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Title:
SUPPORTED HYDROXIDE GASOLINE DEEP ADSORPTION DESULFURIZING AGENT AND PREPARATION METHOD AND OXIDATION REGENERATION METHOD THEREFOR
Document Type and Number:
WIPO Patent Application WO/2019/134428
Kind Code:
A1
Abstract:
A supported hydroxide gasoline deep adsorption desulfurizing agent and a preparation method and oxidation regeneration method therefor. The desulfurizing agent comprises a carrier and a metal hydroxide supported on the carrier, wherein the mass ratio of the metal hydroxide to the carrier is 5-30:100. 100. The preparation method comprises: dissolving a metal salt in water, adding the carrier and mixing uniformly, adjusting the pH value of the mixture with an alkaline regulator, filtering, and drying to obtain a supported gasoline adsorption desulfurizing agent. After adsorption desulfurization, separating the desulfurizing agent and the gasoline, immersing and washing the desulfurizing agent containing adsorbate in a regenerant containing an oxidizing agent, and then drying to obtain a regenerated desulfurizing agent. The supported hydroxide adsorption desulfurizing agent has the advantages of high selectivity, high desulfurization depth, no loss of octane number, and simple and convenient operation. The regeneration method can enable the regenerated desulfurizing agent after adsorption and desulfurization to have efficient absorption and desulfurizing capacity.

Inventors:
XIAO, Jing (No. 381, Wushan Road Tianh, Guangzhou Guangdong 0, 510640, CN)
YANG, Cuiting (No. 381, Wushan Road Tianh, Guangzhou Guangdong 0, 510640, CN)
DONG, Lei (No. 381, Wushan Road Tianh, Guangzhou Guangdong 0, 510640, CN)
LIAO, Neng (No. 381, Wushan Road Tianh, Guangzhou Guangdong 0, 510640, CN)
MIAO, Guang (No. 381, Wushan Road Tianh, Guangzhou Guangdong 0, 510640, CN)
LI, Zhong (No. 381, Wushan Road Tianh, Guangzhou Guangdong 0, 510640, CN)
Application Number:
CN2018/112828
Publication Date:
July 11, 2019
Filing Date:
October 30, 2018
Export Citation:
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Assignee:
SOUTH CHINA UNIVERSITY OF TECHNOLOGY (No. 381, Wushan Road Tianh, Guangzhou Guangdong 0, 510640, CN)
DEEP PURE TECHNOLOGIES (SHENZHEN), LTD. (Building No.2 3101, Dachong New City GardenKeji Road, Yuehai Street, Nansha, Shenzhen Guangdong 7, 518057, CN)
International Classes:
B01J20/08; B01J20/32; B01J20/34; C10G25/00; C10G25/12
Foreign References:
CN108187605A2018-06-22
CN108704630A2018-10-26
CN1193041A1998-09-16
CN101524641A2009-09-09
CN104667872A2015-06-03
CN101134908A2008-03-05
CN103977757A2014-08-13
CN101314726A2008-12-03
CN102773068A2012-11-14
US20060283780A12006-12-21
Attorney, Agent or Firm:
YOGO PATENT & TRADEMARK AGENCY LIMITED COMPANY (Room 4416, Block B SinopecTower,Tiyuxi Road, Tianh, Guangzhou Guangdong 0, 510620, CN)
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