CROSS-REFERENCE TO RELATED APPLICATIONS [0001] This application claims the benefit of U.S. Provisional Application No. 60/578,620, filed on June 10, 2004, which is incorporated herein by reference. FIELD OF THE INVENTION [0002] The present invention relates to a method of synthesizing a caprolactam, and more specifically, synthesizing ε-caprolactam from L-lysine. BACKGROUND [0003] About 2.5 billion tons of nylon 6 is produced annually on a worldwide basis. The production of nylon 6 is accomplished by the ring opening polymerization of the monomer ε-caprolactam. The starting chemical compound for the production of ε-caprolactam is benzene which is converted to either cyclohexane or phenol and either chemical is converted via cyclohexanone to cyclohexanone oxime and then this intermediate is heated in sulfuric acid. This chemical reaction is known as the Beckman rearrangement. The starting chemical benzene is produced via the refinement of petroleum chemicals. SUMMARY [0004] The inventors herein have succeeded in devising a new approach in the production of ε-caprolactam from natural products. The approach is based upon the use of L-lysine in a novel process to produce ε- caprolactam which is needed as a precursor to nylon 6. [0005] Thus, in various embodiments, the present invention provides a method of synthesizing α-amino-ε-caprolactam, comprising heating a salt of L- lysine in a solvent comprising an alcohol. In various embodiments, the methods comprise heating a salt of L-lysine in a solvent comprising an alcohol, and deaminating the reaction product. In various embodiments, the invention includes methods of converting biomass into nylon 6. Such methods comprise heating L-lysine in a solvent comprising an alcohol to produce α-amino-ε- caprolactam, deaminating to produce ε-caprolactam and polymerizing into nylon 6, wherein the L-lysine is derived from the biomass. BRIEF DESCRIPTION OF THE DRAWINGS [0006] The present invention will become more fully understood from the detailed description and the accompanying drawings, wherein: [0007] Figure 1 is a block diagram of a process of converting biomass into nylon 6. [0008] It should be noted that these figures are intended to exemplify the general characteristics of the invention for the purpose of the description of such embodiments herein. These figures may not precisely reflect the characteristics of any given embodiment and is not necessarily intended to define or limit specific embodiments within the scope of this invention. DETAILED DESCRIPTION [0009] The following definitions and non-limiting guidelines must be considered in reviewing the description of this invention set forth herein. The headings (such as "Introduction" and "Summary,") and sub-headings (such as "Amplification") used herein are intended only for general organization of topics within the disclosure of the invention, and are not intended to limit the disclosure of the invention or any aspect thereof. In particular, subject matter disclosed in the "Introduction" may include aspects of technology within the scope of the invention, and may not constitute a recitation of prior art. Subject matter disclosed in the "Summary" is not an exhaustive or complete disclosure of the entire scope of the invention or any embodiments thereof. [0010] The citation of references herein does not constitute an admission that those references are prior art or have any relevance to the patentability of the invention disclosed herein. Any discussion of the content of references cited in the Introduction is intended merely to provide a general summary of assertions made by the authors of the references, and does not constitute an admission as to the accuracy of the content of such references. All references cited in the Description section of this specification are hereby incorporated by reference in their entirety. [0011] The description and specific examples, while indicating embodiments of the invention, are intended for purposes of illustration only and are not intended to limit the scope of the invention. Moreover, recitation of multiple embodiments having stated features is not intended to exclude other embodiments having additional features, or other embodiments