, 4750 g ai/ha or less, 4500 g ai/ha or less, 4250 g ai/ha or less, 4000 g ai/ha or less, 3750 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, or 2100 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2000–7000 g ai/ha, 4750–6500 g ai/ha, 2300–3750 g ai/ha, 4000–6000 g ai/ha, 2700–5000 g ai/ha, 3100–4750 g ai/ha, 2500–4000 g ai/ha, 5750–7000 g ai/ha, 3300–5250 g ai/ha, 2000–4500 g ai/ha, 2900–5500 g ai/ha, or 2100– 6750 g ai/ha. Sintofen Compositions and methods of the present disclosure can include sintofen or an agriculturally acceptable salt or ester thereof. Sintofen, shown below, is a carboxylic acid used for sterilizing spring and winter wheat for use in hybridization, at 800 g/ha. Sintofen, as well as methods of preparing sintofen, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Thidiazuron Compositions and methods of the present disclosure can include thidiazuron or an agriculturally acceptable salt or ester thereof. Thidiazuron, shown below, is a carboxylic acid used for defoliation of cotton, at 210 g/ha. Thidiazuron, as well as methods of preparing thidiazuron, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Thidiazuron can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, thidiazuron is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, or 340 g ai/ha or more; in an amount of 350 g ai/ha or less, such as 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, or 55 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–350 g ai/ha, 125–330 g ai/ha, 60–300 g ai/ha, 70–250 g ai/ha, 250–340 g ai/ha, 130– 190 g ai/ha, 90–240 g ai/ha, 75–220 g ai/ha, 80–325 g ai/ha, 160–200 g ai/ha, 50–240 g ai/ha, or 55–340 g ai/ha. Triacontanol Compositions and methods of the present disclosure can include triacontanol or an agriculturally acceptable salt or ester thereof. Triacontanol, shown below, is a fatty alcohol used to increase the yields in cotton, potato, chilis, tomatoes, rice, grains and peanuts, and to increase the dry matter content, plant height, root spread and uniform, early maturity in crops. Triacontanol, as well as methods of preparing triacontanol, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Trinexapac Compositions and methods of the present disclosure can include trinexapac or an agriculturally acceptable salt or ester thereof. Trinexapac, shown below, is a cyclohexanedione used to: prevent lodging in cereals and winter oilseed rape, at 100–300 g/ha; retard growth in turf, at 150–500 g/ha; and promote maturation in sugar cane, at 100–250 g/ha. Trinexapac, as well as methods of preparing trinexapac, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Trinexapac can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, trinexapac is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, or 575 g ai/ha or more; in an amount of 600 g ai/ha or less, such as 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, or 55 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–600 g ai/ha, 75–500 g ai/ha, 160– 375 g ai/ha, 240–500 g ai/ha, 150–370 g ai/ha, 120–450 g ai/ha, 190–400 g ai/ha, 60–220 g ai/ha, 380–525 g ai/ha, 225–420 g ai/ha, 400–550 g ai/ha, or 55–575 g ai/ha. Uniconazole Compositions and methods of the present disclosure can include uniconazole or an agriculturally acceptable salt or ester thereof. Uniconazole, shown below, is a triazole used to: reduce lodging in rice; reduce vegetative growth and increase flowering in ornamentals, at a spray concentration of 0.5-50 ppm; and reduce vegetative growth in trees. Uniconazole-P is an optically active form of uniconazole. Uniconazole, as well as methods of preparing uniconazole, are known in the art. Its plant growth regulation activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. COMPOSITIONS A composition comprising compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof) may be mixed with or applied in combination with (b) a plant growth regulator (PGR), an agriculturally acceptable salt or ester thereof, or mixtures thereof. In some aspects, (a) and (b) are used in an amount sufficient to induce an enhanced herbicidal effect (e.g., increased damage or injury to undesirable vegetation) while still showing good crop compatibility (e.g., no increased damage to crops or minimal increased damage or injury to crops) when compared to the individual application of the herbicidal compounds (a) or (b). In some aspects, the damage or injury to undesirable vegetation caused by the compositions and methods disclosed herein is evaluated using a scale from 0% to 100%, when compared with the untreated control vegetation, wherein 0% indicates no damage to the undesirable vegetation and 100% indicates complete destruction of the undesirable vegetation. In some aspects, the joint action of (a) the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and (b) the PGR, an agriculturally acceptable salt or ester thereof, or mixtures thereof results in enhanced herbicidal effect against undesirable vegetation, even at application rates below those typically used for the herbicide to have a herbicidal effect on its own. In some aspects, the compositions and methods disclosed herein can, based on the individual components, be used at lower application rates to achieve a herbicidal effect comparable to the effect produced by the individual components at normal application rates. In some aspects, the weight ratio of (a) the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof) (in g ae/ha) to (b) the PGR, an agriculturally acceptable salt or ester thereof, or mixtures thereof (in g ai/ha) is 1:7500 or more, such as 1:7000 or more, 1:6000 or more, 1:5000 or more, 1:4000 or more, 1:3000 or more, 1:2500 or more, 1:2000 or more, 1:1500 or more, 1:1000 or more, 1: 900 or more, 1: 800 or more, 1:700 or more, 1:600 or more, 1:500 or more, 1:400 or more, 1:300 or more, 1:250 or more, 1:200 or more, 1:150 or more, 1:100 or more, 1:90 or more, 1:80 or more, 1:75 or more, 1:70 or more, 1: 60 or more, 1:50 or more, 1:40 or more, 1:35 or more, 1:30 or more, 1:28 or more, 1:26 or more, 1:25 or more, 1:24 or more, 1:22 or more, 1:21 or more, 1:20 or more, 1:18 or more, 1:16 or more, 1:15 or more, 1:14 or more, 1:12 or more, 1:10 or more, 1:9 or more, 1:8 or more, 1:7 or more, 1:6 or more, 1:5 or more, 1:4 or more, 1:3 or more, 1:2 or more, 1:1.9 or more, 1:1.8 or more, 1:1.7 or more, 1:1.6 or more, 1:1.5 or more, 1:1.4 or more, 1:1.3 or more, 1:1.2 or more, 1:1.1 or more, 1:1 or more, 1.1:1 or more, 1.25:1 or more, 1.5:1 or more, 1.75:1 or more, 2:1 or more, 2.5:1 or more, 3:1 or more, 3.5:1 or more, 4:1 or more, 4.5:1 or more, 5:1 or more, 6:1 or more, 7:1 or more, 8:1 or more, 9:1 or more, 10:1 or more, 11:1 or more, 12:1 or more, 13:1 or more, or 14:1 or more; in some aspects, the weight ratio of (a) to (b) is 15:1 or less, such as 14:1 or less, 13:1 or less, 12:1 or less,11:1 or less, 10:1 or less, 9:1 or less, 8:1 or less, 7:1 or less, 6:1 or less, 5:1 or less, 4.5:1 or less, 4:1 or less, 3.5:1 or less, 3:1 or less, 2.5:1 or less, 2:1 or less, 1.75:1 or less, 1.5:1 or less, 1.25:1 or less, 1.1:1 or less, 1:1 or less, 1:1.1 or less, 1:1.2 or less, 1:1.3 or less, 1:1.4 or less, 1:1.5 or less, 1:1.6 or less, 1:1.7 or less, 1:1.8 or less, 1:1.9 or less, 1:2 or less, 1:3 or less, 1:4 or less, 1:5 or less, 1:6 or less, 1:7 or less, 1:8 or less, 1:9 or less, 1:10 or less, 1:12 or less, 1:14 or less, 1:15 or less, 1:16 or less, 1:18 or less, 1:20 or less, 1:21 or less, 1:22 or less, 1:24 or less, 1:25 or less, 1:26 or less, 1:28 or less, 1:30 or less, 1:35 or less, 1:40 or less, 1:50 or less, 1:60 or less, 1:70 or less, 1:80 or less, 1:90 or less, 1:100 or less, 1:150 or less, 1:200 or less, 1:250 or less, 1:300 or less, 1:400 or less, 1:500 or less, 1:600 or less, 1:700 or less, 1:800 or less, 1:900 or less, 1:1000 or less, 1:1500 or less, 1:2000 or less, 1:2500 or less, 1:3000 or less, 1:4000 or less, 1:5000 or less, 1:6000 or less, or 1:7000 or less; or the weight ratio of (a) to (b) can range from any of the minimum ratios to any of the maximum ratios provided above, such as from 1:7500 to 15:1, from 1:6000 to 13:1, from 1:4000 to 11:1, from 1:1250 to 9:1, from 1:1500 to 1:50, from 1:20 to 8:1, from 1:8 to 2:1, or from 1:5 to 1:1. In some aspects, the active ingredients in the compositions disclosed herein consist of compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), and (b) a PGR, an agriculturally acceptable salt or ester thereof, or mixtures thereof. In some aspects, the composition may include other components, such as safeners or adjuvants, but does not include a herbicidal active ingredient in addition to (a) and (b). In some aspects, the compositions may exclude one or more herbicidal active ingredients specified above. In some aspects, the compositions may include one or more herbicidal active ingredients in addition to (a) and (b), but may exclude one or more herbicidal ingredients specified above. In some aspects, (a) and (b), independently, can be employed in a purity of from 90% to 100% (e.g., from 95% to 100%) according to nuclear magnetic resonance (NMR) spectroscopy. ACCASE INHIBITOR HERBICIDES In addition to the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), the compositions include an acetyl CoA carboxylase (ACCase) inhibitor herbicide or an agriculturally acceptable salt or ester thereof. ACCase inhibitor herbicides inhibit lipid biosynthesis in the plant. Examples of ACCase inhibitor herbicides include aryloxyphenoxypropionates, cyclohexanediones, and phenylpyrazolines. In some aspects, the ACCase inhibitor herbicide can include an aryloxyphenoxypropionate herbicide. In some aspects, the ACCase inhibitor herbicide can include a cyclohexanedione herbicide. In some aspects, the ACCase inhibitor herbicide can include a phenylpyrazoline herbicide. In some aspects, the composition can include an ACCase inhibitor selected from the group of cyclohexanediones, aryloxyphenoxypropionates, phenylpyrazolines, or combinations thereof. In some cases, the composition can include clodinafop, cyhalofop, diclofop, fenoxaprop, fenthiaprop, fluazifop, haloxyfop, metamifop, propaquizafop, quizalofop, agriculturally acceptable salts or esters thereof, or combinations thereof. In some cases, the composition can include, alloxydim, butroxydim, clethodim, cloproxydim, cycloxydim, profoxydim, sethoxydim, tepraloxydim, tralkoxydim, agriculturally acceptable salts or esters thereof, or combinations thereof. In some cases, the composition can include pinoxaden. In some aspects, the composition can include an ACCase inhibitor herbicide selected from the group consisting of alloxydim, butroxydim, clethodim, clodinafop, cloproxydim, cycloxydim, cyhalofop, diclofop, fenoxaprop, fenthiaprop, fluazifop, haloxyfop, metamifop, pinoxaden, profoxydim, propaquizafop, quizalofop, sethoxydim, tepraloxydim, tralkoxydim, agriculturally acceptable salts and esters thereof, and combinations thereof. The ACCase inhibitor herbicide or agriculturally acceptable salt or ester thereof can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, the ACCase inhibitor herbicide or agriculturally acceptable salt or ester thereof is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2 g ai/ha or more, such as 2.5 g ai/ha or more, 3 g ai/ha or more, 3.5 g ai/ha or more, 4 g ai/ha or more, 4.5 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, or 1450 g ai/ha or more; in an amount of 1500 g ai/ha or less, such as 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1240 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4.5 g ai/ha or less, 4 g ai/ha or less, 3.5 g ai/ha or less, 3 g ai/ha or less, or 2.5 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2-1500 g ai/ha, 5–1300 g ai/ha, 6-250 g ai/ha, 75–1240 g ai/ha, 90–900 g ai/ha, 55–290 g ai/ha, 7–600 g ai/ha, 20–700 g ai/ha, 190–1450 g ai/ha, 65–1100 g ai/ha, 320–1000 g ai/ha, 250–750 g ai/ha, 700–1200 g ai/ha, 850–1400 g ai/ha, or 2.5–1450 g ai/ha. In some aspects, the composition contains: compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof); and (b) alloxydim, butroxydim, clethodim, clodinafop, cloproxydim, cycloxydim, cyhalofop, diclofop, fenoxaprop, fenthiaprop, fluazifop, haloxyfop, metamifop, pinoxaden, profoxydim, propaquizafop, quizalofop, sethoxydim, tepraloxydim, tralkoxydim, agriculturally acceptable salts and esters thereof, and combinations thereof. Alloxydim Compositions and methods of the present disclosure can include alloxydim or an agriculturally acceptable salt or ester thereof. Alloxydim, shown below, is a cyclohexanedione herbicide that provides post-emergence control of grass weeds and volunteer cereals in sugar beet, vegetables and broad-leaved crops. Alloxydim, as well as methods of preparing alloxydim, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Alloxydim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, alloxydim is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 299 g ai/ha or more, such as 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 620 g ai/ha or more, 640 g ai/ha or more, 660 g ai/ha or more, 680 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, or 1500 g ai/ha or more; in an amount of 1501 g ai/ha or less, such as 1500 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 680 g ai/ha or less, 660 g ai/ha or less, 640 g ai/ha or less, 620 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, or 300 g ai/ha or less; or from any of the minimum values described above to any of the maximum values described above, such as 299–1501 g ai/ha, 380–1250 g ai/ha, 440–850 g ai/ha, 700– 1000 g ai/ha, 320–950 g ai/ha, 680–1350 g ai/ha, 400–1050 g ai/ha, 500–1000 g ai/ha, 600– 900 g ai/ha, 700–1300 g ai/ha, 500–700 g ai/ha, or 320-1400 g ai/ha. Butroxydim Compositions and methods of the present disclosure can include butroxydim or an agriculturally acceptable salt or ester thereof. Butroxydim, shown below, is a cyclohexanedione herbicide that provides post-emergence control of annual grasses in many broad-leaved crops. Butroxydim, as well as methods of preparing butroxydim, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Butroxydim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, butroxydim is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 9 g ai/ha or more, such as10 g ai/ha or more, 15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 105 g ai/ha or more, 110 g ai/ha or more, 115 g ai/ha or more, or 120 g ai/ha or more; in an amount of 121 g ai/ha or less, such as 120 g ai/ha or less, 115 g ai/ha or less, 110 g ai/ha or less, 105 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, or 10 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 9–121 g ai/ha, 10–115 g ai/ha, 20–110 g ai/ha, 15–85 g ai/ha, 30–100 g ai/ha, 50–95 g ai/ha, 15–60 g ai/ha, 25–85 g ai/ha, 40–80 g ai/ha, 20–75 g ai/ha, 35–110 g ai/ha, 25–105 g ai/ha, 15–55 g ai/ha, or 10–120 g ai/ha. Clethodim Compositions and methods of the present disclosure can include clethodim or an agriculturally acceptable salt or ester thereof. Clethodim, shown below, is a cyclohexanedione herbicide that provides post-emergence control of annual and perennial grasses in a wide range of broad-leaved crops, including such field crops as canola/oilseed rape, soybean, cotton, flax, sunflowers, alfalfa, peanuts, sugar beet, tobacco, and potatoes, as well as vegetable crops, trees, and vines. Clethodim, as well as methods of preparing clethodim, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Clethodim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, clethodim is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2 g ai/ha or more, such as 3 g ai/ha or more, 4 g ai/ha or more, 6 g ai/ha or more, 8 g ai/ha or more, 10 g ai/ha or more, 12 g ai/ha or more, 14 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 620 g ai/ha or more, 640 g ai/ha or more, 660 g ai/ha or more, 680 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, or 875 g ai/ha or more; in an amount of 900 g ai/ha or less, such as 875 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 680 g ai/ha or less, 660 g ai/ha or less, 640 g ai/ha or less, 620 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 235 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 215 g ai/ha or less, 210 g ai/ha or less, 205 g ai/ha or less, 200 g ai/ha or less, 195 g ai/ha or less, 190 g ai/ha or less, 185 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 165 g ai/ha or less, 160 g ai/ha or less, 155 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 18 g ai/ha or less, 16 g ai/ha or less, 14 g ai/ha or less, 12 g ai/ha or less, 10 g ai/ha or less, 8 g ai/ha or less, 6 g ai/ha or less, 4 g ai/ha or less, or 3 g ai/ha or less, or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2–900 g ai/ha, 3–800 g ai/ha, 6–700 g ai/ha, 22–500 g ai/ha, 12–600 g ai/ha, 5–500 g ai/ha, 40–440 g ai/ha, 20–700 g ai/ha, 80–400 g ai/ha, 60–270 g ai/ha, 80–750 g ai/ha, 100–290 g ai/ha, 175–750 g ai/ha, 300–900 g ai/ha, 3–100 g ai/ha, 35–320 g ai/ha, 3–205 g ai/ha, 4–50 g ai/ha, or 3–875 g ai/ha. Clodinafop Compositions and methods of the present disclosure can include clodinafop or an agriculturally acceptable salt or ester thereof. Clodinafop-propargyl, shown below, is prop-2- ynyl (R)-2-[4-(5-chloro-3-fluoropyridin-2-yloxy)phenoxy]propionat e and is used for post- emergence control of annual grasses, including Avena, Lolium, Setaria, Phalaris, and Alopecurus spp., in cereals. . Clodinafop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, clodinafop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 10 g ai/ha or more, such as 11 g ai/ha or more, 12 g ai/ha or more, 13 g ai/ha or more, 14 g ai/ha or more,15 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, or 95 g ai/ha or more; in an amount of 100 g ai/ha or less, such as 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 15 g ai/ha or less, 14 g ai/ha or less, 13 g ai/ha or less, 12 g ai/ha or less, or 11 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 10– 100 g ai/ha, 15–90 g ai/ha, 12–80 g ai/ha, 25–70 g ai/ha, 14–40 g ai/ha, 20–85 g ai/ha, 30–60 g ai/ha, 40–90 g ai/ha, 50–100 g ai/ha, 20–90 g ai/ha, 50–95 g ai/ha, 30–90 g ai/ha, 20–60 g ai/ha, 30–80 g ai/ha, 13–75 g ai/ha, or 11–95 g ai/ha. Cloproxydim Compositions and methods of the present disclosure can include cloproxydim or an agriculturally acceptable salt or ester thereof. Cloproxydim, shown below, is a cyclohexanedione herbicide that has been evaluated by the Chevron Chemical Company. Cloproxydim provides post-emergence control of a wide range of annual and perennial grasses in beans, cotton, potatoes, sugar beets, and most vegetable crops. