FOR DEPOSITING A LAYER ON A SUBSTRATE

TECHNICAL FIELD

Various embodiments relate to a system and a method for depositing a layer on a substrate. BACKGROUND

It is known to deposit a layer on a substrate during semiconductor device manufacturing. The layer may be deposited to enhance the substrate, such as, for example, by improving its chemical and/or physical properties.

The substrate may be part of a solar cell (also known as a photovoltaic cell) that is operable to absorb light, such as sunlight, and generate electricity therefrom. The layer may be an antireflective coating of the solar cell which may reduce the amount of light reflected by the substrate thereby increasing the amount of light absorbed for use in generating electricity. Additionally or alternatively, the layer may be a passivating coating for the solar cell which may reduce recombination at the surface or/and bulk of the semiconductor substrate. Accordingly, the layer may enhance the performance of the solar cell.

SUMMARY

Various embodiments provide a system for depositing layers on a substrate, the system comprising: a plurality of plasma sources arranged in a sequence, each plasma source being operable to generate plasma, wherein a spatial separation between successive plasma sources is variable; and a substrate carrier operable to carry the substrate and being relatively moveable with respect to the plurality of plasma sources to successively expose the substrate to plasma from each plasma source, wherein exposing the substrate to plasma from a plasma source causes deposition of a layer on the substrate. In an embodiment, the plurality of plasma sources comprises at least three plasma sources; and wherein a first pair of successive plasma sources is separated by a first spatial separation and a second pair of successive plasma sources is separated by a second spatial separation, the first spatial separation being greater than the second spatial separation.

In an embodiment, the first pair comprises the first and second plasma sources in the sequence and the second pair comprises the second and third plasma sources in the sequence. In an embodiment, successive plasma sources are alternately separated by the first spatial separation and the second spatial separation.

In an embodiment, the first spatial separation is substantially double the second spatial separation.

In an embodiment, the first spatial separation is between 0.40 meters and 1.50 meters. In an embodiment, the first spatial separation may be between 0.75 meters and 1.25 meters, or between 0.90 meters and 1.1 meters, or about 0.90 meters. In an embodiment, the first spatial separation may be between 0.50 meters and 1.00 meter.

In an embodiment, at least one plasma source of the plurality of plasma sources is moveable relative to at least one other plasma source of the plurality of plasma sources such that the spatial separation between the at least one plasma source and the at least one other plasma source is variable. In an embodiment, each plasma source of the plurality of plasma sources is moveable relative to each other plasma source of the plurality of plasma sources such that the spatial separation between each successive plasma source is variable.

Various embodiments provide a system for depositing layers on a substrate, the system comprising: a plurality of plasma sources arranged in a sequence and comprising at least three plasma sources, each plasma source being operable to generate plasma; and a substrate carrier operable to carry the substrate and being relatively moveable with respect to the plurality of plasma sources to successively expose the substrate to plasma from each plasma source, wherein exposing the substrate to plasma from a plasma source causes deposition of a layer on the substrate, the system being operable to at least partly deactivate at least one plasma source such that the at least one plasma source causes no deposition of an effective layer on the substrate.

In an embodiment, the at least one plasma source is deactivated such that the at least one plasma source causes no deposition of a layer on the substrate.

In an embodiment, the at least one plasma source comprises only each alternate plasma source in the sequence. In an embodiment, the at least one plasma source includes the second plasma source in the sequence.

Various embodiments provide a system for depositing layers on a substrate, the system comprising: a plurality of plasma sources comprising a plurality of depositing plasma sources arranged in a sequence and a non-depositing plasma source positioned in the sequence and in-between a pair of successive depositing plasma sources, each depositing plasma source being operable to generate depositing plasma, the non-depositing plasma source being operable to generate non-depositing plasma; and a- substrate carrier operable to carry the substrate and being relatively moveable with respect to the plurality of plasma sources to successively expose the substrate to plasma from each plasma source, wherein exposing the substrate to depositing plasma from a depositing plasma source causes deposition of a layer on the substrate.

In an embodiment, exposing the substrate to non-depositing plasma from a non-depositing plasma source does not cause deposition of a layer on the substrate

In an embodiment, the pair of successive depositing plasma sources comprises the first and second depositing plasma sources in the sequence.

In an embodiment, the plurality of plasma sources further comprises a non-depositing plasma source only in-between each successive odd and even depositing plasma sources in the sequence. In an embodiment, the plurality of plasma sources further comprises a non-depositing plasma source in-between each successive depositing plasma source in the sequence.

Various embodiments provide, a system for depositing layers on a substrate, the system comprising: a plurality of plasma sources arranged in a sequence, each plasma source being operable to generate a plasma, wherein a spatial separation between a pair of successive plasma sources is between 0.40m and 1.50m; and a substrate carrier operable to carry the substrate and being relatively moveable with respect to the plurality of plasma sources to successively expose the substrate to plasma from each plasma source, wherein exposing the substrate to plasma from a plasma source causes deposition of a layer on the substrate. In an embodiment, the spatial separation between the pair of successive plasma sources may be between 0.75 meters and 1.25 meters, or between 0.90 meters and 1.1 meters, or about 0.90 meters. In an embodiment, the spatial separation between the pair of successive plasma sources may be between 0.50 meters and 1.00 meter.

In an embodiment, the pair of successive plasma sources comprises the first and second plasma sources in the sequence. In an embodiment, a spatial separation between each pair of successive plasma sources is between 0.40m and 1.50m. In an embodiment, the spatial separation between each pair of successive plasma sources may be between 0.75 meters and 1.25 meters, or between 0.90 meters and 1.1 meters, or about 0.90 meters. In an embodiment, a spatial separation between each pair of successive plasma sources is between 0.50m and 1.00m

In an embodiment, the plurality of plasma sources is substantially linearly aligned.

In an embodiment, the system is operable to control an environmental condition relating to the deposition. In an embodiment, the environmental condition is at least one of the following group: a temperature during deposition, a pressure during deposition.

In an embodiment, the system further comprises a conveyor operable to move the substrate carrier with respect to the plurality of plasma sources to successively expose the substrate to plasma from each plasma source. In an embodiment, the system is operable to vary a speed of the conveyor.

In an embodiment, the system is operable to control an operational parameter of at least one plasma source. In an embodiment, the operational parameter is at least one of the following group: a rate of plasma generation, a material composition of generated plasma, a power, a duty cycle. In an embodiment, a deposited layer comprises silicon nitride.