incorporating different combinations the stated of features. [0012] As used herein, the words "preferred" and "preferably" refer to embodiments of the invention that afford certain benefits, under certain circumstances. However, other embodiments may also be preferred, under the same or other circumstances. Furthermore, the recitation of one or more preferred embodiments does not imply that other embodiments are not useful, and is not intended to exclude other embodiments from the scope of the invention. [0013] As used herein, the word "include," and its variants, is intended to be non-limiting, such that recitation of items in a list is not to the exclusion of other like items that may also be useful in the materials, compositions, devices, and methods of this invention. [0014] Caprolactam is primarily used in the manufacture of synthetic fibers, especially nylon 6 that is also used in bristle brushes, textile stiffeners, film coatings, synthetic leather, plastics, plasticizers, vehicles, cross linking for polyurethanes, and in the synthesis of lysine. The starting point for the production of ε-caprolactam is benzene which is refined from the non-renewable source of petroleum. In addition to its limitations due to its source of non¬ renewable petroleum, exposure to benzene, which has been linked to acute myeloid leukemia and non-Hodgkin's lymphoma, is a continuing problem for the chemical industry. The most effective way of dealing with benzene's human health risk is to eliminate its use. Such a far reaching solution requires the elaboration of fundamentally new synthesis for chemicals derived from benzene. A sugar such as a non-toxic glucose may be a new starting point for many of these syntheses. In order to use glucose as a replacement for benzene as a starting point for many of these syntheses, a bio-refinery is needed. A bio- refinery is a facility that integrates biomass conversion processes and equipment to produce fuels, power and chemicals from biomass. The bio-refinery concept is analogous to a petroleum refinery which produces multiple fuels and products from petroleum. By producing multiple products, a bio-refinery can take advantage of the differences in biomass components and intermediates and maximize the value derived from the biomass feed stock with minimal waste and emissions. The conversion of biomass into a sugar such as glucose is well known in the art (see Advancing Sustainability Through Green Chemistry and Engineering, ACS Symposium Series, 823, edited by Lanky, R.L. and Anastas, P.T., American Chemical Society, Washington, DC, 2002; Biomass for Energy, Industry and Environment, 6th European Community Conference, edited by Grassi, G., Collina, A. and Zibetta, H., Elsevier Science Publishing Co., Inc., New York, 1998; Biobased Industrial Products: Research and Commercialization Priorities, edited by Dale, B. E., Natural Research Council, Washington, DC, 1999; Emerging Technologies for Materials and Chemicals from Biomass, ASC Symposium 467, edited by Narayan, R., Rowell, R., Schultz, T., American Chemical Society, Washington, DC, 1991). [0015] In the early 1960's, Japanese biotechnology firms discovered a bacterial fermentation technique which started with a sugar and produced lysine. L-Iysine is produced and available from many industrial sources including such companies as Aginomoto, Kyowa Hakko, Sewon, Arthur Daniels Midland, Cheil Jedang, BASF, and Cargill. [0016] The cyclization of L-lysine to form a seven member ring of α- amino-ε-caprolactam has been attempted before and reports have shown low yields. Such attempts have included reactions in near super critical water (see Japanese Patent No. 2003206276 to Goto et al. issued July 22, 2003) or reactions using an excess of AI2O3 in toluene (see Blade-Font, A., Tetrahedron Lett., 1980, 21 , 2443-2446. Pellegata, R., Pinza, M.: Pifferi G., Synthesis 1978, 614-616). [0017] In one aspect, the invention provides an efficient route for the cyclization for a cyclic amidation reaction to form lactams having ring sizes from 5 to 8 ring members. Following cyclic amidation, other reactive groups on the cyclic ring may be removed if desired. In one aspect, the invention provides efficient