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Cycloxydim Compositions and methods of the present disclosure can include cycloxydim or an agriculturally acceptable salt or ester thereof. Cycloxydim, shown below, is a cyclohexanedione herbicide that provides post-emergence control of annual and perennial grasses (except red fescue and Poa spp.) in canola/oilseed rape, beans, potatoes, brassicas, cotton, celery, fennel, beetroot, sugar beets, fodder beets, sunflowers, soybeans, flax, alfalfa, crucifers, and alliums. Cycloxydim, as well as methods of preparing cycloxydim, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Cycloxydim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, cycloxydim is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 55 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, or 675 g ai/ha or more;in an amount of 700 g ai/ha or less, such as 675 g ai/ha or less, 650 g ai/ha or less, 640 g ai/ha or less, 620 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 195 g ai/ha or less, 190 g ai/ha or less, 185 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 165 g ai/ha or less, 160 g ai/ha or less, 155 g ai/ha or less, 150 g ai/ha or less, 145 g ai/ha or less, 140 g ai/ha or less, 135 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 115 g ai/ha or less, 110 g ai/ha or less, 105 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, or 55 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–700 g ai/ha, 60–600 g ai/ha, 90–400 g ai/ha, 100–580 g ai/ha, 50–300 g ai/ha, 75–460 g ai/ha, 110–620 g ai/ha, 190–280 g ai/ha, 140–400 g ai/ha, 95– 660 g ai/ha, 80–580 g ai/ha, 200–700 g ai/ha, 250–300 g ai/ha, 65–400 g ai/ha, 90–320 g ai/ha, or 55–675 g ai/ha. Cyhalofop Compositions and methods of the present disclosure can include cyhalofop or an agriculturally acceptable salt or ester thereof. Cyhalofop, as well as methods of preparing cyhalofop, are known in the art. Cyhalofop is an aryloxyphenoxypropionate ester that is used for post-emergence control of grass weeds in rice. Cyhalofop-butyl, shown below, is an ester of cyhalofop. Cyhalofop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, cyhalofop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 20 g ai/ha or more, such as 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 120 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 180 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, or 500 g ai/ha or more; in an amount of 500 g ai/ha or less, such as 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 180 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 120 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, or 25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 20–500 g ai/ha, 20–450 g ai/ha, 25–200 g ai/ha, 40–400 g ai/ha, 60–375 g ai/ha, 40–350 g ai/ha, 50–250 g ai/ha, 60–325 g ai/ha, 90–275 g ai/ha, 70–325 g ai/ha, 40–225 g ai/ha, 140–300 g ai/ha, 35-160 g ai/ha, 80–350 g ai/ha, 150–450 g ai/ha, 200–425 g ai/ha, or 25–475 g ai/ha. Diclofop Compositions and methods of the present disclosure can include diclofop or an agriculturally acceptable salt or ester thereof. Diclofop-methyl, shown below, is an aryloxyphenoxypropionate that is used for post-emergence control of wild oats, wild millets, and other annual grass weeds in wheat, barley, rye, red fescue, and broad-leaved crops such as soybeans, sugar beets, fodder beets, flax, legumes, canola/oilseed rape, sunflowers, clover, alfalfa, peanuts, brassicas, carrots, celery, parsnips, lettuce, spinach, potatoes, cucumbers, peas, beans, tomatoes, fennel, alliums, and herbs. Diclofop, as well as methods of preparing diclofop, are known in the art. Diclofop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, diclofop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount 100 g ai/ha or more, such as 150 g ai/ha or more, 175 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 620 g ai/ha or more, 640 g ai/ha or more, 660 g ai/ha or more, 680 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, or 1200 g ai/ha or more; in an amount of 1200 g ai/ha or less, such as 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 680 g ai/ha or less, 660 g ai/ha or less, 640 g ai/ha or less, 620 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 175 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, or 101 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 100–1200 g ai/ha, 120–1200 g ai/ha, 140–1100 g ai/ha, 150–900 g ai/ha, 175–1000 g ai/ha, 200–1150 g ai/ha, 360–1050 g ai/ha, 220–640 g ai/ha, 240–800 g ai/ha, 110–700 g ai/ha, 300–440 g ai/ha, 750– 1000 g ai/ha, 360–950 g ai/ha, 175–850 g ai/ha, 400–650 g ai/ha, 150–280 g ai/ha, 500–600 g ai/ha, or 110–1150 g ai/ha). Fenoxaprop Compositions and methods of the present disclosure can include fenoxaprop or an agriculturally acceptable salt or ester thereof. Fenoxaprop is an aryloxyphenoxypropionate that is used for post-emergence control of annual and perennial grass weeds in potatoes, beans, soybeans, beets, vegetables, peanuts, and cotton; and (when applied with the herbicide safener fenchlorazole-ethyl) annual and perennial grass weeds and wild oats in wheat, rye, and triticale. Fenoxaprop-P-ethyl, shown below, is an ester of fenoxaprop. Fenoxaprop, as well as methods of preparing fenoxaprop, are known in the art. Fenoxaprop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, fenoxaprop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 25 g ai/ha or more, such as 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 105 g ai/ha or more, 110 g ai/ha or more, 115 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 135 g ai/ha or more, 140 g ai/ha or more, 145 g ai/ha or more, or 150 g ai/ha or more; in an amount of 151 g ai/ha or less, such as 150 g ai/ha or less, 145 g ai/ha or less, 140 g ai/ha or less, 135 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 115 g ai/ha or less, 110 g ai/ha or less, 105 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, or 25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 25–151 g ai/ha, 30–150 g ai/ha, 35–140 g ai/ha, 50–130 g ai/ha, 30–125 g ai/ha, 85–150 g ai/ha, 45–145 g ai/ha, 25–110 g ai/ha, 40–90 g ai/ha, 55–120 g ai/ha, 40–115 g ai/ha, 60–110 g ai/ha, 30–105 g ai/ha, 90–151 g ai/ha, 25–95 g ai/ha, 50–80 g ai/ha, 60–125 g ai/ha, or 25–145 g ai/ha. Fenthiaprop Compositions and methods of the present disclosure can include fenthiaprop or an agriculturally acceptable salt or ester thereof. Fenthiaprop, shown below, is an aryloxyphenoxypropionate herbicide that is used for post-emergence control of many annual and perennial grasses and volunteer cereals in canola/oilseed rape, potatoes, and sugar beets. Fenthiaprop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, fenthiaprop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount 150 g ai/ha or more, such as 160 g ai/ha or more,170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 550 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 620 g ai/ha or more, 640 g ai/ha or more, 650 g ai/ha or more, 660 g ai/ha or more, 680 g ai/ha or more, 700 g ai/ha or more, or 725 g ai/ha or more; in an amount of 750 g ai/ha or less, such as 725 g ai/ha or less, 700 g ai/ha or less, 680 g ai/ha or less, 660 g ai/ha or less, 650 g ai/ha or less, 640 g ai/ha or less, 620 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 550 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, or 160 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 150–750 g ai/ha, 180–600 g ai/ha, 170–650 g ai/ha, 250–700 g ai/ha, 280–450 g ai/ha, 360– 580 g ai/ha, 220–640 g ai/ha, 240–725 g ai/ha, 340–440 g ai/ha, 260–550 g ai/ha, 170–250 g ai/ha, 400–650 g ai/ha, 190–580 g ai/ha, 500–600 g ai/ha, or 160–725 g ai/ha. Fluazifop Compositions and methods of the present disclosure can include fluazifop or an agriculturally acceptable salt or ester thereof. Fluazifop is an aryloxyphenoxypropionate that is used for post-emergence control of annual and perennial grass weeds in broad-leaved crops, including control of volunteer cereals and other grass weeds in canola/oilseed rape, sugar beet, fodder beet, potatoes, cotton, soybeans, peanuts, pome fruit, bush fruit, vines, citrus fruit, pineapples, bananas, strawberries, sunflowers, alfalfa, coffee, ornamentals and many vegetables. Fluazifop-P-butyl, shown below, is an ester of fluazifop. Fluazifop, as well as methods of preparing fluazifop, are known in the art. Fluazifop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, fluazifop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 100 grams active ingredient per hectare (g ai/ha) or more, such as 105 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, or 1350 g ai/ha or more; in an amount of 1400 g ai/ha or less, such as 1350 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less or 105 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, e.g., 100–1400 g ai/ha, 140–1300 g ai/ha, 180–1200 g ai/ha, 200–950 g ai/ha, 300–800 g ai/ha, 250– 700 g ai/ha, 130–450 g ai/ha, 100–500 g ai/ha, 190–850 g ai/ha, 110–375 g ai/ha, 225–475 g ai/ha, 130–600 g ai/ha, 150–1200 g ai/ha, 190-700 g ai/ha, 175–350 g ai/ha, 500–1100 g ai/ha, or 105–1350 g ai/ha. Haloxyfop Compositions and methods of the present disclosure can include haloxyfop or an agriculturally acceptable salt or ester thereof. Haloxyfop is an aryloxyphenoxypropionate that is used post-emergence for control of annual and perennial grasses in sugar beets, fodder beets, canola/oilseed rape, potatoes, leafy vegetables, onions, flax, sunflowers, soybeans, vines, strawberries and other crops. Haloxyfop-P-methyl, shown below, is an ester of haloxyfop; haloxyfop-R-methyl is the racemic form of this herbicide. Haloxyfop, as well as methods of preparing haloxyfop, are known in the art. Haloxyfop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, haloxyfop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 24 g ai/ha or more, such as 25 g ai/ha or more, 30 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, or 245 g ai/ha or more; in an amount of 250 g ai/ha or less, such as 245 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, or 25 g ai/ha or less; in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 24–250 g ai/ha, 25–225 g ai/ha, 35–200 g ai/ha, 55–190 g ai/ha, 25–180 g ai/ha, 30–175 g ai/ha, 30–230 g ai/ha, 130–220 g ai/ha, 60–160 g ai/ha, 75–150 g ai/ha, 35–150 g ai/ha, 60–140 g ai/ha, 80–230 g ai/ha, 90–210 g ai/ha, 55–110 g ai/ha, 70–240 g ai/ha, or 25– 245 g ai/ha. Metamifop Compositions and methods of the present disclosure can include metamifop. Metamifop, shown below, is an aryloxyphenoxypropionate that is used for post-emergence control of annual and perennial grass weeds (including Echinochloa spp., Leptochloa chinensis, Digitaria spp. and Eleusine indica) in rice, wheat, soybeans, cotton, and turf grass. Metamifop, as well as methods of preparing metamifop, are known in the art. Metamifop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, metamifop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 105 g ai/ha or more, 110 g ai/ha or more, 115 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 135 g ai/ha or more, 140 g ai/ha or more, 145 g ai/ha or more, 150 g ai/ha or more, 155 g ai/ha or more, 160 g ai/ha or more, 165 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 185 g ai/ha or more, 190 g ai/ha or more, 195 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, or 295 g ai/ha or more; in an amount of 300 g ai/ha or less, such as 295 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 195 g ai/ha or less, 190 g ai/ha or less, 185 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 165 g ai/ha or less, 160 g ai/ha or less, 155 g ai/ha or less, 150 g ai/ha or less, 145 g ai/ha or less, 140 g ai/ha or less, 135 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 115 g ai/ha or less, 110 g ai/ha or less, 105 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, or 55 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–300 g ai/ha, 60–275 g ai/ha, 80–250 g ai/ha, 55–125 g ai/ha, 60–200 g ai/ha, 70–160 g ai/ha, 80–210 g ai/ha, 90–270 g ai/ha, 100– 175 g ai/ha, 120–230 g ai/ha, 145–250 g ai/ha, or 55–295 g ai/ha. Pinoxaden Compositions and methods of the present disclosure can include pinoxaden or an agriculturally acceptable salt or ester thereof. Pinoxaden, shown below, is a phenylpyrazoline herbicide that provides post-emergence control of grass weeds in wheat, barley, lawns, and turf. Pinoxaden, as well as methods of preparing pinoxaden, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Pinoxaden can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pinoxaden is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2 g ai/ha or more, such as 2.5 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 8 g ai/ha or more, 10 g ai/ha or more, 12 g ai/ha or more, 14 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, or 490 g ai/ha or more; in an amount of 500 g ai/ha or less, such as 490 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 235 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 215 g ai/ha or less, 210 g ai/ha or less, 205 g ai/ha or less, 200 g ai/ha or less, 195 g ai/ha or less, 190 g ai/ha or less, 185 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 165 g ai/ha or less, 160 g ai/ha or less, 155 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 18 g ai/ha or less, 16 g ai/ha or less, 14 g ai/ha or less, 12 g ai/ha or less, 10 g ai/ha or less, 8 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, or 2.5 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2–500 g ai/ha, 3–400 g ai/ha, 5–300 g ai/ha, 8–100 g ai/ha, 5–500 g ai/ha, 10–120 g ai/ha, 22–190 g ai/ha, 40–300 g ai/ha, 30–400 g ai/ha, 80–270 g ai/ha, 100–480 g ai/ha, 150–250 g ai/ha, 110–380 g ai/ha, 8–235 g ai/ha, 30–260 g ai/ha, 24–50 g ai/ha, 10–300 g ai/ha, 16–180 g ai/ha, or 2.5–490 g ai/ha. Profoxydim Compositions and methods of the present disclosure can include profoxydim or an agriculturally acceptable salt or ester thereof. Profoxydim, shown below, is a cyclohexanedione herbicide. Profoxydim is used for control of grass weeds, including Echinochloa spp., Brachiaria spp., Digitaria spp., Eleusine spp., Leptochloa spp., Setaria spp., Ischaemum rugosum and Rottboellia exaltata, in rice. Profoxydim, as well as methods of preparing profoxydim, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Profoxydim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, profoxydim is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 105 g ai/ha or more, 110 g ai/ha or more, 115 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 135 g ai/ha or more, 140 g ai/ha or more, 145 g ai/ha or more, 150 g ai/ha or more, 155 g ai/ha or more, 160 g ai/ha or more, 165 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 185 g ai/ha or more, 190 g ai/ha or more, 195 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 280 g ai/ha or more, or 290 g ai/ha or more; in an amount of 300 g ai/ha or less (e.g., 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 195 g ai/ha or less, 190 g ai/ha or less, 185 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 165 g ai/ha or less, 160 g ai/ha or less, 155 g ai/ha or less, 150 g ai/ha or less, 145 g ai/ha or less, 140 g ai/ha or less, 135 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 115 g ai/ha or less, 110 g ai/ha or less, 105 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, or 55 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–300 g ai/ha., 60–275 g ai/ha, 85–250 g ai/ha, 60–220 g ai/ha, 120–280 g ai/ha, 150– 180 g ai/ha, 70–160 g ai/ha, 55–240 g ai/ha, 90–290 g ai/ha, 75–100 g ai/ha, 115–270 g ai/ha, 70–200 g ai/ha, or 55–290 g ai/ha. Propaquizafop Compositions and methods of the present disclosure can include propaquizafop. Propaquizafop, shown below, is an aryloxyphenoxypropionate that is to control a wide range of annual and perennial grasses in soybeans, cotton, sugar beets, potatoes, peanuts, peas, canola/oilseed rape and vegetables. Propaquizafop, as well as methods of preparing propaquizafop, are known in the art. Propaquizafop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, propaquizafop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 29 g ai/ha or more, such as 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 280 g ai/ha or more, or 290 g ai/ha or more; in an amount of 300 g ai/ha or less (e.g., 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, or 30 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 29–300 g ai/ha, 30–290 g ai/ha, 35–180 g ai/ha, 40–270 g ai/ha, 45–200 g ai/ha, 50–250 g ai/ha, 60–140 g ai/ha, 80–230 g ai/ha, 40–220 g ai/ha, 65–290 g ai/ha, 35–200 g ai/ha, 80–180 g ai/ha, 60–260 g ai/ha, 30–120 g ai/ha, 80–190 g ai/ha, 160–270 g ai/ha, or 30–290 g ai/ha. Quizalofop Compositions and methods of the present disclosure can include quizalofop or an agriculturally acceptable salt or ester thereof. Quizalofop is an aryloxyphenoxypropionate that is used for selective post-emergence control of annual and perennial grass weeds in potatoes, soybeans, sugar beets, peanuts, canola/oilseed rape, sunflowers, vegetables, cotton and flax. Quizalofop-P-ethyl, shown below, is an ester of quizalofop. Quizalofop, as well as methods of preparing quizalofop, are known in the art. Quizalofop can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, quizalofop is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 24 g ai/ha or more, such as 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, or 245 g ai/ha or more; in an amount of 250 g ai/ha or less (e.g., 245 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, or 25 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 24–250 g ai/ha, 25–225 g ai/ha, 55–200 g ai/ha, 40–190 g ai/ha, 25–80 g ai/ha, 60–175 g ai/ha, 110–225 g ai/ha, 75–160 g ai/ha, 45–220 g ai/ha, 80–150 g ai/ha, 30–90 g ai/ha, 40–100 g ai/ha, 50–180 g ai/ha, 60–230 g ai/ha, 60–120 g ai/ha, 40–100 g ai/ha, or 25–245 g ai/ha. Sethoxydim Compositions and methods of the present disclosure can include sethoxydim or an agriculturally acceptable salt or ester thereof. Sethoxydim, shown below, is a cyclohexanedione herbicide that is used for controlling annual and perennial grasses in broad- leaved crops, including canola/oilseed rape, soybean, cotton, fodder beets, sunflowers, spinach, potatoes, tobacco, peanuts, strawberries, alfalfa, flax, vegetables, and sugar beet. Sethoxydim, as well as methods of preparing sethoxydim, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Sethoxydim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, sethoxydim is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2 g ai/ha or more, such as 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 8 g ai/ha or more, 10 g ai/ha or more, 12 g ai/ha or more, 14 g ai/ha or more, 16 g ai/ha or more, 18 g ai/ha or more, 20 g ai/ha or more, 22 g ai/ha or more, 24 g ai/ha or more, 26 g ai/ha or more, 28 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 620 g ai/ha or more, 640 g ai/ha or more, 660 g ai/ha or more, 680 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, or 900 g ai/ha or more; in an amount of 900 g ai/ha or less, such as 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 680 g ai/ha or less, 660 g ai/ha or less, 640 g ai/ha or less, 620 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 235 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 215 g ai/ha or less, 210 g ai/ha or less, 205 g ai/ha or less, 200 g ai/ha or less, 195 g ai/ha or less, 190 g ai/ha or less, 185 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 165 g ai/ha or less, 160 g ai/ha or less, 155 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 28 g ai/ha or less, 26 g ai/ha or less, 24 g