In an embodiment, the system is a microwave-powered plasma-enhanced chemical vapor deposition system. Various embodiments provide a method for depositing layers on a substrate, the method comprising: varying a spatial separation between successive plasma sources of a plurality of plasma sources, each plasma source being operable to generate plasma; and successively exposing the substrate to plasma generated by each of the plurality of plasma sources, wherein exposing the substrate to plasma from a plasma source causes deposition of a layer on the substrate.

Various embodiments provide a method for depositing layers on a substrate, the method comprising: successively exposing the substrate to plasma generated by each of a plurality of plasma sources, the plurality of plasma sources comprising a plurality of depositing plasma sources arranged in a sequence and a non-depositing plasma source positioned in the sequence and in-between a pair of successive depositing plasma sources, each depositing plasma source being operable to generate a depositing plasma, the non-depositing plasma source being operable to generate a non-depositing plasma, wherein exposing the substrate to depositing plasma from a depositing plasma source causes deposition of a layer on the substrate. The further features mentioned above in respect of the each above- described system are equally applicable and are restated in respect of each above-described method. BRIEF DESCRIPTION OF THE DRAWINGS

Embodiments of the invention will be better understood and readily apparent to one of ordinary skill in the art from the following written description, by way of example only, and in conjunction with the drawings, wherein like reference signs relate to like components, in which:

Figures 1A and 1 B illustrate a system for depositing a layer on a substrate in accordance with an embodiment; Figure 1A provides a schematic diagram whereas Figure 1 B provides a pictorial perspective diagram;

Figure 2 is a flow diagram of a method for depositing a layer on a substrate in accordance with an embodiment; Figures 3 and 4 are schematic diagrams of aspects of a Heating & Process chamber when configured according to a known configuration;

Figure 5 is a transmission electron microscopy (TEM) image of a substrate having three layers deposited thereon;

Figures 6A, 6B, 7A and 7B are schematic diagrams of aspects of a Heating & Process chamber when configured according to an embodiment; Figures 6A and 7A relate to one embodiment whereas Figures 6B and 7B relate to another embodiment; and,

Figures 8 to 12 illustrate experimental results relating to embodiments. DETAILED DESCRIPTION Various embodiments relate to a system and a method for depositing a layer on a substrate. Figure 1 illustrates a system 2 for depositing a layer on a substrate in accordance with an embodiment. The system 2 may be a plasma- enhanced chemical vapor deposition (PECVD) reactor. Figure 1 A provides a schematic diagram of the system 2, whereas Figure 1 B provides a pictorial illustration of the system 2. As can be seen in both Figures 1A and 1 B, the system 2 comprises a loading chamber 4, a heating & processing chamber 6, a cooling chamber 8 and an unloading chamber 10. Furthermore, the system 2 comprises a conveyor 12 which is operable to transport one or more substrate carriers 14 through each chamber 4 to 10. Each substrate carrier 14 is operable to carry one or more substrates 16. For example, each substrate carrier 14 may be operable to carry three substrates 16. Accordingly, a substrate 16 may be loaded onto one of the substrate carriers 16 and transported by the conveyor 12 through each of the following chambers in the following order: the loading chamber 4, the heating & processing chamber 6, the cooling chamber 8 and the unloading chambeMO.

It is to be understood that each chamber 4 to 10 may be configured in use to provide a controlled environment. For example, each chamber 4 to 10 may be air-tight and operable to provide a vacuum. Additionally or alternatively, the pressure inside each chamber 4 to 10 may be configurable. Additionally or alternatively, the temperature inside each chamber 4 to 10 may be configurable. Additionally or alternatively, the environment of each chamber 4 to 10 may be separately controllable or may be jointly controllable with one or more different ones of chambers 4 to 10.

The loading chamber 4 may comprise one or more heaters 18 for heating up a substrate carrier 14 having loaded thereon one or more substrates 16 (hereinafter a loaded substrate carrier). The or each heater 18 may be positioned above the conveyor in order to heat the loaded substrate carriers from above. Accordingly, the loading chamber 4 may be operable to heat-up one or more loaded substrate carriers. The heating & process chamber 6 may comprise a first portion comprising one or more heaters 18 for heating up a loaded substrate carrier. At least one heater 18 may be positioned above the conveyor in order to heat the loaded substrate carriers from above. Additionally or alternatively, at least one heater 8 may be positioned below the conveyor in order to heat the loaded substrate carriers from below. Accordingly, the first portion of the heating & process chamber 6 may be operable to further heat-up each loaded substrate carrier.

The heating & process chamber 6 may comprise a second portion comprising one or more plasma sources 20. In an embodiment, multiple plasma sources may be arranged in linear formation or sequence, i.e. arranged in a line. Whilst three plasma sources are shown in Figure 1A it is to be understood that in some other embodiments more or less than three plasma sources may be used. Each plasma source 20 may be operable to generate plasma. The exposure of the substrate 16 to the plasma from a plasma source may cause deposition of a layer of material onto the external surface of the substrate. Accordingly, such plasma may be referred to as depositing plasma, rather than, for example, non- depositing plasma. The material composition of the deposited layer may be dependent on the material composition of the plasma. Specifically, the layer composition may be dependent on the plasma composition at the area (i.e. location or region) of deposition.

In an embodiment, each plasma source 20 may be a microwave-powered plasma source, for example, a 2.5GHz microwave-powered plasma source. In an embodiment, the plasma sources may be in a remote configuration. Also, each operating parameter relating to each plasma source 20 may be separately controllable. Additionally or alternatively, the same operating parameter relating to multiple plasma 20 sources may be jointly controllable. Additionally or alternatively, multiple operating parameters relating to multiple plasma sources 20 may be jointly controllable: ^xempfary-operatin ^" g"parameters-may- ^" include-gas ^" types-, ^"' -gas-- flows, plasma power (peak and/or average) and gas ratios. An additional operational parameter may be a duty cycle of operation of a plasma source. In an embodiment, a duty cycle may represent, for a given time period, a ratio of the time during which the plasma source is on (i.e. generating plasma) verses the time during which the plasma source is off (i.e. not generating plasma). Therefore, a plasma source may operate according to a predefined time period and/or duty cycle. For example, the time period may be 16 ms and the duty cycle may be 50%. Accordingly, the plasma source may operate by turning on for 8 ms then by turning off for the following 8 ms, following which the operational cycle may repeat. It is to be understood that in some embodiments the time period and/or the duty cycle may be different values. Furthermore, the average power of a plasma source may be determined from the following expression: Average Power = Peak Power x (T ^' ime ₀ n / (Time _on ⁺ Time ₀ ff)).