cyclic amidation carried out in an alcohol solvents having from 2 to 6 carbons. Amino functional carboxylic acid useful in the invention improves those that can cyclize to form a stable lactam, preferably one having from 5 to 8 ring members. The amino functional carboxylic acids can contain other functional groups as long as those functional groups do not interfere with the amidation reaction mediated by the 2 to 6 carbon alcohol solvent. [0018] According to the present invention, a new process for the cyclization of L-lysine to α-amino-ε-caprolactam is described herein. In addition, in accordance with the present invention, a process for the deamination of α- amino-ε-caprolactam to ε-caprolactam is described herein. Commercially available sources of L-lysine such as, but not limited to, L-lysine dihydrochloride, L-lysine hydrochloride, L-lysine phosphate, L-lysine diphosphate, L-lysine acetate, and L-lysine may be used and any needed steps so that the L-lysine is in the proper state for the following reactions will be known by one skilled in the art. In addition, commercially available sources of lysine maybe used but a step to separate the L-lysine from the D-lysine may be added such as, for an example, a chiral separation step and such separation and purification techniques will be known by one skilled in the art. In various embodiments, a cyclization reaction was initiated after neutralization of lysine hydrochloride with sodium hydroxide (NaOH). In this embodiment, the resulting NaCI is precipitated out of the solution and is removed by filtration after the cyclization reaction is completed. In various embodiments, water that is generated during the cyclization reaction may be removed using a Dean-Stark trap. Other methods known within the art may be used to remove the water such as evaporation, crystallization, distillation or any other appropriate method known by one skilled in the art. In various embodiments of the invention, water is removed as an azeotrope. In various embodiments of the invention, the neutralized L-lysine is heated in an alcohol. In various other embodiments of the invention, the neutralized L-lysine is heated in the presence of an alcohol and a catalyst. In some embodiments of the invention, the alcohol has about 2 to about 6 carbons. [0019] Non-limiting examples of alcohols include 1-propanol, 2- propanol, 1 -butanol, 2-butanol, isobutanol, 1 ,2-propanediol, 1 ,3-propanediol, 1 ,2- butanediol, 1 , 4-butanediol, all isomers of 5 carbon monoiols, diols and triols including with out limitation 1-pentanol, 1 ,2-pentanediol, 1 ,5-pentanedioI, and all isomers of 6 carbon monodiols, diols and triols including without limitation, 1- hexanol, 1 ,2-hexanedioI, 1 ,6-hθxanedioI. Other non-limiting examples of 2 to 6 carbon alcohols include glycerol, trimethylolpropane, pentaerythmtol and the like. In various embodiments, the alcohols have a single hydroxyl group. In other embodiments, the alcohols have 2 hydroxyl groups. In some embodiments, the alcohols have 3 hydroxyl groups. Non-limiting examples of glycols include propylene glycol, butylene glycol, neopental glycol and the like. [0020] In some embodiments of the invention, the catalyst is aluminum oxide (AI2O3). In various embodiments of the invention, the heating of the neutralized L-lysine in the alcohol is accomplished by reflux. In various embodiments of the invention, the heating of the alcohol and the neutralized lysine in the presence of a catalyst is accomplished by reflux. In various embodiments, the heating is at a high enough temperature to allow azeotropic removal of water with the alcohol. In various embodiments, the heating is below a temperature that polymerizes the caprolactam. In some embodiments, the heating is at temperatures from about 990C to about 2010C. In a preferred embodiment of the invention, the alcohol is 1 , 2-propanediol. In addition to the higher yields by the use of the 1 , 2-propanediol, this organic alcohol may be readily available at a bio-refinery since it may be obtained by the hydrogenation of lactic acid which may be readily available as a co-product produced from the biomass. The following are some non-limiting examples based on reaction (1).