ai/ha or less, 22 g ai/ha or less, 20 g ai/ha or less, 18 g ai/ha or less, 16 g ai/ha or less, 14 g ai/ha or less, 12 g ai/ha or less, 10 g ai/ha or less, 8 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or more, 4 g ai/ha or less, or 3 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2–900 g ai/ha, 3–500 g ai/ha, 5–270 g ai/ha, 10–600 g ai/ha, 22-440 g ai/ha, 35–560 g ai/ha, 10–400 g ai/ha, 20–700 g ai/ha, 40–280 g ai/ha, 60–680 g ai/ha, 100–750 g ai/ha, 90–300 g ai/ha, 200–700 g ai/ha, 300–500 g ai/ha, 3–100 g ai/ha, 5–90 g ai/ha, 12–105 g ai/ha, or 3–850 g ai/ha. Tepraloxydim Compositions and methods of the present disclosure can include tepraloxydim or an agriculturally acceptable salt or ester thereof. Tepraloxydim, shown below, is a cyclohexanedione herbicide that is used for broad-spectrum post-emergence grass weed control, especially Poa annua and volunteer maize, and also Sorghum halepense and Elymus repens, in broad-leaved crops. Tepraloxydim, as well as methods of preparing tepraloxydim, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Tepraloxydim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, tepraloxydim is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 25 g ai/ha or more, such as 27.5 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, or 195 g ai/ha or more; in an amount of 200 g ai/ha or less, such as 195 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, or 27.5 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 25–200 g ai/ha, 25–190 g ai/ha, 60–180 g ai/ha, 35–170 g ai/ha, 45–120 g ai/ha, 25–65 g ai/ha, 90–160 g ai/ha, 75–195 g ai/ha, 25–150 g ai/ha, 30–190 g ai/ha, 35–130 g ai/ha, 50–120 g ai/ha, 65–180 g ai/ha, or 27.5–195 g ai/ha. Tralkoxydim Compositions and methods of the present disclosure can include tralkoxydim or an agriculturally acceptable salt or ester thereof. Tralkoxydim is a cyclohexanedione herbicide that has the chemical name 2-[1-(ethoxyimino)propyl]-3-hydroxy-5-mesitylcyclohex-2-enon e, and has the following structure: Tralkoxydim is used for post-emergence control of annual grass weeds (including Avena spp., Lolium spp., Setaria viridis, Phalaria spp., Alopecurus myosuroides, and Apera spica-venti) in wheat and barley. Tralkoxydim, as well as methods of preparing tralkoxydim, are known in the art. Its herbicidal activity is described in The Pesticide Manual, Seventeenth Edition, 2016. Tralkoxydim can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 95 g ai/ha or more, such as 100 g ai/ha or more, 105 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 225 g ai/ha or more, 250 g ai/ha or more, 275 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, or 500 g ai/ha or more; in an amount of 501 g ai/ha or less, such as 500 g ai/ha or less, 475 g ai/ha or less, 450 g ai/ha or less, 425 g ai/ha or less, 400 g ai/ha or less, 375 g ai/ha or less, 350 g ai/ha or less, 325 g ai/ha or less, 300 g ai/ha or less, 275 g ai/ha or less, 250 g ai/ha or less, 225 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, or 100 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 95–501 g ai/ha., 100–475 g ai/ha, 120–450 g ai/ha, 110–425 g ai/ha, 225–400 g ai/ha, 150–425 g ai/ha, 180–375 g ai/ha, 190–350 g ai/ha, 110–225 g ai/ha, 180–500 g ai/ha, or 100–500 g ai/ha. VLCFA SYNTHESIS INHIBITOR HERBICIDES In addition to the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), the compositions include a very long chain fatty acid (VLCFA) synthesis inhibitor herbicide. Very long chain fatty acids have multiple functions in the plant, primarily serving as precursors of cuticle wax biosynthesis, and as components of storage lipids, sphingolipids and phospholipids. Examples of VLCFA synthesis inhibitors include, but are not limited to, acetochlor, alachlor, anilofos, butachlor, cafenstrole, dimethachlor, dimethenamid, diphenamid, fentrazamide, flufenacet, ipfencarbazone, mefenacet, metazachlor, metolachlor, naproanilide, napropamide, pethoxamid, piperophos, pretilachlor, propachlor, propisochlor, pyroxasulfone, and thenylchlor. In some aspects, the composition can include a VLCFA synthesis inhibitor herbicide selected from the group consisting of acetochlor, alachlor, anilofos, butachlor, cafenstrole, dimethachlor, dimethenamid, diphenamid, fentrazamide, flufenacet, ipfencarbazone, mefenacet, metazachlor, metolachlor, naproanilide, napropamide, pethoxamid, piperophos, pretilachlor, propachlor, propisochlor, pyroxasulfone, thenylchlor, agriculturally acceptable salts and esters thereof, and combinations thereof. The VLCFA synthesis inhibitor herbicide or agriculturally acceptable salt or ester thereof can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, the VLCFA synthesis inhibitor herbicide or agriculturally acceptable salt or ester thereof is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 40 gram active ingredient per hectare (g ai/ha) or more, such as 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, 2240 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2350 g ai/ha or more, 2400 g ai/ha or more, 2450 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2750 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3750 g ai/ha or more, 3800 g ai/ha or more, 3900 g ai/ha or more, 3950 g ai/ha or more, 4000 g ai/ha or more, 4100 g ai/ha or more, 4200 g ai/ha or more, 4250 g ai/ha or more, 4300 g ai/ha or more, 4400 g ai/ha or more, 4450 g ai/ha or more, 4500 g ai/ha or more, 4640 g ai/ha or more, 4780 g ai/ha or more, 4920 g ai/ha or more, 5060 g ai/ha or more, 5200 g ai/ha or more, 5340 g ai/ha or more, 5480 g ai/ha or more, 5620 g ai/ha or more, 5760 g ai/ha or more, 5900 g ai/ha or more, 6040 g ai/ha or more, 6180 g ai/ha or more, 6320 g ai/ha or more, 6460 g ai/ha or more, or 6600 g ai/ha or more; in an amount of 6720 g ai/ha or less, such as 6645 g ai/ha or less, 6575 g ai/ha or less, 6500 g ai/ha or less, 6425 g ai/ha or less, 6350 g ai/ha or less, 6275 g ai/ha or less, 6200 g ai/ha or less, 6125 g ai/ha or less, 6050 g ai/ha or less, 5975 g ai/ha or less, 5900 g ai/ha or less, 5825 g ai/ha or less, 5750 g ai/ha or less, 5675 g ai/ha or less, 5600 g ai/ha or less, 5525 g ai/ha or less, 5450 g ai/ha or less, 5375 g ai/ha or less, 5300 g ai/ha or less, 5225 g ai/ha or less, 5150 g ai/ha or less, 5075 g ai/ha or less, 5000 g ai/ha or less, 4925 g ai/ha or less, 4850 g ai/ha or less, 4775 g ai/ha or less, 4700 g ai/ha or less, 4625 g ai/ha or less, 4550 g ai/ha or less, 4475 g ai/ha or less, 4450 g ai/ha or less, 4400 g ai/ha or less, 4300 g ai/ha or less, 4250 g ai/ha or less, 4100 g ai/ha or less, 4000 g ai/ha or less, 3950 g ai/ha or less, 3900 g ai/ha or less, 3800 g ai/ha or less, 3750 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2750 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2450 g ai/ha or less, 2400 g ai/ha or less, 2350 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2240 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1240 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, or 45 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 40–6720 g ai/ha, 45–5825 g ai/ha, 60-2500 g ai/ha, 75–3100 g ai/ha, 90–900 g ai/ha, 55–4200 g ai/ha, 50–6050 g ai/ha, 80– 4700 g ai/ha, 120–4775 g ai/ha, 65–2100 g ai/ha, 300–4000 g ai/ha, 1200–3600 g ai/ha, 250– 5000 g ai/ha, 250–1000 g ai/ha, 700–4250 g ai/ha, 800–1400 g ai/ha, or 1000–6720 g ai/ha. In some aspects, the composition contains: compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof); and (b) acetochlor, alachlor, anilofos, butachlor, cafenstrole, dimethachlor, dimethenamid, diphenamid, fentrazamide, flufenacet, ipfencarbazone, mefenacet, metazachlor, metolachlor, naproanilide, napropamide, pethoxamid, piperophos, pretilachlor, propachlor, propisochlor, pyroxasulfone, thenylchlor, or combinations thereof. Acetochlor In some aspects, the VLCFA synthesis inhibitor herbicide can comprise acetochlor or an agriculturally acceptable salt or ester thereof. Acetochlor, shown below, is 2-chloro-N- (ethoxymethyl)-N-(2-ethyl-6-methylphenyl)acetamide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of acetochlor include its use pre-emergence or pre-plant to control annual grasses, certain annual broadleaf weeds and yellow nutsedge (Cyperus esculentus) in maize, peanuts, soybeans, cotton, potatoes and sugarcane. Acetochlor can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, acetochlor is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2500 g ai/ha or more, such as 2600 g ai/ha or more, 2700 g ai/ha or more, 2750 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3750 g ai/ha or more, 3800 g ai/ha or more, 3900 g ai/ha or more, 3950 g ai/ha or more, 4000 g ai/ha or more, 4100 g ai/ha or more, 4200 g ai/ha or more, 4250 g ai/ha or more, 4300 g ai/ha or more, 4400 g ai/ha or more, 4450 g ai/ha or more, 4500 g ai/ha or more, 4640 g ai/ha or more, 4780 g ai/ha or more, 4920 g ai/ha or more, 5060 g ai/ha or more, 5200 g ai/ha or more, 5340 g ai/ha or more, 5480 g ai/ha or more, 5620 g ai/ha or more, 5760 g ai/ha or more, 5900 g ai/ha or more, 6040 g ai/ha or more, 6180 g ai/ha or more, 6320 g ai/ha or more, 6460 g ai/ha or more, or 6600 g ai/ha or more; in an amount of 6720 g ai/ha or less, such as 6645 g ai/ha or less, 6575 g ai/ha or less, 6500 g ai/ha or less, 6425 g ai/ha or less, 6350 g ai/ha or less, 6275 g ai/ha or less, 6200 g ai/ha or less, 6125 g ai/ha or less, 6050 g ai/ha or less, 5975 g ai/ha or less, 5900 g ai/ha or less, 5825 g ai/ha or less, 5750 g ai/ha or less, 5675 g ai/ha or less, 5600 g ai/ha or less, 5525 g ai/ha or less, 5450 g ai/ha or less, 5375 g ai/ha or less, 5300 g ai/ha or less, 5225 g ai/ha or less, 5150 g ai/ha or less, 5075 g ai/ha or less, 5000 g ai/ha or less, 4925 g ai/ha or less, 4850 g ai/ha or less, 4775 g ai/ha or less, 4700 g ai/ha or less, 4625 g ai/ha or less, 4550 g ai/ha or less, 4475 g ai/ha or less, 4450 g ai/ha or less, 4400 g ai/ha or less, 4300 g ai/ha or less, 4250 g ai/ha or less, 4100 g ai/ha or less, 4000 g ai/ha or less, 3950 g ai/ha or less, 3900 g ai/ha or less, 3800 g ai/ha or less, 3750 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2750 g ai/ha or less, 2700 g ai/ha or less, or 2600 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2500–6720 g ai/ha, 3000–5825 g ai/ha, 2700-5525 g ai/ha, 2800–4100 g ai/ha, 4775–6200 g ai/ha, 5000–6645 g ai/ha, 5150–6645 g ai/ha, or 4000–6720 g ai/ha. Alachlor In some aspects, the VLCFA synthesis inhibitor herbicide can comprise alachlor or an agriculturally acceptable salt or ester thereof. Alachlor, show below, is 2-chloro-N-(2,6- diethylphenyl)-N-(methoxymethyl) acetamide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of alachlor include its use for pre-emergence control of annual grasses and many broadleaf weeds in cotton, brassicas, maize, oilseed rape, peanuts, radish, soybeans and sugar cane. Alachlor can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, alachlor is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1500 g ai/ha or more, such as 1550 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, 2240 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2350 g ai/ha or more, 2400 g ai/ha or more, 2450 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2750 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3750 g ai/ha or more, 3800 g ai/ha or more, 3900 g ai/ha or more, 3950 g ai/ha or more, 4000 g ai/ha or more, 4100 g ai/ha or more, 4200 g ai/ha or more, 4250 g ai/ha or more, 4300 g ai/ha or more, 4400 g ai/ha or more, or 4450 g ai/ha or more; in an amount of 4500 g ai/ha or less, such as 4475 g ai/ha or less, 4450 g ai/ha or less, 4400 g ai/ha or less, 4300 g ai/ha or less, 4250 g ai/ha or less, 4100 g ai/ha or less, 4000 g ai/ha or less, 3950 g ai/ha or less, 3900 g ai/ha or less, 3800 g ai/ha or less, 3750 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2750 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2450 g ai/ha or less, 2400 g ai/ha or less, 2350 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2240 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, or 1550 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1500-4500 g ai/ha, 1550–3900 g ai/ha, 2000-2500 g ai/ha, 2350–3700 g ai/ha, 3100–3900 g ai/ha, 2240–4200 g ai/ha, 2450–4300 g ai/ha, 3250–4475 g ai/ha, or 1900–4000 g ai/ha. Anilofos In some aspects, the VLCFA synthesis inhibitor herbicide can comprise anilofos or an agriculturally acceptable salt or ester thereof. Anilofos, shown below, is S-[2-[(4- chlorophenyl)(1-methylethyl)amino]-2-oxoethyl] O,O-dimethyl phosphorodithioate. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of anilofos include its use for control of annual grassy weeds and sedges in transplanted rice.
Anilofos can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, anilofos is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 250 g ai/ha or more, such as 260 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, or 1250 g ai/ha or more; in an amount of 1300 g ai/ha or less, such as 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, or 260 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 250–1300 g ai/ha, 260–1100 g ai/ha, 400–900 g ai/ha, 240–850 g ai/ha, 550–1000 g ai/ha, 400– 775 g ai/ha, 320–1200 g ai/ha, 360–800 g ai/ha, 500–725 g ai/ha, 675–925 g ai/ha, 480–850 g ai/ha, 450–1050 g ai/ha, or 260–1250 g ai/ha. Butachlor In some aspects, the VLCFA synthesis inhibitor herbicide can comprise butachlor or an agriculturally acceptable salt or ester thereof. Butachlor, shown below, is N- (butoxymethyl)-2-chloro-N-(2,6-diethylphenyl) acetamide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of butachlor include its use for pre-emergence control of annual grasses and certain broadleaf weeds in seeded and transplanted rice, barley, sugar beets, wheat, and brassicas. Butachlor thereof can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, butachlor is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 400 g ai/ha or more, such as 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, 2240 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2350 g ai/ha or more, 2400 g ai/ha or more, 2450 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2750 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3750 g ai/ha or more, 3800 g ai/ha or more, 3900 g ai/ha or more, 3950 g ai/ha or more, 4000 g ai/ha or more, 4100 g ai/ha or more, 4200 g ai/ha or more, 4250 g ai/ha or more, 4300 g ai/ha or more, 4400 g ai/ha or more, or 4450 g ai/ha or more; in an amount of 4500 g ai/ha or less, such as 4475 g ai/ha or less, 4450 g ai/ha or less, 4400 g ai/ha or less, 4300 g ai/ha or less, 4250 g ai/ha or less, 4100 g ai/ha or less, 4000 g ai/ha or less, 3950 g ai/ha or less, 3900 g ai/ha or less, 3800 g ai/ha or less, 3750 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2750 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2450 g ai/ha or less, 2400 g ai/ha or less, 2350 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2240 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1240 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 740 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, or 450 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 400- 4500 g ai/ha, 750–1800 g ai/ha, 1200-2900 g ai/ha, 1500–3100 g ai/ha, 2350–3900 g ai/ha, 500–1250 g ai/ha, 2000–3600 g ai/ha, 2750–4000 g ai/ha, or 450–4475 g ai/ha. Cafenstrole In some aspects, the VLCFA synthesis inhibitor herbicide can comprise cafenstrole or an agriculturally acceptable salt or ester thereof. Cafenstrole, shown below, is N,N-diethyl- 3-[(2,4,6-trimethylphenyl)sulfonyl]-1H-1,2,4-triazole-1-carb oxamide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of cafenstrole include its use for pre- and post-emergence control of Echinochloa oryzicola, Cyperus difformis and other weeds in paddy rice. Cafenstrole can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, cafenstrole is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 60 g ai/ha or more, 75 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, or 380 g ai/ha or more; in an amount of 400 g ai/ha or less, such as 380 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 75 g ai/ha or less, or 60 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50-400 g ai/ha, 120–380 g ai/ha, 90-260 g ai/ha, 130–300 g ai/ha, 250–360 g ai/ha, or 110–400 g ai/ha. Dimethachlor In some aspects, the VLCFA synthesis inhibitor herbicide can comprise dimethachlor or an agriculturally acceptable salt or ester thereof. Dimethachlor, shown below, is 2-chloro-N-(2,6-dimethylphenyl)-N-(2-methoxyethyl)acetamide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of dimethachlor include its use for pre-emergence control of most annual grass (Alopecurus myosuroides, Apera spica-venti and Poa annua) and broadleaf weeds in oilseed rape. Dimethachlor can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, dimethachlor is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1250 g ai/ha or more, such as 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, or 1950 g ai/ha or more; in an amount of 2000 g ai/ha or less, such as 1950 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, or 1300 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1250–2000 g ai/ha, 1400–1950 g ai/ha, 1300–1900 g ai/ha, 1250–1500 g ai/ha, 1600–1950 g ai/ha, 1700–2000 g ai/ha, or 1500–1750 g ai/ha. Dimethenamid In some aspects, the VLCFA synthesis inhibitor herbicide can comprise dimethenamid or an agriculturally acceptable salt or ester thereof. Dimethenamid, shown below, is (RS)-2-chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-meth ylethyl) acetamide. Herbicidal activity for dimethenamid is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of dimethenamid include its use for pre- or early post- emergence control of annual grass and broadleaf weeds in maize, soybeans, sugar beet, potatoes, dry beans and other crops. Dimethenamid-P, (S)-2-chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1- methyl-ethyl)acetamide, is a herbicidally active enantiomer of dimethenamid. Dimethenamid can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, dimethenamid is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 400 g ai/ha or more, such as 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1440 g ai/ha or more, or 1450 g ai/ha or more; in an amount of 1500 g ai/ha or less, such as 1450 g ai/ha or less, 1440 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1240 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, or 450 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 400-1500 g ai/ha, 550–1350 g ai/ha, 450–900 g ai/ha, 700–1400 g ai/ha, 1200–1440 g ai/ha, 650–1500 g ai/ha, 1050–1250 g ai/ha, 800–1350 g ai/ha, or 450–1450 g ai/ha. Diphenamid In some aspects, the VLCFA synthesis inhibitor herbicide can comprise diphenamid or an agriculturally acceptable salt or ester thereof. Diphenamid, shown below, is N,N- dimethyl-α-phenylbenzeneacetamide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of diphenamid include its use for pre- emergence control of annual grasses and broadleaf weeds in a wide range of crops, including cotton, potatoes, sweet potatoes, tomatoes, vegetables, capsicums, okra, soybeans, peanuts, tobacco, orchard