In view of the above, each plasma source 20 may be operable to cause the deposition of a layer on a substrate 16 loaded onto a substrate carrier 14. Accordingly, the heating & process chamber 6 may be operable to cause the deposition of one or more layers onto the substrate 16 loaded onto the substrate carrier 14. If multiple plasma sources are arranged in a linear formation, multiple layers may be deposited in sequential order, such that latter layers are laid over (i.e. superimpose) former layers. For example, a line of three plasma sources may produce three layers deposited on-top of each other. In an embodiment, layers are deposited by plasma-enhanced chemical vapor deposition.

The cooling chamber 8 may comprise an area suitable for cooling one or more substrate carriers 14, each having loaded thereon one or more substrates 16, each having deposited thereon one or more layers. The cooling chamber 8 may comprise a cooling device operable to cool the controlled environment of the cooling chamber 8. For example, the cooling device may inject cool air into the chamber 8. In an embodiment, the cooling device may use cooling water to cool. Accordingly, the cooling chamber 8 may be operable to cool a substrate having deposited thereon one or more layers. The unloading chamber 10 may comprise an area suitable for unloading one or more substrate carriers 14 and/or one or more substrates 16. For example, substrates 16 having formed thereon one or more deposited layers may be unloaded from the unloading chamber 10. Additionally or alternatively, substrate carriers 14 carrying substrates 16 having formed thereon one or more deposited layers may be unloaded from the unloading chamber 10. Unloading may be performed manually or by an electro-mechanical unloading device (not shown). The unloading chamber 10 may be substantially open to the environment and, therefore, an airlock may be provided in-between the unloading chamber 10 and the other chambers 4 to 8, in order to isolate the unloading chamber 10.

According to the above-described system of Figures 1A and 1 B, a layer , may be deposited onto a substrate. Figure 2 illustrates a corresponding method 50 for depositing one or more layers on a substrate.

At 52, one or more substrate carriers 14, each having loaded thereon one or more substrates 16 (hereinafter loaded substrate carrier), may be heated. For example, 52 may be performed in the loading chamber 4 of Figure 1A. At 54, the one or more loaded substrate carriers may be further heated. For example, 54 may be performed in the first portion of the Heating & Process chamber 6 of Figure 1 A. At 56, one or more layers may be deposited onto each substrate of the one or more loaded substrate carriers. For example, 56 may be performed in the second portion of the Heating & Process chamber 6 of Figure 1A. At 58, the one or more loaded substrate carriers may be cooled. For example, 58 may be performed in the Cooling chamber 8 of Figure 1A. At 60, the one or more loaded substrate carriers may be unloaded and/or the substrates carried by the or each substrate carrier may be unloaded. For example, 60 may be performed in the unloading chamber 10 of Figure 1A. According to the above-described method a layer may be deposited onto a substrate.

Figures 3 and 4 illustrate in greater detail aspects of a Heating & Process chamber 60 and a Cooling chamber 80. It is to be understood that in Figures 3 and 4 the Heating & Process chamber 60 and the Cooling chamber 80 may have a known configuration. However, in corresponding Figures 6 and 7, which are discussed below, the Heating & Process chamber 60 and the Cooling chamber 80 may be configured in accordance with an embodiment.

The Heating & Process chamber 60 and the Cooling chamber 80 of Figures 3 and 4 may have corresponding features to the above-described Heating & Process chamber 6 and Cooling chamber 8 of Figure 1A, wherein corresponding features are given the same reference sign. A difference between the Heating & Process chamber 6 and the Heating & Process chamber 60 may be that the Heating & Process chamber 60 comprises a plurality of nine plasma sources 20.

Figure 4 illustrates in more detail the second portion of the Heating & Process chamber 60, i.e. the portion in which layer deposition occurs. Each plasma source 20 may be microwave powered. Accordingly, each plasma source 20 may comprise a microwave antenna 62. Also, one or more magnets 64 may be positioned in close proximity to the plasma source. Additionally, one or more ports 66 may be located in close proximity to the plasma source. In operation, a gas introduced (e.g. injected) from the ports 66 may be ionized by the microwaves of the plasma source such that a plasma is generated. In turn, this generated plasma may cause deposition ^" of a layer on a substrate, as described above.

In an embodiment, different ports 66 may introduce different gasses. For example, one of the ports 66 may be operable to introduce ammonia gas whereas another of the ports 66 may be operable to introduce silane gas. For example, a port 66 positioned furthest from the substrate 16 (i.e. positioned the other side of the plasma source 20 to the substrate) may introduce ammonia gas. Also, a port 66 positioned closer to the substrate 6 (i.e. positioned the same side of the plasma source 20 as the substrate 16) may introduce silane gas. In operation, the ammonia gas may become excited by the plasma source and the silane gas may react with the excited ammonia gas. In turn, a silicon nitride layer may then be deposited on the substrate 16 from the ammonia-silane plasma. It is to be understood that additional gases may be introduced by one or more of the ports 66. For example, hydrogen gas and/or nitrous oxide may be introduced by one or more of the ports 66, for example, to change the plasma composition or to facilitate plasma creation. Additionally or alternatively, different gases may be used instead of ammonia and silane in order that a layer of a material different to silicon nitride is deposited on the substrate. Additionally or alternatively, the relative positions of one or more of the ports 66 with respect to the substrate and/or the plasma source may vary between different embodiments. In an embodiment, the deposited layer may be doped or un-doped SiN _x , SiO _y N _y , a-Si, SiO _x or

In accordance with the above description, each plasma source 20 may be used to cause the deposition of a layer onto each substrate 16 which is conveyed beneath it by the conveyor 12. Therefore, multiple layers may be deposited on the substrate 16, one on top of each other, as the substrate 16 is conveyed beneath the plurality of plasma sources 20. In this way, a dielectric stack may be formed, comprising multiple layers 'stacked' on top of each other. It is to be understood that in some embodiments, ^~ one or more plasma sources 20 may be configured differently to one or more other plasma sources 20 such that different layers have different material properties and/or comprise one or more different materials. For example, ports 66 of one plasma source 20 may introduce different gases and/or different proportions of the same gases compared to ports 66 of one or more other plasma sources 20. For example, a first layer laid directly onto the substrate may be chosen to provide particularly good surface passivation performance since the first layer may have the largest effect on surface passivation.