(1)

Example 1 [0021] A stirred mixture of L-lysine hydrochloride 1 (55 g, 300 mmol) and NaOH (12 g, 300 mmol) in hexanol (1.2 L) is heated to reflux with a Dean- Stark trap used to remove H2O. The suspension is refluxed for 8 hours until all starting material is consumed (which maybe determined by 1 H NMR). The suspension is then cooled and filtered to remove byproduct NaCI. The filtrate is concentrated and the resulting crude α-amino-ε-caprolactam 2 is dissolved in water. After acidification to pH 6 with addition of concentrated HCI and partial concentration, crystals maybe formed at room temperature to afford α-amino-ε- caprolactam hydrochloride (37 g) in 75% yield.

Example 2 [0022] A stirred mixture of L-lysine hydrochloride 1 (55 g, 300 mmol) and NaOH (12 g, 300 mmol) in 1 , 2-propanediol (1.2 L) is heated to reflux. A Dean-Stark trap is used to withdraw the first 120 ml_ of condensed solvent. The reaction solution is refluxed for an additional 2 hours until all starting material is consumed (which maybe determined by 1 H NMR). The solution is cooled and is concentrated under vacuum. Ethanol is used to completely dissolve the α-amino- ε-caprolactam 2. Byproduct NaCI is removed by filtration. The filtrate is concentrated and the resulting crude α-amino-ε caprolactam 2 is dissolved in water. After acidification to pH 6 with addition of concentrated HCI and subsequent partial concentration, crystals maybe formed at room temperature to afford α-amino-ε-caprolactam hydrochloride (36.5 g) in 74% yield.

Example 3 [0023] 50 mmols of L-lysine hydrochloride 1 is neutralized with 50 mmols of NaOH and then 200 ml of ethanol is added. This mixture is heated to 2000C for eight hours. The yield of α-amino-ε-caprolactam 2 produced by this reaction is about 47%.

Example 4 [0024] 30 mmols of L-lysine hydrochloride 1 is neutralized with 30 mmols of NaOH and then 120 ml of 1-pentanol is added. This mixture is heated to 1370C and is refluxed for 60 hours. The yield of α-amino-ε-caprolactam 2 produced by this reaction is about 93%. Example 5 [0025] 30 mmols of L-lysine hydrochloride 1 is neutralized with 30 mmols of NaOH and then 120 ml of 1-hexanol is added. This mixture is heated to 1570C and is refluxed for 8 hours. The yield of α-amino-ε-caprolactam 2 produced by this reaction is about 89%.

Example 6 [0026] 300 mmols of L-lysine hydrochloride 1 is neutralized with 300 mmols of NaOH and then 1.2 L of 1-hexanol is added. This mixture is heated to 15O0C and is refluxed for 8 hours. The yield of α-amino-ε-caprolactam 2 produced by this reaction is about 91 %.

Example 7 [0027] 300 mmols of L-lysine hydrochloride 1 is neutralized with 300 mmols of NaOH and then 1.2 L of 1 , 2-propanediol is added. This mixture is heated to 1870C and is refluxed for 2 hours after removing about the 10% of the solvent when the reaction is first brought to reflux. The yield of α-amino-ε- caprolactam 2 produced by this reaction is about 96%.

Example 8 [0028] 30 mmols of L-lysine hydrochloride 1 is neutralized with 30 mmols of NaOH and then 270 mmols of AI2O3 is added, followed by the addition of 120 ml of 1-butanol. This mixture is heated to 1170C and is refluxed for six hours. The yield of α-amino-ε-caprolactam 2 produced by this reaction is about 92%.

Example 9 [0029] 30 mmols of L-lysine hydrochloride 1 is neutralized with 30 mmols of NaOH and then 270 mmols of AI2O3 is added, followed by 120 ml of 1- pentanol. This mixture is heated to 1370C and is refluxed for four hours. The yield of α-amino-ε-caprolactam 2 produced by this reaction is about 96%. [0030] Methods for deaminating organic compounds are well known in the art. Deamination processes are chosen depending on the reaction conditions and yield. In various embodiments, deamination may be accomplished by reacting the amino functional intermediate with hydroxylamine- O-sulphonic acid and KOH catalysis. The hydroxylamine-O-sulphonic acid (NH2OSO3H) may be prepared by the reaction of bis(hydroxylammonium sulfate ((NH2OH)2 H2SO4) with fuming sulphuric acid (H2SO4-SO3) (see Matsuguma et al., Inorg. Syn. 1957, 5, 122-125). In certain embodiments of the invention, the deamination reaction is run after the removal of NaCI after the completion of the cyclization reaction as described above. Deamination reactions using hydroxylamine-O-sulphonic acid have been described before but have produced low yields of ε-caprolactam (see Doldouras, G.A., Kollonitsch, J., J. Am. Chem. Soc. 1978, 100, 341-342; Ramamurthy, T.V., Ravi, S., Viswanathan, K.V. J. Labelled Compd. Rad., 1987, 25, 809-815). In accordance with the present invention, the reaction temperature is lowered to below the freezing point of water during the addition of the hydroxylamine-O-sulphonic acid. In various embodiments of the invention, the temperature is lowered to about -50C and in other embodiments, the temperature is lowered to about -2O0C. In various embodiments, the amine is washed away with a solvent. The solvent may be water or a mixture of water and a small organic alcohol. In various embodiments of the invention, the solvent is water. The following are non-limiting examples based on reaction 2 using a product created from Example 7 and producing similar yields.