fruit, bush fruit, strawberries, forestry nurseries, and ornamental plants, shrubs and trees. Diphenamid can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, diphenamid is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 3500 g ai/ha or more, such as 3600 g ai/ha or more, 3700 g ai/ha or more, 3750 g ai/ha or more, 3800 g ai/ha or more, 3900 g ai/ha or more, 3950 g ai/ha or more, 4000 g ai/ha or more, 4100 g ai/ha or more, 4200 g ai/ha or more, 4250 g ai/ha or more, 4300 g ai/ha or more, 4400 g ai/ha or more, 4500 g ai/ha or more, 4600 g ai/ha or more, 4700 g ai/ha or more, 4750 g ai/ha or more, 4800 g ai/ha or more,4900 g ai/ha or more, 5000 g ai/ha or more, 5100 g ai/ha or more, 5200 g ai/ha or more, 5250 g ai/ha or more, 5300 g ai/ha or more, 5400 g ai/ha or more, 5500 g ai/ha or more, 5600 g ai/ha or more, 5700 g ai/ha or more,5750 g ai/ha or more, 5800 g ai/ha or more, 5900 g ai/ha or more, or 5950 g ai/ha or more; in an amount of 6000 g ai/ha or less, such as 5950 g ai/ha or less, 5900 g ai/ha or less, 5800 g ai/ha or less, 5750 g ai/ha or less, 5700 g ai/ha or less, 5600 g ai/ha or less, 5500 g ai/ha or less, 5400 g ai/ha or less, 5300 g ai/ha or less, 5250 g ai/ha or less, 5200 g ai/ha or less, 5100 g ai/ha or less, 5000 g ai/ha or less, 4900 g ai/ha or less, 4800 g ai/ha or less, 4750 g ai/ha or less, 4700 g ai/ha or less, 4600 g ai/ha or less, 4500 g ai/ha or less, 4400 g ai/ha or less, 4300 g ai/ha or less, 4250 g ai/ha or less, 4200 g ai/ha or less, 4100 g ai/ha or less, 4000 g ai/ha or less, 3950 g ai/ha or less, 3900 g ai/ha or less, 3800 g ai/ha or less, 3750 g ai/ha or less, 3700 g ai/ha or less, or 3600 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 3500-6000 g ai/ha, 4100–5800 g ai/ha, 3750-5500 g ai/ha, 5000–6000 g ai/ha, 5250–5950 g ai/ha, 3600–4750 g ai/ha, 3700– 4250 g ai/ha, 4800–5400 g ai/ha, or 3900–5900 g ai/ha. Fenoxasulfone In some aspects, the VLCFA synthesis inhibitor herbicide can comprise fenoxasulfone or an agriculturally acceptable salt or ester thereof. Fenoxasulfone, shown below, is 2,5-dichloro-4-ethoxybenzyl-4,5-dihydro-5,5-dimethyl-1,2-oxa zol-3-yl sulfone. Its herbicidal use is reported in the online version of The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of fenoxasulfone include control of grass and broadleaf weeds in rice. Fentrazamide In some aspects, the VLCFA synthesis inhibitor herbicide can comprise fentrazamide or an agriculturally acceptable salt or ester thereof. Fentrazamide, shown below, is 4-(2-chlorophenyl)-N-cyclohexyl-N-ethyl-4,5-dihydro-5-oxo-1H -tetrazole-1-carboxamide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of fentrazamide include its use for pre-and early post-emergence control of barnyard grass (Echinochloa spp.) and annual sedges in rice. Flufenacet In some aspects, the VLCFA synthesis inhibitor herbicide can comprise flufenacet or an agriculturally acceptable salt or ester thereof. Flufenacet, shown below, is N-(4- fluorophenyl)-N-(1-methylethyl)-2-[[5-(trifluoromethyl)-1,3, 4-thiadiazol-2-yl]oxy]acetamide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of flufenacet include its use for control of grass and broadleaf weeds in maize, wheat, rice, soybeans, tomatoes, potatoes, and sunflowers. Flufenacet can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, flufenacet is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 40 g ai/ha or more, such as 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 120 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more,160 g ai/ha or more, 180 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 345 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 880 g ai/ha or more, or 890 g ai/ha or more; in an amount of 900 g ai/ha or less, such as 890 g ai/ha or less, 880 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 180 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 120 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, or 42.5 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 40–900 g ai/ha, 45–600 g ai/ha, 60–900 g ai/ha, 140–850 g ai/ha, 250–620 g ai/ha, 400–780 g ai/ha, 220–640 g ai/ha, 360–800 g ai/ha, 300–725 g ai/ha, 90–825 g ai/ha, 140–550 g ai/ha, 450–650 g ai/ha, or 50–880 g ai/ha. Indanofan In some aspects, the VLCFA synthesis inhibitor herbicide can comprise indanofan or an agriculturally acceptable salt or ester thereof. Indanofan, shown below, is (RS)-2-[2-(3- chlorophenyl)-2,3-epoxypropyl]-2-ethylindan-1,3-dione. Its herbicidal activity is exemplified in the online edition of The Pesticide Manual. Exemplary uses of indanofan include pre- and post-emergence control of Echinochloa crus-galli, Monochoria vaginalis, Lindernia procumbens, Cyperus difformis, Scirpus juncoides, and Eleocharis acicularis in transplanted rice. Ipfencarbazone In some aspects, the VLCFA synthesis inhibitor herbicide can comprise ipfencarbazone or an agriculturally acceptable salt or ester thereof. Ipfencarbazone, shown below, is 1-(2,4-dichlorophenyl)-N-(2,4-difluorophenyl)-1,5-dihydro-N- (1-methylethyl)-5- oxo-4H-1,2,4-triazole-4-carboxamide. Its herbicidal activity is exemplified in the online edition of The Pesticide Manual. Exemplary uses of ipfencarbazone include its use for pre- or early post-emergence control of grass, sedge, and some broadleaf weeds in rice. Ipfencarbazone can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, ipfencarbazone is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 150 g ai/ha or more, such as 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, or 390 g ai/ha or more; in an amount of 400 g ai/ha or less, such as 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less,190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less,170 g ai/ha or less, or 160 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 150-400 g ai/ha, 175–380 g ai/ha, 210-275 g ai/ha, 225–310 g ai/ha, 300–390 g ai/ha, 280– 400 g ai/ha, 200–350 g ai/ha, 160–325 g ai/ha, 250–300 g ai/ha, or 180–360 g ai/ha. Mefenacet In some aspects, the VLCFA synthesis inhibitor herbicide can comprise mefenacet or an agriculturally acceptable salt or ester thereof. Mefenacet, shown below, is 2-(2- benzothiazolyloxy)-N-methyl-N-phenylacetamide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of mefenacet include its use for pre-emergence and early post-emergence control of grass weeds in transplanted rice. Mefenacet can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, mefenacet is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 40 g ai/ha or more, such as 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 250 g ai/ha or more, 300 g ai/ha or more, 350 g ai/ha or more, 400 g ai/ha or more, 450 g ai/ha or more, 500 g ai/ha or more, 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, or 1700 g ai/ha or more; in an amount of 1750 g ai/ha or less such as 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1240 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, 550 g ai/ha or less, 500 g ai/ha or less, 450 g ai/ha or less, 400 g ai/ha or less, 350 g ai/ha or less, 300 g ai/ha or less, 250 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, or 50 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 40-1750 g ai/ha, 150–1700 g ai/ha, 300-1500 g ai/ha, 850–1600 g ai/ha, 450–1240 g ai/ha, 1100–1400 g ai/ha, 800–1400 g ai/ha, or 1000–1750 g ai/ha. Metazachlor In some aspects, the VLCFA synthesis inhibitor herbicide can comprise metazachlor or an agriculturally acceptable salt or ester thereof. Metazachlor, shown below, is 2-chloro-N-(2,6-dimethylphenyl)-N-(1H-pyrazol-1-ylmethyl)ace tamide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of metazachlor include its use for pre- and early post-emergence control of winter and annual grasses and broadleaf weeds in a variety of vegetable, fruit, grain, and orchard crops. Metazachlor can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, metazachlor is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 750 g ai/ha or more, such as 775 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1440 g ai/ha or more, or 1450 g ai/ha or more; in an amount of 1500 g ai/ha or less, such as 1450 g ai/ha or less, 1440 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1240 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, or 775 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 750-1500 g ai/ha, 850–1350 g ai/ha, 800–900 g ai/ha, 950–1400 g ai/ha, 1200–1440 g ai/ha, 1250–1500 g ai/ha, 1050–1250 g ai/ha, 800–1350 g ai/ha, or 1000–1450 g ai/ha. Metolachlor In some aspects, the VLCFA synthesis inhibitor herbicide can comprise metolachlor or an agriculturally acceptable salt or ester thereof. Metolachlor, shown below, is 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methyleth yl)acetamide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of metolachlor include its use for control of annual grasses and broadleaf weeds in maize, sorghum, cotton, sugar beet, fodder beet, sugarcane, potatoes, peanuts, soybeans, safflowers, sunflowers, various vegetables, fruit and nut trees, and woody ornamentals. S-metolachlor is a mixture of isomers, containing of 80-200% (S) to 20-0% (R) isomers of metolachlor. Metolachlor can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, metolachlor is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 500 g ai/ha or more, such as 550 g ai/ha or more, 600 g ai/ha or more, 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, 2240 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2350 g ai/ha or more, 2400 g ai/ha or more, 2450 g ai/ha or more, 2500 g ai/ha or more, or 2550 g ai/ha or more; in an amount of 2600 g ai/ha or less, such as 2550 g ai/ha or less, 2500 g ai/ha or less, 2450 g ai/ha or less, 2400 g ai/ha or less, 2350 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2240 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, 2050 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1240 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 650 g ai/ha or less, 600 g ai/ha or less, or 550 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 500-2600 g ai/ha, 1500–2450 g ai/ha, 1240-2500 g ai/ha, 750–2000 g ai/ha, 1300–1900 g ai/ha, 800–1450 g ai/ha, 2000–2500 g ai/ha, 650–1600 g ai/ha, or 550–2550 g ai/ha. Naproanilide In some aspects, the VLCFA synthesis inhibitor herbicide can comprise naproanilide or an agriculturally acceptable salt or ester thereof. Naproanilide, shown below, is 2-(2-naphthalenyloxy)-N-phenyl propanamide. Its herbicidal activity is exemplified in the online edition of The Pesticide Manual. Exemplary uses of naproanilide include its use for control of annual and some perennial weeds, but not Echinochloa crus-galli, in paddy rice, as well as good control of young Sagittaria pygmaea. Naproanilide can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, naproanilide is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2000 g ai/ha or more, such as 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, 2240 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2350 g ai/ha or more, 2400 g ai/ha or more, 2450 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2750 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, or 2950 g ai/ha or more; in an amount of 3000 g ai/ha or less, such as 2950 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2750 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2450 g ai/ha or less, 2400 g ai/ha or less, 2350 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2240 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, or 2050 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2000-3000 g ai/ha, 2150–2750 g ai/ha, 2200-2500 g ai/ha, 2500–3000 g ai/ha, 2050–2600 g ai/ha, 2600–2950 g ai/ha, 2750–3000 g ai/ha, or 2240–2800 g ai/ha. Napropamide In some aspects, the VLCFA synthesis inhibitor herbicide can comprise napropamide or an agriculturally acceptable salt or ester thereof. Napropamide, shown below, is (RS)-N,N-diethyl-2-(1-naphthyloxy) propionamide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of napropamide include its use for pre-emergence control of annual grasses and broadleaf weeds in asparagus, rhubarb, cucurbits, brassicas, oilseed rape, tomatoes, capsicums, potatoes, peas, nuts, fruit trees and bushes (including citrus), vines, strawberries, sunflowers, safflowers, ornamentals, tobacco, olives, figs, mint, turf, and other crops. Napropamide can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, napropamide is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2000 g ai/ha or more, such as 2050 g ai/ha or more, 2100 g ai/ha or more, 2150 g ai/ha or more, 2200 g ai/ha or more, 2240 g ai/ha or more, 2250 g ai/ha or more, 2300 g ai/ha or more, 2350 g ai/ha or more, 2400 g ai/ha or more, 2450 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2750 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3750 g ai/ha or more, 3800 g ai/ha or more, 3900 g ai/ha or more, 3950 g ai/ha or more, 4000 g ai/ha or more, 4100 g ai/ha or more, 4200 g ai/ha or more, 4250 g ai/ha or more, 4300 g ai/ha or more, 4400 g ai/ha or more, 4450 g ai/ha or more, 4500 g ai/ha or more, 4640 g ai/ha or more, 4780 g ai/ha or more, 4920 g ai/ha or more, 5060 g ai/ha or more, 5200 g ai/ha or more, 5340 g ai/ha or more, 5480 g ai/ha or more, 5620 g ai/ha or more, 5760 g ai/ha or more, 5825 g ai/ha or more, or 5900 g ai/ha or more; in an amount of 6000 g ai/ha or less, such as 5900 g ai/ha or less, 5825 g ai/ha or less, 5750 g ai/ha or less, 5675 g ai/ha or less, 5600 g ai/ha or less, 5525 g ai/ha or less, 5450 g ai/ha or less, 5375 g ai/ha or less, 5300 g ai/ha or less, 5225 g ai/ha or less, 5150 g ai/ha or less, 5075 g ai/ha or less, 5000 g ai/ha or less, 4925 g ai/ha or less, 4850 g ai/ha or less, 4775 g ai/ha or less, 4700 g ai/ha or less, 4625 g ai/ha or less, 4550 g ai/ha or less, 4475 g ai/ha or less, 4450 g ai/ha or less, 4400 g ai/ha or less, 4300 g ai/ha or less, 4250 g ai/ha or less, 4100 g ai/ha or less, 4000 g ai/ha or less, 3950 g ai/ha or less, 3900 g ai/ha or less, 3800 g ai/ha or less, 3750 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2750 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2450 g ai/ha or less, 2400 g ai/ha or less, 2350 g ai/ha or less, 2300 g ai/ha or less, 2250 g ai/ha or less, 2240 g ai/ha or less, 2200 g ai/ha or less, 2150 g ai/ha or less, 2100 g ai/ha or less, or 2050 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2000-6000 g ai/ha, 2150–5825 g ai/ha, 2800-5600 g ai/ha, 2350–3700 g ai/ha, 3250–5900 g ai/ha, 2400– 4250 g ai/ha, 2500–5675 g ai/ha, 2700–4925 g ai/ha, or 2050–5525 g ai/ha. Pethoxamid In some aspects, the VLCFA synthesis inhibitor herbicide can comprise pethoxamid or an agriculturally acceptable salt or ester thereof. Pethoxamid is 2-chloro-N-(2-ethoxyethyl)- N-(2-methyl-1-phenyl-1-propen-1-yl)acetamide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of pethoxamid include its use for pre- and early post-emergence control of grass weeds and broadleaf weeds in maize, oilseed rape and soybeans. Pethoxamid can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pethoxamid is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 600 g ai/ha or more, such as 650 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, or 1475 g ai/ha or more; in an amount of 1500 g ai/ha or less, such as 1475 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1240 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, or 650 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 600-1500 g ai/ha, 900-1400 g ai/ha, 1250–1450 g ai/ha, 800–1200 g ai/ha, 1350–1500 g ai/ha, 1000-1240 g ai/ha, or 650–1475 g ai/ha. Piperophos In some aspects, the VLCFA synthesis inhibitor herbicide can comprise piperophos or an agriculturally acceptable salt or ester thereof. Piperophos, shown below, is S-[2-(2- methyl-1-piperidinyl)-2-oxoethyl] O,O-dipropylphosphorodithioate. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of piperophos include its use as a selective herbicide active against annual grasses and sedges in direct seeded or transplanted rice. Piperophos can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, piperophos is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 300 g ai/ha or more, such as 310 g ai/ha or more, 320 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more,550 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 620 g ai/ha or more, 640 g ai/ha or more, 650 g ai/ha or more, 660 g ai/ha or more, 680 g ai/ha or more, 700 g ai/ha or more, 720 g ai/ha or more, or 740 g ai/ha or more; in an amount of 750 g ai/ha or less, such as 740 g ai/ha or less, 720 g ai/ha or less, 700 g ai/ha or less, 680 g ai/ha or less, 660 g ai/ha or less, 650 g ai/ha or less, 640 g ai/ha or less, 620 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 550 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 320 g ai/ha or less, or 310 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 300-750 g ai/ha, 320–580 g ai/ha, 330-660 g ai/ha, 410–650 g ai/ha, 340–700 g ai/ha, 450–520 g ai/ha, 500–750 g ai/ha, 400–600 g ai/ha, 350–720 g ai/ha, or 420-740 g ai/ha. Pretilachlor In some aspects, the VLCFA synthesis inhibitor herbicide can comprise pretilachlor or an agriculturally acceptable salt or ester thereof. Pretilachlor, shown below, is 2-chloro-N- (2,6-diethylphenyl)-N-(2-propoxyethyl)acetamide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of pretilachlor include its use for control of annual grasses, broadleaf weeds and sedges in transplanted and seeded rice. Pretilachlor can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pretilachlor is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 250 g ai/ha or more, such as 260 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 325 g ai/ha or more, 350 g ai/ha or more, 375 g ai/ha or more, 400 g ai/ha or more, 425 g ai/ha or more, 450 g ai/ha or more, 475 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 725 g ai/ha or more, 750 g ai/ha or more, 775 g ai/ha or more, 800 g ai/ha or more, 825 g ai/ha or more, 850 g ai/ha or more, 875 g ai/ha or more, 900 g ai/ha or more, 925 g ai/ha or more, 950 g ai/ha or more, 975 g ai/ha or more, 1000 g ai/ha or more, 1025 g ai/ha or more,1050 g ai/ha or more, 1075 g ai/ha or more,1100 g ai/ha or more, 1125 g ai/ha or more,1150 g ai/ha or more, 1175 g ai/ha or more,1200 g ai/ha or more, 1225 g ai/ha or more, 1250 g ai/ha or more, 1275 g ai/ha or more,1300 g ai/ha or more, or 1325 g ai/ha or more; in an amount of 1350 g ai/ha or less, such as 1325 g ai/ha or less, 1300 g ai/ha or less, 1275 g ai/ha or less, 1250 g ai/ha or less, 1225 g ai/ha or less,1200 g ai/ha or less, 1175 g ai/ha or less,1150 g ai/ha or less, 1125 g ai/ha or less, 1100 g ai/ha or less, 1075 g ai/ha or less,1050 g ai/ha or less, 1025 g ai/ha or less, 1000 g ai/ha or less, 975 g ai/ha or less, 950 g ai/ha or less, 925 g ai/ha or less, 900 g ai/ha or less, 875 g ai/ha or less, 850 g ai/ha or less, 825 g ai/ha or less, 800 g ai/ha or less, 775 g ai/ha or less, 750 g ai/ha or less, 725 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, or 260 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 250-1350 g ai/ha, 1025–1325 g ai/ha, 