It is noted that the spatial separation between each pair of adjacent plasma sources 20 is the same. Stated differently, there is no variation in the spatial separation between adjacent plasma sources 20 in the known configuration. The term 'spatial separation' is taken to mean the distance between two adjacent and successive plasma sources. For example, where the plasma source is substantially circular in cross-section, the spatial separation may be taken as a distance between a central point of two adjacent plasma sources, i.e. a central point of the circular cross- section. Where the plasma sources are in a horizontal line, the distance may be a horizontal distance. If the plasma sources have an alternative shaped cross-section, a corresponding distance may be taken as the spatial separation. For example, if the cross-section is square-shaped or irregular-shaped, the central point may be taken as the central point of the square shape or irregular shape.

Figure 5 illustrates the result of the above-described process. Specifically, Figure 5 shows a portion of a cross-section of a substrate 16 having deposited thereon three layers: a first layer 100, a second layer 102 and a third layer 104. Accordingly, the substrate 16 of Figure 5 has been exposed to a Heating & Process chamber having three plasma sources 20, such as, the Heating & Process chamber 6 of Figure 1 A. As mentioned above, Figures 6 and 7, illustrate the Heating & Process chamber 60 and the Cooling chamber 80 configured in accordance with an embodiment. Figure 6 corresponds with above-described Figure 3, whereas Figure 7 corresponds with above-described Figure 4. Further, Figures 6A and 7A relate to one embodiment, whereas Figures 6B and 7B relate to another embodiment.

Considering the embodiment of Figures 6A and 7A, the first portion of the Heating & Process chamber 60 has been modified such that a spatial separation between different pairs of adjacent (i.e. successive) plasma sources 20 may be variable, i.e. one pair may have a different spatial separation to another pair. Specifically, a spatial separation between the first plasma source 20A and the second plasma source 20B may be different from the spatial separation between each other pair of adjacent plasma sources. In an embodiment, the spatial separation between the first plasma source 20A and the second plasma source 20B may be greater than the spatial separation between each other pair of adjacent plasma sources. In an embodiment, the spatial separation between the first pair may be about double the spatial separation between other pairs.

It is to be understood that in some other embodiments, the spatial separation of one pair of adjacent plasma sources may be different from one or more other pairs of adjacent plasma sources. In an embodiment, the spatial separation of each pair of adjacent plasma sources may be different from each other pair of adjacent plasma sources. In an embodiment, the spatial separation of the first pair (i.e. 20A and 20B) may be greater than the spatial separation of any other pair. During experimentation, it was found that the separation of the first two plasma sources is most important. By changing the separation between the first and second active plasma source, significantly better passivation results can be obtained. Specifically, it was found that the first 20 nm of layer deposition on top of the substrate surface may be most important for surface passivation. In view of the above, various embodiments may provide a system for depositing layers on a substrate. The system may include a plurality of plasma sources arranged in a sequence and a substrate carrier which may be operable to carry the substrate. Each plasma source may be operable to generate plasma. Also, a spatial separation between successive plasma sources may be variable. The substrate carrier may be relatively moveable with respect to the plurality of plasma sources in order to successively expose the substrate to plasma from each plasma source. It is to be understood that exposing the substrate to plasma from a plasma source may cause deposition of a layer on the substrate. Considering Figure 6A, it is noted that the line of eight plasma sources may comprise the sequence of plasma sources. Also, the sequence may be numbered from left to right, i.e. plasma source 20A may be the first, plasma source 20B may be the second, and so on.

Further, various embodiments may provide a method for depositing layers on a substrate. The method may include varying a spatial separation between successive plasma sources of a plurality of plasma sources. Each plasma source may be operable to generate plasma. The method may also include successively exposing the substrate to plasma generated by each of the plurality of plasma sources. Exposing the substrate to plasma from a plasma source may cause deposition of a layer on the substrate. In an embodiment, a first pair of successive plasma sources may be separated by a first spatial separation and a second pair of successive plasma sources may be separated by a second spatial separation. The first spatial separation may be greater than the second spatial separation. In another embodiment, the first pair of successive plasma sources may comprise the first and second plasma sources in the sequence and the second pair comprises the second and third plasma sources in the sequence. In a further embodiment, successive plasma sources may be alternately separated by the first spatial separation and the second spatial separation: For example, the first pair may be separated by a distance A, the second pair separated by a distance B, the third pair separated by the distance A, the fourth pair separated by the distance B, and so on. The first spatial separation (e.g. distance A) may be substantially double the second spatial separation (e.g. distance B). The first spatial separation may be between about 0.40 meters and about 1.50 meters.

In an embodiment, at least one plasma source of the plurality of plasma sources may be relatively moveable with respect to at least one other plasma source of the plurality of plasma sources. Accordingly, the spatial separation between the at least one plasma source and the at least one other plasma source may be variable, i.e. can be changed during depositing and/or in-between successive depositions. In another embodiment, each plasma source of the plurality of plasma sources may be relatively moveable with respect to each other plasma source of the plurality of plasma sources such that the spatial separation between each successive plasma source is variable. For example, one or more plasma sources may be moveably mounted on a rail, such that the or each plasma source can slide along the rail. Accordingly, one or more plasma sources may be relatively moveable with respect to one or more other plasma sources in order that a spatial separation between the one or more plasma sources and the one or more other plasma sources may be variable. Additionally, various embodiments may provide a system for depositing layers on a substrate. The system may include: a plurality of plasma sources and a substrate carrier. The plurality of plasma sources may be arranged in a sequence and include at least three plasma sources. Each plasma source may be configured in use to generate plasma. The substrate carrier may be operable to carry the substrate and be relatively moveable with respect to the plurality of plasma sources. In this way, the system may be used to successively expose the substrate to plasma from each plasma source. Exposing the substrate to plasma from a plasma source may cause deposition of a layer on the substrate. The system may be operable to at least partly deactivate at least one plasma source such that the at least one plasma source causes no deposition of an effective layer on the substrate.

In view of the above, rather than increasing the spatial separation between a pair of adjacent plasma sources, it may be possible to achieve a similar effect by deactivating a plasma source in-between a pair of plasma sources positioned either side of the deactivated plasma source. Stated differently, it may be possible to use a second plasma source with a significantly lower power to achieve a similar effect without actually removing the second plasma source or increasing the spacing. Specifically, the spatial separation between the two plasma sources positioned either side of the deactivated plasma source would then have an increased spatial separation compared to the spatial separation between adjacent plasma sources.