Example 10 [0031] α-Amino-ε-caproiactam 2 (2.56 g, 20 mmol) is dissolved in 100 ml_ water and the solution cooled to -5°C. After addition of KOH (4.48 g, 80 mmol) followed by NH2OSO3H (4.52 g, 40 mmol), the reaction solution is stirred at -5°C for 1 h. The reaction solution is then heated to 70-75 °C and is stirred at this temperature for 1 h. The solution is again cooled to -50C followed by addition of more KOH (4.48g, 80 mmol) followed by NH2OSO3H (4.52 g, 40 mmol). After stirring at -5 0C for 1 h, the reaction solution is heated to 70-75 0C and is stirred for another 1 h. After concentration, the crude product is purified by sublimation to give 1.70 g (75%) of colorless, crystalline ε-caprolactam 3.

Example 11 [0032] After completion of the cyclization reaction (1) as described above, the NaCI is removed. 20 mmols of α-amino-ε-caprolactam 2 is placed in a reaction chamber and the temperature of the chamber is lowered below the freezing point of water to about -2O0C. 800 mmols of KOH is added and then 400 mmols of hydroxylamine-O-sulphonic acid is added. The amine is washed away using a solvent that is 240 ml of water and 160 ml of methanol. The product, ε-caprolactam 3, is then purified by sublimation and the yield is about 61 % based on L-lysine starting material.

Example 12 [0033] After completion of the cyclization reaction (1) as described above, the NaCI is removed. 20 mmols of α-amino-ε-caprolactam 2 is placed in a reaction chamber and the temperature of the chamber is lowered below the freezing point of water to about -2O0C. 800 mmols of KOH is added and then 400 mmols of hydroxylamine-O-sulphonic acid is added. The amine is washed away using a solvent that is 20 ml of water and 80 mi of methanol. The product, ε-caprolactam 3, is then purified by sublimation and the yield is about 62% based on L-lysine starting material.

Example 13 [0034] After completion of the cyclization reaction (1) as described above, the NaCI is removed. 20 mmols of α-amino-ε-caprolactam is placed in a reaction chamber and the temperature of the chamber is lowered below the freezing point of water to about -2O0C. 800 mmols of KOH is added and then 400 mmols of hydroxylamine-O-sulphonic acid is added. The amine is washed away using a solvent that is 60 ml of water and 40 ml of methanol. The product, ε-caprolactam 3, is then purified by sublimation and the yield is about 64% based on L-lysine starting material.

Example 14 [0035] After completion of the cyclization reaction (1) as described above, the NaCI is removed. 20 mmols of α-amino-ε-caprolactam 2 is placed in a reaction chamber and the temperature of the chamber is lowered below the freezing point of water to about -2O0C. 160 mmols of KOH is added and then 80 mmols of hydroxylamine-O-sulphonic acid is added. The amine is washed away using a solvent that is 60 ml of water and 40 ml of methanol. The product, ε- caprolactam 3, is then purified by sublimation and the yield is about 65% based on L-lysine starting material.