500-1250 g ai/ha, 440–850 g ai/ha, 1000–1300 g ai/ha, 300–1100 g ai/ha, or 260–1325 g ai/ha. Propachlor In some aspects, the VLCFA synthesis inhibitor herbicide can comprise propachlor or an agriculturally acceptable salt or ester thereof. Propachlor, shown below, is 2-chloro-N- (1-methylethyl)-N-phenylacetamide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. It is used pre-emergence, pre-planting incorporated or early post-emergence control of annual grasses and some broadleaf weeds in beans, brassicas, cotton, sorghum, peanuts, leeks, maize, onions, peas, roses, ornamental trees and shrubs, soybeans and sugar cane. Propachlor can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, propachlor is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 3250 g ai/ha or more, such as 3300 g ai/ha or more, 3360 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3600 g ai/ha or more, 3700 g ai/ha or more, 3750 g ai/ha or more, 3800 g ai/ha or more, 3900 g ai/ha or more, 3950 g ai/ha or more, 4000 g ai/ha or more, 4100 g ai/ha or more, 4200 g ai/ha or more, 4250 g ai/ha or more, 4300 g ai/ha or more, 4400 g ai/ha or more, 4450 g ai/ha or more, 4500 g ai/ha or more, 4640 g ai/ha or more, 4780 g ai/ha or more, 4920 g ai/ha or more, 5060 g ai/ha or more, 5200 g ai/ha or more, 5340 g ai/ha or more, 5480 g ai/ha or more, 5620 g ai/ha or more, 5760 g ai/ha or more, 5900 g ai/ha or more, 6040 g ai/ha or more, 6180 g ai/ha or more, 6320 g ai/ha or more, 6460 g ai/ha or more, 6600 g ai/ha or more, or 6700 g ai/ha or more; in an amount of 6720 g ai/ha or less, such as 6700 g ai/ha or less, 6645 g ai/ha or less, 6600 g ai/ha or less, 6575 g ai/ha or less, 6500 g ai/ha or less, 6425 g ai/ha or less, 6350 g ai/ha or less, 6275 g ai/ha or less, 6200 g ai/ha or less, 6125 g ai/ha or less, 6050 g ai/ha or less, 5975 g ai/ha or less, 5900 g ai/ha or less, 5825 g ai/ha or less, 5750 g ai/ha or less, 5675 g ai/ha or less, 5600 g ai/ha or less, 5525 g ai/ha or less, 5450 g ai/ha or less, 5375 g ai/ha or less, 5300 g ai/ha or less, 5225 g ai/ha or less, 5150 g ai/ha or less, 5075 g ai/ha or less, 5000 g ai/ha or less, 4925 g ai/ha or less, 4850 g ai/ha or less, 4775 g ai/ha or less, 4700 g ai/ha or less, 4625 g ai/ha or less, 4550 g ai/ha or less, 4475 g ai/ha or less, 4450 g ai/ha or less, 4400 g ai/ha or less, 4300 g ai/ha or less, 4250 g ai/ha or less, 4100 g ai/ha or less, 4000 g ai/ha or less, 3950 g ai/ha or less, 3900 g ai/ha or less, 3800 g ai/ha or less, 3750 g ai/ha or less, 3700 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3360 g ai/ha or less, or 3300 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 3250-6720 g ai/ha, 3500–5825 g ai/ha, 4250–6645 g ai/ha, 3950–6050 g ai/ha, 3300–4700 g ai/ha, 4100–6425 g ai/ha, or 3360–6720 g ai/ha. Propisochlor In some aspects, the VLCFA synthesis inhibitor herbicide can comprise propisochlor or an agriculturally acceptable salt or ester thereof. Propisochlor, shown below, is 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(isopropoxymethyl)acet amide. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of propisochlor include its use in pre-plant or pre-emergence control of annual grass and some broadleaf weeds in maize, sunflowers, soybeans, potatoes, beans, sweet lupins, peas, and onions. Propisochlor can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, propisochlor is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 900 g ai/ha or more, such as 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1550 g ai/ha or more, 1600 g ai/ha or more, 1650 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more, 1800 g ai/ha or more, 1850 g ai/ha or more, 1900 g ai/ha or more, or 1950 g ai/ha or more; in an amount of 2000 g ai/ha or less, such as 1950 g ai/ha or less, 1900 g ai/ha or less, 1850 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1650 g ai/ha or less, 1600 g ai/ha or less, 1550 g ai/ha or less,1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, or 950 g ai/ha or less; in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 900-2000 g ai/ha, 1050–1750 g ai/ha, 1200-1500 g ai/ha, 1400–1700 g ai/ha, 1100–1800 g ai/ha, 1600–1950 g ai/ha, 1350–1850 g ai/ha, 900–1550 g ai/ha, or 1000–1900 g ai/ha. Pyroxasulfone In some aspects, the VLCFA synthesis inhibitor herbicide can comprise pyroxasulfone or an agriculturally acceptable salt or ester thereof. Pyroxasulfone, shown below, is 3-[[[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)-1H-pyr azol-4- yl]methyl]sulfonyl]-4,5-dihydro-5,5-dimethylisoxazole. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Pyroxasulfone provides pre- and early post-emergence control of annual grasses and some broadleaf weeds in maize, soybeans, wheat, triticale, barley, and other crops. The pyroxasulfone can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, the pyroxasulfone is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 40 g ai/ha or more, such as 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 105 g ai/ha or more, 110 g ai/ha or more, 115 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 135 g ai/ha or more, 140 g ai/ha or more, 145 g ai/ha or more, 150 g ai/ha or more, 155 g ai/ha or more, 160 g ai/ha or more, 165 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 185 g ai/ha or more, 190 g ai/ha or more, 195 g ai/ha or more, 200 g ai/ha or more, 205 g ai/ha or more, 210 g ai/ha or more, 215 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, or 235 g ai/ha or more; in an amount of 240 g ai/ha or less, such as 235 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 215 g ai/ha or less, 210 g ai/ha or less, 205 g ai/ha or less, 200 g ai/ha or less, 195 g ai/ha or less, 190 g ai/ha or less, 185 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 165 g ai/ha or less, 160 g ai/ha or less, 155 g ai/ha or less, 150 g ai/ha or less, 145 g ai/ha or less, 140 g ai/ha or less, 135 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 115 g ai/ha or less, 110 g ai/ha or less, 105 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, or 45 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 40–240 g ai/ha, 40–230 g ai/ha, 40–220 g ai/ha, 40–210 g ai/ha, 40– 200 g ai/ha, 50–240 g ai/ha, 50–230 g ai/ha, 50–220 g ai/ha, 50–210 g ai/ha, 50–200 g ai/ha, 60–240 g ai/ha, 60–230 g ai/ha, 60–220 g ai/ha, 60–210 g ai/ha, or 60–200 g ai/ha. Thenylchlor In some aspects, the VLCFA synthesis inhibitor herbicide can comprise thenylchlor or an agriculturally acceptable salt or ester thereof. Thenylchlor, shown below, is 2-chloro-N- (2,6-dimethylphenyl)-N-[(3-methoxy-2-thienyl)methyl]acetamid e. Its herbicidal activity is exemplified in The Pesticide Manual, Seventeenth Edition, 2016. Exemplary uses of thenylchlor include its use for pre-emergence control of annual grass and broadleaf weeds in paddy rice. Thenylchlor can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, thenylchlor is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 225 g ai/ha or more, such as 230 g ai/ha or more, 235 g ai/ha or more, 240 g ai/ha or more, 245 g ai/ha or more, 250 g ai/ha or more, 255 g ai/ha or more, 260 g ai/ha or more, 265 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 285 g ai/ha or more, 290 g ai/ha or more, 295 g ai/ha or more, 300 g ai/ha or more, 305 g ai/ha or more, 310 g ai/ha or more, 315 g ai/ha or more, or 320 g ai/ha or more; in an amount of 325 g ai/ha or less, such as 320 g ai/ha or less, 315 g ai/ha or less, 310 g ai/ha or less, 305 g ai/ha or less, 300 g ai/ha or less, 295 g ai/ha or less, 290 g ai/ha or less, 285 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 265 g ai/ha or less, 260 g ai/ha or less, 255 g ai/ha or less, 250 g ai/ha or less, 245 g ai/ha or less, 240 g ai/ha or less, 235 g ai/ha or less, or 230 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 225-325 g ai/ha, 240-295 g ai/ha, 265–310 g ai/ha, 300–320 g ai/ha, 270–315 g ai/ha, 250–305 g ai/ha, 235–300 g ai/ha, or 230–270 g ai/ha. MICROTUBULE ASSEMBLY INHIBITOR (MAI) HERBICIDES In addition to the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), the compositions can include a microtubule assembly inhibitor (MAI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. MAI herbicides may inhibit plant cell division by binding to tubulin, the major protein needed to form the microtubules required in cell division. Examples of MAI herbicides include benfluralin, butamifos, butralin, carbetamide, chlorpropham, chlorthal, dithiopyr, ethalfluralin, oryzalin, pendimethalin, prodiamine, propham, propyzamide, thiazopyr, trifluralin, and agriculturally acceptable salts or esters thereof. MAI herbicides can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, the MAI herbicide is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 100 g ai/ha or more, such as 105 g ai/ha or more, 110 g ai/ha or more, 115 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 135 g ai/ha or more, 140 g ai/ha or more, 145 g ai/ha or more, 150 g ai/ha or more, 155 g ai/ha or more, 160 g ai/ha or more, 165 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 500 g ai/ha or more, 600 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 900 g ai/ha or more, 1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3750 g ai/ha or more, 4000 g ai/ha or more, 4250 g ai/ha or more, 4500 g ai/ha or more, 4750 g ai/ha or more, 5000 g ai/ha or more, 5250 g ai/ha or more, 5500 g ai/ha or more, 5750 g ai/ha or more, 6000 g ai/ha or more, 6250 g ai/ha or more, 6500 g ai/ha or more, 6750 g ai/ha or more, 7000 g ai/ha or more, 7250 g ai/ha or more, 7500 g ai/ha or more, 7750 g ai/ha or more, 8000 g ai/ha or more, 8250 g ai/ha or more, 8500 g ai/ha or more, 8750 g ai/ha or more, 9000 g ai/ha or more, 9250 g ai/ha or more, 9500 g ai/ha or more, 9750 g ai/ha or more, 10 kg ai/ha or more, 10.5 kg ai/ha or more, 11 kg ai/ha or more, 11.5 kg ai/ha or more, 12k g ai/ha or more, 12.5 kg ai/ha or more, 13 kg ai/ha or more, 13.5 kg ai/ha or more, 14 kg ai/ha or more, 14.5 kg ai/ha or more, 15 kg ai/ha or more, 15.5 kg ai/ha or more, 16 kg ai/ha or more, 16.5 kg ai/ha or more, or 16.75 kg ai/ha or more; in an amount of 17 kg ai/ha or less, such as 16.75 kg ai/ha or less, 16.5 kg ai/ha or less, 16 kg ai/ha or less, 15.5 kg ai/ha or less, 15 kg ai/ha or less, 14.5k g ai/ha or less, 14 kg ai/ha or less, 13.5 kg ai/ha or less, 13 kg ai/ha or less, 12.5 kg ai/ha or less, 12 kg ai/ha or less, 11.5 kg ai/ha or less, 11 kg ai/ha or less, 10.5 kg ai/ha, 10 kg ai/ha or less, 9750 g ai/ha or less, 9500 g ai/ha or less, 9250 g ai/ha or less, 9000 g ai/ha or less, 8750 g ai/ha or less, 8500 g ai/ha or less, 8250 g ai/ha or less, 8000 g ai/ha or less, 7750 g ai/ha or less, 7500 g ai/ha or less, 7250 g ai/ha or less, 7000 g ai/ha or less, 6750 g ai/ha or less, 6500 g ai/ha or less, 6250 g ai/ha or less, 6000 g ai/ha or less, 5750 g ai/ha or less, 5500 g ai/ha or less, 5250 g ai/ha or less, 5000 g ai/ha or less, 4750 g ai/ha or less, 4500 g ai/ha or less, 4250 g ai/ha or less, 4000 g ai/ha or less, 3750 g ai/ha or less, 3600 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 900 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 600 g ai/ha or less, 500 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 165 g ai/ha or less, 160 g ai/ha or less, 155 g ai/ha or less, 150 g ai/ha or less, 145 g ai/ha or less, 140 g ai/ha or less, 135 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 115 g ai/ha or less, 110 g ai/ha or less, or 105 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, e.g., 100 g –17 kg ai/ha, 350–1800 g ai/ha, 160–3750 g ai/ha, 225–2500 g ai/ha, 7.5–12.5 kg ai/ha, 115–350 g ai/ha, 3400–6750 g ai/ha, 185–8000 g ai/ha, 390–3100 g ai/ha, 2000–4250 g ai/ha, 1200–3300 g ai/ha, or 105 g–16.75 kg ai/ha. Benfluralin In some aspects, the MAI herbicide can comprise benfluralin or an agriculturally acceptable salt or ester thereof. Benfluralin, shown below, is a dinitroaniline herbicide used for pre-plant incorporated control of annual grass and some annual broad-leaved weeds in peanuts, lettuce, cucumbers, chicory, endive, field beans, French beans, lentils, alfalfa, clovers, trefoil, tobacco and established turf, at 1000–1500 g/ha. Benfluralin, as well as methods of preparing benfluralin, are known in the art. Its herbicidal activity is described, for example, in Tomlin, C. D. S., Ed. The Pesticide Manual: A World Compendium, 17 th ed.; BCPC: Alton, 2016 (hereafter “The Pesticide Manual, Seventeenth Edition, 2016”). Benfluralin can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, benfluralin is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 900 g ai/ha or more, such as 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1440 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, or 1700 g ai/ha or more; in an amount of 1750 g ai/ha or less, such as 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1440 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, or 950 g ai/ha or less; or in or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 900–1750 g ai/ha, 1100–1350 g ai/ha, 1000–1500 g ai/ha, 1350–1600 g ai/ha, 1150–1400 g ai/ha, 950–1600 g ai/ha, 900–1440 g ai/ha, 1500– 1700 g ai/ha, or 950–1700 g ai/ha. Butamifos In some aspects, the MAI herbicide can comprise butamifos or an agriculturally acceptable salt or ester thereof. Butamifos, shown below, is a phosphoroamidate herbicide used for pre-emergence control of annual grass weeds in beans, turf, rice, at 900–1000 g/ha, and in vegetables, at 1000–2000 g/ha. Butamifos, as well as methods of preparing butamifos, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Butamifos can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, butamifos is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1000 g ai/ha or more, such as 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, or 1950 g ai/ha or more; in an amount of 2000 g ai/ha or less, such as 1950 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, or 1050 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1000–2000 g ai/ha, 1400–1700 g ai/ha, 1600–1950 g ai/ha, 1150–1500 g ai/ha, 1250–1400 g ai/ha, 1900–2000 g ai/ha, 1050–1200 g ai/ha, 1300–1800 g ai/ha, 1200–1500 g ai/ha, or 1050–1950 g ai/ha. Butralin In some aspects, the MAI herbicide can comprise butralin or an agriculturally acceptable salt or ester thereof. Butralin, shown below, is a dinitroaniline herbicide used for pre-emergence control of annual broad-leaved and grass weeds in cotton, soybeans, rice, barley, beans, alliums, vines, ornamentals, fruit and nut trees, at 1120–3400 g/ha; control of suckers in tobacco, at 125 mg/plant. Butralin, as well as methods of preparing butralin, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Butralin can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, butralin is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1100 g ai/ha or more, such as 1120 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3300 g ai/ha or more or 3400 g ai/ha or more; in an amount of 3500 g ai/ha or less, such as 3400 g ai/ha or less, 3300 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, or 1120 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1100–3500 g ai/ha, 1450–2900 g ai/ha, 1300–3200 g ai/ha, 1600–2500 g ai/ha, 1250–3000 g ai/ha, 1800–2400 g ai/ha, 1900–3400 g ai/ha, 1350–2700 g ai/ha, 1120–3100 g ai/ha, 1500–3500 g ai/ha, 2200–2900 g ai/ha, or 1120–3400 g ai/ha. Carbetamide In some aspects, the MAI herbicide can comprise carbetamide or an agriculturally acceptable salt or ester thereof. Carbetamide, shown below, is a carbamate herbicide used for control of annual grass weeds, including volunteer cereals, and some broad-leaved weeds in clover, alfalfa, sainfoin, brassicas, field beans, peas, lentils, sugar beets, oilseed rape, chicory, endive, sunflowers, caraway, strawberries, vines and fruit, at 2000 g/ha. Carbetamide, as well as methods of preparing carbetamide, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Carbetamide can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, carbetamide is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 900 g ai/ha or more, such as 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, or 1750 g ai/ha or more; in an amount of 1800 g ai/ha or less, such as 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, or 950 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 900–1800 g ai/ha, 1400–1700 g ai/ha, 1500–1750 g ai/ha, 1150–1500 g ai/ha, 1250–1400 g ai/ha, 1000–1600 g ai/ha, 1050–1200 g ai/ha, 1300–1800 g ai/ha, 1200–1600 g ai/ha, or 950–1750 g ai/ha. Chlorpropham In some aspects, the MAI herbicide can comprise chlorpropham or an agriculturally acceptable salt or ester thereof. Chlorpropham, shown below, is a carbamate herbicide used to inhibit sprouting in stored potatoes, at 8–64 g/t and control suckers in tobacco. Chlorpropham is also used for pre-emergence control of annual grass and some broad-leaved weeds in onions, leeks, garlic, shallots, alfalfa, clover, sugar beets, spinach, lettuce, endive, chicory, herbs, peas, beans, carrots, celery, black salsify, fennel, soybeans, cotton, rice, safflowers, sunflowers, cranberries, cane berries, ornamentals, ornamental trees and shrubs, perennial grass seed crops, etc., at up to 240 g/ha. Chlorpropham, as well as methods of preparing chlorpropham, are known in the art. Its herbicide activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Chlorpropham can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, chlorpropham is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 15 g ai/ha or more, such as 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, or 245 g ai/ha or more; in an amount of 250 g ai/ha or less, such as 245 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, or 20 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 15–250 g ai/ha, 30–65 g ai/ha, 40–175 g ai/ha, 65–250 g ai/ha, 50–150 g ai/ha, 110–190 g ai/ha, 120–230 g ai/ha, 75–220 g ai/ha, 80–230 g ai/ha, 100–140 g ai/ha, 95–160 g ai/ha, or 20–245 g ai/ha. Chlorthal In some aspects, the MAI herbicide can comprise chlorthal or an agriculturally acceptable salt or ester thereof. Chlorthal, shown below, is a benzoic acid herbicide used for preemergence control of annual grass and some broad-leaved weeds in onions, garlic, leeks, tomatoes, lettuce, cucurbits, peppers, aubergines, brassicas, potatoes, sweet potatoes, horseradish, field beans, soybeans, cotton, strawberries, ornamentals, established turf and other crops. One common ester of chlorthal is chlorthal-dimethyl. Chlorthal, as well as methods of preparing chlorthal, are known in the art. Its herbicide activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Chlorthal can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, chlorthal is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 5000 g ai/ha or more, such as 5250 g ai/ha or more, 5500 g ai/ha or more, 5750 g ai/ha or more, 6000 g ai/ha or more, 6250 g ai/ha or more, 6500 g ai/ha or more, 6750 g ai/ha or more, 7000 g ai/ha or more, 7250 g ai/ha or more, 7500 g ai/ha or more, 7750 g ai/ha or more, 8000 g ai/ha or more, 8250 g ai/ha or more, 8500 g ai/ha or more, 8750 g ai/ha or more, 9000 g ai/ha or more, 9250 g ai/ha or more, 9500 