In view of the above, the at least one deactivated plasma source may not be fully deactivated. Accordingly, the at least one deactivated plasma source may generate some plasma. However, the amount of plasma generated may be insufficient to form any effective layer on the substrate, i.e. the deposited layer is not effective at reducing reflection and/or increasing passivation, for example, surface passivation. Accordingly, the at least one deactivated plasma source may be only partly deactivated such that no layer having any appreciable effect on the physical or chemical properties of the substrate may be formed. In an embodiment, no appreciable effect may include providing no noticeable improvement of the surface passivation performance or the antireflection performance of the substrate.

In an embodiment, the at least one plasma source may be deactivated such that the at least one plasma source causes no deposition of a layer on the substrate, i.e. the at least one deactivated plasma source may be completely turned off.

In an embodiment, the at least one plasma source may consist of each alternate plasma source in the sequence. In an embodiment, the at least one plasma source may include the second plasma source in the sequence.

Considering the embodiment of Figures 6B and 7B, the first portion of the Heating & Process chamber 60 has been modified such that a spatial separation between pairs of adjacent plasma sources 20 may be larger than in the known configuration of Figures 3 and 4. Specifically, in the know configuration, the spatial separation between pairs may be between about 0.25 meters and about 0.35 meters. Alternatively, according to an embodiment, the spatial separation between pairs may be larger, for example, between about 0.40 meters and about 1.50 meters, or between about 0.75 meters and about 1.25 meters, or between about 0.90 meters and about 1.1 meters, or about 0.90 meters. In an embodiment, the spatial separation between pairs may be between about 0.50 meters and about 1.00 meter. In an embodiment, the term 'about' may be taken to mean ±0.025 meters.

In view of the above, various embodiments provide a system for depositing layers on a substrate. The system may include: a plurality of plasma sources and a substrate carrier. The plurality of plasma sources may be arranged in a sequence and each plasma source may be operable to generate a plasma. Further, a spatial separation between a pair of successive plasma sources may be between about 0.40m and about 1.50m. The substrate carrier may be operable to carry the substrate and be relatively moveable with respect to the plurality of plasma sources to successively expose the substrate to plasma from each plasma source. Exposing the substrate to plasma from a plasma source may cause deposition of a layer on the substrate. In an embodiment, the pair of successive plasma sources may include the first and second plasma sources in the sequence. In an embodiment, a spatial separation between each pair of successive plasma sources may be between about 0.40m and about 1 .50m.

The following describes a specific embodiment in greater detail. In the following embodiment, a system substantially as described with reference to Figures 1A and 1 B is used. Also, the second portion of the Heating & Process chamber 6 is configured as shown in Figures 6B and 7B, with the exception that only the first two plasma sources 20 were present.

In an embodiment, SiN _x films or coatings (i.e. layers) were deposited on planar low-resistivity (e.g. 1.5 Qcm) boron-doped (p-type) float-zone silicon wafers (i.e. substrates 16) with a thickness of approximately 280 pm. Prior to the SiN _x deposition, the samples (i.e. the silicon wafers) may receive a standard Radio Corporation of America (RCA) clean with a final hydrofluoric acid (HF) dip, plus water rinse, to ensure a clean hydrogen-terminated surface.

In an embodiment, the SiN _x films may be dynamically deposited onto each side of the silicon wafer in a commercial inline microwave-powered PECVD reactor (e.g. Roth & Rau, SiNA-XS) using two deposition runs, i.e. one run for each side of the silicon wafer. In an embodiment, the reactor may have a throughput of about five-hundred wafers per hour.

In an embodiment, the silicon wafers to be coated (i.e. with a SiN _x film) are put on the substrate carriers 14, which pass through the Heating & Process chamber 6 (i.e. the second portion) where the SiN _x deposition takes place onto the top surface (i.e. the surface facing the plasma sources 20). The substrate carriers 14 may be made of a composite material with carbon-fiber reinforcement. The substrate carriers 14 may be conditioned before the actual SiN _x deposition run, by passing them five to seven times through the system to preheat the carriers- for better SiN _x uniformity. In- an embodiment, the heaters in the loading chamber 4 and/or the first portion of the Heating & Process chamber 6 may be used for carrier conditioning. In an embodiment, the loaded carrier (i.e. the substrate carrier 14 having loaded thereon a silicon wafer 16) first gets heated in the Loading chamber 4 for about 30 seconds at about 400 °C. Next, the loaded carrier is moved (i.e. conveyed by conveyor 12) to the Heating & Process chamber 6. In the first portion of Heating & Process chamber 6, the loaded carrier may receive isothermal heating.

In an embodiment, in the deposition zone (i.e. the second portion of Heating & Process chamber 6), ammonia and silane may be uniformly fed into the reactor by gas showers located adjacent to each of the linear plasma sources, i.e. the plurality of three plasma sources arranged in linear formation. Ammonia may enter the reactor above the plasma sources and get excited. Silane may enter below the plasma sources and react with the excited ammonia. The SiN _x layer may be deposited continuously from the ammonia- silane plasma during a PECVD process.

In an embodiment, the gas flows and gas ratios may be configurable to an experimentally optimized ratio for deposition of SiN _x having a desired refractive index. For example, the total gas flow may be set to about 350 sees (standard cubic cm per second) and the gas flow ratio may be set to about 3.5. However, this may depend on the system design and/or the desired refractive index of the S ^' iN _x film. In an embodiment, the deposition temperature may be between about 200 °C to about 500 °C (e.g. about 400 °C), however, the wafer temperature may be about 50 °C lower than the set temperature. In an embodiment, the deposition pressure may be between about 0.05 mbar and about 0.4 mbar (e.g. about 0.3 mbar). The deposition temperature and/or the deposition pressure may be experimentally optimized using carrier lifetime samples. In an embodiment, the peak plasma power may be between about 500 Watts and about 4500 Watts (e.g. about 3500 Watts). - In an embodiment, the average plasma power may be between about 500 Watts and about 2500 Watts. In an embodiment, the carrier transport speed (i.e. conveyor speed) may be selected to give about 75 nm SiN _x thickness per run, for example, the transport (i.e. conveyor) speed may be between about 20 cm/min and about 300 cm/min. In an embodiment, the transport speed may be dependent upon the size of the system and/or the thickness of the film. For example, the transport speed may be set so that the cumulative thickness of the deposited layers is between about 60nm and about 80nm, (e.g. about 70nm).