Example 15 [0036] After completion of the cyclization reaction (1) as described above, the NaCI is removed. 20 mmols of α-amino-ε-caprolactam 2 is placed in a reaction chamber and the temperature of the chamber is lowered below the freezing point of water to about -2O0C. 160 mmols of KOH is added and then 80 mmols of hydroxylamine-O-sulphonic acid is added. The amine is washed away using a solvent that is 60 ml of water and 40 ml of ethanol. The product, ε- caprolactam 3, is then purified by sublimation and the yield is about 70% based on L-lysine starting material.

Example 16 [0037] After completion of the cyclization reaction (1) as described above, the NaCI is removed. 20 mmols of α-amino-ε-caprolactam 2 is placed in a reaction chamber and the temperature of the chamber is lowered below the freezing point of water to about -50C. 160 mmols of KOH is added and then 80 mmols of hydroxylamine-O-sulphonic acid is added. The amine is washed away using a solvent that is 10O ml of water. The product, ε-caprolactam 3, is then purified by sublimation and the yield is about 75% based on L-lysine starting material. [0038] Referring to Figure 1 , a process of the present invention is illustrated by a block diagram showing biomass being converted into nylon 6. Biomass, as described earlier, which is a material produced by the growth of microorganisms, plants or animals, is supplied to the system. Examples of a biomass include agricultural products and by-products such as corn, husks, stalks, cereal crops, alfalfa, clover, grass clippings, vegetable residues, straw, maize, grain, grape, hemp, sugar cane, flax, and potatoes; forestry and paper products and by-products such as sawdust paper, cellulose, wood pulp, wood chips, pulp sludge and leaves, and other appropriate materials that are known in the art. In various embodiments of the invention, the biomass is high cellulose- containing materials. In other embodiments of the invention, the biomass is high starch-containing materials. In alternative embodiments, the biomass goes through fractionization which yields such components as cellulose, hemicellulose, lignocellulose, plant oil, and/or starch as represented by step A. In various embodiments, the box labeled "Cellulose and/or Starch" may comprise but is not limited to starch, cellulose, hemicellulose, lignocellulose, or combinations thereof and the like. Such separation or fractionization of biomass into cellulose components and/or starch is well known in the art (see U.S. Patent No. 6,022,419 to Torget et al. issued February 8, 2000; U.S. Patent No. 5,047,332 to Chahal issued September 10, 1991 and U.S. Patent No. 6,228,177 to Torget issued May 8, 2001 , U.S. Patent No. 6,620,292 to Wingerson issued September 16, 2003, and B. Kamm and M. Kamm, Biorefinery-Systems, Chem. Biochem. Eng. Q. 18 (1) 1-6 2004). In various embodiments of the invention, the biomass goes through step A can result in a combination of both cellulose components and starch. In various embodiments of the invention, the biomass is not separated but, rather, the biomass moves directly to step B. In step B of Figure 1 , cellulose components, starch, or combinations thereof are converted to a sugar such as glucose by hydrolyzsis. In various embodiments, the box labeled "Sugar" may comprise but is not limited to glucose, dextrose, xylose, sucrose, fructose, arabinose, glyercerol, other sugars or polyols known to one skilled in the art or combinations thereof and the like. In various embodiments of the invention, the raw biomass is converted to a sugar by hydrolization. In various embodiments of the invention, the hydrolyzation is an acid hydrolyzation. In other embodiments of the invention, the hydrolyzation is enzymatic hydrolization. Hydrolyzation methods that could produce a sugar such as glucose are well known in the art (see U.S. Patent No. 6,692,578 to Schmidt et al. issued February 17, 2004, U.S. Patent No. 5,868,851 to Lightner issued February 9, 1999, U.S. Patent No. 5,628,830 to Brink issued May 13, 1997, U.S. Patent No. 4,752,579 to Arena et al. issued June 21 , 1988, U.S. Patent No. 4,787,939 to Barker et al. issued November 29, 1988, U.S. Patent No. 5,221 ,357 to Brink