g ai/ha or more, 9750 g ai/ha or more, 10 kg ai/ha or more, 10.5 kg ai/ha or more, 11 kg ai/ha or more, 11.5 kg ai/ha or more, 12k g ai/ha or more, 12.5 kg ai/ha or more, 13 kg ai/ha or more, 13.5 kg ai/ha or more, 14 kg ai/ha or more, 14.5 kg ai/ha or more, 15 kg ai/ha or more, 15.5 kg ai/ha or more, 16 kg ai/ha or more, 16.5 kg ai/ha or more, or 16.75 kg ai/ha or more; in an amount of 17 kg ai/ha or less, such as 16.5 kg ai/ha or less, 16 kg ai/ha or less, 15.5 kg ai/ha or less, 15 kg ai/ha or less, 14.5k g ai/ha or less, 14 kg ai/ha or less, 13.5 kg ai/ha or less, 13 kg ai/ha or less, 12.5 kg ai/ha or less, 12 kg ai/ha or less, 11.5 kg ai/ha or less, 11 kg ai/ha or less, 10.5 kg ai/ha, 10 kg ai/ha or less, 9750 g ai/ha or less, 9500 g ai/ha or less, 9250 g ai/ha or less, 9000 g ai/ha or less, 8750 g ai/ha or less, 8500 g ai/ha or less, 8250 g ai/ha or less, 8000 g ai/ha or less, 7750 g ai/ha or less, 7500 g ai/ha or less, 7250 g ai/ha or less, 7000 g ai/ha or less, 6750 g ai/ha or less, 6500 g ai/ha or less, 6250 g ai/ha or less, 6000 g ai/ha or less, 5750 g ai/ha or less, 5500 g ai/ha or less, or 5250 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 5000 g–17.5 kg ai/ha, 6250–9500 g ai/ha, 5500– 8750 g ai/ha, 6000 g–12.5 kg ai/ha, 10.5–15 kg ai/ha, 9250 g–14.5 kg ai/ha, 8000–10,000 g ai/ha, 7750 g–16 kg ai/ha, 500–1400 g ai/ha, 6500–8500 g ai/ha, or 5250 g–16.5 kg ai/ha. Dithiopyr In some aspects, the MAI herbicide can comprise dithiopyr or an agriculturally acceptable salt or ester thereof. Dithiopyr, shown below, is a pyridine herbicide used for pre- and early post-emergence control of annual grass, e.g. crabgrass, and broad-leaved weeds in turf, at 280–1100 g/ha. Dithiopyr, as well as methods of preparing dithiopyr, are known in the art. Its herbicide activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Dithiopyr can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, dithiopyr is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 200 g ai/ha or more, such as 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, or 1200 g ai/ha or more; in an amount of 1250 g ai/ha or less, such as 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, or 210 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 200– 1250 g ai/ha, 350–650 g ai/ha, 460–750 g ai/ha, 600–1150 g ai/ha, 280–550 g ai/ha, 310–450 g ai/ha, 400–900 g ai/ha, 750–1200 g ai/ha, 430–850 g ai/ha, 500–1000 g ai/ha, 260–1100 g ai/ha, or 210–1200 g ai/ha. Ethalfluralin In some aspects, the MAI herbicide can comprise ethalfluralin or an agriculturally acceptable salt or ester thereof. Ethalfluralin, shown below, is a dinitroaniline herbicide used for pre-plant incorporated control of annual grass and broad-leaved weeds in cotton, soybeans, dry beans, lentils, maize, sorghum, safflowers and sunflowers, at 1000–1250 g/ha; and as post- plant surface application for control of annual grass and broad-leaved weeds in peanuts and cucurbits. Ethalfluralin, as well as methods of preparing ethalfluralin, are known in the art. Its herbicide activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016.
Ethalfluralin can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, ethalfluralin is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 750 g ai/ha or more, such as 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, or 1450 g ai/ha or more; in an amount of 1500 g ai/ha or less, such as 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, or 800 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 750–1500 g ai/ha, 950–1200 g ai/ha, 850–1250 g ai/ha, 1050–1300 g ai/ha, 800–1400 g ai/ha, 1100–1450 g ai/ha, 900–1150 g ai/ha, 750–1200 g ai/ha, 1350–1450 g ai/ha, 1000–1400 g ai/ha, or 800– 1450 g ai/ha. Oryzalin In some aspects, the MAI herbicide can comprise oryzalin or an agriculturally acceptable salt or ester thereof. Oryzalin, shown below, is a dinitroaniline herbicide used for pre-emergence control of annual grass and broad-leaved weeds in cotton, at 720–960 g/ha, soybeans, at 960–2160 g/ha, rice, at 240–480 g/ha, tree fruit, nut trees, vines, ornamentals, berries, amenity turf and non-crop areas, at 1920–4500 g/ha. Oryzalin, as well as methods of preparing oryzalin, are known in the art. Its herbicide activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016.
Oryzalin can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, oryzalin is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 200 g ai/ha or more, such as 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, or 1450 g ai/ha or more; in an amount of 1500 g ai/ha or less, such as 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, or 210 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 200– 1500 g ai/ha, 350–650 g ai/ha, 460–750 g ai/ha, 600–1150 g ai/ha, 280–550 g ai/ha, 310–450 g ai/ha, 400–900 g ai/ha, 750–1300 g ai/ha, 430–850 g ai/ha, 500–1450 g ai/ha, 260–1200 g ai/ha, or 210–1450 g ai/ha. Pendimethalin In some aspects, the MAI herbicide can comprise pendimethalin or an agriculturally acceptable salt or ester thereof. Pendimethalin, shown below, is a dinitroaniline herbicide used for pre-plant incorporated, pre- and early post-emergence control of annual grass and broad- leaved weeds in cereals, onions, leeks, garlic, fennel, maize, sorghum, rice, soybeans, peanuts, brassicas, carrots, celery, black salsify, peas, field beans, lupins, evening primroses, tulips, potatoes, cotton, hops, pome fruit, stone fruit, berries, strawberries, citrus, lettuce, aubergines, peppers, established turf and in transplanted tomatoes, sunflowers and tobacco, at 600–2400 g/ha; control of suckers in tobacco. Pendimethalin, as well as methods of preparing pendimethalin, are known in the art. Its herbicide activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Pendimethalin can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, pendimethalin is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 500 g ai/ha or more, such as 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, or 2400 g ai/ha or more; in an amount of 2500 g ai/ha or less, such as 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, or 525 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 500–2500 g ai/ha, 950–1800 g ai/ha, 625–1750 g ai/ha, 900–1900 g ai/ha, 850–2300 g ai/ha, 1150–1450 g ai/ha, 1900–2000 g ai/ha, 750–2200 g ai/ha, 1350–2100 g ai/ha, 575–1400 g ai/ha, 675–900 g ai/ha, or 525–2400 g ai/ha Prodiamine In some aspects, the MAI herbicide can comprise prodiamine or an agriculturally acceptable salt or ester thereof. Prodiamine, shown below, is a dinitroaniline herbicide used for pre- plant or pre-emergence control of annual grass and broad-leaved weeds in non-crop land, ornamentals, turf, conifer and hardwood seedlings, at 375–1600 g/ha. Prodiamine, as well as methods of preparing prodiamine, are known in the art. Its herbicide activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016.
Prodiamine can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, prodiamine is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 350 g ai/ha or more, such as 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, or 1750 g ai/ha or more; in an amount of 1800 g ai/ha or less, such as 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, or 360 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 350–1800 g ai/ha, 430–650 g ai/ha, 550–1350 g ai/ha, 600–1500 g ai/ha, 375–1300 g ai/ha, 675–1150 g ai/ha, 900–1450 g ai/ha, 750–1200 g ai/ha, 380–1700 g ai/ha, 500–1400 g ai/ha, 440–850 g ai/ha, or 360–1750 g ai/ha. Propham In some aspects, the MAI herbicide can comprise propham or an agriculturally acceptable salt or ester thereof. Propham, shown below, is a carbamate herbicide used for control of annual grass and some broad-leaved weeds in alfalfa, clover, sugar beets, spinach, lettuce, peas, beans, flax, safflowers, beetroot, fodder beets, lettuce, chard, lentils and perennial grass seed crops, at 2300–5000 g/ha, and as a sprouting inhibitor in potatoes. Propham, as well as methods of preparing propham, are known in the art. Its herbicide activity is described, for example, in The Pesticide Manual, Eighteenth Edition, 2016. Propham can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, propham is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2000 g ai/ha or more, such as 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3750 g ai/ha or more, 4000 g ai/ha or more, 4250 g ai/ha or more, 4500 g ai/ha or more, 4750 g ai/ha or more, 5000 g ai/ha or more, 5250 g ai/ha or more, 5500 g ai/ha or more, 5750 g ai/ha or more, 6000 g ai/ha or more, 6250 g ai/ha or more, 6500 g ai/ha or more, or 6750 g ai/ha or more; in an amount of 7000 g ai/ha or less, such as 6750 g ai/ha or less, 6500 g ai/ha or less, 6250 g ai/ha or less, 6000 g ai/ha or less, 5750 g ai/ha or less, 5500 g ai/ha or less, 5250 g ai/ha or less, 5000 g ai/ha or less, 4750 g ai/ha or less, 4500 g ai/ha or less, 4250 g ai/ha or less, 4000 g ai/ha or less, 3750 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, or 2100 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2000–7000 g ai/ha, 4750–6500 g ai/ha, 2300–3750 g ai/ha, 4000–6000 g ai/ha, 2700–5000 g ai/ha, 3100–4750 g ai/ha, 2500–4000 g ai/ha, 5750–7000 g ai/ha, 3300–5250 g ai/ha, 2000–4500 g ai/ha, 2900–5500 g ai/ha, or 2100– 6750 g ai/ha. Propyzamide In some aspects, the MAI herbicide can comprise propyzamide or an agriculturally acceptable salt or ester thereof. Propyzamide, shown below, is a benzamide herbicide used for pre- and early post-emergence control of annual and perennial grass and some broad-leaved weeds, in fruit, vines, lettuce, endive, chicory, brassicas, oilseed rape, legumes, alfalfa, clover, trefoil, sainfoin, artichokes, sugar beets, roses, ornamental trees and shrubs, warm season amenity grass, fallow land and forestry and Poa annua in Bermuda grass, zoysia grass and certain other turf species, at 560–2200 g/ha. Propyzamide, as well as methods of preparing propyzamide, are known in the art. Its herbicide activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Propyzamide can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, propyzamide is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 250 g ai/ha or more, such as 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, or 2400 g ai/ha or more; in an amount of 2500 g ai/ha or less, such as 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, or 260 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 250–2500 g ai/ha, 950–1900 g ai/ha, 360–1750 g ai/ha, 600–2000 g ai/ha, 550–1350 g ai/ha, 1100–1450 g ai/ha, 1900–2400 g ai/ha, 270–2200 g ai/ha, 380–1050 g ai/ha, 700–1700 g ai/ha, 440–1600 g ai/ha, or 260–2400 g ai/ha. Thiazopyr In some aspects, the MAI herbicide can comprise thiazopyr or an agriculturally acceptable salt or ester thereof. Thiazopyr, shown below, is a pyridine herbicide used for pre- emergence control of annual grass and some broad-leaved weeds in tree fruit, vines, citrus, sugar cane, pineapples, alfalfa and forestry, at 100–560 g/ha. Thiazopyr, as well as methods of preparing thiazopyr, are known in the art. Its herbicide activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Thiazopyr can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, thiazopyr is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 100 g ai/ha or more, such as 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, or 575 g ai/ha or more; in an amount of 600 g ai/ha or less, such as 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, or 110 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 100–600 g ai/ha, 210–470 g ai/ha, 360–550 g ai/ha, 200–430 g ai/ha, 280–575 g ai/ha, 310–450 g ai/ha, 400–600 g ai/ha, 125–370 g ai/ha, 430– 525 g ai/ha, 300–470 g ai/ha, 160–500 g ai/ha, or 110–575 g ai/ha. Trifluralin In some aspects, the MAI herbicide can comprise trifluralin or an agriculturally acceptable salt or ester thereof. Trifluralin, shown below, is a dinitroaniline herbicide used for pre-plant incorporated or pre-emergence control of annual grass and broad-leaved weeds in brassicas, beans, peas, carrots, parsnips, lettuce, peppers, tomatoes, artichokes, onions, garlic, vines, strawberries, raspberries, citrus, oilseed rape, peanuts, soybeans, sunflowers, safflowers, ornamentals, including trees and shrubs, cotton, sugar beets, sugar cane, winter cereals, amenity grass and forestry, at 500–1000 g/ha. Trifluralin, as well as methods of preparing trifluralin, are known in the art. Its herbicide activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Trifluralin can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, trifluralin is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 400 g ai/ha or more, such as 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, or 1150 g ai/ha or more; in an amount of 1200 g ai/ha or less, such as 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, or 410 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 400–1200 g ai/ha, 490–650 g ai/ha, 625–1150 g ai/ha, 500–1200 g ai/ha, 750– 1000 g ai/ha, 410–850 g ai/ha, 800–1050 g ai/ha, 700–1100 g ai/ha, 440–900 g ai/ha, 400–1000 g ai/ha, 575–950 g ai/ha, or 410–1150 g ai/ha. FATTY ACID AND LIPID SYNTHESIS INHIBITOR (FA/LSI) HERBICIDES In addition to the compounds according to Formula I or the compounds PYR-1 through PYR-21 (and all stereoisomers thereof), the compositions can include a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. FA/LSI herbicides appear to interfere with the biosynthesis of fatty acids and lipids, thereby reducing the deposition of cuticle wax, and to cause abnormal cell development or to inhibit cell division in germinating seedlings. Examples of FA/LSI herbicides include benfuresate, bensulide, butylate, cycloate, dalapon, EPTC, esprocarb, ethofumesate, flupropanate, molinate, orbencarb, prosulfocarb, thiobencarb, tiocarbazil, tri- allate, vernolate. In some aspects, the composition can include a FA/LSI herbicide selected from the group consisting of benfuresate, bensulide, butylate, cycloate, dalapon, EPTC, esprocarb, ethofumesate, flupropanate, molinate, orbencarb, prosulfocarb, thiobencarb, tiocarbazil, tri- allate, vernolate, agriculturally acceptable salts or esters thereof, and mixtures thereof. FA/LSI herbicides can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, the FA/LSI herbicide is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 300 g ai/ha or more, such as 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more,1000 g ai/ha or more, 1100 g ai/ha or more, 1200 g ai/ha or more, 1300 g ai/ha or more, 1400 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3250 g ai/ha or more, 3500 g ai/ha or more, 3750 g ai/ha or more, 4000 g ai/ha or more, 4250 g ai/ha or more, 4500 g ai/ha or more, 4750 g ai/ha or more, 5000 g ai/ha or more, 5250 g ai/ha or more, 5500 g ai/ha or more, 5750 g ai/ha or more, 5000 g ai/ha or more, 5250 g ai/ha or more, 5500 g ai/ha or more, 5750 g ai/ha or more, 6000 g ai/ha or more, 6250 g ai/ha or more, 6500 g ai/ha or more, 6750 g ai/ha or more, 7000 g ai/ha or more, 7250 g ai/ha or more, 7500 g ai/ha or more, 7750 g ai/ha or more, 8000 g ai/ha or more, 8250 g ai/ha or more, 8500 g ai/ha or more, 8750 g ai/ha or more, 9000 g ai/ha or more, 9250 g ai/ha or more, 9500 g ai/ha or more, 9750 g ai/ha or more, 10 kg ai/ha or more, 10.5 kg ai/ha or more, 11 kg ai/ha or more, 11.5 kg ai/ha or more, 12k g ai/ha or more, 12.5 kg ai/ha or more, 13 kg ai/ha or more, 13.5 kg ai/ha or more, 14 kg ai/ha or more, 14.5 kg ai/ha or more, 15 kg ai/ha or more, 15.5 kg ai/ha or more, 16 kg ai/ha or more, 16.5 kg ai/ha or more, 16.75 kg ai/ha or more, 17 kg ai/ha or more, 17.5 kg ai/ha or more, 18 kg ai/ha or more, 18.5 kg ai/ha or more, 19 kg ai/ha or more, 19.5 kg ai/ha or more, 20 kg ai/ha or more, or 20.5 kg ai/ha or more; in an amount of 21 kg ai/ha or less, such as 20.5 kg ai/ha or less, 20 kg ai/ha or less, 19.5k g ai/ha or less, 19 kg ai/ha or less, 18.5 kg ai/ha or less, 18 kg ai/ha or less, 17.5 kg ai/ha or less, 17 kg ai/ha or less, 16.5 kg ai/ha or less, 16 kg ai/ha or less, 15.5 kg ai/ha or less, 15 kg ai/ha or less, 14.5k g ai/ha or less, 14 kg ai/ha or less, 13.5 kg ai/ha or less, 13 kg ai/ha or less, 12.5 kg ai/ha or less, 12 kg ai/ha or less, 11.5 kg ai/ha or less, 11 kg ai/ha or less, 10.5 kg ai/ha, 10 kg ai/ha or less, 9750 g ai/ha or less, 9500 g ai/ha or less, 9250 g ai/ha or less, 9000 g ai/ha or less, 8750 g ai/ha or less, 8500 g ai/ha or less, 8250 g ai/ha or less, 8000 g ai/ha or less, 7750 g ai/ha or less, 7500 g ai/ha or less, 7250 g ai/ha or less, 7000 g ai/ha or less, 6750 g ai/ha or less, 6500 g ai/ha or less, 6250 g ai/ha or less, 6000 g ai/ha or less, 6750 g ai/ha or less, 6500 g ai/ha or less, 5250 g ai/ha or less, 5000 g ai/ha or less, 4750 g ai/ha or less, 4500 g ai/ha or less,4250 g ai/ha or less, 4000 g ai/ha or less, 3750 g ai/ha or less, 3500 g ai/ha or less, 3250 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1400 g ai/ha or less, 1300 g ai/ha or less, 1200 g ai/ha or less, 1100 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, or 310 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 300 g–21 kg ai/ha, 950–4500 g ai/ha, 460– 3750 g ai/ha, 6–15 kg ai/ha, 900–1700 g ai/ha, 320–450 g ai/ha, 8500 g–14 kg ai/ha, 750–2200 g ai/ha, 390–5250 g ai/ha, 400–1200 g ai/ha, 1200–3500 g ai/ha, or 310 g–20.5 kg ai/ha. Benfuresate In some aspects, the FA/LSI herbicide can comprise benfuresate or an agriculturally acceptable salt or ester thereof. Benfuresate, shown below, is a benzofuran herbicide used for post-emergence control of grass and broad-leaved weeds in paddy rice, fruit, beans, maize, sugar cane and perennial crops, at 450–600 g/ha and pre-plant incorporated in cotton and tobacco, at 2000–3000 g/ha. Benfuresate, as well as methods of preparing benfuresate, are known in the art. Its herbicidal activity is described, for example, in Tomlin, C. D. S., Ed. The Pesticide Manual: A World Compendium, 17 th ed.; BCPC: Alton, 2016 (hereafter “The Pesticide Manual, Seventeenth Edition, 2016”). Benfuresate can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, benfuresate is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 150 g ai/ha or more, such as 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, or 2900 g ai/ha or more; in an amount of 3000 g ai/ha or less, such as 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, or 160 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 150–3000 g ai/ha, 950–2800 g ai/ha, 575–850 g ai/ha, 250–2500 g ai/ha, 1350–2700 g ai/ha, 1150–2300 g ai/ha, 1900–2600 g ai/ha, 270–1200 g ai/ha, 480–5250 g ai/ha, 500–1400 g ai/ha, 440–1700 g ai/ha, or 160–2900 g ai/ha. Bensulide In some aspects, the FA/LSI herbicide can comprise bensulide or an agriculturally acceptable salt or ester thereof. Bensulide, shown below, is a phosphorodithioate herbicide used for pre-emergence control of broad-leaved weeds in brassicas, cucurbits, lettuce, onions, etc., at 5600–6700 g/ha, and in established turf, at 8400–28000 g/ha per season. Bensulide, as well as methods of preparing bensulide, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Bensulide