Silicon nitride (a-SiN _x :H or SiN _x ) layers (also known as films or coatings), such as those deposited as described above, may be used as an antireflection coating for industrial silicon wafer solar cells. Specifically, this coating may reduce reflection losses and simultaneously provide good surface and bulk passivation. In an embodiment, the layers may be hydrogenated amorphous silicon nitride (a-SiN _x :H or SiN _x ) layers.

Silicon nitride can be used in solar research labs and manufacturing lines, and can be a mainstream industrial processing step. SiN film may provide an excellent surface passivation for lowly and moderately doped p-type and n- type crystalline silicon (c-Si), as well as highly doped n-type c-Si surfaces (such as n ⁺ emitters)

In 1996, T. Lauinger et al., "Record low surface recombination velocities on Qcm p-silicon using remote plasma silicon nitride passivation," Applied Physics Letters, vol. 68, pp. 1232-1234, Feb 1996, achieved record passivation using remote plasma a-SiN _x :H (τ _β « values up to 1.3 ms for n = 2.3) deposited statically (i.e. deposited onto a non-moving substrate) in a remote plasma deposition system. In 2002, M.J. Kerr and A. Cuevas, "Recombination at the interface between silicon and stoichiometric plasma silicon nitride," Semiconductor Science and Technology, vol. 17, pp. 166-172, Feb 2002, used the direct high-frequency (HF) plasma technique to deposit a-SiN _x :H that gave similar passivation (x _e ff values up to 1.39 ms) for stoichiometric nitride (n = 1 .9-2.0). Importantly, however, these record values of surface passivation were limited to laboratory-type static deposition systems. Stated differently, these systems involved depositing one or more layers onto static (i.e. non- moving) substrates, rather than moving (e.g. conveyed) substrates, such as those described above with reference to Figures 1 to 7.

For industrial applications, a challenge is to obtain an excellent level of both surface and bulk passivation whilst maintaining excellent antireflection coating performance of a-SiN _x :H films deposited using industrial deposition systems, i.e. systems involving moving substrates. In particular, surface passivation is becoming more and more important, as the photovoltaic industry moves towards higher-efficiency cells fabricated on thinner silicon wafers.

For inline industrial dynamic (i.e. moving substrate) deposition systems, J.D. Moschner et a/., "High-quality surface passivation of silicon solar cells in an industrial-type inline plasma silicon nitride deposition system," Progress in Photovoltaics, vol. 12, pp. 21 -31 , Jan 2004, reported effective lifetimes of up to 750 ps for Si-rich a-S ^' iN _x :H (n 2* 2.3). Embodiments can improve the passivation performance of remote plasma silicon nitride films deposited dynamically in an industrial inline PECVD machine. This can be achieved by optimization of process and hardware parameters. Specifically, a spatial separation between adjacent plasma sources can be increased (e.g. doubled) compared to known arrangements. For example, the spatial separation can be increased to between about 0.40 meters and about 1 .50 meters. Further, a spatial separation between adjacent plasma sources can be varied, i.e. the spatial separation between one (e.g. the first) pair of adjacent plasma sources can be different to (e.g. greater than) the spatial separation between another (e.g. each other) pair of adjacent plasma sources. Accordingly, the level of surface passivation obtained with silicon nitride films dynamically deposited (i.e. deposited onto a moving substrate) in an industrial microwave-powered remote PECVD reactor can be improved to levels that were previously only thought possible with static laboratory systems. The following describes a comparison between a known configuration and a configuration according to an embodiment. In the known configuration three plasma sources are used, wherein the spatial separation between each pair of adjacent plasma sources is about 0.3 meters. In the configuration according to an embodiment, two plasma sources are used, wherein the spatial separation between the adjacent plasma sources is about 0.6 meters. Other aspects of the system and method are substantially as described above with reference to Figure 4, for the known configuration, and Figure 7B, for the configuration according to an embodiment. The effective carrier lifetime of the samples (i.e. a c-Si wafer coated on both sides with a SiN _x film) was measured using a commercial effective minority carrier lifetime tester (e.g. Sinton Consulting, WCT-120), operated in either the "transient" or the "QSSPC" mode. The effective lifetime values are reported for an excess carrier density of 10 ¹⁵ cm ^"3 (unless noted otherwise).

With the known configuration of the SiNA-XS system, as-deposited effective carrier lifetimes in the range of 200-250 ps were obtained on low-resistivity p- type Si wafers (Fz, 1.5 Qcm) symmetrically passivated with a-SiN _x :H films having a refractive index in the range of 2.0-2.1. These values are comparable to values obtained by other groups on similar equipment, for example: (1 ) J.D. Moschner et a/., "High-quality surface passivation of silicon solar cells in an industrial-type inline plasma silicon nitride deposition system," Progress in Photovoltaics, vol. 12, pp. 21-31 , Jan 2004; (2) W. Soppe et ai, "Bulk and surface passivation of silicon solar cells accomplished by silicon nitride deposited on industrial scale by microwave PECVD," Progress in Photovoltaics, vol. 13, pp. 551-569, Nov 2005; and, (3) A. Cuevas et ai, "Passivation of crystalline silicon using silicon nitride", Proc. 3rd World Conference on Photovoltaic Solar Energy Conversion, Osaka, Japan, pp. 913-918, May 2003.

Figures 8 and 9 graphically show effective lifetime and upper limit surface recombination velocity for low-resistivity p-type c-Si wafers passivated with nearly-stoichiometric (Figure 8) and silicon-rich (Figure 9) SiN _x films grown with the known configuration (downward pointing triangles), and the configuration according to an embodiment (upward pointing triangles). It can be seen that the embodiment results in significantly better surface passivation, and hence can lead to higher-efficiency silicon wafer solar cells. Surface recombination velocity may provide a suitable indicator of performance since the lower the surface recombination velocity the less recombination is occurring and, therefore, the more opportunity there is for an electron-hole pair to be separately captured and used in an electric circuit before they are recombined. Thus, a lower surface recombination velocity may be better.

As an example, the lower curve in Figures 8 and 9 shows the injection level dependent effective lifetime data of a low-resistivity p-type silicon wafer symmetrically passivated at SERIS by nearly-stoichiometric (n = 2.05) a- SiN _x :H films.

