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Title:
SURFACE ROUGHENING OF CMC AND COATED CMC
Document Type and Number:
WIPO Patent Application WO/2018/087081
Kind Code:
A1
Abstract:
By surface roughening of CMC component via a pico-laser treatment a good adhering of a plasma sprayed coating is achieved.

Inventors:
FLORES RENTERIA ARTURO (DE)
MITCHELL DAVID J (US)
VAN DER LAAG NIELS (DE)
Application Number:
PCT/EP2017/078459
Publication Date:
May 17, 2018
Filing Date:
November 07, 2017
Export Citation:
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Assignee:
SIEMENS AG (DE)
International Classes:
B23K26/00; B23K26/0622; C04B41/00; C04B41/87; C04B41/91; B23K103/00; B23K103/16
Foreign References:
EP2189504A12010-05-26
EP2669041A12013-12-04
Other References:
LIU YONGSHENG ET AL: "Effect of energy density and feeding speed on micro-holes drilling in SiC/SiC composites by picosecond laser", INTERNATIONAL JOURNAL OF ADVANCED MANUFACTURING TECHNOLOGY, SPRINGER VERLAG, LONDON; GB, vol. 84, no. 9, 23 September 2015 (2015-09-23), pages 1917 - 1925, XP035976250, ISSN: 0268-3768, [retrieved on 20150923], DOI: 10.1007/S00170-015-7844-1
LI WEINAN ET AL: "Effect of different parameters on machining of SiC/SiC composites via pico-second laser", APPLIED SURFACE SCIENCE, ELSEVIER, AMSTERDAM, NL, vol. 364, 15 December 2015 (2015-12-15), pages 378 - 387, XP029411465, ISSN: 0169-4332, DOI: 10.1016/J.APSUSC.2015.12.089
DATABASE WPI 2013 Derwent World Patents Index; AN 2013-R76162, XP002770228, "Method for hole machining with picosecond laser"
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Claims:
Patent claims

1. Method of roughening a surface (5) of a CMC substrate (4) of a CMC component (1),

wherein a pico-laser with pulses in the pico-second area is used to roughen or engrave the surface (5) of the CMC sub¬ strate ( 4 ) .

2. Method according to claim 1,

wherein holes,

especially round holes (10), and/or

engravings (13, 16) and/or

grids (11) or

combinations are produced into the surface (5) of the CMC substrate ( 4 ) .

3. Product (1),

especially produced by a method according to claim 1 or 2, which has a ceramic layer (7) on a roughened surface (5) of a substrate ( 4 ) ,

wherein the ceramic layer (7) has a APS applied-like micro- structure.

4. Product according to claim 3,

wherein the material of the ceramic layer (7) comprises zirconia,

especially 8YSZ,

alumina,

48YSZ or

a 48YSZ-alumina mixture.

5. Product according to claims 3 or 4,

wherein the surface (5) of the substrate (4) under the ceramic layer (7) comprises holes (10),

especially round holes,

elongated engravings (13, 16),

grids (11) or

combinations of it.

6. Product according to claim 5,

wherein the depth of the holes 10, engravings (13, 16) or grids (11) are between 50ym to lOOym.

Description:
Surface roughening of CMC and coated CMC

The invention relates to a surface roughening of a CMC part which will be coated with a ceramic layer.

Oxide based Ceramic Matrix Composites (CMC's) provide a higher temperature capability (1423K) than superalloys 1273K C) and superior oxidation resistance. The limited fracture resistance and damage tolerance of ceramic materials is sub ¬ stantially improved by the fiber reinforcement. However, the load bearing capacity (mechanical strength) of these Oxide- Oxide (Ox-Ox) CMCs is also limited by grain growth and reac ¬ tion processes with the matrix and/or the environment at 1423K and higher. With firing temperatures as high as 1873 - 1973K, Ox-Ox CMCs need Environmental Barrier Coatings (EBCs) that maintain CMCs below 1423K. Thus, CMCs can be used to its full potential, only if the coating can be integrated in to the system design.

For oxide-oxide CMCs, application of the thermal barrier was by a FGI (Friable Graded Insulation) system. FGI was

coprocessed along with CMC, however, currently the hollow spheres needed for this coating system are not commercially available. In addition, the capability of the coating to recession at high surface temperatures (1873K-1973K) is not expected to match behavior of zirconia based materials.

It is therefore aim of the invention to overcome the problems described above.

The current proposal takes into account the experience of using proper roughening of the substrate surface for TBC adhesion .

The problems are solved by an method according to claim 1 and a product according to claim 3. In the further dependent claims further advantages are listed which can be arbitrarily combined with each other to yield further advantages. The description and the figure are only examples of the invention .

Application of plasma sprayed coating on CMC surface is not easy. Depending upon the local macro roughness of the ceramic fibers and matrix infiltration characteristics, the adhesion of plasma sprayed coatings are poor. Plasma sprayed coating don't adhere well to CMC surfaces especially on the surface of in-plane fibers direction. The proposed invention embodiments provide significant im ¬ provements in the ability for plasma sprayed coatings to adhere to the CMC substrate.

Better adhesion is achieved by increasing mechanical inter- locking via surface roughening of the CMC by using pico-laser machining. This technology allows the grinding of the CMC surface in a better controlled way compared to standard grit- blasting processing or as received conditions. Moreover, the pico-laser avoids the glassing of the ceramic material sur- face by its capability of almost fully evaporate the CMC dur ¬ ing machining.

The inventive step is the use of pico-laser to prepare the CMC surface in the out of plane configuration prior to the APS coating process enhancing the engineering capability of the surface preparation compared to standard processes like grit blasting.

Furthermore, no extra phases are introduced into the top re- gion of the CMC due to the capability of pico-laser machining to overcome glassing. This allows an improved chemical bond ¬ ing with the EBC without a potentially weak glassy inter- layer. Additionally it allows an enhanced shape of the rough ¬ ness (macro- and micro roughness of hills and valleys) .

The figure 1 shows a CMC component 1 which comprises a CMC substrate 4 with a surface 5.

The substrate 4 is made of a CMC, preferably of an Ox-Ox-CMC, but not limited. As described above the surface 5 of the CMC-substrate 4 is roughened or structured by a pico-laser, which leads to no melting of the material of the CMC.

Pulses in the pico-second region are used, especially max 900ps .

The surface 5 of the CMC-substrate 4 can comprises holes 10 (Fig. 2), especially round holes, elongated engravings 13, 16 (Fig. 3), which can be straight 13 or waved 16 or grids 11 (Fig. 4) . These forms 10, 13, 16, 11 can appear alone or in combination with each other in the surface 5.

An alternative is to randomly remove locally material from the surface to roughen the surface 5 deeper and additionally (Fig. 5) .

Especially a depth of 50ym to lOOym is at least given for the holes 10, engravings 13, 16 or grids 11.

After that a ceramic layer 7 is applied on which is prefera- bly performed by APS.

The material of the ceramic layer 7 is preferably zirconia (Zr0 2 ) , stabilized zirconia 8YSZ and/or an alumina sublayer, or alumina or 48YSZ (fully stabilized zirkonia) .