can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, bensulide is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 5000 g ai/ha or more, such as 5250 g ai/ha or more, 5500 g ai/ha or more, 5750 g ai/ha or more, 6000 g ai/ha or more, 6250 g ai/ha or more, 6500 g ai/ha or more, 6750 g ai/ha or more, 7000 g ai/ha or more, 7250 g ai/ha or more, 7500 g ai/ha or more, 7750 g ai/ha or more, 8000 g ai/ha or more, 8250 g ai/ha or more, 8500 g ai/ha or more, 8750 g ai/ha or more, 9000 g ai/ha or more, 9250 g ai/ha or more, 9500 g ai/ha or more, 9750 g ai/ha or more, 10 kg ai/ha or more, 10.5 kg ai/ha or more, 11 kg ai/ha or more, 11.5 kg ai/ha or more, 12k g ai/ha or more, 12.5 kg ai/ha or more, 13 kg ai/ha or more, or 13.5 kg ai/ha or more; in an amount of 14 kg ai/ha or less, such as 13.5 kg ai/ha or less, 13 kg ai/ha or less, 12.5 kg ai/ha or less, 12 kg ai/ha or less, 11.5 kg ai/ha or less, 11 kg ai/ha or less, 10.5 kg ai/ha, 10 kg ai/ha or less, 9750 g ai/ha or less, 9500 g ai/ha or less, 9250 g ai/ha or less, 9000 g ai/ha or less, 8750 g ai/ha or less, 8500 g ai/ha or less, 8250 g ai/ha or less, 8000 g ai/ha or less, 7750 g ai/ha or less, 7500 g ai/ha or less, 7250 g ai/ha or less, 7000 g ai/ha or less, 6750 g ai/ha or less, 6500 g ai/ha or less, 6250 g ai/ha or less, 6000 g ai/ha or less, 5750 g ai/ha or less, 5500 g ai/ha or less, or 5250 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 5–15 kg ai/ha, 9500 g–13 kg ai/ha, 6250–8750 g ai/ha, 7–12 kg ai/ha, 8500–9750 g ai/ha, 11–13.5 kg ai/ha, 5750–7750 g ai/ha, 9750 g–12 kg ai/ha, 10–11 kg ai/ha, 7500–9500 g ai/ha, or 5250 g–13.5 kg ai/ha. Butylate In some aspects, the FA/LSI herbicide can comprise butylate or an agriculturally acceptable salt or ester thereof. Butylate, shown below, is a thiocarbamate herbicide used for pre-plant incorporated control of annual grass weeds and Cyperus spp. in maize and pineapples at 3000–4000 g/ha. Butylate, as well as methods of preparing butylate, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Butylate can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, butylate is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 3000 g ai/ha or more, such as 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3750 g ai/ha or more, 4000 g ai/ha or more, 4250 g ai/ha or more, 4500 g ai/ha or more, 4750 g ai/ha or more, 5000 g ai/ha or more, 5250 g ai/ha or more, 5500 g ai/ha or more, 5750 g ai/ha or more, 6000 g ai/ha or more, 6250 g ai/ha or more, 6500 g ai/ha or more, or 6750 g ai/ha or more; in an amount of 7000 g ai/ha or less, such as 6750 g ai/ha or less, 6500 g ai/ha or less, 6250 g ai/ha or less, 6000 g ai/ha or less, 5750 g ai/ha or less, 5500 g ai/ha or less, 5250 g ai/ha or less, 5000 g ai/ha or less, 4750 g ai/ha or less, 4500 g ai/ha or less, 4250 g ai/ha or less, 4000 g ai/ha or less, 3750 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, or 3100 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 3000–7000 g ai/ha, 4500–6500 g ai/ha, 3100–3750 g ai/ha, 6000–7000 g ai/ha, 3750–5500 g ai/ha, 3300–4250 g ai/ha, 5000–6000 g ai/ha, 4250–5750 g ai/ha, 3250–5250 g ai/ha, 3500– 4000 g ai/ha, or 3100–6750 g ai/ha. Cycloate In some aspects, the FA/LSI herbicide can comprise cycloate or an agriculturally acceptable salt or ester thereof. Cycloate, shown below, is a thiocarbamate herbicide used for pre-plant incorporated control of annual and some perennial grass weeds, Cyperus spp., and some annual broad-leaved weeds in sugar beets, fodder beets, beetroot and spinach, at 3000– 4000 g/ha. Cycloate, as well as methods of preparing cycloate, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Cycloate can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, cycloate is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2500 g ai/ha or more, such as 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3750 g ai/ha or more, 4000 g ai/ha or more, or 4250 g ai/ha or more; in an amount of 4500 g ai/ha or less, such as 4250 g ai/ha or less, 4000 g ai/ha or less, 3750 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, or 2600 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2500–4500 g ai/ha, 3200–4000 g ai/ha, 2800–3750 g ai/ha, 3600–4250 g ai/ha, 3750–4250 g ai/ha, 2900–4000 g ai/ha, 3250–4500 g ai/ha, 3100–4000 g ai/ha, 2500–3400 g ai/ha, or 2600–4250 g ai/ha. Dalapon In some aspects, the FA/LSI herbicide can comprise dalapon or an agriculturally acceptable salt or ester thereof. Dalapon, shown below, is a thiocarbamate herbicide used for pre- and post-emergence control of annual and perennial grass weeds in non-crop land, e.g. embankments, roadside verges, industrial sites, railway tracks, irrigation channels, ditches, etc., pome fruit, stone fruit, bush fruit, citrus, nuts, olives, grapes, forestry, bananas, sugar cane, rhubarb, asparagus, potatoes, peas, soybeans, beets, oilseed rape, flax, maize, sorghum, coffee, tea, rubber, cotton and ornamental shrubs; control of reed, sedge, rush, halophyte and semi- aquatic grass weeds in water courses. Common agriculturally acceptable salts of dalapon include the magnesium and sodium salts thereof. Dalapon, as well as methods of preparing dalapon, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Dalapon can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, dalapon is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1500 g ai/ha or more, such as 1600 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3750 g ai/ha or more, 4000 g ai/ha or more, 4250 g ai/ha or more, 4500 g ai/ha or more, 4750 g ai/ha or more, 5000 g ai/ha or more, 5250 g ai/ha or more, 5500 g ai/ha or more, 5750 g ai/ha or more, 6000 g ai/ha or more, 6250 g ai/ha or more, 6500 g ai/ha or more, 6750 g ai/ha or more, 7000 g ai/ha or more, 7250 g ai/ha or more, 7500 g ai/ha or more, 7750 g ai/ha or more, 8000 g ai/ha or more, 8250 g ai/ha or more, 8500 g ai/ha or more, 8750 g ai/ha or more, 9000 g ai/ha or more, 9250 g ai/ha or more, 9500 g ai/ha or more, 9750 g ai/ha or more, 10 kg ai/ha or more, 10.5 kg ai/ha or more, 11 kg ai/ha or more, 11.5 kg ai/ha or more, 12k g ai/ha or more, 12.5 kg ai/ha or more, 13 kg ai/ha or more, 13.5 kg ai/ha or more, 14 kg ai/ha or more, 14.5 kg ai/ha or more, 15 kg ai/ha or more, 15.5 kg ai/ha or more, 16 kg ai/ha or more, 16.5 kg ai/ha or more, 16.75 kg ai/ha or more, 17 kg ai/ha or more, 17.5 kg ai/ha or more, 18 kg ai/ha or more, 18.5 kg ai/ha or more, 19 kg ai/ha or more, 19.5 kg ai/ha or more, 20 kg ai/ha or more, or 20.5 kg ai/ha or more; in an amount of 21 kg ai/ha or less, such as 20.5 kg ai/ha or less, 20 kg ai/ha or less, 19.5k g ai/ha or less, 19 kg ai/ha or less, 18.5 kg ai/ha or less, 18 kg ai/ha or less, 17.5 kg ai/ha or less, 17 kg ai/ha or less, 16.5 kg ai/ha or less, 16 kg ai/ha or less, 15.5 kg ai/ha or less, 15 kg ai/ha or less, 14.5k g ai/ha or less, 14 kg ai/ha or less, 13.5 kg ai/ha or less, 13 kg ai/ha or less, 12.5 kg ai/ha or less, 12 kg ai/ha or less, 11.5 kg ai/ha or less, 11 kg ai/ha or less, 10.5 kg ai/ha, 10 kg ai/ha or less, 9750 g ai/ha or less, 9500 g ai/ha or less, 9250 g ai/ha or less, 9000 g ai/ha or less, 8750 g ai/ha or less, 8500 g ai/ha or less, 8250 g ai/ha or less, 8000 g ai/ha or less, 7750 g ai/ha or less, 7500 g ai/ha or less, 7250 g ai/ha or less, 7000 g ai/ha or less, 6750 g ai/ha or less, 6500 g ai/ha or less, 6250 g ai/ha or less, 6000 g ai/ha or less, 5750 g ai/ha or less, 5500 g ai/ha or less, 5250 g ai/ha or less, 5000 g ai/ha or less, 4750 g ai/ha or less, 4500 g ai/ha or less, 4250 g ai/ha or less, 4000 g ai/ha or less, 3750 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, or 1600 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1500 g–21 kg ai/ha, 7250–8500 g ai/ha, 14–20 kg ai/ha, 6500–8250 g ai/ha, 5–15 kg ai/ha, 11–14.5 kg ai/ha, 12.5–19 kg ai/ha, 7500 g–17 kg ai/ha, 1800–5250 g ai/ha, 4500–8500 g ai/ha, 6750–9750 g ai/ha, or 1600 g–20.5 kg ai/ha EPTC In some aspects, the FA/LSI herbicide can comprise S-ethyl dipropylthiocarbamate, more commonly known as EPTC, or an agriculturally acceptable salt or ester thereof. EPTC, shown below, is a thiocarbamate herbicide used for pre-plant incorporated control of annual and perennial grass, especially couch grass, sedge, e.g. Cyperus spp. and some broad-leaved weeds in potatoes, beans, peas, forage legumes, beetroot, sugar beets, alfalfa, trefoil, clover, cotton, maize, flax, sweet potatoes, safflowers, sunflowers, strawberries, citrus, almonds, walnuts, ornamentals, pineapples and pine nurseries, at 4500–6700 g/ha, and in maize, with dichlormid safener. EPTC, as well as methods of preparing EPTC, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. EPTC can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, EPTC is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1000 g ai/ha or more, such as 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3750 g ai/ha or more, 4000 g ai/ha or more, 4250 g ai/ha or more, 4500 g ai/ha or more, 4750 g ai/ha or more, 5000 g ai/ha or more, 5250 g ai/ha or more, 5500 g ai/ha or more, 5750 g ai/ha or more, 6000 g ai/ha or more, 6250 g ai/ha or more, 6500 g ai/ha or more, 6750 g ai/ha or more, 7000 g ai/ha or more, 7250 g ai/ha or more, 7500 g ai/ha or more, 7750 g ai/ha or more, 8000 g ai/ha or more, 8250 g ai/ha or more, 8500 g ai/ha or more, or 8750 g ai/ha or more; in an amount of 9000 g ai/ha or less, such as 8750 g ai/ha or less, 8500 g ai/ha or less, 8250 g ai/ha or less, 8000 g ai/ha or less, 7750 g ai/ha or less, 7500 g ai/ha or less, 7250 g ai/ha or less, 7000 g ai/ha or less, 6750 g ai/ha or less, 6500 g ai/ha or less, 6250 g ai/ha or less, 6000 g ai/ha or less, 5750 g ai/ha or less, 5500 g ai/ha or less, 5250 g ai/ha or less, 5000 g ai/ha or less, 4750 g ai/ha or less, 4500 g ai/ha or less, 4250 g ai/ha or less, 4000 g ai/ha or less, 3750 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, or 1050 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1000–9000 g ai/ha, 2200–6500 g ai/ha, 1450–3750 g ai/ha, 2600–7500 g ai/ha, 1050–4000 g ai/ha, 2100–4500 g ai/ha, 1900–5500 g ai/ha, 7250– 8500 g ai/ha, 3300–6250 g ai/ha, 1500–3000 g ai/ha, 2500–8250 g ai/ha, or 1050–8750 g ai/ha. Esprocarb In some aspects, the FA/LSI herbicide can comprise esprocarb, or an agriculturally acceptable salt or ester thereof. Esprocarb, shown below, is a thiocarbamate herbicide used for pre- and post-emergence control of annual weeds, e.g. Echinochloa spp., in paddy rice, at 1500–4000 g/ha. Esprocarb, as well as methods of preparing esprocarb, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Esprocarb can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, esprocarb is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 400 g ai/ha or more, such as 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, or 3750 g ai/ha or more; 4000 g ai/ha or less, such as 3750 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, or 410 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 400–4000 g ai/ha, 2500–3500 g ai/ha, 600–2700 g ai/ha, 3100–4000 g ai/ha, 2000–3000 g ai/ha, 1800–3250 g ai/ha, 900–3400 g ai/ha, 1750–2200 g ai/ha, 2800–3750 g ai/ha, 550–1900 g ai/ha, 1700–3300 g ai/ha, or 410– 3750 g ai/ha. Ethofumesate In some aspects, the FA/LSI herbicide can comprise ethofumesate, or an agriculturally acceptable salt or ester thereof. Ethofumesate, shown below, is a benzofuran herbicide used for pre- and post-emergence control of grass and broad-leaved weeds in sugar and other beets, turf, ryegrass and other pasture grasses, at 300–2000 g/ha. Ethofumesate, as well as methods of preparing ethofumesate, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Ethofumesate can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, ethofumesate is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 200 g ai/ha or more, such as 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, or 2900 g ai/ha or more; in an amount of 3000 g ai/ha or less, such as 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, or 210 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 200–3000 g ai/ha, 950–2500 g ai/ha, 460–1750 g ai/ha, 600–2500 g ai/ha, 350–2200 g ai/ha, 310–450 g ai/ha, 500–2400 g ai/ha, 750–2200 g ai/ha, 380–1350 g ai/ha, 575–1300 g ai/ha, 440–2600 g ai/ha, or 210–2900 g ai/ha. Flupropanate In some aspects, the FA/LSI herbicide can comprise flupropanate, or an agriculturally acceptable salt or ester thereof. Flupropanate, shown below, is a halogenated alkanoic acid herbicide used for post-emergence control of annual and perennial grass weeds, e.g., serrated tussock and Chilean needle grass, in pastures and in uncultivated land. One agriculturally acceptable salt of flupropanate is flupropanate-sodium. Flupropanate, as well as methods of preparing flupropanate, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Flupropanate can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, flupropanate is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1000 g ai/ha or more, such as 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, or 2900 g ai/ha or more; in an amount of 3000 g ai/ha or less, such as 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, or 1050 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1000–3000 g ai/ha, 1150–2500 g ai/ha, 1400–1750 g ai/ha, 1600–2500 g ai/ha, 1050–2200 g ai/ha, 1350–2400 g ai/ha, 2500–2900 g ai/ha, 1750–2700 g ai/ha, 1300–1600 g ai/ha, 1800– 2300 g ai/ha, or 1050–2900 g ai/ha. Molinate In some aspects, the FA/LSI herbicide can comprise molinate, or an agriculturally acceptable salt or ester thereof. Molinate, shown below, is a thiocarbamate herbicide used for control of germinating broad-leaved and grass weeds, particularly Echinochloa spp. and Glyceria spp., in rice, at 2500–5000 g/ha, applied either before planting to water-seeded or shallow soil-seeded rice or post-flood, post-emergence in other types of rice culture. Molinate, as well as methods of preparing molinate, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Molinate can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, molinate is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 2500 g ai/ha or more, such as 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3750 g ai/ha or more, 4000 g ai/ha or more, 4250 g ai/ha or more, 4500 g ai/ha or more, or 4750 g ai/ha or more; in an amount of 5000 g ai/ha or less, such as 4750 g ai/ha or less, 4500 g ai/ha or less, 4250 g ai/ha or less, 4000 g ai/ha or less, 3750 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, or 2600 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 2500–5000 g ai/ha, 3200–4500 g ai/ha, 2600–3750 g ai/ha, 3000–3500 g ai/ha, 2800–3400 g ai/ha, 2700–3100 g ai/ha, 2900– 4250 g ai/ha, 3750–4750 g ai/ha, 3300–4500 g ai/ha, 2500–3500 g ai/ha, or 2600–4750 g ai/ha. Orbencarb In some aspects, the FA/LSI herbicide can comprise orbencarb, or an agriculturally acceptable salt or ester thereof. Orbencarb, shown below, is a thiocarbamate herbicide used for pre-emergence control of annual grass, except wild oats, and broad-leaved weeds in barley, wheat, rye, maize, soybeans, cotton and turf, at 4000–5000 g/ha. Orbencarb, as well as methods of preparing orbencarb, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Orbencarb can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, orbencarb is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 4000 g ai/ha or more, such as 4100 g ai/ha or more, 4200 g ai/ha or more, 4300 g ai/ha or more, 4400 g ai/ha or more, 4500 g ai/ha or more, 4600 g ai/ha or more, 4700 g ai/ha or more, 4800 g ai/ha or more, or 4900 g ai/ha or more; in an amount of 5000 g ai/ha or less, such as 4900 g ai/ha or less, 4800 g ai/ha or less, 4700 g ai/ha or less, 4600 g ai/ha or less, 4500 g ai/ha or less, 4400 g ai/ha or less, 4300 g ai/ha or less, 4200 g ai/ha or less, or 4100 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 4000–5000 g ai/ha, 4200–4500 g ai/ha, 4600–4900 g ai/ha, 4100–4400 g ai/ha, 4500–5000 g ai/ha, or 4100–4900 g ai/ha. Prosulfocarb In some aspects, the FA/LSI herbicide can comprise prosulfocarb, or an agriculturally acceptable salt or ester thereof. Prosulfocarb, shown below, is a thiocarbamate herbicide used for pre- and early post-emergence control of grass and broad-leaved weeds in winter wheat, winter barley and rye, at 3000–4000 g/ha. Prosulfocarb, as well as methods of preparing prosulfocarb, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Prosulfocarb can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, prosulfocarb is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 250 g ai/ha or more, such as 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, 675 g ai/ha or more, 700 g ai/ha or more, 750 g ai/ha or more, 800 g ai/ha or more, 850 g ai/ha or more, 900 g ai/ha or more, 950 g ai/ha or more, 1000 g ai/ha or more, 1050 g ai/ha or more, 1100 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, or 3750 g ai/ha or more; in an amount of 4000 g ai/ha or less, such as 3750 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, 1100 g ai/ha or less, 1050 g ai/ha or less, 1000 g ai/ha or less, 950 g ai/ha or less, 900 g ai/ha or less, 850 g ai/ha or less, 800 g ai/ha or less, 750 g ai/ha or less, 700 g ai/ha or less, 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 250–4000 g ai/ha, 1350–3500 g ai/ha, 1600–3750 g ai/ha, 800–2500 g ai/ha, 1250–2000 g ai/ha, 1100–3100 g ai/ha, 1900–2400 g ai/ha, 320– 3200 g ai/ha, 450–850 g ai/ha, 2700–3400 g ai/ha, 1500–2900 g ai/ha, or 260–3750 g ai/ha. Thiobencarb In some aspects, the FA/LSI herbicide can comprise thiobencarb, or an agriculturally acceptable salt or ester thereof. Thiobencarb, shown below, is a thiocarbamate herbicide used for pre- to early post-emergence control of Echinochloa, Leptochloa and Cyperus spp. and other grass and annual broad-leaved weeds in direct-seeded and transplanted rice, at 1500–7500 g/ha. Thiobencarb, as well as methods of preparing thiobencarb, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Thiobencarb can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, thiobencarb is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1100 g ai/ha or more, such as 1120 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1600 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, 2900 g ai/ha or more, 3000 g ai/ha or more, 3100 g ai/ha or more, 3200 g ai/ha or more, 3250 g ai/ha or more, 3300 g ai/ha or more, 3400 g ai/ha or more, 3500 g ai/ha or more, 3750 g ai/ha or more, 4000 g ai/ha or more, 4250 g ai/ha or more, 4500 g ai/ha or more, 4750 g ai/ha or more, 5000 g ai/ha or more, 5250 g ai/ha or more, 5500 g ai/ha or more, 5750 g ai/ha or more, 6000 g ai/ha or more, 6250 g ai/ha or more, 6500 g ai/ha or more, 6750 g ai/ha or more, 7000 g ai/ha or more, or 7250 g ai/ha or more; in an amount of 7500 g ai/ha or less, such as 7250 g ai/ha or less, 7000 g ai/ha or less, 6750 g ai/ha or less, 6500 g ai/ha or less, 6250 g ai/ha or less, 6000 g ai/ha or less, 5750 g ai/ha or less, 5500 g ai/ha or less, 5250 g ai/ha or less, 5000 g ai/ha or less, 4750 g ai/ha or less, 4500 g ai/ha or less, 4250 g ai/ha or less, 4000 g ai/ha or less, 3750 g ai/ha or less, 3500 g ai/ha or less, 3400 g ai/ha or less, 3300 g ai/ha or less, 3250 g ai/ha