The upper curves in Figures 8 and 9 were obtained with the deposition reactor according to an embodiment. It is clear from this curve that high-quality surface passivation can be achieved for nearly-stoichiometric nitride in an inline (i.e. moving substrate) PECVD machine, after making the process optimization and hardware changes detailed above. This SiN _x can be used as an antireflective coating on silicon wafer solar cells, making this film capable of realizing both high-quality passivation and high-quality antireflection properties. The AM1.5G weighted average reflectance in air of random- pyramid textured mono-Si wafers coated with this SiN _x film is about 2.3% (S. Dutta Gupta et a/., "Optimised antireflection coatings using silicon nitride on textured silicon surfaces based on measurements and multi-dimensional modeling," Proc. International Conference on Materials for Advanced Technologies (ICMAT) 201 , Singapore, Jun 2011).

Figures 8 and 9 show the effective lifetime data of low-resistivity p-type c-Si lifetime samples symmetrically passivated by Si-rich (n = 2.5) as-deposited a- SiN _x :H films, for both configurations. The effective lifetime may provide an indication of performance since the longer the lifetime of a separated electron- hole pair the more opportunity there is for the pair to be captured and used in an electric circuit before they recombine. Accordingly, a longer effective lifetime may be better. As can be seen, a lifetime value of 1.8 ms was achieved with the know configuration of the deposition reactor. In combination, the results in Figures 8 and 9 demonstrate the capability of the inline PECVD machine for high levels of surface passivation throughout the range of useful refractive indices. As described above, this has been achieved by carefully optimizing each process parameter and some proprietary hardware modifications in the reactor, i.e. increasing or varying the spatial separation between adjacent plasma sources. Specifically, the following process parameters may be optimized: total gas flow, gas ratio, deposition temperature, and deposition pressure.

Figure 10a graphically illustrates effective lifetime data (at Δη = 1 *10 ¹⁵ cm ^"3 ) of an embodiment (upwards pointing triangles) compared to the best literature results for inline (i.e. dynamically) deposited SiN _x films (solid symbols). Figure 10b pictorially illustrates a structure of the embodiment tested. As seen on Figure 10b, a p-type c-Si wafer is sandwiched in-between two deposited layer structures comprising a-SiN _x :H. In an embodiment, the wafer is an undiffused p-type c-Si. Also shown, for comparison, are record laboratory results for statically deposited SiN _x films (by the remote plasma and direct plasma deposition techniques). In Figure 10a, the effective lifetime values obtained in the embodiment are shown together with results available in the literature for inline (i.e. dynamically) deposited plasma silicon nitride films. The upper dotted line in the figure represents the results obtained with the embodiment, whereas the lower dotted line represents the trend of the results reported in the literature for inline PECVD machines similar to the one used in the embodiment. The open symbols represent the results from static depositions obtained in the above-mentioned literature. Figure 11a graphically illustrates emitter saturation current density for an embodiment illustrated in Figure 11b. As seen more particularly on Figure 11 b, the embodiment comprises a p-type c-Si wafer having n-type emitters (n+) on both sides that can be done either by diffusion or ion-implantation. This structure is then passivated on both sides with SiNx. In an embodiment, the n-type emitters are diffused with sheet resistance of 150 ohm/sq. The emitter saturation current density can be thought of as a current loss per unit area due to recombination in the volume of the emitter and at the front surface of the solar cell. Therefore, a lower emitter saturation current density can be beneficial since current losses are reduced. As seen more particularly on Figure 11a, values of emitter saturation current density (1/t _e ff - 1/T _Aug er(10 ³ s ^"1 )) are plotted against values of injection level (10 ¹⁶ cm ^"3 ).

Figure 12 graphically illustrates effective lifetime data (at An = 1 x10 ¹⁵ cm ^"3 ) for n-type c-Si wafers passivated with nearly-stoichiometric SiN _x films grown with the known method (two left bars) and the embodiment (two right bars). This also demonstrates the thermal stability of the films deposited by the embodiment, which is important for industrial solar cell applications. Figure 12 moreover shows that the films deposited by the embodiment are stable under a standard industrial firing.

In summary, the above results report effective carrier lifetimes of above 1 ms for dynamically as-deposited plasma SiN _x films on p-type Si wafers. Importantly, these results were obtained in a commercial high-throughput reactor. The improvement is the result of a hardware change in the deposition reactor relating to spatial separation that can be easily transferred to industry. It should be noted that the SiN _x films deposited using the embodiment demonstrate a very high level of surface passivation in the as-deposited state for both nearly-stoichiometric and Si-rich SiN _x films. Hence, the above results show that plasma SiN _x films with an excellent surface passivation in the as- deposited state can be deposited via an embodiment in a widely used industrial high-throughput microwave-powered PECVD reactor. An advantage of the above-described embodiments is that lab-type levels of surface passivation quality (typically achieved using static deposition) can be achieved on industrial high-volume production equipment using inline/dynamic deposition. Furthermore, the embodiments can be implemented via an adaptation of an existing industrial tool, hence, enabling fast deployment into industry.

Possible industrial applications of the above-described embodiments are silicon nitride deposition as an anti-reflection and passivation film for silicon wafer solar cells.

In the above-described embodiments, the improvements compared to known configurations may be due to the relative spacing of plasma sources in an inline system changing the growth dynamics. Additionally or alternatively, the improvements may be due to a difference in the thickness of one (e.g. the first) layer in the film compared to one or more other layers in the film.

In the above-described embodiments, the improvements compared to known configurations may be due to improved chemical passivation and/or field- effect passivation. In an embodiment, the deposited layers may improve field- effect passivation because of an inherent charge of the deposited layers. Specifically, this inherent charge may attract some charged particles (e.g. electrons) generated by the photovoltaic effect, but repel some other charged particles (e.g. holes) from the surface. Accordingly, as recombination requires the presence of both electrons and holes the recombination rate at the surface may be thus reduced. In this way, the separated charged particles may be used in an electric circuit before they recombine. For example, separated electron and hole pairs may be maintained in a separated state and used to generate electrical power before they are allowed to recombine. Stated differently, electron or hole concentration at the surface may be reduced. Accordingly, this may lead to improvements in the efficiency of electricity generation from solar energy. Therefore, solar cell efficiency may be improved.