issued June 22, 1993 and U.S. Patent No. 4,615,742 to Wright issued October 7, 1986). Depolymerization of hemicellulose produces D-xylose and L- arabinose, which can serve as alternative starting materials for microbial synthesis of chemicals. Plant oils are another component of biomass. Transesterification of plant oils leads to esterified fatty acids which maybe used as biodiesel and glycerol, which is another polyol suitable for use as a starting material in microbial synthesis. In various embodiments of the invention, step B may produce other sugars that may or may not include glucose. [0039] Since the early 1960's, Japanese companies have been perfecting fermentation of L-lysine produced from sugars such as glucose. Unlike human beings and animals, the Corynebactθrium glutamicum bacterium is able to synthesize lysine. Through classical strain optimization, the bacteria have become able to synthesize large quantities of lysine. Production takes place in fermenters in which the Corynebactθrium glutamicum bacterium converts raw sugars such as glucose, sugar cane, and/or molasses into lysine. Such processes are well known in the art (see U.S.- Patent No. 2,979,439 to Kinoshita et al. issued April 11 , 1961 , U.S. Patent No. 3,687,810 to Kurihara et al. issued August 29, 1972, U.S. Patent No. 3,707,441 to Shiio et al. issued December 26, 1972, U.S. Patent No. 3,871 ,960 to Kubota et al. issued March 18, 1975, U.S. Patent No. 4,275,157 issued to Tosaka et al. issued June 23, 1981 , U.S. Patent No. 4,601 ,829 issued to Kaneko issued July 22, 1986, U.S. Patent No. 4,623,623 issued to Nakanishi et al. issued November 18, 1986, U.S. Patent No. 4,411 ,997 issued to Shimazaki et al. issued October 25, 1983, U.S. Patent No. 5,954,411 issued to Katsumata et al. issued September 4, 1990, U.S. Patent No. 5,650,304 issued to lshii et al. issued July 22, 1997, U.S. Patent No. 5,250,423 issued to Murakami et al. issued October 5, 1993, U.S. Patent No. 4,861 ,722 issued to Sano et al. issued October 29, 1989, and Manufacturing of Stabilised Brown Juice for L-lysine Production - from University Lab Scale over Pilot Scale to Industrial Production, M. H. Thomsen et al., Chem. Biochem. Eng. Q. 18 (1) 37-46 (2004). [0040] L-lysine hydrochloride is produced by the treatment of L-lysine solutions with 10% hydrochloric acid to adjust the pH to about 4.5 to about 4.7. It is then heated with activated charcoal at about 8O0C for about 40 minutes to eliminate the color then filtered. The clear filtrate is evaporated under vacuum at about 4O0C, cooled and allowed to stand at about 40C for about 24 to about 36 hours. The precipitated crystalline L-lysine monochloric acid is separated by filtration and purified by repeated crystallization from ethanol. [0041] Step D is the cyclization of the L-lysine hydrochloric acid to α- amino-ε-caprolactam as described in the present invention from above. Such examples as 1 -9 herein and any modifications that would be apparent to one skilled in the art are conditions and reactions for step D. In various embodiments, L-lysine is not converted to L-lysine hydrochloride. In such embodiments, the neutralization step may be omitted from step D. Step E is the deaminization of α-amino-ε-caprolactam to ε-caprolactam as described herein. Examples 10-16 and any modifications that would be apparent to one skilled in the art are reactions that may be used in step E. [0042] The polymerization of ε-caprolactam to nylon 6 is step F and this reaction was invented by Paul Schlack of IG Farben in Germany on about January 28, 1938. The reaction is a ring opening polymerization from the monomer ε-caprolactam which is accomplished by heating the ε-caprolactam to about 25O0C with about 0.3% to about 10% water present. See U.S. Patent No. 2,142,007 to Schlack issued December 27, 1938 and U.S. Patent No. 2,241 ,321 to Schlack issued May 6, 1941. The polymerization of ε-caprolactam to nylon 6 is well known in the art. A non-limiting example of such polymerization is as follows: nylon 6 may be produced by hydrolytic polymerization of caprolactam, with predominant use of the VK tube (abbreviation for the. German expression "vereinfacht Kontinuierlich" which means