or less, 3200 g ai/ha or less, 3100 g ai/ha or less, 3000 g ai/ha or less, 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, 1600 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, or 1120 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1100–7500 g ai/ha, 3750–6500 g ai/ha, 1250–3400 g ai/ha, 2600–5500 g ai/ha, 1800–5000 g ai/ha, 2100–6250 g ai/ha, 1900–4000 g ai/ha, 2700– 4500 g ai/ha, 2000–5250 g ai/ha, 6500–7500 g ai/ha, 1300–4000 g ai/ha, or 1120–7250 g ai/ha. Tiocarbazil In some aspects, the FA/LSI herbicide can comprise tiocarbazil, or an agriculturally acceptable salt or ester thereof. Tiocarbazil, shown below, is a thiocarbamate herbicide used for pre- or post-emergence control of grass weeds, e.g., Echinochloa spp. and Lolium perenne, and sedge weeds, e.g., Cyperus spp., in rice paddies, at 4000 g/ha. Tiocarbazil, as well as methods of preparing tiocarbazil, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Tri-allate In some aspects, the FA/LSI herbicide can comprise tri-allate, or an agriculturally acceptable salt or ester thereof. Tri-allate, shown below, is a thiocarbamate herbicide used for pre-plant or post-plant incorporated control of wild oats and some annual grass weeds in wheat, barley, rye, field beans, peas, lentils, beets, oilseed rape, maize, flax, alfalfa, clover, vetches, sainfoin, safflowers, sunflowers and vegetables, at 1120–1680 g/ha. Tri-allate, as well as methods of preparing tri-allate, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Tri-allate can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, tri-allate is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1100 g ai/ha or more, such as 1120 g ai/ha or more, 1150 g ai/ha or more, 1200 g ai/ha or more, 1250 g ai/ha or more, 1300 g ai/ha or more, 1350 g ai/ha or more, 1400 g ai/ha or more, 1450 g ai/ha or more, 1500 g ai/ha or more, 1550 g ai/ha or more, 1600 g ai/ha or more, 1650 g ai/ha or more, or 1680 g ai/ha or more; in an amount of 1700 g ai/ha or less, such as 1680 g ai/ha or less, 1650 g ai/ha or less, 1600 g ai/ha or less, 1550 g ai/ha or less, 1500 g ai/ha or less, 1450 g ai/ha or less, 1400 g ai/ha or less, 1350 g ai/ha or less, 1300 g ai/ha or less, 1250 g ai/ha or less, 1200 g ai/ha or less, 1150 g ai/ha or less, or 1120 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1100–1700 g ai/ha, 1250–1600 g ai/ha, 1550–1650 g ai/ha, 1200–1500 g ai/ha, 1150–1300 g ai/ha, 1120–1400 g ai/ha, 1450–1700 g ai/ha, 1100–1350 g ai/ha, or 1120–1680 g ai/ha. Vernolate In some aspects, the FA/LSI herbicide can comprise vernolate, or an agriculturally acceptable salt or ester thereof. Vernolate, shown below, is a thiocarbamate herbicide used for pre-plant or post-plant incorporated control of wild oats and some annual grass weeds in wheat, barley, rye, field beans, peas, lentils, beets, oilseed rape, maize, flax, alfalfa, clover, vetches, sainfoin, safflowers, sunflowers and vegetables, at 1120–1680 g/ha. Vernolate, as well as methods of preparing vernolate, are known in the art. Its herbicidal activity is described, for example, in The Pesticide Manual, Seventeenth Edition, 2016. Vernolate can be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount sufficient to induce a herbicidal effect. In some aspects, vernolate is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1500 g ai/ha or more, such as 1600 g ai/ha or more, 1700 g ai/ha or more, 1750 g ai/ha or more, 1800 g ai/ha or more, 1900 g ai/ha or more, 2000 g ai/ha or more, 2100 g ai/ha or more, 2200 g ai/ha or more, 2300 g ai/ha or more, 2400 g ai/ha or more, 2500 g ai/ha or more, 2600 g ai/ha or more, 2700 g ai/ha or more, 2800 g ai/ha or more, or 2900 g ai/ha or more; in an amount of 3000 g ai/ha or less, such as 2900 g ai/ha or less, 2800 g ai/ha or less, 2700 g ai/ha or less, 2600 g ai/ha or less, 2500 g ai/ha or less, 2400 g ai/ha or less, 2300 g ai/ha or less, 2200 g ai/ha or less, 2100 g ai/ha or less, 2000 g ai/ha or less, 1900 g ai/ha or less, 1800 g ai/ha or less, 1750 g ai/ha or less, 1700 g ai/ha or less, or 1600 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1500–3000 g ai/ha, 1800–2500 g ai/ha, 1700–1900 g ai/ha, 1600–2800 g ai/ha, 1750–2200 g ai/ha, 2350–2900 g ai/ha, 1600–2100 g ai/ha, 1750–2700 g ai/ha, 2100–2600 g ai/ha, 1800–2300 g ai/ha, or 1600–2900 g ai/ha. OTHER HERBICIDES Broclozone Broclozone, the ISO name for 2-[(2-bromo-4-chlorophenyl)methyl]-4,4-dimethyl- 3-isoxazolidinone (CAS No. 2766607-82-1), is a DOXP-inhibiting oxazole herbicide from Qingdao KingAgroot Chemical Compound Co. and is disclosed in WO202302027. Broclozone may be used with foliar and/or soil applications, and may be used on crops such as wheat, soybeans, peanuts, oilseed rape, cabbage, rice, cotton, garlic, and watermelon. Broclozone may be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 300 g ai/ha or more, such as 310 g ai/ha or more, 320 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more,550 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 620 g ai/ha or more, 640 g ai/ha or more, 650 g ai/ha or more, 660 g ai/ha or more, 680 g ai/ha or more, 700 g ai/ha or more, 720 g ai/ha or more, or 740 g ai/ha or more; in an amount of 750 g ai/ha or less, such as 740 g ai/ha or less, 720 g ai/ha or less, 700 g ai/ha or less, 680 g ai/ha or less, 660 g ai/ha or less, 650 g ai/ha or less, 640 g ai/ha or less, 620 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 550 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 320 g ai/ha or less, or 310 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 300- 750 g ai/ha, 320–580 g ai/ha, 330-660 g ai/ha, 410–650 g ai/ha, 340–700 g ai/ha, 450–520 g ai/ha, 500–750 g ai/ha, 400–600 g ai/ha, 350–720 g ai/ha, or 420-740 g ai/ha. Flufenoximacil Flufenoximacil, the ISO name for methyl (2R)-2-[[(E)-[[2-chloro-5-[3,6-dihydro- 3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-4- fluorophenyl]methylene]amino]oxy]propanoate (CAS No. 2759011-88-4), is a phenyluracil herbicide for non-selective weed control from Qingdao KingAgroot Chemical Compound Co. and is described in U.S Patent Application Publication No.2023/0111310. Flufenoximacil is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 2 g ai/ha or more, 2.5 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 142.5 g ai/ha or more, 145 g ai/ha or more, 147 g ai/ha or more, or 149 g ai/ha or more; in an amount of 150 g ai/ha or less, such as 149 g ai/ha or less, 147.5 g ai/ha or less, 145 g ai/ha or less, 142.5 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, 12.5 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, 2.5 g ai/ha or less, or 2 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–150 g ai/ha, 2–130 g ai/ha, 2.5–45 g ai/ha, 3–70 g ai/ha, 4- 147 g ai/ha, 5–100 g ai/ha, 6–75 g ai/ha, 7–50 g ai/ha, 10–149 g ai/ha, 20–120 g ai/ha, 25–90 g ai/ha, 30–60 g ai/ha, 50–150 g ai/ha, 60–130 g ai/ha, or 100–145 g ai/ha. Flusulfinam Flusulfinam, the ISO name for 2-fluoro-N-(5-methyl-1,3,4-oxadiazol-2-yl)-3- (propylsulfinyl)-4-(trifluoromethyl)benzamide (the (R)-enantiomer), is an amide herbicide from Qingdao KingAgroot Chemical Compound Co., and is described in US Patent Application Publication No.2023/0041563. Flusulfinam is effective in controlling weeds commonly found around rice crops (such as indica rice, japonica rice), gramineous weed (such as rice barnyardgrass, Qianjinjin, barnyard grass, horse tang, Setaria), broad-leaved weeds (such as gazania, velvetleaf, amaranth, chickweed), and sedge weeds (such as sedge, fireflies). Flusulfinam is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 2 g ai/ha or more, 2.5 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 142.5 g ai/ha or more, 145 g ai/ha or more, 147 g ai/ha or more, or 149 g ai/ha or more; in an amount of 150 g ai/ha or less, such as 149 g ai/ha or less, 147.5 g ai/ha or less, 145 g ai/ha or less, 142.5 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, 12.5 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, 2.5 g ai/ha or less, or 2 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–150 g ai/ha, 2–130 g ai/ha, 2.5–45 g ai/ha, 3–70 g ai/ha, 4- 147 g ai/ha, 5–100 g ai/ha, 6–75 g ai/ha, 7–50 g ai/ha, 10–149 g ai/ha, 20–120 g ai/ha, 25–90 g ai/ha, 30–60 g ai/ha, 50–150 g ai/ha, 60–130 g ai/ha, or 100–145 g ai/ha. Icafolin Icafolin, the ISO name for (2RS,4RS)-4-({[(5S)-3-(3,5-difluorophenyl)-5-vinyl- 4,5-dihydroisoxazol-5-yl]carbonyl}amino)tetrahydrofuran-2-ca rboxylic acid (including combinations of the (2S,4S), (2R,4R) isomers), is an isoxazole herbicide from Bayer AG (CAS Reg. No. 2749998-21-6) and is a broad-spectrum herbicide for the control of mono dicotyledonous annual weeds, such as Abutilon theophrasti, Alopecurus myosuroides, Amaranthus retroflexus, Avena fatua, Polygonum convolvulus, Setaria viridis, Veronica persica. Icafolin esters and salts activities are disclosed in International PCT Application Publication Nos. WO2018228985 and WO2018228986. Icafolin can be applied pre-emergence or post-emergence to control various weeds, such as butilon theophrasti, Alopecurus myosuroides, Amaranthus retroflexus, Avena fatua, Echinochloca crus, during preemergence treatment. gallium, Hordeum murinum, Lolium rigidum, Pharitis purpurea, Polygonum convolvulus, Setaria viridis, Stellaria media, Veronica persica and Viola tricolor. Icafolin is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 1 g ai/ha or more, such as 2 g ai/ha or more, 2.5 g ai/ha or more, 3 g ai/ha or more, 4 g ai/ha or more, 5 g ai/ha or more, 6 g ai/ha or more, 7 g ai/ha or more, 8 g ai/ha or more, 9 g ai/ha or more, 10 g ai/ha or more, 12.5 g ai/ha or more, 15 g ai/ha or more, 17.5 g ai/ha or more, 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 60 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 142.5 g ai/ha or more, 145 g ai/ha or more, 147 g ai/ha or more, or 149 g ai/ha or more; in an amount of 150 g ai/ha or less, such as 149 g ai/ha or less, 147.5 g ai/ha or less, 145 g ai/ha or less, 142.5 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 90 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 60 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, 20 g ai/ha or less, 17.5 g ai/ha or less, 15 g ai/ha or less, 12.5 g ai/ha or less, 10 g ai/ha or less, 9 g ai/ha or less, 8 g ai/ha or less, 7 g ai/ha or less, 6 g ai/ha or less, 5 g ai/ha or less, 4 g ai/ha or less, 3 g ai/ha or less, 2.5 g ai/ha or less, or 2 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 1–150 g ai/ha, 2–130 g ai/ha, 2.5–45 g ai/ha, 3–70 g ai/ha, 4- 147 g ai/ha, 5–100 g ai/ha, 6–75 g ai/ha, 7–50 g ai/ha, 10–149 g ai/ha, 20–120 g ai/ha, 25–90 g ai/ha, 30–60 g ai/ha, 50–150 g ai/ha, 60–130 g ai/ha, 100–145 g ai/ha, or preferably 30-80 g ai/ha. Iptriazopyrid Iptriazopyrid, the ISO name for 3-[[(1-methylethyl)sulfonyl]methyl]-N-(5-methyl- 1,3,4-oxadiazol-2-yl)-5-(trifluoromethyl)-1,2,4-triazolo[4,3 -a]pyridine-8-carboxamide, is an amide herbicide from Nissan Chemical Corp. (CAS Reg. No.1994348-72-9) and is disclosed in International PCT Application Publication Nos. WO2014192936 and WO2020189576 (polymorphic crystal forms of Iptriazopyrid may be used as an herbicide for paddy fields in any of the treatment methods of soil treatment and foliage treatment under flooding. In some embodiments, can be preferably used in a treatment method by foliar treatment when in mixtures of the disclosed compounds. For example, iptriazopyrid may also be used with crops such as corn, rice, wheat, barley, lime tree, embaku, sorghum, cotton, soybean, peanut, buckwheat, tensai, rapeseed, sunflower, sugar cane, tobacco and the like. Iptriazopyrid may be applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 50 g ai/ha or more, such as 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 220 g ai/ha or more, 240 g ai/ha or more, 260 g ai/ha or more, 280 g ai/ha or more, 300 g ai/ha or more, 320 g ai/ha or more, 340 g ai/ha or more, 360 g ai/ha or more, 380 g ai/ha or more, 400 g ai/ha or more, 420 g ai/ha or more, 440 g ai/ha or more, 460 g ai/ha or more, 480 g ai/ha or more, 500 g ai/ha or more, 520 g ai/ha or more, 540 g ai/ha or more, 560 g ai/ha or more, 580 g ai/ha or more, 600 g ai/ha or more, 620 g ai/ha or more, 640 g ai/ha or more, 650 g ai/ha or more, 660 g ai/ha or more, 670 g ai/ha or more, 680 g ai/ha or more, or 690 g ai/ha or more; in an amount of 700 g ai/ha or less, such as 690 g ai/ha or less, 680 g ai/ha or less, 670 g ai/ha or less, 660 g ai/ha or less, 650 g ai/ha or less, 640 g ai/ha or less, 620 g ai/ha or less, 600 g ai/ha or less, 580 g ai/ha or less, 560 g ai/ha or less, 540 g ai/ha or less, 520 g ai/ha or less, 500 g ai/ha or less, 480 g ai/ha or less, 460 g ai/ha or less, 440 g ai/ha or less, 420 g ai/ha or less, 400 g ai/ha or less, 380 g ai/ha or less, 360 g ai/ha or less, 340 g ai/ha or less, 320 g ai/ha or less, 300 g ai/ha or less, 280 g ai/ha or less, 260 g ai/ha or less, 240 g ai/ha or less, 220 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, or 55 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 50–700 g ai/ha, 55–400 g ai/ha, 60–650 g ai/ha, 75–520 g ai/ha, 80–400 g ai/ha, 85–500 g ai/ha, 90–220 g ai/ha, 100–700 g ai/ha, 100–500 g ai/ha, 110–640 g ai/ha, 120–420 g ai/ha, 120–500 g ai/ha, 140– 670 g ai/ha, or 150–580 g ai/ha. Metproxybicyclone Metproxybicyclone, the ISO name for the racemic mixture (1RS,5SR)-3-[2- methoxy-4-(prop-1-yn-1-yl)phenyl]-4-oxobicyclo[3.2.1]oct-2-e n-2-yl methyl carbonate, available from Syngenta Crop Protection (CAS Reg. No. 1848207-89-5) and is described in International PCT Application Publication No. WO2015197468. Metproxybicyclone is applied to vegetation or an area adjacent the vegetation or applied to soil or water to prevent the emergence or growth of vegetation in an amount of 15 g ai/ha or more, such as 20 g ai/ha or more, 25 g ai/ha or more, 30 g ai/ha or more, 35 g ai/ha or more, 40 g ai/ha or more, 45 g ai/ha or more, 50 g ai/ha or more, 55 g ai/ha or more, 60 g ai/ha or more, 65 g ai/ha or more, 70 g ai/ha or more, 75 g ai/ha or more, 80 g ai/ha or more, 85 g ai/ha or more, 90 g ai/ha or more, 95 g ai/ha or more, 100 g ai/ha or more, 110 g ai/ha or more, 120 g ai/ha or more, 125 g ai/ha or more, 130 g ai/ha or more, 140 g ai/ha or more, 150 g ai/ha or more, 160 g ai/ha or more, 170 g ai/ha or more, 175 g ai/ha or more, 180 g ai/ha or more, 190 g ai/ha or more, 200 g ai/ha or more, 210 g ai/ha or more, 220 g ai/ha or more, 225 g ai/ha or more, 230 g ai/ha or more, 240 g ai/ha or more, 250 g ai/ha or more, 260 g ai/ha or more, 270 g ai/ha or more, 275 g ai/ha or more, 280 g ai/ha or more, 290 g ai/ha or more, 300 g ai/ha or more, 310 g ai/ha or more, 320 g ai/ha or more, 325 g ai/ha or more, 330 g ai/ha or more, 340 g ai/ha or more, 350 g ai/ha or more, 360 g ai/ha or more, 370 g ai/ha or more, 375 g ai/ha or more, 380 g ai/ha or more, 390 g ai/ha or more, 400 g ai/ha or more, 410 g ai/ha or more, 420 g ai/ha or more, 425 g ai/ha or more, 430 g ai/ha or more, 440 g ai/ha or more, 450 g ai/ha or more, 460 g ai/ha or more, 470 g ai/ha or more, 475 g ai/ha or more, 480 g ai/ha or more, 490 g ai/ha or more, 500 g ai/ha or more, 525 g ai/ha or more, 550 g ai/ha or more, 575 g ai/ha or more, 600 g ai/ha or more, 625 g ai/ha or more, 650 g ai/ha or more, or 675 g ai/ha or more; in an amount of 700 g ai/ha or less, such as 675 g ai/ha or less, 650 g ai/ha or less, 625 g ai/ha or less, 600 g ai/ha or less, 575 g ai/ha or less, 550 g ai/ha or less, 525 g ai/ha or less, 500 g ai/ha or less, 490 g ai/ha or less, 480 g ai/ha or less, 475 g ai/ha or less, 470 g ai/ha or less, 460 g ai/ha or less, 450 g ai/ha or less, 440 g ai/ha or less, 430 g ai/ha or less, 425 g ai/ha or less, 420 g ai/ha or less, 410 g ai/ha or less, 400 g ai/ha or less, 390 g ai/ha or less, 380 g ai/ha or less, 375 g ai/ha or less, 370 g ai/ha or less, 360 g ai/ha or less, 350 g ai/ha or less, 340 g ai/ha or less, 330 g ai/ha or less, 325 g ai/ha or less, 320 g ai/ha or less, 310 g ai/ha or less, 300 g ai/ha or less, 290 g ai/ha or less, 280 g ai/ha or less, 275 g ai/ha or less, 270 g ai/ha or less, 260 g ai/ha or less, 250 g ai/ha or less, 240 g ai/ha or less, 230 g ai/ha or less, 225 g ai/ha or less, 220 g ai/ha or less, 210 g ai/ha or less, 200 g ai/ha or less, 190 g ai/ha or less, 180 g ai/ha or less, 175 g ai/ha or less, 170 g ai/ha or less, 160 g ai/ha or less, 150 g ai/ha or less, 140 g ai/ha or less, 130 g ai/ha or less, 125 g ai/ha or less, 120 g ai/ha or less, 110 g ai/ha or less, 100 g ai/ha or less, 95 g ai/ha or less, 90 g ai/ha or less, 85 g ai/ha or less, 80 g ai/ha or less, 75 g ai/ha or less, 70 g ai/ha or less, 65 g ai/ha or less, 60 g ai/ha or less, 55 g ai/ha or less, 50 g ai/ha or less, 45 g ai/ha or less, 40 g ai/ha or less, 35 g ai/ha or less, 30 g ai/ha or less, 25 g ai/ha or less, or 20 g ai/ha or less; or in an amount ranging from any of the minimum values described above to any of the maximum values described above, such as 15–700 g ai/ha, 45–650 g ai/ha, 30– 375 g ai/ha, 160–250 g ai/ha, 220–550 g ai/ha, 110–450 g ai/ha, 290–490 g ai/ha, 70–430 g ai/ha, 300–525 g ai/ha, 500–650 g ai/ha, 340–575 g ai/ha, or 20–675 g ai/ha. The substituted 5-membered ring molecules, compositions and methods of the appended claims are not limited in scope by the specific compositions and methods described herein, which are intended as illustrations of a few aspects of the claims and any compositions and methods that are functionally equivalent are intended to fall within the scope of the claims. Various modifications of the substituted 5-membered ring molecules, compositions, and methods in addition to those shown and described herein are intended to fall within the scope of the appended claims. Further, while only certain representative substituted 5-membered ring molecules, compositions and method steps disclosed herein are specifically described, other combinations of the compositions and method steps also are intended to fall within the scope of the appended claims, even if not specifically recited. Thus, a combination of steps, elements, components, or constituents may be explicitly mentioned herein; however, other combinations of steps, elements, components, and constituents are included, even though not explicitly stated. The term “comprising” and variations thereof as used herein is used synonymously with the terms “including” and “containing” and variations thereof, and are open, non-limiting terms. Although the terms “comprising,” “including,” and “containing” have been used herein to describe various aspects, the terms “consisting essentially of” and “consisting of” can be used in place of “comprising,” “including,” or “containing” to provide for more specific aspects and are also disclosed. Other than in the examples, or where otherwise noted, all numbers expressing quantities of ingredients, reaction conditions, and so forth used in the specification and claims are to be understood to be construed in light of the number of significant digits and ordinary rounding approaches, and not as an attempt to limit the application of the doctrine of equivalents to the scope of the claims.
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