In an embodiment, the material properties of a deposited layer may be dependent on the position of the substrate with respect to the corresponding plasma source. Increasing the spatial separation between adjacent plasma sources may mean that a plasma source causes deposition of a layer over a greater distance travelled by the substrate. In particular, plasma may be generated via a charge transfer operation in which stable atoms are transformed into highly reactive free radicals and/or ions. For example, a stable NH ₃ (i.e. ammonia) atom may form the following highly reactive free radicals: NH ₂ , NH, and N. Additionally, a stable SiH (i.e. silane) atom may form the following highly reactive free radicals: SiH ₃ , S1H2, SiH, and Si. Each free radical may have its own reactive probability, i.e. a probability of reacting (e.g. binding) with another free radical. Assuming that an ammonia-silane plasma is generated, the above-mentioned seven different types of free radicals may be produced. These seven different types of free radicals may then combine in different combinations to form a deposited silicon nitride layer. The material precise composition of the deposited layer may change depending on the free radicals used to form it. Therefore, as the substrate moves past the plasma source, the composition of the layer deposited may vary since the plasma composition may vary. Stated differently, the material composition of the plasma may vary with distance from the plasma source and, therefore, the material composition of the layer deposited at different distances from the plasma source may vary. Thus, increasing the spatial separation may in turn alter the material composition of the layer deposited from a plasma source.

In an embodiment, a non-depositing plasma treatment source may be included between the spatially separated deposition sources. In an embodiment, a non-depositing plasma source may be used to modify the growth dynamic at the deposited layer's surface. Additionally or alternatively, non-depositing plasma from a non-depositing plasma source may be used to stabilize (e.g. dilute) the depositing plasma, for example, to improve surface passivation. In an embodiment, the non-depositing plasma source may generate H2 plasma and/or NH3 plasma. For example, such modifications may increase the level of hydrogenation of the film to provide improved post-firing passivation levels especially on multicrystailine silicon materials. Considering the embodiment of Figures 6A and 7A, a non-depositing plasma source may be positioned in-between the first plasma (i.e. depositing plasma) source 20A and the second plasma (i.e. depositing plasma) source 20B. Considering the embodiment of Figures 6B and 7B, a non-depositing plasma source may be positioned in-between each pair of adjacent plasma (i.e. depositing plasma) sources 20.

In view of the above, various embodiments may provide a system for depositing layers on a substrate. The system may include: a plurality of plasma sources and a substrate carrier. The plurality of plasma sources may include a plurality of depositing plasma sources arranged in a sequence and a non-depositing plasma source positioned in the sequence and in-between a pair of successive depositing plasma sources. Each depositing plasma source may be operable to generate depositing plasma. The non-depositing plasma source may be operable to generate non-depositing plasma. The substrate carrier may be operable to carry the substrate and may be relatively moveable with respect to the plurality of plasma sources to successively expose the substrate to plasma from each plasma source. Exposing the substrate to depositing plasma from a depositing plasma source may cause deposition of a layer on the substrate. Further, various embodiments may provide a method for depositing layers on a substrate. The method may include successively exposing the substrate to plasma generated by each of a plurality of plasma sources. The plurality of plasma sources may include a plurality of depositing plasma sources arranged in a sequence and a non-depositing plasma source positioned in the sequence and in-between a pair of successive depositing plasma sources. Each depositing plasma source may be operable to generate depositing plasma. The non-depositing plasma source may be operable to generate non-depositing plasma. Exposing the substrate to depositing plasma from a depositing plasma source may cause deposition of a layer on the substrate.

In an embodiment, exposing the substrate to non-depositing plasma from a non-depositing plasma source may not cause deposition of a layer on the substrate.

In an embodiment, the pair of successive depositing plasma sources may include the first and second depositing plasma sources in the sequence. In an embodiment, the plurality of plasma sources may further comprise a non-depositing plasma source only in-between each successive odd and even depositing plasma sources in the sequence, i.e. only in-between the first and second, the third and fourth, the fifth and sixth, and so on. In an embodiment, the plurality of plasma sources may further comprise a non- depositing plasma source in-between each successive depositing plasma source in the sequence.

The above-described embodiments disclose a method to achieve a record- high level of surface passivation with SiN _x films deposited by an inline industrial high-throughput reactor. Specifically, surface recombination velocities of 14 cm/s and 4 cm/s may be obtained on low-resistivity p-type c-Si for nearly-stoichiometric and silicon-rich as-deposited SiN _x films, respectively. Also very low surface recombination velocities of 12 cm/s and 3.5 cm/s may be realized on low-resistivity n-type c-Si for nearly-stoichiometric and silicon- rich as-deposited SiN _x films, respectively.

It should be noted that SiN _x films deposited in accordance with the above- described embodiments may demonstrate a very high level of surface passivation in the as-deposited state, and the nearly-stoichiometric SiN _x films may be thermally stable in a standard industrial firing process for screen- printed contacts. Hence, these embodiments may demonstrate firing-stable plasma SiN _x films with an excellent surface passivation in the as-deposited state which can be deposited in a widely used industrial high-throughput microwave-powered PECVD reactor.

The above-described results may be obtained by making significant changes to the geometry of the industrial reactor. In some embodiments, the spatial separation of the multiple plasma sources may be doubled. This hardware change can result in SiN _x films with a significantly higher level of surface passivation.

In the above-described embodiments, the plurality of plasma sources are substantially linearly aligned. However, it is to be understood that in some other embodiments, the plurality of plasma sources may be differently arranged. For example, they may be arranged in a circular or curved formation. Furthermore, the formation may be curved vertically and/or horizontally. It is to be understood that in this case, the spatial separation may have a horizontal and a vertical component.

In the above-described embodiments, the system is operable to control an environmental condition relating to the deposition. In an embodiment, the environmental condition may be: a temperature during deposition or a pressure during deposition.

In an embodiment, the system may be operable to control an operational parameter of at least one plasma source. For example, the operational parameter may be at least one of the following group: a rate of plasma generation, a material composition of generated plasma, a plasma power. It is noted that controlling the material composition may include changing at least one material used to make the plasma and/or changing the proportion of at least one material used to make the plasma. In the above-described embodiments, the system includes a conveyor operable to move the substrate carrier with respect to the plurality of plasma sources to successively expose the substrate to plasma from each plasma source. In an embodiment, a speed of the conveyor is variable and controllable by the system.

It will be appreciated by a person skilled in the art that numerous variations and/or modifications may be made to one or more of the above-described embodiments without departing from the spirit or scope of the invention as broadly described in the appended claims. The above-described embodiments are, therefore, to be considered in all respects to be illustrative and not restrictive. It is also to be understood that one or more features of one embodiment may be combined with one or more features from one or more other embodiments in order to form one or more new embodiments, without departing from the scope of the appended claims.