simplified continuous) a heated vertical flow pipe. The molten caprolactam, with 0.3-5% of water, chain length regulators, and, if necessary, a dulling agent, is fed from above, and the polymer melt is discharged at the reactor bottom. Typically the VK tube is equipped with 3 heat exchangers establishing the temperature profile along the reactor. The VK-tube consists of a plug flow zone in the lower part and a mixing/evaporating zone in the top. The function of the top part is to heat up the reaction mass and to evaporate excess water thus setting the total water content in the polymer melt. The endothermic caprolactam ring opening reaction is started, followed by exothermal polyaddition and polycondensation. With the central heat exchanger, the temperature is corrected and equalized over the tube cross section. After passing the central heat exchanger, the temperature rises to about 270-2800C due to the heat of reaction. The bottom heat exchanger drops the temperature to 240-2500C, thus reaching a higher degree of polymerization in the equilibrium. Simultaneously a higher degree of caprolactam conversion to nylon 6 is achieved. Specifically designed inserts are applied evening out the dwell time over the tube cross section. Sixteen to twenty hours may be the mean dwell time in the tube. Relative solution viscosities from 2.4 to 2.8 are achieved with a single stage process (solvent: 96% sulphuric acid, concentration: 1 g/100ml, temperature: 250C). The maximum capacity may be 130 tonnes/day. In the 2- stage technology, a prepolymerizer, operated under pressure and with high water content, is followed by a final VK polymerizer operated at atmospheric pressure or vacuum. The high reaction rate of the caprolactam ring opening under the conditions in the prepolymerizer yields a low total residence time making the process suitable for very high throughput rates up to 300 tonnes/day. [0043] In various embodiments of the process as described in Figure 1 , additions may be made such that the amine that is a by-product from step E may be recycled so that the nitrogen may be added in step C as a nutrient for fermentation. In other embodiments, the amine that is a by-product in step E may be recycled so that the nitrogen may be added in step B as a nutrient for fermentation. In an alterative embodiment, one skilled in the art may precipitate the monophosphate or diphosphate salt of lysine. The sodium phosphate salt (monobasic or dibasic) generated during cyclization of lysine phosphate maybe (like ammonia above) from step E may be recycled so that the phosphorus may be added in step C as a nutrient for fermentation. [0044] In various embodiments of the invention, a portion of the biomass may be converted into lactic acid and then hydrogenated into 1 ,2- propanediol which maybe used in Step D. The process of taking biomass and converting it into lactic acid is well known in the art. (See U.S. Patent No. 6,403,844 to Zhang et al. issued July 11 , 2002, U.S. Patent No. 4,963,486 to Hang issued October 16, 1990, U.S. Patent No. 5,177,009 issued Kampen issued January 5, 1993, U.S. Patent No. 6,610,530 issued to Blank et al. issued August 26, 2003, U.S. Patent No. 5,798,237 issued to Pacatagio et al. issued August 25, 1998, and U.S. Patent No. 4,617,090 to Kumm et al. issued October 14, 1996, Zhang, Z; Jackson, J. E.; Miller, DJ. Appl. Catal. A-Gen. 2001 , 219, 89-98, Zhang, Z; Jackson, J. E.; Miller, Ind. Eng. Chem. Res. 2002, 41 , 691-696). [0045] The examples and other embodiments described herein are exemplary and are not intended to be limiting in describing the full scope of apparatus, systems, compositions, materials, and methods of this invention. Equivalent changes, modifications, variations in specific embodiments, apparatus, systems, compositions, materials and methods may be made within the scope of the present invention with substantially similar results. Such changes, modifications or variations are not to be regarded as a departure from the spirit and scope of the invention. All patents cited herein, as well as, all publications, articles, brochures and product information discussed herein, are incorporated in their entirety herein by reference: